WO2007098478A3 - Electrochemistry of carbon subfluorides - Google Patents

Electrochemistry of carbon subfluorides Download PDF

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Publication number
WO2007098478A3
WO2007098478A3 PCT/US2007/062518 US2007062518W WO2007098478A3 WO 2007098478 A3 WO2007098478 A3 WO 2007098478A3 US 2007062518 W US2007062518 W US 2007062518W WO 2007098478 A3 WO2007098478 A3 WO 2007098478A3
Authority
WO
WIPO (PCT)
Prior art keywords
carbonaceous materials
subfluorides
electrochemistry
carbon
subfluorinated carbonaceous
Prior art date
Application number
PCT/US2007/062518
Other languages
French (fr)
Other versions
WO2007098478A2 (en
WO2007098478A9 (en
Inventor
Rachid Yazami
Andre Hamwi
Original Assignee
California Inst Of Techn
Centre Nat Rech Scient
Univ Blaise Pascal
Rachid Yazami
Andre Hamwi
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US11/422,564 external-priority patent/US7563542B2/en
Priority claimed from US11/675,308 external-priority patent/US20070218364A1/en
Priority claimed from PCT/US2007/062243 external-priority patent/WO2007098369A2/en
Application filed by California Inst Of Techn, Centre Nat Rech Scient, Univ Blaise Pascal, Rachid Yazami, Andre Hamwi filed Critical California Inst Of Techn
Priority to EP07757289A priority Critical patent/EP1999812A2/en
Priority to CN2007800060814A priority patent/CN101390234B/en
Priority to JP2008555538A priority patent/JP2009527441A/en
Publication of WO2007098478A2 publication Critical patent/WO2007098478A2/en
Publication of WO2007098478A3 publication Critical patent/WO2007098478A3/en
Publication of WO2007098478A9 publication Critical patent/WO2007098478A9/en

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/10—Carbon fluorides, e.g. [CF]nor [C2F]n
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/20—Graphite
    • C01B32/21—After-treatment
    • C01B32/22—Intercalation
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H01M4/5835—Comprising fluorine or fluoride salts
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
    • H01M2004/028—Positive electrodes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M6/00—Primary cells; Manufacture thereof
    • H01M6/14—Cells with non-aqueous electrolyte
    • H01M6/18—Cells with non-aqueous electrolyte with solid electrolyte
    • H01M6/181—Cells with non-aqueous electrolyte with solid electrolyte with polymeric electrolytes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Electrochemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Environmental & Geological Engineering (AREA)
  • Materials Engineering (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Primary Cells (AREA)
  • Secondary Cells (AREA)

Abstract

Subfluorinated carbonaceous materials obtained through direct fluorination of graphite or coke particles are provided. One set of subfluorinated carbonaceous materials has an average chemical composition CFx in which 0.63<x ≤0.95, 0.66<x ≤0.95 or 0.7<x ≤0.95. The subfluorinated carbonaceous materials are capable of electrochemical performance superior to commercial CF at relatively high rates of discharge.
PCT/US2007/062518 2006-02-21 2007-02-21 Electrochemistry of carbon subfluorides WO2007098478A2 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
EP07757289A EP1999812A2 (en) 2006-02-21 2007-02-21 Electrochemistry of carbon subfluorides
CN2007800060814A CN101390234B (en) 2006-02-21 2007-02-21 Electrochemistry of carbon subfluorides
JP2008555538A JP2009527441A (en) 2006-02-21 2007-02-21 Electrochemistry of partially fluorinated carbon

Applications Claiming Priority (12)

Application Number Priority Date Filing Date Title
US77511006P 2006-02-21 2006-02-21
US60/775,110 2006-02-21
US77555906P 2006-02-22 2006-02-22
US60/775,559 2006-02-22
US11/422,564 US7563542B2 (en) 2005-10-05 2006-06-06 Subfluorinated graphite fluorides as electrode materials
US11/422,564 2006-06-06
US90040907P 2007-02-09 2007-02-09
US60/900,409 2007-02-09
US11/675,308 US20070218364A1 (en) 2005-10-05 2007-02-15 Low temperature electrochemical cell
PCT/US2007/062243 WO2007098369A2 (en) 2006-02-16 2007-02-15 Low temperature electrochemical cell
USPCT/US2007/62243 2007-02-15
US11/675,308 2007-02-15

Publications (3)

Publication Number Publication Date
WO2007098478A2 WO2007098478A2 (en) 2007-08-30
WO2007098478A3 true WO2007098478A3 (en) 2007-12-27
WO2007098478A9 WO2007098478A9 (en) 2008-08-28

Family

ID=38438103

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2007/062518 WO2007098478A2 (en) 2006-02-21 2007-02-21 Electrochemistry of carbon subfluorides

Country Status (5)

Country Link
EP (1) EP1999812A2 (en)
JP (1) JP2009527441A (en)
KR (1) KR20080095909A (en)
CN (1) CN101390234B (en)
WO (1) WO2007098478A2 (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8377586B2 (en) 2005-10-05 2013-02-19 California Institute Of Technology Fluoride ion electrochemical cell
JP5533110B2 (en) * 2009-07-21 2014-06-25 パナソニック株式会社 Lithium primary battery
JP5417116B2 (en) * 2009-10-17 2014-02-12 国立大学法人福井大学 Organic solvent paint
JP5325070B2 (en) * 2009-10-17 2013-10-23 国立大学法人福井大学 Fluorinated carbon fine particles
GB201009718D0 (en) * 2010-06-10 2010-07-21 Univ Manchester Functionalised graphene
US8981167B2 (en) * 2010-12-22 2015-03-17 Ocean's King Lighting Science & Technology Co., Ltd. Fluorographene and preparation method thereof
CN103703602B (en) 2012-04-16 2017-09-15 松下电器产业株式会社 Electrochemical energy storage device and active material and its manufacture method for the device
FR2999340B1 (en) * 2012-12-12 2015-01-09 Univ Blaise Pascal Clermont Ferrand Ii USE OF FLUORINATED CARBON NANOBJETS AS ELECTRODE MATERIAL OF LITHIUM PRIMARY BATTERIES OF HIGH CAPACITY
WO2014141789A1 (en) * 2013-03-11 2014-09-18 Jx日鉱日石金属株式会社 Sputtering target for forming magnetic recording film, and carbon raw material used for production of said target
JP6250879B2 (en) 2013-12-26 2017-12-20 国立大学法人京都大学 Secondary battery
CN104952712B (en) * 2014-03-26 2018-01-12 朗姆研究公司 NH4F manufactures n doped graphenes and the method for electric device and the graphene and device
US9755235B2 (en) 2014-07-17 2017-09-05 Ada Technologies, Inc. Extreme long life, high energy density batteries and method of making and using the same
JP6783505B2 (en) * 2014-07-18 2020-11-11 積水化学工業株式会社 Flaked graphite, electrode material and flake graphite-resin composite material
WO2017023797A1 (en) 2015-07-31 2017-02-09 Ada Technologies, Inc. High energy and power electrochemical device and method of making and using same
US11024846B2 (en) 2017-03-23 2021-06-01 Ada Technologies, Inc. High energy/power density, long cycle life, safe lithium-ion battery capable of long-term deep discharge/storage near zero volt and method of making and using the same
CN110957492A (en) * 2018-09-26 2020-04-03 中国科学院宁波材料技术与工程研究所 Lithium metal interface protection, preparation method thereof and battery containing lithium metal interface protection
CN110243855B (en) * 2019-07-02 2020-09-11 厦门大学 Detection method and comparison method for pole piece reaction uniformity
CN111204735B (en) * 2020-01-16 2021-07-27 厦门稀土材料研究所 Preparation method and application of carbon fluoride material

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4438086A (en) * 1981-09-02 1984-03-20 Central Glass Company Limited Method for preparation of graphite fluoride by contact reaction between carbon and fluorine gas
US5116592A (en) * 1986-06-02 1992-05-26 The Electrosynthesis Company, Inc. Fluorinated carbons and uses thereof
US5702844A (en) * 1995-03-03 1997-12-30 Saft Nickel electrode for an alkaline storage cell
US6068921A (en) * 1992-11-06 2000-05-30 Daikin Industries, Ltd. Carbon fluoride particles, preparation process and users of the same
US6358649B1 (en) * 1996-04-26 2002-03-19 Centre National De La Recherche Scientifique Carbons containing fluorine, method of preparation thereof and use as electrode material
FR2856674A1 (en) * 2003-06-27 2004-12-31 Centre Nat Rech Scient Producing fluorinated carbon useful as a battery electrode material comprises reacting a carbon material with fluorine and hydrogen fluoride in the presence of a fluoride, and fluorinating the product with fluorine

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4681823A (en) * 1986-05-19 1987-07-21 Allied Corporation Lithium/fluorinated carbon battery with no voltage delay

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4438086A (en) * 1981-09-02 1984-03-20 Central Glass Company Limited Method for preparation of graphite fluoride by contact reaction between carbon and fluorine gas
US5116592A (en) * 1986-06-02 1992-05-26 The Electrosynthesis Company, Inc. Fluorinated carbons and uses thereof
US6068921A (en) * 1992-11-06 2000-05-30 Daikin Industries, Ltd. Carbon fluoride particles, preparation process and users of the same
US5702844A (en) * 1995-03-03 1997-12-30 Saft Nickel electrode for an alkaline storage cell
US6358649B1 (en) * 1996-04-26 2002-03-19 Centre National De La Recherche Scientifique Carbons containing fluorine, method of preparation thereof and use as electrode material
FR2856674A1 (en) * 2003-06-27 2004-12-31 Centre Nat Rech Scient Producing fluorinated carbon useful as a battery electrode material comprises reacting a carbon material with fluorine and hydrogen fluoride in the presence of a fluoride, and fluorinating the product with fluorine

Also Published As

Publication number Publication date
KR20080095909A (en) 2008-10-29
WO2007098478A2 (en) 2007-08-30
CN101390234A (en) 2009-03-18
EP1999812A2 (en) 2008-12-10
WO2007098478A9 (en) 2008-08-28
JP2009527441A (en) 2009-07-30
CN101390234B (en) 2011-03-23

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