US2967927A - Process for making metal particles - Google Patents

Process for making metal particles Download PDF

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US2967927A
US2967927A US762598A US76259858A US2967927A US 2967927 A US2967927 A US 2967927A US 762598 A US762598 A US 762598A US 76259858 A US76259858 A US 76259858A US 2967927 A US2967927 A US 2967927A
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wheel
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Victor P Weismann
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F9/00Making metallic powder or suspensions thereof
    • B22F9/02Making metallic powder or suspensions thereof using physical processes
    • B22F9/04Making metallic powder or suspensions thereof using physical processes starting from solid material, e.g. by crushing, grinding or milling
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T29/00Metal working
    • Y10T29/14Shredding metal or metal wool article making

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  • This invention relates to a process for producing finely divided metal particles of a relatively high degree of uniformity and of generally smooth globular configuration from solid relatively large pieces of metal.
  • the process and apparatus of the invention is usable with any fusible material having a surface tension such as to cause freefalling molten particles thereof to assume generally ovoid or globular form.
  • Fine metal particles referred to as shot or grit are used extensively in industry as abrasives for glass cleaning and for surface conditioning in a process which involves projecting such shot or grit at high velocity against a surface to be treated.
  • the invention is not concerned with this cleaning or treating process as such, and accordingly this process is not described in detail.
  • the invention is directed to method and apparatus for forming shot and grit for this and any other uses and is characterized by the formation of such material at considerably lower costs than is achieved in present practice.
  • the low cost of the product is due in part to the inherent nature of the method of its manufacture, and in part to the adaptability of the process to scrap materials of widely varying composition and configuration.
  • the process of the present invention in contrast involves feeding a relatively large piece of metal or other fusible material toward a moving heat-resistant surface and heating the metal piece at the point of proximity to the moving surface to approximately its melting point or higher.
  • the moving surface may constitute the periphery or side face of a rotating wheel or the linearly moving surface of an endless steel belt, or the like.
  • the effect of the interaction between the locally heated metallic feed member and the moving surface is to discharge a stream of metal into the ambient atmosphere for consequent formation either at the point of discharge or shortly thereafter of very small particles of relatively high degree of uniformity in size and in generally spherical shape.
  • the material produced as described may be screened or otherwise sorted into various size ranges of any desired size differential.
  • Fig. 1 is a schematic illustration of one form of apparatus for accomplishing disintegration as described
  • Fig. 2 is a partial plan view of the apparatus of Fig. 1;
  • Fig. 3 is a partial schematic view of an alternative apparatus.
  • Ice Fig. 4 is a partial schematic of still another alternative form of apparatus.
  • the apparatus there shown comprises a wheel 10 mounted for rotation on an axle 11.
  • the axle is supported between two pillow blocks 12, 13 and is connected to a motor 14 by a belt 15 traveling over a motor pulley 16 and an axle pulley 17.
  • the structure may be supported on a bed 18 and, in the embodiment shown, insulated therefrom by the insulating mounting blocks 19, 20.
  • the process depends upon the application of moderately high heat to the localized point of the feed stock 24 in proximity to the wheel surface.
  • this is accomplished by applying electrical power between the feed stock and the wheel so as to produce a localized are between the wheel surface and the proximate end of the feed.
  • This may be accomplished by fixing an armature 26 to the axle 11 and connecting this armature through a brush 27 to one side of a power source 28 and connecting the feed stock 24 to the other side of the power source 28.
  • the power source may be either DC. or AC. and among other parameters the rate of disintegration of the metal bar 24 is a function of the magnitude of the power applied to the arc.
  • Fig. 3 shows schematically a portion of apparatus similar to that of Fig. 1 including a wheel 30 mounted for rotation on an axle 31, a feed platen 32 and a feed stock 33 adapted to be moved toward the surface of the wheel 30.
  • the electrical heat source of the Fig. 1 embodiment is replaced by an external source comprising a torch 34 directed on the end of the feed stock 33 proximate to the wheel periphery.
  • the torch 34 is representative of any form of external heat application which may be accomplished through an induction coil or through a radiant heating coil disposed around the feed stock 33 in the region of approach to the wheel.
  • the object in any case is to apply to this localized portion of the stock sulficient heat to produce fusion in conjunction with the discharge thereof from the parent metal.
  • the process is dependent upon the interaction of the locally heated metal feed stock with the moving heat resistant surface, which can be also accomplished in the manner shown in Fig. 4 in which the wheel of the previous embodiments has been replaced by a moving belt 36 traveling over rollers 37, 38 which may be driven by conventional means.
  • a metal feed member 40 fed across a platen 41 is introduced against the surface of the belt 36 in the same manner as against the periphery of the wheel 10 in Fig. 1.
  • heat may be applied electrically, as indicated schematically by leads 42, by brush 43 and leads 44, or by any of the other means discussed above.
  • the process has been successfully carried out using as the feed a inch chromium nickel alloy rod, a large quantity of such rods being avail able virtually as scrap as used sucker rods from the oil industry.
  • a mild steel wheel 12 inches in diameter and approximately 2 /2 inches wide was rotated at approximately 1200 rpm. by a 5 horsepower motor.
  • An electric current of between 75 and 100 amps. was applied between the rod and the wheel with a rod consumption of approximately one inch per minute.
  • the process is exceedingly flexible relative to operating variables and applicable materials.
  • production rate increases significantly with power increase, with an increase in the linear speed of the moving surface and with the application of preheat to the feed material.
  • bronze or stainless forgings are preferred to minimize surface burning, although any relatively heat-resistant material appears to be suitable. Where are heating is used, this material of course must be conductive or at least must be provided with a conductive surface. Configuration of the moving surface is susceptible to many modifications, variations therein having effect on the particle size of the product. A smooth surface will produce a smaller product in general than will a roughened surface, and it is even possible to employ a serrated surface so as to achieve a roughly pulsed operation producing even larger particles.
  • Apparatus for producing particulate metal from a solid metal piece which comprises a wheel having a heatresistant surface, means rotating the wheel, means for feeding the solid metal piece toward the wheel surface and generally normal thereto, and means for heating substantially the entire portion of the piece approaching proximity to the wheel surface to a temperature at least approximating the melting point of the piece.
  • Apparatus for producing particulate metal from a solid metal piece which comprises a continuous belt having a heat-resistant surface, means for causing movement of the belt, means for feeding the solid metal piece toward the moving belt, and means for heating substantially the entire portion of the piece approaching proximity to the belt to a temperature at least approximating the melting point of the piece.
  • Apparatus for producing particulate metal from a solid metal piece which comprises a heat-resistant member, means for feeding the solid metal piece toward the heat-resistant member, means for moving the heat-resistant member so that a surface thereof adjacent the metal piece is displaced substantially normal relative to the motion of the metal piece, and means for striking an electric arc between the member and the piece to heat substantially the entire portion of the piece approaching proximity to the moving surface to a temperature at least approximating the melting point of the piece.
  • a process for producing finely divided metal particles from a relatively large metal piece which comprises progressively advancing the piece against a moving heatresistant surface, and heating substantially the entire end of the piece in the proximity of the moving surface to at least approximately its melting point.
  • a process for producing finely divided metal particles from an elongate metal bar which comprises progressively advancing the bar lengthwise and linearly against a heat-resistant surface, and heating substantially the entire end of the bar in the proximity of the surface to at least approximately its melting point, and moving the surface relative to the bar to place successive areas of the surface in the proximity of said end of the bar being heated.
  • a process for producing finely divided metal particles from an elongate metal bar which comprises progressively advancing the bar lengthwise against and approximately normal to a heat-resistant surface and heating substantially the entire end of the bar in the proximity of the surface to at least approximately its melting point, and moving the surface approximately normal to the direction of movement of the bar to place successive areas of the surface adjacent said end of the bar being heated.
  • a process for producing finely divided metal particles from a relatively large metal piece which comprises progressively advancing the piece against the surface of a rotating wheel and heating substantially the entire end of the piece in the proximity of the surface to at least approximately its melting point.
  • a process for producing finely divided metal particles from a relatively large metal piece which comprises progressively advancing the piece against a surface of a moving heat-resistant belt, and heating substantially the entire end of the piece in the proximity of the belt to at least approximately its melting point.
  • a process for producing finely divided metal particles from a relatively large metal piece which comprises progressively advancing the piece against a heat-resistant surface, heating substantially the entire end of the piece in the proximity of the surface to at least approximately its melting point by striking an electric are between the moving surface and the piece and moving the surface relative to the piece to place successive areas of the surface in the proximity of said end of the piece being heated.
  • a process for producing finely divided metal particles from a relatively large metal piece which comprises progressively advancing the piece against a heatresistant surface, heating substantially the entire end of the piece in the proximity of the surface by external means to at least approximately its melting point and moving the surface relative to the piece to place successive areas of the surface adjacent said end of the piece being heated.
  • Apparatus for producing particulate metal from a solid metal piece which comprises a heat-resistant member, means for feeding the solid metal piece toward a surface of the heat-resistant member, means for moving said surface approximately normal to the direction of movement of the solid metal piece, and means for heating substantially the entire portion of the piece approaching proximity to the moving surface to a temperature at least approximating the melting point of the piece.
  • a process for producing finely divided metal parts from a relatively large piece of metal which comprises progressively advancing the piece against a heat-resistant surface having an area at least as great as the area of the piece parallel to the surface, heating the piece to at least approximately its melting point at the point of proximity to the surface and moving the surface relative to the piece so that successive areas of the surface are placed in the proximity of the heated portion of the piece.
  • Apparatus for producing particulate metal from a solid metal piece which comprises a heat-resistant member, means for feeding one end of the metal piece toward a surface of the member, means for moving said surface relative to said end of the metal piece to continually place successive areas of the surface in the proximity of said one end, the heat-resistant member being arranged so that the surface area thereof in the proximity of said one end of the metal piece is always greater than the surface area of said one end of the metal piece exposed to the heat-resistant member and means for heating said end

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  • Manufacture Of Metal Powder And Suspensions Thereof (AREA)

Description

Jan. 10, 1961 Filed Sept. 22, 1958 IN VEN TOR.
United States Patent (3 2,967,927 PROCESS FOR MAKING METAL PARTICLES Victor P. Weisniann, 430 Prospect Circle, South Pasadena, Calif.
Filed Sept. 22, 1958, Ser. No. 762,598
'13 Claims. (Cl. 219-121) This invention relates to a process for producing finely divided metal particles of a relatively high degree of uniformity and of generally smooth globular configuration from solid relatively large pieces of metal. Although the invention is described relative to disintegration of metal in particulate form because of the relative importance of this aspect, it will be observed that the process and apparatus of the invention is usable with any fusible material having a surface tension such as to cause freefalling molten particles thereof to assume generally ovoid or globular form.
Fine metal particles referred to as shot or grit, depending upon size range, are used extensively in industry as abrasives for glass cleaning and for surface conditioning in a process which involves projecting such shot or grit at high velocity against a surface to be treated. The invention is not concerned with this cleaning or treating process as such, and accordingly this process is not described in detail. The invention, however, is directed to method and apparatus for forming shot and grit for this and any other uses and is characterized by the formation of such material at considerably lower costs than is achieved in present practice. The low cost of the product is due in part to the inherent nature of the method of its manufacture, and in part to the adaptability of the process to scrap materials of widely varying composition and configuration. Present techniques of shotforming involve the ejection of molten cupola metal into a high velocity stream of superheated steam with rapid quenching in a liquid bath. Another process referred to as the cut-Wire process involves shearing steel wire with a rotary cutter at very high speed.
The process of the present invention in contrast involves feeding a relatively large piece of metal or other fusible material toward a moving heat-resistant surface and heating the metal piece at the point of proximity to the moving surface to approximately its melting point or higher. The moving surface may constitute the periphery or side face of a rotating wheel or the linearly moving surface of an endless steel belt, or the like. The effect of the interaction between the locally heated metallic feed member and the moving surface is to discharge a stream of metal into the ambient atmosphere for consequent formation either at the point of discharge or shortly thereafter of very small particles of relatively high degree of uniformity in size and in generally spherical shape. Depending upon the grade of product desired by the ultimate user, the material produced as described may be screened or otherwise sorted into various size ranges of any desired size differential.
The invention will be more clearly understood by reference to the accompanying drawing, in which:
Fig. 1 is a schematic illustration of one form of apparatus for accomplishing disintegration as described;
Fig. 2 is a partial plan view of the apparatus of Fig. 1;
Fig. 3 is a partial schematic view of an alternative apparatus; and
"ice Fig. 4 is a partial schematic of still another alternative form of apparatus.
Referring to Figs. 1 and 2 of the drawing, the apparatus there shown comprises a wheel 10 mounted for rotation on an axle 11. The axle is supported between two pillow blocks 12, 13 and is connected to a motor 14 by a belt 15 traveling over a motor pulley 16 and an axle pulley 17. The structure may be supported on a bed 18 and, in the embodiment shown, insulated therefrom by the insulating mounting blocks 19, 20.
A feed platen 21 supporting feed rollers 22, 23, which may be driven by any conventional means, not shown, is supported adjacent the periphery of the wheel 10 and provides means for advancing a feed stock 24 toward the periphery of the wheel 10.
As previously noted, the process depends upon the application of moderately high heat to the localized point of the feed stock 24 in proximity to the wheel surface. In the embodiment shown in Figs. 1 and 2 this is accomplished by applying electrical power between the feed stock and the wheel so as to produce a localized are between the wheel surface and the proximate end of the feed. This may be accomplished by fixing an armature 26 to the axle 11 and connecting this armature through a brush 27 to one side of a power source 28 and connecting the feed stock 24 to the other side of the power source 28. I have found that the power source may be either DC. or AC. and among other parameters the rate of disintegration of the metal bar 24 is a function of the magnitude of the power applied to the arc.
For high speed operation in which considerable heat is developed it may be desirable to artificially cool the wheel 10. This may be accomplished by making the wheel hollow, as shown in the top sectional view of Fig. 2, permitting the flow of the cooling medium, as for example through the axle 11 which can also be made hollow, into the interior of the wheel 10. Other conventional cooling techniques can be employed.
Fig. 3 shows schematically a portion of apparatus similar to that of Fig. 1 including a wheel 30 mounted for rotation on an axle 31, a feed platen 32 and a feed stock 33 adapted to be moved toward the surface of the wheel 30. In this instance the electrical heat source of the Fig. 1 embodiment is replaced by an external source comprising a torch 34 directed on the end of the feed stock 33 proximate to the wheel periphery. The torch 34 is representative of any form of external heat application which may be accomplished through an induction coil or through a radiant heating coil disposed around the feed stock 33 in the region of approach to the wheel. The object in any case is to apply to this localized portion of the stock sulficient heat to produce fusion in conjunction with the discharge thereof from the parent metal.
The process is dependent upon the interaction of the locally heated metal feed stock with the moving heat resistant surface, which can be also accomplished in the manner shown in Fig. 4 in which the wheel of the previous embodiments has been replaced by a moving belt 36 traveling over rollers 37, 38 which may be driven by conventional means. A metal feed member 40 fed across a platen 41 is introduced against the surface of the belt 36 in the same manner as against the periphery of the wheel 10 in Fig. 1. In this embodiment heat may be applied electrically, as indicated schematically by leads 42, by brush 43 and leads 44, or by any of the other means discussed above.
By way of a specific example, the process has been successfully carried out using as the feed a inch chromium nickel alloy rod, a large quantity of such rods being avail able virtually as scrap as used sucker rods from the oil industry. A mild steel wheel 12 inches in diameter and approximately 2 /2 inches wide was rotated at approximately 1200 rpm. by a 5 horsepower motor. An electric current of between 75 and 100 amps. was applied between the rod and the wheel with a rod consumption of approximately one inch per minute.
The process is exceedingly flexible relative to operating variables and applicable materials. With respect to operating variables, production rate increases significantly with power increase, with an increase in the linear speed of the moving surface and with the application of preheat to the feed material. In this latter respect it may be desirable to pre-heat the feed material prior to the ap plication of higher intensity localized heat at the point of approach to the moving surface. This pre-heat reduces the power requirements or the localized heating requirements for a given production rate.
With respect to the moving surface, bronze or stainless forgings are preferred to minimize surface burning, although any relatively heat-resistant material appears to be suitable. Where are heating is used, this material of course must be conductive or at least must be provided with a conductive surface. Configuration of the moving surface is susceptible to many modifications, variations therein having effect on the particle size of the product. A smooth surface will produce a smaller product in general than will a roughened surface, and it is even possible to employ a serrated surface so as to achieve a roughly pulsed operation producing even larger particles.
Many materials can be disintegrated by this process including mild steel, alloys, non-metallic fusible materials such as various refractories and ceramic compositions, providing the surface tension of these materials in molten or semi-molten state is such as to result in formation of discrete particles during a free travel in the ambient atmosphere. One of the major advantages of the process is the adaptability to a wide range of feed stocks, permitting the use of low cost and even semi-scrap materials. In some instances it may be desirable to carry out the process in an inert atmosphere so as to prevent car bonization of certain feed materials such as high carbon steel.
It is apparent that the process of the invention has a wide flexibility as to the materials to which it is applicable and with respect to the parameters of operation in the production of a product of widely differing properties. Many modifications will occur from the description herein given.
I claim:
1. Apparatus for producing particulate metal from a solid metal piece which comprises a wheel having a heatresistant surface, means rotating the wheel, means for feeding the solid metal piece toward the wheel surface and generally normal thereto, and means for heating substantially the entire portion of the piece approaching proximity to the wheel surface to a temperature at least approximating the melting point of the piece.
2. Apparatus for producing particulate metal from a solid metal piece which comprises a continuous belt having a heat-resistant surface, means for causing movement of the belt, means for feeding the solid metal piece toward the moving belt, and means for heating substantially the entire portion of the piece approaching proximity to the belt to a temperature at least approximating the melting point of the piece.
3. Apparatus for producing particulate metal from a solid metal piece which comprises a heat-resistant member, means for feeding the solid metal piece toward the heat-resistant member, means for moving the heat-resistant member so that a surface thereof adjacent the metal piece is displaced substantially normal relative to the motion of the metal piece, and means for striking an electric arc between the member and the piece to heat substantially the entire portion of the piece approaching proximity to the moving surface to a temperature at least approximating the melting point of the piece.
4. A process for producing finely divided metal particles from a relatively large metal piece which comprises progressively advancing the piece against a moving heatresistant surface, and heating substantially the entire end of the piece in the proximity of the moving surface to at least approximately its melting point.
5. A process for producing finely divided metal particles from an elongate metal bar which comprises progressively advancing the bar lengthwise and linearly against a heat-resistant surface, and heating substantially the entire end of the bar in the proximity of the surface to at least approximately its melting point, and moving the surface relative to the bar to place successive areas of the surface in the proximity of said end of the bar being heated.
6. A process for producing finely divided metal particles from an elongate metal bar which comprises progressively advancing the bar lengthwise against and approximately normal to a heat-resistant surface and heating substantially the entire end of the bar in the proximity of the surface to at least approximately its melting point, and moving the surface approximately normal to the direction of movement of the bar to place successive areas of the surface adjacent said end of the bar being heated.
7. A process for producing finely divided metal particles from a relatively large metal piece which comprises progressively advancing the piece against the surface of a rotating wheel and heating substantially the entire end of the piece in the proximity of the surface to at least approximately its melting point.
8. A process for producing finely divided metal particles from a relatively large metal piece which comprises progressively advancing the piece against a surface of a moving heat-resistant belt, and heating substantially the entire end of the piece in the proximity of the belt to at least approximately its melting point.
9. A process for producing finely divided metal particles from a relatively large metal piece which comprises progressively advancing the piece against a heat-resistant surface, heating substantially the entire end of the piece in the proximity of the surface to at least approximately its melting point by striking an electric are between the moving surface and the piece and moving the surface relative to the piece to place successive areas of the surface in the proximity of said end of the piece being heated.
10. A process for producing finely divided metal particles from a relatively large metal piece which comprises progressively advancing the piece against a heatresistant surface, heating substantially the entire end of the piece in the proximity of the surface by external means to at least approximately its melting point and moving the surface relative to the piece to place successive areas of the surface adjacent said end of the piece being heated.
11. Apparatus for producing particulate metal from a solid metal piece which comprises a heat-resistant member, means for feeding the solid metal piece toward a surface of the heat-resistant member, means for moving said surface approximately normal to the direction of movement of the solid metal piece, and means for heating substantially the entire portion of the piece approaching proximity to the moving surface to a temperature at least approximating the melting point of the piece.
'12. A process for producing finely divided metal parts from a relatively large piece of metal which comprises progressively advancing the piece against a heat-resistant surface having an area at least as great as the area of the piece parallel to the surface, heating the piece to at least approximately its melting point at the point of proximity to the surface and moving the surface relative to the piece so that successive areas of the surface are placed in the proximity of the heated portion of the piece.
13. Apparatus for producing particulate metal from a solid metal piece which comprises a heat-resistant member, means for feeding one end of the metal piece toward a surface of the member, means for moving said surface relative to said end of the metal piece to continually place successive areas of the surface in the proximity of said one end, the heat-resistant member being arranged so that the surface area thereof in the proximity of said one end of the metal piece is always greater than the surface area of said one end of the metal piece exposed to the heat-resistant member and means for heating said end References Cited in the file of this patent UNITED STATES PATENTS Tilghman Dec. 10, Holz et al. Mar. 9, Wissler Feb. 6,
Rudorfi Oct. 17,
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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3122629A (en) * 1962-02-05 1964-02-25 Union Carbide Corp Consumable electrode arcless electric working
US5458754A (en) * 1991-04-22 1995-10-17 Multi-Arc Scientific Coatings Plasma enhancement apparatus and method for physical vapor deposition
US5761779A (en) * 1989-12-07 1998-06-09 Nippon Steel Corporation Method of producing fine metal spheres of uniform size
US20210146442A1 (en) * 2018-04-04 2021-05-20 Metal Powder Works, LLC System and Method for Manufacturing Powders from Ductile Materials

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US416873A (en) * 1889-12-10 Cutting metal by electricity
US1333311A (en) * 1918-03-21 1920-03-09 Fahy Process of scoring metal
US2189387A (en) * 1938-03-05 1940-02-06 Haynes Stellite Co Method of making hard compositions
US2526423A (en) * 1947-04-10 1950-10-17 Rudorff Dagobert William Apparatus and method for cutting materials

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US416873A (en) * 1889-12-10 Cutting metal by electricity
US1333311A (en) * 1918-03-21 1920-03-09 Fahy Process of scoring metal
US2189387A (en) * 1938-03-05 1940-02-06 Haynes Stellite Co Method of making hard compositions
US2526423A (en) * 1947-04-10 1950-10-17 Rudorff Dagobert William Apparatus and method for cutting materials

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3122629A (en) * 1962-02-05 1964-02-25 Union Carbide Corp Consumable electrode arcless electric working
US5761779A (en) * 1989-12-07 1998-06-09 Nippon Steel Corporation Method of producing fine metal spheres of uniform size
US5458754A (en) * 1991-04-22 1995-10-17 Multi-Arc Scientific Coatings Plasma enhancement apparatus and method for physical vapor deposition
US6139964A (en) * 1991-04-22 2000-10-31 Multi-Arc Inc. Plasma enhancement apparatus and method for physical vapor deposition
US20210146442A1 (en) * 2018-04-04 2021-05-20 Metal Powder Works, LLC System and Method for Manufacturing Powders from Ductile Materials
US11648610B2 (en) * 2018-04-04 2023-05-16 Metal Powder Works, LLC System and method for manufacturing powders from ductile materials
US20230241672A1 (en) * 2018-04-04 2023-08-03 Metal Powder Works, LLC System and Method for Manufacturing Powders from Ductile Materials
US12023731B2 (en) * 2018-04-04 2024-07-02 Metal Powder Works, LLC System and method for manufacturing powders from ductile materials

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