WO2004079089A1 - A composite forming fabric - Google Patents

A composite forming fabric Download PDF

Info

Publication number
WO2004079089A1
WO2004079089A1 PCT/EP2004/050218 EP2004050218W WO2004079089A1 WO 2004079089 A1 WO2004079089 A1 WO 2004079089A1 EP 2004050218 W EP2004050218 W EP 2004050218W WO 2004079089 A1 WO2004079089 A1 WO 2004079089A1
Authority
WO
WIPO (PCT)
Prior art keywords
interchanging
weft
yarns
side layer
pairs
Prior art date
Application number
PCT/EP2004/050218
Other languages
French (fr)
Inventor
Stewart Lister Hay
Original Assignee
Voith Fabrics Patent Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Voith Fabrics Patent Gmbh filed Critical Voith Fabrics Patent Gmbh
Priority to US10/547,034 priority Critical patent/US20060231154A1/en
Priority to EP04715332A priority patent/EP1604063A1/en
Publication of WO2004079089A1 publication Critical patent/WO2004079089A1/en

Links

Classifications

    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21FPAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
    • D21F1/00Wet end of machines for making continuous webs of paper
    • D21F1/0027Screen-cloths
    • D21F1/0036Multi-layer screen-cloths

Definitions

  • the present invention relates to fabrics with paired, interchanging yarns, and more particularly, to fabrics employed in web forming equipment, such as papermaking and non-woven web forming equipment. More particularly, the preferred fabrics of this invention are employed as forming fabrics in web forming equipment.
  • Papermaking involves the forming, pressing and drying of cellulosic fiber sheets.
  • the forming process includes the step of depositing an aqueous stock solution of the fibers, and possibly other additives, onto the forming fabric upon which the initial paper web is formed.
  • the forming fabric may run on a so-called Gap Former machine in which the aqueous stock initially is dewatered, and the initial paper sheet is formed between two forming fabrics.
  • An effective forming process typically produces a sheet with a very regular distribution of fibers and with a relatively high solids content, i.e., a high fiber-to-water weight ratio.
  • the forming fabric In order to form a fibrous web with a desired uniform, regular distribution and high fiber-to-water weight ratio, the forming fabric must possess a number of properties.
  • the papermaking surface should be relatively planar; resulting from the yarn floats in both the machine direction (MD) and cross-machine-direction (CD) lying at substantially the same height, to thereby prevent localized penetration of the fibers into the fabric. Such localized penetration results in "wire marks" which actually is the result of fiber density variations throughout the sheet area.
  • the MD and CD floats need to be distributed in a regular manner to avoid introducing undesired wire marks into the formed sheet.
  • these basis weight variations can result in undesired variations in sheet absorption properties; a property very relevant to the functionality of quality graphical papers where a consistent uptake of print ink is necessary to produce a clear sharp image.
  • wire marks can be introduced into the sheet by the flow of water around yarns positioned below the fabric's papermaking surface. This phenomena, referred to as "strike through” needs to be taken into account in designing the fabric construction.
  • the forming fabric must also possess a high degree of dimensional stability. This high stability is necessary, for example, to minimize cyclic variations in fabric width, which can result in MD wrinkles in the fabric. This, in turn, contributes to the so-called, streaky sheet, i.e., a sheet with machine direction streaks created by variations in fiber density.
  • One type of multi-layer structure is a triple-layer fabric made by joining two (2) distinct fabrics, each with their own machine direction (warp) yarns and cross-direction (weft) yams, by the use of additional and independent "binding yarns.” These binding yarns can be employed in either the machine direction or cross-machine-direction, and in this system provide the sole function of binding the two separate fabrics together. In other words, these binding yarns are not intended to function as part of the warp or weft yarn system in either the top fabric or the bottom fabric of the multi-layer structure.
  • Such a triple-layer fabric is illustrated in EP 0,269,070(JWI Ltd.).
  • Nonwovenafilt AB discloses a triple-layer structure wherein paper side yarns are used to bind the paper side and wear side fabrics into one structure.
  • Triple-layer structures whether employing separate and distinct binding yarns or intrinsic binding yarns that form part of the paper side and/or wear side weave structure, allow, to some extent, for the use of fine machine direction and cross-machine-direction yams in the paper side fabric layer for improved papermaking quality and sheet release. Additionally, the use of significantly coarser yarns can be employed in the lower fabric layer, or wear side fabric layer, which contacts the paper machine elements, to thereby provide good stability and fabric life. Thus, these triple-layer structures have the capability of providing optimum papermaking properties in the paper side fabric layer and optimum mechanical properties in the wear side fabric layer.
  • a further common feature of the known self-stitched and other triple-layer designs is that they are relatively thick structures with a high amount of empty space distributed throughout their thickness.
  • the relatively high "void volume" is typically associated with sheet rewetting on the paper machine such that the sheet solids content at transfer to the press section may be undesirably low. That is, the fibrous web formed on the papermaking fabric has an undesirably low fiber-to-weight ratio. This can result in reduced papermaking machine performance through a higher amount of sheet breaks, reduced running speed and higher drying costs downstream of initial web formation.
  • U.S. Patent No. 4,636,426, discloses a relatively thin, forming fabric with reduced rewetting potential.
  • this forming fabric includes two adjacent, monofilaments strands of conventional circular cross-section glued together using a heat-activated polymeric adhesive.
  • the joined cylindrical strands are utilized in either or both of the machine and cross-direction yarns of the fabric.
  • the adhesive also is used to adhere the machine direction and cross-direction yarns at their cross-over points. By this means yarns of smaller than normal diameter can be used to thereby reduce the overall height of the fabric.
  • fabrics formed in the above way have the disadvantage that an additional gluing process is required which adds to the manufacturing cost of the fabric.
  • results may not be permanent, in that the fabrics are susceptible to separation of the joined (glued or fused) yarns. Additionally, the reduction in yam mass, compared with prior art structures of the type disclosed in the U.S. Patent No. 4,636,426, may result in reduced fabric stability.
  • the paper side layer and the machine side layer each comprise machine direction warp yams and non- interchanging cross-machine-direction weft yarns woven together; said paper side layer and said machine side layer each having a weave pattern in the cross-machine direction with a predetermined repeat; each pair of first and second interchanging yarns having at least two (2) segments in the paper side layer within each repeat of the weave pattern, said segments providing an unbroken weft path in the paper side surface, with each succeeding segment being separated in the paper side surface of the paper side layer by at least one paper side layer transitional warp yarn; at least one pair of first and second interchanging yarns within each repeat of the weave pattern being intrinsic top weft binder yarn pairs for stiffening the fabric and binding together the paper side layer and the machine side layer of the fabric.
  • the transitional warp yam defines the length of each segment made in the paper side layer of the fabric by each individual yarn of an interchanging yarn pair. Specifically, one yarn of each pair forms a segment of the paper side weft path and then drops out of the paper side surface adjacent one side of the transitional warp yarn, while the other yam of the pair moves into the paper side layer adjacent the opposite side of the transitional warp yam to begin forming a second segment of the paper side weft path.
  • Intrinsic weft binder yarns are weft yarns that are part of the weave structure of the paper side surface of the paper side layer and also serve to bind together the paper side layer and machine side layer within each repeat of the weave pattern.
  • each intrinsic weft binder yam of each pair of first and second intrinsic weft binder yams provides two functions within each repeat of the weave pattern. One function is to contribute to the weave structure of the paper side surface of the paper side layer, and the second function is to bind together the paper side layer and the machine side layer.
  • Each intrinsic weft binder yarn within each pair of interchanging yarns forms the weft path in at least one segment of the paper side layer within each repeat of the weave pattern, and then disappears from the paper side surface at a transitional warp yarn by dropping down to engage at least one warp yarn in the machine side layer underlying another segment within each repeat of the weave pattern to thereby bind the machine side layer to the paper side layer.
  • one yarn forms part of the weft path in a segment of the paper side layer within each repeat of the weave pattern that is not occupied by the other yarn of the intrinsic weft binder yarn pair, and then drops down to engage at least one warp yarn of the machine side layer in a region underlying the other intrinsic weft binder yam which is forming another segment of the weft path of the paper side layer.
  • each of the weft binder yams within each pair of intrinsic weft binder yarns contributes to the weft path in the paper side surface in at least one segment of the repeat and also drops down to engage at least one machine direction yarn in the machine side layer in a region underlying a different segment within said repeat of the weave pattern.
  • one of the intrinsic weft binder yarns within each pair of binder yams provides a weft path in the paper side surface in one segment while the second intrinsic weft binder yam of the pair engages at least one machine direction warp yarn in the machine side layer underlying said one segment, and said first intrinsic weft binder yarn then moves out of the paper side layer and into the machine side layer to engage at least one machine direction warp yarn of the machine side layer in the second segment within each repeat of the weave pattern and said second intrinsic weft binder yam moves up into the second segment of the paper side layer to continue the weft path in the cross-machine-direction of the paper side fabric layer.
  • the segments in the paper side layer formed by pairs of interchanging yams within each repeat of the weave pattern provide an unbroken weft path in the paper side surface, with each succeeding segment being separated in the paper side surface of the paper side layer by at least one paper side layer transitional warp yarn.
  • This latter arrangement of intrinsic binder yarn pairs in a weave pattern having only two segments in the paper side layer is disclosed in Seabrook et al., U.S. Patent No. 5,826,627, the subject matter of which is herein fully incorporated by reference. It should be understood that in the structures disclosed in the Seabrook et al., '627 patent, all of the interchanging weft yarn pairs are binder yarn pairs and the disclosed papermaking fabrics include only two segments in the paper side layer within each repeat of the weave pattern.
  • Intrinsic top weft/binder yarn pairs means a pair of yams wherein one yarn of the pair; namely the binder yarn of the pair, forms the weft path in the paper side surface of the paper side layer in at least one segment of each repeat of the weave pattern and then drops down to encircle at least one warp yarn in the machine side layer in a region underlying at least another segment within each repeat of the weave pattern in the paper side layer.
  • the weft yarn of the weft/binder yam pair forms the weft path in a segment in the paper side layer within each repeat of the weave pattern that is not occupied by the binder yarn of the pair, and then drops our of the paper side layer to float between the paper side layer and machine side layer in one or more other segments within each repeat of the weave pattern; without in any way binding the paper side layer to the machine side layer.
  • a "top weft/binder yarn pair" is illustrated in Fig. 2(b) of International Publication No. WO 02/14601, the subject matter of which is incorporated herein by reference.
  • the fabric includes a plurality of intrinsic interchanging binder yarn pairs and a plurality of intrinsic, interchanging top weft/binder yarn pairs.
  • at least 50% of the interchanging yam pairs are intrinsic interchanging top weft/binder yam pairs.
  • alternate top weft yarns are provided by interchanging yarn pairs; with alternate pairs being binder yarn pairs and the other alternate pairs being top weft/binder yarn pairs.
  • 50% of the top weft yarns are formed by interchanging yarn pairs, with 50% of such interchanging yarn pairs being binder yam pairs and the other 50% of such interchanging yam pairs being intrinsic top weft/binder yam pairs.
  • the composite fabric in addition to including at least one pair of intrinsic, interchanging binder yam pairs and at least one pair of intrinsic interchanging top weft/binder yarn pairs, also includes at least one pair of intrinsic interchanging weft yam/weft yarn pairs.
  • weft yarn/weft yam in referring to a pair or pairs of yarn(s) refer(s) to a pair of intrinsic interchanging yarns wherein each yarn forms the cross direction weave path in alternate segments of the paper side surface and then drops down to float between the paper side layer and the machine side layer in the remaining segments within the repeat, and then, after floating between the paper side layer and machine side layer, moves back into the paper side layer to provide a continuation of the weft path in the fabric.
  • One ya of the weft yarn/weft yarn pair floats between the paper side layer and the machine side layer in a region underlying the segment in which the other weft yam of the pair forms the weft path in the paper side surface, and then moves up into the paper side surface in an adjacent segment to form the weft path in that segment of the paper side surface overlying the portion of the other weft yarn of the pair that has moved out of the paper side layer to float between the paper side layer and machine side layer in such adjacent segment.
  • the weft yam/weft yam pair cooperates to provide a continuous unbroken weft path across the paper side surface and also includes segments that float between the paper side layer and the machine side layer to stiffen the fabric.
  • Neither yam of the weft yarn/weft yarn pair cooperates to bind the paper side layer and the machine side layer together.
  • segments within each repeat of the weave pattern may have different lengths, if desired. That is, one weft yarn of a pair of interchanging yarns interlaces with a number of adjacent top warp yarns in one segment that is different from the number of adjacent top warp yams that interlace with the other weft yarn of the pair in another segment within each repeat of the weave pattern.
  • the paper side layer and the machine layer together are woven in a predetermined number of sheds to provide the repeat pattern of the composite fabric.
  • a twenty (20) shed fabric includes ten (10) machine direction warp yarns in the paper side layer and ten (10) machine direction warp yarns in the machine side layer vertically underlying machine direction warp yams in the paper side layer.
  • At least some of the binder yams in the pairs of first and second intrinsic, interchanging yarns float under at least two adjacent wear side machine direction yams, and if desired, under at least three adjacent wear side machine direction yarns to provide enhanced binding of the paper side layer to the machine side layer.
  • the overall height and void volume within the fabric is reduced. This reduces the potential water carrying potential of the fabric; resulting in the formation of a dryer sheet on the fabric.
  • At least some of the binder yarns of the interchanging binder yarn pairs interlace with a number of single, non-adjacent wear side MD yarn within each repeat of the weave pattern.
  • all or some of the wear side and/or paper side warp yams can be of a non-circular cross section but particularly of bi- nodal (e.g., dumbbell - or "figure 8" shaped) cross-section.
  • the bi-nodal yarn(s) is (are) extruded with the bi-nodal cross section and thus require(s) no bonding process of the type employed in the prior art, where two adjacent, but separately-formed warp yams have been woven to an identical weave repeat.
  • bi-nodal warps with a vertical-to- horizontal aspect ratio of at least 1:1.25, allows a thinner fabric to be provided but with the same overall cross sectional area as prior art structures. This will reduce the water carrying capacity of the fabric, thereby resulting in the formation of a paper sheet with reduced moisture content in the forming section, which, in turn, reduces production costs.
  • each bi-nodal yarn provides a drainage channel along the center thereof to effectively direct water through the fabric; (2) the use of bi-nodal yarns avoids the single large surface of the prior rectangular and ovate yarns, which could directly or indirectly undesirably mark the sheet; (3) when used as a wear side warp the bi-nodal yarn is less likely to cause as severe a distortion of the interlacing weft yam knuckles as a yam of similar cross-sectional area but of a circular cross section to thereby potentially cause less strike-through marking of a paper sheet formed thereon and (4) when used in the fabric paper side layer in the same number as prior art, circular cross-section yarns the bi-nodal yarn will double the MD orientated fiber support points of the fabric due to the two, generally circular, dumbbell shaped
  • the binder position relative to the interlacings of the warp and weft yarns in the wear side layer of the fabric can be selected to facilitate a significant increase in fabric bending stiffness and thus the ability of the fabric to control sheet basis weight profiles in a desired manner.
  • the embodiments of the invention illustrated herein typically have 2:1 ratio of paper side layer cross-machine-direction weft paths to wear side cross-machine- direction weft paths.
  • the preferred embodiments of this invention include non-interchanging weft yams in the paper side layer, it is within the scope of this invention to form the paper side layer with warp yarns and only interchanging CD yarn pairs.
  • Fabrics of the invention may be made on looms such as Juergen's JP2000 or Jaeger's BK600, which have been fitted with a suitably high shaft capacity, or may be made on looms which utilize jacquard control over all or for some of the warp yarns.
  • a table showing preferred fabrics combinations and the required shafts is shown below. It can be seen that there are generally higher number of weave repeats when using the "high shaft” technique. This provides a significant benefit by allowing more randomness and flexibility in distributing binding points in composite fabrics and in distributing interchange points of interchanging yam pairs employed in the fabric. In this way, a fabric with a reduced tendency to form undesired wiremarks in the formed paper sheet can be provided compared to the prior art.
  • Fig. 1 illustrates transverse sectional views between each weft path in one repeat of a fabric in accordance with this invention
  • Fig. 2 illustrates transverse sectional views between each weft path in one repeat of a fabric in accordance with another embodiment of this invention.
  • the composite forming fabric has a 20 shaft - 40 pick repeat and includes a paper side layer 12 having a paper side surface 14, a machine side layer 16 having a bottom wear side surface 18 and a plurality of first and second interchanging yams pairs, e.g., 20.
  • the paper side layer 12 and the machine side layer 16 each comprise a plurality of warp yarns 22 in the machine direction and plurality of non-interchanging weft yams 24 woven together with the warp yarns.
  • the paper side layer 12 and the machine side layer 16 each have a predetermined repeat of the weave pattern in the cross-machine direction.
  • the illustrated composite fabric 10 is a twenty (20) shed - forty (40) pick fabric including ten (10) machine direction warp yarns 22 in the paper side layer, shown at 1, 3, 5, 7, 9, 11, 13, 15, 17 and 19, and ten (10) machine direction warp yarns 22 in the machine side layer, show at 2, 4, 6, 8, 10, 12, 14, 16, 18 and 20.
  • the non-interchanging weft yams in the paper side layer 12 are designated in Fig. 1 by the prefix "T" and the non-interchanging weft yarns in the machine side layer 16 are designated in Fig. 1 by the prefix "B.”
  • the first and second interchanging yarns of each pair of interchanging yarns are designated with the prefix "I"; a first pair being designated 11, 12; another pair being designated 13, 14, and so on.
  • Each pair of interchanging yarns has two segments in the paper side layer within each repeat of the weave pattern. These segments provide an unbroken weft path in the paper side surface, with each succeeding segment being separated in the paper side surface of the paper side layer by at least one paper side layer transitional warp yarn 22T (e.g., lop warp yams 5 and 13 are transitional warp yarns for interchanging binder yarns 19, 110).
  • the pairs of interchanging yarns 20 move out of and into the paper side layer, respectively, on opposite sides of each transitional warp yarn. As is shown in Fig. 1, the interchanging yarns cross each other as they move in opposite directions in a region generally underlying the transitional warp yams.
  • the fabric 10 of this invention includes a first set of alternating pairs of first and second interchanging yarns within each repeat of the weave pattern constituting binder yarn pairs 26 for binding together the paper side layer and machine side layer, i.e., 11-12; 15-16; 19-110; 113-114 and 117-118.
  • the fabric 10 also includes a second, alternating set of pairs of first and second interchanging yarns within each repeat of the weave pattern constituting top weft/binder yarn pairs 28 for stiffening the fabric and binding together the paper side layer and the machine side layer of the fabric. This second set of top weft/binder yarn pairs is shown at 13-14; 17-18; 111-112; 115- 116 and 119-120.
  • the top weft yarn in each of the top/weft binder yarn pairs floats between the paper side layer 12 and the machine side layer 16 to provide a stiffening function.
  • the top weft yarn of each of the top weft/binder yarn pairs actually floats between five (5) sets of upper and lower warp yarns in the paper side layer and machine side layer, respectively, e.g., the top weft yarn in the top weft/binder yarn pair I3-I4 floats between adjacent upper and lower warp yarns 13-14; 15-16; 17-18; 19-20 and 1-2.
  • the binder yam in each of the top weft/binder yarn pairs forms two knuckles in the paper side layer segment within each weave repeat, e.g., the binder yam in the top weft/binder yarn pair I3-I4 forms knuckles over top warp yarns 15 and 19; the binder yarn in the top weft/binder yarn pair I7-I8 forms knuckles overtop warp yarns 3 and 7; etc.
  • both the float distance of the top weft yam and the number of formed knuckles of the binder yarn in the paper side layer in top weft binder yarn pairs can be varied within each repeat of the weave pattern.
  • the binder yarn pairs and the weft binder yarn pairs each constitute 50% of the interchanging yam pairs in the fabric
  • the percentage of interchanging yarn pairs provided by binder yam pairs and top weft binder yam pairs cam be varied.
  • alternate unbroken weft paths are provided by the pairs of first and second interchanging yarns, which alternate with non- interchanging, top weft yarns that weave only with the warp yarns of the paper side layer.
  • 50% of the weft yarn paths in the cross-machine direction of the paper side layer are provided by interchanging pairs of ya s, and the other 50% are provided by non-interchanging weft yarns that interweave solely with the warp yarns of the paper side layer.
  • the weft yarns in the paper side layer and in the machine side layer are non-interchanging yarns, i.e., they are disposed only in the paper side layer and the machine layer, respectively, in accordance with the broadest aspect of this invention the number of such non-interchanging weft yarns can be varied within wide limits. Additionally, the percentage of binder yarn pairs and top weft binder yarn pairs also can be varied within wide limits and, if desired, may form all of the weft paths in the paper side layer.
  • adjacent weft paths in the paper side layer are provided successively by a non- interchanging top weft yam, a pair of interchanging binder yam pairs, a non- interchanging top weft yarn and a pair of top weft/binder yam pairs.
  • These four weft paths repeat continuously throughout the fabric structure.
  • one-half of the weft yarn paths in the paper side layer fabric are provided by non- interchanging weft yams; one-quarter of the weft yarn paths in the paper side layer are provided by binder yarns pairs and the other one-quarter of the weft yarn paths in the paper side layer are provided by weft/binder yam pairs.
  • each of the different weft yarns in the paper side layer can be varied within wide limits.
  • within each repeat of the weave pattern there is included at least one pair of first and second interchanging yarns in the form of a binder yarn pair and at least one pair of first and second interchanging yarns in the form of a top weft/binder yarn pair.
  • 50% of the interchanging yarn pairs are binder yarn pairs and 50% of the interchanging yarn pairs are top weft/binder yarn pairs.
  • an alternate embodiment of a fabric of this invention is indicated at 100.
  • the fabric 100 has a number of features that are similar to the fabric 10.
  • the fabric 100 like the fabric 10 includes alternating, non- interchanging top weft yarns and interchanging yarn pairs.
  • every other interchanging yam pair is a binder/binder pair and the other alternate interchanging yarn pairs are top weft/binder yarn pairs.
  • the fabric 100 has a 20 shaft - 80 pick repeat, unlike the 20 shaft - 20 pick repeat of the Fig. 1 embodiment.
  • the increase in the pick repeat results from two variations in the weave pattern of the top weft binder yarn pairs in the Fig. 2 embodiment.
  • the top weft yam in adjacent lop weft binder yam pairs float, respectively, between five (5) sets of upper and lower warp yarns and seven (7) sets of upper and lower warp yarns, e.g., the top weft yarn of the top weft yarn/binder yarn pair 13-14 floats between the five (5) sets of upper and lower warp yarns 13-14, 15- 16, 1 -18, 19-20 and 1 -2, and the top weft yarn of the adjacent top weft yarn/binder yarn pair I7-I8 floats between the seven (7) sets of upper and lower warp yarns 9-10, 11-12, 13-14, 15-16, 17-18, 19-20 and 1-2.
  • the second variation is that the binder yarn of adjacent top weft/ binder yarn pairs alternately forms two (2) paper side knuckles and three (3) paper side knuckles within each repeat of the weave pattern, e.g., the binder yarn in the top weft/binder yarn pair 13-
  • the percentage of non-interchanging binder yarn pairs, the percentage of interchanging top weft/binder yam pairs and the percentage of interchanging binder yam pairs can be varied within wide limits. If desired the interchanging top weft binder yarn pairs and interchanging binder yarn pairs can form all of the weft paths in the structure.
  • Applicant has determined that significant advantages may be obtained in the fabrics 10 and 100 of this invention, as compared to prior art structures in which all of the interchanging yarn pairs are binder/binder pairs.
  • prior art structures and the fabrics 10, 100 were formed with the warp and weft yarns being of the same diameter and with the same number of warp and weft paths per unit area.
  • the prior art structures included alternating weft paths formed by non-interchanging top weft yarns having a diameter of 0.13 mm and by interchanging binder/binder yarns with each yam of the pair having a diameter of 0.13 mm.
  • the fabrics 10 and 100 included alternating weft paths formed by non-interchanging top weft yams having a diameter of 0.13 mm and by interchanging yarn pairs with each yarn of the pair having a diameter of 0.13 mm, wherein every other interchanging yarn pair was a bind/binder yarn pair and a top weft/binder yarn pair, respectively.
  • the fabrics 10 and 100 had a higher air permeability (cubic feet per minute), a greater thickness, or caliper (millimeters) and a higher void volume (cubic centimeters/square meter) than the prior art structure.
  • a composite forming fabric has the same construction as the forming fabric 10 or 100, with the exception that one or more weft yarns, e.g., either non-interchanging weft yarns, interchanging binder/binder weft yarn pairs and/or interchanging lop weft binder yam pairs, is (are) replaced with a fourth type of weft yarn system; namely, an intrinsic interchanging weft yarn/weft yarn pair.
  • weft yarns e.g., either non-interchanging weft yarns, interchanging binder/binder weft yarn pairs and/or interchanging lop weft binder yam pairs
  • an intrinsic interchanging weft yarn/weft yarn pair cooperates to provide a continuous weft path in the top fabric layer within each repeat of the weave pattern, just like the interchanging bind/binder yarn pairs and the interchanging top weft/binder yarn pairs.
  • the yarns of the interchanging weft yarn/weft yarn pairs when they drop out of the top surface adjacent a top warp transitional yarn, float between the top warp yarns and bottom warp yarns without binding to a bottom warp yarn.
  • alternating weft paths in the paper side layer are provided by non-interchanging weft yams, and located between each pair of these non-interchanging weft yarn paths is a binder yarn pair, a top weft/binder yam pair and a weft yarn/weft yarn pair, respectively, in any desired order.
  • one half of the weft paths are provided by non- interchanging top weft yarns; one-third of the weft paths provided by interchanging yarn pairs are provided by top weft/binder yarn pairs, one-third of the weft paths provided by interchanging yam pairs are provided by weft yarn/binder yarn pairs and one-third of the weft paths provided by interchanging yarn pairs are provided by weft yam/weft yarn pairs.
  • the percentages of each of the different types of interchanging yarn pairs can be varied within wide limits.
  • the composite forming fabric can include a single pair of first and second interchanging yarns in the form of weft yarn/weft yarn pairs, with the remaining interchanging yam pairs being binder yarn pairs and/or weft binder yarn pairs.
  • interchanging yarn pairs of the same or different type can be included adjacent to each other, in which case at least some of the adjacent non-interchanging top weft yarns will be spaced apart from each other by more than one interchanging yarn pair.
  • Embodiments of the invention including non-interchanging lop weft yarns in the paper side layer; binder yarn pairs having segments in the paper side layer providing an unbroken weft path within each repeat of the weave pattern; top weft/top weft yarn pairs providing an unbroken weft path within each repeat of the weave pattern and weft yarn/binder yarn pairs providing an unbroken weft path with each repeat of the weave pattern have been described earlier herein. Suffice it to state that the form of the fabrics of this invention can include a combination of each of the four types of cross-machine direction weft yarns in the paper side layer. By varying the structure of the top weft path in the paper side layer to include different types of interchanging yarns and non- interchanging yarns, the overall properties of the forming fabric can be varied within wide limits, as dictated by the particular application of the fabric.
  • segments of one or more pairs of interchanging yams can be of a different length within each repeat of the weave pattern.
  • the paper side segments provided by either all or some of the interchanging yarn pairs; whether such interchanging yam pairs are binder yam pairs, weft yam/binder yarn pairs and/or weft yarn/weft yarn pairs can be of different lengths.
  • each interchanging yarn pair provides segments of different length within each repeat of the weave pattern it is possible to vary the sequence in which the pair of yams are placed in the fabric. For example, in a first pair of interchanging yam pairs, the yarn providing the longest segment may be positioned prior to the other yarn of the pair, which provides the shortest segment. This arrangement may be reversed for the yams of other interchanging yarn pairs throughout the fabric weave repeat. Furthermore, each interchanging yarn pair need not provide segments of the same length as other interchanging yarn pairs. In this case, it may be that the number of segments in some pairs of interchanging yarn pairs differs from the number of segments in other pairs of interchanging yarn pairs. This latter feature will be the subject of a separate patent application.
  • the shape of the warp and weft yams in both the paper side layer and the machine side layer can be varied within the broadest aspects of the invention.
  • a more planar forming surface is provided, which should achieve a more uniform formation of the fibrous web.
  • modifications include having one or more of the binder yarns of interchanging binder yarn pairs and/or interchanging top weft binder yarn pairs bind to more than one bottom warp yarn.
  • Such multiple bottom warp yams can be adjacent to each other or spaced-apart from each other. In either case the binding preferably takes place with bottom warp yams underlying top segments in which the other yarn of the pair is forming a portion of the top weft path.

Landscapes

  • Paper (AREA)

Abstract

A composite forming fabric comprising a paper side layer having a paper side surface, a machine side layer having a bottom wear side surface, and a plurality of pairs of first and second interchanging yarns, wherein: the paper side layer and the machine side layer each comprise warp yarns and weft yarns woven together; said paper side layer and said machine side layer each having a predetermined repeat of the weave pattern in the cross-machine-direction; each pair of first and second interchanging yarns having at least two segments in the paper side layer within each repeat of the weave pattern, said segments providing an unbroken weft path in the paper side surface, with each succeeding segment being separated in the paper side surface of the paper side layer by at least one paper side layer transitional warp yarn; at least one pair of first and second interchanging yarns within each repeat of the weave pattern being binder yarn pairs, each binder yarn in each binder yarn pair binding together the paper side layer and the machine side layer, and at least one pair of first and second interchanging within each repeat of the weave pattern being top weft/binder yarn pairs for stiffening the fabric and binding together the paper side layer and the machine side layer of the fabric.

Description

A COMPOSITE FORMING FABRIC
FIELD OF THE INVENTION
The present invention relates to fabrics with paired, interchanging yarns, and more particularly, to fabrics employed in web forming equipment, such as papermaking and non-woven web forming equipment. More particularly, the preferred fabrics of this invention are employed as forming fabrics in web forming equipment.
BACKGROUND OF THE INVENTION
Papermaking involves the forming, pressing and drying of cellulosic fiber sheets. The forming process includes the step of depositing an aqueous stock solution of the fibers, and possibly other additives, onto the forming fabric upon which the initial paper web is formed. The forming fabric may run on a so-called Gap Former machine in which the aqueous stock initially is dewatered, and the initial paper sheet is formed between two forming fabrics.
An effective forming process typically produces a sheet with a very regular distribution of fibers and with a relatively high solids content, i.e., a high fiber-to-water weight ratio. In order to form a fibrous web with a desired uniform, regular distribution and high fiber-to-water weight ratio, the forming fabric must possess a number of properties. First, the papermaking surface should be relatively planar; resulting from the yarn floats in both the machine direction (MD) and cross-machine-direction (CD) lying at substantially the same height, to thereby prevent localized penetration of the fibers into the fabric. Such localized penetration results in "wire marks" which actually is the result of fiber density variations throughout the sheet area. In addition, the MD and CD floats need to be distributed in a regular manner to avoid introducing undesired wire marks into the formed sheet. Moreover, these basis weight variations can result in undesired variations in sheet absorption properties; a property very relevant to the functionality of quality graphical papers where a consistent uptake of print ink is necessary to produce a clear sharp image.
Other factors also cause the formation of undesired wire marks. For example, wire marks can be introduced into the sheet by the flow of water around yarns positioned below the fabric's papermaking surface. This phenomena, referred to as "strike through" needs to be taken into account in designing the fabric construction.
Importantly, the forming fabric must also possess a high degree of dimensional stability. This high stability is necessary, for example, to minimize cyclic variations in fabric width, which can result in MD wrinkles in the fabric. This, in turn, contributes to the so-called, streaky sheet, i.e., a sheet with machine direction streaks created by variations in fiber density.
Dimensional stability of a fabric typically is obtained by manufacturing the forming fabric with a relatively high mass of material. However, the use of thick yarns often causes undesirable wire marks. Consequently, there has been a trend to providing composite forming fabrics, that is, "multi-layer" structures, whereby a high number of relatively thin yarns are distributed throughout various fabrics layers to facilitate fabric stability.
One type of multi-layer structure is a triple-layer fabric made by joining two (2) distinct fabrics, each with their own machine direction (warp) yarns and cross-direction (weft) yams, by the use of additional and independent "binding yarns." These binding yarns can be employed in either the machine direction or cross-machine-direction, and in this system provide the sole function of binding the two separate fabrics together. In other words, these binding yarns are not intended to function as part of the warp or weft yarn system in either the top fabric or the bottom fabric of the multi-layer structure. Such a triple-layer fabric is illustrated in EP 0,269,070(JWI Ltd.). Where the two fabrics of the triple-layer structure are joined in either the machine direction of cross-machine-direction by binding yarns that also belong, or form part of the weave pattern of either, or both, of the paper side or wear side fabrics, the resulting structures are referred to more specifically as "self-stitched" triple-layer structures. Such binding yarns are referred to as intrinsic binding yarns. Self-stitched structures are taught in a number of prior art patents. For example, U.S. Patent No. 4,501,303
(Nordiskafilt AB) discloses a triple-layer structure wherein paper side yarns are used to bind the paper side and wear side fabrics into one structure.
Triple-layer structures, whether employing separate and distinct binding yarns or intrinsic binding yarns that form part of the paper side and/or wear side weave structure, allow, to some extent, for the use of fine machine direction and cross-machine-direction yams in the paper side fabric layer for improved papermaking quality and sheet release. Additionally, the use of significantly coarser yarns can be employed in the lower fabric layer, or wear side fabric layer, which contacts the paper machine elements, to thereby provide good stability and fabric life. Thus, these triple-layer structures have the capability of providing optimum papermaking properties in the paper side fabric layer and optimum mechanical properties in the wear side fabric layer.
In the triple-layer and self-stitched fabrics of the prior art there is typically contact between the internal surfaces of the paper side and wear side fabric layers. The internal surface of the wear side fabric layer is dominated by floats of machine direction yarns in all known commercial embodiments of the triple-layer and self-stitched fabrics. Where wear side fabric cross-direction yarns interlace with wear side fabric machine direction yarns, such that the wear side cross-direction yams appear in the internal region between the paper side and wear side fabric layers, relatively prominent short weft knuckles are formed. The pressure of relatively stiff wear side machine direction yarns acting on the wear side cross-direction yarns during the production of the fabric can cause so-railed "knuckle spread," whereby the wear side cross-direction yarn knuckles are distorted and their width increased lo form a relatively large area. It has been found that fibrous sheet areas formed on the paper side fabric above such knuckles are noticeably different in appearance from adjacent sheet areas. Such sheet differences can contribute to variations in the quality of print imparted to the fibrous sheet in a subsequent printing step.
A further common feature of the known self-stitched and other triple-layer designs is that they are relatively thick structures with a high amount of empty space distributed throughout their thickness. The relatively high "void volume" is typically associated with sheet rewetting on the paper machine such that the sheet solids content at transfer to the press section may be undesirably low. That is, the fibrous web formed on the papermaking fabric has an undesirably low fiber-to-weight ratio. This can result in reduced papermaking machine performance through a higher amount of sheet breaks, reduced running speed and higher drying costs downstream of initial web formation.
U.S. Patent No. 4,636,426, discloses a relatively thin, forming fabric with reduced rewetting potential. Specifically, this forming fabric includes two adjacent, monofilaments strands of conventional circular cross-section glued together using a heat-activated polymeric adhesive. The joined cylindrical strands are utilized in either or both of the machine and cross-direction yarns of the fabric. The adhesive also is used to adhere the machine direction and cross-direction yarns at their cross-over points. By this means yarns of smaller than normal diameter can be used to thereby reduce the overall height of the fabric. However, fabrics formed in the above way have the disadvantage that an additional gluing process is required which adds to the manufacturing cost of the fabric.
Moreover, the results may not be permanent, in that the fabrics are susceptible to separation of the joined (glued or fused) yarns. Additionally, the reduction in yam mass, compared with prior art structures of the type disclosed in the U.S. Patent No. 4,636,426, may result in reduced fabric stability.
A variety of compromise fabrics employing intrinsic interchanging yarn pairs have been disclosed to attempt to deal with the various problems of fabric strength, fabric stability, e.g., fabric stiffness, desired papermaking side performance and desired wear side performance. In particular, various different composite fabric constructions are disclosed in U.S. Patent Nos. 4,501,303 (Oslerberg); 5,152,326 (Voehringer); 5,826,627
(Seabrook, et al.); 5,967,195 (Ward) and International Publication WO 02/14601 A1
(Andreas Kufferath GMBH&Co. KG).
Although the aforementioned composite papermaking fabrics employing intrinsic interchanging yarn pairs have provided improved structures, applicant believes that there still is a need for additional, improved composite structures of the type employing intrinsic interchanging yarn pairs having improved properties, such as reduced sheet marking potential and/or longer service life potential and/or higher resistance to layer delamination. It is to such structures that the present invention is directed.
SUMMARY OF THE INVENTION
The above and other objects of this invention are obtained in composite forming fabrics having a paper side layer with a paper side surface, a machine side layer having a bottom wear side surface and a plurality of pairs of first and second intrinsic interchanging yams. Reference throughout this application to "intrinsic interchanging yams" or "interchanging yams" means yarns that form a part of the weave structure in at least the paper side layer of the composite fabric.
In accordance with a first preferred embodiment of this invention, the paper side layer and the machine side layer each comprise machine direction warp yams and non- interchanging cross-machine-direction weft yarns woven together; said paper side layer and said machine side layer each having a weave pattern in the cross-machine direction with a predetermined repeat; each pair of first and second interchanging yarns having at least two (2) segments in the paper side layer within each repeat of the weave pattern, said segments providing an unbroken weft path in the paper side surface, with each succeeding segment being separated in the paper side surface of the paper side layer by at least one paper side layer transitional warp yarn; at least one pair of first and second interchanging yarns within each repeat of the weave pattern being intrinsic top weft binder yarn pairs for stiffening the fabric and binding together the paper side layer and the machine side layer of the fabric.
The transitional warp yam defines the length of each segment made in the paper side layer of the fabric by each individual yarn of an interchanging yarn pair. Specifically, one yarn of each pair forms a segment of the paper side weft path and then drops out of the paper side surface adjacent one side of the transitional warp yarn, while the other yam of the pair moves into the paper side layer adjacent the opposite side of the transitional warp yam to begin forming a second segment of the paper side weft path.
"Intrinsic weft binder yarns" are weft yarns that are part of the weave structure of the paper side surface of the paper side layer and also serve to bind together the paper side layer and machine side layer within each repeat of the weave pattern. Thus, each intrinsic weft binder yam of each pair of first and second intrinsic weft binder yams provides two functions within each repeat of the weave pattern. One function is to contribute to the weave structure of the paper side surface of the paper side layer, and the second function is to bind together the paper side layer and the machine side layer.
Each intrinsic weft binder yarn within each pair of interchanging yarns forms the weft path in at least one segment of the paper side layer within each repeat of the weave pattern, and then disappears from the paper side surface at a transitional warp yarn by dropping down to engage at least one warp yarn in the machine side layer underlying another segment within each repeat of the weave pattern to thereby bind the machine side layer to the paper side layer. With respect to the intrinsic binder yarn pairs employed in this embodiment of the invention, one yarn forms part of the weft path in a segment of the paper side layer within each repeat of the weave pattern that is not occupied by the other yarn of the intrinsic weft binder yarn pair, and then drops down to engage at least one warp yarn of the machine side layer in a region underlying the other intrinsic weft binder yam which is forming another segment of the weft path of the paper side layer. In other words, within each repeat of the weave pattern, each of the weft binder yams within each pair of intrinsic weft binder yarns contributes to the weft path in the paper side surface in at least one segment of the repeat and also drops down to engage at least one machine direction yarn in the machine side layer in a region underlying a different segment within said repeat of the weave pattern.
In a composite fabric structure including two segments in the paper side layer within each repeat of the weave pattern, one of the intrinsic weft binder yarns within each pair of binder yams provides a weft path in the paper side surface in one segment while the second intrinsic weft binder yam of the pair engages at least one machine direction warp yarn in the machine side layer underlying said one segment, and said first intrinsic weft binder yarn then moves out of the paper side layer and into the machine side layer to engage at least one machine direction warp yarn of the machine side layer in the second segment within each repeat of the weave pattern and said second intrinsic weft binder yam moves up into the second segment of the paper side layer to continue the weft path in the cross-machine-direction of the paper side fabric layer.
Most preferably the segments in the paper side layer formed by pairs of interchanging yams within each repeat of the weave pattern provide an unbroken weft path in the paper side surface, with each succeeding segment being separated in the paper side surface of the paper side layer by at least one paper side layer transitional warp yarn. This latter arrangement of intrinsic binder yarn pairs in a weave pattern having only two segments in the paper side layer is disclosed in Seabrook et al., U.S. Patent No. 5,826,627, the subject matter of which is herein fully incorporated by reference. It should be understood that in the structures disclosed in the Seabrook et al., '627 patent, all of the interchanging weft yarn pairs are binder yarn pairs and the disclosed papermaking fabrics include only two segments in the paper side layer within each repeat of the weave pattern.
Reference throughout this application to "intrinsic top weft/binder yarn pairs" means a pair of yams wherein one yarn of the pair; namely the binder yarn of the pair, forms the weft path in the paper side surface of the paper side layer in at least one segment of each repeat of the weave pattern and then drops down to encircle at least one warp yarn in the machine side layer in a region underlying at least another segment within each repeat of the weave pattern in the paper side layer. The weft yarn of the weft/binder yam pair forms the weft path in a segment in the paper side layer within each repeat of the weave pattern that is not occupied by the binder yarn of the pair, and then drops our of the paper side layer to float between the paper side layer and machine side layer in one or more other segments within each repeat of the weave pattern; without in any way binding the paper side layer to the machine side layer. A "top weft/binder yarn pair" is illustrated in Fig. 2(b) of International Publication No. WO 02/14601, the subject matter of which is incorporated herein by reference.
In a preferred embodiment of this invention the fabric includes a plurality of intrinsic interchanging binder yarn pairs and a plurality of intrinsic, interchanging top weft/binder yarn pairs. In a preferred embodiment of this invention at least 50% of the interchanging yam pairs are intrinsic interchanging top weft/binder yam pairs.
In one preferred embodiment of this invention alternate top weft yarns are provided by interchanging yarn pairs; with alternate pairs being binder yarn pairs and the other alternate pairs being top weft/binder yarn pairs. Thus, in this preferred embodiment, 50% of the top weft yarns are formed by interchanging yarn pairs, with 50% of such interchanging yarn pairs being binder yam pairs and the other 50% of such interchanging yam pairs being intrinsic top weft/binder yam pairs.
In a further embodiment of this invention, the composite fabric, in addition to including at least one pair of intrinsic, interchanging binder yam pairs and at least one pair of intrinsic interchanging top weft/binder yarn pairs, also includes at least one pair of intrinsic interchanging weft yam/weft yarn pairs.
As used throughout this application, reference to "weft yarn/weft yam" in referring to a pair or pairs of yarn(s) refer(s) to a pair of intrinsic interchanging yarns wherein each yarn forms the cross direction weave path in alternate segments of the paper side surface and then drops down to float between the paper side layer and the machine side layer in the remaining segments within the repeat, and then, after floating between the paper side layer and machine side layer, moves back into the paper side layer to provide a continuation of the weft path in the fabric. One ya of the weft yarn/weft yarn pair floats between the paper side layer and the machine side layer in a region underlying the segment in which the other weft yam of the pair forms the weft path in the paper side surface, and then moves up into the paper side surface in an adjacent segment to form the weft path in that segment of the paper side surface overlying the portion of the other weft yarn of the pair that has moved out of the paper side layer to float between the paper side layer and machine side layer in such adjacent segment. Thus, in this embodiment the weft yam/weft yam pair cooperates to provide a continuous unbroken weft path across the paper side surface and also includes segments that float between the paper side layer and the machine side layer to stiffen the fabric. Neither yam of the weft yarn/weft yarn pair cooperates to bind the paper side layer and the machine side layer together.
In accordance with this invention, segments within each repeat of the weave pattern may have different lengths, if desired. That is, one weft yarn of a pair of interchanging yarns interlaces with a number of adjacent top warp yarns in one segment that is different from the number of adjacent top warp yams that interlace with the other weft yarn of the pair in another segment within each repeat of the weave pattern.
In one form of the invention, the paper side layer and the machine layer together are woven in a predetermined number of sheds to provide the repeat pattern of the composite fabric. For example, a twenty (20) shed fabric includes ten (10) machine direction warp yarns in the paper side layer and ten (10) machine direction warp yarns in the machine side layer vertically underlying machine direction warp yams in the paper side layer.
In accordance with certain embodiments of the invention at least some of the binder yams in the pairs of first and second intrinsic, interchanging yarns float under at least two adjacent wear side machine direction yams, and if desired, under at least three adjacent wear side machine direction yarns to provide enhanced binding of the paper side layer to the machine side layer.
In addition, by floating the interchanging yams under two or more adjacent wear side machine direction yarns, the overall height and void volume within the fabric is reduced. This reduces the potential water carrying potential of the fabric; resulting in the formation of a dryer sheet on the fabric.
In an alternative structure for providing a thin fabric with minimal delamination tendency at least some of the binder yarns of the interchanging binder yarn pairs interlace with a number of single, non-adjacent wear side MD yarn within each repeat of the weave pattern.
In all embodiments of the invention disclosed herein all or some of the wear side and/or paper side warp yams can be of a non-circular cross section but particularly of bi- nodal (e.g., dumbbell - or "figure 8" shaped) cross-section. The bi-nodal yarn(s) is (are) extruded with the bi-nodal cross section and thus require(s) no bonding process of the type employed in the prior art, where two adjacent, but separately-formed warp yams have been woven to an identical weave repeat. Use of bi-nodal warps, with a vertical-to- horizontal aspect ratio of at least 1:1.25, allows a thinner fabric to be provided but with the same overall cross sectional area as prior art structures. This will reduce the water carrying capacity of the fabric, thereby resulting in the formation of a paper sheet with reduced moisture content in the forming section, which, in turn, reduces production costs. Furthermore, unlike the use of profiled and flat warp yams employed in prior art forming fabrics, the bi-nodal yarns employed in this invention provide several benefits as follows: (1 ) each bi-nodal yarn provides a drainage channel along the center thereof to effectively direct water through the fabric; (2) the use of bi-nodal yarns avoids the single large surface of the prior rectangular and ovate yarns, which could directly or indirectly undesirably mark the sheet; (3) when used as a wear side warp the bi-nodal yarn is less likely to cause as severe a distortion of the interlacing weft yam knuckles as a yam of similar cross-sectional area but of a circular cross section to thereby potentially cause less strike-through marking of a paper sheet formed thereon and (4) when used in the fabric paper side layer in the same number as prior art, circular cross-section yarns the bi-nodal yarn will double the MD orientated fiber support points of the fabric due to the two, generally circular, dumbbell shaped ends forming part of each bi-nodal yarn; thereby reducing, or minimizing the formation of undesired wire-marks in the formed paper sheet.
In accordance with another aspect of this invention, the binder position relative to the interlacings of the warp and weft yarns in the wear side layer of the fabric can be selected to facilitate a significant increase in fabric bending stiffness and thus the ability of the fabric to control sheet basis weight profiles in a desired manner.
The embodiments of the invention illustrated herein typically have 2:1 ratio of paper side layer cross-machine-direction weft paths to wear side cross-machine- direction weft paths. However, it is within the scope of this invention to provide different ratios of paper side layer CD weft paths to wear side layer CD weft paths, such ratio being dictated by the desired use of the fabric. For example, and not by way of limitation, it is within the scope of this invention to employ paper side layer to machine side layer CD weft path ratios of 1:1, 3:2, 4:3, or another ratio.
Although the preferred embodiments of this invention include non-interchanging weft yams in the paper side layer, it is within the scope of this invention to form the paper side layer with warp yarns and only interchanging CD yarn pairs.
Although the preferred embodiments of the inventions employ a paperside to wearside warp ratio of equal number, specifically 1:1, it is also envisaged that all embodiments can be manufactured with a different warp ratio, e.g., 2:1 or 3:2.
Fabrics of the invention may be made on looms such as Juergen's JP2000 or Jaeger's BK600, which have been fitted with a suitably high shaft capacity, or may be made on looms which utilize jacquard control over all or for some of the warp yarns. A table showing preferred fabrics combinations and the required shafts is shown below. It can be seen that there are generally higher number of weave repeats when using the "high shaft" technique. This provides a significant benefit by allowing more randomness and flexibility in distributing binding points in composite fabrics and in distributing interchange points of interchanging yam pairs employed in the fabric. In this way, a fabric with a reduced tendency to form undesired wiremarks in the formed paper sheet can be provided compared to the prior art.
Figure imgf000014_0001
Figure imgf000015_0001
It should be noted that in some of the identified high shaft fabrics having 28 shafts or more the number of weave repeats in the fabric cross-direction of the weft yams with the warp yarns in the paper side layer within the repeat pattern of the composite fabric is greater than the number of weave repeats in the fabric cross-direction of the weft yams with the warp yams in the machine side layer within the repeat pattern of the composite fabric by a ratio of more than 3:1. The benefits of this feature will be described and claimed in a subsequently filed application.
BRIEF DESCRIPTION OF THE DRAWINGS
Fig. 1 , illustrates transverse sectional views between each weft path in one repeat of a fabric in accordance with this invention; and Fig. 2, illustrates transverse sectional views between each weft path in one repeat of a fabric in accordance with another embodiment of this invention.
DESCRIPTION OF THE PREFERRED EMBODIMENTS OF THE INVENTION
The weft paths of the paper side, wear side and interchanging yam pairs for one preferred embodiment of a composite forming fabric 10 in accordance with this invention are shown in Fig. 1. In accordance with this embodiment, the composite forming fabric has a 20 shaft - 40 pick repeat and includes a paper side layer 12 having a paper side surface 14, a machine side layer 16 having a bottom wear side surface 18 and a plurality of first and second interchanging yams pairs, e.g., 20.
The paper side layer 12 and the machine side layer 16 each comprise a plurality of warp yarns 22 in the machine direction and plurality of non-interchanging weft yams 24 woven together with the warp yarns. The paper side layer 12 and the machine side layer 16 each have a predetermined repeat of the weave pattern in the cross-machine direction. As illustrated, but not by a way of limitation, the illustrated composite fabric 10 is a twenty (20) shed - forty (40) pick fabric including ten (10) machine direction warp yarns 22 in the paper side layer, shown at 1, 3, 5, 7, 9, 11, 13, 15, 17 and 19, and ten (10) machine direction warp yarns 22 in the machine side layer, show at 2, 4, 6, 8, 10, 12, 14, 16, 18 and 20. The non-interchanging weft yams in the paper side layer 12 are designated in Fig. 1 by the prefix "T" and the non-interchanging weft yarns in the machine side layer 16 are designated in Fig. 1 by the prefix "B."
As illustrated in Fig. 1, the first and second interchanging yarns of each pair of interchanging yarns are designated with the prefix "I"; a first pair being designated 11, 12; another pair being designated 13, 14, and so on. Each pair of interchanging yarns has two segments in the paper side layer within each repeat of the weave pattern. These segments provide an unbroken weft path in the paper side surface, with each succeeding segment being separated in the paper side surface of the paper side layer by at least one paper side layer transitional warp yarn 22T (e.g., lop warp yams 5 and 13 are transitional warp yarns for interchanging binder yarns 19, 110). The pairs of interchanging yarns 20 move out of and into the paper side layer, respectively, on opposite sides of each transitional warp yarn. As is shown in Fig. 1, the interchanging yarns cross each other as they move in opposite directions in a region generally underlying the transitional warp yams.
Still referring to Fig. 1, the fabric 10 of this invention includes a first set of alternating pairs of first and second interchanging yarns within each repeat of the weave pattern constituting binder yarn pairs 26 for binding together the paper side layer and machine side layer, i.e., 11-12; 15-16; 19-110; 113-114 and 117-118. The fabric 10 also includes a second, alternating set of pairs of first and second interchanging yarns within each repeat of the weave pattern constituting top weft/binder yarn pairs 28 for stiffening the fabric and binding together the paper side layer and the machine side layer of the fabric. This second set of top weft/binder yarn pairs is shown at 13-14; 17-18; 111-112; 115- 116 and 119-120.
In the embodiment illustrated in Fig. 1, the top weft yarn in each of the top/weft binder yarn pairs floats between the paper side layer 12 and the machine side layer 16 to provide a stiffening function. In the embodiment illustrated in Fig. 1 , the top weft yarn of each of the top weft/binder yarn pairs actually floats between five (5) sets of upper and lower warp yarns in the paper side layer and machine side layer, respectively, e.g., the top weft yarn in the top weft/binder yarn pair I3-I4 floats between adjacent upper and lower warp yarns 13-14; 15-16; 17-18; 19-20 and 1-2. Moreover, the binder yam in each of the top weft/binder yarn pairs forms two knuckles in the paper side layer segment within each weave repeat, e.g., the binder yam in the top weft/binder yarn pair I3-I4 forms knuckles over top warp yarns 15 and 19; the binder yarn in the top weft/binder yarn pair I7-I8 forms knuckles overtop warp yarns 3 and 7; etc. As will be illustrated and explained below, both the float distance of the top weft yam and the number of formed knuckles of the binder yarn in the paper side layer in top weft binder yarn pairs can be varied within each repeat of the weave pattern. Although in a preferred embodiment of the invention the binder yarn pairs and the weft binder yarn pairs each constitute 50% of the interchanging yam pairs in the fabric, in accordance with the broadest aspects of the invention, the percentage of interchanging yarn pairs provided by binder yam pairs and top weft binder yam pairs cam be varied.
Moreover, it should be apparent that alternate unbroken weft paths are provided by the pairs of first and second interchanging yarns, which alternate with non- interchanging, top weft yarns that weave only with the warp yarns of the paper side layer. In other words, in the embodiment illustrated in Fig. 1, 50% of the weft yarn paths in the cross-machine direction of the paper side layer are provided by interchanging pairs of ya s, and the other 50% are provided by non-interchanging weft yarns that interweave solely with the warp yarns of the paper side layer.
Although, in the preferred embodiment at least some of the weft yarns in the paper side layer and in the machine side layer are non-interchanging yarns, i.e., they are disposed only in the paper side layer and the machine layer, respectively, in accordance with the broadest aspect of this invention the number of such non-interchanging weft yarns can be varied within wide limits. Additionally, the percentage of binder yarn pairs and top weft binder yarn pairs also can be varied within wide limits and, if desired, may form all of the weft paths in the paper side layer.
In accordance with the preferred embodiment of the invention illustrated in Fig. 1, adjacent weft paths in the paper side layer are provided successively by a non- interchanging top weft yam, a pair of interchanging binder yam pairs, a non- interchanging top weft yarn and a pair of top weft/binder yam pairs. These four weft paths repeat continuously throughout the fabric structure. In this latter arrangement, one-half of the weft yarn paths in the paper side layer fabric are provided by non- interchanging weft yams; one-quarter of the weft yarn paths in the paper side layer are provided by binder yarns pairs and the other one-quarter of the weft yarn paths in the paper side layer are provided by weft/binder yam pairs.
It should be understood that the arrangement and percentage of each of the different weft yarns in the paper side layer can be varied within wide limits. In accordance with the broadest aspects of this invention, within each repeat of the weave pattern there is included at least one pair of first and second interchanging yarns in the form of a binder yarn pair and at least one pair of first and second interchanging yarns in the form of a top weft/binder yarn pair.
In accordance with the preferred embodiment of the invention illustrated in Fig. 1 , 50% of the interchanging yarn pairs are binder yarn pairs and 50% of the interchanging yarn pairs are top weft/binder yarn pairs. However, it is within the scope of the invention to include a greater percentage of interchanging binder yam pairs; thereby resulting in a reduction of the percentage of pairs of top weft/binder yarn pairs and/or non- interchanging top weft yarns. Alternatively, it is within the scope of this invention to include more than 50% interchanging yarn pairs as top weft/binder yarn pairs; resulting in a reduction in the percentage of interchanging binder yarn pairs and/or non- interchanging top weft yams.
Referring to Fig. 2, an alternate embodiment of a fabric of this invention is indicated at 100. The fabric 100 has a number of features that are similar to the fabric 10. For example, the fabric 100, like the fabric 10 includes alternating, non- interchanging top weft yarns and interchanging yarn pairs. Also, every other interchanging yam pair is a binder/binder pair and the other alternate interchanging yarn pairs are top weft/binder yarn pairs.
However, the fabric 100 has a 20 shaft - 80 pick repeat, unlike the 20 shaft - 20 pick repeat of the Fig. 1 embodiment. The increase in the pick repeat results from two variations in the weave pattern of the top weft binder yarn pairs in the Fig. 2 embodiment. First, in the fabric 100, the top weft yam in adjacent lop weft binder yam pairs float, respectively, between five (5) sets of upper and lower warp yarns and seven (7) sets of upper and lower warp yarns, e.g., the top weft yarn of the top weft yarn/binder yarn pair 13-14 floats between the five (5) sets of upper and lower warp yarns 13-14, 15- 16, 1 -18, 19-20 and 1 -2, and the top weft yarn of the adjacent top weft yarn/binder yarn pair I7-I8 floats between the seven (7) sets of upper and lower warp yarns 9-10, 11-12, 13-14, 15-16, 17-18, 19-20 and 1-2.
The second variation is that the binder yarn of adjacent top weft/ binder yarn pairs alternately forms two (2) paper side knuckles and three (3) paper side knuckles within each repeat of the weave pattern, e.g., the binder yarn in the top weft/binder yarn pair 13-
14 forms two (2) knuckles over top warp yarns 15 and 19, and the binder yam in the adjacent top weft/ binder yam pair I7-I8 forms three (3) knuckles over top warp yams 11 ,
15 and 19, etc.
The above discussed two variations in the weave pattern of the top weft/binder yarn pairs accompanied by the fact that alternate top weft yarns are non-interchanging yarns and the alternate interchanging yarn pairs are bind/binder yarn pairs results in a repeat of the weave pattern every eighty (80) picks.
It is within the scope of the embodiment of the invention illustrated in Fig. 2 to make the same modifications as disclosed for the fabric 10. That is, the percentage of non-interchanging binder yarn pairs, the percentage of interchanging top weft/binder yam pairs and the percentage of interchanging binder yam pairs can be varied within wide limits. If desired the interchanging top weft binder yarn pairs and interchanging binder yarn pairs can form all of the weft paths in the structure.
Applicant has determined that significant advantages may be obtained in the fabrics 10 and 100 of this invention, as compared to prior art structures in which all of the interchanging yarn pairs are binder/binder pairs. In particular prior art structures and the fabrics 10, 100 were formed with the warp and weft yarns being of the same diameter and with the same number of warp and weft paths per unit area. The prior art structures included alternating weft paths formed by non-interchanging top weft yarns having a diameter of 0.13 mm and by interchanging binder/binder yarns with each yam of the pair having a diameter of 0.13 mm. The fabrics 10 and 100 included alternating weft paths formed by non-interchanging top weft yams having a diameter of 0.13 mm and by interchanging yarn pairs with each yarn of the pair having a diameter of 0.13 mm, wherein every other interchanging yarn pair was a bind/binder yarn pair and a top weft/binder yarn pair, respectively.
It was determined that the fabric 10 was approximately 17% stiffer and the fabric
100 was approximately 19% stiffer than the prior art structure.
It was determined that the fabrics 10 and 100 had a higher air permeability (cubic feet per minute), a greater thickness, or caliper (millimeters) and a higher void volume (cubic centimeters/square meter) than the prior art structure.
Although a higher air permeability and greater void volume may not be desirable, because of the possibility of greater water retention in the fabric, it should be understood that these higher permeability and void volume values were obtained in fabrics of this invention having the same concentration of warp and weft yams as the prior art structure and with the warp and weft yams having the same diameter as the prior art structure, and also without a significant reduction in fabric strength as compared to the prior art structure. Therefore, improved resistance to undesired water marks can be obtained in the fabrics of this invention by increasing the concentration of top weft and/or top warp yarns, and improvements in mechanical properties can be achieved by increasing the diameter of the bottom warp and/or weft yarns, while also achieving a reduction in air permeability and void volume to more desirable levels. Alternatively, it is possible to reduce yarn diameter in fabrics of the invention and still get identical CD stiffness to fabrics of the prior art but with reduced thickness. In accordance with an additional embodiment of this invention (not illustrated), a composite forming fabric has the same construction as the forming fabric 10 or 100, with the exception that one or more weft yarns, e.g., either non-interchanging weft yarns, interchanging binder/binder weft yarn pairs and/or interchanging lop weft binder yam pairs, is (are) replaced with a fourth type of weft yarn system; namely, an intrinsic interchanging weft yarn/weft yarn pair. As explained earlier in the summary of the invention, an intrinsic interchanging weft yarn/weft yarn pair cooperates to provide a continuous weft path in the top fabric layer within each repeat of the weave pattern, just like the interchanging bind/binder yarn pairs and the interchanging top weft/binder yarn pairs. However, the yarns of the interchanging weft yarn/weft yarn pairs, when they drop out of the top surface adjacent a top warp transitional yarn, float between the top warp yarns and bottom warp yarns without binding to a bottom warp yarn.
In one embodiment employing weft yam/weft yarn pairs, alternating weft paths in the paper side layer are provided by non-interchanging weft yams, and located between each pair of these non-interchanging weft yarn paths is a binder yarn pair, a top weft/binder yam pair and a weft yarn/weft yarn pair, respectively, in any desired order. As noted, in this embodiment one half of the weft paths are provided by non- interchanging top weft yarns; one-third of the weft paths provided by interchanging yarn pairs are provided by top weft/binder yarn pairs, one-third of the weft paths provided by interchanging yam pairs are provided by weft yarn/binder yarn pairs and one-third of the weft paths provided by interchanging yarn pairs are provided by weft yam/weft yarn pairs. However, in accordance with the broadest aspect of this invention, the percentages of each of the different types of interchanging yarn pairs can be varied within wide limits. In fact, in accordance with certain aspects of this invention, the composite forming fabric can include a single pair of first and second interchanging yarns in the form of weft yarn/weft yarn pairs, with the remaining interchanging yam pairs being binder yarn pairs and/or weft binder yarn pairs. Moreover, interchanging yarn pairs of the same or different type can be included adjacent to each other, in which case at least some of the adjacent non-interchanging top weft yarns will be spaced apart from each other by more than one interchanging yarn pair. Embodiments of the invention including non-interchanging lop weft yarns in the paper side layer; binder yarn pairs having segments in the paper side layer providing an unbroken weft path within each repeat of the weave pattern; top weft/top weft yarn pairs providing an unbroken weft path within each repeat of the weave pattern and weft yarn/binder yarn pairs providing an unbroken weft path with each repeat of the weave pattern have been described earlier herein. Suffice it to state that the form of the fabrics of this invention can include a combination of each of the four types of cross-machine direction weft yarns in the paper side layer. By varying the structure of the top weft path in the paper side layer to include different types of interchanging yarns and non- interchanging yarns, the overall properties of the forming fabric can be varied within wide limits, as dictated by the particular application of the fabric.
As should be noted in the fabrics 10 and 100, segments of one or more pairs of interchanging yams can be of a different length within each repeat of the weave pattern. In accordance with the broadest aspects of this invention, the paper side segments provided by either all or some of the interchanging yarn pairs; whether such interchanging yam pairs are binder yam pairs, weft yam/binder yarn pairs and/or weft yarn/weft yarn pairs, can be of different lengths.
In fabrics of the invention in which the yarns of each interchanging yarn pair provide segments of different length within each repeat of the weave pattern it is possible to vary the sequence in which the pair of yams are placed in the fabric. For example, in a first pair of interchanging yam pairs, the yarn providing the longest segment may be positioned prior to the other yarn of the pair, which provides the shortest segment. This arrangement may be reversed for the yams of other interchanging yarn pairs throughout the fabric weave repeat. Furthermore, each interchanging yarn pair need not provide segments of the same length as other interchanging yarn pairs. In this case, it may be that the number of segments in some pairs of interchanging yarn pairs differs from the number of segments in other pairs of interchanging yarn pairs. This latter feature will be the subject of a separate patent application.
Various modifications can be made to the fabrics of this invention. For example, and not by way of limitation, the shape of the warp and weft yams in both the paper side layer and the machine side layer can be varied within the broadest aspects of the invention. As described earlier in the summary of the invention, it may be desirable to employ top warp yarns having a dumbbell-shaped ("figure 8") cross-section, so that the two bulbous ends of each warp yam provide two support point for a fibrous web formed on the fabric. By increasing the number of support points for the web on the paper side layer of the fabric, a more planar forming surface is provided, which should achieve a more uniform formation of the fibrous web.
Other modifications include having one or more of the binder yarns of interchanging binder yarn pairs and/or interchanging top weft binder yarn pairs bind to more than one bottom warp yarn. Such multiple bottom warp yams can be adjacent to each other or spaced-apart from each other. In either case the binding preferably takes place with bottom warp yams underlying top segments in which the other yarn of the pair is forming a portion of the top weft path.
Yet other modifications include the utilization of a weave other than a plain weave in the fabric papermaking layer. For example in a 24 shaft fabric of the invention a suitable paperside weave could be a 3 shaft twill.
Although the embodiments of the invention described in detail herein utilize CD orientated interchanging yarn pairs it is understood that within the broadest aspects of the invention MD orientated interchanging yarn pairs can be employed to bind and stiffen the fabric.
Without further elaboration, the foregoing will so fully illustrate our invention that others may, be applying current or future knowledge, readily adapt the same for use under various conditions of service.

Claims

CLAIMSWhat I claim as the invention is:
1. A composite forming fabric comprising a paper side layer having a paper side surface, a machine side layer having a bottom wear side surface, and a plurality of pairs of first and second interchanging yarns, wherein: the paper side layer and the machine side layer each comprise warp yarns and weft yarns woven together; said paper side layer and said machine side layer each having a predetermined repeat of the weave pattern in the cross-machine-direction; each pair of first and second interchanging yarns having at least two segments in the paper side layer within each repeat of the weave pattern, said segments providing an unbroken weft path in the paper side surface, with each succeeding segment being separated in the paper side surface of the paper side layer by at least one paper side layer transitional warp yarn; at least one pair of first and second interchanging yams within each repeat of the weave pattern being binder yam pairs, each binder yarn in each binder yam pair binding together the paper side layer and the machine side layer, and at least one pair of first and second interchanging yams within each repeat of the weave pattern being top weft/binder yam pairs for stiffening the fabric and binding together the paper side layer and the machine side layer of the fabric.
2. The composite forming fabric of claim 1 , wherein at least 50% of the interchanging yarn pairs are binder yam pairs.
3. The composite forming fabric of claim 1 , wherein at least 50% of the interchanging yam pairs are top weft binder yarns pairs.
4. The composite forming fabric of claim 1 , wherein at least one pair of first and second interchanging yarns is a weft yarn/weft yarn pair.
5. The composite forming fabric of claim 1 , wherein a plurality of pairs of first and second interchanging yarns is weft yarn/weft yarn pairs.
6. The composite forming fabric of claim 2, wherein at least one pair of first and second interchanging yarns is a weft yarn/weft yarn pair.
7. The composite forming fabric of claim 2, wherein a plurality of pairs of first and second interchanging yarns is weft yarn/weft yarn pairs.
8. The composite forming fabric of claim 3, wherein at least one pair of first and second interchanging yams is a weft yam/weft yarn pair.
9. The composite forming fabric of claim 3, wherein a plurality of pairs of first and second interchanging yarns is weft yarn/weft yarn pairs.
10. The composite forming fabric of claim 1 , wherein at least one of said at least two segments of at least one pair of first and second interchanging yams has a different length than at least one other segment of said at least two segments of said at least one pair of first and second interchanging yarns.
11. The composite forming fabric of claim 1 , wherein at least one of said at least two segments of each pair of first and second interchanging yarns has a different length that at least one other segment of said at least two segments of each pair of first and second interchanging yarns.
12. The composite forming fabric of claim 1 , wherein at least some of the binder yarns in the pairs of first and second interchanging yarns float under at least two wear side machine direction yarns in a region underlying at least one of said at least two segments.
13. The composite forming fabric of claim 12, wherein said at least two wear side machine direction yams are adjacent to each other.
14. The composite forming fabric of claim 12, wherein said at least two wear side machine direction yarns are spaced apart by at least one wear side machine direction yam.
PCT/EP2004/050218 2003-03-03 2004-02-27 A composite forming fabric WO2004079089A1 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
US10/547,034 US20060231154A1 (en) 2003-03-03 2004-02-27 Composite forming fabric
EP04715332A EP1604063A1 (en) 2003-03-03 2004-02-27 A composite forming fabric

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US45178003P 2003-03-03 2003-03-03
US60/451,780 2003-03-03

Publications (1)

Publication Number Publication Date
WO2004079089A1 true WO2004079089A1 (en) 2004-09-16

Family

ID=32962637

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2004/050218 WO2004079089A1 (en) 2003-03-03 2004-02-27 A composite forming fabric

Country Status (2)

Country Link
EP (1) EP1604063A1 (en)
WO (1) WO2004079089A1 (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005017254A1 (en) * 2003-08-13 2005-02-24 Voith Fabrics Patent Gmbh Fabrics employing binder/top interchanging yarn pairs
EP1645683A1 (en) * 2004-10-05 2006-04-12 Voith Fabrics Patent GmbH Yarn having a bi-nodal cross-section and papermaking fabric comprising such a yarn
CN105143549A (en) * 2013-06-18 2015-12-09 安德里茨技术资产管理有限责任公司 Paper machine wire

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5152326A (en) * 1989-11-16 1992-10-06 F. Oberdorfer Gmbh & Co. Kg, Industriegewebe-Technik Binding thread arrangement in papermaking wire

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5152326A (en) * 1989-11-16 1992-10-06 F. Oberdorfer Gmbh & Co. Kg, Industriegewebe-Technik Binding thread arrangement in papermaking wire

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005017254A1 (en) * 2003-08-13 2005-02-24 Voith Fabrics Patent Gmbh Fabrics employing binder/top interchanging yarn pairs
EP1645683A1 (en) * 2004-10-05 2006-04-12 Voith Fabrics Patent GmbH Yarn having a bi-nodal cross-section and papermaking fabric comprising such a yarn
CN105143549A (en) * 2013-06-18 2015-12-09 安德里茨技术资产管理有限责任公司 Paper machine wire
US9528223B2 (en) 2013-06-18 2016-12-27 Andritz Technology & Asset Management Gmbh Paper machine wire
US10060076B2 (en) 2013-06-18 2018-08-28 Andritz Technology & Asset Management Gmbh Paper machine screen

Also Published As

Publication number Publication date
EP1604063A1 (en) 2005-12-14

Similar Documents

Publication Publication Date Title
US6123116A (en) Low caliper mechanically stable multi-layer papermaker's fabrics with paired machine side cross machine direction yarns
US6179013B1 (en) Low caliper multi-layer forming fabrics with machine side cross machine direction yarns having a flattened cross section
US6854488B2 (en) Fabrics with paired, interchanging yarns having discontinuous weave pattern
CA2288029C (en) Multi-layer forming fabric with stitching yarn pairs integrated into papermaking surface
US7007722B2 (en) Forming fabric
US7415993B2 (en) Fabrics with multi-segment, paired, interchanging yarns
US6920902B2 (en) Multi-layer fabric
US8196613B2 (en) Multi-layer papermaker's forming fabric with paired MD binding yarns
KR101262015B1 (en) Stable forming fabric with high fiber support
WO2008077695A1 (en) Forming fabric having offset binding warps
US7507679B2 (en) Paper machine fabric
US20170037572A1 (en) Paper machine screen
US7506670B2 (en) Paper machine fabric
US20120178330A1 (en) Papermakers' forming fabric including pairs of machine side complementary yarns
CN102852023B (en) Warp-runner triple layer fabric with paired intrinsic warp binders
US20060231154A1 (en) Composite forming fabric
WO2004079089A1 (en) A composite forming fabric
AU2003300929B2 (en) Multi-layer fabric for paper making machine

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A1

Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BW BY BZ CA CH CN CO CR CU CZ DE DK DM DZ EC EE EG ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NA NI NO NZ OM PG PH PL PT RO RU SC SD SE SG SK SL SY TJ TM TN TR TT TZ UA UG US UZ VC VN YU ZA ZM ZW

AL Designated countries for regional patents

Kind code of ref document: A1

Designated state(s): BW GH GM KE LS MW MZ SD SL SZ TZ UG ZM ZW AM AZ BY KG KZ MD RU TJ TM AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LU MC NL PT RO SE SI SK TR BF BJ CF CG CI CM GA GN GQ GW ML MR NE SN TD TG

121 Ep: the epo has been informed by wipo that ep was designated in this application
WWE Wipo information: entry into national phase

Ref document number: 2004715332

Country of ref document: EP

WWP Wipo information: published in national office

Ref document number: 2004715332

Country of ref document: EP

WWE Wipo information: entry into national phase

Ref document number: 2006231154

Country of ref document: US

Ref document number: 10547034

Country of ref document: US

WWP Wipo information: published in national office

Ref document number: 10547034

Country of ref document: US