WO1991001980A3 - Process for preparing plastics from raw fats and oils - Google Patents

Process for preparing plastics from raw fats and oils

Info

Publication number
WO1991001980A3
WO1991001980A3 PCT/EP1990/001259 EP9001259W WO9101980A3 WO 1991001980 A3 WO1991001980 A3 WO 1991001980A3 EP 9001259 W EP9001259 W EP 9001259W WO 9101980 A3 WO9101980 A3 WO 9101980A3
Authority
WO
WIPO (PCT)
Prior art keywords
oils
plastics
epoxy
raw
fats
Prior art date
Application number
PCT/EP1990/001259
Other languages
German (de)
French (fr)
Other versions
WO1991001980A2 (en
Inventor
Rainer Frische
Juergen Volkheimer
Original Assignee
Battelle Institut E V
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Battelle Institut E V filed Critical Battelle Institut E V
Publication of WO1991001980A2 publication Critical patent/WO1991001980A2/en
Publication of WO1991001980A3 publication Critical patent/WO1991001980A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/02—Polycondensates containing more than one epoxy group per molecule
    • C08G59/027—Polycondensates containing more than one epoxy group per molecule obtained by epoxidation of unsaturated precursor, e.g. polymer or monomer
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/38—Compounds containing oxirane rings with hydrocarbon radicals, substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
    • C07D303/40—Compounds containing oxirane rings with hydrocarbon radicals, substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals by ester radicals
    • C07D303/42—Acyclic compounds having a chain of seven or more carbon atoms, e.g. epoxidised fats
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/36—Hydroxylated esters of higher fatty acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/50—Amines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/62—Alcohols or phenols

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Fats And Perfumes (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Epoxy Compounds (AREA)

Abstract

In a process for preparing plastics comonomers and plastics from raw fats and oils containing unsaturated fatty acids, raw unsaturated fats and oils are oxidized with performic acid or peracetic acid to epoxy or hydroxy compounds. To prepare plastics, the epoxy or hydroxy compounds are then converted to polymers with duo- or multifunctional compounds capable of reacting with epoxy or hydroxy groups.
PCT/EP1990/001259 1989-08-09 1990-08-01 Process for preparing plastics from raw fats and oils WO1991001980A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE3926285 1989-08-09
DEP3926285.5 1989-08-09

Publications (2)

Publication Number Publication Date
WO1991001980A2 WO1991001980A2 (en) 1991-02-21
WO1991001980A3 true WO1991001980A3 (en) 1991-03-21

Family

ID=6386786

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP1990/001259 WO1991001980A2 (en) 1989-08-09 1990-08-01 Process for preparing plastics from raw fats and oils

Country Status (5)

Country Link
EP (1) EP0437592A1 (en)
JP (1) JPH04501284A (en)
CA (1) CA2038936A1 (en)
DE (1) DE4024364A1 (en)
WO (1) WO1991001980A2 (en)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4119295C2 (en) * 1991-06-12 1994-12-01 Frische Gmbh Environmentally safe composite material made of natural fibers or products and plastics of the polyurethane-polyester and / or polyurethane-polyamide type and process for its production
JPH09504045A (en) * 1993-10-20 1997-04-22 ヘンケル・コマンディットゲゼルシャフト・アウフ・アクチェン Binder based on oleochemical reaction product
CN1103791C (en) * 1995-07-05 2003-03-26 空间分割系统预成形股份有限公司 Polymer material, process for its production and use thereof
DE19646424A1 (en) 1996-11-11 1998-05-14 Henkel Kgaa Use of polyols for isocyanate casting resins and coating compositions
DE19834048A1 (en) * 1998-07-30 2000-02-03 Cognis Deutschland Gmbh Composites based on renewable raw materials
EP0992569A1 (en) * 1998-10-05 2000-04-12 Nederlandse Organisatie Voor Toegepast-Natuurwetenschappelijk Onderzoek Tno Preservation/lubricant/primercomposition for metallic surfaces
DE10015913A1 (en) * 1999-04-16 2000-10-19 Henkel Kgaa Adducts used as binders for adhesives or as tackifiers are obtained from unsaturated natural fats or oils by ene or Diels-Alder reactions followed by radical or oxidative treatment
DE19930770A1 (en) 1999-07-03 2001-01-04 Cognis Deutschland Gmbh Process for the production of fiber composite materials
DE102006003762A1 (en) * 2006-01-25 2007-07-26 Dracowo Forschungs- Und Entwicklungs Gmbh Fiber composite materials are made using natural epoxide resins matrices obtained by acid reaction of ethoxylated linseed oil epoxides or other highly ethoxylated fatty acid epoxides without use of comonomers
DE102008014558A1 (en) 2008-03-15 2009-09-17 Dracowo Forschungs- Und Entwicklungs Gmbh Polycarboxylic acid modified native epoxides with a specific ratio of epoxide-polycarboxylic acid in glycidyl ester epoxide, useful for preparing polyether and polyester
DE102010040601A1 (en) 2009-09-11 2011-03-17 Dracowo Forschungs- Und Entwicklungs Gmbh Technical production of carboxylic acid-modified epoxide from native oils, useful e.g as food preservative, comprises epoxidating the native oil, separating the epoxide phase, reacting the separated epoxide phase with polycarboxylic acid

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2569502A (en) * 1945-02-07 1951-10-02 Swern Daniel Epoxidized oils
FR1129495A (en) * 1954-03-23 1957-01-22 Fmc Corp Epoxidation process for natural unsaturated oils
FR1295619A (en) * 1961-05-09 1962-06-08 Swift & Co Process for the production of a prepolymer of highly epoxidized fatty oils and polyamines and prepolymer obtained by this process
US3051729A (en) * 1957-09-10 1962-08-28 Archer Daniels Midland Co Method of preparing epoxidized oils and the like
FR1335729A (en) * 1961-08-22 1963-08-23 Mobay Chemical Corp Polyurethane plastics
DE1645570A1 (en) * 1965-02-17 1970-09-24 Unilever Nv Process for the production of a modified drying or semi-drying oil with improved film properties
EP0111626A1 (en) * 1982-12-16 1984-06-27 Henkel Kommanditgesellschaft auf Aktien Process for the preparation of modified triglycerides containing epoxy, hydroxy and ether groups
EP0113801A1 (en) * 1982-12-16 1984-07-25 Henkel Kommanditgesellschaft auf Aktien Compositions of alkyde resins comprising functional epoxydes
EP0121699A1 (en) * 1983-03-03 1984-10-17 RHEIN-CHEMIE RHEINAU GmbH Preparation and application of cured epoxidized fatty oils

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL302304A (en) * 1962-12-20 1900-01-01 British Celanese
US3843391A (en) * 1969-11-10 1974-10-22 Ciba Geigy Ag Process for finishing textiles
DE3320219A1 (en) * 1983-06-03 1984-12-06 Henkel KGaA, 4000 Düsseldorf CONTINUOUS, CATALYTIC EPOXIDATION OF DOUBLE OLEFINIC BINDINGS WITH HYDROGEN PEROXIDE AND FORMIC ACID

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2569502A (en) * 1945-02-07 1951-10-02 Swern Daniel Epoxidized oils
FR1129495A (en) * 1954-03-23 1957-01-22 Fmc Corp Epoxidation process for natural unsaturated oils
US3051729A (en) * 1957-09-10 1962-08-28 Archer Daniels Midland Co Method of preparing epoxidized oils and the like
FR1295619A (en) * 1961-05-09 1962-06-08 Swift & Co Process for the production of a prepolymer of highly epoxidized fatty oils and polyamines and prepolymer obtained by this process
FR1335729A (en) * 1961-08-22 1963-08-23 Mobay Chemical Corp Polyurethane plastics
DE1645570A1 (en) * 1965-02-17 1970-09-24 Unilever Nv Process for the production of a modified drying or semi-drying oil with improved film properties
EP0111626A1 (en) * 1982-12-16 1984-06-27 Henkel Kommanditgesellschaft auf Aktien Process for the preparation of modified triglycerides containing epoxy, hydroxy and ether groups
EP0113801A1 (en) * 1982-12-16 1984-07-25 Henkel Kommanditgesellschaft auf Aktien Compositions of alkyde resins comprising functional epoxydes
EP0121699A1 (en) * 1983-03-03 1984-10-17 RHEIN-CHEMIE RHEINAU GmbH Preparation and application of cured epoxidized fatty oils

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
CHEMICAL ABSTRACTS, Band 74, Nr. 26, 28. Juni 1971, (Columbus Ohio, US), E. PALTIN et al.: "Epoxidation with Performic Acid "in Situ". Epoxidized Plastifiers", siehe seite 31, Zusammenfassung 142777k, & Mater. Plast. (Bucharest) 1971, 7(12), 635-40 *
Journal of the American Oil Chemists' Society, Band 45, Nr. 2, Februar 1968, (Champaign, US), F. SCHOLNICK et al.: "Urethane Foams from Animal Fats. IV. Rigid Foams from Epoxidized Glycerides", seiten 76,77 siehe den ganze artikel *
Journal of the American Oil Chemists' Society, Band 47, Nr. 9, September 1970, (Champaign, US), G.O. HUSTAD et al.: "Urethane Polymers from Hydroxylated Fish Oil", seiten 333-336 siehe den ganze artikel *

Also Published As

Publication number Publication date
CA2038936A1 (en) 1991-02-10
JPH04501284A (en) 1992-03-05
WO1991001980A2 (en) 1991-02-21
DE4024364A1 (en) 1991-02-14
EP0437592A1 (en) 1991-07-24

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