US2368473A - Method of making abrasive articles - Google Patents

Method of making abrasive articles Download PDF

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US2368473A
US2368473A US465131A US46513142A US2368473A US 2368473 A US2368473 A US 2368473A US 465131 A US465131 A US 465131A US 46513142 A US46513142 A US 46513142A US 2368473 A US2368473 A US 2368473A
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particles
layer
blank
metal
tool
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George F Keeleric
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24DTOOLS FOR GRINDING, BUFFING OR SHARPENING
    • B24D18/00Manufacture of grinding tools or other grinding devices, e.g. wheels, not otherwise provided for
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S76/00Metal tools and implements, making
    • Y10S76/11Tungsten and tungsten carbide

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  • This invention relates to the manufacture of abrasive articles or tools employed for grinding or cutting purposes and including a base or body having a working surface formed of particles of an abrasive material, such as diamond dust,
  • the new method insuring anchoring of the particles in the working surface of the article in such manner that the article cuts cleanly, the particles are not dislodged during use, and the surface does not become clogged.
  • particles employed are preferably equidimensional, and, since the layer is substantially thinner than the greatest dimension of any particle, substantial portions of the particles will remain exposed above the layer, after the particles have thus been forced through the layer into contact with the blank.
  • a hard bonding metal is next applied to the surface of the layer, for example, by electrodeposition, to enclose the portions of the particles exposed above the layer and to build up a body of the desired thickness.
  • the blank employed is preferably made of metal and best results are obtained by the use of substantially equidimensional particles, since, regardless ofthe positions of such particles when they are forced into the metal layer to make contact with the blank, they will not be wholly embedded in the layer and portions will remain exposed for enclosure in the bonding metal.
  • equidimensional particles are available, they are somewhat more expensive than particles that the non-.equidimen-
  • the present invention is, accordingly, directed to the provision of a method by which satisfactory tools may be made by the use of non-equidimensional particles and a blank of non-conductive material, although it will be apparent that the utility of the method is-not restricted to the use of particles of any particular shape or of a blank of any particular material.
  • a suitable material which may be non-conductive, is prepared, the blank having a surface corresponding to the working surface of the tool to be produced. That surface of the blank is coated with an adhesive and while the latter is in tacky condition, particles of the abrasive, such as diamond dust, are distributed on the adhesive coating in the desired concentration. If the particles employed are non-equidimensional, they sional and their use adds somewhat to the cost to employ a blank of non-metallic material in forming the tool.
  • the coating electrostatically, so that they will be oriented and lie with their long axes normal to the coated surface.
  • metal is applied to the coating and particles to enclose the particles and build up a body of substantial thickness.
  • the body, with the particles in place, is then removed from the blank and part of the metal deposited may be removed from around the particles, if desired. After suitable finishing operations, the body will ordinarily be attached to a support or backing to complete the tool.
  • FIG. 1 is a view in side elevation of a blank which may 'be used in the practice of the new partly in section of the blank at one stage in the practice of the method;
  • FIGs. 3, 4, and 5 are fragmentary sectional views of the blank illustrating'diflerent steps in the method
  • Fig. 6 is a fragmentary sectional view through the abrasive member of a tool being made in accordance with the invention.
  • Fig. '7 is a view similar to Fig. 5 showing an alternative operation.
  • Fig. 8 is a sectional view through a com- 1pileted tool made in accordance with the inven-
  • the new method may be employed in the production of tools of various kinds" and, for purposes of explanation, the employment of the of the rotary type and it includes a base "I of dish formation formed with an opening H for receiving a shaft and a fiat circular surface I! around the edge of a concavity I13.
  • abrasive member consisting of a body of hard bonding metal II in which are embedded particles I! of abrasive material.
  • the abrasive member may include a metal lining for the concavity ll! of base "I, this lining being formed integrally with the body II.
  • the blank 16 employed in the formation of the tool shown may be made of any suitable material, .whichmay be conductive or non-conductive, and it is provided with a flat circular surface II corresponding to the surface l2 of the tool.
  • the blank is also preferably formed with a frusto-conical extension III which is of the same shape as the poncavity l3.
  • the blank is placed on a surface with its extension l8 projecting upward and a coating of adhesive material I9is' applied to the surface H.
  • the particles l of abrasive material such as diamond dust, are then distributed over the adhesive coating while the latter is still tacky.
  • the distribution of the particles may be effected in any suitable way with the particles applied in any desired concentration.
  • the particles are nonequidimensional, they are applied to the coating electrostatically, that is, by being thrown against the coating by the action of an electrostatic field. When this method is used, the particles will be oriented and lie with their long axes normal to the coated surface.
  • the adhesive coating is quite thin, only small portions of the particles are embedded therein, although, as illustrated, the particles all extend through the coating and have portions which make contact with the surface 'tion.
  • the surface of the coating is rendered electroconductive in any suitable way, as by the application of graphite or powdered metal, to form the thin conductive film 20.
  • the particles are held in place by the portions thereof which are anchored in the body 2l' of bonding metal, which may be iron, nickel, or chromium, for exam le.
  • the body ' is of substantial thickness and the particles are completely enclosed within the body, except for such portions as lie within the thin films of adhesive and conductive material, when the latter is employed.
  • After completion of the body it is removed from the blank and carries the particles with it.
  • the particles have an insufiicient exposure from the working surface of the body and some of the bonding material must be removed from around the particles in order to increase the exposure of the particles to the desired extent.
  • the metal of the body may be removed to the plane indicated by the line. 23, so that the particles have about a two-thirds exposure from the surface of the completed body It.
  • an exposure of the particles of about one-third of their length is satisfactory and, in that event, the deplating will be carried on for a shorter period of time.
  • a thin layer 24 of metal which is difierent from the hard bonding metal, is first applied to the adhesive coating to form a layer after which the bonding metal is applied over the layer to build up a body of the desired thickness.
  • the layer 24 is preferably made of copper and it may be applied by electrodeposition or by spraying.
  • the adhesive coating is first provided with .a conductive layer 20.
  • the layer 24 does notentirely enclose the particles and when it is completed, portions of the particles project above it.
  • the hard bonding metal is.
  • the body 25 with layer 2% in place is then separated from the blank and the layer may be removed, as by dissolving it in acid, by deplating, or by melting it out by heat, to cause the particles to project from the body 25 to the extent desired in the final tool. It is not necessary, although preferred, to remove the layer 24 before the tool is put in use, since the layer will be worn away during grinding operations. If the layer is not to be preliminarily removed, it
  • the abrasive member When the abrasive member has been produced as described, it will ordinarily be mounted on a base I 0 which may conveniently be made by molding a suitable plastic to the abrasive member. If the base is thus formed by molding the blank l6 can be used as a part of the mold and the base [0 can be formed while the abrasive member is still mounted on the blank. This will insure the formation of a tool which will run true.
  • the entire surface of the frusto-conical extension ill of the base will be rendered conductive at the appropriate stage in the operations and bonding metal will be deposited thereon to form a lining of the desired thickness.
  • bonding metal may be sprayed over the surface of extension 18 at the time the body I4 is built up. In either case, the lining will be integral with the body of bonding metal.
  • a method of making an abrasive tool which comprises applying a layer of. adhesive to the surface of a blank, embedding abrasive (particles in saidadhesive layer, applying metal to the layer to enclose the particles and to build up a body of substantial thickness, applying a tool base to the body while said body, the abrasive particles and the layer of adhesive still are on the blank, and thereafter removing the base and the body with the particles embedded therein from the adhesive layer.
  • a method of making, an abrasive tool which comprises applying a layer of adhesive to the surface of a blank, embedding abrasive particles in said adhesive layer, applying metal to the layer to enclose the particles and to build up a body of substantial thickness, applying a tool base to the body while said body, the abrasive particles and the layer of adhesive still are on the blank, thereafter removing the base and the body with the particles embedded therein from the adhesive layer, and removing metal from around the particles to give them the desired maximum exposure.
  • a method of. making an abrasive tool which comprisesapplying a layer of adhesive of the size and shape of the working surface of the tool to be made to the surface of a blank, embedding abrasive particles in said adhesive layer, applying metal to the adhesive coating and to the exposed portion of the particles embedded therein'to enclose the particles and to build up a body of substantial thickness, afilxing a tool base to the body while the body, the abrasive particles and the adhesive layer still are on the blank, and thereafter removing the base and the body with the particles embedded therein from the blank.
  • a method of making an abrasive tool which comprises applying a layer of adhesive of the same size and shape as the working surface of the tool to be made to the surface of a blank,
  • a method of making an abrasive tool which comprises applying a layer of adhesive of the same size and shape as the working surface of the tool to be made o the surface of a blank,
  • embeddingv abrasive particles in said adhesive coating applying metal to the particles to form a layer enclosing a portion of the particles, applying another and harder metal to the surface of the layer of the first-applied metal to enclose the portions of the particles projecting therethrough and to build up a body of substantial thickness, afilxing a tool base to the body while the adhesive layer, the particles and the applied layers of metal still are on the blank,
  • a method of making an abrasive tool which comprises applying a layer of adhesive to the surface of a blank, embedding abrasive particles in said adhesive layer, electrodepositing metal onto the layer to enclose the particles and to build up a body of substantial thickness, applying a tool base to the body while said body, the
  • abrasiveparticles and the layer of adhesive still are on the blank, and thereafter removing the base and the body with the particles embedded therein from the'adhesive layer.
  • a method of making an abrasive tool which comprises applying a. layer of adhesive of the size and shape of the working surface of the tool to be made to the surface of a blank, embedding abrasive particles in said adhesive layer, electrodepositing metal onto the adhesive coating and to the exposed portion of. the particles'embedded therein to enclose the particles and to build up .a body of substantial thickness, aiflxing a tool base to the body while the body, the
  • an abrasive particles and the adhesive layer still are onthe blank, and thereafter removing the base and the body with the particles embedded therein from, the blank.
  • a method of making an abrasive tool which comprlses'applying a layer of adhesive or the same size and shape as the working surface of the tool to be made to the surface of a blank, em-

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Polishing Bodies And Polishing Tools (AREA)

Description

Jan. 30, 1945. GVF. KEELERK 2,368,473 v METHOD OF MAKING ABRASIVE ARTICLES filed NOV. 10 1942 ATTORNEY; 1
Patented Jan. 30, 1945 UNITE o STATES PATENT OFFICE v Ms'rnon or MAK IfI Zi ZBASIVE ARTICLES 8 Claims. ('01; 51-809) This invention relates to the manufacture of abrasive articles or tools employed for grinding or cutting purposes and including a base or body having a working surface formed of particles of an abrasive material, such as diamond dust,
\ bound in place by a layer of metal in which the particles are embedded. More particularly, the
invention is concerned with a novel method for making such. articles, the new method insuring anchoring of the particles in the working surface of the article in such manner that the article cuts cleanly, the particles are not dislodged during use, and the surface does not become clogged.
In my co-pending application Serial No. 491,- 827, filed June 22, 1943, I have disclosed and claimed a method of making such abrasive tools, in the practice of which I prepare a blank having a surface of the same shape and size as the working surface of the tool to be produced. A layer of soft metal is applied to that surface of the blank in any suitable way but preferably by electrodeposition and ordinarily, the layer has a thickness equal to the desired maximum projection of the particles from the working surface of the tool. The particles are then distributed on the surface of the layer and forced'into the layer until they strike the surface of the blank. The
particles employed are preferably equidimensional, and, since the layer is substantially thinner than the greatest dimension of any particle, substantial portions of the particles will remain exposed above the layer, after the particles have thus been forced through the layer into contact with the blank. A hard bonding metal is next applied to the surface of the layer, for example, by electrodeposition, to enclose the portions of the particles exposed above the layer and to build up a body of the desired thickness.
In the practice of the method of the co-pending application, the blank employed is preferably made of metal and best results are obtained by the use of substantially equidimensional particles, since, regardless ofthe positions of such particles when they are forced into the metal layer to make contact with the blank, they will not be wholly embedded in the layer and portions will remain exposed for enclosure in the bonding metal. Although such equidimensional particles are available, they are somewhat more expensive than particles that the non-.equidimen- The present invention is, accordingly, directed to the provision of a method by which satisfactory tools may be made by the use of non-equidimensional particles and a blank of non-conductive material, although it will be apparent that the utility of the method is-not restricted to the use of particles of any particular shape or of a blank of any particular material.
In the practice of the new method, a blank of.
a suitable material, which may be non-conductive, is prepared, the blank having a surface corresponding to the working surface of the tool to be produced. That surface of the blank is coated with an adhesive and while the latter is in tacky condition, particles of the abrasive, such as diamond dust, are distributed on the adhesive coating in the desired concentration. If the particles employed are non-equidimensional, they sional and their use adds somewhat to the cost to employ a blank of non-metallic material in forming the tool.
are applied to the coating electrostatically, so that they will be oriented and lie with their long axes normal to the coated surface. After the adhesive coating has set, metal is applied to the coating and particles to enclose the particles and build up a body of substantial thickness. The body, with the particles in place, is then removed from the blank and part of the metal deposited may be removed from around the particles, if desired. After suitable finishing operations, the body will ordinarily be attached to a support or backing to complete the tool.
For a better understanding of the invention, reference may be had to the accompanying drawing in which Fig. 1 is a view in side elevation of a blank which may 'be used in the practice of the new partly in section of the blank at one stage in the practice of the method;
Figs. 3, 4, and 5 are fragmentary sectional views of the blank illustrating'diflerent steps in the method;
Fig. 6 is a fragmentary sectional view through the abrasive member of a tool being made in accordance with the invention;
Fig. '7 is a view similar to Fig. 5 showing an alternative operation; and
Fig. 8 is a sectional view through a com- 1pileted tool made in accordance with the inven- The new method may be employed in the production of tools of various kinds" and, for purposes of explanation, the employment of the of the rotary type and it includes a base "I of dish formation formed with an opening H for receiving a shaft and a fiat circular surface I! around the edge of a concavity I13. On the surface I2 is mounted an abrasive member consisting of a body of hard bonding metal II in which are embedded particles I! of abrasive material. If desired, the abrasive member may include a metal lining for the concavity ll! of base "I, this lining being formed integrally with the body II.
The blank 16 employed in the formation of the tool shown may be made of any suitable material, .whichmay be conductive or non-conductive, and it is provided with a flat circular surface II corresponding to the surface l2 of the tool. The blank is also preferably formed with a frusto-conical extension III which is of the same shape as the poncavity l3.
In practicing the new method, the blank is placed on a surface with its extension l8 projecting upward and a coating of adhesive material I9is' applied to the surface H. The particles l of abrasive material, such as diamond dust, are then distributed over the adhesive coating while the latter is still tacky. The distribution of the particles may be effected in any suitable way with the particles applied in any desired concentration. When the particles are nonequidimensional, they are applied to the coating electrostatically, that is, by being thrown against the coating by the action of an electrostatic field. When this method is used, the particles will be oriented and lie with their long axes normal to the coated surface. As the adhesive coating is quite thin, only small portions of the particles are embedded therein, although, as illustrated, the particles all extend through the coating and have portions which make contact with the surface 'tion. When electrodeposition is used, the surface of the coating is rendered electroconductive in any suitable way, as by the application of graphite or powdered metal, to form the thin conductive film 20.
In the completed tool, the particles are held in place by the portions thereof which are anchored in the body 2l' of bonding metal, which may be iron, nickel, or chromium, for exam le. The body 'is of substantial thickness and the particles are completely enclosed within the body, except for such portions as lie within the thin films of adhesive and conductive material, when the latter is employed. After completion of the body, it is removed from the blank and carries the particles with it. At this stage, the particles have an insufiicient exposure from the working surface of the body and some of the bonding material must be removed from around the particles in order to increase the exposure of the particles to the desired extent. For this pur pose, such portions of the adhesive and conductive coatings as have remained in place during the separation of the bodyfrom the blank are removed to expose the hard metal between the particles. That metal may then be conveniently removed by deplating, that is, by mounting the body in an electrolytic cell with the body connected as the anode. The depleting is continued to produce such exposure of the particles as may .desired thickness.
be appropriate with reference to the use to which the tool is to be put and, for example, in the production of atool to be used on ceramics, the metal of the body may be removed to the plane indicated by the line. 23, so that the particles have about a two-thirds exposure from the surface of the completed body It. In tools to be used in metal operations, an exposure of the particles of about one-third of their length is satisfactory and, in that event, the deplating will be carried on for a shorter period of time.
In Fig. 7, there is illustrated a stage in an alternative method, according to which a thin layer 24 of metal, which is difierent from the hard bonding metal, is first applied to the adhesive coating to form a layer after which the bonding metal is applied over the layer to build up a body of the desired thickness. The layer 24 is preferably made of copper and it may be applied by electrodeposition or by spraying. When the layer is applied by electrodeposition, the adhesive coating is first provided with .a conductive layer 20. The layer 24 does notentirely enclose the particles and when it is completed, portions of the particles project above it. The hard bonding metal is. applied over layer 24 by spraying or electrodeposition to enclose the exposed portions of the particles and build up a body 24 of the The body 25 with layer 2% in place is then separated from the blank and the layer may be removed, as by dissolving it in acid, by deplating, or by melting it out by heat, to cause the particles to project from the body 25 to the extent desired in the final tool. It is not necessary, although preferred, to remove the layer 24 before the tool is put in use, since the layer will be worn away during grinding operations. If the layer is not to be preliminarily removed, it
is preferably made of metal which is relatively brittle and will beworn away rapidly in service.
When the abrasive member has been produced as described, it will ordinarily be mounted on a base I 0 which may conveniently be made by molding a suitable plastic to the abrasive member. If the base is thus formed by molding the blank l6 can be used as a part of the mold and the base [0 can be formed while the abrasive member is still mounted on the blank. This will insure the formation of a tool which will run true.
If it is desired to provide the concavity I3 of the base in with a liner, the entire surface of the frusto-conical extension ill of the base will be rendered conductive at the appropriate stage in the operations and bonding metal will be deposited thereon to form a lining of the desired thickness. Alternatively, bonding metal may be sprayed over the surface of extension 18 at the time the body I4 is built up. In either case, the lining will be integral with the body of bonding metal.
I claim:
l. A method of making an abrasive tool which comprises applying a layer of. adhesive to the surface of a blank, embedding abrasive (particles in saidadhesive layer, applying metal to the layer to enclose the particles and to build up a body of substantial thickness, applying a tool base to the body while said body, the abrasive particles and the layer of adhesive still are on the blank, and thereafter removing the base and the body with the particles embedded therein from the adhesive layer.
2. A method of making, an abrasive tool which comprises applying a layer of adhesive to the surface of a blank, embedding abrasive particles in said adhesive layer, applying metal to the layer to enclose the particles and to build up a body of substantial thickness, applying a tool base to the body while said body, the abrasive particles and the layer of adhesive still are on the blank, thereafter removing the base and the body with the particles embedded therein from the adhesive layer, and removing metal from around the particles to give them the desired maximum exposure.
3 A method of. making an abrasive tool which comprisesapplying a layer of adhesive of the size and shape of the working surface of the tool to be made to the surface of a blank, embedding abrasive particles in said adhesive layer, applying metal to the adhesive coating and to the exposed portion of the particles embedded therein'to enclose the particles and to build up a body of substantial thickness, afilxing a tool base to the body while the body, the abrasive particles and the adhesive layer still are on the blank, and thereafter removing the base and the body with the particles embedded therein from the blank.
4. A method of making an abrasive tool which comprises applying a layer of adhesive of the same size and shape as the working surface of the tool to be made to the surface of a blank,
embedding abrasive particles in said adhesive coating, applying metal to the" particles to form a layer enclosing a portion of the particles, applying another and harder metal to the surface of the layer of the first-applied metal to enclose the portions of the particles projecting therethrough and to build up a body of substantial thickness, aflixing a tool base to the body while the adhesive layer, the particles and the applied layers of metal still are on the blank,
- and thereafter separating the base, the body with the particles embedded therein and the first-applied metal layer from the blank.
5. A method of making an abrasive tool which comprises applying a layer of adhesive of the same size and shape as the working surface of the tool to be made o the surface of a blank,
embeddingv abrasive particles in said adhesive coating, applying metal to the particles to form a layer enclosing a portion of the particles, applying another and harder metal to the surface of the layer of the first-applied metal to enclose the portions of the particles projecting therethrough and to build up a body of substantial thickness, afilxing a tool base to the body while the adhesive layer, the particles and the applied layers of metal still are on the blank,
5 thereafter separating the base, the body with the particles embedded therein and the first-applied metal layer from the blank, and thereafter r moving the layer of first applied metal.
6. A method of making an abrasive tool which comprises applying a layer of adhesive to the surface of a blank, embedding abrasive particles in said adhesive layer, electrodepositing metal onto the layer to enclose the particles and to build up a body of substantial thickness, applying a tool base to the body while said body, the
abrasiveparticles and the layer of adhesive still are on the blank, and thereafter removing the base and the body with the particles embedded therein from the'adhesive layer.
7. A method of making an abrasive tool which comprises applying a. layer of adhesive of the size and shape of the working surface of the tool to be made to the surface of a blank, embedding abrasive particles in said adhesive layer, electrodepositing metal onto the adhesive coating and to the exposed portion of. the particles'embedded therein to enclose the particles and to build up .a body of substantial thickness, aiflxing a tool base to the body while the body, the
an abrasive particles and the adhesive layer still are onthe blank, and thereafter removing the base and the body with the particles embedded therein from, the blank. Y
8. A method of making an abrasive tool which comprlses'applying a layer of adhesive or the same size and shape as the working surface of the tool to be made to the surface of a blank, em-
' bedding abrasive particles in said adhesive coating, applying metal to the particles to form a 40 layer enclosing a portion of the particles, electrodepositing another and harder metal onto the surface of the layer of the first-applied metal to enclose the portions of the particles projecting therethrough and to build up a body of substantial thickness, a tool base to the body while the adhesive layer, the particles and the applied layers of metal still are on the blank, and thereafter separating the base, the body with the particles embedded therein and the first-applied metal layer from the blank. I
' GEORGE 1".
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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2457156A (en) * 1946-01-12 1948-12-28 Jones John Paul Method of manufacturing diamond studded tools
US2545676A (en) * 1948-06-03 1951-03-20 Service Diamond Tool Company Diamond impregnated dressing tool
US2785060A (en) * 1952-10-15 1957-03-12 George F Keeleric Process for making abrasive article
US2799980A (en) * 1953-11-25 1957-07-23 George F Keeleric Grinding wheel assembly
US2820746A (en) * 1953-11-25 1958-01-21 George F Keeleric Method of making an abrasive tool
US3168387A (en) * 1959-11-17 1965-02-02 Donald R Adams Abrasives
US3295941A (en) * 1963-06-26 1967-01-03 Du Pont Diamond reinforced coatings and method of preparing same
US3343932A (en) * 1963-10-03 1967-09-26 Juillerat Henri Method for making a diamond-carrying tool
US3440774A (en) * 1963-05-13 1969-04-29 Naradi Narodni Podnik Diamond tool
US3517464A (en) * 1968-03-19 1970-06-30 Budd Co Method of making abrasive tools by electro-deposition

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2457156A (en) * 1946-01-12 1948-12-28 Jones John Paul Method of manufacturing diamond studded tools
US2545676A (en) * 1948-06-03 1951-03-20 Service Diamond Tool Company Diamond impregnated dressing tool
US2785060A (en) * 1952-10-15 1957-03-12 George F Keeleric Process for making abrasive article
US2799980A (en) * 1953-11-25 1957-07-23 George F Keeleric Grinding wheel assembly
US2820746A (en) * 1953-11-25 1958-01-21 George F Keeleric Method of making an abrasive tool
US3168387A (en) * 1959-11-17 1965-02-02 Donald R Adams Abrasives
US3440774A (en) * 1963-05-13 1969-04-29 Naradi Narodni Podnik Diamond tool
US3295941A (en) * 1963-06-26 1967-01-03 Du Pont Diamond reinforced coatings and method of preparing same
US3343932A (en) * 1963-10-03 1967-09-26 Juillerat Henri Method for making a diamond-carrying tool
US3517464A (en) * 1968-03-19 1970-06-30 Budd Co Method of making abrasive tools by electro-deposition

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