US20150251396A1 - Method and apparatus for temporary bonding of ultra thin wafers - Google Patents
Method and apparatus for temporary bonding of ultra thin wafers Download PDFInfo
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- US20150251396A1 US20150251396A1 US14/714,587 US201514714587A US2015251396A1 US 20150251396 A1 US20150251396 A1 US 20150251396A1 US 201514714587 A US201514714587 A US 201514714587A US 2015251396 A1 US2015251396 A1 US 2015251396A1
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- adhesive layer
- wafer
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- cured
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Images
Classifications
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- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/0046—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by constructional aspects of the apparatus
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
- B32B37/1284—Application of adhesive
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/14—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
- B32B37/16—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with all layers existing as coherent layers before laminating
- B32B37/18—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with all layers existing as coherent layers before laminating involving the assembly of discrete sheets or panels only
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- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02002—Preparing wafers
- H01L21/02005—Preparing bulk and homogeneous wafers
- H01L21/02008—Multistep processes
- H01L21/0201—Specific process step
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- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/20—Deposition of semiconductor materials on a substrate, e.g. epitaxial growth solid phase epitaxy
- H01L21/2003—Deposition of semiconductor materials on a substrate, e.g. epitaxial growth solid phase epitaxy characterised by the substrate
- H01L21/2007—Bonding of semiconductor wafers to insulating substrates or to semiconducting substrates using an intermediate insulating layer
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- H01L21/67005—Apparatus not specifically provided for elsewhere
- H01L21/67011—Apparatus for manufacture or treatment
- H01L21/67092—Apparatus for mechanical treatment
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- H—ELECTRICITY
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- H01L21/683—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping
- H01L21/6835—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping using temporarily an auxiliary support
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- H01L21/683—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping
- H01L21/6835—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping using temporarily an auxiliary support
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- H01L2221/683—Apparatus for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components; Apparatus not specifically provided for elsewhere for supporting or gripping
- H01L2221/68304—Apparatus for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components; Apparatus not specifically provided for elsewhere for supporting or gripping using temporarily an auxiliary support
- H01L2221/68318—Auxiliary support including means facilitating the separation of a device or wafer from the auxiliary support
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- H01L2221/683—Apparatus for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components; Apparatus not specifically provided for elsewhere for supporting or gripping
- H01L2221/68304—Apparatus for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components; Apparatus not specifically provided for elsewhere for supporting or gripping using temporarily an auxiliary support
- H01L2221/68327—Apparatus for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components; Apparatus not specifically provided for elsewhere for supporting or gripping using temporarily an auxiliary support used during dicing or grinding
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- H—ELECTRICITY
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- H01L2221/683—Apparatus for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components; Apparatus not specifically provided for elsewhere for supporting or gripping
- H01L2221/68304—Apparatus for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components; Apparatus not specifically provided for elsewhere for supporting or gripping using temporarily an auxiliary support
- H01L2221/6834—Apparatus for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components; Apparatus not specifically provided for elsewhere for supporting or gripping using temporarily an auxiliary support used to protect an active side of a device or wafer
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- H01L2221/68304—Apparatus for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components; Apparatus not specifically provided for elsewhere for supporting or gripping using temporarily an auxiliary support
- H01L2221/68381—Details of chemical or physical process used for separating the auxiliary support from a device or wafer
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T156/00—Adhesive bonding and miscellaneous chemical manufacture
- Y10T156/17—Surface bonding means and/or assemblymeans with work feeding or handling means
Definitions
- the present invention relates to a method and an apparatus for temporary bonding of ultra thin wafers, and more particularly to temporary wafer bonding that includes a dual coating and dual curing process.
- wafer thinning steps include wafer thinning steps.
- the wafers are thinned down to a thickness of less than 100 micrometers for the fabrication of integrated circuit (IC) devices.
- Thin wafers have the advantages of improved heat removal and better electrical operation of the fabricated IC devices.
- GaAs wafers are thinned down to 25 micrometers to fabricate power complementary metal oxide semiconductor (CMOS) devices with improved heat removal.
- CMOS complementary metal oxide semiconductor
- Wafer thinning also contributes to a reduction of the device capacitance and to an increase of its impedance, both of which result in an overall size reduction of the fabricated device.
- wafer thinning is used for 3D-Integration bonding and for fabricating through wafer vias.
- Wafer thinning is usually performed via back-grinding and/or chemical mechanical polishing (CMP).
- CMP involves bringing the wafer surface into contact with a hard and flat rotating horizontal platter in the presence of liquid slurry.
- the slurry usually contains abrasive powders, such as diamond or silicon carbide, along with chemical etchants such as ammonia, fluoride, or combinations thereof.
- the abrasives cause substrate thinning, while the etchants polish the substrate surface at the submicron level.
- the wafer is maintained in contact with the abrasives until a certain amount of substrate has been removed in order to achieve a targeted thickness.
- the wafer For wafer thicknesses of over 200 micrometers, the wafer is usually held in place with a fixture that utilizes a vacuum chuck or some other means of mechanical attachment.
- a fixture that utilizes a vacuum chuck or some other means of mechanical attachment.
- it becomes increasingly difficult to mechanically hold the wafers and to maintain control of the planarity and integrity of the wafers during thinning In these cases, it is actually common for wafers to develop microfractures and to break during CMP.
- An alternative to mechanical holding of the wafers during thinning involves attaching a first surface of the device wafer (i.e., wafer processed into a device) onto a carrier wafer and then thinning down the exposed opposite device wafer surface.
- the bond between the carrier wafer and the device wafer is temporary and is removed upon completion of the thinning and any other processing steps.
- Several temporary bonding techniques have been suggested including using of adhesive compounds that are thermally cured.
- adhesive based temporary bonding techniques a wet thick adhesive layer is applied onto the device wafer surface so that it covers all the structures of the device wafer surface including solder bumps, connectors, and integrated circuit (IC) devices.
- the wet adhesive layer has a typical thickness in the range of in the range of 25 to 150 micrometers.
- the wet adhesive layer is then brought into contact with the carrier wafer surface and the adhesive is then cured thereby resulting in bonding the device wafer to the carrier wafer.
- the bond is temporary and can be removed by dissolving the adhesive layer after processing by using chemicals, heat or radiation.
- the thick adhesive layer causes high total thickness variations (TTV) in the wafer surface planarity.
- TTV total thickness variations
- a primary TTV influence comes from the post-join thermal curing process.
- the thickness of the post-join adhesive layer directly correlates to the TTV error magnitude.
- a thick wet adhesive layer increases the risk of “squeezing-out” of the adhesive from the sides during the wafer joining step in the uncured state. Accordingly, it is desirable to reduce the thickness of the adhesive layer that is used for temporary bonding of thinned wafers.
- the present invention relates to a method and an apparatus for temporary bonding and fabrication of ultra thin wafers, and more particularly to temporary wafer bonding that includes a dual coating and dual curing process.
- the invention features a method for temporary bonding two wafer surfaces including the following. First providing a first wafer comprising first and second wafer surfaces opposite to each other. Next, providing a second wafer comprising first and second wafer surfaces opposite to each other. Next, applying a first adhesive layer upon the first surface of the first wafer. Next, curing the first adhesive layer, thereby producing a cured first adhesive layer. Next, applying a second adhesive layer upon the first surface of the second wafer. Next, providing a bonder module comprising an upper chuck assembly and a lower chuck assembly arranged below and opposite the upper chuck assembly.
- Implementations of this aspect of the invention may include one or more of the following features.
- the second adhesive layer is cured by bringing a hot plate in contact with the second surface of the second wafer.
- the first adhesive layer is applied upon the first surface of the first wafer via spin coating.
- the first adhesive layer comprises a silicone elastomer.
- the curing of the first and second adhesive layers occurs at a curing temperature in the range of 80° C. to 160° C. and a curing time in the range of 1-15 minutes.
- the upper and lower chuck assemblies comprise low force upper and lower chucks, respectively, and the second adhesive layer is brought in contact with the cured first adhesive layer by first evacuating the bonder module and then bringing the bonder module to atmospheric pressure via purging.
- the method further includes curing the temporary bonded first and second wafers.
- the curing of the temporary bonded first and second wafers occurs at a curing temperature in the range of 120° C. to 220 ° C. and a curing time in the range of 1 to 15 minutes.
- the method further includes thinning the second surface of the first wafer and then debonding the thinned first wafer from the second wafer.
- the invention features an apparatus for temporary bonding two wafer surfaces including a first coating chamber, a second coating chamber, a curing chamber and a bonder module.
- the first coating chamber is configured to apply a first adhesive layer upon a first surface of a first wafer.
- the second coating chamber is configured to apply a second adhesive layer upon a first surface of a second wafer.
- the curing chamber is configured to cure the first adhesive layer of the first wafer.
- the bonder module includes an upper chuck assembly and a lower chuck assembly arranged below and opposite the upper chuck assembly.
- the upper chuck assembly is configured to hold the first wafer so that its first surface with the cured first adhesive layer faces down.
- the lower chuck assembly is configured to hold the second wafer so that the second adhesive layer faces up and is opposite to the cured first adhesive layer.
- the lower chuck assembly is configured to move upwards and thereby to bring the second adhesive layer in contact with the cured first adhesive layer.
- the curing chamber is further configured to cure the second adhesive layer by bringing a hot plate in contact with a second surface of the second wafer, thereby forming a temporary bond between the first and second wafers.
- the upper and lower chuck assemblies comprise low force upper and lower chucks, respectively, and the second adhesive layer is brought in contact with the cured first adhesive layer by first evacuating the bonder module and then bringing the bonder module to atmospheric pressure via purging.
- the invention features a method for temporary bonding two wafer surfaces including the following. Providing a first wafer comprising first and second wafer surfaces opposite to each other. Providing a second wafer comprising first and second wafer surfaces opposite to each other. Applying a first adhesive layer upon the first surface of the first wafer. Next, curing the first adhesive layer, thereby producing a cured first adhesive layer. Next, applying a second adhesive layer upon the cured first adhesive layer.
- Providing a bonder module comprising an upper chuck assembly and a lower chuck assembly arranged below and opposite the upper chuck assembly.
- the invention features an apparatus for temporary bonding two wafer surfaces including a first coating chamber, a curing chamber, a second coating chamber and a bonder module.
- the first coating chamber is configured to apply a first adhesive layer upon a first surface of a first wafer.
- the curing chamber is configured to cure the first adhesive layer of the first wafer, thereby producing a first cured adhesive layer.
- the second coating chamber is configured to apply a second adhesive layer upon the first cured adhesive layer.
- the bonder module comprises an upper chuck assembly and a lower chuck assembly arranged below and opposite the upper chuck assembly.
- the upper chuck assembly is configured to hold the first wafer so that its first surface with the cured first adhesive layer and the second adhesive layer faces down.
- the lower chuck assembly is configured to hold a second wafer so that a first surface of the second wafer faces up and is opposite to the second adhesive layer.
- the lower chuck assembly is configured to move upwards and thereby to bring the first surface of the second wafer in contact with the second adhesive layer.
- the curing chamber is further configured to cure the second adhesive layer, thereby forming a temporary bond between the first and second wafers.
- the invention features a method for temporary bonding two wafer surfaces including the following. Providing a first wafer comprising first and second wafer surfaces opposite to each other. Providing a second wafer comprising first and second wafer surfaces opposite to each other. Applying a first adhesive layer upon the first surface of the first wafer. Next, curing the first adhesive layer, thereby producing a cured first adhesive layer. Next, applying a second adhesive layer upon the first surface of the second wafer. Providing a bonder module comprising an upper chuck assembly and a lower chuck assembly arranged below and opposite the upper chuck assembly. Next, inserting the first wafer into the bonder module and placing the first wafer upon the lower chuck assembly so that its first surface with the cured first adhesive layer faces up.
- the invention features a method for temporary bonding two wafer surfaces including the following. Providing a first wafer comprising first and second wafer surfaces opposite to each other. Providing a second wafer comprising first and second wafer surfaces opposite to each other. Applying a first adhesive layer upon the first surface of the first wafer. Next, curing the first adhesive layer, thereby producing a cured first adhesive layer. Next, applying a second adhesive layer upon the first surface of the second wafer. Next, bringing the first adhesive layer in contact with the second adhesive layer. Finally, curing the second adhesive layer, thereby forming a temporary bond between the first and second wafers.
- FIG. 1A is a schematic diagram of first example of a temporary wafer bonding process and a debonding process
- FIG. 1B is a schematic diagram of second example of a temporary wafer bonding process and a debonding process
- FIG. 2 depicts a schematic cross-sectional view of a bonder and a list of the process steps for performing the temporary wafer bonding process of FIG. 1A and FIG. 1B ;
- FIG. 3 depicts a schematic cross-sectional side view of the laser debonding step of FIG. 1A ;
- FIG. 4 depicts a schematic cross-sectional side view of the mechanical debonding step of FIG. 1A and FIG. 1B ;
- FIG. 5 is a schematic diagram of the detaping process of FIG. 1A and FIG. 1B ;
- FIG. 6A and FIG. 6B are schematic diagrams of the dual coat and dual cure temporary bonding process, according to this invention.
- FIG. 7 depicts post bond TTV results achieved with the dual coat and dual cure temporary bonding process, according to this invention.
- FIG. 8 is an overview block diagram of the dual coat and dual cure temporary bonder system according to this invention.
- temporary bond process 80 a includes the following steps. First, a surface of the device wafer 20 is coated with an adhesive layer 23 ( 82 ). In one example, adhesive layer 23 is a UV curable adhesive LC3200TM, manufactured by 3M Company, MN, USA. The adhesive coated device wafer is then flipped ( 84 ). Next, a light absorbing release layer 33 is spin coated on a surface 30 a of the carrier wafer 30 ( 86 ). In one example, light absorbing release layer 33 is a LC4000, manufactured by 3M Company, MN, USA.
- the flipped device wafer 20 is aligned with the carrier wafer 30 so that the surface 20 a of the device wafer with the adhesive layer 23 is opposite to the surface 30 a of the carrier wafer 30 with the light absorbing release layer 33 .
- the two surfaces 20 a and 30 a are brought into contact and the adhesive layer 23 is cured with UV light ( 87 ).
- the two wafers are bonded ( 88 ) in temporary bonder 410 , shown in FIG. 2 .
- the bond is a temporary bond between the light absorbing release layer 33 and the adhesive layer 23 and is formed under vacuum of 0.1 mbar and low applied bond force.
- the carrier wafer 30 with the laser absorbing release layer LTHC layer 33 is placed on the top chuck 412 and held in place by holding pins 413 .
- the device wafer 20 is placed on the bottom chuck 414 with the adhesive layer 23 facing up.
- the wafers 20 , 30 are aligned, the chamber is evacuated, and the top chuck 412 with the carrier wafer 30 is dropped onto the device wafer 20 .
- a low force is applied for the formation of the bond between the release layer 33 and the adhesive layer 23 .
- the bonded wafer stack 10 is unloaded and the adhesive is cured with UV light.
- the carrier wafer 30 is placed on the bottom chuck 414 and the device wafer 20 is placed on the top chuck 412 .
- the adhesive layer is thermally cured by bringing the wafers in contact with a hot plate or via thermal radiation.
- the temporary bonded wafer stack 10 is placed in a CMP chamber and the back surface of the device wafer 20 is thinned via CMP. After the thinning process, the wafer stack 10 is debonded via the debond process 80 b.
- the debond process 80 b includes the following steps.
- the bonded wafer stack 10 is mounted onto a dicing frame 25 ( 56 ) and the carrier wafer 30 is illuminated with a YAG laser beam, as shown in FIG. 3 .
- the laser beam causes the separation of the wafer stack along the release layer 33 ( 57 ) and the separated carrier wafer 30 is mechanically lifted away from the device wafer 20 ( 58 ) by pushing edge 31 away, as shown in FIG. 4 .
- the laser debonding process is a low stress process that utilizes no chemicals and is carried out at room temperature.
- the mechanical debonding process utilizes very low force. After separation the carrier is recycled, cleaned and reused again.
- the mechanical debonding operation is described in co-pending application Ser.
- detaping tape 155 is applied on top of the exposed adhesive layer 23 .
- detaping tape 155 is tape 3305 manufactured by 3M Company.
- Tape 3305 is a transparent polyester film tape with an aggressive rubber adhesive specifically designed for the removal of silicon backgrinding tape.
- the detaping tape 155 is pressed onto and attached to the adhesive layer 23 and when the tape 155 is peeled away the adhesive layer 155 is also peeled away from the surface 20 a of the device wafer 20 .
- Chemical cleaning may be used to remove any remaining adhesive residue from the device wafer surface 20 a .
- the adhesive residue levels on the device wafer 20 after the removal of the adhesive layer 23 with the detaping process 150 are minimal and usually no post-peel cleaning is required. Removal of the adhesive layer with the detaping process creates very little stress to the thinned wafer and is compatible with low-k dielectrics.
- the temporary bonding process 80 c includes the following steps. First, the device wafer 20 is coated with a very thin layer 21 of a precursor which subsequently is transformed to a “release layer” 21 a via a plasma enhanced chemical vapor deposition process (PECVD). The total thickness of the finished “release layer” 21 is around 100 nm. Low plasma energy of about 10 Watts keeps the wafer at room temperature. By varying the plasma parameters the adhesion force of the release layer 21 can be modified. In the next step, the carrier wafer 30 is spin-coated with a thicker layer 23 of an elastomer in order to cover any topography of the device wafer.
- PECVD plasma enhanced chemical vapor deposition process
- Layer thicknesses from about 60 ⁇ m up to 200 ⁇ m are possible within one coating step.
- the elastomer is a liquid, highly viscose material.
- the mechanical properties of the elastomer after bonding and curing allow the grinding wheel to back grind the elastomer outside the wafer rim as well.
- the device wafer 20 is bonded to the carrier wafer 30 using the above described low force bonding process. Both samples are placed into the bond chamber 410 in a center-to-center aligned position with a separation from each other of about 10 mm.
- the device wafer 20 is coated with the very thin release layer 21 of about 100 nm thickness and the carrier wafer 30 is coated with the much thicker elastomer 23 (approximately 100 ⁇ m).
- the elastomer 23 at this point in time is still liquid, forming an edge bead of some 10 ⁇ m at the outer rim of the carrier wafer.
- the bonded wafer stack 10 is thinned via CMP and then the thinned device wafer 20 is debonded from the carrier wafer 30 .
- de-bonding is done in a purely mechanical way.
- the wafer stack 10 is mounted to a dicing tape which is held on a dicing frame with the thinned wafer side being adhered to the tape.
- a flat, porous plate the thinned wafer mounted onto the tape is sucked down by vacuum.
- This assembly keeps the sensitive thinned wafer in a fixed, flat and very stable position.
- the carrier wafer 30 can be taken off by lifting it from one side, as shown in FIG. 1B .
- the adhesive layer 23 is thick (in the range of 25 to 150 micrometers) and this causes high total thickness variations (TTV) in the device wafer surface planarity.
- TTV total thickness variations
- a primary TTV influence comes from the post-join curing process.
- the thickness of the post-join adhesive layer correlates to the TTV error magnitude.
- a thick wet adhesive layer increases the risk of “squeezing-out” from the sides during the wafer joining step ( 84 ) in the uncured state.
- the present invention addresses these problems by applying a process that includes dual coating steps and dual curing steps.
- the dual coating/dual curing process 300 of this invention includes the following steps.
- the device wafer 20 is spin coated with the wet adhesive layer 23 a so that the solder bumps 20 a are covered, as shown in FIG. 6A .
- the device wafer 20 may also include a release layer 21 , as was described above.
- the solder bumps 20 a have a height 62 of 80 micrometers and the adhesive layer 23 a is deposited so that the thickness 61 of the adhesive layer above the solder bumps is about 25 micrometers.
- the wet adhesive layer 23 a on the device wafer 20 is cured, thereby resulting in a cured adhesive layer 23 a having a total thickness 64 of 105 micrometers.
- the curing temperature is 120° C. and the curing time is 10 minutes for the first curing step 330 .
- the carrier wafer 30 is spin coated with a thin wet adhesive layer 23 b .
- the thickness 65 of the wet adhesive layer 23 b is 25 micrometers. The thickness of the wet adhesive layer 23 b may be further decreased by changing the coating process parameters or the coating composition.
- the device wafer 20 with the cured adhesive layer 23 a is placed in the bonder 410 so that it is held by the top chuck 412 and the carrier wafer 30 with the wet adhesive layer 23 b is placed on the bottom chuck 414 , so that the wet adhesive layer 23 b is opposite to the cured adhesive layer 23 a , as shown in FIG. 6A and FIG. 6B .
- both the top 412 and bottom 414 chucks are low force chucks.
- the bonder chamber 410 is pumped down to a level of 10 mbar.
- the lower chuck 414 moves up along direction 415 and the two adhesive layers 23 a and 23 b are brought into contact with each other in order to form a joined wafer stack 10 ( 350 ), as shown in FIG. 6B .
- the bonder chamber 410 is then vented and brought to atmospheric pressure and then the joined wafer stack 10 is removed.
- the joined wafer stack 10 is placed in the curing chamber 406 (shown in FIG. 6B and FIG. 8 ) in order for the second cure step to take place.
- a hot plate 416 is brought into contact with the backside of the carrier wafer 30 and the wet adhesive layer 23 b is cured, thereby resulting in temporary bonding the carrier wafer 30 to the device wafer 20 .
- the curing temperature for this second curing step is also 120° C. and the time is about 15 minutes.
- a final cure step (not shown) is also applied to ensure that all adhesive layers 23 a , 23 b are fully cured.
- the final curing temperature is 190° C. and the time is 10 minutes.
- the bonded wafer stack 10 is thinned via CMP and then the thinned device wafer 20 is debonded from the carrier wafer 30 , as was described above.
- the device wafer 20 has a thickness of 775 micrometers (without the solder bumps), the solder bumps have a height of 80 micrometers.
- the carrier wafer 30 is a blank silicon wafer having a thickness of 775 micrometers or a glass wafer with a thickness of 600 micrometers.
- the adhesive is a silicone elastomer TMAT 3.2 supplied by Thin Materials AG, Kunststoff Germany.
- the temporary bonding equipment 410 is bonder XBS 300 supplied by Suss Microtec, Garching Germany. Surface metrology is provided by the integrated XBS 300 laser displacement thickness measurement or by a surface metrology instrument provided by Foothill Instruments for measuring coating uniformity on a blank wafer.
- FIG. 7 depicts typical post bond TTV results.
- wet adhesive layer 23 b is applied to the cured adhesive layer 23 a instead of to the carrier wafer 30 . In all cases, no squeeze-out of the adhesive on any bonded wafer pair was observed.
- a plurality of coating modules 402 , 404 , 408 may be used in order to improve throughput of the process, as shown in FIG. 8 .
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Abstract
Description
- This application is a divisional application and claims the benefit of U.S. application Ser. No. 13/790,684 filed Mar. 8, 2013 and entitled “METHOD AND APPARATUS FOR TEMPORARY BONDING OF ULTRA THIN WAFERS”, the contents of which are expressly incorporated herein by reference.
- The present invention relates to a method and an apparatus for temporary bonding of ultra thin wafers, and more particularly to temporary wafer bonding that includes a dual coating and dual curing process.
- Several semiconductor wafer processes include wafer thinning steps. In some applications the wafers are thinned down to a thickness of less than 100 micrometers for the fabrication of integrated circuit (IC) devices. Thin wafers have the advantages of improved heat removal and better electrical operation of the fabricated IC devices. In one example, GaAs wafers are thinned down to 25 micrometers to fabricate power complementary metal oxide semiconductor (CMOS) devices with improved heat removal. Wafer thinning also contributes to a reduction of the device capacitance and to an increase of its impedance, both of which result in an overall size reduction of the fabricated device. In other applications, wafer thinning is used for 3D-Integration bonding and for fabricating through wafer vias.
- Wafer thinning is usually performed via back-grinding and/or chemical mechanical polishing (CMP). CMP involves bringing the wafer surface into contact with a hard and flat rotating horizontal platter in the presence of liquid slurry. The slurry usually contains abrasive powders, such as diamond or silicon carbide, along with chemical etchants such as ammonia, fluoride, or combinations thereof. The abrasives cause substrate thinning, while the etchants polish the substrate surface at the submicron level. The wafer is maintained in contact with the abrasives until a certain amount of substrate has been removed in order to achieve a targeted thickness.
- For wafer thicknesses of over 200 micrometers, the wafer is usually held in place with a fixture that utilizes a vacuum chuck or some other means of mechanical attachment. However, for wafer thicknesses of less than 200 micrometer and especially for wafers of less than 100 micrometers, it becomes increasingly difficult to mechanically hold the wafers and to maintain control of the planarity and integrity of the wafers during thinning In these cases, it is actually common for wafers to develop microfractures and to break during CMP.
- An alternative to mechanical holding of the wafers during thinning involves attaching a first surface of the device wafer (i.e., wafer processed into a device) onto a carrier wafer and then thinning down the exposed opposite device wafer surface. The bond between the carrier wafer and the device wafer is temporary and is removed upon completion of the thinning and any other processing steps.
- Several temporary bonding techniques have been suggested including using of adhesive compounds that are thermally cured. In these adhesive based temporary bonding techniques a wet thick adhesive layer is applied onto the device wafer surface so that it covers all the structures of the device wafer surface including solder bumps, connectors, and integrated circuit (IC) devices. The wet adhesive layer has a typical thickness in the range of in the range of 25 to 150 micrometers. The wet adhesive layer is then brought into contact with the carrier wafer surface and the adhesive is then cured thereby resulting in bonding the device wafer to the carrier wafer. As was mentioned the bond is temporary and can be removed by dissolving the adhesive layer after processing by using chemicals, heat or radiation.
- One of the problems with this process is that the thick adhesive layer causes high total thickness variations (TTV) in the wafer surface planarity. A primary TTV influence comes from the post-join thermal curing process. In particular, the thickness of the post-join adhesive layer directly correlates to the TTV error magnitude. Furthermore, a thick wet adhesive layer increases the risk of “squeezing-out” of the adhesive from the sides during the wafer joining step in the uncured state. Accordingly, it is desirable to reduce the thickness of the adhesive layer that is used for temporary bonding of thinned wafers.
- The present invention relates to a method and an apparatus for temporary bonding and fabrication of ultra thin wafers, and more particularly to temporary wafer bonding that includes a dual coating and dual curing process.
- In general, in one aspect, the invention features a method for temporary bonding two wafer surfaces including the following. First providing a first wafer comprising first and second wafer surfaces opposite to each other. Next, providing a second wafer comprising first and second wafer surfaces opposite to each other. Next, applying a first adhesive layer upon the first surface of the first wafer. Next, curing the first adhesive layer, thereby producing a cured first adhesive layer. Next, applying a second adhesive layer upon the first surface of the second wafer. Next, providing a bonder module comprising an upper chuck assembly and a lower chuck assembly arranged below and opposite the upper chuck assembly. Next, inserting the first wafer into the bonder module and holding the first wafer by the upper chuck assembly so that its first surface with the cured first adhesive layer faces down. Next, inserting the second wafer into the bonder module and placing the second wafer upon the lower chuck assembly so that the second adhesive layer faces up and is opposite to the first adhesive layer. Next, moving the lower chuck assembly upwards and bringing the second adhesive layer in contact with the cured first adhesive layer, and then curing the second adhesive layer, thereby forming a temporary bond between the first and second wafers.
- Implementations of this aspect of the invention may include one or more of the following features. The second adhesive layer is cured by bringing a hot plate in contact with the second surface of the second wafer. The first adhesive layer is applied upon the first surface of the first wafer via spin coating. The first adhesive layer comprises a silicone elastomer. The curing of the first and second adhesive layers occurs at a curing temperature in the range of 80° C. to 160° C. and a curing time in the range of 1-15 minutes. The upper and lower chuck assemblies comprise low force upper and lower chucks, respectively, and the second adhesive layer is brought in contact with the cured first adhesive layer by first evacuating the bonder module and then bringing the bonder module to atmospheric pressure via purging. The method further includes curing the temporary bonded first and second wafers. The curing of the temporary bonded first and second wafers occurs at a curing temperature in the range of 120° C. to 220 ° C. and a curing time in the range of 1 to 15 minutes. The method further includes thinning the second surface of the first wafer and then debonding the thinned first wafer from the second wafer.
- In general, in another aspect, the invention features an apparatus for temporary bonding two wafer surfaces including a first coating chamber, a second coating chamber, a curing chamber and a bonder module. The first coating chamber is configured to apply a first adhesive layer upon a first surface of a first wafer. The second coating chamber is configured to apply a second adhesive layer upon a first surface of a second wafer. The curing chamber is configured to cure the first adhesive layer of the first wafer. The bonder module includes an upper chuck assembly and a lower chuck assembly arranged below and opposite the upper chuck assembly. The upper chuck assembly is configured to hold the first wafer so that its first surface with the cured first adhesive layer faces down. The lower chuck assembly is configured to hold the second wafer so that the second adhesive layer faces up and is opposite to the cured first adhesive layer. The lower chuck assembly is configured to move upwards and thereby to bring the second adhesive layer in contact with the cured first adhesive layer. The curing chamber is further configured to cure the second adhesive layer by bringing a hot plate in contact with a second surface of the second wafer, thereby forming a temporary bond between the first and second wafers. The upper and lower chuck assemblies comprise low force upper and lower chucks, respectively, and the second adhesive layer is brought in contact with the cured first adhesive layer by first evacuating the bonder module and then bringing the bonder module to atmospheric pressure via purging.
- In general, in another aspect, the invention features a method for temporary bonding two wafer surfaces including the following. Providing a first wafer comprising first and second wafer surfaces opposite to each other. Providing a second wafer comprising first and second wafer surfaces opposite to each other. Applying a first adhesive layer upon the first surface of the first wafer. Next, curing the first adhesive layer, thereby producing a cured first adhesive layer. Next, applying a second adhesive layer upon the cured first adhesive layer. Providing a bonder module comprising an upper chuck assembly and a lower chuck assembly arranged below and opposite the upper chuck assembly. Inserting the first wafer into the bonder module and holding the first wafer by the upper chuck assembly so that its first surface with the cured first adhesive layer and the second adhesive layer faces down. Next, inserting the second wafer into the bonder module and placing the second wafer upon the lower chuck assembly so that the first surface of the second wafer faces up and is opposite to the second adhesive layer. Next, moving the lower chuck assembly upwards and bringing the first surface of the second wafer in contact with the second adhesive layer, and then curing the second adhesive layer, thereby forming a temporary bond between the first and second wafers.
- In general, in another aspect, the invention features an apparatus for temporary bonding two wafer surfaces including a first coating chamber, a curing chamber, a second coating chamber and a bonder module. The first coating chamber is configured to apply a first adhesive layer upon a first surface of a first wafer. The curing chamber is configured to cure the first adhesive layer of the first wafer, thereby producing a first cured adhesive layer. The second coating chamber is configured to apply a second adhesive layer upon the first cured adhesive layer. The bonder module comprises an upper chuck assembly and a lower chuck assembly arranged below and opposite the upper chuck assembly. The upper chuck assembly is configured to hold the first wafer so that its first surface with the cured first adhesive layer and the second adhesive layer faces down. The lower chuck assembly is configured to hold a second wafer so that a first surface of the second wafer faces up and is opposite to the second adhesive layer. The lower chuck assembly is configured to move upwards and thereby to bring the first surface of the second wafer in contact with the second adhesive layer. The curing chamber is further configured to cure the second adhesive layer, thereby forming a temporary bond between the first and second wafers.
- In general in another aspect, the invention features a method for temporary bonding two wafer surfaces including the following. Providing a first wafer comprising first and second wafer surfaces opposite to each other. Providing a second wafer comprising first and second wafer surfaces opposite to each other. Applying a first adhesive layer upon the first surface of the first wafer. Next, curing the first adhesive layer, thereby producing a cured first adhesive layer. Next, applying a second adhesive layer upon the first surface of the second wafer. Providing a bonder module comprising an upper chuck assembly and a lower chuck assembly arranged below and opposite the upper chuck assembly. Next, inserting the first wafer into the bonder module and placing the first wafer upon the lower chuck assembly so that its first surface with the cured first adhesive layer faces up. Next, inserting the second wafer into the bonder module and holding the second wafer by the upper chuck assembly so that the second adhesive layer faces down and is opposite to the first adhesive layer. Next, moving the lower chuck assembly upwards and bringing the first adhesive layer in contact with the second adhesive layer. Finally, curing the second adhesive layer, thereby forming a temporary bond between the first and second wafers.
- In general in another aspect, the invention features a method for temporary bonding two wafer surfaces including the following. Providing a first wafer comprising first and second wafer surfaces opposite to each other. Providing a second wafer comprising first and second wafer surfaces opposite to each other. Applying a first adhesive layer upon the first surface of the first wafer. Next, curing the first adhesive layer, thereby producing a cured first adhesive layer. Next, applying a second adhesive layer upon the first surface of the second wafer. Next, bringing the first adhesive layer in contact with the second adhesive layer. Finally, curing the second adhesive layer, thereby forming a temporary bond between the first and second wafers.
- Referring to the figures, wherein like numerals represent like parts throughout the several views:
-
FIG. 1A is a schematic diagram of first example of a temporary wafer bonding process and a debonding process; -
FIG. 1B is a schematic diagram of second example of a temporary wafer bonding process and a debonding process; -
FIG. 2 depicts a schematic cross-sectional view of a bonder and a list of the process steps for performing the temporary wafer bonding process ofFIG. 1A andFIG. 1B ; -
FIG. 3 depicts a schematic cross-sectional side view of the laser debonding step ofFIG. 1A ; -
FIG. 4 depicts a schematic cross-sectional side view of the mechanical debonding step ofFIG. 1A andFIG. 1B ; -
FIG. 5 is a schematic diagram of the detaping process ofFIG. 1A andFIG. 1B ; -
FIG. 6A andFIG. 6B are schematic diagrams of the dual coat and dual cure temporary bonding process, according to this invention; -
FIG. 7 depicts post bond TTV results achieved with the dual coat and dual cure temporary bonding process, according to this invention; and -
FIG. 8 is an overview block diagram of the dual coat and dual cure temporary bonder system according to this invention. - Referring to
FIG. 1A ,temporary bond process 80 a includes the following steps. First, a surface of thedevice wafer 20 is coated with an adhesive layer 23 (82). In one example,adhesive layer 23 is a UV curable adhesive LC3200™, manufactured by 3M Company, MN, USA. The adhesive coated device wafer is then flipped (84). Next, a light absorbingrelease layer 33 is spin coated on asurface 30 a of the carrier wafer 30 (86). In one example, light absorbingrelease layer 33 is a LC4000, manufactured by 3M Company, MN, USA. Next, the flippeddevice wafer 20 is aligned with thecarrier wafer 30 so that thesurface 20 a of the device wafer with theadhesive layer 23 is opposite to thesurface 30 a of thecarrier wafer 30 with the light absorbingrelease layer 33. The twosurfaces adhesive layer 23 is cured with UV light (87). The two wafers are bonded (88) intemporary bonder 410, shown inFIG. 2 . The bond is a temporary bond between the light absorbingrelease layer 33 and theadhesive layer 23 and is formed under vacuum of 0.1 mbar and low applied bond force. - Referring to
FIG. 2 , thecarrier wafer 30 with the laser absorbing releaselayer LTHC layer 33 is placed on thetop chuck 412 and held in place by holdingpins 413. Next, thedevice wafer 20 is placed on thebottom chuck 414 with theadhesive layer 23 facing up. Next, thewafers top chuck 412 with thecarrier wafer 30 is dropped onto thedevice wafer 20. A low force is applied for the formation of the bond between therelease layer 33 and theadhesive layer 23. Next, the bondedwafer stack 10 is unloaded and the adhesive is cured with UV light. In other embodiments, thecarrier wafer 30 is placed on thebottom chuck 414 and thedevice wafer 20 is placed on thetop chuck 412. In other embodiments, the adhesive layer is thermally cured by bringing the wafers in contact with a hot plate or via thermal radiation. - Next, the temporary bonded
wafer stack 10 is placed in a CMP chamber and the back surface of thedevice wafer 20 is thinned via CMP. After the thinning process, thewafer stack 10 is debonded via thedebond process 80 b. - Referring back to
FIG. 1A , thedebond process 80 b includes the following steps. The bondedwafer stack 10 is mounted onto a dicing frame 25 (56) and thecarrier wafer 30 is illuminated with a YAG laser beam, as shown inFIG. 3 . The laser beam causes the separation of the wafer stack along the release layer 33 (57) and the separatedcarrier wafer 30 is mechanically lifted away from the device wafer 20 (58) by pushingedge 31 away, as shown inFIG. 4 . The laser debonding process is a low stress process that utilizes no chemicals and is carried out at room temperature. The mechanical debonding process utilizes very low force. After separation the carrier is recycled, cleaned and reused again. The mechanical debonding operation is described in co-pending application Ser. No. 12/761,014 entitled “Apparatus for mechanically debonding temporary bonded semiconductor wafers” the contents of which are incorporated herein by reference. Theadhesive layer 23 is then peeled away from thedevice wafer surface 20 a (59) and the thinneddevice wafer 20 remains supported by the dicingframe 25. Referring toFIG. 5 , adetaping tape 155 is applied on top of the exposedadhesive layer 23. In oneexample detaping tape 155 is tape 3305 manufactured by 3M Company. Tape 3305 is a transparent polyester film tape with an aggressive rubber adhesive specifically designed for the removal of silicon backgrinding tape. Thedetaping tape 155 is pressed onto and attached to theadhesive layer 23 and when thetape 155 is peeled away theadhesive layer 155 is also peeled away from thesurface 20 a of thedevice wafer 20. Chemical cleaning may be used to remove any remaining adhesive residue from thedevice wafer surface 20 a. However, the adhesive residue levels on thedevice wafer 20 after the removal of theadhesive layer 23 with thedetaping process 150 are minimal and usually no post-peel cleaning is required. Removal of the adhesive layer with the detaping process creates very little stress to the thinned wafer and is compatible with low-k dielectrics. - Referring to
FIG. 1B , in another example, thetemporary bonding process 80 c includes the following steps. First, thedevice wafer 20 is coated with a verythin layer 21 of a precursor which subsequently is transformed to a “release layer” 21 a via a plasma enhanced chemical vapor deposition process (PECVD). The total thickness of the finished “release layer” 21 is around 100 nm. Low plasma energy of about 10 Watts keeps the wafer at room temperature. By varying the plasma parameters the adhesion force of therelease layer 21 can be modified. In the next step, thecarrier wafer 30 is spin-coated with athicker layer 23 of an elastomer in order to cover any topography of the device wafer. Layer thicknesses from about 60 μm up to 200 μm are possible within one coating step. The elastomer is a liquid, highly viscose material. The mechanical properties of the elastomer after bonding and curing allow the grinding wheel to back grind the elastomer outside the wafer rim as well. In the next step, thedevice wafer 20 is bonded to thecarrier wafer 30 using the above described low force bonding process. Both samples are placed into thebond chamber 410 in a center-to-center aligned position with a separation from each other of about 10 mm. Thedevice wafer 20 is coated with the verythin release layer 21 of about 100 nm thickness and thecarrier wafer 30 is coated with the much thicker elastomer 23 (approximately 100 μm). Theelastomer 23 at this point in time is still liquid, forming an edge bead of some 10 μm at the outer rim of the carrier wafer. After evacuating thebond chamber 410 the twowafers upper device wafer 20 first touching theelastomer 23 on thecarrier wafer 30 on the top of the edge bead, thus sealing an inner chamber between both samples. By purging the bond chamber, both samples are pressed together just by the atmospheric pressure in thebond chamber 410, without any mechanical forces touching the wafer. Next, the bondedwafer stack 10 is thinned via CMP and then the thinneddevice wafer 20 is debonded from thecarrier wafer 30. In this case, de-bonding is done in a purely mechanical way. Thewafer stack 10 is mounted to a dicing tape which is held on a dicing frame with the thinned wafer side being adhered to the tape. Using a flat, porous plate the thinned wafer mounted onto the tape is sucked down by vacuum. This assembly keeps the sensitive thinned wafer in a fixed, flat and very stable position. By means of a slightly flexible, soft bendable vacuum chuck thecarrier wafer 30 can be taken off by lifting it from one side, as shown inFIG. 1B . - As was mentioned above, one of the problems with these temporary bonding processes 80 a, 80 c is that the
adhesive layer 23 is thick (in the range of 25 to 150 micrometers) and this causes high total thickness variations (TTV) in the device wafer surface planarity. A primary TTV influence comes from the post-join curing process. Actually, the thickness of the post-join adhesive layer correlates to the TTV error magnitude. Furthermore, a thick wet adhesive layer increases the risk of “squeezing-out” from the sides during the wafer joining step (84) in the uncured state. The present invention addresses these problems by applying a process that includes dual coating steps and dual curing steps. - Referring to
FIG. 6A , the dual coating/dual curing process 300 of this invention includes the following steps. In thefirst coating step 310, thedevice wafer 20 is spin coated with the wetadhesive layer 23 a so that the solder bumps 20 a are covered, as shown inFIG. 6A . Thedevice wafer 20 may also include arelease layer 21, as was described above. In one example, the solder bumps 20 a have aheight 62 of 80 micrometers and theadhesive layer 23 a is deposited so that thethickness 61 of the adhesive layer above the solder bumps is about 25 micrometers. In the subsequentfirst curing step 330, the wetadhesive layer 23 a on thedevice wafer 20 is cured, thereby resulting in a curedadhesive layer 23 a having atotal thickness 64 of 105 micrometers. In one example, the curing temperature is 120° C. and the curing time is 10 minutes for thefirst curing step 330. In thesecond coating step 320, thecarrier wafer 30 is spin coated with a thin wetadhesive layer 23 b. In one example, thethickness 65 of the wetadhesive layer 23 b is 25 micrometers. The thickness of the wetadhesive layer 23 b may be further decreased by changing the coating process parameters or the coating composition. In thenext step 340, thedevice wafer 20 with the curedadhesive layer 23 a is placed in thebonder 410 so that it is held by thetop chuck 412 and thecarrier wafer 30 with the wetadhesive layer 23 b is placed on thebottom chuck 414, so that the wetadhesive layer 23 b is opposite to the curedadhesive layer 23 a, as shown inFIG. 6A andFIG. 6B . As was mentioned above, both the top 412 and bottom 414 chucks are low force chucks. Thebonder chamber 410 is pumped down to a level of 10 mbar. Next, thelower chuck 414 moves up alongdirection 415 and the twoadhesive layers FIG. 6B . Thebonder chamber 410 is then vented and brought to atmospheric pressure and then the joinedwafer stack 10 is removed. In thenext step 360, the joinedwafer stack 10 is placed in the curing chamber 406 (shown inFIG. 6B andFIG. 8 ) in order for the second cure step to take place. In thissecond cure step 360, ahot plate 416 is brought into contact with the backside of thecarrier wafer 30 and the wetadhesive layer 23 b is cured, thereby resulting in temporary bonding thecarrier wafer 30 to thedevice wafer 20. In one example, the curing temperature for this second curing step is also 120° C. and the time is about 15 minutes. A final cure step (not shown) is also applied to ensure that alladhesive layers wafer stack 10 is thinned via CMP and then the thinneddevice wafer 20 is debonded from thecarrier wafer 30, as was described above. - In one example the
device wafer 20 has a thickness of 775 micrometers (without the solder bumps), the solder bumps have a height of 80 micrometers. Thecarrier wafer 30 is a blank silicon wafer having a thickness of 775 micrometers or a glass wafer with a thickness of 600 micrometers. The adhesive is a silicone elastomer TMAT 3.2 supplied by Thin Materials AG, Munich Germany. Thetemporary bonding equipment 410 isbonder XBS 300 supplied by Suss Microtec, Garching Germany. Surface metrology is provided by theintegrated XBS 300 laser displacement thickness measurement or by a surface metrology instrument provided by Foothill Instruments for measuring coating uniformity on a blank wafer.FIG. 7 depicts typical post bond TTV results. - In other embodiments, wet
adhesive layer 23 b is applied to the curedadhesive layer 23 a instead of to thecarrier wafer 30. In all cases, no squeeze-out of the adhesive on any bonded wafer pair was observed. A plurality ofcoating modules FIG. 8 . - Several embodiments of the present invention have been described. Nevertheless, it will be understood that various modifications may be made without departing from the spirit and scope of the invention. Accordingly, other embodiments are within the scope of the following claims.
Claims (10)
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US9478496B1 (en) * | 2015-10-26 | 2016-10-25 | United Microelectronics Corp. | Wafer to wafer structure and method of fabricating the same |
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Also Published As
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US20130244400A1 (en) | 2013-09-19 |
EP2826065A1 (en) | 2015-01-21 |
CN104145330B (en) | 2017-05-17 |
US9064686B2 (en) | 2015-06-23 |
WO2013136188A1 (en) | 2013-09-19 |
CN104145330A (en) | 2014-11-12 |
JP6174059B2 (en) | 2017-08-02 |
KR20140138898A (en) | 2014-12-04 |
KR102050541B1 (en) | 2019-11-29 |
JP2015517201A (en) | 2015-06-18 |
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