WO2007049287A3 - Method for bio-oxidative desulfurization of liquid hydrocarbon fuels and product thereof - Google Patents

Method for bio-oxidative desulfurization of liquid hydrocarbon fuels and product thereof Download PDF

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Publication number
WO2007049287A3
WO2007049287A3 PCT/IN2005/000355 IN2005000355W WO2007049287A3 WO 2007049287 A3 WO2007049287 A3 WO 2007049287A3 IN 2005000355 W IN2005000355 W IN 2005000355W WO 2007049287 A3 WO2007049287 A3 WO 2007049287A3
Authority
WO
WIPO (PCT)
Prior art keywords
product
bio
liquid hydrocarbon
hydrocarbon fuels
oxidative desulfurization
Prior art date
Application number
PCT/IN2005/000355
Other languages
French (fr)
Other versions
WO2007049287A2 (en
Inventor
Mahendra Pratap Singh
Manoj Kumar
Wadhava Ram Kalsi
Alex Cheru Pulikottil
Rakesh Sarin
Deepak Kumar Tuli
Ravinder Kumar Malhotra
Ram Prakash Verma
Brij Mohan Bansal
Original Assignee
Indian Oil Corp Ltd
Mahendra Pratap Singh
Manoj Kumar
Wadhava Ram Kalsi
Alex Cheru Pulikottil
Rakesh Sarin
Deepak Kumar Tuli
Ravinder Kumar Malhotra
Ram Prakash Verma
Brij Mohan Bansal
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Indian Oil Corp Ltd, Mahendra Pratap Singh, Manoj Kumar, Wadhava Ram Kalsi, Alex Cheru Pulikottil, Rakesh Sarin, Deepak Kumar Tuli, Ravinder Kumar Malhotra, Ram Prakash Verma, Brij Mohan Bansal filed Critical Indian Oil Corp Ltd
Priority to PCT/IN2005/000355 priority Critical patent/WO2007049287A2/en
Priority to DK05823611.8T priority patent/DK1957118T3/en
Priority to EP05823611.8A priority patent/EP1957118B1/en
Priority to US12/091,913 priority patent/US20090217571A1/en
Publication of WO2007049287A2 publication Critical patent/WO2007049287A2/en
Publication of WO2007049287A3 publication Critical patent/WO2007049287A3/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G32/00—Refining of hydrocarbon oils by electric or magnetic means, by irradiation, or by using microorganisms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G21/00—Refining of hydrocarbon oils, in the absence of hydrogen, by extraction with selective solvents
    • C10G21/06—Refining of hydrocarbon oils, in the absence of hydrogen, by extraction with selective solvents characterised by the solvent used
    • C10G21/12—Organic compounds only
    • C10G21/16—Oxygen-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G27/00—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
    • C10G27/04—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G27/00—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
    • C10G27/04—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen
    • C10G27/12—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen with oxygen-generating compounds, e.g. per-compounds, chromic acid, chromates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G53/00—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more refining processes
    • C10G53/02—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more refining processes plural serial stages only
    • C10G53/04—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more refining processes plural serial stages only including at least one extraction step
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G53/00—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more refining processes
    • C10G53/02—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more refining processes plural serial stages only
    • C10G53/14—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more refining processes plural serial stages only including at least one oxidation step
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/02—Gasoline
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/04—Diesel oil
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/06—Gasoil

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Microbiology (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

Disclosed herein is a method for producing ultra-low-sulfur content hydrocarbon fuel and product thereof. The method comprises selective biocatalytic oxidation of sulfur containing compounds present in the fuels employing enzyme lipase as biocatalyst in presence of controlled and incremental amount of hydrogen peroxide and carboxylic acid without using water or any co-factor for the reactivity of said enzymes.
PCT/IN2005/000355 2005-10-28 2005-10-28 Method for bio-oxidative desulfurization of liquid hydrocarbon fuels and product thereof WO2007049287A2 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
PCT/IN2005/000355 WO2007049287A2 (en) 2005-10-28 2005-10-28 Method for bio-oxidative desulfurization of liquid hydrocarbon fuels and product thereof
DK05823611.8T DK1957118T3 (en) 2005-10-28 2005-10-28 PROCEDURE FOR BIO-OXIDATIVE SULFURATION OF LIQUID CARBON HYDROID FUELS AND PRODUCT THEREOF
EP05823611.8A EP1957118B1 (en) 2005-10-28 2005-10-28 Method for bio-oxidative desulfurization of liquid hydrocarbon fuels and product thereof
US12/091,913 US20090217571A1 (en) 2005-10-28 2005-10-28 Method for bio-oxidative desulfurization of liquid hydrocarbon fuels and product thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/IN2005/000355 WO2007049287A2 (en) 2005-10-28 2005-10-28 Method for bio-oxidative desulfurization of liquid hydrocarbon fuels and product thereof

Publications (2)

Publication Number Publication Date
WO2007049287A2 WO2007049287A2 (en) 2007-05-03
WO2007049287A3 true WO2007049287A3 (en) 2007-11-08

Family

ID=37968221

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/IN2005/000355 WO2007049287A2 (en) 2005-10-28 2005-10-28 Method for bio-oxidative desulfurization of liquid hydrocarbon fuels and product thereof

Country Status (4)

Country Link
US (1) US20090217571A1 (en)
EP (1) EP1957118B1 (en)
DK (1) DK1957118T3 (en)
WO (1) WO2007049287A2 (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010008750A2 (en) * 2008-06-24 2010-01-21 Novozymes A/S Recovery of liquid hydrocarbons
US9023120B2 (en) * 2009-06-19 2015-05-05 Cyuba Enzyme Ltd. Fuel production method, fuel production apparatus, and fuel oil
EP3339399A1 (en) * 2016-12-22 2018-06-27 Rainer Tesch A method for treating petroleum or natural gas

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5876990A (en) * 1996-10-22 1999-03-02 Reddy; Malireddy S. Biochemical media system for reducing pollution
US5980733A (en) * 1994-04-15 1999-11-09 United Laboratories International Method of removing sulfur compounds from hydrocarbon streams
US6398707B1 (en) * 2001-05-31 2002-06-04 Wen-Teng Wu Method of preparing lower alkyl fatty acids esters and in particular biodiesel

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3551328A (en) * 1968-11-26 1970-12-29 Texaco Inc Desulfurization of a heavy hydrocarbon fraction
JP3227521B2 (en) * 1992-04-06 2001-11-12 舟越 泉 Method for recovering organic sulfur compounds from liquid oil
AU693633B2 (en) * 1994-12-08 1998-07-02 Energy Biosystems Corporation Method of desulfurization of fossil fuel with flavoprotein
US6071738A (en) * 1997-09-19 2000-06-06 Energy Biosystems Corporation Conversion of organosulfur compounds to oxyorganosulfur compounds for desulfurization of fossil fuels
US6160193A (en) * 1997-11-20 2000-12-12 Gore; Walter Method of desulfurization of hydrocarbons
US6171478B1 (en) * 1998-07-15 2001-01-09 Uop Llc Process for the desulfurization of a hydrocarbonaceous oil
US5958224A (en) * 1998-08-14 1999-09-28 Exxon Research And Engineering Co Process for deep desulfurization using combined hydrotreating-oxidation
FR2793256B1 (en) * 1999-05-05 2001-07-27 Total Raffinage Distrib PROCESS FOR OBTAINING LOW SULFUR OIL PRODUCTS BY DESULPHURIZING EXTRACTS
US6251289B1 (en) * 1999-06-03 2001-06-26 Grt, Inc. Treatment of contaminated liquids with oxidizing gases and liquids
US6461859B1 (en) * 1999-09-09 2002-10-08 Instituto Mexicano Del Petroleo Enzymatic oxidation process for desulfurization of fossil fuels
ATE513056T1 (en) * 1999-10-15 2011-07-15 Avatar Medical L L C STABILIZED PROTEINS
US6596914B2 (en) * 2000-08-01 2003-07-22 Walter Gore Method of desulfurization and dearomatization of petroleum liquids by oxidation and solvent extraction

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5980733A (en) * 1994-04-15 1999-11-09 United Laboratories International Method of removing sulfur compounds from hydrocarbon streams
US5876990A (en) * 1996-10-22 1999-03-02 Reddy; Malireddy S. Biochemical media system for reducing pollution
US6398707B1 (en) * 2001-05-31 2002-06-04 Wen-Teng Wu Method of preparing lower alkyl fatty acids esters and in particular biodiesel

Also Published As

Publication number Publication date
US20090217571A1 (en) 2009-09-03
EP1957118A4 (en) 2009-12-23
DK1957118T3 (en) 2013-09-08
EP1957118A2 (en) 2008-08-20
EP1957118B1 (en) 2013-06-19
WO2007049287A2 (en) 2007-05-03

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