M338359 八 新型說明： 【新型所屬之技術領域】 本新型係有關於-種電致變色薄膜裝置，尤指 能驅動電解液中的陽離子改變電致變色材料晶格 成其光學性質之改變之電致變色薄膜裝置。 ^ 【先前技術】 ' 舀知之變色薄膜前案，例如已核准之中華民 092102124號專利，即揭示一種「可自動辨識變色 組」，其主要係由一可自動辨識變色薄膜之模組，其係、入、： 兩組或兩組以上之可量測反射光之頻譜資訊之光哭· j 組或兩組以上之光偵器配置於至少兩組反射角度上。月3^ 已核准之中華民國第_133309 “利，即揭示 一種，、有光致變色性彈性體薄膜之透鏡及其製法，易 -造光致變色鏡片之方法，其特徵在於其 含、.M338359 Eight new descriptions: [New technical field] This new type relates to electrochromic thin film devices, especially those that can drive the cations in the electrolyte to change the crystal lattice of the electrochromic material into its optical properties. Color changing film device. ^ [Prior Art] 'In the case of the color-changing film, for example, the Chinese Patent No. 092102124 has been approved, which discloses an "automatically recognizable color-changing group", which is mainly composed of a module capable of automatically recognizing a color-changing film. , In,: Two or more sets of spectroscopic reflected light spectrum information light crying j group or more than two sets of optical detectors are configured in at least two sets of reflection angles. Month 3^ Approved Republic of China No. _133309 "Lee, that is, a lens having a photochromic elastomer film and a method for producing the same, and a method for producing a photochromic lens, characterized in that it contains.
將=變色染料溶解於含彈性體之預雜的溶液“ U 1=^的=體膜，其巾該雜賊硬度介於tait， 又例如已核准之中華民國第8〇1〇2〇85號 一 種電致變色·電場發光和電致化學發光顯，置1 電致變色顯示圖素包含基板，成對電極二、Ύ ，、揭不一種 側成侧側相鄰，彼此 素。 及相對非傳導邊界區包圍該圖 然上述前針並未見相聚二？基魏燒(pdms)做為透 5 M338359 變色薄膜裝置，以缺點，本新型提供一種電致 【新型内容】 本新型之一目的係提供一種電致變g# 二甲基魏炫做供一種電致變色薄膜裝置，其以聚 軟性變色_置，其使用 括:Hi!:層本?色,膜裝置’其包 透明物質層之下方，其可提$帶^：f=U置於該高分子 係置於該透明導電薄膜層之·^方·、^變色薄膜’ 於該透明導電薄膜層之下方，1可化物層，係置 變色薄膜於接受該透明導電薄子；俾該 【?施=严式雜佳具體實麵之詳細說=后 請一併參照圖1至圖2,其中圖1洽干太安— ί電致變色薄膜裝置之組合示意圖圖IS; 薄膜裝置可應用在燈具上做變色燈之示意i。木之"致受色 如圖所不，本新型之電致變色薄膜 透明基材層彳0卜透明導電薄膜層2G ;色、薄、| ·:= -金屬氧化物層40所組合而成者。又色細30，以及 其中，該第-透明基獅彳〇例如但不限於為—高分子聚 6 M338359 矽t?MS)，其具有強的S_h〇鍵，所以具有良好的 …釔，、、岔合性、安定性以及高變形率之彈性 。子的 该透明導電薄膜層2〇例如但不限於 ， 該第—透明基材層1g之下方，其負 該;sr内電軸2。上施加負電愿時』 .明導限於為—氧化鶴層叫該透 I】ϊ ίϊί之電子會注入該變色薄膜3。後，顏色备忍 .^色、、化械應式如下：w〇3(無色)+Li++e_ =⑽曰^盒 化物層4Q例如但不限於為鋰鹽化合物，1可* ΐί =電薄膜層20及該變色薄膜30形成rr〇-t/CV、2 严日口士物層結構’當該金屬氧化物層4G上施加正ί 改變該變色薄膜3〇材料晶格内部，而造成並而 兮ϋ膜fo S透明導電薄膜I 20上施加負電壓即ί吏 .ΐ;ί=變色薄膜30氧化而呈現無可ΐ 此外’本案之電致變色薄膜裝置進一步 .口金屬氧化物層4。之下方:ί例二:= =良好的熱穩定、密合性、安定性以及高變形率之二= f I此夕I卜^^ %致變色薄膜裝置進—步具有—聚苯胺 (polya—e)層60 ’係置於該第二透明基材層5〇之下 =盆 南分子經由電化學氧化還原的電荷轉移，在能帶間隙間生成新 7 M338359 的月&階’使電子轉移能量|Τ备你，士 卷氧化還原反應所產生的變色現象，它有Ζ光譜’此因y化 還原狀態，因此具有多重電變色性質上不同的氧化 依序呈現黃色、綠色、C:變:隨位的施加 明顯的對比性。 在顏色减示上具有 遍Ϊη外’本案之電致變色薄職置進—步且有H明其 f層70，係置於該聚苯胺層60之下*，^為古月f ，性、安繼轉穩定、密合 材料，色薄膜裝置可將多種電變色材料以高分子 高變形率之彈性透明物有質良=仏= 成多重電變色機制。 《 g且木此巴形 在燈===本t電致變色薄膜裝置於組合後，可應用 ‘ϋ色其中之變色薄膜30可將光源所發出之光 功j *出’而達到可變式彩色玻璃畫等室内藝術裝潢之 盘=外k本案之電致變色薄職·組合後，亦可配合日光 “Ξϋ卜f度感測11來控制顏色深淺做内部溫、亮度調控， Μ用在％控溫室、玻璃展示屋。 車择ϊΐ1本案之電致變色薄膜裝置於組合後，亦可裝置於汽 壤;Μ呙上’控制系統藉由所感測之亮度而改變輸出至變色 _ 3(3 H _改變汽車觀玻狀魅。 動承ίίΐ述，本新型之電致變色薄膜裝置，其可利用電能驅 中的陽離子改變電致變色材料晶格内部，進而造成其 予性貝之改變，此外，亦可將兩種以上之電#色材料透過堆 8 M338359 ί以 變色機制等優點’因此較習知變色襄置具 源於ίί:【:乃ΐ佳實施例，舉凡局部之變更或修•而 原於本木之技術心想而為熟習該項技藝之人於 ς飾而 不脫本案之專利權範疇。 丨勿％推知者，俱 異於術鈸無新:=;巧 【圖式簡單說明】 膜裝其緣示本案—較佳實施例之電致變色薄 意圖，其1會示本案之電致變色薄膜裝置可應用 在燈具上做變色燈之示意圖。 第一透明基材層 變色薄膜30 第二透明基材層 第三透明基材層 【主要元件符號說明】 10 50 透明導電薄膜層20 金屬氧化物層40 聚笨胺層60 70 9Dissolving the color-changing dye in the pre-mixed solution containing the elastomer "U 1 = ^ = body film, the hardness of the thief is between tait, and for example, the Republic of China No. 8〇1〇2〇85 has been approved. An electrochromic, electric field luminescence, and electrochemiluminescence display, the electrochromic display element comprises a substrate, the pair of electrodes 2, Ύ, and the side of the side are adjacent to each other, adjacent to each other, and relatively non-conducting The boundary area encloses the above-mentioned anterior needle. The anterior needle does not see the condensed di-base Wei-burn (pdms) as the 5 M338359 color-changing film device. The disadvantage is that the present invention provides an electro-optic [new content] An electro-induced g# dimethyl Wei Xuan is made for an electrochromic thin film device, which is provided with a soft discoloration, which is used for: Hi!: layer color, and the film device is below the layer of transparent substance. It can be provided with a band of ^:f=U, and the polymer is placed on the transparent conductive film layer, and the color-changing film is below the transparent conductive film layer, and the compound layer is discolored. The film accepts the transparent conductive thin piece; 俾 = 严 严 严 严 严 严 严 严After saying =, please refer to Fig. 1 to Fig. 2 together, in which Fig. 1 is a schematic diagram of the combination of the electro-optical film device of the dry-Tai-an-thick film device; the film device can be applied to the lamp to make the indication of the color-changing lamp i. The color-sensitive film transparent substrate layer of the present invention is a transparent conductive film layer 2G; the color, the thin, the |==-metal oxide layer 40 are combined. Color fine 30, and wherein the first transparent base griffon, for example but not limited to, is a high molecular poly 6 M338359 矽t? MS), which has a strong S_h〇 bond, so it has a good ... 钇,, 岔The flexibility, stability, and high deformation rate of the transparent conductive film layer 2, for example but not limited to, below the first transparent substrate layer 1g, which is negative; sr inner electric axis 2. negatively applied The time is limited to - the oxidized crane layer is called the transparent I] ϊ ϊ ϊ 之 之 之 之 电子 电子 电子 电子 电子 电子 电子 电子 电子 电子 电子 电子 电子 电子 电子 电子 电子 电子 电子 电子 电子 电子 电子 电子 电子 电子 电子 电子 电子 电子 电子 电子 电子 电子 电子 电子 电子 电子 电子+Li++e_ = (10) 盒 ^ boxed layer 4Q, for example but not limited to, a lithium salt compound, 1 can be * = = = electrical film layer 20 and the color changing film 30 form r R〇-t/CV, 2 Yan Rikou layer structure 'When the metal oxide layer 4G is applied, the color change film 3 〇 material inside the lattice is changed, and the 兮ϋ film fo S transparent conductive film is caused. A negative voltage is applied to I 20 , that is, ί; ΐ; ί = color film 30 is oxidized to exhibit no flaws. Further, the electrochromic thin film device of the present invention further has a metal oxide layer 4. Below: ί Example 2: = = Good thermal stability, adhesion, stability and high deformation rate of the second = f I this eve I ^ ^ ^ ^ ^ ^ 2 photochromic film device further step - polyaniline (polya - e) layer 60 ' is placed in the The second transparent substrate layer 5 〇 = the charge transfer of the phenanthrene molecule via electrochemical redox, generating a new 7 M338359 'month & step ' between the band gaps to make electron transfer energy | The discoloration phenomenon produced by the reduction reaction has a Ζ spectrum, which is a y-reduction state, so that the oxidization sequence having multiple electrochromic properties exhibits yellow, green, and C: changes: significant contrast is applied to the position. In the color reduction, there is an electrochromic thin placement in the present case, and there is a H layer 70, which is placed under the polyaniline layer 60, ^ is the ancient moon f, sex, An successor to stable, close-fitting materials, color film device can be a variety of electrochromic materials with high polymer deformation rate elastic transparent material quality = 仏 = into multiple electrochromic mechanism. "g and the shape of the bar in the lamp === this t electrochromic film device after the combination, can apply 'color, which color film 30 can light the light from the light source j * out to reach the variable Colored glass painting and other indoor art decoration plate = outside k this case of electrochromic thin post / combination, can also be combined with daylight "Ξϋ f f 感 sensing 11 to control the color depth to do internal temperature and brightness control, in % Control the greenhouse, glass display house. The electrochromic film device of this case can also be installed in the steam soil after the combination; the control system changes the output to the color change by the sensed brightness _ 3 (3 H _ changes the car view glass charm. In this article, the novel electrochromic thin film device, which can use the cation in the electric drive to change the interior of the crystal lattice of the electrochromic material, thereby causing the change of the pre-existing shell, in addition It is also possible to pass two or more types of electric materials through the stack 8 M338359 ί with the advantages of color change mechanism. Therefore, it is more common to use the color change device from the ίί: [: ΐ ΐ 实施 实施 , , , , , , 局部 局部 局部 局部 局部I was familiar with the original technology of the wood. The person of the art is not limited to the patent right of the case. 丨 Do not infer the inferior, it is different from the surgery, no new: =; smart [schematic description] The film is the case - the preferred embodiment Electrochromic thin is intended to be a schematic diagram of the electrochromic thin film device of the present invention which can be applied to a lamp to be a color changing lamp. First transparent substrate layer color changing film 30 second transparent substrate layer third transparent substrate layer Main component symbol description] 10 50 transparent conductive film layer 20 metal oxide layer 40 polyamine layer 60 70 9