US3314923A - Process for preparing imide containing polyisocyanates - Google Patents

Process for preparing imide containing polyisocyanates Download PDF

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US3314923A
US3314923A US326255A US32625563A US3314923A US 3314923 A US3314923 A US 3314923A US 326255 A US326255 A US 326255A US 32625563 A US32625563 A US 32625563A US 3314923 A US3314923 A US 3314923A
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parts
polyisocyanates
polyisocyanate
diisocyanate
solution
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Muller Gerhard
Merten Rudolf
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Bayer AG
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/34—Carboxylic acids; Esters thereof with monohydroxyl compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/34—Carboxylic acids; Esters thereof with monohydroxyl compounds
    • C08G18/343—Polycarboxylic acids having at least three carboxylic acid groups
    • C08G18/345—Polycarboxylic acids having at least three carboxylic acid groups having three carboxylic acid groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/80—Masked polyisocyanates
    • C08G18/8003—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen
    • C08G18/8048—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen with compounds of C08G18/34
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
    • C08G73/10—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
    • C08G73/1003—Preparatory processes
    • C08G73/1035—Preparatory processes from tetracarboxylic acids or derivatives and diisocyanates

Definitions

  • This invention relates to isocyanate compositions and more particularly to a novel process for high molecular weight polyisocyanates.
  • polyisocyanates by a number of Ways, for example, high molecular weight polyisocyanates may be obtained by the phosgenation of amines. Also polyisocyanates may be prepared by treating compounds containing several active hydrogen atoms with an excess of polyisocyanate monomers. An addition reaction, with migration of the reactive hydrogen atoms, takes place and the addition product has a higher molecular weight, and may have more -NCO groups per molecule than the polyisocyanate monomer put into the reaction. The use of compounds with only one reactive hydrogen atom leads to a reduction in the functionality and is, therefore, of no technical interest.
  • polyisocyanates containing imide groups which involves reacting monomeric polyisocyanates with compositions containing at least one cyclic carboxylic acid anhydride group, said polyisocyanate being used in the reaction is a stoichiometric excess over the corresponding functional group of said anhydride.
  • R is a radical selected from the group consisting of aliphatic, aromatic, cycloaliphatic, araliphatic, and mixtures thereof, and n is an integer of from 2 to 3.
  • the process according to the invention therefore, concerns the preparation of high molecular weight polyisocyanates which contain imide groups and which may be masked.
  • the process is characterized. in that monomeric polyisocyanates are reacted with compounds which contain one or more cyclic anhydride groups, and which, where only one anhydride group is present, must contain also at least one hydrogen atom capable of reacting with -NCO groups; the high molecular weight polyisocyanates so obtained may, if desired, subsequently be masked in a manner known per se.
  • polyisocyanates such as butane-, hexaneand heptane diisocyanate, aliphatic diisocyanates with a built in ring system such as w,w-diisocyanate-l,3-dimethylbenzene, w,w'-diisocyanate-1,4-dimethylcyclohexane, w,w'-Cliisocyanate-l,4-diethylbenzene and cyclohex-ane-l,3, cyclohexene-1,4-, l-methylcyclohexane-ZA- and dicyclohexylethanel, 4'-diisocyanates.
  • aliphatic diisocyanates such as butane-, hexaneand heptane diisocyanate
  • aliphatic diisocyanates with a built in ring system such as w,w-diisocyanate-l,3-d
  • mixed aromatic aliphatic and aromatic hydroaromatic diisocyanates such as 4-phenylisocyanate-methylisocyanate, tetrahydronaphthylene-l,5-, hexahydrobenzidine-4,4- and hexahydrodiphenylmethane-4,4'-diisocyanates, also diisocyanates of benezene and its homologues, for example, 1,3-phenylene-, 1,4-phenylene-, l-methylenebenzene-2,4- and 1-methylbenzene-2,6-diisocyanate and mixtures of their isomers, mono-, diand triisopropylbenzyl-diisocyanates, polyisocyanates of naphthalene of diphenyls and of diand :tri-phenylmethane with polynuclear ring systems or of polyphenyl compounds.
  • diisocyanates of benezene and its homologues for example,
  • naphthalene- 1,4-, naphthalene-Li diphenyl-4,4'-, diphenylmethane- 4,4-, anthraquinone-2,6 and diphenylsulphide-2,4-diisocyanates
  • triphenylmethane-4,4,4"-triisocyanate 4,4-dimethyldiphenylmethane-2,2'-, 5,5-tetraisocyanate
  • the polyisocyanates used according to the invention may also be substituted by halogen, alkoxy-, azo-, nit ro-,. cyano-, esteror sulphonic groups.
  • halogen alkoxy-, azo-, nit ro-,. cyano-, esteror sulphonic groups.
  • examples of these are l-chlorobenzene-, l-nitrobenzeneand 1-methoxybenzene-2,4-diisocyanate, tetrachloroap-phenylene diisocyanate, azobenzene-4,4-diisocyanate and benzidine sulphonic-4,4-diisocyanate.
  • Compounds with several functional groups are used for reaction with the polyisocyanates and at least one of these groups must be a cyclic anhydride group, i.e. these compounds contain either two or more cyclic anhydride groups or at least one cyclic anhydride group and additional reactive hydrogen atoms; these additional reactive hydrogen atoms being, for example, in hydroxy, mercapto, carboxyl or amino groups. Additional reactive hydrogen atoms may, of course, be present when there are several anhydride groups in the molecule.
  • Compounds of this kind may be derived, for example, from pyromellitic acid, trimellitic acid, mellitic acid, naphthalene-l,4,5,8- naphthalene-2,3,6,7- or naphthalene-1,2,5,6-tetracarboxylic acid, diphenyl-3,3',4,4'- and dipheny-l-2,2',3,3'-tetracarboxylic acid, 2,2-di-(3,4-dicarboxyphenyl)propane, di- (3 ,4-dicarboxyphenyl) -sulphone, perylene-3 ,4,9, l O-tetracarboxylic acid and ethylene tetracarboxylic acid.
  • the components are placed :ogether, as far as possible under anhydrous conditions, preferably in solvents which are inert under the reaction :onditions.
  • Suitable solvents are halogenated hydrocar- DOnS, phenols, esters, ketones, ethers, substituted amides, sulphoxides and sulphones such as xylene, phenol, cresol, acetophenone, monoand dichlorobenzene, ethylene gly- :ol monomethyl ether acetate, N-methylpynrolidone, dimethylformamide, dimethylacetamide, dimethylsulphoxide and dimethylsulphone and mixtures thereof. Phenols behave as inert solvents under the reaction conditions.
  • the propontion of anhydride to polyisocyanate may be varied widely, provided that an excess of the polyisocyanate is added.
  • at least 1.1 equivalents, preferably 1.1 to 3 equivalents of -NCO will be used per functional group.
  • the reaction is carried out at temperatures of about 50 C. to about 200 C., preferably about 100 C. to 170 C., and is complete after one hour.
  • the reaction components may be added in any sequence; for example, polyisocyanate, if desired, in solution may be put into the reaction vessel and the anhydride may be added as second reaction component or conversely.
  • the isocyanate groups of the resulting high molecular weight polyisocyanates which contain imide groups may be masked in known manner by reaction with compounds which can be split 01f again, for example, phenols, substituted phenols or compounds containing active methylene groups.
  • Polyisocyanates with any desired isocyanate content i.e. of any desired degree of condensation may be produced depending upon the ratio of the starting components, the duration of the reaction and the reaction temperature.
  • the high molecular Weight polyisocyanates obtained by the process described above may be isolated in known manner as free isocyanates in pure form or in solution, for example, by crystallization, precipitation or sublimation.
  • the products of the process may be used as adhesives or as auxiliary agents for rubber.
  • the product of Example 8 (with free NCO groups instead of the blocked ones) can be dissolved in a solvent of equal parts of dimethyl formamide and N-methylpyrrolidone. With this solution steel plates can be sprayed and rubber sheets pressed onto the prefabricated plates which results in a strong bond between steel and rubber.
  • EXAMPLE 1 A solution of about 110 parts by weight of diphenylmethane-4,4'-diisocyanate and about 52.5 parts of hexamethylene-1,6-diisocyanate in about 250 parts of N- methylpyrrolidone is added dropwise to a solution of about 96 parts of trimellitic acid anhydride in about 250 parts of N-methylpyrrolidone at about 50 C. to 60 C. The mixture is heated for about 4 hours at about 120 C. in an atmosphere of nitrogen While stirring. The isocyanate content of the solution is then 1.35%. The polyisocyanate obtained is masked by reaction with about 25 parts of crude cresol.
  • EXAMPLE 2 A mixture of about 65 parts of toluylene-2,4-diisocyanate and about 63 parts of hexamethylene-1,6-diisocyanate is added dropwise at about 40 C. over to minutes, to a solution of about 96 parts of trimellitic acid anhydride in about 500 parts of N-methyl-pyrrolidone. After heating the reaction mixture at about 120 C. for about 6 /2 hours, the isocyanate content is 1.5%. The polyisocyanate obtained is masked by reaction with about 30 parts of crude cresol. About 705 parts of a solution of the masked polyisocyanate in N-methylpyrrolidone are obtained (viscosity 144 cp./, solids content 34%). The masked polyisocyanate has absorption bands at 1710 and 1768 cm.” in the IR spectrum, which correspond to imide groups.
  • EXAMPLE 3 A solution of about 281 parts of diphenylmethane-4,4- diisocyanate and about 195 parts of toluylene-2,4- and 2,6- diisocyanate in about 750 parts of N-methylpyrrolidone is added dropwise at about 50 to 60 C. to a solution of about 288 parts of trimellitic acid anhydride in about 750 parts of N-methylpyrrolidone. The reaction mixture is heated for about 1 /2 hours at about 120 C. The isocyanate content of the solution is then 1.44%. The polyisocyanate formed is masked by reaction with about 90 parts of crude cresol.
  • EXAMPLE 4 A solution of about 16.8 parts of hexamethylene-1,6- diisocyanate in about parts of N-methylpyrrolidone is added drOpWise at about 25 C. to a solution of about 9.6 parts of trimellitic acid anhydride in about parts of N-methylpyrroli-done. The reaction mixture is heated for about 2 hours at about 100 C. The solution of the polyisocyanate thus formed has an isocyanate content of 5.6%. The imide absorption bands may be observed in the IR spectrum.
  • EXAMPLE 5 A solution of about 25 parts of diphenylmethane-4,4'- diisocyanate in about 100 parts of dimethylformamide is added dropwise at about 25 C. to a solution of about 10.9 parts of pyromellitic acid anhydride in about 100 parts of dimethylsulphoxide. The reaction mixture is heated for about 20 minutes at about 100 C. and the solution of the polyisocyanate then has an isocyanate content of 0.73%. The IR spectrum has absorption bands at 1710 and 1770 cm.” which correspond to imide groups.
  • EXAMPLE 6 A solution of about 38.4 parts of hexahydrodiphenyl methane-4,4-diisocyanate in about 70 parts of dimethyl formamide is added .dropwise at about to C. to a solution of about 19.2 parts of trimellitic acid anhydride in about parts of N-methylpyrrolidone. The reaction product is heated for about 3 hours at about C. The isocyanate content of the solution is then 3.15%. The bands due to the imide structure of the olyisocyanate formed may be detected in the IR spectrum.
  • EXAMPLE 7 A solution of about 18.3 parts of 2,4-diisopropylbenzene-1,5-diisocyanate and about 12.6 parts of hexamethylene-1,6-diisocyanate in about 50 parts of N-methylpyrrolidone is added dropwise at about 50 to 60 C. to a solution of about 19.2 parts of trimellitic acid anhydride in about 50 parts of N-methylpyrrolidone. The mixture is heated for about 5 hours at about 100 C. The solution of the polyisocyanate produced has an isocyanate content of 4.96%. The bands due to the imide groups in the polyisocyanate may be detected in the IR spectrum.
  • EXAMPLE 8 About 50 parts of 4,4-diisocyanate-diphenyl-methane are heated to about C. in about 250 parts of commercial dichlorobenzene and about 19.2 parts of trimel- 4. Aprocess for the preparation of polyisocyanates conlitic acid anhydride are introduced over about 30 mintaining imide groups which comprises condensing a mixutes. Carbon dioxide is evolved. After about 2 hours, ture comprising diphenyl methane-4,4'-diisocyanate, and about 22 parts of commercial cresol are added at about 2.4- and 2,6-tolylene diisocyanate with trimellitic acid an- 160 C. The solution, which is at first clear becomes 5 hydride in the presence of N-methylpyrrolidone at a temturbid after some time. perature of about 120 C.
  • EXAMPLE 10 11. The process of claim 1 conducted under substantially anhydrous conditions. About 100 parts of commercial cresol, about 50 parts 12. The process of claim 1 wherein at least one of the of diphenylmethane-4,4-diisocyanate and about 19.2 reaction components is in an inert solvent. parts of trimellitic acid anhydride are reacted together in 13- The process f claim 1 whereby said reaction is three separate experiments. In each of these expericarried out at a temperature of about 50 C. to about ments, two of the three components are mixed together 00 C- at about 160 C. and the third component is then added. 14.

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Description

United States Patent Office 3,314,923 Patented Apr. 18, 1967 3,314,923 PROCESS FOR PREPARING llVHDlE CONTAINING POLYHSQCYANATES Gerhard Muller, Leverkusen, and Rudolf Merton, 6Cologne-Flittard, Germany, assignors to Farbenfabriken Bayer Alttiengeseilschaft, Leverltusen, Germany, a corporation of Germany N Drawing. Filed Nov. 26, 1963, Ser. No. 326,255
16 Claims. (Cl. 260-48) This invention relates to isocyanate compositions and more particularly to a novel process for high molecular weight polyisocyanates.
It is known to prepare polyisocyanates by a number of Ways, for example, high molecular weight polyisocyanates may be obtained by the phosgenation of amines. Also polyisocyanates may be prepared by treating compounds containing several active hydrogen atoms with an excess of polyisocyanate monomers. An addition reaction, with migration of the reactive hydrogen atoms, takes place and the addition product has a higher molecular weight, and may have more -NCO groups per molecule than the polyisocyanate monomer put into the reaction. The use of compounds with only one reactive hydrogen atom leads to a reduction in the functionality and is, therefore, of no technical interest.
It is, therefore, an object of this invention to provide a novel process for the preparation of polyisocyanates. Another object of this invention is to provide a method for the preparation of polyisocyanates containing imide groups. Another object of this invention is to provide a method for the preparation of masked isocyanates. Still a further object of this invention is to provide a comparatively simple method for the preparation of polyisocyanates which will require little, if any, modification in the production system. Still a further object of this invention is to provide a process for the preparation of polyisocyanates which does not always require the phosgenation of compositions containing active hydrogen atoms.
The foregoing objects and others which will become apparent from the following description are accomplished in accordance with this invention, generally speaking, by
providing a process for the preparation of polyisocyanates containing imide groups which involves reacting monomeric polyisocyanates with compositions containing at least one cyclic carboxylic acid anhydride group, said polyisocyanate being used in the reaction is a stoichiometric excess over the corresponding functional group of said anhydride.
It has now been found that compounds which contain one or more cyclic carboxylic acid anhydride groups instead of one or more transferable hydrogen atoms are also suitable for condensation with monomeric polyvalent isocyanates. The anhydride structure reacts with one equivalent of isocyanate, CO is split off and a cyclic imide is formed as represented by the following equation scheme showing how an isocyanate group reacts with a cyclic anhydride configuration. This mode of reaction is employed in the present invention for polyfunctional starting materials,
0 O C O (C )11 O OON-R (O )11 N--R C01 wherein R is a radical selected from the group consisting of aliphatic, aromatic, cycloaliphatic, araliphatic, and mixtures thereof, and n is an integer of from 2 to 3.
The process according to the invention, therefore, concerns the preparation of high molecular weight polyisocyanates which contain imide groups and which may be masked. The process is characterized. in that monomeric polyisocyanates are reacted with compounds which contain one or more cyclic anhydride groups, and which, where only one anhydride group is present, must contain also at least one hydrogen atom capable of reacting with -NCO groups; the high molecular weight polyisocyanates so obtained may, if desired, subsequently be masked in a manner known per se.
The following are examples of polyisocyanates: aliphatic diisocyanates such as butane-, hexaneand heptane diisocyanate, aliphatic diisocyanates with a built in ring system such as w,w-diisocyanate-l,3-dimethylbenzene, w,w'-diisocyanate-1,4-dimethylcyclohexane, w,w'-Cliisocyanate-l,4-diethylbenzene and cyclohex-ane-l,3, cyclohexene-1,4-, l-methylcyclohexane-ZA- and dicyclohexylethanel, 4'-diisocyanates. In addition, there may be mentioned mixed aromatic aliphatic and aromatic hydroaromatic diisocyanates such as 4-phenylisocyanate-methylisocyanate, tetrahydronaphthylene-l,5-, hexahydrobenzidine-4,4- and hexahydrodiphenylmethane-4,4'-diisocyanates, also diisocyanates of benezene and its homologues, for example, 1,3-phenylene-, 1,4-phenylene-, l-methylenebenzene-2,4- and 1-methylbenzene-2,6-diisocyanate and mixtures of their isomers, mono-, diand triisopropylbenzyl-diisocyanates, polyisocyanates of naphthalene of diphenyls and of diand :tri-phenylmethane with polynuclear ring systems or of polyphenyl compounds. Examples of the last mentioned class-es of substances are naphthalene- 1,4-, naphthalene-Li, diphenyl-4,4'-, diphenylmethane- 4,4-, anthraquinone-2,6 and diphenylsulphide-2,4-diisocyanates, triphenylmethane-4,4,4"-triisocyanate, 4,4-dimethyldiphenylmethane-2,2'-, 5,5-tetraisocyanate, triphenyl phosphate 4,4,4-triisocyanate and polyphenylmethylpolyisocyanates as obtained by aniline/formaldehyde condensation followed by phosgenating. The polyisocyanates used according to the invention may also be substituted by halogen, alkoxy-, azo-, nit ro-,. cyano-, esteror sulphonic groups. Examples of these are l-chlorobenzene-, l-nitrobenzeneand 1-methoxybenzene-2,4-diisocyanate, tetrachloroap-phenylene diisocyanate, azobenzene-4,4-diisocyanate and benzidine sulphonic-4,4-diisocyanate.
Compounds with several functional groups are used for reaction with the polyisocyanates and at least one of these groups must be a cyclic anhydride group, i.e. these compounds contain either two or more cyclic anhydride groups or at least one cyclic anhydride group and additional reactive hydrogen atoms; these additional reactive hydrogen atoms being, for example, in hydroxy, mercapto, carboxyl or amino groups. Additional reactive hydrogen atoms may, of course, be present when there are several anhydride groups in the molecule. Compounds of this kind may be derived, for example, from pyromellitic acid, trimellitic acid, mellitic acid, naphthalene-l,4,5,8- naphthalene-2,3,6,7- or naphthalene-1,2,5,6-tetracarboxylic acid, diphenyl-3,3',4,4'- and dipheny-l-2,2',3,3'-tetracarboxylic acid, 2,2-di-(3,4-dicarboxyphenyl)propane, di- (3 ,4-dicarboxyphenyl) -sulphone, perylene-3 ,4,9, l O-tetracarboxylic acid and ethylene tetracarboxylic acid. In addition, there may be mentioned the internal anhydrides of hydroxy-, mercaptoor amino-o-phthalic acid or of hydroxy-, mercapto-, or amino-naphthalinic-dicarboxylic acid Whose carboxyl groups are in the o-position one to another. Suitable for [the process according to the invention are also di-adducts of maleic acid or maleic anhydride with styrene or substituted styrene as well as phenylene-di-[alkane-di-(carboxylic acid anhydride)] as described in Belgian patent specification No. 613,374 and dicyclo-tetra-carboxylic acid dianhydrides as described in US. Patent No. 3,037,966 as well as polyanhydrides ob- :ained by 'chlorinating paraflins, for example, in the pres- :nce of maleic anhydride,
To carry out the process, the components are placed :ogether, as far as possible under anhydrous conditions, preferably in solvents which are inert under the reaction :onditions. Suitable solvents are halogenated hydrocar- DOnS, phenols, esters, ketones, ethers, substituted amides, sulphoxides and sulphones such as xylene, phenol, cresol, acetophenone, monoand dichlorobenzene, ethylene gly- :ol monomethyl ether acetate, N-methylpynrolidone, dimethylformamide, dimethylacetamide, dimethylsulphoxide and dimethylsulphone and mixtures thereof. Phenols behave as inert solvents under the reaction conditions.
The propontion of anhydride to polyisocyanate may be varied widely, provided that an excess of the polyisocyanate is added. In general, at least 1.1 equivalents, preferably 1.1 to 3 equivalents of -NCO will be used per functional group.
The reaction is carried out at temperatures of about 50 C. to about 200 C., preferably about 100 C. to 170 C., and is complete after one hour. The reaction components may be added in any sequence; for example, polyisocyanate, if desired, in solution may be put into the reaction vessel and the anhydride may be added as second reaction component or conversely.
The isocyanate groups of the resulting high molecular weight polyisocyanates which contain imide groups may be masked in known manner by reaction with compounds which can be split 01f again, for example, phenols, substituted phenols or compounds containing active methylene groups.
Polyisocyanates with any desired isocyanate content, i.e. of any desired degree of condensation may be produced depending upon the ratio of the starting components, the duration of the reaction and the reaction temperature. The high molecular Weight polyisocyanates obtained by the process described above may be isolated in known manner as free isocyanates in pure form or in solution, for example, by crystallization, precipitation or sublimation.
The products of the process may be used as adhesives or as auxiliary agents for rubber. Thus, for instance, the product of Example 8 (with free NCO groups instead of the blocked ones) can be dissolved in a solvent of equal parts of dimethyl formamide and N-methylpyrrolidone. With this solution steel plates can be sprayed and rubber sheets pressed onto the prefabricated plates which results in a strong bond between steel and rubber.
The following examples will further illustrate the process of the present invention and will describe various preferred embodiments of the present invention. Parts and percentages are by weight unless otherwise specified.
EXAMPLE 1 A solution of about 110 parts by weight of diphenylmethane-4,4'-diisocyanate and about 52.5 parts of hexamethylene-1,6-diisocyanate in about 250 parts of N- methylpyrrolidone is added dropwise to a solution of about 96 parts of trimellitic acid anhydride in about 250 parts of N-methylpyrrolidone at about 50 C. to 60 C. The mixture is heated for about 4 hours at about 120 C. in an atmosphere of nitrogen While stirring. The isocyanate content of the solution is then 1.35%. The polyisocyanate obtained is masked by reaction with about 25 parts of crude cresol. About 718 parts of a solution of the masked polyisocyanate in N-methylpyrrolidone are obtained (viscosity 2070 cp./25, solids content 33%). The masked polyisocyanate has absorption bands at 1710 and 1768 cm. in the IR spectrum, indicating an imide structure.
EXAMPLE 2 A mixture of about 65 parts of toluylene-2,4-diisocyanate and about 63 parts of hexamethylene-1,6-diisocyanate is added dropwise at about 40 C. over to minutes, to a solution of about 96 parts of trimellitic acid anhydride in about 500 parts of N-methyl-pyrrolidone. After heating the reaction mixture at about 120 C. for about 6 /2 hours, the isocyanate content is 1.5%. The polyisocyanate obtained is masked by reaction with about 30 parts of crude cresol. About 705 parts of a solution of the masked polyisocyanate in N-methylpyrrolidone are obtained (viscosity 144 cp./, solids content 34%). The masked polyisocyanate has absorption bands at 1710 and 1768 cm." in the IR spectrum, which correspond to imide groups.
EXAMPLE 3 A solution of about 281 parts of diphenylmethane-4,4- diisocyanate and about 195 parts of toluylene-2,4- and 2,6- diisocyanate in about 750 parts of N-methylpyrrolidone is added dropwise at about 50 to 60 C. to a solution of about 288 parts of trimellitic acid anhydride in about 750 parts of N-methylpyrrolidone. The reaction mixture is heated for about 1 /2 hours at about 120 C. The isocyanate content of the solution is then 1.44%. The polyisocyanate formed is masked by reaction with about 90 parts of crude cresol. About 2205 parts of a solution of the masked polyisocyanate in N-methylpyrrolidone are obtained (viscosity 425 cp./25, solids content 33%). The imide structure of the polyisocyanate is demonstrated in the IR spectrum as in Examples 1 and 2.
EXAMPLE 4 A solution of about 16.8 parts of hexamethylene-1,6- diisocyanate in about parts of N-methylpyrrolidone is added drOpWise at about 25 C. to a solution of about 9.6 parts of trimellitic acid anhydride in about parts of N-methylpyrroli-done. The reaction mixture is heated for about 2 hours at about 100 C. The solution of the polyisocyanate thus formed has an isocyanate content of 5.6%. The imide absorption bands may be observed in the IR spectrum.
EXAMPLE 5 A solution of about 25 parts of diphenylmethane-4,4'- diisocyanate in about 100 parts of dimethylformamide is added dropwise at about 25 C. to a solution of about 10.9 parts of pyromellitic acid anhydride in about 100 parts of dimethylsulphoxide. The reaction mixture is heated for about 20 minutes at about 100 C. and the solution of the polyisocyanate then has an isocyanate content of 0.73%. The IR spectrum has absorption bands at 1710 and 1770 cm." which correspond to imide groups.
EXAMPLE 6 A solution of about 38.4 parts of hexahydrodiphenyl methane-4,4-diisocyanate in about 70 parts of dimethyl formamide is added .dropwise at about to C. to a solution of about 19.2 parts of trimellitic acid anhydride in about parts of N-methylpyrrolidone. The reaction product is heated for about 3 hours at about C. The isocyanate content of the solution is then 3.15%. The bands due to the imide structure of the olyisocyanate formed may be detected in the IR spectrum.
EXAMPLE 7 A solution of about 18.3 parts of 2,4-diisopropylbenzene-1,5-diisocyanate and about 12.6 parts of hexamethylene-1,6-diisocyanate in about 50 parts of N-methylpyrrolidone is added dropwise at about 50 to 60 C. to a solution of about 19.2 parts of trimellitic acid anhydride in about 50 parts of N-methylpyrrolidone. The mixture is heated for about 5 hours at about 100 C. The solution of the polyisocyanate produced has an isocyanate content of 4.96%. The bands due to the imide groups in the polyisocyanate may be detected in the IR spectrum.
EXAMPLE 8 About 50 parts of 4,4-diisocyanate-diphenyl-methane are heated to about C. in about 250 parts of commercial dichlorobenzene and about 19.2 parts of trimel- 4. Aprocess for the preparation of polyisocyanates conlitic acid anhydride are introduced over about 30 mintaining imide groups which comprises condensing a mixutes. Carbon dioxide is evolved. After about 2 hours, ture comprising diphenyl methane-4,4'-diisocyanate, and about 22 parts of commercial cresol are added at about 2.4- and 2,6-tolylene diisocyanate with trimellitic acid an- 160 C. The solution, which is at first clear becomes 5 hydride in the presence of N-methylpyrrolidone at a temturbid after some time. perature of about 120 C.
It is maintained at about 160 C. for about 3 hours 5. The process of claim 4 wherein the imide'containand is then allowed to cool slowly, a resinous mas precipiing polyisocyanates are reacted with cresol. tates. By decanting the dichlorobenzene and triturating 6. A process for the preparation of polyisocyanates the residue with petroleum ether, a 95% yield of a yellow containing imide groups which comprises condensing dipowder, softening about 130 C. to 135 C. is obtained phenylmethane-4,4'-diisocyanate with trimellitic acid anwhich has an IR spectrum consistent wtih the supposed hydride at a temperature of about 160 C. in the presence structure of a masked imide-amide diisocyanate of the of ethylene glycol monomethyl ether acetate.
formula '7. The process of claim 6 wherein the imide containing 00*N11- CI-Iz-NHCO OCO NH @CH-@ N 2. cm i 6 EXAMPLE 9 polyisocyanates are reacted with phenol at a temperature About 19.2 parts of trimellitic acid anhydride are slowly of shout 160 added at about 160 C. to a solution of about 50 parts of The process of Glam 1 wherein the compound 4,4l diisoc anawdi h en lmethane i ab t 40 a S 0 talus acyclic canboxylic acid anhydr de and at least one ethylene g ycol m noni ethyl ether acet i e, abci ut wj hydrogen atom Capable of reactmg Wlth the N130 groups parts of phenol are added after about 1 hour. The mixq i for the prefparatmn t ture is kept at about 160 C. for about 4 hours, whereby contammg lmlde f fl which E condepimg (1.1- a yellow product is precipitamd' After cooling, the phenylmethane-4,4 -o11socyanate with pyromellitic acid solvent may be removed by suction filtration at about 50 ilnhydnde i tempeliature 9 about 100 to form an and 12 mm. Hg. Masked polyisocyanate showing evilmlde contammg polylsoqyanate dence in the infra-red spectrum of imide groups is ob- The Process clalin 1 wherein mlxture Pi tained in quantitative yield. Softening point about 180 lsocyanates mated w t compouild contammg at to 135. least one cyclic carboxyl c acid anhydride group.
EXAMPLE 10 11. The process of claim 1 conducted under substantially anhydrous conditions. About 100 parts of commercial cresol, about 50 parts 12. The process of claim 1 wherein at least one of the of diphenylmethane-4,4-diisocyanate and about 19.2 reaction components is in an inert solvent. parts of trimellitic acid anhydride are reacted together in 13- The process f claim 1 whereby said reaction is three separate experiments. In each of these expericarried out at a temperature of about 50 C. to about ments, two of the three components are mixed together 00 C- at about 160 C. and the third component is then added. 14. The process of claim 1 wherein said reaction is Cresol solutions of the imidopolyisocyanate in the form carried out at a temperature of about 100 C. to about of a product from which cresol can be split on? are ob- 170 C. tained after about 3 hours at about 160 C. The three 15. The process of claim 1 wherein said compound solutions have identical IR spectra. contains at least one cyclic carboxylic acid anhydride It is to be understood that this invention is not limited group also contains an active hydrogen containing group by the examples, but that any of the compositions menas determined by the Zerewitinoif method. tioned above as typical for use in the present invention 16. The process of claim 1 wherein said polyisocyanate may be u d in place f tho set [fo th i th am le and said anhydride are reacted in an amount whereby with imilar re ult from about 1.1 to about 3 equivalents of NCO groups Although the invention has been described in considerare present for each equivalent of the functional group able detail in the foregoing, it is to be understood that in said anhydride. such detail is solely for the purpose of illustration and that many variations can be made by those skilled in the References CHM y the Examine-f art without departing from the spirit and scope of the UNITED STATES PATENTS invention except as set forth in the claims.
2 268 586 1/l942 Gilman 260*78 What is claimed is: i a 1. A process for the preparation of polyisocyanates 2,621,168 12/1952 R0133 et 260 78 containing imide groups which comprises condensing a 2,723,265 11/1955 stalmmn 26O 77'5 carbocyclic aromatic compound having functional groups OTHER REFERENCES selected from the class consisting of hydroxyl, mercapto, amino, carboxylic acid and cyclic carboxylic acid anhydrides, said compound containing at least one cyclic carboxylic acid anhydride group with a monomeric polyisocyanate at a temperature of at least about 50 C., said polyisocyanate being used in a stoichiometric excess over Wiley & Sons Inc. New York 1953 p 568 645 675 the functional groups in said compound. 676 and 678 2. The process of claim 1 wherein the carbocyclic aromatic compound is condensed with a monomeric polyiso- WILLIAM SHORT, Primary Examflnen cyanate under substantially anhydrous conditions.
3. The process of claim 2. wherein the imide contain- NICHOLAS RIZZO Examme" ing polyisocyanates are reacted with a compound selected H D, ANDERSON, MARY U. OBRIEN, from the group consisting of phenols and cresols. Assistant Examiners Otvos et al.: Tetrahedron Letters, 1960, No. 2, pp. 15-18.
Staiger et al.: Journal of Chemical and Engineering Data, vol. 8, July 1963, pp. 454-456.
Wagner et al.: Synthetic Organic Chemistry, John

Claims (1)

1. A PROCESS FOR THE PREPARATION OF POLYISOCYANATES CONTAINING IMIDE GROUPS WHICH COMPRISES CONDENSING A CARBOCYCLIC AROMATIC COMPOUND HAVING FUNCTIONAL GROUPS SELECTED FROM THE CLASS CONSISTING OF HYDROXYL, MERCAPTO, AMINO, CARBOXYLIC ACID AND CYCLIC CARBOXYLIC ACID ANHYDRIDES, SAID COMPOUND CONTAINING AT LEAST ONE CYCLIC CARBOXYLIC ACID ANHYDRIDE GROUP WITH A MONOMERIC POLYISOCYANATE AT A TEMPERATURE OF AT LEAST ABOUT 50*C., SAID POLYISOCYANATE BEING USED IN A STOICHIOMETRIC EXCESS OVER
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Cited By (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3423354A (en) * 1965-07-27 1969-01-21 Dunlop Co Ltd Adhesive compositions
US3433771A (en) * 1965-12-02 1969-03-18 Du Pont Polyurethane adhesives based on diisocyanates and an epoxy esterdibasic acid adduct
US3479305A (en) * 1968-01-17 1969-11-18 Standard Oil Co Process for producing foams from carboxylic acid derivatives and isocyanates by water catalysis
US3489696A (en) * 1966-10-06 1970-01-13 Mobay Chemical Corp Process of preparing polyimides from isocyanates and polycarboxylic acids
US3493540A (en) * 1964-07-21 1970-02-03 Bayer Ag Polyimides which are soluble in organic solvents
US3518230A (en) * 1968-01-04 1970-06-30 Schenectady Chemical Imide modified amide imide wire enamel
US3532661A (en) * 1966-03-09 1970-10-06 Gen Constr Elect Mec Impregnating varnish for electric motors wound with wire enamelled with polyester-imide
US3541038A (en) * 1965-03-30 1970-11-17 Hitachi Chemical Co Ltd Novel polyimidamide resin
US3620996A (en) * 1967-07-05 1971-11-16 Sumitomo Electric Industries Polyester-amide-imide insulating varnish and method of preparation
US3625911A (en) * 1965-11-08 1971-12-07 Mobil Oil Corp Polyamide/imide polymer derived from trimellitic anhydride and organic diisocyanate and the enameling of wire therewith
US3669937A (en) * 1968-04-05 1972-06-13 Bayer Ag Process for the production of polyimides
US3717696A (en) * 1968-06-04 1973-02-20 Rhodiaceta Process for the preparation of polyamide-imide filaments
US3852106A (en) * 1967-06-30 1974-12-03 Du Pont Polyamide-imide polymer having an ordered structure
US3852248A (en) * 1972-03-13 1974-12-03 Standard Oil Co Film forming polyamide composition containing fumaric acid and trimellitic acid residues
US3868389A (en) * 1973-06-22 1975-02-25 Gen Electric Method for making n-substituted nitrophthalimides
US3869428A (en) * 1969-05-14 1975-03-04 Schweizerische Isolawerke Enamel composition for the manufacture of solderable enameled wires
US3875183A (en) * 1971-08-23 1975-04-01 Union Carbide Corp Process for the production of imido-isocyanates
US3884880A (en) * 1973-09-21 1975-05-20 Phelps Dodge Magnet Wire Corp Modified amide-imide resins and method of making the same
US3929691A (en) * 1968-12-30 1975-12-30 Rhodiaceta Solutions of copolymers containing amide and imide groups and process for their preparation
US3937673A (en) * 1973-09-21 1976-02-10 Phelps Dodge Industries, Inc. Modified amide-imide resins and method of making the same
US3948941A (en) * 1973-10-26 1976-04-06 Exxon Research And Engineering Company Preparation of imides using CN- catalysts
USRE29213E (en) * 1973-02-09 1977-05-10 Schenectady Chemicals, Inc. Wire enamel based on amide-imide hydantoin polymers
US4028310A (en) * 1974-07-30 1977-06-07 Bayer Aktiengesellschaft Process for the production of polyureas
US4454257A (en) * 1983-04-06 1984-06-12 The Dow Chemical Company Isocyanurate/imide cross-linked resins and foams
US8436125B2 (en) 2010-05-27 2013-05-07 Basf Se Materials, methods for production thereof and components thereof
WO2020163674A1 (en) 2019-02-08 2020-08-13 Lanxess Solutions Us Inc. Degradable urethane and urethane-urea systems
WO2023247391A1 (en) 2022-06-22 2023-12-28 Huntsman International Llc Flexible and semi-rigid polyimide comprising foams with superior heat resistance

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US2621168A (en) * 1949-09-27 1952-12-09 Sprague Electric Co Condensation resins of halogenated benzene compounds
US2723265A (en) * 1952-07-21 1955-11-08 Du Pont Doubly hindered diisocyanates

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US2268586A (en) * 1939-07-06 1942-01-06 Du Pont Preparation of polyamides
US2621168A (en) * 1949-09-27 1952-12-09 Sprague Electric Co Condensation resins of halogenated benzene compounds
US2723265A (en) * 1952-07-21 1955-11-08 Du Pont Doubly hindered diisocyanates

Cited By (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3493540A (en) * 1964-07-21 1970-02-03 Bayer Ag Polyimides which are soluble in organic solvents
US3541038A (en) * 1965-03-30 1970-11-17 Hitachi Chemical Co Ltd Novel polyimidamide resin
US3423354A (en) * 1965-07-27 1969-01-21 Dunlop Co Ltd Adhesive compositions
US3625911A (en) * 1965-11-08 1971-12-07 Mobil Oil Corp Polyamide/imide polymer derived from trimellitic anhydride and organic diisocyanate and the enameling of wire therewith
US3433771A (en) * 1965-12-02 1969-03-18 Du Pont Polyurethane adhesives based on diisocyanates and an epoxy esterdibasic acid adduct
US3532661A (en) * 1966-03-09 1970-10-06 Gen Constr Elect Mec Impregnating varnish for electric motors wound with wire enamelled with polyester-imide
US3622525A (en) * 1966-10-06 1971-11-23 Mobay Chemical Corp Polyimides and polyimide precursors
US3489696A (en) * 1966-10-06 1970-01-13 Mobay Chemical Corp Process of preparing polyimides from isocyanates and polycarboxylic acids
US3852106A (en) * 1967-06-30 1974-12-03 Du Pont Polyamide-imide polymer having an ordered structure
US3620996A (en) * 1967-07-05 1971-11-16 Sumitomo Electric Industries Polyester-amide-imide insulating varnish and method of preparation
US3518230A (en) * 1968-01-04 1970-06-30 Schenectady Chemical Imide modified amide imide wire enamel
US3479305A (en) * 1968-01-17 1969-11-18 Standard Oil Co Process for producing foams from carboxylic acid derivatives and isocyanates by water catalysis
US3669937A (en) * 1968-04-05 1972-06-13 Bayer Ag Process for the production of polyimides
US3717696A (en) * 1968-06-04 1973-02-20 Rhodiaceta Process for the preparation of polyamide-imide filaments
US3929691A (en) * 1968-12-30 1975-12-30 Rhodiaceta Solutions of copolymers containing amide and imide groups and process for their preparation
US3869428A (en) * 1969-05-14 1975-03-04 Schweizerische Isolawerke Enamel composition for the manufacture of solderable enameled wires
US3875183A (en) * 1971-08-23 1975-04-01 Union Carbide Corp Process for the production of imido-isocyanates
US3852248A (en) * 1972-03-13 1974-12-03 Standard Oil Co Film forming polyamide composition containing fumaric acid and trimellitic acid residues
USRE29213E (en) * 1973-02-09 1977-05-10 Schenectady Chemicals, Inc. Wire enamel based on amide-imide hydantoin polymers
US3868389A (en) * 1973-06-22 1975-02-25 Gen Electric Method for making n-substituted nitrophthalimides
US3884880A (en) * 1973-09-21 1975-05-20 Phelps Dodge Magnet Wire Corp Modified amide-imide resins and method of making the same
US3937673A (en) * 1973-09-21 1976-02-10 Phelps Dodge Industries, Inc. Modified amide-imide resins and method of making the same
US3948941A (en) * 1973-10-26 1976-04-06 Exxon Research And Engineering Company Preparation of imides using CN- catalysts
US4028310A (en) * 1974-07-30 1977-06-07 Bayer Aktiengesellschaft Process for the production of polyureas
US4454257A (en) * 1983-04-06 1984-06-12 The Dow Chemical Company Isocyanurate/imide cross-linked resins and foams
US8436125B2 (en) 2010-05-27 2013-05-07 Basf Se Materials, methods for production thereof and components thereof
WO2020163674A1 (en) 2019-02-08 2020-08-13 Lanxess Solutions Us Inc. Degradable urethane and urethane-urea systems
WO2023247391A1 (en) 2022-06-22 2023-12-28 Huntsman International Llc Flexible and semi-rigid polyimide comprising foams with superior heat resistance

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