WO2016142224A1 - Mélanges fongicides contenant des fongicides de type strobilurine - Google Patents

Mélanges fongicides contenant des fongicides de type strobilurine Download PDF

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Publication number
WO2016142224A1
WO2016142224A1 PCT/EP2016/054367 EP2016054367W WO2016142224A1 WO 2016142224 A1 WO2016142224 A1 WO 2016142224A1 EP 2016054367 W EP2016054367 W EP 2016054367W WO 2016142224 A1 WO2016142224 A1 WO 2016142224A1
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WO
WIPO (PCT)
Prior art keywords
methyl
phenyl
pyrazol
oxy
dimethyl
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PCT/EP2016/054367
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English (en)
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WO2016142224A8 (fr
Inventor
Ian Robert CRAIG
Wassilios Grammenos
Joachim Rheinheimer
Ana Escribano Cuesta
Lutz Brahm
Egon Haden
Original Assignee
Basf Se
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Publication date
Application filed by Basf Se filed Critical Basf Se
Priority to CN201680014851.9A priority Critical patent/CN107427005A/zh
Priority to RU2017134847A priority patent/RU2017134847A/ru
Priority to US15/556,880 priority patent/US20180235221A1/en
Priority to BR112017019117A priority patent/BR112017019117A2/pt
Priority to EP16707145.5A priority patent/EP3267797A1/fr
Publication of WO2016142224A1 publication Critical patent/WO2016142224A1/fr
Publication of WO2016142224A8 publication Critical patent/WO2016142224A8/fr

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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles

Definitions

  • the present invention relates to mixtures comprising, as active components
  • n is an integer and is 0, 1 , 2, 3, 4 or 5;
  • R which may be the same or different to any other R, is halogen, hydroxyl, carboxyl, Ci-C4-alkyl, C2-C4-alkenyl, C2-Ce-alkynyl, Ci-C4-haloalkyl, Ci-C4-alkoxy, Ci-C4-halo- alkoxy, Ci-C4-alkylsulfanyl, Ci-C4-haloalkylsulfanyl, Ci-C6-alkoxyimino-Ci-C4-alkyl, C2-C6-alkenyloxyimino-Ci-C4-alkyl , C2-C6-alkynyloxyimino-Ci-C4-alkyl, C1-C4- alkoxyimino-Ci-C4-alkyl, Ci-C6-alkoxyimino-, C2-C6-alkenyloxyimino-, C2-C6- alkynyloxyimin
  • R a which may be the same or different to any other R a , is halogen, Ci-C4-alkyl or Ci-C4-haloalkyl;
  • n is 1 , 2 or 3 in formula I.
  • R is halogen, Ci-C4-alkyl, Ci-C4-haloalkyl, Ci-C4-alkoxy, Ci-C4-haloalkoxy, Ci-C4-alkylsulfanyl, Ci-C4-haloalkylsulfanyl or C3-C6-cycloalkyl in formula I .
  • compounds of formula I are selected from
  • compounds of formula I are selected from (Z,2E)-5-[1 -(4-chlorophenyl)pyrazol-3-yl]oxy-2-methoxyimino-N,3-dimethyl-pent-3-enamide (1-1 ), (Z,2E)-5-[1 -(2,4-dichlorophenyl)pyrazol-3-yl]oxy-2-methoxyimino-N,3-dimethyl-pent-3-enamide (I-3), and (Z,2E)-5-[1 -(4-chloro-2-fluoro-phenyl)pyrazol-3-yl]oxy-2-methoxyimino-N,3-dimethyl- pent-3-enamide (1-13).
  • component 1 in the inventive mixtures is selected from (Z,2E)-5-[1 -(4-chlo- rophenyl)pyrazol-3-yl]oxy-2-methoxyimino-N,3-dimethyl-pent-3-enamide (1-1 ),
  • the components 1 ) and 2) in these mixtures are present in a synergistically effective amount.
  • the invention also relates to a method for controlling phytopathogenic harmful fungi using mixtures of at least one compound I and and at least one pesticide I I and to the use of compounds I and pesticides I I for preparing such mixtures, and to compositions comprising these mixtures and seed comprising these mixtures or coated with these mixtures.
  • compositions comprising at least one compound I and at least one pesticide I I .
  • Agriculturally acceptable salts of the compounds I encompass especially the salts of those cations or the acid addition salts of those acids whose cations and anions, respectively, have no adverse effect on the fungicidal action of the compounds I.
  • Suitable cations are thus in particular the ions of the alkali metals, preferably sodium and potassium, of the alkaline earth metals, preferably calcium, magnesium and barium, of the transition metals, preferably manganese, copper, zinc and iron, and also the ammonium ion which, if desired, may carry 1 to 4 Ci-C4-alkyl substituents and/or one phenyl or benzyl substituent, preferably diisopropylammo- nium, tetramethylammonium, tetrabutylammonium, trimethylbenzylammonium, furthermore phosphonium ions, sulfonium ions, preferably tri(Ci-C4-alkyl)sulfonium, and sul
  • Anions of useful acid addition salts are primarily chloride, bromide, fluoride, hydrogensulfate, sulfate, dihydrogenphosphate, hydrogenphosphate, phosphate, nitrate, bicarbonate, carbonate, hexafluorosilicate, hexafluorophosphate, benzoate, and the anions of Ci-C4-alkanoic acids, preferably formate, acetate, propionate and butyrate. They can be formed by reacting a compound I with an acid of the corresponding anion, preferably of hydrochloric acid, hydrobromic acid, sulfuric acid, phosphoric acid or nitric acid.
  • the scope of the present invention includes mixtures of the (R)- and (S)-isomers and the racemates of compounds I and/or pesticides I I having one or more chiral centers.
  • atrope isomers of compounds I and/or I I may be present. They also form part of the subject matter of the invention.
  • the pesticides II described by lUPAC nomenclature, their preparation and their fungicidal activity are also known (WO 13/084223; WO 13/162072; WO 13/162077; WO 14/051 161 , WO 14/051 165, WO 14/098201 ).
  • Table A Binary Mixtures A-1 to A-198 comprising as active ingredients one compound I as defined and numbered above as component 1 ) (Co. 1 ) and one pesticide II as defined and numbered above as component 2) (Co. 2).
  • the mixtures comprise, as active ingredients, component 1) selected from compounds 1-1 and I-3 and component 2) selected from pesticides 11-1, II-2, 11—3 , II-4, II-5 and 11-11 as defined above, preferably in a weight ratio of from 50 : 1 to 1: 50; more preferably if from 20 : 1 to 1 : 20.
  • the mixtures and compositions thereof according to the invention can, in the use form as fungicides, also be present together with other active substances, e. g. with herbicides, insecticides, growth regulators, fungicides or else with fertilizers, as pre-mix or, if appropriate, not until immeadiately prior to use (tank mix).
  • the order of application is not essential for working of the present invention.
  • the time between both applications may vary e. g. between 2 hours to 7 days.
  • the weight ratio of the component 1 ) and the component 2) generally depends from the properties of the active components used, usually it is in the range of from 1 :10,000 to 10,000:1 , often it is in the range of from 1 :100 to 100:1 , regularly in the range of from 1 :50 to 50:1 , preferably in the range of from 1 :20 to 20:1 , more preferably in the range of from 1 :10 to 10:1 , even more preferably in the range of from 1 :4 to 4:1 and in particular in the range of from 1 :2 to 2:1 .
  • the weight ratio of the component 1 ) and the component 2) usually is in the range of from 1000:1 to 1 :1 , often in the range of from 100: 1 to 1 :1 , regularly in the range of from 50:1 to 1 :1 , preferably in the range of from 20:1 to 1 :1 , more preferably in the range of from 10:1 to 1 :1 , even more preferably in the range of from 4:1 to 1 :1 and in particular in the range of from 2:1 to 1 :1 .
  • the weight ratio of the component 1 ) and the component 2) usually is in the range of from 20,000:1 to 1 :10, often in the range of from 10,000:1 to 1 :1 , regularly in the range of from 5,000:1 to 5:1 , preferably in the range of from 5,000:1 to 10:1 , more preferably in the range of from 2,000:1 to 30:1 , even more preferably in the range of from 2,000:1 to 100:1 and in particular in the range of from 1 ,000:1 to 100:1.
  • the weight ratio of the component 1 ) and the component 2) usually is in the range of from 1 :1 to 1 :1000, often in the range of from 1 :1 to 1 :100, regularly in the range of from 1 :1 to 1 :50, preferably in the range of from 1 :1 to 1 :20, more preferably in the range of from 1 :1 to 1 :10, even more preferably in the range of from 1 :1 to 1 :4 and in particular in the range of from 1 :1 to 1 :2.
  • the weight ratio of the component 1 ) and the component 2) usually is in the range of from 10:1 to 1 :20,000, often in the range of from 1 :1 to 1 :10,000, regularly in the range of from 1 :5 to 1 :5,000, preferably in the range of from 1 :10 to 1 :5,000, more preferably in the range of from 1 :30 to 1 :2,000, even more preferably in the range of from 1 :100 to 1 :2,000 to and in particular in the range of from 1 :100 to 1 :1 ,000.
  • the mixtures comprise besides one compound I and one pesticide II as component 3) a further pesticide III (being different than the pesticide II), preferably in a synergistically effective amount.
  • a further pesticide III being different than the pesticide II
  • Another embodiment relates to mixtures wherein the component 3) is a further pesticide III selected from groups A) to O):
  • Inhibitors of complex III at Q 0 site e. g. strobilurins: azoxystrobin (A.1 .1 ), coumethoxy- strobin (A.1 .2), coumoxystrobin (A.1.3), dimoxystrobin (A.1.4), enestroburin (A.1.5), fenaminstrobin (A.1 .6), fenoxystrobin/flufenoxystrobin (A.1 .7), fluoxastrobin (A.1 .8), kresoxim-methyl (A.1 .9), mandestrobin (A.1.10), metominostrobin (A.1.1 1 ), orysastrobin
  • inhibitors of complex II e. g. carboxamides: benodanil (A.3.1 ), benzovindiflupyr (A.3.2), bixafen (A.3.3), boscalid (A.3.4), carboxin (A.3.5), fenfuram (A.3.6), fluopyram (A.3.7), flutolanil (A.3.8), fluxapyroxad (A.3.9), furametpyr (A.3.10), isofetamid (A.3.1 1 ), isopyrazam (A.3.12), mepronil (A.3.13), oxycarboxin (A.3.14), penflufen (A.3.14), penthiopyrad (A.3.15), sedaxane (A.3.16), tecloftalam (A.3.17), thifluzamide (A.3.18), N-(4'- trifluoromethylthiobiphenyl-2-yl)-3-difluoromethyl-1-methyl-1 H-pyrazole-4
  • respiration inhibitors e. g. complex I, uncouplers: diflumetorim (A.4.1 ), (5,8-difluoro- quinazolin-4-yl)- ⁇ 2-[2-fluoro-4-(4-trifluoromethylpyridin-2-yloxy)-phenyl]-ethyl ⁇ -amine (A.4.2); nitrophenyl derivates: binapacryl (A.4.3), dinobuton (A.4.4), dinocap (A.4.5), fluazinam (A.4.6); ferimzone (A.4.7); organometal compounds: fentin salts, such as fentin-acetate (A.4.8), fentin chloride (A.4.9) or fentin hydroxide (A.4.10); ametoctradin (A.4.1 1 ); and silthiofam (A.4.12);
  • fentin salts such as fentin-acetate (A.4.8), fentin chloride (A.
  • DMI fungicides triazoles: azaconazole (B.1.1 ), bitertanol
  • fluquinconazole (B.1 .10), flusilazole (B.1 .1 1 ), flutriafol (B.1 .12), hexaconazole (B.1 .13), imibenconazole (B.1 .14), ipconazole (B.1.15), metconazole (B.1 .17), myclobutanil (B.1 .18), oxpoconazole (B.1 .19), paclobutrazole (B.1.20), penconazole (B.1 .21 ), propiconazole (B.1.22), prothioconazole (B.1 .23), simeconazole (B.1.24), tebuconazole (B.1.25), tetraconazole (B.1.26), triadimefon (B.1.27), triadimenol (B.1.28), triticonazole (B.1 .29), uniconazole (
  • benalaxyl (C.1.1 ), benalaxyl-M (C.1 .2), kiralaxyl (C.1 .3), metalaxyl (C.1 .4), metalaxyl-M (mefenoxam, C.1 .5), ofurace (C.1.6), oxadixyl (C.1 .7);
  • hymexazole C.2.1
  • octhilinone C.2.2
  • oxolinic acid C.2.3
  • bupirimate C.2.4
  • 5- fluorocytosine C.2.5
  • 5-fluoro-2-(p-tolylmethoxy)pyrimidin-4-amine C.2.6
  • 5-fluoro-2-(4- fluorophenylmethoxy)pyrimidin-4-amine C.2.7
  • tubulin inhibitors such as benzimidazoles, thiophanates: benomyl (D1.1 ), carbendazim
  • triazolopyrimidines 5-chloro-7-(4-methylpiperidin-1-yl)-6-(2,4,6-trifluorophenyl)-[1 ,2,4]tri- azolo[1 ,5-a]pyrimidine (D1 .6);
  • diethofencarb (D2.1 ), ethaboxam (D2.2), pencycuron (D2.3), fluopicolide (D2.4), zoxamide (D2.5), metrafenone (D2.6), pyriofenone (D2.7);
  • - methionine synthesis inhibitors anilino-pyrimidines: cyprodinil (E.1.1 ), mepanipyrim (E.1 .2), pyrimethanil (E.1 .3);
  • blasticidin-S (E.2.1 ), kasugamycin (E.2.2), kasugamycin
  • fluoroimid F.1.1
  • iprodione F.1.2
  • procymidone F.1 .3
  • vinclozolin F.1 .4
  • fenpiclonil F.1.5
  • fludioxonil F.1 .6
  • quinoxyfen F.2.1 ;
  • edifenphos G.1.1
  • iprobenfos G.1.2
  • pyrazophos G.1.3
  • isoprothiolane G.1.4
  • dicloran G.2.1
  • quintozene G.2.2
  • tecnazene G.2.3
  • tolclofos-methyl G.2.4
  • biphenyl G.2.5
  • chloroneb G.2.6
  • etridiazole G.2.7
  • dimethomorph G.3.1
  • flumorph G.3.2
  • mandipropamid G.3.3
  • pyrimorph G.3.4
  • benthiavalicarb G.3.5
  • iprovalicarb G.3.6
  • valifenalate G.3.7
  • N-(1-(1-(4-cyano-phenyl)ethanesulfonyl)-but-2-yl) carbamic acid-(4- fluorophenyl) ester G.3.8
  • organochlorine compounds e. g. phthalimides, sulfamides, chloronitriles: anilazine (H.3.1 ), chlorothalonil (H.3.2), captafol (H.3.3), captan (H.3.4), folpet (H.3.5), dichlofluanid (H.3.6), dichlorophen (H.3.7), hexachlorobenzene (H.3.8), pentachlorphenole (H.3.9) and its salts, phthalide (H.3.10), tolylfluanid (H.3.1 1 ), N-(4-chloro-2-nitro-phenyl)-N-ethyl-4-methyl- benzenesulfonamide (H.3.12);
  • guanidine H.4.1
  • dodine H.4.2
  • dodine free base H.4.3
  • guazatine H.4.4
  • guazatine-acetate H.4.5
  • iminoctadine H.4.6
  • iminoctadine-triacetate H.4.7
  • iminoctadine-tris(albesilate) H.4.8
  • dithianon H.4.9
  • 2,6-dimethyl-1 H,5H- [1 ,4]dithiino[2,3-c:5,6-c']dipyrrole-1 ,3,5,7(2H,6H)-tetraone H.4.10;
  • prohexadione-calcium J.1 .5
  • phosphonates fosetyl (J.1 .6), fosetyl-aluminum (J.1.7), phosphorous acid and its salts (J.1 .8), potassium or sodium bicarbonate (J.1.9);
  • Microbial pesticides with fungicidal, bactericidal, viricidal and/or plant defense activator activity Ampelomyces quisqualis, Aspergillus flavus, Aureobasidium pullulans, Bacillus altitudinis, B. amyloliquefaciens, B. megaterium, B. mojavensis, B. mycoides, B.
  • pumilus B. simplex, B. solisalsi, B. subtilis, B. subtiHs Msx. amyloliquefaciens, Candida oleophila, C. saitoana, Clavibacter michiganensis (bacteriophages), Coniothyrium minitans, Cryphonectria parasitica, Cryptococcus albidus, Dilophosphora alopecuri, Fusarium oxysporum, Clonostachys rosea f. catenulate (also named Gliocladium catenulatum), Gliocladium roseum, Lysobacter antibioticus, L. enzymogenes,
  • violaceusniger Talaromyces flavus, Trichoderma asperelloides, T. asperellum, T. atroviride, T. fertile, T. gamsii, T. harmatum, T. harzianum, T. polysporum, T. stromaticum, T. virens, T. viride, Typhula phacorrhiza, Ulocladium oudemansii, Verticillium dahlia, zucchini yellow mosaic virus (avirulent strain);
  • activator activity harpin protein, Reynoutria sachalinensis extract
  • Agrobacterium radiobacter Bacillus cereus, B. firmus, B. thuringiensis, B. thuringiensis ssp. aizawai, B. t. ssp. israelensis, B. t. ssp. galleriae, B. t. ssp. kurstaki, B. t. ssp. tenebrionis, Beauveria bass/ana, B. brongniartii, Burkholderia spp., Chromobacterium subtsugae, Cydia pomonella granulovirus (CpGV), Cryptophlebia leucotreta
  • HearNPV Helicoverpa zea nucleopolyhedrovirus
  • HzNPV Helicoverpa zea single capsid nucleopolyhedrovirus
  • HzSNPV Helicoverpa zea single capsid nucleopolyhedrovirus
  • Metarhizium anisopliae Metarhizium anisopliae, Metarhizium anisopliae var. anisopliae, M. anisopliae var. acridum, Nomuraea rileyi, Paecilomyces fumosoroseus, P. ///acinus, Paenibacillus popilliae, Pasteur/a spp., P. nishizawae, P. penetrans, P. ramosa, P. thornea, P. usgae, Pseudomonas fluorescens, Spodoptera littoralis nucleopolyhedrovirus (SpliNPV), Steinernema carpocapsae, S. feltiae, S. kraussei, Streptomyces ga/bus, S. micro flavus,
  • Microbial pesticides with plant stress reducing, plant growth regulator, plant growth promoting and/or yield enhancing activity Azospirillum amazonense, A. brasilense, A. lipoferum, A. irakense, A. halopraeferens, Bradyrhizobium spp., B. elkanii, B. japoni- cum, B. liaoningense, B. lupini, Delftia acidovorans, Glomus intraradices, Mesorhizo- b/um spp., Rhizobium leguminosarum bv. phaseoli, R. I. bv. trifolii, R. I. bv. viciae, R. tropici, Sinorhizobium melilotr,
  • abscisic acid (M.1 .1 ), amidochlor, ancymidol, 6-benzylaminopurine, brassinolide, butralin, chlormequat, chlormequat chloride, choline chloride, cyclanilide, daminozide, dikegulac, dimethipin, 2,6-dimethylpuridine, ethephon, flumetralin, flurprimidol, fluthiacet, forchlorfenuron, gibberellic acid, inabenfide, indole-3-acetic acid , maleic hydrazide, mefluidide, mepiquat, mepiquat chloride, naphthaleneacetic acid, N-6-benzyladenine, paclobutrazol, prohexadione, prohexadione-calcium, prohydrojasmon, thidiazuron, triapenthenol, tributyl phosphorotrithioate,
  • acetochlor N.1.1
  • alachlor butachlor, dimethachlor, dimethenamid (N.1 .2), flufenacet (N.1 .3), mefenacet (N.1.4), metolachlor (N.1.5), metazachlor (N.1 .6),
  • napropamide naproanilide, pethoxamid, pretilachlor, propachlor, thenylchlor;
  • fluazifop N.3.3
  • haloxyfop N.3.4
  • metamifop propaquizafop
  • quizalofop quizalofop-P- tefuryl
  • EPTC esprocarb, molinate, orbencarb, phenmedipham (N.5.1 ), prosulfocarb, pyributicarb, thiobencarb, triallate;
  • acifluorfen N.8.1
  • aclonifen bifenox
  • diclofop diclofop
  • ethoxyfen fomesafen
  • imidazolinones imazamethabenz, imazamox (N.10.1 ), imazapic (N.10.2), imazapyr (N.10.3), imazaquin (N.10.4), imazethapyr (N.10.5);
  • - phenoxy acetic acids clomeprop, 2,4-dichlorophenoxyacetic acid (2,4-D) (N.1 1 .1 ), 2,4-DB, dichlorprop, MCPA, MCPA-thioethyl, MCPB, Mecoprop;
  • - pyridines aminopyralid, clopyralid (N.12.1 ), diflufenican, dithiopyr, fluridone, fluroxypyr
  • - sulfonyl ureas amidosulfuron, azimsulfuron, bensulfuron (N.13.1 ), chlorimuron-ethyl (N.13.2), chlorsulfuron, cinosulfuron, cyclosulfamuron (N.13.3), ethoxysulfuron, flazasulfuron, flucetosulfuron, flupyrsulfuron, foramsulfuron, halosulfuron, imazosulfuron, iodosulfuron (N.13.4), mesosulfuron (N.13.5), metazosulfuron, metsulfuron-methyl (N.13.6), nicosulfuron (N.13.7), oxasulfuron, primisulfuron, prosulfuron, pyrazosulfuron, rimsulfuron (N.13.8), sulfometuron, sulfos
  • ureas chlorotoluron, daimuron, diuron (N.15.1 ), fluometuron, isoproturon, linuron, metha- benzthiazuron, tebuthiuron;
  • acetolactate synthase inhibitors bispyribac-sodium, cloransulam-methyl, diclosulam, florasulam (N.16.1 ), flucarbazone, flumetsulam, metosulam, ortho-sulfamuron, penoxsulam, propoxycarbazone, pyribambenz-propyl, pyribenzoxim, pyriftalid, pyriminobac-methyl, pyrimisulfan, pyrithiobac, pyroxasulfone (N.16.2), pyroxsulam;
  • amicarbazone amicarbazone, aminotriazole, anilofos, beflubutamid, benazolin,
  • organo(thio)phosphates acephate (0.1 .1 ), azamethiphos (0.1.2), azinphos-methyl (0.1.3), chlorpyrifos (0.1.4), chlorpyrifos-methyl (0.1 .5), chlorfenvinphos (0.1.6), diazinon (0.1.7), dichlorvos (0.1.8), dicrotophos (0.1 .9), dimethoate (0.1.10), disulfoton (0.1.1 1 ), ethion (0.1.12), fenitrothion (0.1.13), fenthion (0.1 .14), isoxathion (0.1.15), malathion (0.1.16), methamidophos (0.1.17), methidathion (0.1 .18), methyl-parathion (0.1 .19), mevinphos (0.1.20), monocrotophos (0.1.21 ), oxydemeton-methyl (0.1.22), paraoxon (0.1.23), parathion (0.1.24
  • phosphamidon (0.1 .28), phorate (0.1.29), phoxim (0.1.30), pirimiphos-methyl (0.1 .31 ), profenofos (0.1.32), prothiofos (0.1.33), sulprophos (0.1.34), tetrachlorvinphos (0.1 .35), terbufos (0.1 .36), triazophos (0.1.37), trichlorfon (0.1 .38);
  • allethrin (0.3.1 ), bifenthrin (0.3.2), cyfluthrin (0.3.3), cyhalothrin (0.3.4),
  • cyphenothrin (0.3.5), cypermethrin (0.3.6), alpha-cypermethrin (0.3.7), beta-cypermethrin (0.3.8), zeta-cypermethrin (0.3.9), deltamethrin (0.3.10), esfenvalerate (0.3.1 1 ), etofenprox (0.3.1 1 ), fenpropathrin (0.3.12), fenvalerate (0.3.13), imiprothrin (0.3.14), lambda- cyhalothrin (0.3.15), permethrin (0.3.16), prallethrin (0.3.17), pyrethrin I and II (0.3.18), resmethrin (0.3.19), silafluofen (O.3.20), tau-fluvalinate (0.3.21 ), tefluthrin (0.3.22), tetramethrin (0.3.23), tralomethrin (0.3.
  • chitin synthesis inhibitors benzoylureas: chlorfluazuron (0.4.1 ), cyramazin (0.4.2), diflubenzuron (0.4.3), flucycloxuron (0.4.4), flufenoxuron (0.4.5), hexaflumuron (0.4.6), lufenuron (0.4.7), novaluron (0.4.8), teflubenzuron (0.4.9), triflumuron (0.4.10); buprofezin (0.4.1 1 ), diofenolan (0.4.12), hexythiazox (0.4.13), etox- azole (0.4.14), clofentazine (0.4.15); b) ecdysone antagonists: halofenozide (0.4.16), methoxyfenozide (0.4.17), tebufenozide (0.4.18), azadirachtin (0.4.19); c) juvenoids:
  • pyriproxyfen O.4.20
  • methoprene 0.4.21
  • fenoxycarb 0.4.22
  • d lipid biosynthesis inhibitors: spirodiclofen (0.4.23), spiromesifen (0.4.24), spirotetramat (0.4.24);
  • - nicotinic receptor agonists/antagonists compounds clothianidin (0.5.1 ), dinotefuran (0.5.2), flupyradifurone (0.5.3), imidacloprid (0.5.4), thiamethoxam (0.5.5), nitenpyram (0.5.6), acetamiprid (0.5.7), thiacloprid (0.5.8), 1-2-chloro-thiazol-5-ylmethyl)-2-nitrimino-3,5- dimethyl-[1 ,3,5]triazinane (0.5.9);
  • endosulfan 0.6.19, ethiprole (0.6.2), fipronil (0.6.3),
  • vaniliprole (0.6.4), pyrafluprole (0.6.5), pyriprole (0.6.6), 5-amino-1-(2,6-dichloro-4-methyl- phenyl)-4-sulfinamoyl-1 H-pyrazole-3-carbothioic acid amide (0.6.7);
  • cyhexatin 0.1 1 .1
  • diafenthiuron 0.1 1.2
  • fenbutatin oxide 0.1 1.3
  • propargite 0.1 1 .4
  • cryomazine (0.12.1 );
  • chlorantraniliprole 0.15.1
  • cyantraniliprole 0.15.2
  • flu- bendiamide 0.15.3
  • N-[4-chloro-2-[(di- ethyl-lambda-4-sulfanylidene)carbamoyl]-6-methyl-phenyl]-2-(3-chloro-2-pyn oromethyl)pyrazole-3-carboxamide 0.15.5
  • pyridalyl 0.16.5
  • pymetrozine 0.16.6
  • sulfur 0.16.7
  • thiocyclam 0.116.8
  • cyenopyrafen (0.16.9)
  • flupyrazofos O.16.10
  • cyflumetofen 0.16.1 1
  • amidoflumet 0.16.12
  • imicyafos 0.16.13
  • bistrifluron 0.16.14
  • pyrifluquinazon 0.16.15)
  • component 3 The active substances referred to as component 3, their preparation and their activity e. g. against harmful fungi is known (cf.: https://www.alanwood.net/pesticides/); these substances are commercially available.
  • the compounds described by lUPAC nomenclature, their preparation and their pesticidal activity are also known (cf. Can. J. Plant Sci.
  • ternary mixtures AA-1 to AA-198 which comprise component 1 and component 2 as listed in each row of Table A (A-1 to A-198) and in addition in each case as component 3, the further pesticide azoxystrobin.
  • ternary mixtures AB-1 to AB-198 which comprise component 1 and component 2 as listed in each row of Table A (A-1 to A-198) and in addition in each case as component 3, the further pesticide kresoxim-methyl.
  • Particularly preferred are the following ternary mixtures AC-1 to AC-198 which comprise component 1 and component 2 as listed in each row of Table A (A-1 to A-198) and in addition in each case as component 3, the further pesticide mandestrobin.
  • ternary mixtures AD-1 to AD-198 which comprise component 1 and component 2 as listed in each row of Table A (A-1 to A-198) and in addition in each case as component 3, the further pesticide metaminostrobin.
  • ternary mixtures AE-1 to AE-198 which comprise component 1 and component 2 as listed in each row of Table A (A-1 to A-198) and in addition in each case as component 3, the further pesticide picoxystrobin.
  • ternary mixtures AF-1 to AF-198 which comprise component 1 and component 2 as listed in each row of Table A (A-1 to A-198) and in addition in each case as component 3, the further pesticide pyraclostrobin.
  • ternary mixtures AG-1 to AG-198 which comprise component 1 and component 2 as listed in each row of Table A (A-1 to A-198) and in addition in each case as component 3, the further pesticide trifloxystrobin.
  • ternary mixtures AH-1 to AH-198 which comprise component 1 and component 2 as listed in each row of Table A (A-1 to A-198) and in addition in each case as component 3, the further pesticide benzovindiflupyr.
  • ternary mixtures AI-1 to AI-198 which comprise component 1 and component 2 as listed in each row of Table A (A-1 to A-198) and in addition in each case as component 3, the further pesticide bixafen.
  • ternary mixtures AJ-1 to AJ-198 which comprise component 1 and component 2 as listed in each row of Table A (A-1 to A-198) and in addition in each case as component 3, the further pesticide boscalid.
  • ternary mixtures AK-1 to AK-198 which comprise component 1 and component 2 as listed in each row of Table A (A-1 to A-198) and in addition in each case as component 3, the further pesticide fluopyram.
  • ternary mixtures AL-1 to AL-198 which comprise component 1 and component 2 as listed in each row of Table A (A-1 to A-198) and in addition in each case as component 3, the further pesticide fluxapyroxad.
  • ternary mixtures AM-1 to AM-198 which comprise component 1 and component 2 as listed in each row of Table A (A-1 to A-198) and in addition in each case as component 3, the further pesticide 3-(difluoromethyl)-1-methyl-/V-(1 ,1 ,3-tri- methylindan-4-yl)pyrazole-4-carboxamide.
  • ternary mixtures AN-1 to AN-198 which comprise component 1 and component 2 as listed in each row of Table A (A-1 to A-198) and in addition in each case as component 3, the further pesticide 3-(trifluoromethyl)-1 -methyl-/V-(1 ,1 ,3-tri- methylindan-4-yl)pyrazole-4-carboxamide.
  • ternary mixtures AO-1 to AO-198 which comprise component 1 and component 2 as listed in each row of Table A (A-1 to A-198) and in addition in each case as component 3, the further pesticide 1 , 3-d im ethyl- ⁇ (1 ,1 ,3-trimethylindan- 4-yl)pyrazole-4-carboxamide.
  • ternary mixtures AO-1 to AO-198 which comprise component 1 and component 2 as listed in each row of Table A (A-1 to A-198) and in addition in each case as component 3, the further pesticide 3-(trifluoromethyl)-1 ,5-dimethyl-/V-(1 ,1 ,3- trimethylindan ⁇ -yl ⁇ pyrazole ⁇ -carboxamide.
  • ternary mixtures AP-1 to AP-198 which comprise component 1 and component 2 as listed in each row of Table A (A-1 to A-198) and in addition in each case as component 3, the further pesticide 1 ,3,5-tri-methyl-/V-(1 ,1 ,3-trimethylindan-4- y I ) py razol e-4-ca rboxa m i d e .
  • ternary mixtures AQ-1 to AQ-198 which comprise component 1 and component 2 as listed in each row of Table A (A-1 to A-198) and in addition in each case as component 3, the further pesticide cyproconazole.
  • ternary mixtures AR-1 to AR-198 which comprise component 1 and component 2 as listed in each row of Table A (A-1 to A-198) and in addition in each case as component 3, the further pesticide difenoconazole.
  • ternary mixtures AS-1 to AS-198 which comprise component 1 and component 2 as listed in each row of Table A (A-1 to A-198) and in addition in each case as component 3, the further pesticide epoxiconazole.
  • ternary mixtures AT-1 to AT-198 which comprise component 1 and component 2 as listed in each row of Table A (A-1 to A-198) and in addition in each case as component 3, the further pesticide metconazole.
  • ternary mixtures AU-1 to AU-198 which comprise component 1 and component 2 as listed in each row of Table A (A-1 to A-198) and in addition in each case as component 3, the further pesticide propiconazole.
  • ternary mixtures AV-1 to AV-198 which comprise component 1 and component 2 as listed in each row of Table A (A-1 to A-198) and in addition in each case as component 3, the further pesticide prothioconazole.
  • ternary mixtures AW-1 to AW-198 which comprise component 1 and component 2 as listed in each row of Table A (A-1 to A-198) and in addition in each case as component 3, the further pesticide tebuconazole.
  • ternary mixtures AX-1 to AX-198 which comprise component 1 and component 2 as listed in each row of Table A (A-1 to A-198) and in addition in each case as component 3, the further pesticide triticonazole.
  • ternary mixtures AY-1 to AY-198 which comprise component 1 and component 2 as listed in each row of Table A (A-1 to A-198) and in addition in each case as component 3, the further pesticide fenpropimorph.
  • ternary mixtures AZ-1 to AZ-198 which comprise component 1 and component 2 as listed in each row of Table A (A-1 to A-198) and in addition in each case as component 3, the further pesticide fenpropidin.
  • ternary mixtures AAA-1 to AAA-198 which comprise component 1 and component 2 as listed in each row of Table A (A-1 to A-198) and in addition in each case as component 3, the further pesticide spiroxamine.
  • ternary mixtures AAF-1 to AAF-198 which comprise component 1 and component 2 as listed in each row of Table A (A-1 to A-198) and in addition in each case as component 3, the further pesticide metrafenone.
  • the weight ratio of component 1 ) and component 2) depends from the properties of the active substances used, usually it is in the range of from 1 :100 to 100:1 , regularly in the range of from 1 :50 to 50:1 , preferably in the range of from 1 :20 to 20:1 , more preferably in the range of from 1 :10 to 10:1 and in particular in the range of from 1 :4 to 4:1 , and the weight ratio of component 1 ) and component 3) usually it is in the range of from 1 :100 to 100:1 , regularly in the range of from 1 :50 to 50:1 , preferably in the range of from 1 :20 to 20:1 , more preferably in the range of from 1 :10 to 10:1 and in particular in the range of from 1 :4 to 4:1.
  • any further active components are, if desired, added in a ratio of from 20:1 to 1 :20 to the component 1 ).
  • mixtures and compositions according to the invention are suitable as fungicides. They are distinguished by an outstanding effectiveness against a broad spectrum of phytopathogenic fungi, including soil-borne fungi, which derive especially from the classes of the
  • Zygomycetes Ascomycetes, Basidiomycetes and Deuteromycetes (syn. Fungi imperfecti). Some are systemically effective and they can be used in crop protection as foliar fungicides, fungicides for seed dressing and soil fungicides. Moreover, they are suitable for controlling harmful fungi, which inter alia occur in wood or roots of plants.
  • the mixtures and compositions according to the invention are particularly important in the control of a multitude of phytopathogenic fungi on various cultivated plants, such as cereals, e. g. wheat, rye, barley, triticale, oats or rice; beet, e. g. sugar beet or fodder beet; fruits, such as pomes, stone fruits or soft fruits, e. g.
  • cereals e. g. wheat, rye, barley, triticale, oats or rice
  • beet e. g. sugar beet or fodder beet
  • fruits such as pomes, stone fruits or soft fruits, e. g.
  • inventive mixtures and compositions are used for controlling a multitude of fungi on field crops, such as potatoes sugar beets, tobacco, wheat, rye, barley, oats, rice, corn, cotton, soybeans, rape, legumes, sunflowers, coffee or sugar cane; fruits; vines; ornamentals; or vegetables, such as cucumbers, tomatoes, beans or squashes.
  • field crops such as potatoes sugar beets, tobacco, wheat, rye, barley, oats, rice, corn, cotton, soybeans, rape, legumes, sunflowers, coffee or sugar cane; fruits; vines; ornamentals; or vegetables, such as cucumbers, tomatoes, beans or squashes.
  • plant propagation material is to be understood to denote all the generative parts of the plant such as seeds and vegetative plant material such as cuttings and tubers (e. g.
  • potatoes which can be used for the multiplication of the plant. This includes seeds, roots, fruits, tubers, bulbs, rhizomes, shoots, sprouts and other parts of plants, including seedlings and young plants, which are to be transplanted after germination or after emergence from soil.
  • These young plants may also be protected before transplantation by a total or partial treatment by immersion or pouring.
  • treatment of plant propagation materials with the inventive combination of compound I and compounds II and compositions thereof, respectively, is used for controlling a multitude of fungi on cereals, such as wheat, rye, barley and oats; rice, corn, cotton and soybeans.
  • cultiva plants is to be understood as including plants which have been modified by breeding, mutagenesis or genetic engineering including but not limiting to agricultural biotech products on the market or in development (cf. https://cera-gmc.org/, see GM crop database therein).
  • Genetically modified plants are plants, which genetic material has been so modified by the use of recombinant DNA techniques that under natural circumstances cannot readily be obtained by cross breeding, mutations or natural recombination.
  • one or more genes have been integrated into the genetic material of a genetically modified plant in order to improve certain properties of the plant.
  • Such genetic modifications also include but are not limited to targeted post-transtional modification of protein(s), oligo- or polypeptides e. g. by glycosylation or polymer additions such as prenylated, acetylated or farnesylated moieties or PEG moieties.
  • inventive mixtures and compositions are particularly suitable for controlling the following plant diseases:
  • Albugo spp. white rust
  • vegetables e. g. A. Candida
  • sunflowers e. g. A. tragopogonis
  • Alternaria spp. Alternaria leaf spot) on vegetables, rape (A brassicola or brassicae), sugar beets (A tenuis), fruits, rice, soybeans, potatoes (e. g. A so/an/ or A.
  • alternata tomatoes (e. g. A solani or A alternata) and wheat; Aphanomyces spp. on sugar beets and vegetables; Ascochyta spp. on cereals and vegetables, e. g. A /r/f/c/(anthracnose) on wheat and A horde/ on barley; Bipo/aris and Drechslera spp. (teleomorph: Cochliobolus spp.) on corn (e. g. D. maydis), cereals (e. g. B. sorok/n/ana: spot blotch), rice (e. g. B.
  • Cercospora spp. (Cercospora leaf spots) on corn, rice, sugar beets (e. g. C. beticola), sugar cane, vegetables, coffee, soybeans (e. g. C. sojina or C. kikuchil) and rice; Cladosporium spp. on tomatoes (e. g. C. fulvurrr. leaf mold) and cereals, e. g. C. herbarum (black ear) on wheat; Claviceps purpurea (ergot) on cereals; Cochiioboius (anamorph:
  • Helminthosporium of Bipolaris spp. (leaf spots) on corn (C. carbonum), cereals (e. g. C.
  • Colletotrichum teleomorph: Glomerella
  • spp. anthracnose
  • cotton e. g. C. gossypii
  • corn e. g. C. graminicola
  • soft fruits e. g. C. coccodes. black dot
  • beans e. g. C.
  • lindemuthianum and soybeans (e. g. C. truncatum or C. gloeosporioides); Corticium spp., e. g. C. sasak/i (sheath blight) on rice; Corynespora cassiicola (leaf spots) on soybeans and ornamentals; Cycloconium spp., e. g. C. oleaginum on olive trees; Cylindrocarpon spp. (e. g. fruit tree canker or young vine decline, teleomorph: Nectria o Neonectria spp.) on fruit trees, vines (e. g. C.
  • liriodendri Neonectria liriodendri. Black Foot Disease) and ornamentals; Dematophora (teleomorph: Rosellinia) necatrix (root and stem rot) on soybeans; Diaporthe spp., e. g. D. phaseolorum (damping off) on soybeans; Drechslera (syn.
  • Phaeomoniella chlamydospora (earlier Phaeoacremonium chlamydosporum)
  • spp. wilt, root or stem rot
  • various plants such as F. graminearum or F. culmorum (root rot, scab or head blight) on cereals (e. g. wheat or barley), F. oxysporum on tomatoes, F. so/ani( sp. glycines now syn. F. virguliforme ) and F. tucumaniae and F.
  • Microsphaera diffusa (powdery mildew) on soybeans; Monilinia spp., e. g. M. laxa, M. fructicola and M. fructigena (bloom and twig blight, brown rot) on stone fruits and other rosaceous plants; Mycosphaerella spp. on cereals, bananas, soft fruits and ground nuts, such as e. g. M. graminicola (anamorph: Septoria tritici, Septoria blotch) on wheat or M. fijiensis (black Sigatoka disease) on bananas; Peronospora spp. (downy mildew) on cabbage (e. g. P. brassicae), rape (e. g. P. parasitica), onions (e. g. P. destructor), tobacco ⁇ P. tabacina) and soybeans (e. g. P. manshurica);
  • Monilinia spp. e. g.
  • Phakopsora pachyrhizi and P. meibomiae (soybean rust) on soybeans; Phialophora spp. e. g. on vines (e. g. P. tracheiphila and P. tetraspora) and soybeans (e. g. P. gregata: stem rot); Phoma lingam (root and stem rot) on rape and cabbage and P. betae (root rot, leaf spot and damping-off) on sugar beets; Phomopsis spp. on sunflowers, vines (e. g. P. viticola: can and leaf spot) and soybeans (e. g. stem rot: P. phaseoli, teleomorph: Diaporthe phaseolorum);
  • Physoderma maydis (brown spots) on corn; Phytophthora spp. (wilt, root, leaf, fruit and stem root) on various plants, such as paprika and cucurbits (e. g. P. capsici), soybeans (e. g. P.
  • Plasmodiophora brassicae club root
  • Plasmopara spp. e. g. P. viticola (grapevine downy mildew) on vines and P. ha/stediion sunflowers
  • Podosphaera spp. powdery mildew
  • hum/lion hop Pseudopezicula tracheiphila (red fire disease or .rotbrenner', anamorph: Phialophora) on vines; Puccinia spp. (rusts) on various plants, e. g. P. triticina (brown or leaf rust), P. striiformis (stripe or yellow rust), P. horde/ (dwarf rust), P. graminis (stem or black rust) or P. recondita (brown or leaf rust) on cereals, such as e. g. wheat, barley or rye, and asparagus (e. g. P. asparagi); Pyrenophora (anamorph:
  • Drechsiera tritici-repentis (tan spot) on wheat or P. teres (net blotch) on barley; Pyricularia spp., e. g. P. oryzae (teleomorph: Magnaporthe grisea, rice blast) on rice and P. grisea on turf and cereals; Pythium spp. (damping-off) on turf, rice, corn, wheat, cotton, rape, sunflowers, soy- beans, sugar beets, vegetables and various other plants (e. g. P. ultimum o P. aphani- dermatum); Ramularia spp., e. g. R.
  • collo-cygni Roso-cygni (Ramularia leaf spots, Physiological leaf spots) on barley and R. bet/cola on sugar beets; Rh/zocton/a spp. on cotton, rice, potatoes, turf, corn, rape, potatoes, sugar beets, vegetables and various other plants, e. g. R. so/ani (root and stem rot) on soybeans, R. so/ani (sheath blight) on rice or R.
  • Rhizoctonia spring blight on wheat or barley
  • Rhizopus sto/onifer b ⁇ ack mold, soft rot
  • strawberries a plant rot
  • cabbage a plant rot
  • tomatoes a plant rot
  • Rhynchosporium secalis scald
  • Sarocladium oryzae and S. attenuatum sheath rot
  • Sclerotinia spp. stem rot or white mold
  • vegetables and field crops such as rape, sunflowers (e. g. S. sclerotiorum) and soybeans (e. g. S. ro/fsiior S.
  • Septoria spp. on various plants, e. g. S. glycines (brown spot) on soybeans, S. tritici (Septoria blotch) on wheat and S. (syn. Stagonospora) nodorum
  • Leptosphaeria [syn. Phaeosphaeria] nodorum) on wheat; Synchytrium endobioticum on potatoes (potato wart disease); Taphrina spp., e. g. T. deformans (leaf curl disease) on peaches and T. pruni (p ⁇ um pocket) on plums; Thielaviopsis spp. (black root rot) on tobacco, pome fruits, vegetables, soybeans and cotton, e. g. T. basicola (syn. Chalara elegans); Tilletia spp.
  • Plant propagation materials may be treated with the mixtures and compositions of the invention prophylactically either at or before planting or transplanting.
  • the invention also relates to agrochemical compositions comprising an auxiliary and at least one compound I and at least one pesticide II according to the invention.
  • An agrochemical composition comprises a fungicidally effective amount of a compound I and a pesticide II.
  • effective amount denotes an amount of the composition or of the compounds I, which is sufficient for controlling harmful fungi on cultivated plants or in the protection of materials and which does not result in a substantial damage to the treated plants. Such an amount can vary in a broad range and is dependent on various factors, such as the fungal species to be controlled, the treated cultivated plant or material, the climatic conditions and the specific compound I used.
  • compositions e.g. solutions, emulsions, suspensions, dusts, powders, pastes, granules, pressings, capsules, and mixtures thereof.
  • composition types are suspensions (e.g. SC, OD, FS), emulsifiable concentrates (e.g. EC), emulsions (e.g. EW, EO, ES, ME), capsules (e.g. CS, ZC), pastes, pastilles, wettable powders or dusts (e.g. WP, SP, WS, DP, DS), pressings (e.g.
  • compositions types are defined in the "Catalogue of pesticide formulation types and international coding system", Technical
  • compositions are prepared in a known manner, such as described by Mollet and Grubemann, Formulation technology, Wiley VCH, Weinheim, 2001 ; or Knowles, New
  • auxiliaries are solvents, liquid carriers, solid carriers or fillers, surfactants, dispersants, emulsifiers, wetters, adjuvants, solubilizers, penetration enhancers, protective colloids, adhesion agents, thickeners, humectants, repellents, attractants, feeding stimulants, compatibilizers, bactericides, anti-freezing agents, anti-foaming agents, colorants, tackifiers and binders.
  • the agrochemical compositions generally comprise between 0.01 and 95%, preferably between 0.1 and 90%, and in particular between 0.5 and 75%, by weight of active substances.
  • the active substances are employed in a purity of from 90% to 100%, preferably from 95% to 100% (according to NMR spectrum).
  • Solutions for seed treatment (LS), Suspoemulsions (SE), flowable concentrates (FS), powders for dry treatment (DS), water-dispersible powders for slurry treatment (WS), water- soluble powders (SS), emulsions (ES), emulsifiable concentrates (EC) and gels (GF) are usually employed for the purposes of treatment of plant propagation materials, particularly seeds.
  • the compositions in question give, after two-to-tenfold dilution, active substance concentrations of from 0.01 to 60% by weight, preferably from 0.1 to 40%, in the ready-to-use preparations.
  • Methods for applying or treating compound I and pesticide II and compositions thereof, respectively, on to plant propagation material, especially seeds include dressing, coating, pelleting, dusting, soaking and in-furrow application methods of the propagation material.
  • compound I and pesticide II or the compositions thereof, respectively are applied on to the plant propagation material by a method such that germination is not induced, e. g. by seed dressing, pelleting, coating and dusting.
  • the amounts of active substances applied are, depending on the kind of effect desired, from 0.001 to 2 kg per ha, preferably from 0.005 to 2 kg per ha, more preferably from 0.05 to 0.9 kg per ha, in particular from 0.1 to 0.75 kg per ha.
  • amounts of active substance of from 0.1 to 1000 g, preferably from 1 to 1000 g, more preferably from 1 to 100 g and most preferably from 5 to 100 g, per 100 kilogram of plant propagation material (preferably seed) are generally required.
  • the amount of active substance applied depends on the kind of application area and on the desired effect. Amounts customarily applied in the protection of materials are 0.001 g to 2 kg, preferably 0.005 g to 1 kg, of active substance per cubic meter of treated material.
  • oils, wetters, adjuvants, fertilizer, or micronutrients, and further pesticides may be added to the active substances or the compositions comprising them as premix or, if appropriate not until immediately prior to use (tank mix).
  • pesticides e.g. herbicides, insecticides, fungicides, growth regulators, safeners
  • These agents can be admixed with the compositions according to the invention in a weight ratio of 1 :100 to 100:1 , preferably 1 :10 to 10:1.
  • the user applies the composition according to the invention usually from a predosage device, a knapsack sprayer, a spray tank, a spray plane, or an irrigation system.
  • the agrochemical composition is made up with water, buffer, and/or further auxiliaries to the desired application concentration and the ready-to-use spray liquor or the agrochemical composition according to the invention is thus obtained.
  • 20 to 2000 liters, preferably 50 to 400 liters, of the ready-to-use spray liquor are applied per hectare of agricultural useful area.
  • the components can be used individually or already partially or completely mixed with one another to prepare the composition according to the invention. It is also possible for them to be packaged and used as combination such as a kit of parts.
  • composition according to the invention such as parts of a kit or parts of a binary or ternary mixture may be mixed by the user himself in a spray tank and further auxiliaries may be added, if appropriate.
  • the compound ratios e. g. compound l/pesticide
  • I l/pesticide III ratio are advantageously chosen so as to produce a synergistic effect.
  • compositions according to the invention can be shown by the tests described below.
  • the active compounds were formulated separately as a stock solution having a
  • the stock solutions were mixed according to the ratio, pipetted onto a micro titer plate (MTP) and diluted with water to the stated concentrations.
  • MTP micro titer plate
  • a spore suspension of the respective plant pathogen in an aqueous nutrient solution as described for the respective plant pathogen was then added.
  • the plates were placed in a water vapor-saturated chamber at a temperature of 18 °C. Using an absorption photometer, the MTPs were measured at 405 nm 7 days after the inoculation.
  • the measured parameters were compared to the growth of the active compound-free control variant (100%) and the fungus-free and active compound-free blank value to determine the relative growth in % of the pathogens in the respective active compounds. These percentages were converted into efficacies using Abbot's formula. The expected efficacies of active compound mixtures were determined using Colby's formula and compared with the observed efficacies.
  • a spore suspension of a Qol resistant Alternaria soiani isolate (141 ) in an aqueous biomalt or yeast-bactopeptone-glycerine solution was used.

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Abstract

La présente invention concerne des mélanges fongicides, comprenant au moins un composé I de type strobilurine à action fongicide et au moins un pesticide II, tel que défini dans la description, ainsi que des compositions comprenant ces mélanges.
PCT/EP2016/054367 2015-03-12 2016-03-02 Mélanges fongicides contenant des fongicides de type strobilurine WO2016142224A1 (fr)

Priority Applications (5)

Application Number Priority Date Filing Date Title
CN201680014851.9A CN107427005A (zh) 2015-03-12 2016-03-02 包含嗜球果伞素型杀真菌剂的杀真菌混合物
RU2017134847A RU2017134847A (ru) 2015-03-12 2016-03-02 Фунгицидные смеси, содержащие фунгициды стробилуринового типа
US15/556,880 US20180235221A1 (en) 2015-04-10 2016-03-02 Fungicidal mixtures comprising strobilurin-type fungicides
BR112017019117A BR112017019117A2 (pt) 2015-03-12 2016-03-02 ?mistura, composição agroquímica, uso da mistura ou da composição, método para controle de fungos prejudiciais fitopatogênicos, e, material de propagação de plantas?
EP16707145.5A EP3267797A1 (fr) 2015-03-12 2016-03-02 Mélanges fongicides contenant des fongicides de type strobilurine

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
EP15158821 2015-03-12
EP15158821.7 2015-03-12
EP15163110.8 2015-04-10
EP15163110 2015-04-10

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WO2016142224A1 true WO2016142224A1 (fr) 2016-09-15
WO2016142224A8 WO2016142224A8 (fr) 2017-10-19

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BR (1) BR112017019117A2 (fr)
RU (1) RU2017134847A (fr)
WO (1) WO2016142224A1 (fr)

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US10112891B2 (en) 2014-10-10 2018-10-30 Basf Se Stereoselective process to obtain (Z)-5-cyclyloxy-2-[(E)-methoxyimino]-3-methyl-pent-3-enic acid methyl amides using E,Z-isomer mixture of and intermediates thereof
WO2019007717A1 (fr) * 2017-07-06 2019-01-10 Basf Se Mélanges pesticides
EP3427587A1 (fr) * 2017-07-10 2019-01-16 Basf Se Mélanges de pesticides
US10499644B2 (en) 2015-11-19 2019-12-10 Basf Se Substituted oxadiazoles for combating phytopathogenic fungi
US10555526B2 (en) 2015-11-05 2020-02-11 Basf Se Substituted oxadiazoles for combating phytopathogenic fungi
US10674727B2 (en) 2015-11-19 2020-06-09 Basf Se Substituted oxadiazoles for combating phytopathogenic fungi
US10785980B2 (en) 2016-06-09 2020-09-29 Basf Se Substituted oxadiazoles for combating phytopathogenic fungi
WO2021053136A1 (fr) * 2019-09-19 2021-03-25 Syngenta Crop Protection Ag Procédé de lutte contre les champignons
US10986839B2 (en) 2016-04-11 2021-04-27 Basf Se Substituted oxadiazoles for combating phytopathogenic fungi
US11425910B2 (en) 2017-02-21 2022-08-30 Basf Se Substituted oxadiazoles for combating phytopathogenic fungi

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WO2014202421A1 (fr) * 2013-06-18 2014-12-24 Basf Se Mélanges fongicides i comprenant des fongicides de type strobilurine

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014202421A1 (fr) * 2013-06-18 2014-12-24 Basf Se Mélanges fongicides i comprenant des fongicides de type strobilurine

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10112891B2 (en) 2014-10-10 2018-10-30 Basf Se Stereoselective process to obtain (Z)-5-cyclyloxy-2-[(E)-methoxyimino]-3-methyl-pent-3-enic acid methyl amides using E,Z-isomer mixture of and intermediates thereof
US10555526B2 (en) 2015-11-05 2020-02-11 Basf Se Substituted oxadiazoles for combating phytopathogenic fungi
US10499644B2 (en) 2015-11-19 2019-12-10 Basf Se Substituted oxadiazoles for combating phytopathogenic fungi
US10674727B2 (en) 2015-11-19 2020-06-09 Basf Se Substituted oxadiazoles for combating phytopathogenic fungi
US10986839B2 (en) 2016-04-11 2021-04-27 Basf Se Substituted oxadiazoles for combating phytopathogenic fungi
US10785980B2 (en) 2016-06-09 2020-09-29 Basf Se Substituted oxadiazoles for combating phytopathogenic fungi
US11425910B2 (en) 2017-02-21 2022-08-30 Basf Se Substituted oxadiazoles for combating phytopathogenic fungi
WO2019007717A1 (fr) * 2017-07-06 2019-01-10 Basf Se Mélanges pesticides
EP3427587A1 (fr) * 2017-07-10 2019-01-16 Basf Se Mélanges de pesticides
WO2021053136A1 (fr) * 2019-09-19 2021-03-25 Syngenta Crop Protection Ag Procédé de lutte contre les champignons

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