US5417938A - Device for carrying out catalyzed reactions - Google Patents

Device for carrying out catalyzed reactions Download PDF

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Publication number
US5417938A
US5417938A US07/499,367 US49936790A US5417938A US 5417938 A US5417938 A US 5417938A US 49936790 A US49936790 A US 49936790A US 5417938 A US5417938 A US 5417938A
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layer
layers
set forth
walls
catalyst material
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Ronald Shelden
Jean-Paul Stringaro
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Sulzer AG
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Gebrueder Sulzer AG
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Priority to US08/092,504 priority Critical patent/US5473082A/en
Priority to US08/412,898 priority patent/US5550298A/en
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/05—Preparation of ethers by addition of compounds to unsaturated compounds
    • C07C41/06—Preparation of ethers by addition of compounds to unsaturated compounds by addition of organic compounds only
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/009—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping in combination with chemical reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J12/00—Chemical processes in general for reacting gaseous media with gaseous media; Apparatus specially adapted therefor
    • B01J12/007—Chemical processes in general for reacting gaseous media with gaseous media; Apparatus specially adapted therefor in the presence of catalytically active bodies, e.g. porous plates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/2415—Tubular reactors
    • B01J19/2425—Tubular reactors in parallel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/32—Packing elements in the form of grids or built-up elements for forming a unit or module inside the apparatus for mass or heat transfer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/56—Foraminous structures having flow-through passages or channels, e.g. grids or three-dimensional monoliths
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/215—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of saturated hydrocarbyl groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
    • B01J2219/00094—Jackets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/18—Details relating to the spatial orientation of the reactor
    • B01J2219/185—Details relating to the spatial orientation of the reactor vertical
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/19—Details relating to the geometry of the reactor
    • B01J2219/194—Details relating to the geometry of the reactor round
    • B01J2219/1941—Details relating to the geometry of the reactor round circular or disk-shaped
    • B01J2219/1943—Details relating to the geometry of the reactor round circular or disk-shaped cylindrical
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/32—Details relating to packing elements in the form of grids or built-up elements for forming a unit of module inside the apparatus for mass or heat transfer
    • B01J2219/322—Basic shape of the elements
    • B01J2219/32203—Sheets
    • B01J2219/32206—Flat sheets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/32—Details relating to packing elements in the form of grids or built-up elements for forming a unit of module inside the apparatus for mass or heat transfer
    • B01J2219/322—Basic shape of the elements
    • B01J2219/32203—Sheets
    • B01J2219/3221—Corrugated sheets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/32—Details relating to packing elements in the form of grids or built-up elements for forming a unit of module inside the apparatus for mass or heat transfer
    • B01J2219/322—Basic shape of the elements
    • B01J2219/32203—Sheets
    • B01J2219/32213—Plurality of essentially parallel sheets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/32—Details relating to packing elements in the form of grids or built-up elements for forming a unit of module inside the apparatus for mass or heat transfer
    • B01J2219/322—Basic shape of the elements
    • B01J2219/32203—Sheets
    • B01J2219/32255—Other details of the sheets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/32—Details relating to packing elements in the form of grids or built-up elements for forming a unit of module inside the apparatus for mass or heat transfer
    • B01J2219/322—Basic shape of the elements
    • B01J2219/32279—Tubes or cylinders
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/32—Details relating to packing elements in the form of grids or built-up elements for forming a unit of module inside the apparatus for mass or heat transfer
    • B01J2219/324—Composition or microstructure of the elements
    • B01J2219/32408—Metal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/32—Details relating to packing elements in the form of grids or built-up elements for forming a unit of module inside the apparatus for mass or heat transfer
    • B01J2219/324—Composition or microstructure of the elements
    • B01J2219/32466—Composition or microstructure of the elements comprising catalytically active material
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency

Definitions

  • the invention relates to a device for carrying out catalyzed reactions and to the use of devices of this kind.
  • Catalytic solid bed reactors represent an important field of use of the invention, for example for oxidation or hydrogenation reactions.
  • the reaction space of known embodiments of reactors of this kind contains fills of solid catalyst particulates which are spherical or pellet-shaped, for example, and around which the reactants flow.
  • the layers of the actual devices are to be formed from catalyst material, this depends on the possibility of shaping the material as required in a simple manner. Materials of this kind may also be very expensive.
  • the object of the invention is to provide a device which permits advantageous utilization of the catalyst materials and a long useful life when carrying out catalyzed reactions and allows a wide range of catalyst materials to be used.
  • the invention provides a device for catalyzed reactions comprising a plurality of layers disposed in parallel relation with flow channels between the layers for reactants and with each layer defining an interspace therein.
  • a catalyst material is disposed in each interspace of each layer.
  • each layer is made of a material impermeable to the catalyst material and permeable to the reactants to permit a catalyzed reaction to occur in a respective interspace.
  • a plurality of guide elements space the layers from each other while at the same time defining the flow channels.
  • each layer has a pair of flat parallel walls defining a pocket-like interspace.
  • each layer has a pair of corrugated walls defining a respective interspace with at least some of the walls being in contact with an adjacent wall of an adjacent layer to define the flow channels.
  • the respective elements may be in the form of a corrugated plate, a rod element, and/or a plate disposed perpendicular and between a pair of adjacent layers.
  • each layer may be made of one of wire cloth and knitted wire fabric.
  • each layer may be made of a material selected from the group consisting of metal, glass and plastic.
  • each layer may be made of non-woven plastic or non-woven glass fibers.
  • each layer may be made of a porous material, a semipermeable membrane or a sintered material.
  • the catalyst material may be selected from the group consisting of solid particles, liquids including materials dissolved in a liquid and gases. Still further, the catalyst material may be a polymerized solid or may be a porous ceramic or a sintered structure.
  • the devices for catalyzed reactions may be used in a catalytic reactor as well as a catalytic rectifying column.
  • a plurality of tubes are disposed to connect the two spaces with each other while a plurality of the catalyzed reaction devices are disposed in each tube for a catalyzed reaction therein.
  • the reactor may also be provided with a suitable tube connection in the housing for supplying a heat conveying medium to a heat exchange space about the tube while a tube connection is provided in the housing for removing the medium from the heat exchange space.
  • a catalytic solid bed reactor is provided with a plurality of devices of the above type for a catalyzed reaction.
  • a mass transfer section is disposed both above and below the reactor.
  • a drain can be provided below the lower mass transfer section to remove a liquid product while a line is disposed above the other mass transfer to remove gaseous product.
  • a uniform temperature distribution, concentration equalization over the cross section, limited residence time and very little, if any, back mixing are essential advantages of the invention.
  • the uniform temperature equalization and the favourable heat transfer to the reactor walls are in particular decisive for a long useful life of the catalyst materials and for a high product yield and selectivity. This effect is particularly important in exothermic reactions, as heat resulting from these can be more quickly conducted away from overheated spots to the reactor walls. This also results in improved operating safety (no runaway).
  • the desired reaction product can be obtained in large quantities and with a high quality and there is only a relatively small quantity of non-reacted educts.
  • a further essential advantage of the invention lies in the fact that it also utilizes the properties which are known per se for pure mixing processes, such as, e.g. uniform temperature distribution and concentration equalization over the cross section, limited residence time and very little, if any, back mixing.
  • the solid bed reactors fitted with devices according to the invention can be formed with a substantially smaller number of individual tubes than known solid bed reactors, with the same flow rate.
  • a single device according to the invention may be sufficient for a solid bed reactor, i.e. in this case the cross section of the device corresponds to that of the reactor housing.
  • the known rectifying columns comprise at least one solid bed reactor and mass transfer zones, in which the products resulting from the reaction are separated from the non-reacted educts and any undesirable by-products.
  • the rectification is a continuous process and therefore also takes place in the catalytic zone in addition to the catalyzed reaction, preferably at the boiling temperature of the product to be obtained, with the boiling temperature being regulated by adjusting the column pressure accordingly. Details relating to the way in which a combined process of this kind is carried out are found in the above-mentioned article.
  • coiled bodies are arranged in the catalytic reaction zone in the known process.
  • These coiled bodies which serve to hold a solid catalyst material, consist of a wound wire cloth strip of stainless steel, by means of which a layer consisting of glass fibres and containing corrosive catalyst particles is secured.
  • the advantage of this embodiment lies in the fact that the column wall can be made of a corrosive material, such as carboniferous steel, which does not come into contact with the catalyst material.
  • FIG. 1 is an example of a device formed according to the invention
  • FIG. 1a is the example of FIG. 1 in a disassembled arrangement
  • FIGS. 1b and 1c are each perspective views of pocket-like layers
  • FIGS. 2a and 2b are side and plan views, respectively, of a variant
  • FIG. 3 is a catalytic solid bed reactor
  • FIG. 4 is a rectifying column for carrying out a combined process
  • FIG. 5 is a perspective view of another embodiment of a device formed according to the invention.
  • the device 41 shown in FIGS. 1 and 1a consists of pocket-like layers 42 which are arranged parallel to one another and are in each case connected at a side wall 43 to guide elements 44.
  • these guide elements consist of corrugated sheet metal plates, with the crests and troughs forming side walls of the flow channels 45 for the reactants.
  • Adjacent layers are then joined when a reactor 41 is assembled such that the flow channels 45 of adjacent layers 42 intersect. This permits excellent radial cross mixing of the component flows of the reactants in the manner of a static mixer, in particular in the case of a plurality of devices 41 which are arranged one after the other and preferably staggered by approximately 90°.
  • the guide elements 44 simultaneously serve to reinforce layer 42, which is connected to them by, for example, spot welding. Their crests contact the side wall of the adjacent layer 42 without guide elements and thus simultaneously serve as a spacing means. It should be mentioned that the term "corrugated" also covers zigzag profiling of the plate.
  • the guide elements 44 may, for example, consist of sheet metal, perforated sheet metal, plastic or a wire cloth or similar.
  • the side walls 43 of the pocket-like layers 42 consist of a material which is permeable to the reactants and impermeable to the catalyst material.
  • the layers 42 may be made of one of wire cloth and knitted wire fabric.
  • each layer 42 may be made of a material selected from the group consisting of metal, glass and plastic.
  • each layer 42 may be made of at least one of non-woven plastic and glass fibers.
  • each layer 42 maybe made of a semi-permeable membrane or a sintered material.
  • a solid, liquid or gaseous catalyst material 46 which is chosen in accordance with the intended purpose, is placed in the pockets of the layers 42, (see FIG. 1).
  • the catalyst material 46 is selected from the group consisting of particles, liquids and gases.
  • Another possibility lies in filling the interspaces with a pourable catalyst material and then forming a porous ceramic or sintered structure from this by treating it accordingly.
  • the device 41 may have a circular cross section.
  • the shape of the cross section is adapted to that selected for the reactor housing, i.e. the device 41 may, for example, also be square, rectangular or polygonal.
  • the guide elements of the pockets 42' are formed as rod elements 47 and connected to the layers walls 43', e.g. by spot welding. Otherwise all the above information relating to the example illustrated in FIGS. 1, 1a, 1b and 1c applies.
  • FIG. 3 is a diagrammatic representation of a catalytic solid bed reactor 6 with a cylindrical housing 7. Tubes 8, the open ends of which are secured in tube plates 9, are arranged in the housing 7.
  • Devices 10 which are formed according to the invention, are arranged above one another in the tubes 8, with adjacent devices in each case being staggered by an angle of 90° with respect to the tube axis when they are formed as the embodiments illustrated in FIGS. 1, 1a-1c and 2a and 2b.
  • Tube connections 12 and 13 adjoin the heat exchange space 11 to supply and remove a heat-supplying and heat-removing medium, e.g. a molten salt, which flows around the tubes 8.
  • a heat-supplying and heat-removing medium e.g. a molten salt
  • An admission space 14 for the reactants supplied through a connection sleeve 15 is arranged below the reaction tubes 8 and a delivery space 16 for carrying away the product and the by-products is arranged above the reaction tubes 8.
  • a mixture of air and n-butane is fed through the connection sleeve 15 and the admission space 14 into the tubes 8 at a temperature of, for example, 200°-300° C., in which case the reaction can be carried out at approximately 1 bar.
  • Phosphorus pentoxide and vanadium pentoxide may be used as catalysts in this case.
  • the reaction is exothermic and the heat produced is absorbed by a molten salt, for example, which flows over the reaction tubes 8.
  • the heated molten mass is removed in a manner which is not shown through the outlet 13, cooled to the required temperature and recirculated through the inlet 12 into the heat exchange space 11.
  • the product obtained is gaseous maleic anhydride, which is fed from the reactor 6 through the outlet 17 to a further processing stage.
  • the product is not obtained in a pure form, being mixed with educts, in the present case n-butane or by-products resulting from the formation of maleic anhydride, such as oxygen, water, maleic acid, carbon monoxide and carbon dioxide.
  • the further processing may take place in a manner which is known per se, for example in distillation processes.
  • a catalytic solid bed reactor consisting of only one tube, in which at least one device according to the invention is arranged.
  • FIG. 4 is a diagrammatic representation of a catalytic rectifying column 20, in which a catalytic solid bed reactor section 21, which is provided with devices formed according to the invention (see, e.g., FIG. 1), is arranged.
  • Mass transfer sections 22 and 23 are arranged above and below this solid bed reactor section 21.
  • the mass transfer of the products resulting in the section 21 takes place in the sections 22 and 23.
  • These sections may be formed in a known manner as, for example, sieve or bubble-cap plates. Liquid and gaseous or vaporous phases may pass through the packing material in counter-flow.
  • the individual folded layers may also be formed as single layers, i.e. they do not have double walls with interspaces.
  • a drain 26 for the liquid bottom product is connected to the bottom of the column. Some of this product is recirculated in a manner which is known per se through a line 27 into the column 20 following vaporization in a vaporizer 28.
  • a line 29 for removing the gaseous or vaporous head product is also connected in a known manner to the head of the column 20. After this head product has been liquefied in a condenser 30, some of it is returned to the column as reflux through a line 31, while the remaining quantity of liquid is removed from the rectification process via a line 32.
  • the use of the invention also enables plant of this kind to be scaled up on the basis of the above-mentioned advantages.
  • the solid catalyst section 21 is arranged in the central, lower or upper part of the column, according to the process.
  • the object of the embodiment in question is to obtain 3-methyl butyl ether from methanol and a mixture of saturated and unsaturated 4 carbon-chain hydrocarbons.
  • Acidic ion exchange resins for example, may be used as the catalyst material in the section 21.
  • the reactant consisting of methanol is fed into the column 20 through the line 24 above the section 21, while the reactant consisting of a mixture of saturated and unsaturated 4 carbon-chain hydrocarbons is fed into the column 20 through the line 25 below the section 21.
  • Non-reacted 4 carbon-chain hydrocarbons are separated in counter-flow to the liquid phase from the reaction products in the mass transfer section 22, removed in the form of vapours at the head of the column 20, liquefied in the condenser 30 and returned in part to the column 20 as reflux.
  • the remaining quantity may, for example, be returned as a reactant through the line 25 to the column 20.
  • the end product which is obtained in liquid form and consists of 3-methyl butyl ether, is conveyed out of the column 20 at the bottom of the latter. Some is vaporized in the vaporizer 28 and recirculated into the column 20. The liquid end product is removed from the plant for further processing through a line 33.
  • the device 51 illustrated in FIG. 5 consists of folded layers 52 which are arranged parallel to one another and in each case consist of a double shell 52a and 52b, the walls consisting of a material which is permeable to the reactants and impermeable to the catalyst material.
  • a solid, liquid or gaseous catalyst material 54 which is chosen in accordance with the intended purpose, is introduced into the interspaces formed by the double walls 52a and 52b.
  • Another possibility lies in filling the interspaces with pourable catalyst material and then forming a porous ceramic or sintered structure from this by treating it accordingly.
  • the device 51 has a circular cross section.
  • the shape of the cross section is adapted to that selected for the reactor housing, i.e. the device 51 may, for example, also be square, rectangular or polygonal.
  • the individual layers 52 are folded, with the folds 55 being at an angle to the longitudinal axis of the device and the folds of adjacent layers 52 intersecting.
  • the invention should thus be applicable to both solid catalyst material, such as platinum, metal oxides, zeolite or ion exchange resins, and catalytic solutions, such as aqueous palladium oxide and copper chloride solutions, or liquid catalyst materials, such as sulphuric or hydrochloric acid.
  • the invention should also permit the use of gaseous catalyst material such as hydrogen chloride or hydrogen fluoride, for example.

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
US07/499,367 1988-09-02 1989-08-22 Device for carrying out catalyzed reactions Expired - Lifetime US5417938A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
US08/092,504 US5473082A (en) 1988-09-02 1993-07-15 Device for carrying out catalyzed reactions
US08/412,898 US5550298A (en) 1988-09-02 1995-03-29 Device for carrying out catalyzed reactions

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
CH03295/88 1988-09-02
CH329588 1988-09-02
CH57789 1989-02-17
CH00577/89 1989-02-17
PCT/CH1989/000150 WO1990002603A1 (de) 1988-09-02 1989-08-22 Vorrichtung zur durchführung katalysierter reaktionen

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EP (1) EP0396650B2 (de)
WO (1) WO1990002603A1 (de)

Cited By (44)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5730843A (en) * 1995-12-29 1998-03-24 Chemical Research & Licensing Company Catalytic distillation structure
US5817901A (en) * 1994-09-08 1998-10-06 Institut Francais Du Petrole Selective hydrogenation of hydrocarbon cuts containing monounsaturated and polyunsaturated hydrocarbons
US5877331A (en) * 1997-11-12 1999-03-02 Huntsman Petrochemical Corporation Prevention of catalyst attrition and tar formation in manufacture of maleic anhydride
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EP2502655A1 (de) 2011-03-25 2012-09-26 Sulzer Chemtech AG Reaktives Destillationsverfahren und Anlage zur Gewinnung von Essigsäure und Alkohol aus der Hydrolyse von Methylacetat
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US9943819B2 (en) 2014-11-03 2018-04-17 Singh Instrument LLC Small-scale reactor having improved mixing
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US10053440B2 (en) 2015-01-14 2018-08-21 Evonik Degussa Gmbh Integrated process for making propene oxide and an alkyl tert-butyl ether
US10053438B2 (en) 2015-01-14 2018-08-21 Evonik Degussa Gmbh Integrated process for making propene oxide and an alkyl tert-butyl ether
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