USRE22373E - Manufacture of abrasive articles - Google Patents
Manufacture of abrasive articles Download PDFInfo
- Publication number
- USRE22373E USRE22373E US22373DE USRE22373E US RE22373 E USRE22373 E US RE22373E US 22373D E US22373D E US 22373DE US RE22373 E USRE22373 E US RE22373E
- Authority
- US
- United States
- Prior art keywords
- metal
- abrasive
- particles
- granules
- coated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000004519 manufacturing process Methods 0.000 title description 13
- 239000002184 metal Substances 0.000 description 48
- 229910052751 metal Inorganic materials 0.000 description 48
- 239000002245 particle Substances 0.000 description 22
- 238000000576 coating method Methods 0.000 description 16
- 239000008187 granular material Substances 0.000 description 15
- 238000000034 method Methods 0.000 description 14
- 239000011248 coating agent Substances 0.000 description 10
- 229910003460 diamond Inorganic materials 0.000 description 8
- 239000010432 diamond Substances 0.000 description 8
- 238000005507 spraying Methods 0.000 description 7
- 238000005245 sintering Methods 0.000 description 6
- 238000002844 melting Methods 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- 239000006061 abrasive grain Substances 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 239000000956 alloy Substances 0.000 description 3
- 229910045601 alloy Inorganic materials 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 238000003466 welding Methods 0.000 description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000012255 powdered metal Substances 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 208000036366 Sensation of pressure Diseases 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 239000007931 coated granule Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000009713 electroplating Methods 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24D—TOOLS FOR GRINDING, BUFFING OR SHARPENING
- B24D7/00—Bonded abrasive wheels, or wheels with inserted abrasive blocks, designed for acting otherwise than only by their periphery, e.g. by the front face; Bushings or mountings therefor
- B24D7/02—Wheels in one piece
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24D—TOOLS FOR GRINDING, BUFFING OR SHARPENING
- B24D18/00—Manufacture of grinding tools or other grinding devices, e.g. wheels, not otherwise provided for
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12486—Laterally noncoextensive components [e.g., embedded, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12639—Adjacent, identical composition, components
Definitions
- This invention relates generally to metal bonded abrasive articles.
- It relates particularly to abrasive articles wherein the abrasive particles are uniformly distributed throughout a metallic bondand the method of making same.
- metal bonded abrasive articles such as wheels
- metal bonded abrasive articles have been made by mixing the abrasive granules with molten metal and allowing the mass to harden.
- Thismethod has proven unsatisfactory because the high temperature of the molten metal impairs the abrasive characteristics of the granules, and it is impossible to produce an article wherein the abrasive granules are uniformly distributed throughout the metal bond because the diflference in specific view of an abrasive wheel formed by compacting with heat and pressure, the sheets shown in Figure l.
- the abrasive grains are first given a uniform coating of metal. This may be done by any suitable means, such as electroplating, spraying,etc.
- the invention herein claimed and described overcomes the difllculties mentioned.
- it is possible to easily and economically produce metal bonded articles which have the abrasive uniformly distributed throughout the mass, the bonds of which have the desired brittle characteristics and the abrasive granules of which are unaffected by the heat applied during manufacture.
- Figure 1 is a diagrammatic view of a group of abrasive containing metal sheets to be compacted into an abrasive wheel, the sheets being shown in' sec-- tion
- Figure 2 is a diagrammatic sectional I welding.
- the metal coated grains are then compacted in a. mold under pressure and are sintered at a temperature just below the melting point of the particular bond chosen.
- a temporary binder of glue or its equivalent may be added to the mix before pressing. This is desirable if the compacted mass is to be removed fromthe mold before sintering.
- the temporary binder should be sumciently volatile so that it will be driven 01f during the heat treating operation.
- powdered metal may be added to the mass before it is compacted. If this is done, a somewhat stronger and much more dense wheel is the result.
- the powdered metal is mixed uniformly with, the coated granules and may be the same type of metal with which the granules are coated, or it may be a metal which will alloy with the coating on the granules.
- the pressure applied to the aggregate will depend upon the desired porosity of the wheel.
- the time of sintering also will vary with the diameter and thickness of the wheel and with the kind of metal used.
- the pressure is chosen that will give the desired porosity and the sintering is carried on until the metal coated particles are firmly united into a homogeneous aggregate.
- the wheels produced by this method have the uniform grinding and self-dressing characteristics which have longbeen sought for in the art.
- the particles instead of sintering the mass to unite the particles, the particlesmay be weldedinto a compact mass. This may be accomplished by the process of electrical resistance welding known as shot In carrying out this operation.
- the sides of the mold are lined with paper or other suitable insulating material and electrical connections are made to the bottonr of the mold and to the plunger. 7 1
- the article may then be immediately removed from the mold and is ready for use.
- Wheels made by welding possess the selfdressing" characteristics in a remarkable degree.
- This method is also faster than any other known method and is therefore economical because it does not require that large numbers of molds and sintering ovens be tied up for long periods.
- Metal bonded abrasive wheels may also be made by the following method:
- Abrasive granules are adh'esively attached to a suitable support, or backing, such as paper or cloth, by -means of a volatile adhesive. After the adhesive has hardened, the coated side of the paper is given a relatively thick coating'of metal by spraying. The paper or cloth backing is then peeled off leaving a thin metal sheet with abrasive granules imbedded th'erein.
- a number of, these sheets, depending upon the wheel thickness desired, are assembled, one on top of another, and placed in a press. Pressure is applied to compact the sheets.
- the wheel may then be sintered or welded, as described above. into a homogeneous article.
- the adhesive being volatile, will be driven ofl during the heating.
- Figure 1 of the drawing shows diagrammatically a plurality of sheets A, B and C formed as described above, abrasive grain I being embedded in spray metal 2.
- Figure 2 shows diagrammati cally an abrasive wheel D having an arbor hole H formed by compacting sheets A, B and C with' zinc, tin or copper may be used. If a very brittle bond is required, alloys may be employed but due to the fact that our method produces a wheel bonded with pure metal that has an exceptionally good brittleness characteristic, the use of alloys will not be necessary in most cases.
- the methods herein described are especially suitable for the manufacture of metallic bonded diamond wheels.
- the diamond particles are at first treated with a flux to dissolve any surface impurities, then they are given a coating of metal, preferably zinc, by spraying. Either of the above described methods may then be employed for forming the aggregate.
- the method of manufacturing a metal bonded abrasive article comprising the steps of spraying an unsized abrasivecoated web with metal, peeling ofi the backing web, assembling successive layers of the metal bondedabrasive granules into the desired shape, then applying heat and pres sure to compact the mass.
- the method of manufacturing abrasive articles comprising the steps of coating individual abrasive particles with metal, compacting the coated abrasive particles to a desired shape and porosity, and uniting said coated particles at their points of contact by passing a high amperage electric current through the shaped mass for an interval of time so short that melting of the metal coatings takes place'substantially only at said points of contact.
- the method ofmanufacturing abrasive articles comprising the steps of coating" individual abrasive particles with metal, compacting the coated abrasive particles to a desired shape and porosity, and fusing together the metal coatings substantially only at their points of contact by the heat produced by the resistance of the shaped mass to the passage, during a very short interval of time, of a high amperage electric current and' in the absence of substantial heating from other sources.
- the method of manufacturing abrasive articles comprising the steps of spraying a surface coating of metal onto individual abrasive particles, compacting the coated abrasive particles to a desired shape and porosity, and uniting said coated particles at their points of contact by passing a high amperage electric current through the shaped mass for an interval of time so short that melting of the metal coatings takes.
- the method of manufacturing abrasive articles comprising the steps of coating individual abrasive'particles with a metal bond of desired brittleness characteristics, compacting the coated abrasive particles to a desired shape and porosity,
- the method of manufacturing metal bonded diamond abrasive wheels comprising the steps of coating individual diamond particles with metal, compacting the coated diamond particles to a desired shape and porosity, and uniting said diamond particles at their points of contact by passing a high amperage electric current through the shaped mass for a duration of time so short that fusion of the metal coatings takes place substantialiy only at said points of contact.
- a sintered abrasive wheel comprising a togetherinto a homogeneous body plurality of thin metal sheets, having abrasive 10.
- An abrasive wheel formed by assembling granules lmbedded at least partially therein, a plurality of thin metal sheets having abrasive compacted and sintered together into a homogranules imbedded at least partially therein into I geneous article.
- i v a wheel of the desired shape and thickness, com- RAYMOND C. BENNER. pacting said assembled sheets, and slntering them ROMIE L. MEL-TON. together into a homogeneous body.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Polishing Bodies And Polishing Tools (AREA)
Description
. Sept. 14, 1943. R; c. BENNER EI'AL 1 2,
- MANUFACTURE OF ABRASIVE ARTICLES I Original Filed Sept. 1, 1937' Innken-ford, IP/IYMO/YD 6. 56111756 ROM/E L. MEI-TON Re'iuued Sept. 14, 1943 MANUFACTURE OF ABRASIVE ARTICLES 7 Raymond c. Benner and Bonnie L. Melton, m;-
aral 'alls, N. Y asslgnors to .The Carborudum C mpa of Delaware NlagaraFalls N. Y., a corporation Original No. 2,193,285, dated March 12, 1940,
Serial No. 161,996, filed September 1, 1937. Ap-
March 10, 1942, Serial No.
11 Claims. 31. 51-309) plioation for reissue This invention relates generally to metal bonded abrasive articles.
It relates particularly to abrasive articles wherein the abrasive particles are uniformly distributed throughout a metallic bondand the method of making same.
Heretofore in the art, metal bonded abrasive articles, such as wheels, have been made by mixing the abrasive granules with molten metal and allowing the mass to harden. Thismethod has proven unsatisfactory because the high temperature of the molten metal impairs the abrasive characteristics of the granules, and it is impossible to produce an article wherein the abrasive granules are uniformly distributed throughout the metal bond because the diflference in specific view of an abrasive wheel formed by compacting with heat and pressure, the sheets shown in Figure l.
In our improved method, the abrasive grains are first given a uniform coating of metal. This may be done by any suitable means, such as electroplating, spraying,etc.
gravity between the abrasive granules and the metal allows the granules to float to the top of the mix before the metal h'as solidified.
, In an effort to overcome the above mentioned dimculties, precoating of the granules with metal by electrolytic means before adding them to the molten metal has been tried. This method has proven only partially successful. Thecoating of metal does, to someextent, protect the abrasive granules during the coating operation, but the coated grains float to the top of the mix and a non-uniform article results. I
Another serious defect in abrasive articles made by the above described methods lies in their lack of brittleness. It has been considered to be necessary that grinding wheels have the abrasive particles bonded together by a bond with brittle characteristics so that, as the wheel is worn down to a smaller diameter through use, the bond will break away and expose fresh abrasive. Otherwise, the wheel will soon become glazed and smooth because of the outer layer of abrasive particles being worn away and the inner layers becomining covered by the bond.
The invention herein claimed and described overcomes the difllculties mentioned. By means of the methods now about to be described, it is possible to easily and economically produce metal bonded articles which have the abrasive uniformly distributed throughout the mass, the bonds of which have the desired brittle characteristics and the abrasive granules of which are unaffected by the heat applied during manufacture.
In the accompanying drawing, Figure 1 is a diagrammatic view of a group of abrasive containing metal sheets to be compacted into an abrasive wheel, the sheets being shown in' sec-- tion, and Figure 2 is a diagrammatic sectional I welding.
The metal coated grains are then compacted in a. mold under pressure and are sintered at a temperature just below the melting point of the particular bond chosen. If desired, a temporary binder of glue or its equivalent may be added to the mix before pressing. This is desirable if the compacted mass is to be removed fromthe mold before sintering. The temporary binder should be sumciently volatile so that it will be driven 01f during the heat treating operation.
If desired, a small quantity of powdered metal may be added to the mass before it is compacted. If this is done, a somewhat stronger and much more dense wheel is the result. The powdered metal is mixed uniformly with, the coated granules and may be the same type of metal with which the granules are coated, or it may be a metal which will alloy with the coating on the granules.
The pressure applied to the aggregate will depend upon the desired porosity of the wheel.
This, of course, will vary for wheels of different diameters, and thicknesses, and will depend also somewhat upon the particular abrasive and/or bond used.
The time of sintering also will vary with the diameter and thickness of the wheel and with the kind of metal used.
These two factors must be determined experimentally to suit each specific set of conditions. In general, the pressure is chosen that will give the desired porosity and the sintering is carried on until the metal coated particles are firmly united into a homogeneous aggregate.
The wheels produced by this method have the uniform grinding and self-dressing characteristics which have longbeen sought for in the art.
Asa variation of the above described method, instead of sintering the mass to unite the particles, the particlesmay be weldedinto a compact mass. This may be accomplished by the process of electrical resistance welding known as shot In carrying out this operation. the sides of the mold are lined with paper or other suitable insulating material and electrical connections are made to the bottonr of the mold and to the plunger. 7 1
After the mass of metal coated abrasive particles has been compacted by the application of- The article may then be immediately removed from the mold and is ready for use.
Wheels made by welding possess the selfdressing" characteristics in a remarkable degree.
' This method is also faster than any other known method and is therefore economical because it does not require that large numbers of molds and sintering ovens be tied up for long periods.
Metal bonded abrasive wheels may also be made by the following method:
Abrasive granules are adh'esively attached to a suitable support, or backing, such as paper or cloth, by -means of a volatile adhesive. After the adhesive has hardened, the coated side of the paper is given a relatively thick coating'of metal by spraying. The paper or cloth backing is then peeled off leaving a thin metal sheet with abrasive granules imbedded th'erein.
A number of, these sheets, depending upon the wheel thickness desired, are assembled, one on top of another, and placed in a press. Pressure is applied to compact the sheets. The wheel may then be sintered or welded, as described above. into a homogeneous article. The adhesive, being volatile, will be driven ofl during the heating.
Figure 1 of the drawing shows diagrammatically a plurality of sheets A, B and C formed as described above, abrasive grain I being embedded in spray metal 2. Figure 2 shows diagrammati cally an abrasive wheel D having an arbor hole H formed by compacting sheets A, B and C with' zinc, tin or copper may be used. If a very brittle bond is required, alloys may be employed but due to the fact that our method produces a wheel bonded with pure metal that has an exceptionally good brittleness characteristic, the use of alloys will not be necessary in most cases.
The methods herein described are especially suitable for the manufacture of metallic bonded diamond wheels.
The diamond particles are at first treated with a flux to dissolve any surface impurities, then they are given a coating of metal, preferably zinc, by spraying. Either of the above described methods may then be employed for forming the aggregate.
Having thus described our invention, we claim:
1. The method of manufacturing a metal bonded abrasive article comprising the steps of spraying an unsized abrasivecoated web with metal, peeling ofi the backing web, assembling successive layers of the metal bondedabrasive granules into the desired shape, then applying heat and pres sure to compact the mass.
2. The method of manufacturing metal bonded diamond abrasive wheels comprising the" backing web, spraying the coated web with metal,
peeling off the backing web, assembling successive layers of the metal bonded diamond particles into the desired shape; th'en applying heat and pressure to compact the mass. 3. The method of manufacturing abrasive articles comprising the steps of coating individual abrasive particles with metal, compacting the coated abrasive particles to a desired shape and porosity, and uniting said coated particles at their points of contact by passing a high amperage electric current through the shaped mass for an interval of time so short that melting of the metal coatings takes place'substantially only at said points of contact.
The method ofmanufacturing abrasive articles comprising the steps of coating" individual abrasive particles with metal, compacting the coated abrasive particles to a desired shape and porosity, and fusing together the metal coatings substantially only at their points of contact by the heat produced by the resistance of the shaped mass to the passage, during a very short interval of time, of a high amperage electric current and' in the absence of substantial heating from other sources. p
5. The method of manufacturing abrasive articles, comprising the steps of spraying a surface coating of metal onto individual abrasive particles, compacting the coated abrasive particles to a desired shape and porosity, and uniting said coated particles at their points of contact by passing a high amperage electric current through the shaped mass for an interval of time so short that melting of the metal coatings takes.
place substantially only at said points of contact.
6. The method of manufacturing abrasive articles, comprising the steps of coating individual abrasive'particles with a metal bond of desired brittleness characteristics, compacting the coated abrasive particles to a desired shape and porosity,
and uniting said coated particles at their points of contact by passing a. high amperage electric current through the shapedmass for an interval of time so short that melting of the metal coatings occurs substantially only at the points of contact, whereby the brittle character of the metal coatings remains for the most part unchanged. g
"l. The method of manufacturing metal bonded diamond abrasive wheels, comprising the steps of coating individual diamond particles with metal, compacting the coated diamond particles to a desired shape and porosity, and uniting said diamond particles at their points of contact by passing a high amperage electric current through the shaped mass for a duration of time so short that fusion of the metal coatings takes place substantialiy only at said points of contact.
8.,The method of manufacturing a metal bonded abrasive article which comprises spraying metal against a layer of abrasive grain so as to form a thin metal sheet having abrasive granules imbedded therein, assembling a plurality of I pacting said assembled sheets, and sintering them 11. A sintered abrasive wheel comprising a togetherinto a homogeneous body plurality of thin metal sheets, having abrasive 10. An abrasive wheel formed by assembling granules lmbedded at least partially therein, a plurality of thin metal sheets having abrasive compacted and sintered together into a homogranules imbedded at least partially therein into I geneous article. i v a wheel of the desired shape and thickness, com- RAYMOND C. BENNER. pacting said assembled sheets, and slntering them ROMIE L. MEL-TON. together into a homogeneous body.
Publications (1)
Publication Number | Publication Date |
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USRE22373E true USRE22373E (en) | 1943-09-14 |
Family
ID=2088877
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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US22373D Expired USRE22373E (en) | Manufacture of abrasive articles |
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US (1) | USRE22373E (en) |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2424140A (en) * | 1942-01-22 | 1947-07-15 | Norton Co | Method of making abrasive articles |
US2427565A (en) * | 1944-09-25 | 1947-09-16 | Bay State Abrasive Products Co | Metal bonded abrasive |
US2452478A (en) * | 1944-05-10 | 1948-10-26 | Carboloy Company Inc | Diamond tool and method for making the same |
US2545676A (en) * | 1948-06-03 | 1951-03-20 | Service Diamond Tool Company | Diamond impregnated dressing tool |
US2578167A (en) * | 1945-09-21 | 1951-12-11 | Dentatus Ab | Grinding wheel and method of producing same |
US2836641A (en) * | 1948-05-04 | 1958-05-27 | Vogt Hans | Process for the production of electrodes for electro-chemical purposes |
US3031300A (en) * | 1957-03-27 | 1962-04-24 | Ici Ltd | Method of manufacturing consumable electrodes |
US3260576A (en) * | 1962-04-28 | 1966-07-12 | Siemens Ag | Porous sintered body and method of preparation |
US4873149A (en) | 1986-06-20 | 1989-10-10 | Nisshin Steel Co., Ltd. | Vibration-damper metal sheets |
US5334809A (en) * | 1990-02-14 | 1994-08-02 | Particle Interconnect, Inc. | Particle enhanced joining of metal surfaces |
US5677372A (en) * | 1993-04-06 | 1997-10-14 | Sumitomo Electric Industries, Ltd. | Diamond reinforced composite material |
-
0
- US US22373D patent/USRE22373E/en not_active Expired
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2424140A (en) * | 1942-01-22 | 1947-07-15 | Norton Co | Method of making abrasive articles |
US2452478A (en) * | 1944-05-10 | 1948-10-26 | Carboloy Company Inc | Diamond tool and method for making the same |
US2427565A (en) * | 1944-09-25 | 1947-09-16 | Bay State Abrasive Products Co | Metal bonded abrasive |
US2578167A (en) * | 1945-09-21 | 1951-12-11 | Dentatus Ab | Grinding wheel and method of producing same |
US2836641A (en) * | 1948-05-04 | 1958-05-27 | Vogt Hans | Process for the production of electrodes for electro-chemical purposes |
US2545676A (en) * | 1948-06-03 | 1951-03-20 | Service Diamond Tool Company | Diamond impregnated dressing tool |
US3031300A (en) * | 1957-03-27 | 1962-04-24 | Ici Ltd | Method of manufacturing consumable electrodes |
US3260576A (en) * | 1962-04-28 | 1966-07-12 | Siemens Ag | Porous sintered body and method of preparation |
US4873149A (en) | 1986-06-20 | 1989-10-10 | Nisshin Steel Co., Ltd. | Vibration-damper metal sheets |
US5334809A (en) * | 1990-02-14 | 1994-08-02 | Particle Interconnect, Inc. | Particle enhanced joining of metal surfaces |
US5835359A (en) * | 1990-02-14 | 1998-11-10 | Particle Interconnect Corporation | Electrical interconnect using particle enhanced joining of metal surfaces |
US5677372A (en) * | 1993-04-06 | 1997-10-14 | Sumitomo Electric Industries, Ltd. | Diamond reinforced composite material |
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