WO2000077831A3 - Methods for regulating surface sensitivity of insulating films in semiconductor devices - Google Patents

Methods for regulating surface sensitivity of insulating films in semiconductor devices Download PDF

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Publication number
WO2000077831A3
WO2000077831A3 PCT/US2000/015851 US0015851W WO0077831A3 WO 2000077831 A3 WO2000077831 A3 WO 2000077831A3 US 0015851 W US0015851 W US 0015851W WO 0077831 A3 WO0077831 A3 WO 0077831A3
Authority
WO
WIPO (PCT)
Prior art keywords
deposition
ozone
films
sio2
methods
Prior art date
Application number
PCT/US2000/015851
Other languages
French (fr)
Other versions
WO2000077831A2 (en
Inventor
Sasangan Ramanathan
Joseph Ellul
Asharf R Khan
Hariram Krishnamoorthy
Dilip Vijay
Giovanni Antonio Foggiato
Original Assignee
Quester Technology Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Quester Technology Inc filed Critical Quester Technology Inc
Priority to AU54767/00A priority Critical patent/AU5476700A/en
Publication of WO2000077831A2 publication Critical patent/WO2000077831A2/en
Publication of WO2000077831A3 publication Critical patent/WO2000077831A3/en

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/02104Forming layers
    • H01L21/02107Forming insulating materials on a substrate
    • H01L21/02225Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer
    • H01L21/0226Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a deposition process
    • H01L21/02263Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a deposition process deposition from the gas or vapour phase
    • H01L21/02271Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a deposition process deposition from the gas or vapour phase deposition by decomposition or reaction of gaseous or vapour phase compounds, i.e. chemical vapour deposition
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/02104Forming layers
    • H01L21/02107Forming insulating materials on a substrate
    • H01L21/02296Forming insulating materials on a substrate characterised by the treatment performed before or after the formation of the layer
    • H01L21/02299Forming insulating materials on a substrate characterised by the treatment performed before or after the formation of the layer pre-treatment
    • H01L21/02304Forming insulating materials on a substrate characterised by the treatment performed before or after the formation of the layer pre-treatment formation of intermediate layers, e.g. buffer layers, layers to improve adhesion, lattice match or diffusion barriers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/70Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
    • H01L21/71Manufacture of specific parts of devices defined in group H01L21/70
    • H01L21/76Making of isolation regions between components
    • H01L21/762Dielectric regions, e.g. EPIC dielectric isolation, LOCOS; Trench refilling techniques, SOI technology, use of channel stoppers
    • H01L21/76224Dielectric regions, e.g. EPIC dielectric isolation, LOCOS; Trench refilling techniques, SOI technology, use of channel stoppers using trench refilling with dielectric materials
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/02104Forming layers
    • H01L21/02107Forming insulating materials on a substrate
    • H01L21/02109Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates
    • H01L21/02112Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer
    • H01L21/02123Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer the material containing silicon
    • H01L21/02164Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer the material containing silicon the material being a silicon oxide, e.g. SiO2

Landscapes

  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Manufacturing & Machinery (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Formation Of Insulating Films (AREA)

Abstract

Methods are provided for regulating surface sensitivity of the deposition of silicon dioxide films that can permit the deposition of high quality silicon dioxide films for use in shallow trench isolation. By the use of super low ozone concentrations to deposit a seed layer (112a) having low ozone content, the subsequent deposition of high-quality, high ozone films (116) can be facilitated, without the appearance of defects that can appear during conventional high ozone film deposition. Controlling the ozone concentration during seed layer deposition, the thickness of the seed layer, the rates of deposition of the high ozone film, deposition temperature and ozone concentration of the high ozone film, the resulting SiO2 film can exhibit desired properties. Semiconductor thin films according to the methods of this invention can be made thinner than conventional TEOS/ozone films, permitting the manufacture of integrated circuit devices having smaller dimensions. Additionally, methods are presented for increasing the surface sensitivity of deposition of SiO2 films on semiconductor wafers having different materials thereon. By increasing surface sensitivity, differential growth rate of SiO2 on nitride, thermal oxide and silicon can be adjusted to provide increased planarity of the deposited SiO2 layer and can result in reduced dimensions of SiO2 layers to achieve planar surfaces and thereby can decrease manufacturing cost and device size.
PCT/US2000/015851 1999-06-11 2000-06-09 Methods for regulating surface sensitivity of insulating films in semiconductor devices WO2000077831A2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU54767/00A AU5476700A (en) 1999-06-11 2000-06-09 Methods for regulating surface sensitivity of insulating films in semiconductor devices

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US13889899P 1999-06-11 1999-06-11
US60/138,898 1999-06-11

Publications (2)

Publication Number Publication Date
WO2000077831A2 WO2000077831A2 (en) 2000-12-21
WO2000077831A3 true WO2000077831A3 (en) 2001-07-05

Family

ID=22484160

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2000/015851 WO2000077831A2 (en) 1999-06-11 2000-06-09 Methods for regulating surface sensitivity of insulating films in semiconductor devices

Country Status (3)

Country Link
AU (1) AU5476700A (en)
TW (1) TW563223B (en)
WO (1) WO2000077831A2 (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7141483B2 (en) 2002-09-19 2006-11-28 Applied Materials, Inc. Nitrous oxide anneal of TEOS/ozone CVD for improved gapfill
US7431967B2 (en) * 2002-09-19 2008-10-07 Applied Materials, Inc. Limited thermal budget formation of PMD layers
US9142400B1 (en) 2012-07-17 2015-09-22 Stc.Unm Method of making a heteroepitaxial layer on a seed area

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5051380A (en) * 1989-12-27 1991-09-24 Semiconductor Process Laboratory Co., Ltd. Process for producing semiconductor device
US5290358A (en) * 1992-09-30 1994-03-01 International Business Machines Corporation Apparatus for directional low pressure chemical vapor deposition (DLPCVD)
US5356722A (en) * 1992-06-10 1994-10-18 Applied Materials, Inc. Method for depositing ozone/TEOS silicon oxide films of reduced surface sensitivity
US5420065A (en) * 1993-05-28 1995-05-30 Digital Equipment Corporation Process for filling an isolation trench
US5458919A (en) * 1987-03-18 1995-10-17 Kabushiki Kaisha Toshiba Method for forming a film on a substrate by activating a reactive gas
US5462899A (en) * 1992-11-30 1995-10-31 Nec Corporation Chemical vapor deposition method for forming SiO2
US5489553A (en) * 1995-05-25 1996-02-06 Industrial Technology Research Institute HF vapor surface treatment for the 03 teos gap filling deposition
US5891810A (en) * 1996-05-16 1999-04-06 Lg Semicon Co., Ltd. Process for supplying ozone (O3) to TEOS-O3 oxidizing film depositing system

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5458919A (en) * 1987-03-18 1995-10-17 Kabushiki Kaisha Toshiba Method for forming a film on a substrate by activating a reactive gas
US5051380A (en) * 1989-12-27 1991-09-24 Semiconductor Process Laboratory Co., Ltd. Process for producing semiconductor device
US5356722A (en) * 1992-06-10 1994-10-18 Applied Materials, Inc. Method for depositing ozone/TEOS silicon oxide films of reduced surface sensitivity
US5290358A (en) * 1992-09-30 1994-03-01 International Business Machines Corporation Apparatus for directional low pressure chemical vapor deposition (DLPCVD)
US5462899A (en) * 1992-11-30 1995-10-31 Nec Corporation Chemical vapor deposition method for forming SiO2
US5420065A (en) * 1993-05-28 1995-05-30 Digital Equipment Corporation Process for filling an isolation trench
US5489553A (en) * 1995-05-25 1996-02-06 Industrial Technology Research Institute HF vapor surface treatment for the 03 teos gap filling deposition
US5891810A (en) * 1996-05-16 1999-04-06 Lg Semicon Co., Ltd. Process for supplying ozone (O3) to TEOS-O3 oxidizing film depositing system

Also Published As

Publication number Publication date
WO2000077831A2 (en) 2000-12-21
AU5476700A (en) 2001-01-02
TW563223B (en) 2003-11-21

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