WO2009031756A3 - Continuous-flow dual-bed reactor for production of liquid-phase hydrocarbon mixture on fischer-tropsch catalysis using synthetic gas - Google Patents

Continuous-flow dual-bed reactor for production of liquid-phase hydrocarbon mixture on fischer-tropsch catalysis using synthetic gas Download PDF

Info

Publication number
WO2009031756A3
WO2009031756A3 PCT/KR2008/004125 KR2008004125W WO2009031756A3 WO 2009031756 A3 WO2009031756 A3 WO 2009031756A3 KR 2008004125 W KR2008004125 W KR 2008004125W WO 2009031756 A3 WO2009031756 A3 WO 2009031756A3
Authority
WO
WIPO (PCT)
Prior art keywords
fischer
hydrocarbon mixture
bed reactor
liquid
continuous
Prior art date
Application number
PCT/KR2008/004125
Other languages
French (fr)
Other versions
WO2009031756A2 (en
Inventor
Ki-Won Jun
In Kyu Song
Kyung Min Cho
Sunyoung Park
Sung-Hyeon Baeck
Original Assignee
Korea Research Institute Of Chemical Technology
Daelim Industrial Co., Ltd.
Doosan Mecatec Co., Ltd.
Korea National Oil Corporation
Hyundai Engineering Co., Ltd.
Sk Energy Co., Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Korea Research Institute Of Chemical Technology, Daelim Industrial Co., Ltd., Doosan Mecatec Co., Ltd., Korea National Oil Corporation, Hyundai Engineering Co., Ltd., Sk Energy Co., Ltd. filed Critical Korea Research Institute Of Chemical Technology
Priority to EP08778783A priority Critical patent/EP2190568A2/en
Publication of WO2009031756A2 publication Critical patent/WO2009031756A2/en
Publication of WO2009031756A3 publication Critical patent/WO2009031756A3/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
    • B01J8/0446—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical
    • B01J8/0449—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical in two or more cylindrical beds
    • B01J8/0457—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical in two or more cylindrical beds the beds being placed in separate reactors
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
    • C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/75—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/03—Catalysts comprising molecular sieves not having base-exchange properties
    • B01J29/0308—Mesoporous materials not having base exchange properties, e.g. Si-MCM-41
    • B01J29/0316—Mesoporous materials not having base exchange properties, e.g. Si-MCM-41 containing iron group metals, noble metals or copper
    • B01J29/0333—Iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
    • B01J8/0492—Feeding reactive fluids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
    • B01J8/0496—Heating or cooling the reactor
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • C10G2/332—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the iron-group
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
    • C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
    • C10G47/12—Inorganic carriers
    • C10G47/14—Inorganic carriers the catalyst containing platinum group metals or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G69/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process
    • C10G69/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)

Abstract

The present invention relates to a process of preparing liquid-phase hydrocarbon mixture, which comprises continuously conducting Fischer-Tropsch synthesis reaction in the upper part and hydrocracking reaction in the lower part by using a continuous-flow dual-bed reactor which comprises two fixed-bed reactors filled with catalysts and continuously placed in upper and lower parts and a hydrogen-supplying pipe between the upper and the lower fixed-bed reactors and continuously supplying hydrogen in the lower fixed-bed reactor, thereby remarkably increasing the yield of C10-C20 liquid-phase hydrocarbon mixture as compared to the conventional Fischer-Tropsch synthesis reaction.
PCT/KR2008/004125 2007-09-04 2008-07-14 Continuous-flow dual-bed reactor for production of liquid-phase hydrocarbon mixture on fischer-tropsch catalysis using synthetic gas WO2009031756A2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP08778783A EP2190568A2 (en) 2007-09-04 2008-07-14 Continuous-flow dual-bed reactor for production of liquid-phase hydrocarbon mixture on fischer-tropsch catalysis using synthetic gas

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR10-2007-0089634 2007-09-04
KR1020070089634A KR100920504B1 (en) 2007-09-04 2007-09-04 Continuous-flow Dual-bed Reactor for Production of Liquid-phase Hydrocarbon Mixture on Fischer-Tropsch Catalysis Using Synthetic Gas

Publications (2)

Publication Number Publication Date
WO2009031756A2 WO2009031756A2 (en) 2009-03-12
WO2009031756A3 true WO2009031756A3 (en) 2009-08-27

Family

ID=40429508

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/KR2008/004125 WO2009031756A2 (en) 2007-09-04 2008-07-14 Continuous-flow dual-bed reactor for production of liquid-phase hydrocarbon mixture on fischer-tropsch catalysis using synthetic gas

Country Status (3)

Country Link
EP (1) EP2190568A2 (en)
KR (1) KR100920504B1 (en)
WO (1) WO2009031756A2 (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7973086B1 (en) * 2010-10-28 2011-07-05 Chevron U.S.A. Inc. Process of synthesis gas conversion to liquid hydrocarbon mixtures using alternating layers of synthesis gas conversion catalyst and hydrocracking catalyst
US8461220B2 (en) 2010-06-10 2013-06-11 Chevron U.S.A. Inc. Process and system for reducing the olefin content of a fischer-tropsch product stream
US8519011B2 (en) * 2010-10-28 2013-08-27 Chevron U.S.A. Inc. Process of synthesis gas conversion to liquid hydrocarbon mixtures using alternating layers of synthesis gas conversion catalyst, hydrocracking and hydroisomerization catalyst
US9670115B2 (en) 2012-02-15 2017-06-06 Clariant Corporation Method and system for purifying an ethylene-containing gas stream
KR102365335B1 (en) 2019-12-12 2022-02-18 한국화학연구원 Direct Method for Preparing Liquid―phase Hydrocarbon Mixture of Gasoline Range by Using Syngas

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5028634A (en) * 1989-08-23 1991-07-02 Exxon Research & Engineering Company Two stage process for hydrocarbon synthesis
US6156809A (en) * 1999-04-21 2000-12-05 Reema International Corp. Multiple reactor system and method for fischer-tropsch synthesis
US6169120B1 (en) * 1999-09-17 2001-01-02 Syntroleum Corporation Extended catalyst life two stage hydrocarbon synthesis process
US6277894B1 (en) * 1999-03-30 2001-08-21 Syntroleum Corporation System and method for converting light hydrocarbons into heavier hydrocarbons with a plurality of synthesis gas subsystems
US6992113B2 (en) * 2003-11-25 2006-01-31 Chevron U.S.A. Inc. Control of CO2 emissions from a fischer-tropsch facility by use of dual functional syngas conversion

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6589415B2 (en) * 2001-04-04 2003-07-08 Chevron U.S.A., Inc. Liquid or two-phase quenching fluid for multi-bed hydroprocessing reactor
US6656978B2 (en) 2001-04-05 2003-12-02 Chiyoda Corporation Process of producing liquid hydrocarbon oil or dimethyl ether from lower hydrocarbon gas containing carbon dioxide
CN101253132A (en) 2005-07-08 2008-08-27 北卡罗来纳-查佩尔山大学 A dual catalyst system for alkane metathesis

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5028634A (en) * 1989-08-23 1991-07-02 Exxon Research & Engineering Company Two stage process for hydrocarbon synthesis
US6277894B1 (en) * 1999-03-30 2001-08-21 Syntroleum Corporation System and method for converting light hydrocarbons into heavier hydrocarbons with a plurality of synthesis gas subsystems
US6156809A (en) * 1999-04-21 2000-12-05 Reema International Corp. Multiple reactor system and method for fischer-tropsch synthesis
US6169120B1 (en) * 1999-09-17 2001-01-02 Syntroleum Corporation Extended catalyst life two stage hydrocarbon synthesis process
US6992113B2 (en) * 2003-11-25 2006-01-31 Chevron U.S.A. Inc. Control of CO2 emissions from a fischer-tropsch facility by use of dual functional syngas conversion

Also Published As

Publication number Publication date
EP2190568A2 (en) 2010-06-02
WO2009031756A2 (en) 2009-03-12
KR100920504B1 (en) 2009-10-08
KR20090024557A (en) 2009-03-09

Similar Documents

Publication Publication Date Title
AU2008288198B2 (en) A hydrocarbon synthesis process
NZ604743A (en) Method for producing methane from biomass
US9005554B1 (en) Fischer tropsch method for offshore production risers or oil and gas wells
WO2011057976A3 (en) Process for producing olefins
WO2013076293A3 (en) Conversion of carbon dioxide to hydrocarbons via hydrogenation
MY156576A (en) Methods of producing jet fuel from natural oil feedstocks through metathesis reactions
WO2010033848A3 (en) Processes for gasification of a carbonaceous feedstock
WO2010006386A3 (en) Catalytic co2 methanation process
WO2011093749A3 (en) Process for producing synthetic liquid hydrocarbons and reactor for fischer-tropsch synthesis
WO2009031756A3 (en) Continuous-flow dual-bed reactor for production of liquid-phase hydrocarbon mixture on fischer-tropsch catalysis using synthetic gas
IN2015DN02290A (en)
Savost'yanov et al. Unexpected increase in C5+ selectivity at temperature rise in high pressure Fischer-Tropsch synthesis over Co-Al2O3/SiO2 catalyst
WO2009054616A3 (en) Process for producing light olefins from synthesis gas using dual sequential bed reactor
Van de Loosdrecht et al. 5.4 synthesis gas to hydrogen, methanol, and synthetic fuels
MY158205A (en) Method for upgrading ft synthesis oil, and mixed crude oil
US9074148B2 (en) Hydrogen and carbon utilization in synthetic fuels production plants
AU2009263607A8 (en) Catalyst for Fischer-Tropsch synthesis and method for producing hydrocarbons
AU2013291949B2 (en) Hydrocarbon recovery from Fischer-Tropsch off-gas
WO2005047424A3 (en) Integrated process for the production of lubricating base oils and liquid fuels from fischer-tropsch materials using split feed hydroprocessing
KR101776927B1 (en) Synthetic fuel containing high Diesel fuel and gasoline using slurry bubble column reactor
SG155091A1 (en) Hydrocarbon synthesis and production onboard a marine system using varied feedstock
SG155094A1 (en) Hydrocarbon synthesis and production onboard a marine system using varied feedstock
MY171719A (en) Fischer-tropsch process
CA2926550C (en) Method and apparatus for producing a hydrocarbon fraction and a hydrocarbon fraction and its use
WO2009108131A3 (en) Hydrocarbon synthesis and production onboard a marine system using varied feedstock

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 08778783

Country of ref document: EP

Kind code of ref document: A2

WWE Wipo information: entry into national phase

Ref document number: 2008778783

Country of ref document: EP

NENP Non-entry into the national phase

Ref country code: DE