US2947699A

US2947699A - Non-inflammable hydraulic fluid

Info

Publication number: US2947699A
Application number: US534386A
Authority: US
Inventors: Jones I Wasson; Arnold J Morway
Original assignee: Exxon Research and Engineering Co
Current assignee: ExxonMobil Technology and Engineering Co
Priority date: 1955-09-14
Filing date: 1955-09-14
Publication date: 1960-08-02
Anticipated expiration: 1977-08-02

Description

United 1 NON-INFLAMMABLE HYDRAULIC FLUID Jones I. Wasson, Union, and Arnold J. Morway, Clark,

NJ assignors toEsso Research and Engineering Company, a corporation of Delaware No Drawing. Filed Sept. 14, 1955, Ser. No. 534,386 5 Claims. (Cl. 252-76) proposed. Some of these are of the hydrocarbon type which are advantageous for many applications but which are rather highly inflammable and unsuitable for certain uses. In industrial operation, such as the die casting of metals, for example, the control of the heavy casting machineryare operated largely by hydraulic means. The hydraulic fluids used in such controls have frequently been a source of fire and danger. For this reason there is a growing demand for noninflammable, hydraulic fluids. Glycolwater base'type fluids have been investigated to a considerable extent for this application. These fluids are not absolutely noninflammable but their resistance 'to flame is so much "greater than that of the hydrocarbon oils that they may be considered substantially noninflammable.

,On the other hand, although the flame resistant prop with the glycol-water base. Unless the thickener is compatible, the solution is unstable, the thickener tending to settle out and to interfere with proper operation of the Y fluid or the mechanism in which his used.

Furthermore,j as suggested above, water base hydraulic fluids have relatively very poor lubricating characteristics.

While hydraulic fluids are used primarily to'transmit forces through hydraulic means, they must provide lubrication for hydraulic pumps and associated mechanical parts in order topre'ventexcessive wear. The prior art hydraulic fluids of this type have been poor lubricants, on the whole. Many of them have permitted rusting of ferrous metalswhich obviously is highly objectionable. Aside from the damage done by the rust itself, the parts frequently stick, or freeze, 'so. that the operation is uncertain [and erratic; In vital hydraulic controls, such erratic o'perat ion'cannot be'tolerated at all and it is alwaysobjectionable in any'hydraulic mechanism.

It is known that certain of the long chain fatty acids and derivatives thereof have useful anti-wear and rust preventive properties when used in hydrocarbon base oils. Thus, the use of oleic acid, stearic acid, lauric acid, the

" tent Patented Aug. 2, 1960 2 corresponding fatty oils or glycerides and the like, in mineral base oils to reduce wear and also to help inhibit rust is well known. These materials, however, are sub stantially insoluble in water base hydraulic oils or fluids and are, therefore, unsuitable for use in the compositions of the present invention.

According to the present invention it has been discovered that a combination of glycol-water base fluid may be blended with a polyglycol or polyglycolether type polymeric thickener to improve viscosity and viscosity index, and a water soluble soap of an organic aliphatic acid may be used to impart the other required properties. In particular a water soluble soap, preferably an alkali metal soap of a moderately long chain aliphatic acid, shows exceptional utility as an anti-wear and anti-rust agent.

The alkali metal soaps of straight chain fatty acids of C chain length or longer are substantially insoluble in Water. The branched chain soaps, however, of acids having from at least 7 carbon atoms up to about 14 carbon atoms are soluble in water, and soaps of highly branched acids up to about C are soluble in the composi tions of this invention. They may be used to form stable blends having good wear preventing properties,

5 branched chain acids and are obtained by subjecting vated temperatures and pressures. Operable catalysts include the Well known cobalt containing catalysts, for example, cobalt, stearate, cobalt carbonyl, and the like. Pressures ranging from about 100 to about 300 atmospheres are used and a temperature in the rangeof about 200 to about 400 F. The ratio of hydrogen to carbon monoxide employed may vary betweenabout 0.5 volume to 2.0, volumes of hydrogen 'per volume of carbon monoxide. i

The olefinic starting material preferably comprises olefins having frorn 8 to 12 carbon atoms per molecule,

however, olefins having from 6 to; 24 carbon atoms may 1 be used. The olefin is carbonylated in the process and r the resulting aldehyde hasone more carbon atom the starting olefin. The process proceeds in accordance with the following equatiom 7 r V 7 RCH=CH2+CO+HZWRCHPCHFCHO V a Ron-on.

one The aldehyde resulting from the carbonylat-ion of the olefin is .then oxidized to obtain the desired branched chain acid. This reaction is brought about by subjecting the aldehyde in basic solution to the action of an oxygenating substance suchiasa; mixture ofnitrogen and oxygen (a irj)',. a material. releasing Enasc ent oxygen (KMnQ or thelike; 'Theoxidation reaction, one which is well known in the art, proceeds in accordance with the following equation:

i RCHz-CHz-CHO+[O1wROHr-CHr-(F-OH If desired, the Oxo reaction may be carried out in the presence of water in the form of vapor instead of hydrogen. The desired branched chain acid is thus ob tained directly from the x0 process. The same conditions of temperature and pressure are necessary for this reaction as for the carbonylation reaction resulting in the aldehyde as described above.

Regardless of the manner of preparing the acid for the concept of this invention it is essential only that material be a branched chain acid and that it contain from 9 to 13 carbon atoms. 7 V Y The soaps of these branched chain acids are prepared by reaction of the acid with the desired alkali metal hydroxide. Especially preferred are the sodium or potassium soaps which have excellent water solubility and thus provide clear stable solutions.

' A preferred composition consists of about 40 to 65% by weight of water, about 9 to 34% of ethylene glycol, 20 to 30% of a polyglycol or polyglycolether thickener of sufficiently high molecular weight to increase the viscosity substantially, and 0.5 to 2% of the sodium soap of Oxo or other branched chain acids of the C to C range. The potassium soaps may be substituted for the sodium soaps and the proportion of water to ethylene glycol may be varied considerably depending upon the viscosity, pour point, freezing point, or other requirements.

EXAMPLE I A fluid containing 62.9% by weight of water, 11.1% of ethylene glycol, 25% of a polymeric glycolether having a viscosity of about 90,000 S.U.S. at 100 F., sold by Union Carbide and Carbon Chemical Corp., under the trade name Ucon 75 H-90,000 1 was modified by addition of 1% of the sodium soap of a C 0x0 acid. This product had a viscosity of 290 S.U.S. at 100 F. and a viscosity index of 162.

EXAMPLE II A composition was prepared exactly as above except that 1% of sodium soap of 0,, 0x0 acid was used as the modifier. Comparative lubrication tests were made using the 4-ball wear tester wherein three ball bearings, onehalf inch in diameter, are clamped in a holding device and a fourth ball is rotated so as to bear on the first three under an applied load. This test of steel on steel was conducted at 167 F. under a 10 kg. load for one hour. In this test a glycol water base fluid containing only the polymer (no soap present) showed a wear scar diameter of 1.5 mm. after the one hour test. This is considered excessive wear. The same product containing 1% of sodium soap of C Oxo acid (Example I) showed a wear scar diameter of only 0.54 mm. which is fully equivalent to results obtained with mineral oils. The product of Example II showed only slightly higher wear, 0.67 mm. scar diameter. The blends containing the soaps also prevented rusting of steel specimens stored in the fluids for periods up to a month.

From the foregoing it is evident that the soaps are highly eifective for imparting anti-wear and anti-rust properties to the blends. Results are tabulated as follows:

A commercially available polyalkylene glycol prepared by Table I Wear Scar, Rust Test Fluid mm. in 4- Result Ball Test;

Example I 0. 54 N 0 Rust. Example II 0. 67 N 0 Rust. Fluid Without Soap 1. 50 Heavy Rust in less than 24 hours.

The quantity of soap which may be used may varywill depend upon its type, but in general about to of a polyglycol ether type thickener is preferred. These are highly suitable because of their excellent compatibility with the glycols. In some cases as little as 5% up to as much as 40% of the-thickener may be employed. A preferred thickener is the material mentioned above with a viscosity of about 90,000 S.U.S. at 100 F. However, polymeric glycol ether products with S.U.S. viscosities substantially lower than 90,000, e.g., 400 and up to as much as 200,000 S.U.S. at 100 'F., may also be '1 used. Some of the commercial products in this class in- I alkali metal soap is a sodium soap.

clude Ucon H-490, Ucon 75 H-1400, and Ucon 75 H-9150 sold by the Carbide and Carbon Chemical Corp.

. It will be understood that additional conventional modifiers such as rust inhibitors, anti-foaming agents and the i for the same inventors.

What is claimed is:

1. A composition consisting essentially of about 40 to 65% by Weight of water, about 9 to 34% by weight of ethylene glycol, about 20 to 30% by weight of a polyalkylene glycol having a viscosity at of between thus obtained.

2. A composition according to claim 1 wherein said polyalkylene glycol has a viscosity at 100 'F. of about 90,000 S.U.S.

3. A composition according to claim 2 wherein said 4. A composition according to claim 2 wherein said branched chain acid contains 13 carbon atoms.

5. A composition according to claim 2 wherein said branched chain acid contains 9 carbon atoms.

References Cited in the file of this patent UNITED STATES PATENTS 1,928,956 Tatter Oct. 3, 1933 2,553,364 Fasce May 15, 1951 2,558,030 Zisman June 26, 1951 2,602,780 Zisman et a1. July 8, 1952 2,737,497 Wasson et a1. Mar. 6, 1956 2,768,141 Langer Oct. 23, 1956

Claims

1. A COMPOSITION CONSISTING ESSENTIALLY OF ABOUT 40 TO 65% BY WEIGHT OF WATER, ABOUT 9 TO 34% BY WEIGHT OF ETHYLENE GLYCOL, ABOUT 20 TO 30% BY WEIGHT OF A POLYALKYLENE GLYCOL HAVING A VISCOSITY OF 100*F. OF BETWEEN 400 AND 200,000 S.U.S AND 0.5 TO 2.0% BY WEIGHT OF AN ALKALI METAL SOAP OF A BRANCHED CHAIN ACID CONTAINING FROM 9 TO 13 CARBON ATOMS, SAID ACID BEING PREPARED BY THE CARBONYLATION OF AN OLEFINIC HYDROCARBON HAVING FROM 8 TO 12 CARBON ATOMS WITH CARBON MONOXIDE AND HYDROGEN IN THE PRESENCE OF A COBALT CARBONYLATION CATALYST AT A TEMPERATURE OF ABOUT 200 TO ABOUT 400*F. AND AT A PRESSURE OF ABOUT 100 TO ABOUT 300 ATMOSPHERES AND THE SUBSEQUENT OXIDATION OF THE CARBONYLATED OLEFINS THUS OBTAINED.