US793077A - Cathode-plate for batteries. - Google Patents

Cathode-plate for batteries. Download PDF

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Publication number
US793077A
US793077A US22706604A US1904227066A US793077A US 793077 A US793077 A US 793077A US 22706604 A US22706604 A US 22706604A US 1904227066 A US1904227066 A US 1904227066A US 793077 A US793077 A US 793077A
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Prior art keywords
nickel
plate
cathode
mass
oxid
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US22706604A
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Harry C Hubbell
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/48Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Definitions

  • This invention relates to cathode-plates for zinc being deposited upon the plate or holder when the battery is under charge.
  • my catliode plate I use fine hair-like fibers or filaments of nickel, which may be produced in various ways, but which I preferably produce by means of electrolysis at a liigh voltage or amperage.
  • These hair like nickel fibers are mixed and intermingled with an oxid of nickel, which is moistened and formed into a dough-like or pasty plastic mass.
  • the hair-like fibers are thoroughly incorporated with the oxid mass, the quantity of fibers preferably being greater both in weight and bulk than the oxid. mass, the said fibers or filaments serving to gather and hold or bind the oxid mass into a mat-like or matted mass,
  • the numeral 1 det' nates the intertwined hair-like nickel.
  • fibers, and 2 denotes the oxid-of-nickel mass. shown, the filaments of nickel extend in all directions and interlock one strand with another and are held in a firm cake, mat, or brick like form with the plastic oxid.
  • Fig. 2 I have shown a quantity of the cake or mat inserted in a wire-gauze pocket 3, said pocket being made of iron or nickelplated-iron gauze or wire-cloth of fine mesh.
  • my invention provides a permanentand durable battery cathode-plate which may be produced at comparatively slight cost and which has many advantages in use over the structures and materials commonly utilized for this purpose.
  • a storage-battery cathode composed of hair-like fibers of nickel intertwined and embedded in a mass of nickel oxid, forming a plastic mat or cake.
  • a cathode comprising hair-like fibers of ickel and a mass of plastic nickel oxirl fanned U150 a. mat-like body.
  • a batterymlate composed of nickel filaments interlocked in a mass of nickel oxid in nasty 0r dough-like condition and forming mat or cake.
  • a cathode consisting of hair-like nickel fibers mixed and intertwined with a mass of nickel one] and inserted ina wire-gauze pocket I or sack.

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  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Battery Electrode And Active Subsutance (AREA)

Description

PATENTED JUNE 27,1905.
H. 0. HUBBELL. I GATHODE PLATE FOR BATTERIBS..
- APPLIOATION FILED OCT. 3. 1904.
[NVENTOR j w a B Y Z; Altomq Patented June 27, 1905.
I PATENT OFFICE.-
CAT-HOD E-PLATE FOR BATTERI ES.
SPEGIFIGATION fanning part of Letters Patent 150,793,077, dated June 27,1905.
Application filed October 3, 1904. Serial 1%. 227,066.
To all whom it may concern/.-
Beit known that I, HARRY O. HUBBELL, a citizen of the Uni ted States, residing at Jersey City, in the county of Hudson and Stateof New Jersey, have in vented new and useful Improvements in Cathode-Plates for Batteries,
01 which the following is a specification.
This invention relates to cathode-plates for zinc being deposited upon the plate or holder when the battery is under charge.
I It is one of the principal objects of'my present invention to provide a battery-plate of low resistance and high conductivity which will be stable and permanent and which will oxidize freely and reduce readily. These and other objects are attained by means of the batteryplate illustrated in the accompanying drawings, in which Figure l is a perspective view of a cathodeplate made in accordance with my invention. Fig. 2 is a sectional View or" a cathode-plate contained Within a wire-cloth pocket or sack.
In making up my catliode plate I use fine hair-like fibers or filaments of nickel, which may be produced in various ways, but which I preferably produce by means of electrolysis at a liigh voltage or amperage. These hair like nickel fibers are mixed and intermingled with an oxid of nickel, which is moistened and formed into a dough-like or pasty plastic mass. The hair-like fibers are thoroughly incorporated with the oxid mass, the quantity of fibers preferably being greater both in weight and bulk than the oxid. mass, the said fibers or filaments serving to gather and hold or bind the oxid mass into a mat-like or matted mass,
cake, or brick, which may be formed or molded.
by kneading into any required shape. To give greater stability and peri'nanency to the elefnent, I prefer to place the matted material into pockets or bags made of iron or nickelplated-iron wire-cloth or gauze of fine mesh.
,In this manner a comparatively large quan-v tity of material may be made to occupy but a. small space, and thus affords a compact and stable battery-plate of great'permanency and efficiency at a slight cost.
The hereinbefore-described fibrous structure which'serves to hold the oxid mass to' It has been proposed to'use sticks, flakes, Y
or particles of graphite or'other finely-divided carbon or comminuted particles of lead and certain other minerals with oxid of nickel; but owing to the difierent specific gravitics of :the two materials in this form separation and disintegration of the structure are liable to be soon accomplished. To overcome this defect in this character of battervplates, I have provided the foregoing construction.
.Referring to the drawings, the numeral 1 det' nates the intertwined hair-like nickel.
fibers, and 2 denotes the oxid-of-nickel mass. shown, the filaments of nickel extend in all directions and interlock one strand with another and are held in a firm cake, mat, or brick like form with the plastic oxid.
In Fig. 2 I have shown a quantity of the cake or mat inserted in a wire-gauze pocket 3, said pocket being made of iron or nickelplated-iron gauze or wire-cloth of fine mesh.
From the foregoing it will be obvious that my invention provides a permanentand durable battery cathode-plate which may be produced at comparatively slight cost and which has many advantages in use over the structures and materials commonly utilized for this purpose.
Having thus fully described my invention, what idesire to secure by Letters Patent and claim is 1. A storage-battery cathode composed of hair-like fibers of nickel intertwined and embedded in a mass of nickel oxid, forming a plastic mat or cake.
A cathode comprising hair-like fibers of ickel and a mass of plastic nickel oxirl fanned U150 a. mat-like body.
3. A batterymlate composed of nickel filaments interlocked in a mass of nickel oxid in nasty 0r dough-like condition and forming mat or cake.
i. A cathode consisting of hair-like nickel fibers mixed and intertwined with a mass of nickel one] and inserted ina wire-gauze pocket I or sack.
H ARRY C. ,HUBBELL.
I In presence of-
US22706604A 1904-10-03 1904-10-03 Cathode-plate for batteries. Expired - Lifetime US793077A (en)

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2810008A (en) * 1952-09-16 1957-10-15 Yardney International Corp Electrode for electric batteries
US2960558A (en) * 1957-10-09 1960-11-15 Union Carbide Corp Dry cell
US2962540A (en) * 1957-10-09 1960-11-29 Union Carbide Corp Cement bonded cathodes
US2977401A (en) * 1957-10-09 1961-03-28 Union Carbide Corp Cathodes
US3108908A (en) * 1958-01-11 1963-10-29 Krebs Willi Hermetically sealed storage battery and method for its manufacture
US3401063A (en) * 1966-08-03 1968-09-10 Lockheed Aircraft Corp Salt water galvanic cell with steel wool cathode
US3660167A (en) * 1970-11-04 1972-05-02 Cho Kin Ching Alkaline dry cell

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2810008A (en) * 1952-09-16 1957-10-15 Yardney International Corp Electrode for electric batteries
US2960558A (en) * 1957-10-09 1960-11-15 Union Carbide Corp Dry cell
US2962540A (en) * 1957-10-09 1960-11-29 Union Carbide Corp Cement bonded cathodes
US2977401A (en) * 1957-10-09 1961-03-28 Union Carbide Corp Cathodes
US3108908A (en) * 1958-01-11 1963-10-29 Krebs Willi Hermetically sealed storage battery and method for its manufacture
US3401063A (en) * 1966-08-03 1968-09-10 Lockheed Aircraft Corp Salt water galvanic cell with steel wool cathode
US3660167A (en) * 1970-11-04 1972-05-02 Cho Kin Ching Alkaline dry cell

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