US3349141A

US3349141A - Detergent alkylate composition of secondary phenyl-substituted n-alkanes

Info

Publication number: US3349141A
Application number: US338635A
Authority: US
Inventors: Sweeney William Alan
Original assignee: Chevron Research and Technology Co
Current assignee: Chevron USA Inc
Priority date: 1964-01-20
Filing date: 1964-01-20
Publication date: 1967-10-24
Anticipated expiration: 1984-10-24
Also published as: GB1041491A; DE1518622C3; FR1420865A; DE1518622B2; JPS504203B1; US3487023A; DE1518622A1

Description

United States Patent 3,349,141 DETERGENT ALKYLATE COMPOSITION OF SECONDARY PHENYL SUBSTITUTED n- ALKANES William Alan Sweeney, San Rafael, Calif., assignor to Chevron Research Company, San Francisco, Calif a corporation of Delaware No Drawing. Filed Jan. 20, 1964, Ser. No. 338,635 9 Claims. (Cl. 260-668) The present invention relates to a unique composition of aryl-substituted n-alkanes. More particularly, the invention is concerned with detergent alkylate intermediate convertible into biologically soft detergent having, in addition, good detersive properties.

For a great number of years the bulk of detergent alkylate used to make the finished detergent composition by conversion to the sulfonic acid, followed by neutralization, has been the monophenyl-substituted polypropylene polymers, as described, for example, in US. Patents Nos. 2,477,382 and 2,477,383 to Lewis. Detergent compositions as thus prepared have been developed and improved to the point that they are regarded as exhibiting optimum detersive performance. Polypropylene-based detergents, however, suffer from a serious disadvantage. Because of the branched-chain nature of the alkyl polypropylene precursor used in making the detergent alkylate, they do not meet the recently specified requirements of biodegradability. Therefore, in order to produce a more biodegradable detergent, intensive effort has been and is being expended in order to develop a new type of detergent alkylate or aryl-substituted alkanes in Which the hydrocarbyl or alkyl radical is derived from straight-chain or normal hydrocarbons.

Detergent alkylate compositions consisting essentially of a mixture of secondary phenyl-substituted n-alkanes of 11]4 carbon atoms have excellent biodegradability and can be prepared in known fashion by a number of reactions. Conventional reactions involve catalytic alkylation of benzenes or some other aryl compound, such as toluene or xylene, with either an n-alkene or an n-alkyl halide alkylating agent of the desired molecular Weight range, which can be derived from distillate cracking or wax cracking, catalytic dehydrogenation of n-parafiins, chlorination dehydrochlorination of n paraffins, ethylene polymerization and chlorination of n-parafiins. In addition, the raw materials from which the straight-chain stock is to be derived may be subjected to iso-normal sep aration processes, such as molecular sieves and urea clathration to produce a more linear product than could otherwise be obtained.

By whatever method the detergent alkylate is'prepared. its finished form meets the requirements of biodegradability, but does not possess the detergency effectiveness of the phenyl-substituted polypropylene derived detergents. It has now unexpectedly been found that the deficiency in detersive power is due to the widespread composition, particularly as to the isomer distribution that results when the aryl or aromatic compound is alkylated with the straight-chain stock. Mixtures of phenyl-substituted nalkanes are produced upon alkylation of benzene with a C C alkyl chloride or olefin mixture. These include the terminal or end-chain 2- and 3-phenyl alkanes, the intermediate 4-phenyl alkanes and the mid-chain 5-, 6-, and 7-phenyl alkanes.

Broadly, the invention is based on the discovery that the presence of the terminal 2- and S-phenyl alkanes impairs the detersive effectiveness of the alkylate mixture, and that by increasing the proportion of the mid-chain 5-, 6- and 7-phenyl alkane isomers, detergency is enhanced.

Accordingly, in one embodiment of the invention, a

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detergent alkylate composition is contemplated consisting essentially of secondary phenyl-substituted n-alkanes having 11 to 14 carbon atoms in the alkane portion of the molecule. At least 50% by weight of the composition consists of phenyl-substituted n-alkanes having 12 to 14 carbon atoms in the alkane portion of the molecule, a major proportion of which is mid-chain phenyl-substituted alkanes; 5 to 30%, preferably 5 to 15%, by Weight, of intermediate 4-phenyl alkane; and a minor proportion of 2- and 3-phenyl alkane below about 35%, generally below 20%, and preferably below 10%, by weight, of the G -C phenyl alkanes.

Surprisingly, the 2- and 3phenyl undecanes, as well as the 4-pheny1 and mid-chain phenyl undecanes, can be tolerated in relatively large amounts. Indeed, these terminal phenyl alkanes manifest better detergency properties than the mid-chain 5- and 6-phenyl undecanes. Therefore, satisfactory detergent alkylate compositions can contain up to 50% by weight, generally below 30%, and often 5-10% by weight of phenyl-substituted undecanes, the remainder of the detergent alkylate having the characteristics described above.

In accordance with the invention, the detergent alkylate compositions can be composed of the phenyl-substituted alkanes of a single number carbon fraction, for example, the phenyl isomers of dodecane, or of tridecane or of tetradecane, again the proportions of the various isomers being as specified above.

Most conveniently, the alkylate mixture can be prepared from a mixture of at least two homologous carbon fractions, for example, a mixture of phenyl-substituted tridecanes and tetradecanes, again the proportions of the various position isomers and the content of phenylsubstituted n-alkanes being as specified above.

Homologous mixtures as above described are readily obtained by the process of alkylation. For example, one convenient way is to effect alkylations of benzene and chlorinated paraffins, or alkanes, in the presence of AlC1 catalyst. The pararfin precursor materials obtained from paraffin-containing petroleum oil, and, if desired, subjected to a molecular sieve treatment, can be so selected as to correspond to a single number carbon fraction or to a blend of multiple number carbon fractions containing all of the C C homologs, the various homologs being present in approximately equal molar proportions.

The terminal 2- and 3-phenyl isomers of a given carbon number, because of their higher boiling point, are separable from more centrally attached phenyl alkane isomers by simple distillation. Therefore, mixtures of phenyl alkanes can be prepared having the desired 2- and I l-phenyl alkane content by separating the 2- and 3-phenyl isomers from one fraction and the 2- and 3-phenyl alkane content from another fraction, the fractions remaining having a higher proportion of the more centrally phenyl attached isomers being combined. For example, a fraction containing phenyl undecanes and phenyl dodecanes is treated by distillation to lower the 2- and 3-phenyl dodecane content, and the resulting mixture combined with a mixture of phenyl tridecanes and tetradecanes, from which also the 2- and 3-phenyl tetradecanes have been removed. As can readily be appreciated when proceeding in this manner, the proportions of the various homologs can vary. In general, however, in any mixture of homologs, any one homolog will be present in a proportion of at least 25% by weight of the homologous mixture.

Accordingly, in a particular useful embodiment of the invention, a detergent alkylate composition of a mixture of phenyl-substituted alkanes is contemplated, substantially all of said mixture consisting of phenyl-substituted alkanes containing 11 to 14 carbon atoms in the alkane portion of the molecule. The said mixture is further characterized in that 5 to 30%, by weight, of the mixture is phenyl undecanes, while the remainder of the mixture consists of phenyl alkanes having 12 to 14 carbon atoms in the alkane portion of the molecule, and contains at least 25%, based on said remainder, each of phenyl (lodecanes, phenyl tridecanes and phenyl tetradecanes. Moreover, said remainder consists of at least about 45% of phenyl-substituted alkanes other than the 2-, 3- and 4- phenyl alkanes, the aggregate contentof 2- and 3-phenyl tetradecanes being less than 4 percent.

The detergency effectiveness of the alkylate compositions of the present invention is manifested by mixtures of. the sulfonate derivative, obtained in conventional fashion, 'with so-called heavy duty detergent builders, in which the sulfonate can be present in proportions of 10 to 30% by weight of the finished composition. As is known in the art, these detergent builders are principally condensed inorganic phosphate detergent salt builders, used in conjunction with nonsoap synthetic surfactants to produce heavy duty detergent compositions. They can be used in their commercially available anhydrous form, obtained by the high temperature dehydration of the orthophosphates-tripolyphosphates, from a mixture of disodium orthophosphate and monosodium orthophosphate; tetrasodium pyrop-hosphates, from disodium orthophosphate; and sodium polymetaphosphates, from ortho phosphate. The various condensed phosphates can be used singly or in admixture. As is known in the detergent art, the proportions of thevarious phosphates are frequently altered in practice, and similar practice can prevail here. Generally, good results are obtained when. tripolyphosphate is essentially the sole condensed phosphate or is admixed with the other condensed phosphates, for example, 80% tripolyphosphate and.20% pyrophosphate.

Other compatible optional ingredients which are particularly useful in the preparation of the compositions herein contemplated are those customarily present in heavy duty detergent formulations. These include, in weight amounts, based on the composition: an anticorrosion and stabilizing agent, such as sodium silicate, wherein the SiO -to-Na O ratio can range from /2 to /3,

in proportions of, for example, 5%; an. antiredeposition agent, such as sodium carboxymethyl cellulose, as described, for example, in US. Patent No. 2,568,334, proportions of about 1 to 3% being cited as illustrative; a foam modifier, such as a monoor diethanolamide of a fatty acid, such as lauric isopropanolarnide, in proportions, for example, of 5%; a chemical bleaching agent, such as sodium perborate or sodium per-carbonate, for example, in an amount of 2 to 5%; optical whiteners, in amounts of the order of 0.1 to 0.2%, such as the triazinyl and. aroylstilbenes, benzidinesulpho'nes, bisbenzimidazoles, triazoles, and amino coumarins; sequestering agents, in amounts, for example, of the order less than 1%, such as tetrasodium ethylene diamine; finally, certain inorganic salts, up to about 30%, such as inorganic sulfate, carbonate, or borate.

A significant test for determining the detersive effectiveness of a detergent, and the one used in obtaining the data below with the biodegradable detergent alkylate of the present invention is the so-called Hand Dishwashing Test. This test is based on a-procedure presented at the ASTM D-12 Subcommitteeon Detergents, March 10, 1959, New York, NY.

According to thisqtest, dinner dishes or plates having a diameter of nine inches are washed under conditions simulating home. dishwashing, the total, number of plates washed before the foam collapses being determined.

In this test the dishes are smeared with molten, partially hydrogenated vegetable oils, melting point of 110- 115 F. (Crisco), treated with a dye, such as Sudan Red Dye to impart a uniform appearance to the grease.

Using a syringe, 2.2 cc. of the molten soil is placed in the 117 F. are placed in an 8000 ml. container having a faucet outlet in the base (Scientific Glass, item P-2350). Samples of the built detergent to be tested are made up into 6% solutions, and 150 cc. of each solution is added to a dishpan 13.5 inches in diameter and 5.75 inches deep, thereby giving a final concentration of 0.15% by weight.

The water container is then placed above the dishpan in such a position that the distance between faucet outlet and bottom of the dishpan is 18 inches. Further, the dishpan is so placed that the stream of water strikes the center of the dishpan. The water from the container is drained into the dishpan with the water faucets fully open. This requires about 4560 seconds. When the dishpan is completely charged, washing of the dishes is begun.

Five soiled plates and a clean dishcloth are placed in the dishpan. The dishes are washed in a circular manner to remove the grease from the front of the plate, then turned over and the grease clinging to the back is removed in the same way. During. the washing, each plate is held at. an angle so that almost one-half of the plate is kept under the washing solution. This is repeated until the five plates are washed. Another set of five plates is then placed in the dishwater and washing c ntinued, this,

procedure being repeated until the foam collapses in the dishpan. At this point the surface is nearly devoid of foam. A detergent formulation capable of washing at least twenty plates and preferably at least twenty-four plates is regarded as suitable.

The following tabulated examples illustrate the practice of the invention, the column headed Plates indi- Based on the 012-014 Portion Percent -014 Ex. No. Plates Percent Percent Mid-Chain Percent 4 Percent 2 plus 3e 0 2 C C 4 Total C C C 4 T0131 Cu 0 3 C T0181 C 2 C 3 C Total 18 16 32 32 20 84 13. 1 16. 4 11.9 41. 4 5. 7 4. r 2. 6 12.8 19. 4 17.1 9. 3 45. 8 19 9 37 41 13 91 14. 3 19. 3 12. 4 46 6. 3 5. 4 1. 4 13. 1 20.1 20. 4 0.4 40. 9 24 9 31 34 26 91 12 22.8 49. 8 5. 1 4. 8 4. 3 I 14. 2 17. 1 17.5 1. 4 36 24 8 13 44 92 4. 8 16.4 41.4 62. 6 2.1 4. 6 4.9 11.6 7.3 17. 1 1.4 25.8 29 10 30 39 21 90 29. 2 42 22. 3 93.5 4. 1 1. 2 0. 8 6. 1 0.4 0 0 0.4 18 0 0 100 0 100 43 43 12 12 45 45 24. 5 0 0 100 0 100 0 63 0 63 0 12 0 12 25 25 29 0 O 100 0 100 85 10 10 5 5 16 0 0 0 100 50 5O 11 11 39 20 0 0 0 100 100 66 66 13 13 21 26. 5 0 100 0 0 100 84 0 0 84 14 0 0 14 2 18 0 48 52 0 100 16. 3 22.4 38. 7 7.2 6. 2 13. 4 47. 9 24 0 48 52 0 100 16. 3 44. 2 0 60. 5 7. 2 5. 2 0 12. 4 27.1 5 100 0 0 0 0 0 0 0 0 0 0 0 0 0 30 0 35 36 29 100 26 29.2 23 78. 2 7. 6 5 4. 1 16. 7 5. 1 24. 5 47.5 0 0 52. 5 52. 5 0 0 87 87 0 0 10 10 3 25 0 0 100 0 100 0 53 0 53 0 31 0 31 16 31 0 0 100 0 100 O 96 0 96 0 4 0 4 0 cating the number of plates washed in accordance with the previously described test.

In the examples the sulfonate is produced by sulionating the detergent alkylate intermediate, followed by neutralization with sodium hydroxide and drying. The resulting sulfonate product is compounded into a built detergent composition analyzing as follows, by weight: 25% sodium alkylbenzene sulfonate, 40% trisodium polyphosphate, 7% sodium silicate, 1% carboxy methyl cellulose, 19% sodium sulfate, and 8% water.

Referring to the table, Experiment 1 represents a phenyl alkane mixture obtained by the alkylation reaction of benzene and chlorinated parafiins having 11 to 14 carbon atoms. The sulfonate of the alkylate when compounded into a heavy duty detergent composition as described above washes eighteen dishes. It will be noted that the 2- and 3-phenyl C C alkanes content is 45.8%. Progressively lowering the 2- and 3-phenyl alkane content gives increasingly better results as shown in Experiments 25.

Substantially the same effect is noted using a single carbon number fraction, that is, one in which the phenyl alkanes have the same number of carbon atoms, as shown in Experiments 68 (C Experiments 91O (C and Experiment 11 (C In Experiments 12 and 13, mixtures of two homologous fractions (phenyl C and C alkanes) are shown the effects of decreasing 2- and 3-phenyl alkane content.

On the other hand, a mixture consisting of phenyl undecanes gives poor results, as shown in Experiment 14. Although no phenyl undecanes need be present, as indicated in Experiment 15, up to 50% phenyl undecanes can be tolerated as shown in Experiment 16.

Finally, the 4-phenyl content of mixtures contemplated by the present invention can vary widely as shown in Experiments 17 and 18.

What is claimed is:

1. A detergent alkylate composition consisting essentially of secondary phenyl-substituted n-alkanes, 5 to 50% by weight of said phenyl-substituted n-alkanes having 11 carbon atoms in the alkane portion of the molecule, the remainder of said phenyl-substituted n-alkane having 12 to 14 carbon atoms in the alkane portion of the molecule, said remainder consisting of a major proportion of mid-chain substituted phenyl alkanes, from 5 to 30% by weight of 4-phenyl alkanes, and a minor proportion of 2- and 3-phenyl alkanes not exceeding about 35% by weight.

2. Composition according to claim 1, wherein the C C 4-phenyl alkanes range from 5 to 15 percent.

3. Composition according to claim 2 wherein the phenyl-substituted n-alkane having 11 carbon atoms is present in an amount of 5 to percent.

4. A detergent alkylate composition consisting essentially of secondary phenyl-substituted n-alkanes having 11 to 14 carbon atoms in the alkane portion of the molecule, at least 50% by weight of said composition being a mixture of secondary phenyl-substituted n-alkanes of at least two homologous fractions selected from the group consisting of C C and C n-alkane homologous fractions, at major proportion of said mixture consisting of mid-chain phenyl-substituted n-alkanes, from 5 to by weight of 4-phenyl-substituted alkanes and a minor proportion of 2- and 3-phenyl alkanes not exceeding by weight.

5. A composition according to claim 4 wherein the 4-phenyl-substituted n-alkanes are present in an amount of 5 to 15%, and the 2- and 3-phenyl alkanes do not exceed 20 percent.

6. Composition according to claim 5, wherein the composition contains 5 to 50% by weight of phenyl-substituted alkanes containing 11 carbon atoms in the alkane portion.

7. A detergent alkylate composition consisting essentially of a mixture of phenyl-substituted alkanes, substantially all of the mixture consisting of phenyl-substituted alkanes containing 11 to 14 carbon atoms in the alkane portion of the molecule, 5 to 30% of the mixture consisting of phenyl undecanes, substantially all of the remainder of the mixture consisting of phenyl alkanes containing 12 to 14 carbon atoms in the alkane portion of the molecule and containing at least 25% each of phenyl dodecanes, phenyl tridecanes and phenyl tetradecanes, said remainder consisting of at least of phenyl-substituted alkanes other than the 2-, 3- and 4- phenyl alkanes, and said remainder having an aggregate content of 2- and 3-phenyl tetradecanes less than 4 percent.

8. A detergent alkylate composition consisting essentially of secondary phenyl-substituted n-alkane within the range of 11 to 14 carbon atoms in the alkane portion of the molecule with at least by weight of said composition composed of secondary phenyl-substituted nalkanes wherein the alkane portion contains 12, 13 and 14 carbon atoms and in which the phenyl attachment to said n-alkane is predominantly in the 4, 5, 6 and 7 position and a minor proportion of 2- and 3-phenyl alkanes in the phenyl-substituted C -C n-alkane portion of said composition which does not exceed 35% by weight.

9. Composition according to claim 8 wherein the 2- and 3-phenyl alkanes of the phenyl-substituted C -C n-alkane portion of said composition does not exceed 20 percent.

References Cited UNITED STATES PATENTS 2,695,326 11/1954 Lippincott et a1. 260-671 X 3,169,987 2/1965 Bloch 260671 X 3,248,443 4/ 1966 McEwan et a1. 260671 OTHER REFERENCES Swisher, Soap and Chemical Specialties, July 1963, pp. 47-50 and 95.

DELBERT E. GANTZ, Primary Examiner.

C. R. DAVIS, Assistant Examiner.

Claims

1. A DETERGENT ALKYLATE COMPOSITION CONSISTING ESSENTIALLY OF SECNDARY PHENYL-SUBSTITUTED N-ALKANES, 5 TO 50% BY WEIGHT OF SAID PHENYL-SUBSTITUTED N-ALKANES HAVING 11 CARBON ATOMS IN THE ALKANE PORTION OF THE MOLECULE, THE REMAINDER OF SAID PHENYL-SUBSTITUED N-ALKANE HAVING 12 TO 14 CARBON ATOMS IN THE ALKANE PORTION OF THE MOLECULE, SAID RMAINDER CONSISTING OF A MAYOR PROPORTION OF MID-CHAIN SUBSTITUTED PHENYL LAKANES, FROM 5 TO 30% BY WEIGHT OF 4-PHENYL ALKANES, AND A MINOR PROPORTION OF 2- AND 3-PHENYL ALKANES NOT EXCEEDING ABOUT 35% BY WEIGHT.