TW201829867A - Bi-elastic down-proof non-woven insert - Google Patents
Bi-elastic down-proof non-woven insert Download PDFInfo
- Publication number
- TW201829867A TW201829867A TW107103188A TW107103188A TW201829867A TW 201829867 A TW201829867 A TW 201829867A TW 107103188 A TW107103188 A TW 107103188A TW 107103188 A TW107103188 A TW 107103188A TW 201829867 A TW201829867 A TW 201829867A
- Authority
- TW
- Taiwan
- Prior art keywords
- lining
- interlining
- weight
- polyurethane
- vinyl acetate
- Prior art date
Links
Classifications
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4326—Condensation or reaction polymers
- D04H1/4358—Polyurethanes
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
- D04H1/56—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving in association with fibre formation, e.g. immediately following extrusion of staple fibres
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/58—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
- D04H1/64—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives the bonding agent being applied in wet state, e.g. chemical agents in dispersions or solutions
- D04H1/68—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives the bonding agent being applied in wet state, e.g. chemical agents in dispersions or solutions the bonding agent being applied in the form of foam
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
- D04H3/005—Synthetic yarns or filaments
- D04H3/009—Condensation or reaction polymers
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
- D04H3/08—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating
- D04H3/16—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between thermoplastic filaments produced in association with filament formation, e.g. immediately following extrusion
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47G—HOUSEHOLD OR TABLE EQUIPMENT
- A47G9/00—Bed-covers; Counterpanes; Travelling rugs; Sleeping rugs; Sleeping bags; Pillows
- A47G9/02—Bed linen; Blankets; Counterpanes
- A47G9/0207—Blankets; Duvets
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47G—HOUSEHOLD OR TABLE EQUIPMENT
- A47G9/00—Bed-covers; Counterpanes; Travelling rugs; Sleeping rugs; Sleeping bags; Pillows
- A47G9/08—Sleeping bags
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47G—HOUSEHOLD OR TABLE EQUIPMENT
- A47G9/00—Bed-covers; Counterpanes; Travelling rugs; Sleeping rugs; Sleeping bags; Pillows
- A47G9/10—Pillows
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dispersion Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Laminated Bodies (AREA)
Abstract
Description
本發明涉及一種雙彈性襯布,所述襯布能夠以輕的克重而製成並且儘管如此卻同時仍具有防絨性以及對於良好的穿著特性和使用特性所需要的透氣性和抗撕裂強度。本發明還涉及一種用於製備襯布的方法以及其用於防止羽絨從填充有羽絨的紡織產品中鑽出的應用。 The present invention relates to a double elastic lining which can be made in a light weight and nevertheless has the same anti-velvet properties as well as the breathability and tear strength required for good wearing characteristics and use characteristics. The invention also relates to a method for preparing a lining and to the use thereof for preventing duvet from being drilled from a down filled textile product.
在製備服裝時,襯布通常用外層面料加工,以便實現每件衣服的定型。所述襯布形成服裝的“骨架”。通常使用不織織物、織物或由網孔構成的、大多為針織物的紡織面料作為襯布。在加工中,襯布藉由大部分已經編織完成或由網孔構成的外層面料縫合和/或黏接。 In the preparation of garments, the lining is usually processed with an outer fabric to achieve the shaping of each garment. The lining forms a "skeleton" of the garment. Nonwoven fabrics, woven fabrics or woven fabrics composed of mesh, mostly knitted fabrics, are generally used as the lining. In processing, the lining is stitched and/or bonded by a majority of the outer fabric that has been woven or formed of mesh.
根據其變形特性來區分穩定的襯布、單彈性襯布和雙彈性襯布。穩定的襯布在伸長時係不可逆地變形,而單彈性襯布的特徵在於沿著一個方向(縱向方向或橫向方向)可逆的變形特性。雙彈性襯布的特徵在於沿著兩個方向(縱向方向和橫向方向)可逆的變形特性。 A stable lining, a single elastic lining, and a double elastic lining are distinguished according to their deformation characteristics. A stable lining is irreversibly deformed upon elongation, while a single elastic lining is characterized by reversible deformation characteristics in one direction (longitudinal direction or transverse direction). The double elastic interlining is characterized by reversible deformation characteristics in two directions (longitudinal direction and transverse direction).
襯布在其應用中通常被選擇為,使得其成形能力與外層面料相匹配。雙彈性外層面料以理想方式與雙彈性襯布共同加工。襯布的雙彈性能夠借助DIN 53835-2:1981-08測量。如果在根據DIN 53835-2:1981-08檢驗熱塑性特性時,襯布可在縱向方向和橫向方向上無損地伸長直至至少25%的伸長的上反轉點並且附加地具有至多10%的殘餘伸長和/或優選至多12%的永久伸長,那麼所述襯布在其成形能力方面通常與大多雙彈性外層面料良好地匹配。 Liners are typically selected in their application to match their forming ability to the outer fabric. The double elastic outer fabric is ideally machined with a double elastic interlining. The double elasticity of the lining can be measured by means of DIN 53835-2:1981-08. If the thermoplastic properties are tested in accordance with DIN 53835-2:1981-08, the interlining can be stretched non-destructively in the longitudinal and transverse directions up to an upper reversal point of at least 25% elongation and additionally with a residual elongation of up to 10% and / or preferably at least 12% permanent elongation, then the lining is generally well matched to most of the bielastic outer fabric in terms of its forming ability.
在與外層面料相結合時,襯布應產生:小的皺縮;良好的護理性能,即良好的耐洗滌性和耐化學清洗性;以及在褶皺能力良好的情況下柔軟的紡織品手感。如果與外層面料相結合經受熱過程,如熨燙或洗滌,那麼所述襯布完全不應黏接或僅應相當微弱地黏接,使得無損的分離是可行的。 在重量方面,襯布同樣適宜地與外層面料相協調:對於輕的外層面料理想上使用非常輕的襯布。 When combined with the outer fabric, the lining should produce: small shrinkage; good care properties, ie good wash and chemical wash resistance; and a soft textile hand with good pleatability. If subjected to a thermal process, such as ironing or washing, in combination with the outer fabric, the lining should not adhere at all or should only be relatively weakly bonded, making non-destructive separation feasible. In terms of weight, the interlining is also suitably coordinated with the outer fabric: for light outer fabrics it is desirable to use very light interlinings.
通常襯布在其加工之後在外層面料的外側上應是不可見的或僅少量可見。此外,所述襯布在其外觀方面應盡可能良好地對應於外層面料並且此外不應例如由於其厚度而外層面料上呈現出來或由於其顏色、結構或其光澤而在外層面料的外側上是可見的。根據本發明,作為附加的功能,襯布應將防止在具有羽絨填充物的紡織品中羽絨遷移。 Typically the lining should be invisible or only a small amount visible on the outside of the outer fabric after it has been processed. Furthermore, the lining should correspond as far as possible to the outer fabric in terms of its appearance and should not be visible on the outer fabric, for example due to its thickness or visible on the outer side of the outer fabric due to its colour, structure or gloss. of. According to the invention, as an additional function, the lining should prevent migration of the down in the textile having the down filling.
附加地,襯布本身以及襯布和外層面料的複合結構的透氣性應在確定的界限之內。由此,能夠實現紡織品的非常好的熱作用。這種特性能夠借助如下襯布而實現,所述襯布的透氣性根據DIN EN ISO 9237:1995-12測量位於至少20[dm3/s×m2]至450[dm3/s×m2]的範圍中。將透氣性設定為上述值的另一優點是,所包圍的空氣在壓縮時能夠足夠快速地洩露,使得在壓縮時不出現氣球效應。由此,可以以令人滿意的方式壓縮設置有根據本發明的襯布的紡織品,例如在打包到箱子中或在洗衣機中洗滌時。此外,在透氣性為至少20[dm3/s×m2]的情況下,可行的是,羽絨借助空氣吹入到襯布中,而不出現氣球效應。低於20[dm3/s×m2]的透氣性會導致羽絨填充物在其潮濕之後難以被乾燥。於是會出現生物學過程,如細菌生長、真菌形成或黴菌形成。此外,不再充分確保空氣交換,使得在皮膚和紡織品之間積聚汗水,這會降低穿著舒適性並且導致穿著者感冒。 Additionally, the breathability of the lining itself and the composite structure of the lining and outer fabric should be within certain limits. Thereby, a very good thermal effect of the textile can be achieved. This property can be achieved by means of a lining which has a gas permeability of at least 20 [dm 3 /s×m 2 ] to 450 [dm 3 /s×m 2 ] as measured according to DIN EN ISO 9237:1995-12. In the scope. Another advantage of setting the gas permeability to the above value is that the enclosed air can leak quickly enough when compressed so that no ballooning occurs during compression. Thereby, the textile provided with the interlining according to the invention can be compressed in a satisfactory manner, for example when packed into a box or washed in a washing machine. Further, in the case where the gas permeability is at least 20 [dm 3 /s × m 2 ], it is possible that the down is blown into the lining by the air without a balloon effect. A gas permeability of less than 20 [dm 3 /s × m 2 ] causes the down filling to be difficult to dry after it is wet. Biological processes such as bacterial growth, fungal formation or mold formation can occur. In addition, air exchange is no longer sufficiently ensured, so that sweat accumulates between the skin and the textile, which reduces wearing comfort and causes the wearer to catch a cold.
透氣性中高於450[dm3/s×m2]的值同樣是不利的。如果空氣和風同樣過強地穿透襯布和外層面料的複合結構,那麼不再提供足夠的熱作用。在透氣性值較高的情況下,緊密性通常也不足以確保足夠的防絨性或防羽絨遷移性。 A value higher than 450 [dm 3 /s × m 2 ] in the gas permeability is also disadvantageous. If the air and wind also penetrate the composite structure of the lining and the outer fabric too strongly, then no sufficient heat is provided. In the case of a high gas permeability value, the tightness is usually not sufficient to ensure sufficient anti-velvet or anti-down migration.
羽絨(也稱作絨羽(Unterfedern))是具有短的羽莖和柔軟的羽毛分枝的羽毛。在紡織產品、如夾克、床上用品或睡袋中,羽絨用作為進行熱隔離的填充物。在此,羽絨包含並且封入在由面狀的紡織結構構成的包套中。在所提出的應用中,用羽絨填充的紡織產品必須是“防絨的”。這意味著:羽絨不穿透或者伸出(遷移出)包套。因為羽絨的羽莖是尖銳的並且是硬的,所以包套必須具有高的抗撕裂強度。在本發明的範圍中,用術語“羽絨”表示鳥類的絨毛(Unterfedern),所述絨毛適合用於紡織填充。在DIN 12934中提供羽絨的定義。羽絨尤其是具有非常短的羽莖和長的、輻射狀設置的羽毛分枝的羽毛。與其他羽毛相比,羽絨通常也具有更少的小鉤。由於其高的彈性和結合隔熱特性的形穩性,羽絨用於大量紡織應用。 Down (also known as Unterfedern) is a feather with short plumes and soft feather branches. In textile products such as jackets, bedding or sleeping bags, down is used as a filler for thermal insulation. Here, the down comprises and encloses in a jacket made of a planar textile structure. In the proposed application, the down-filled textile product must be "anti-velvet". This means that the down does not penetrate or extend (migrate) the wrap. Because the feathered plume is sharp and hard, the sheath must have high tear strength. Within the scope of the invention, the term "down" is used to mean the fluff of a bird, which is suitable for textile filling. The definition of down is provided in DIN 12934. Down is especially feathers with very short plumes and long, radial feathers. Downs usually have fewer hooks than other feathers. Due to its high elasticity and dimensional stability combined with thermal insulation properties, down is used in a wide range of textile applications.
在具有完全或部分包含羽絨的填充物的紡織品中存在尤其由於表面摩擦,如在穿著、洗滌或化學清洗衣服時的手動應力的情況下,將羽絨微粒或羽毛微粒穿透外層面料稱作羽絨遷移。在其鑽出時這些微粒會損害外層面料並且是不期望的,因為它們在那是可見的。大量遷移使衣服的熱作用變差,因為填充物的品質減少。 In textiles having a full or partial down filling, there is a tendency to penetrate down the outer fabric, especially due to surface friction, such as manual stress during wearing, washing or chemical cleaning of the garment. . These particles can damage the outer fabric as it is drilled and are undesirable because they are visible there. A large amount of migration deteriorates the thermal effects of the clothes because the quality of the filling is reduced.
目前為了防止羽絨遷移使用防絨的織物作為襯布。根據標準測試方法GB/T 12705.2-2009“Textile-Methods of testing the down-proofproperties of fabrics-Part 2 Tumble test”例如能夠確定織物相對於羽絨的緊密性,其中在此穿透的微粒的低於15的數量視為是良好的或可接受的。 At present, in order to prevent the migration of down, an anti-velvet fabric is used as a lining cloth. According to the standard test method GB/T 12705.2-2009 "Textile-Methods of testing the down-proof properties of fabrics-Part 2 Tumble test", for example, the tightness of the fabric relative to the down can be determined, wherein the particles penetrated here are below 15 The quantity is considered to be good or acceptable.
防絨的織物襯布通常藉由高的羽毛密度和因使用非常纖細的紗線引起的細度實現其防絨性。然而,所述織物襯布提供低的彈性和透氣性。所述織物襯布無法以令人滿意的方式用彈性的外層面料加工,因為其成形能力無法良好地與雙彈性外層面料匹配。此外,在用非常輕的、透明的外層面料加工時,由於Moirée效應,這種防絨的織物襯布在衣服的外側上能夠是可見的,所述Moirée效應因襯布的紡織結構與外層面料的紡織結構或網孔結構的疊加產生。 Flock-resistant fabric linings are typically achieved with high feather density and fineness due to the use of very fine yarns. However, the fabric lining provides low elasticity and breathability. The fabric lining cannot be processed in a satisfactory manner with an elastic outer fabric because its forming ability does not match well with the bielastic outer fabric. Furthermore, when processed with a very light, transparent outer fabric, this anti-velvet fabric lining can be visible on the outside of the garment due to the Moirée effect, which is due to the textile structure of the interlining and the textile of the outer fabric. A superposition of structures or mesh structures is produced.
對於非常輕的、透明的外層面料而言,通常必須使用具有小的克重和厚度的非常輕的襯布。這在紡織襯布和針織襯布中是有問題的,因為所述襯布僅可在生產速度低、成本高並且有品質問題的情況下以高的耗費製備。也就是說,必須使用非常細的紗線/長絲。但是所述紗線/長絲難以加工並且通常具有如此高的細度和滑動能力,使得在用外層面料加工時所述紗線/長絲幾乎無法平坦並且無褶皺地鋪放並且幾乎無法筆直地並且形狀準確地剪裁。這種襯布趨於形成褶皺或打滑,其結果是難於操作和差的可加工性。 For very light, transparent outer fabrics, it is often necessary to use very light linings with a small grammage and thickness. This is problematic in textile linings and knit linings because the linings can only be produced at high cost in the case of low production speed, high cost and quality problems. That is to say, very fine yarns/filaments must be used. However, the yarns/filaments are difficult to process and generally have such high fineness and sliding ability that the yarns/filaments are barely flat and wrinkle-free when processed with the outer fabric and are almost impossible to straighten and The shape is accurately cut. Such linings tend to form pleats or slip, which results in difficult handling and poor processability.
此外,目前在市場上無法購得基於雙彈性的並且同時適合用作防羽絨遷移的襯布的紡織物。 In addition, textiles based on bi-elastic and suitable for use as a lining for down-migration are currently not available on the market.
由不織織物構成的襯布也可以小的克重良好地剪裁並且無褶皺地鋪 放,並且由於其結構能夠在沒有已知的問題的情況下加工。非常輕的不織織物通常由纖度小於1分特的紡黏纖維或短纖維製成。這種不織織物具有柔軟的手感並且尤其可以具有良好的抗撕裂強度的小的克重製備。 The interlining composed of the non-woven fabric can also be cut nicely and with a small wrinkle and can be laid without wrinkles, and can be processed without known problems due to its structure. Very light non-woven fabrics are usually made of spunbond or staple fibers having a fineness of less than 1 dtex. Such non-woven fabrics have a soft hand and can be prepared in particular with a small grammage of good tear strength.
在習知技術中提出,用於保存羽絨的不織織物用作層壓材料的組分。因此,例如JP2008/303480A提出,使用由防織物與不織織物構成的複合材料。JP2006/291421A也公開防絨的層壓材料,所述層壓材料包含熱黏合的不織織物。但是層壓材料通常相對耗費地製備,也是因為組分必須黏接或必須以其他方式彼此牢固地連接。 It is proposed in the prior art that a nonwoven fabric for storing down is used as a component of the laminate. Thus, for example, JP 2008/303480 A proposes to use a composite material composed of a fabric and a non-woven fabric. JP 2006/291421 A also discloses an anti-textile laminate comprising a thermally bonded nonwoven fabric. However, laminates are usually produced relatively inexpensively, also because the components must be bonded or must be securely joined to one another in other ways.
具有雙彈性的變形特性的不織織物通常僅可耗費地製備。此外,所述不織織物通常僅在結構緊密並且克重同時高的情況下才是防絨的。 Nonwoven fabrics having bielastic deformation characteristics are usually only produced at a costly rate. Moreover, the nonwoven fabric is generally only anti-velvet in the case where the structure is tight and the weight is high at the same time.
本發明的目的是提供一種雙彈性襯布,所述襯布能夠以簡單的方式製備並且所述襯布在其成形能力方面與大多數雙彈性的外層面料良好地匹配並且即使在克重小的情況下也具有良好的或至少可接受的防絨性。 It is an object of the present invention to provide a bi-elastic lining which can be prepared in a simple manner and which is well matched to most bi-elastic outer fabrics in terms of its forming ability and even in the case of small gram weights Has good or at least acceptable anti-textile properties.
襯布應能夠具有用於對於良好的穿著特性和使用特性所需要的透氣性,柔軟的手感以及與外層面料結合時良好的熱作用。 The lining should be able to have the breathability required for good wearing characteristics and use characteristics, a soft hand and good thermal action when combined with the outer fabric.
最後,襯布應具有對於加工而言良好匹配的滑動能力。 Finally, the lining should have a sliding ability that is well matched for processing.
在需要時,襯布還應可以小的厚度製備並且具有對於良好的加工而言必需的抗撕裂強度。 The lining should also be prepared in small thicknesses when needed and have the tear strength necessary for good processing.
該目的藉由包括熔噴不織織物的雙彈性襯布實現,所述熔噴不織織物包含熔融紡絲的熔噴聚氨酯纖維,其中不織織物在至少一側上具有泡沫覆層,所述泡沫覆層包含醋酸乙烯酯共聚物和/或聚丙烯酸酯和/或聚氨酯。 The object is achieved by a bielastic lining comprising a meltblown nonwoven fabric comprising melt spun meltblown polyurethane fibers, wherein the nonwoven fabric has a foam coating on at least one side, the foam The coating comprises a vinyl acetate copolymer and/or a polyacrylate and/or a polyurethane.
根據本發明已經發現,由於將彈性的聚氨酯纖維與由同樣高彈性的聚合物構成的泡沫覆層組合使用,根據本發明的襯布具有高的雙彈性。 It has been found in accordance with the invention that the interlining according to the invention has a high bielasticity due to the combination of elastic polyurethane fibers with a foam coating composed of the same highly elastic polymer.
由此,襯布在其成形能力方面與大多數雙彈性的外層面料良好地匹配。此外,即使在克重小的情況下,襯布也具有良好的或至少可接受的防絨性。這大概歸因於:泡沫覆層非常有效地封閉不織織物中羽絨的通道並且提高了抗穿透強度和抗撕裂強度。 Thus, the lining is well matched to most of the bi-elastic outer fabric in terms of its forming ability. Moreover, the lining has good or at least acceptable shedding resistance even in the case of small grammage. This is presumably attributed to the fact that the foam coating very effectively seals the passage of the down in the nonwoven fabric and increases the penetration resistance and tear strength.
由於泡沫結構的固有的高的透氣性,襯布還能夠具有對於良好的穿著特 性和使用特性而言所需要的透氣性。最後,將聚氨酯與用於泡沫覆層的聚合物組合使用實現柔軟的手感以及在與外側面料結合時良好的熱作用。 Due to the inherently high gas permeability of the foam structure, the interlining can also have the breathability required for good wearing characteristics and use characteristics. Finally, the use of polyurethane in combination with the polymer used for the foam coating achieves a soft hand and good thermal action when combined with the outer fabric.
此外,已經令人驚訝地發現,根據本發明的襯布在洗滌和乾燥時具有小的皺縮。這在過去是不可預料的,因為一方面基於聚氨酯纖維的不織織物通常具有高的皺縮,而另一方面在使用分別包含具有低的軟化溫度和/或玻璃化轉變溫度的聚合物的纖維和泡沫覆層時,更確切地說,提高的皺縮特性是意料之中的。假設小的皺縮趨勢歸因於泡沫覆層的穩定性作用,其方式是:所述泡沫覆層藉由黏接至少在表面上穩定纖維。當泡沫覆層包含呈至少部分地交聯的形式的醋酸乙烯酯共聚物和/或聚丙烯酸酯和/或聚氨酯時,這種黏接能夠尤其強烈地進行。 Furthermore, it has surprisingly been found that the lining according to the invention has a small shrinkage during washing and drying. This has been unpredictable in the past because, on the one hand, non-woven fabrics based on polyurethane fibers generally have high shrinkage, and on the other hand, fibers comprising polymers each having a low softening temperature and/or glass transition temperature are used. In contrast to foam coatings, more specifically, increased shrinkage characteristics are expected. It is assumed that the small shrinkage tendency is attributed to the stability of the foam coating by the fact that the foam coating stabilizes the fibers at least on the surface by bonding. Such adhesion can be carried out particularly strongly when the foam coating comprises a vinyl acetate copolymer and/or a polyacrylate and/or a polyurethane in an at least partially crosslinked form.
因此,根據本發明的襯布的皺縮優選低於5%,更優選低於3%,更尤其優選低於2%。 Accordingly, the shrinkage of the interlining according to the invention is preferably less than 5%, more preferably less than 3%, still more preferably less than 2%.
此外,已經令人驚訝地發現,即使在整面地塗覆時,也就是說,超過95%的表面積由泡沫覆層覆蓋,根據本發明的襯布也具有柔軟的手感。 Furthermore, it has surprisingly been found that the lining according to the invention has a soft hand even when coated over the entire surface, that is to say that more than 95% of the surface area is covered by the foam coating.
此外,已經令人驚訝地發現,只要所述襯布製備為縫合襯布並且在不利用對此常用的熱熔膠製備為黏襯,那麼儘管使用分別包含具有低的軟化溫度和/或玻璃化轉變溫度的聚合物的纖維和泡沫覆層,但是在熱過程中如在高達110℃熨燙時或在40℃洗滌時,根據本發明的襯布不黏接或僅微弱地黏接,使得所述襯布可再次無損地分離。 Furthermore, it has surprisingly been found that as long as the lining is prepared as a quilted lining and is prepared as a lining without the use of hot melt adhesives which are conventionally used, the use, respectively, has a low softening temperature and/or glass transition temperature. Fiber and foam coating of the polymer, but during the thermal process such as ironing at up to 110 ° C or washing at 40 ° C, the lining according to the invention does not stick or only weakly bond, so that the lining can be Separate again without damage.
此外,根據本發明已經令人驚訝地發現,在與結構化的外層面料熱黏合時,根據本發明的襯布與外層面料可塑地匹配並且能夠採用外層面料的結構。在此,外層面料的結構轉移到襯布上並且在其上呈現。由此,襯布具有突出的成形能力。 Furthermore, it has surprisingly been found in accordance with the invention that the lining according to the invention is plastically compatible with the outer fabric and can be constructed with the outer fabric when thermally bonded to the structured outer fabric. Here, the structure of the outer fabric is transferred to and presented on the lining. Thereby, the lining has a protruding forming ability.
根據本發明將聚氨酯纖維理解為如下纖維,所述纖維包含優選份額超過90重量%,更優選超過95%的聚氨酯。特別地,聚氨酯纖維由聚氨酯構成,其中能夠包含常用的添加劑。尤其適合的聚氨酯基於聚酯化學、聚醚化學和/或聚己內酯化學是具有芳香鏈和/或脂肪鏈的彈性的聚氨酯。脂肪族聚氨酯由於其較高的耐變黃性是有利的。聚氨酯纖維優選具有高於120℃,優選160℃至175℃的軟化範圍。 According to the invention, polyurethane fibers are understood to be fibers which comprise a preferred proportion of more than 90% by weight, more preferably more than 95%, of polyurethane. In particular, the polyurethane fibers are composed of polyurethane, which can contain conventional additives. Particularly suitable polyurethanes are based on polyester chemistry, polyether chemistry and/or polycaprolactone chemistry which are polyurethanes having an aromatic chain and/or a fatty chain. Aliphatic polyurethanes are advantageous due to their high resistance to yellowing. The polyurethane fibers preferably have a softening range above 120 °C, preferably from 160 °C to 175 °C.
熔噴不織織物,在下文中也簡稱不織織物,其製備能夠以已知的方法借 助熔噴方法實現。 Meltblown nonwoven fabrics, hereinafter also referred to as nonwoven fabrics, can be prepared by known methods by meltblowing.
在熔噴方法中,不織布由纖維通過直接鋪設形成,所述纖維直接由穿過噴嘴的聚合物熔體噴紡並且借助熱空氣流拉伸直至斷裂。產生所謂的熔噴不織布。基於其構造的黏合的不織布稱作熔噴不織織物。熔噴纖維通常具有非常小的纖度。根據本發明,所述纖度優選小於1分特,例如在0.1分特和1分特之間。 In the meltblowing process, the nonwoven fabric is formed from the fibers by direct laying, which is directly spun from the polymer melt passing through the nozzle and stretched by means of a stream of hot air until breaking. A so-called meltblown nonwoven fabric is produced. A bonded nonwoven fabric based on its configuration is called a melt blown nonwoven fabric. Meltblown fibers typically have very small deniers. According to the invention, the denier is preferably less than 1 dtex, for example between 0.1 dtex and 1 dtex.
與此相應地,纖維的平均纖維直徑優選小於1μm(微米),尤其小於0.5μm,例如在0.1μm至1μm之間。本發明的目的在於藉由光學測量方法確定平均纖維直徑,尤其藉由對借助於電子掃描顯微鏡產生的圖像(REM圖像)進行圖像分析評估。這包含用於給出在多個測量點上關於纖維直徑和其散佈的可重現的、客觀的從而具有代表性的結論的統計學有效的分析方法。 Correspondingly, the fibers have an average fiber diameter of preferably less than 1 [mu]m (micrometer), in particular less than 0.5 [mu]m, for example between 0.1 [mu]m and 1 [mu]m. The object of the invention is to determine the average fiber diameter by optical measurement methods, in particular by image analysis of images (REM images) produced by means of scanning electron microscopy. This includes statistically valid analytical methods for giving reproducible, objective, and thus representative conclusions about fiber diameter and its spread at multiple measurement points.
根據本發明,不織織物是包含熔噴聚氨酯纖維的不織織物。在此,熔噴不織織物中聚氨酯纖維的份額優選超過90重量%,更優選超過95重量%。熔噴不織織物尤其由聚氨酯纖維構成。 According to the invention, the nonwoven fabric is a nonwoven fabric comprising meltblown polyurethane fibers. Here, the proportion of the polyurethane fibers in the melt-blown nonwoven fabric is preferably more than 90% by weight, more preferably more than 95% by weight. The meltblown nonwoven fabric is composed in particular of polyurethane fibers.
關於不織織物構成為熔噴不織織物,有利的是,構成非常均勻並且緊密的結構,由此也在整個層中均勻地構成預設的彈性。此外,緊密的結構引起高的防絨性和抗撕裂強度。 With regard to the non-woven fabric being constituted as a melt-blown nonwoven fabric, it is advantageous to constitute a very uniform and compact structure, whereby the predetermined elasticity is also uniformly formed throughout the layer. In addition, the compact structure causes high anti-velvet properties and tear strength.
由於習知的纖維結構,透氣性儘管如此仍然能夠被設定到期望的值。襯布優選具有抗撕裂強度,所述抗撕裂強度被測量為縱向方向上15N至60N而在橫向方向上10N至60N的最大拉力和/或100%至400%的最大拉伸強度。在此,抗撕裂強度涉及不具有必要時用於製備不織織物的載體材料的泡沫覆層的不織織物。 Due to the conventional fiber structure, the gas permeability can be set to a desired value despite this. The lining preferably has a tear strength measured as a maximum tensile force of 15N to 60N in the longitudinal direction and 10N to 60N in the transverse direction and/or a maximum tensile strength of 100% to 400%. Here, the tear strength relates to a nonwoven fabric which does not have a foam coating of a carrier material for preparing a nonwoven fabric, if necessary.
不織織物的機械特性能夠藉由接下來的黏合,尤其熱黏合進一步改進。 The mechanical properties of the nonwoven fabric can be further improved by the subsequent bonding, especially thermal bonding.
在本發明的一個優選的實施方式中,熔噴不織織物作為載體材料上的功能層來製備。就傳統意義而言,該實施方式不視為層壓材料,因為所述實施方式實現熔噴不織織物和載體材料的簡單的可分離性。緊接著,泡沫覆層能夠以尤其簡單的方式塗覆到借助載體材料穩定的不織織物上。 In a preferred embodiment of the invention, a meltblown nonwoven web is prepared as a functional layer on a carrier material. In a conventional sense, this embodiment is not considered a laminate because the embodiment achieves a simple separability of the meltblown nonwoven web and the carrier material. Subsequently, the foam coating can be applied in a particularly simple manner to the nonwoven fabric which is stabilized by the carrier material.
載體材料優選在至少一個方向上具有比熔噴不織織物更低的彈性,以便即使在借助拉應力加工材料的過程中,例如在塗覆泡沫覆層時也實現簡單 的操作。在施加泡沫覆層之後,例如能夠在與外層面料結合的前一刻以簡單的方式使載體材料分離出來。載體材料能夠是不織織物、紡織物、編織物、針織物等,優選例如基於聚酯、聚醯胺或聚丙烯的紡黏型不織織物。 The carrier material preferably has a lower elasticity in at least one direction than the meltblown nonwoven fabric in order to achieve a simple operation even in the process of processing the material by means of tensile stress, for example when applying a foam coating. After the application of the foam coating, for example, the carrier material can be separated in a simple manner immediately before the combination with the outer fabric. The carrier material can be a nonwoven fabric, a woven fabric, a woven fabric, a knitted fabric or the like, preferably a spunbonded nonwoven fabric based on, for example, polyester, polyamide or polypropylene.
在沒有如果需要的話存在的載體材料的情況下,熔融紡絲的聚氨酯纖維占襯布總重量的份額優選在30重量%至90重量%之間,更優選在40重量%至80重量%之間,更尤其優選在50重量%至70重量%之間。 In the absence of a carrier material which is present if desired, the proportion of melt-spun polyurethane fibers to the total weight of the lining is preferably between 30% and 90% by weight, more preferably between 40% and 80% by weight, More particularly preferably between 50% and 70% by weight.
固有的高的雙彈性使得根據本發明的襯布實現高的穿著舒適性和在選擇外層面料時高的靈活性。所述襯布尤其也可以非常小的克重製備並且儘管如此具有良好的防絨性、抗撕裂強度和足夠小的滑動能力,使得所述襯布可良好地加工。 The inherently high double elasticity allows the lining according to the invention to achieve high wearing comfort and high flexibility in the selection of the outer fabric. In particular, the lining can also be produced in a very small gramm weight and nevertheless has good anti-velvet properties, tear strength and a sufficiently small sliding capacity, so that the lining can be processed well.
在沒有如果需要的話存在的載體材料的情況下,襯布尤其優選具有30g/m2至90g/m2,優選為40g/m2至80g/m2,尤其為50g/m2至70g/m2的克重。 In the case of a carrier material which is present if not required, the interlining preferably has a basis weight of from 30 g/m 2 to 90 g/m 2 , preferably from 40 g/m 2 to 80 g/m 2 , in particular from 50 g/m 2 to 70 g/m 2 The weight of the weight.
根據本發明的襯布實現突出的防絨性。優選地,在根據標準測試方法GB/T 12705.2-2009“Textile-Methods of testing the down-proof properties of fabrics-Part 2 Tumble test”檢驗襯布時,穿透的微粒的數量不超過最大15,更優選不超過最大10並且尤其最大5。 The lining according to the invention achieves outstanding velvet resistance. Preferably, when the lining is tested according to the standard test method GB/T 12705.2-2009 "Textile-Methods of testing the down-proof properties of fabrics-Part 2 Tumble test", the number of penetrating particles does not exceed a maximum of 15, more preferably Do not exceed a maximum of 10 and especially a maximum of 5.
根據DIN EN ISO 9237:1995-12測量的根據本發明的襯布的透氣性優選在10[dm3/s×m2]至450[dm3/s×m2],更優選在50[dm3/s×m2]至350[dm3/s×m2],尤其在100[dm3/s×m2]至300[dm3/s×m2]的範圍中。由此,所述襯布可良好地壓縮,確保當羽絨填充物潮濕時羽絨填充物的快速乾燥以及由於汗水能夠被運走而具有高的穿著舒適性,但同時提供熱作用。 The gas permeability of the interwoven fabric according to the invention measured according to DIN EN ISO 9237:1995-12 is preferably from 10 [dm 3 /s × m 2 ] to 450 [dm 3 /s × m 2 ], more preferably at 50 [dm 3 /s × m 2 ] to 350 [dm 3 /s × m 2 ], especially in the range of 100 [dm 3 /s × m 2 ] to 300 [dm 3 /s × m 2 ]. Thereby, the interlining can be well compressed, ensuring rapid drying of the down filling when the down filling is wet and high wearing comfort due to the sweat being able to be carried away, but at the same time providing thermal action.
由於使用聚氨酯作為纖維材料,根據本發明的襯布可良好地著色並且在熱影響、老化和/或光影響方面顯示出小的變黃趨勢。熔噴纖維與泡沫覆層的組合使用已經實現襯布的良好的內聚作用,使得能夠棄用纖維的熱熔合,例如借助於結構化的砑光輥的熱熔合。因此,能夠製成具有非常均勻的表面的根據本發明的襯布,所述表面尤其不具有發亮的焊接點。聚氨酯纖維與泡沫覆層的組合使用還實現良好的耐熱性。 Due to the use of polyurethane as the fibrous material, the interlining according to the invention can be well colored and exhibits a small yellowing tendency in terms of heat influence, aging and/or light influence. The combined use of meltblown fibers and foam coatings has achieved good cohesion of the interlining, enabling the thermal fusion of the fibers to be discarded, for example by means of thermal fusion of structured calender rolls. Thus, it is possible to produce a lining according to the invention having a very uniform surface, which surface in particular does not have shiny solder joints. The combination of polyurethane fibers and foam coatings also achieves good heat resistance.
在本發明的一個實施方式中,泡沫覆層具有分佈其中的熱熔膠。替選地,熱熔膠也能夠例如作為散佈的粉末層和/或附著物質點存在於泡沫覆層 上。熱熔膠長久以來是已知的。優選的熱熔膠是熱塑性聚合物,如共聚醯胺、共聚酯、聚乙烯(PE)、聚丙烯(PP)和/或其混合物和/或共聚物。 In one embodiment of the invention, the foam coating has a hot melt adhesive distributed therein. Alternatively, the hot melt adhesive can also be present on the foam coating, for example as a dispersed powder layer and/or an adherent material. Hot melt adhesives have long been known. Preferred hot melt adhesives are thermoplastic polymers such as copolyamines, copolyesters, polyethylene (PE), polypropylene (PP) and/or mixtures and/or copolymers thereof.
熱熔膠的熔點範圍優選為70℃至190℃,更優選為80℃至150℃,更優選為90℃至130℃。 The melting point of the hot melt adhesive is preferably from 70 ° C to 190 ° C, more preferably from 80 ° C to 150 ° C, still more preferably from 90 ° C to 130 ° C.
根據本發明,熱熔膠尤其優選是共聚醯胺或共聚酯。借助這些熱熔膠,襯布可在良好的分離力下與外層面料黏接。然而,根據本發明的襯布也能夠藉由縫合來與外層面料連接。該實施方式的優點是,與用熱熔膠連接的襯布不同,複合結構的手感不變硬。 According to the invention, the hot melt adhesive is particularly preferably a copolymerized decylamine or a copolyester. With these hot melt adhesives, the interlining can be bonded to the outer fabric with good separation force. However, the interlining according to the invention can also be joined to the outer fabric by stitching. An advantage of this embodiment is that unlike the linings that are joined by hot melt adhesive, the feel of the composite structure does not become stiff.
已發現,專用的泡沫覆層根據本發明使得襯布的滑動能力能夠如下有針對性地調節:能夠達到可縫合性的理想值。對於該目的,滑動能力同樣也不應過低,以便確保襯布經過縫合機的壓腳並且在縫合針上滑動。 It has been found that a dedicated foam coating according to the invention enables the sliding ability of the lining to be adjusted in a targeted manner as follows: an ideal value for the stitchability can be achieved. For this purpose, the sliding ability should also not be too low in order to ensure that the lining passes through the presser foot of the sewing machine and slides over the sewing needle.
根據本發明的襯布的另一優點是,所述襯布能夠用具有均勻厚度的平坦的、均勻的表面製成從而也能夠用呈均勻的外觀的非常輕的、透明的外層面料加工。 A further advantage of the lining according to the invention is that the lining can be made with a flat, uniform surface of uniform thickness and thus also with a very light, transparent outer layer of fabric having a uniform appearance.
泡沫覆層占襯布的份額能夠與襯布的所期望的特性相關,例如關於分別所期望的彈性變化。實際研究已經表明:在沒有如果需要的話所存在的載體材料的情況下,分別按襯布的總重量計,如果泡沫覆層占襯布的重量份額在20重量%至80重量%的範圍中,尤其優選在70重量%至40重量%的範圍中,那麼能夠獲得具有由柔軟性和雙彈性構成的尤其良好的組合的襯布。 The proportion of the foam coating in the lining can be related to the desired properties of the lining, for example with respect to the respectively desired elastic change. Practical studies have shown that, in the absence of a carrier material which is present if desired, it is particularly preferred if the foam coating comprises a weight fraction of the interlining in the range from 20% by weight to 80% by weight, based on the total weight of the lining, respectively. In the range from 70% by weight to 40% by weight, it is then possible to obtain a lining having a particularly good combination of softness and bi-elasticity.
泡沫覆層的層厚度能夠根據面料的所期望的特性設置。對於大多數應用目的已證實有利的是,對於泡沫覆層,設置在5μm至400μm,優選在5μm至100μm並且尤其在10μm至50μm的範圍中的平均層厚度。層厚度能夠以電子顯微鏡的方式確定。 The layer thickness of the foam coating can be set according to the desired properties of the fabric. For most application purposes, it has proven to be advantageous for the foam coating to have an average layer thickness in the range from 5 μm to 400 μm, preferably from 5 μm to 100 μm and in particular from 10 μm to 50 μm. The layer thickness can be determined by electron microscopy.
根據本發明的襯布即時在泡沫覆層的量相對高的情況下也具有柔軟的紡織手感和良好的褶皺能力。原則上,泡沫覆層的份額也能夠被設置為比80重量%更高的值。然而,在這種情況下,必須接受關於不織織物的抗撕裂強度、紡織特徵和柔軟性方面的損失。泡沫覆層的份額也能夠設置為低於20重量%。然而,在這種情況下,襯布的防絨性、雙彈性和其對於熱熔膠的結合能力降低。 The lining according to the invention also has a soft textile hand and good pleating ability in the case of a relatively high amount of foam coating. In principle, the proportion of the foam coating can also be set to a value higher than 80% by weight. However, in this case, it is necessary to accept a loss in tear strength, textile characteristics, and softness of the nonwoven fabric. The proportion of the foam coating can also be set below 20% by weight. However, in this case, the lining resistance, the double elasticity, and the ability to bond the hot melt adhesive are lowered.
泡沫覆層的份額越高,不織織物的透氣性就越低,這提高襯布的熱隔離特性。在泡沫覆層伸長時藉由熱產生的熵效應附加地有助於熱作用。 The higher the share of the foam coating, the lower the air permeability of the nonwoven fabric, which improves the thermal insulation properties of the lining. The entropy effect produced by the heat as the foam coating elongates additionally contributes to the thermal action.
其他的功能特性,如親水性、防水或防油、熱調節或阻燃的特性,如果期望的話,能夠以簡單的方式方法藉由使用根據習知技術已知的、產生這些效果的添加劑來設置。熱調節特性例如能夠借助微膠囊化的相變材料,例如基於烷烴的相變材料設置。 Other functional properties, such as hydrophilic, water-repellent or oil-repellent, heat-regulating or flame-retardant properties, can be set in a simple manner by using additives known from the prior art to produce these effects, if desired. . The thermal conditioning properties can, for example, be provided by means of microencapsulated phase change materials, for example alkane-based phase change materials.
醋酸乙烯酯共聚物和/或聚丙烯酸酯和/或聚氨酯能夠用於泡沫覆層。 Vinyl acetate copolymers and/or polyacrylates and/or polyurethanes can be used for the foam coating.
泡沫覆層能夠以傳統方式藉由聚合物分散體或聚合物乳濁液起泡,例如藉由機械碰撞製備並且藉由通常的塗覆方法、例如刮塗法塗覆。 The foam coating can be foamed in a conventional manner by polymer dispersion or polymer emulsion, for example by mechanical impact and by conventional coating methods such as knife coating.
使用醋酸乙烯酯共聚物的優點是:在熱過程中,如在甚至高達140℃進行熨燙或在高達60℃進行洗滌時,所產生的泡沫覆層不黏接或僅微弱地黏接,使得所述襯布可再次無損地分離。附加地,醋酸乙烯酯共聚物簡單並且成本低地製備。用其製成的襯布還具有尤其小的變黃趨勢並且顯示出極低的染色(color-pick-up),也就是說,被小程度地在洗滌時從其他紡織品離開的著色劑污染。此外,襯布顯示出尤其輕微的皺縮。 The advantage of using a vinyl acetate copolymer is that during the thermal process, such as ironing at even up to 140 ° C or washing up to 60 ° C, the resulting foam coating does not stick or only weakly bond, making The lining can be separated again without damage. Additionally, vinyl acetate copolymers are prepared simply and at low cost. The linings made therefrom also have a particularly small yellowing tendency and exhibit a very low color-pick-up, that is to say, being contaminated with a small amount of coloring agent which leaves the other textiles during washing. In addition, the interlining shows a particularly slight shrinkage.
優選的醋酸乙烯酯共聚物是醋酸乙烯酯-乙烯共聚物。這些共聚物例如能夠借助乳濁液聚合來製備。因此,根據本發明,醋酸乙烯酯共聚物優選基於含水的醋酸乙烯酯-乳濁液和/或醋酸乙烯酯-分散體,尤其基於包含65重量%至98重量%的醋酸乙烯酯的醋酸乙烯酯-乙烯-乳濁液和/或醋酸乙烯酯-乙烯-分散體來製備。分別按單體的總重量計,醋酸乙烯酯-乙烯-乳濁液和/或醋酸乙烯酯-乙烯-分散體優選在含水介質中包含65重量%至98重量%的醋酸乙烯酯以及2重量%至30重量%的乙烯,優選係75重量%至95重量%的醋酸乙烯酯和5重量%至25重量%的乙烯。 A preferred vinyl acetate copolymer is a vinyl acetate-ethylene copolymer. These copolymers can be prepared, for example, by emulsion polymerization. Thus, according to the invention, the vinyl acetate copolymer is preferably based on aqueous vinyl acetate-emulsion and/or vinyl acetate-dispersion, in particular based on vinyl acetate comprising from 65% to 98% by weight of vinyl acetate. - Ethylene-emulsion and/or vinyl acetate-ethylene-dispersion. The vinyl acetate-ethylene-emulsion and/or vinyl acetate-ethylene-dispersion preferably comprises from 65% to 98% by weight of vinyl acetate and 2% by weight, based on the total weight of the monomers, respectively, in an aqueous medium. Up to 30% by weight of ethylene, preferably from 75% to 95% by weight of vinyl acetate and from 5% to 25% by weight of ethylene.
分別按單體的總重量計,醋酸乙烯酯-乳濁液和/或醋酸乙烯酯-分散體必要時還能夠包含直至10重量%、優選係0.1重量%至10重量%的其他共聚單體。 The vinyl acetate-emulsion and/or vinyl acetate dispersion can also comprise up to 10% by weight, preferably from 0.1% to 10% by weight, based on the total weight of the monomers, of further comonomers.
用於醋酸乙烯酯-乳濁液和/或醋酸乙烯酯-分散體的其他適合的共聚單體例如選自:在羧基殘基中具有3個至12個碳原子的乙烯基酯,如丙酸乙烯酯;月桂酸乙烯酯;具有8個至11個碳原子的α-支鏈的羧酸的乙烯基酯。具有1個至15個碳原子的未分支的或分支的醇的甲基丙烯酸酯或丙烯酸 酯,如丙烯酸甲酯、甲基丙烯酸甲酯、丙烯酸乙酯、甲基丙烯酸乙酯、丙烯酸丙酯、甲基丙烯酸丙酯、丙烯酸正丁酯、甲基丙烯酸正丁酯、2-乙基己基丙烯酸酯、丙烯酸降冰片酯也是適合的。乙烯基鹵化物如氯乙烯也是適合的。 Further suitable comonomers for the vinyl acetate-emulsion and/or vinyl acetate-dispersion are, for example, selected from the group consisting of vinyl esters having from 3 to 12 carbon atoms in the carboxyl residue, such as propionic acid Vinyl ester; vinyl laurate; vinyl ester of an alpha-branched carboxylic acid having from 8 to 11 carbon atoms. a methacrylate or acrylate of an unbranched or branched alcohol having from 1 to 15 carbon atoms, such as methyl acrylate, methyl methacrylate, ethyl acrylate, ethyl methacrylate, propyl acrylate, Propyl methacrylate, n-butyl acrylate, n-butyl methacrylate, 2-ethylhexyl acrylate, and norbornyl acrylate are also suitable. Vinyl halides such as vinyl chloride are also suitable.
其它適合的共聚單體也是烯屬不飽和單羧酸和二羧酸,優選丙烯酸、甲基丙烯酸、富馬酸和馬來酸;烯屬不飽和羧酸醯胺和羧酸腈,優選丙烯醯胺和丙烯腈;富馬酸和馬來酸的單酯和二酯,如二乙酯和二異丙基酯,以及馬來酸酐;烯屬不飽和磺酸或其鹽類,優選乙烯基磺酸、2-丙烯醯胺基-2-甲基丙磺酸。其他實例是預交聯的共聚單體,如烯屬多重不飽和共聚單體,例如二乙烯基己二酸酯、馬來酸二烯丙酯、甲基丙烯酸烯丙酯或氰尿酸三烯丙酯,或者後交聯共聚單體,例如丙烯醯氨基乙醇酸(AGA)、甲基丙烯醯胺乙醇酸甲酯(MAGME)、N-羥甲基丙烯醯胺(NMA)、N-羥甲基甲基丙烯醯胺(NMMA)、N-羥甲基烯丙基氨基甲酸酯、烷基醚,如N-羥甲基丙烯醯胺的,N-羥甲基甲基丙烯醯胺的和N-羥甲基烯丙基氨基甲酸酯的異丁氧基醚或酯。具有羥基或羧基的單體也是適合的,例如甲基丙烯酸羥烷基酯和丙烯酸羥烷基酯,如丙烯酸羥乙酯、丙烯酸羥丙酯或丙烯酸羥丁酯或羥基甲基丙烯酸酯;以及1,3-二羰基化合物,如乙醯乙醯氧基乙酯、丙烯酸乙醯乙醯氧基甲基丙烯酸酯、乙醯乙醯氧基乙酯、乙醯乙酸乙酯、2,3-二(乙醯乙醯氧基)丙基甲基-聚丙烯酸酯和乙醯乙酸烯丙酯。 Other suitable comonomers are also ethylenically unsaturated monocarboxylic acids and dicarboxylic acids, preferably acrylic acid, methacrylic acid, fumaric acid and maleic acid; ethylenically unsaturated carboxylic acid decylamines and carboxylic acid nitriles, preferably acrylonitrile Amines and acrylonitrile; monoesters and diesters of fumaric acid and maleic acid, such as diethyl ester and diisopropyl ester, and maleic anhydride; ethylenically unsaturated sulfonic acids or salts thereof, preferably vinyl sulfonate Acid, 2-acrylamido-2-methylpropanesulfonic acid. Further examples are pre-crosslinked comonomers, such as olefinic polyunsaturated comonomers, such as divinyl adipate, diallyl maleate, allyl methacrylate or triallyl cyanurate Ester, or post-crosslinking comonomer, such as acrylonitrile aminoglycolic acid (AGA), methyl methacrylate methyl glycolate (MAGME), N-methylol acrylamide (NMA), N-methylol Methyl acrylamide (NMMA), N-methylol allyl carbamate, alkyl ether, such as N-methylol acrylamide, N-methylol methacrylamide and N - Isobutoxy ether or ester of hydroxymethylallyl carbamate. Monomers having a hydroxyl or carboxyl group are also suitable, such as hydroxyalkyl methacrylate and hydroxyalkyl acrylates such as hydroxyethyl acrylate, hydroxypropyl acrylate or hydroxybutyl acrylate or hydroxy methacrylate; , 3-dicarbonyl compound, such as acetamethylene ethoxyethyl ester, acetamethylene ethoxy methacrylate, acetamethylene ethoxyethyl ester, ethyl acetate ethyl acetate, 2,3-di ( Ethylene ethoxylated) propylmethyl-polyacrylate and allyl acetate.
在此,單體選擇優選進行為,使得醋酸乙烯酯共聚物,尤其醋酸乙烯酯-乙烯共聚物,具有-20℃至+20℃,優選係-20℃至+0℃,更優選係-20℃至-10℃的玻璃化轉變溫度Tg。 Here, the monomer selection is preferably carried out such that the vinyl acetate copolymer, especially the vinyl acetate-ethylene copolymer, has a temperature of from -20 ° C to +20 ° C, preferably from -20 ° C to +0 ° C, more preferably -20 Glass transition temperature Tg from °C to -10 °C.
聚合物的玻璃化轉變溫度Tg能夠以已知的方式借助DSC(差示掃描量熱法(Dynamische Differenz-Thermoanalyse),DIN EN ISO 11357-1/2)確定。Tg也能夠借助Fox方程近似估算。在聚合物手冊第二版,J.Wiley & Sons,New York(1975)中列舉均聚物的Tg值。 The glass transition temperature Tg of the polymer can be determined in a known manner by means of DSC (Dynamische Differenz-Thermoanalyse, DIN EN ISO 11357-1/2). Tg can also be approximated by the Fox equation. The Tg values of homopolymers are listed in the second edition of the Polymer Handbook, J. Wiley & Sons, New York (1975).
更尤其優選使用Celanese Emulsions公司商標名Vinamul®Elite 25的醋酸乙烯酯共聚物。 More particularly preferably, a vinyl acetate copolymer of the brand name Vinamul® Elite 25 of the company Celanese Emulsions is used.
優選的聚丙烯酸酯是聚丙烯酸丁酯,在下文中也簡稱丙烯酸丁酯。丙烯酸丁酯同樣能夠借助乳濁液聚合來製備。因此,聚丙烯酸酯優選基於聚丙 烯酸酯-乳濁液和/或聚丙烯酸酯-分散體,尤其如下丙烯酸丁酯-乳濁液和/或丙烯酸丁酯-分散體來製備,其包含優選至少40重量%,優選至少50重量%,尤其優選至少60重量%的丙烯酸正丁酯或甲基丙烯酸正丁酯(簡稱(甲基)丙烯酸正丁酯);優選是丙烯酸正丁酯。 A preferred polyacrylate is polybutyl acrylate, also referred to hereinafter as butyl acrylate. Butyl acrylate can also be prepared by emulsion polymerization. The polyacrylates are therefore preferably prepared on the basis of polyacrylate-emulsions and/or polyacrylate-dispersions, in particular butyl acrylate-emulsion and/or butyl acrylate-dispersions, which preferably comprise at least 40 % by weight, preferably at least 50% by weight, particularly preferably at least 60% by weight, of n-butyl acrylate or n-butyl methacrylate (abbreviated as n-butyl (meth) acrylate); preferably n-butyl acrylate.
除上述丙烯酸丁酯之外,聚丙烯酸酯-乳濁液和/或聚丙烯酸酯-分散體能夠包含其他共聚單體,優選選自:1至20個碳原子的烷基(甲基)丙烯酸酯、包含高達20個碳原子的羧酸的乙烯基酯、具有高達20個碳原子的乙烯基芳烴、烯屬不飽和腈、乙烯基鹵化物、包含1個至10個碳原子的醇的乙烯基醚、具有2個至8個碳原子和一個或兩個雙鍵的脂肪烴或這些單體的混合物。例如列舉具有C1-C10烷基的(甲基)丙烯酸酯,如甲基丙烯酸甲酯、丙烯酸甲酯、丙烯酸乙酯和2-乙基己基丙烯酸酯。 In addition to the abovementioned butyl acrylates, the polyacrylate-emulsion and/or polyacrylate-dispersion can comprise further comonomers, preferably selected from alkyl (meth) acrylates of from 1 to 20 carbon atoms. a vinyl ester of a carboxylic acid containing up to 20 carbon atoms, a vinyl arene having up to 20 carbon atoms, an ethylenically unsaturated nitrile, a vinyl halide, a vinyl group containing an alcohol of 1 to 10 carbon atoms An ether, an aliphatic hydrocarbon having 2 to 8 carbon atoms and one or two double bonds or a mixture of these monomers. For example, (meth) acrylates having a C1-C10 alkyl group such as methyl methacrylate, methyl acrylate, ethyl acrylate and 2-ethylhexyl acrylate are listed.
尤其優選的共聚單體是後交聯共聚單體,例如丙烯醯氨基乙醇酸(AGA)、甲基丙烯醯胺乙醇酸甲酯(MAGME)、N-羥甲基丙烯醯胺(NMA)、N-羥甲基甲基丙烯醯胺(NMMA)、N-羥甲基烯丙基氨基甲酸酯、烷基醚,如N-羥甲基丙烯醯胺的,N-羥甲基甲基丙烯醯胺的和N-羥甲基烯丙基氨基甲酸酯的異丁氧基醚或酯。 Particularly preferred comonomers are postcrosslinking comonomers such as propylene guanidine aminoglycolic acid (AGA), methyl methacrylate methyl glycolate (MAGME), N-methylol acrylamide (NMA), N - hydroxymethylmethacrylamide (NMMA), N-methylolallyl carbamate, alkyl ether, such as N-methylol acrylamide, N-methylol methacrylate Isobutoxy ether or ester of amine and N-methylolallyl carbamate.
在此,單體選擇優選進行為,使得聚丙烯酸酯,尤其丙烯酸丁酯,具有<-25℃,例如-50℃至-25℃,優選係-45℃至-25℃,更優選係-40℃至-25℃的玻璃化轉變溫度Tg。 Here, the monomer selection is preferably carried out such that the polyacrylate, especially butyl acrylate, has <-25 ° C, for example -50 ° C to -25 ° C, preferably -45 ° C to -25 ° C, more preferably -40 Glass transition temperature Tg from °C to -25 °C.
更尤其優選使用Archroma公司的商標名為Appretan® N 92100的聚丙烯酸酯。 It is more particularly preferred to use a polyacrylate ester of the type of Appretan® N 92100 from Archroma.
使用聚丙烯酸酯的優點是,所述聚丙烯酸酯價格便宜並且儘管如此仍實現良好的防絨性。 The advantage of using polyacrylates is that the polyacrylates are inexpensive and nevertheless achieve good anti-velvet properties.
此外,對於泡沫覆層能夠使用各種聚氨酯。根據本發明,優選的是脂肪族聚氨酯,因為所述脂肪族聚氨酯具有僅輕微的變黃趨勢。尤其優選的是聚酯型聚氨酯。同樣尤其優選的是由含水的聚合物分散體製備的聚氨酯。 根據本發明,尤其優選藉由如下方式進行聚氨酯的製備I.將a)至少一個多元的脂肪族異氰酸酯或芳香族異氰酸酯,b)二元醇,其中b1)按二元醇(b)的總量計占10摩爾%至100摩爾%, 具有500至5000的分子量,而b2)按二元醇(b)的總量計占0摩爾%至90摩爾%,具有60至500g/mol的分子量,c)與單體(a)、(b)不同的單體,所述單體具有至少一個異氰酸酯基團或至少一個相對於異氰酸酯基團反應性基團,所述反應性基團還承載至少一個親水基團或潛在的親水基團,由此引起聚氨酯的水中可分散性,在存在溶劑時轉化成聚氨酯,並且II.緊接著使聚氨酯分散在水中。 In addition, various polyurethanes can be used for the foam coating. According to the invention, aliphatic polyurethanes are preferred because the aliphatic polyurethanes have a slight yellowing tendency. Particularly preferred is a polyester polyurethane. Also especially preferred are polyurethanes prepared from aqueous polymer dispersions. According to the invention, it is especially preferred to carry out the preparation of the polyurethane by the following: I) a) at least one polybasic aliphatic isocyanate or aromatic isocyanate, b) a diol, wherein b1) is based on the total amount of the diol (b) 10% to 100% by mole, having a molecular weight of 500 to 5,000, and b2) 0% to 90% by mole based on the total amount of the diol (b), having a molecular weight of 60 to 500 g/mol, c a monomer different from the monomers (a), (b) having at least one isocyanate group or at least one reactive group relative to an isocyanate group, the reactive group also carrying at least one hydrophilic group A group or a latent hydrophilic group, thereby causing dispersibility in the water of the polyurethane, conversion to polyurethane in the presence of a solvent, and II. followed by dispersing the polyurethane in water.
尤其優選的是脂肪族異氰酸酯,其中全部異氰酸酯基團結合到脂肪鏈上。 Especially preferred are aliphatic isocyanates in which all isocyanate groups are bonded to the fatty chain.
根據本發明優選的脂肪族異氰酸酯包括4個至12個碳原子。優選的脂肪族異氰酸酯是四亞甲基二異氰酸酯、六亞甲基二異氰酸酯(1,6-二異氰酸己烷)、八亞甲基二異氰酸酯、十亞甲基二異氰酸酯、十二亞甲基二異氰酸酯、十四亞甲基二異氰酸酯、賴氨酸二異氰酸酯的酯、四甲基苯二甲基二異氰酸酯、三甲基己烷二異氰酸酯或四甲基己烷二異氰酸酯,尤其優選的是1,6-六亞甲基二異氰酸酯。 Preferred aliphatic isocyanates according to the invention comprise from 4 to 12 carbon atoms. Preferred aliphatic isocyanates are tetramethylene diisocyanate, hexamethylene diisocyanate (hexane, 1,6-diisocyanate), octamethylene diisocyanate, decamethylene diisocyanate, twelve methylene Particularly preferred is bis-isocyanate, tetradecyl diisocyanate, ester of lysine diisocyanate, tetramethyl dimethyl diisocyanate, trimethyl hexane diisocyanate or tetramethyl hexane diisocyanate. 1,6-hexamethylene diisocyanate.
根據本發明優選的芳香族異氰酸酯是:異佛爾酮二異氰酸酯、甲苯二異氰酸酯、二環己基甲烷二異氰酸酯、亞苯基二異氰酸酯、2,4-甲苯二異氰酸酯和2,6-甲苯二異氰酸酯、苯基異氰酸酯、二苯基甲烷系列的異氰酸酯、1,5-萘二異氰酸酯、對氯苯基異氰酸酯、碳二亞胺化的三異丙基亞苯基二異氰酸酯。 Preferred aromatic isocyanates according to the invention are: isophorone diisocyanate, toluene diisocyanate, dicyclohexylmethane diisocyanate, phenylene diisocyanate, 2,4-toluene diisocyanate and 2,6-toluene diisocyanate, Phenyl isocyanate, diphenylmethane series isocyanate, 1,5-naphthalene diisocyanate, p-chlorophenyl isocyanate, carbodiimidated triisopropylphenylene diisocyanate.
首先考慮高分子量的二元醇(b1)作為二元醇(b),其具有大約500g/mol至5000g/mol,優選係大約700g/mol至3000g/mol,尤其優選係800g/mol至2500g/mol的數均分子量(Mn)。 The high molecular weight diol (b1) is first considered as the diol (b) having from about 500 g/mol to 5000 g/mol, preferably from about 700 g/mol to 3000 g/mol, particularly preferably from 800 g/mol to 2500 g/ The number average molecular weight (Mn) of mol.
根據本發明,二元醇(b1)是聚酯多元醇。除二元醇(b1)之外,還使用具有大約50g/mol至500g/mol,優選係60g/mol至200g/mol的分子量的低分子量的二元醇(b2)作為二元醇(b)。 According to the invention, the diol (b1) is a polyester polyol. In addition to the diol (b1), a low molecular weight diol (b2) having a molecular weight of from about 50 g/mol to 500 g/mol, preferably from 60 g/mol to 200 g/mol, is used as the diol (b) .
主要使用對於製備聚酯多元醇所提及的短鏈的烷基二醇的構造成分作為單體(b2),例如乙二醇、1,2-丙二醇、1,3-丙二醇、1,1-二甲基乙烷-1,2-二醇、2-丁基-2-乙基-1,3-丙二醇、2-乙基-1,3-丙二醇、2-甲基-1,3-丙二醇、新戊二醇、羥基特戊酸新戊二醇酯、1,2-丁二醇、1,3-丁二醇或1,4-丁二醇、 1,6-己二醇、1,10-癸二醇、異亞丙基雙(4-羥基環己烷)、四甲基環丁二醇、1,2-環己二醇、1,3-環己二醇或1,4-環己二醇、環辛二醇、降冰片烷二醇、蒎二醇、十氫化萘二醇、2-乙基-1,3-己二醇、2,4-二乙基辛烷-1,3-二醇、氫醌、雙酚A、雙酚F、雙酚B、雙酚S、2,2-雙(4-羥基環己基)丙烷、1,1-環己烷二甲醇、1,2-環己烷二甲醇、1,3-環己烷二甲醇和1,4-環己烷二甲醇、1,2-環己二醇、1,3-環己二醇或1,4-環己二醇,其中優選具有2個至12個碳原子和偶數個碳原子的未分支二元醇以及戊二醇-1,5和新戊二醇。 The constituent component of the short-chain alkyl diol mentioned for the preparation of the polyester polyol is mainly used as the monomer (b2), such as ethylene glycol, 1,2-propanediol, 1,3-propanediol, 1,1- Dimethylethane-1,2-diol, 2-butyl-2-ethyl-1,3-propanediol, 2-ethyl-1,3-propanediol, 2-methyl-1,3-propanediol , neopentyl glycol, neopentyl glycol hydroxypivalate, 1,2-butanediol, 1,3-butanediol or 1,4-butanediol, 1,6-hexanediol, 1, 10-decanediol, isopropylidene bis(4-hydroxycyclohexane), tetramethylcyclobutanediol, 1,2-cyclohexanediol, 1,3-cyclohexanediol or 1,4- Cyclohexanediol, cyclooctanediol, norbornanediol, decanediol, decalindiol, 2-ethyl-1,3-hexanediol, 2,4-diethyloctane-1 , 3-diol, hydroquinone, bisphenol A, bisphenol F, bisphenol B, bisphenol S, 2,2-bis(4-hydroxycyclohexyl)propane, 1,1-cyclohexanedimethanol, 1 , 2-cyclohexanedimethanol, 1,3-cyclohexanedimethanol and 1,4-cyclohexanedimethanol, 1,2-cyclohexanediol, 1,3-cyclohexanediol or 1,4 a cyclohexanediol, preferably an unbranched diol having 2 to 12 carbon atoms and an even number of carbon atoms, and pentanediol-1,5 and pentane Alcohol.
為了達到聚氨酯的水中可分散性,除組分(a)和(b)之外,聚氨酯優選由與組分(a)、(b)不同的單體(c)構成,所述單體(c)承載至少一個異氰酸酯基團或至少一個相對於異氰酸酯基團反應性基團的並且此外承載至少一個親水性基團或可轉化成親水基團的基團。在下文中,術語“親水性基團或潛在的親水性基團”簡寫為“(潛在的)親水性基團”。與單體的用於構成聚合物主鏈的官能團相比,(潛在的)親水性基團與異氰酸酯明顯更緩慢地反應。(潛在的)親水性基團能夠是非離子親水性基團或優選是離子親水性基團,即陽離子親水性基團或陰離子親水性基團,或者是潛在的離子的親水性基團並且尤其優選是陰離子親水性基團或潛在的陰離子親水性基團。 In order to achieve dispersibility in water of the polyurethane, in addition to the components (a) and (b), the polyurethane preferably consists of a monomer (c) different from the components (a) and (b), the monomer (c) A group carrying at least one isocyanate group or at least one reactive group relative to the isocyanate group and which additionally carries at least one hydrophilic group or which can be converted into a hydrophilic group. Hereinafter, the term "hydrophilic group or potentially hydrophilic group" is abbreviated as "(potentially) hydrophilic group". The (potential) hydrophilic group reacts significantly more slowly with the isocyanate than the monomeric functional group used to form the polymer backbone. The (potential) hydrophilic group can be a nonionic hydrophilic group or preferably an ionic hydrophilic group, ie a cationic hydrophilic group or an anionic hydrophilic group, or a latent hydrophilic group and is particularly preferred It is an anionic hydrophilic group or a latent anionic hydrophilic group.
例如考慮由優選為5至100,優選為10至80的環氧乙烷重複單元構成的混合的或純的聚乙二醇醚作為非離子親水性基團。聚乙二醇醚也能夠包含環氧丙烷單元。如果是這種情況,那麼按混合的聚乙二醇醚計,環氧丙烷單元的含量應不超過50重量%,優選為不超過30重量%。 For example, a mixed or pure polyethylene glycol ether composed of an ethylene oxide repeating unit of preferably 5 to 100, preferably 10 to 80, is considered as a nonionic hydrophilic group. Polyglycol ethers can also contain propylene oxide units. If this is the case, the content of the propylene oxide unit should not exceed 50% by weight, preferably not more than 30% by weight, based on the mixed polyethylene glycol ether.
在此,單體選擇優選進行為,使得聚氨酯,尤其脂肪族聚氨酯,具有0℃至-65℃,優選係-60℃至-20℃,更優選係-55℃至-30℃的玻璃化轉變溫度Tg。 Here, the monomer selection is preferably carried out such that the polyurethane, especially the aliphatic polyurethane, has a glass transition of from 0 ° C to -65 ° C, preferably from -60 ° C to -20 ° C, more preferably from -55 ° C to -30 ° C. Temperature Tg.
更尤其優選使用CHT R.BEITLICH有限責任公司商標名為PUS的聚氨酯。 More particularly preferably, polyurethanes of the trademark PUS by CHT R. BEITLICH GmbH are used.
使用泡沫覆層的優點是,所述泡沫覆層是透氣和透濕的,這對穿著舒適性產生積極作用。泡沫覆層的多孔結構還實現均勻的空氣迴圈和均勻的透氣性。 An advantage of using a foam coating is that the foam coating is breathable and moisture permeable, which has a positive effect on wearing comfort. The porous structure of the foam coating also achieves a uniform air loop and uniform gas permeability.
此外,相對於通常以旋轉絲網印刷方法或借助刮塗方法施加的傳統的漿 覆層,泡沫覆層的施加通常提供不同的優點。 Moreover, the application of the foam coating generally provides different advantages over conventional coatings typically applied by rotary screen printing methods or by means of knife coating methods.
因此,泡沫覆層與純的漿印相比是明顯更成本有效的,因為在相同的塗層中原料的份額是明顯更少的。 Therefore, the foam coating is significantly more cost effective than pure paste printing because the share of the raw materials in the same coating is significantly less.
另一優點是:穿過襯布滲透係小程度地發生。而純的黏合劑印刷混合物(Binderdruckmischung)明顯更強滲透到襯布中/滲透穿過襯布。 Another advantage is that the permeation through the lining occurs to a small extent. The pure binder printing mixture (Binderdruckmischung) is significantly more penetrating into the lining/infiltrating through the lining.
根據本發明的一個優選的實施方式,泡沫覆層具有多孔結構,在所述多孔結構中超過50%的孔具有根據DIN ASTM E 1294測量的直徑,所述直徑在1μm至100μm,優選5μm至30μm範圍中。 According to a preferred embodiment of the invention, the foam coating has a porous structure in which more than 50% of the pores have a diameter measured according to DIN ASTM E 1294, said diameter being between 1 μm and 100 μm, preferably between 5 μm and 30 μm In the scope.
泡沫覆層的聚合物能夠以化學交聯或非交聯的方式存在。根據本發明,聚合物優選至少部分地以交聯的方式存在。因此,泡沫覆層能夠具有至少一種交聯劑。藉由使用交聯劑來調整泡沫覆層的聚合物,能夠有針對性地調整泡沫覆層的黏彈特性並且設置揭取性能。此外,藉由交聯劑能夠有針對性地改變手感和耐清洗性。因此,藉由使用交聯劑,主要是在洗滌或化學清洗之後能夠實現包含熱熔膠的泡沫的分離力的性能提高。 The foam coated polymer can be present in a chemically crosslinked or non-crosslinked manner. According to the invention, the polymer is preferably present at least partially in a crosslinked manner. Thus, the foam coating can have at least one crosslinking agent. By using a crosslinking agent to adjust the polymer of the foam coating, the viscoelastic properties of the foam coating can be adjusted in a targeted manner and the peeling performance can be set. In addition, the handle and the washability can be changed in a targeted manner by the crosslinking agent. Therefore, by using a crosslinking agent, the performance of the separation force of the foam containing the hot melt adhesive can be improved mainly after washing or chemical cleaning.
根據本發明已證實有利的是,泡沫覆層包含起泡劑,尤其表面活性劑。 It has proven to be advantageous according to the invention for the foam coating to comprise a foaming agent, in particular a surfactant.
同樣證實有利的是,泡沫覆層包含增稠劑,尤其纖維素醚、聚丙烯酸酯、聚丙烯醯胺、聚醚或聚氨酯-增稠劑。 It has also proven to be advantageous for the foam coating to comprise a thickener, in particular a cellulose ether, a polyacrylate, a polyacrylamide, a polyether or a polyurethane-thickener.
此外,已證實有利的是,泡沫覆層包含手感增強劑(Griffgebungsmittel),尤其矽樹脂。 Furthermore, it has proven to be advantageous for the foam coating to comprise a hand-feeling agent, in particular an anthracene resin.
本發明的另一主題是一種用於製備根據本發明的襯布的方法,所述方法包括下列步驟:製備和/或提供包括熔融紡絲的熔噴聚氨酯纖維的熔噴不織織物並且將包含醋酸乙烯酯共聚物和/或聚丙烯酸酯和/或聚氨酯的泡沫覆層施加在不織織物上。 A further subject of the invention is a process for the preparation of a lining according to the invention, which comprises the steps of preparing and/or providing a meltblown nonwoven fabric comprising melt-spun meltblown polyurethane fibers and comprising acetic acid A foam coating of a vinyl ester copolymer and/or a polyacrylate and/or polyurethane is applied to the nonwoven fabric.
將泡沫覆層施加到不織織物上能夠根據本領域技術人員已知的各種塗覆技術執行。泡沫覆層優選以起泡的水基聚合物分散體或聚合物乳濁液的形式施加到不織織物上。必要時,所述泡沫覆層能夠包含其他附加物,例如上述添加劑。 Application of the foam coating to the nonwoven fabric can be performed according to various coating techniques known to those skilled in the art. The foam coating is preferably applied to the nonwoven fabric in the form of a foamed water-based polymer dispersion or a polymer emulsion. If desired, the foam coating can contain other addenda such as the above additives.
由於泡沫結構,在乾燥之後能夠避免由聚合物分散體形成完全封閉的膜。根據方法,膜的形成能夠作為纖維之間的跨度帆(Spannsegel)點狀 地進行,或者作為面狀的具有孔的膜進行。 Due to the foam structure, it is possible to avoid the formation of a completely closed film from the polymer dispersion after drying. According to the method, the formation of the film can be carried out as a span of the span between the fibers, or as a planar film having pores.
根據本發明,泡沫覆層的塗覆優選借助塗抹法、印刷法,如藉由借助於印刷模版的輪轉絲網印刷執行,或借助浸漬執行。 According to the invention, the coating of the foam coating is preferably carried out by means of smearing, printing, for example by rotary screen printing by means of a printing stencil, or by means of impregnation.
在塗覆泡沫覆層之後,所述泡沫覆層優選,尤其優選在低於纖維的熔化範圍或分解溫度的溫度中藉由熱處理來硬化。硬化優選在溫度處於60℃至200℃的範圍中時進行15s至120s。根據本發明的襯布為了與外層面料黏合能夠設置有熱熔膠。這例如藉由如下方式發生:熱熔膠優選以具有聚合物分散體的粉末形式施加,使得無需其他覆層步驟就能夠獲得熱熔膠覆層的襯布,或者使得所述熱熔膠作為粉末散佈到泡沫覆層上。所述熱熔膠也能夠作為附著物質點施加到襯布上。 After the application of the foam coating, the foam coating preferably, preferably, is hardened by heat treatment at a temperature below the melting range or decomposition temperature of the fiber. The hardening is preferably carried out for 15 s to 120 s when the temperature is in the range of 60 ° C to 200 ° C. The lining according to the present invention can be provided with a hot melt adhesive for bonding to the outer layer fabric. This takes place, for example, by the fact that the hot melt adhesive is preferably applied in the form of a powder having a polymer dispersion, so that a lining of the hot melt adhesive layer can be obtained without additional coating steps, or the hot melt adhesive can be dispersed as a powder. On the foam coating. The hot melt adhesive can also be applied to the lining as a point of attachment.
然而,根據本發明襯布優選係被縫合。為此,泡沫覆層優選係不具有帶有熱熔膠的覆層。用其加工襯布的外層面料優選係具有50g/qm至400g/qm,更優選係在小於300g/qm,更尤其優選係小於200g/qm的重量。 However, the lining according to the invention is preferably stitched. For this purpose, the foam coating preferably does not have a coating with a hot melt adhesive. The outer layer fabric from which the interlining is processed preferably has a weight of from 50 g/qm to 400 g/qm, more preferably less than 300 g/qm, still more preferably less than 200 g/qm.
本發明的主題也是一種填充有羽絨的紡織產品,尤其選自夾克、床上用品、靠墊、床墊或睡袋,所述紡織產品包括紡織包套和包含在其中的羽絨。包套包括用於防止羽絨鑽出的上述襯布。 The subject of the invention is also a down-filled textile product, in particular selected from the group consisting of a jacket, a bedding, a cushion, a mattress or a sleeping bag, said textile product comprising a textile wrap and a downhole contained therein. The wrap includes the above-described interlining for preventing down feathers from being drilled.
包套是一種紡織層,所述紡織層具有適合的形狀,以便保存位於其中的羽絨。紡織包套基本上能夠由襯布構成,優選係與外層面料組合地構成。這表示,襯布以與外層面料組合的方式至少形成紡織包套的一部分,藉由所述部分實現羽絨的保存和與環境的分離。此外,紡織包套能夠為了其他目的而改型,例如配備有裝飾元件或封閉機構,如按鈕或拉鍊。 The wrap is a textile layer having a suitable shape to preserve the downhole located therein. The textile wrap can consist essentially of a lining, preferably in combination with an outer fabric. This means that the interlining forms at least part of the textile wrap in combination with the outer fabric, by which the preservation of the down and separation from the environment is achieved. In addition, the textile wrap can be modified for other purposes, such as with decorative elements or closure mechanisms such as buttons or zippers.
紡織產品優選是床上用品、夾克、靠墊、床墊或睡袋。紡織產品尤其優選是夾克。由於兼具良好的機械特性和尤其高的柔軟性和彈性的防絨性,襯布與外層面料組合也適合作為身體墊板或身體護墊,如床罩、枕頭或褥墊。 The textile product is preferably a bedding, a jacket, a cushion, a mattress or a sleeping bag. The textile product is especially preferably a jacket. Due to the combination of good mechanical properties and especially high softness and elastic fleece, the combination of interlining and outer fabric is also suitable as a body pad or body pad, such as a bed cover, pillow or mattress.
本發明的另一主題是襯布用於防止羽絨從填充有羽絨的紡織產品中鑽出的應用,尤其作為在服裝和家用紡織品如羽絨夾克、床上用品、睡袋中的防絨襯布的應用。除羽絨之外,填充物也能夠包含其他常見的填充材料,如羽毛或合成的填充材料。對於紡織應用而言,羽絨經常用作為混有羽毛的混合物。羽絨占填充物的份額優選至少為30重量%或至少50重量%, 尤其至少70重量%。 Another subject of the invention is the use of a lining for preventing duvets from being drilled from down-filled textile products, especially as an anti-velvet lining in garments and household textiles such as down jackets, bedding, and sleeping bags. In addition to down, the filler can also contain other common filler materials such as feathers or synthetic filler materials. For textile applications, down is often used as a mixture of feathers. The proportion of the down filling to the filler is preferably at least 30% by weight or at least 50% by weight, in particular at least 70% by weight.
在一個優選的實施方式中,襯布直接接觸羽絨填充物。這表示,在襯布和羽絨之間不存在其他層。 In a preferred embodiment, the lining is in direct contact with the down filling. This means that there are no other layers between the lining and the down.
在此,優選的是,襯布的具有泡沫覆層的側面直接鄰接羽絨從而形成屏障。 Here, it is preferred that the side of the lining with the foam coating directly adjoins the down to form a barrier.
在下文中根據多個實例詳細闡述本發明。 The invention is explained in detail below on the basis of a plurality of examples.
在實例中使用包含下列型號的熔融紡絲的熔噴聚氨酯纖維的熔噴不織織物:肖氏A硬度為86並且熔化範圍為160℃至175℃的基於聚醚的熱塑性脂肪族聚氨酯,所述熱塑性脂肪族聚氨酯在含水量<0.1%時在標準熔噴設備上紡絲。 A meltblown nonwoven fabric comprising melt spun meltblown polyurethane fibers of the following type is used in the examples: a polyether-based thermoplastic aliphatic polyurethane having a Shore A hardness of 86 and a melting range of 160 ° C to 175 ° C, The thermoplastic aliphatic polyurethane is spun on a standard meltblowing apparatus at a water content of <0.1%.
實例1:借助刮塗法製備根據本發明的可縫合的襯布 Example 1: Preparation of a sewable interlining according to the present invention by means of a doctor blade method
413g的基於丙烯醯胺、乙烯和N-羥甲基丙烯醯胺(固體含量55%)的含水醋酸乙烯酯-聚合物分散體與318g的基於硬酯酸銨的起泡劑(固體含量30%)和103g的基於聚氫甲基矽氧烷(固體含量44%)的乳濁液以及與12g的水在攪拌條件下混合。所給出的固體含量是重量份額,所述重量份額能夠在液態成分蒸發之後藉由稱量重量確定。 413 g of aqueous vinyl acetate-polymer dispersion based on acrylamide, ethylene and N-methylol acrylamide (55% solids) and 318 g of ammonium stearate-based foaming agent (30% solids) And 103 g of an emulsion based on polyhydrogen methyloxane (44% solids content) and with 12 g of water were mixed under stirring. The solids content given is a weight fraction which can be determined by weighing the liquid component after evaporation of the liquid component.
混合物在攪拌條件下用154g的由甲基羥乙基纖維素構成的原液增稠。為了製備原液,29.1g的甲基羥乙基纖維素(固體含量100%)拌入970.9g的水中並且可在室溫下泡脹48h。原液的黏度為50000cp至75000cp。 The mixture was thickened with 154 g of a stock solution consisting of methyl hydroxyethyl cellulose under stirring. To prepare the stock solution, 29.1 g of methyl hydroxyethyl cellulose (solid content 100%) was stirred into 970.9 g of water and allowed to swell for 48 h at room temperature. The viscosity of the stock solution is from 50,000 cp to 75,000 cp.
在添加原液之後,攪拌混合物。接著,混合物用泡沫混合器起泡成2升的泡沫。 After the stock solution was added, the mixture was stirred. Next, the mixture was foamed into a 2 liter foam using a foam mixer.
泡沫用200μm的刮刀施加到由藉由克重為40g/m2的聚氨酯熔融紡絲而成的纖維構成的不織織物上並且在對流加熱爐中在130℃至150℃時乾燥15s至90s。產生克重為25g/qm的泡沫覆層。作為用於不織織物的載體材料,使用克重為20g/qm的由聚丙烯構成的紡黏不織織物。不織織物能夠從中無損地脫離的其他載體也是適合的。 The foam was applied to a nonwoven fabric composed of fibers melt-spun by a polyurethane having a basis weight of 40 g/m 2 with a 200 μm doctor blade and dried at 130 ° C to 150 ° C for 15 s to 90 s in a convection oven. A foam coating having a basis weight of 25 g/qm was produced. As the carrier material for the nonwoven fabric, a spunbonded nonwoven fabric composed of polypropylene having a basis weight of 20 g/qm was used. Other carriers from which the nonwoven fabric can be detached without damage are also suitable.
襯布具有滑動能力,所述滑動能力突出地適用於其縫合。襯布還具有柔軟的手感並且能夠作為縫合襯布以各種彈性的和非彈性的外層面料加工。 與外層面料相結合時所述襯布具有良好的熱作用。 The lining has a sliding ability that is outstandingly suitable for its stitching. The interlining also has a soft hand and can be processed as a stitching interlining in a variety of elastic and non-elastic outer layers. The lining has a good thermal effect when combined with the outer fabric.
實例2:借助刮塗方法製備根據本發明的可縫合的襯布 Example 2: Preparation of a sewable interlining according to the present invention by means of a knife coating method
361g的基於聚酯型聚氨酯的含水的聚氨酯-聚合物分散體(固體含量49%)與278g的基於硬酯酸銨的起泡劑(固體含量30%)和90g的基於聚氫甲基矽氧烷的乳濁液(固體含量44%)以及與91g的水在攪拌條件下混合。所給出的固體含量是重量份額,所述重量份額能夠在液體成分蒸發之後藉由稱量重量確定。 361 g of a polyurethane-based aqueous polyurethane-polymer dispersion (solids content 49%) with 278 g of ammonium stearate-based foaming agent (solids content 30%) and 90 g of polyhydrogen methyl oxime The emulsion of the alkane (solids content 44%) was mixed with 91 g of water under stirring. The solids content given is the weight fraction which can be determined by weighing the weight after evaporation of the liquid component.
混合物在攪拌條件下用270g的由甲基羥乙基纖維素構成的原液增稠。為了製備原液,29.1g的甲基羥乙基纖維素(固體含量100%)拌入970.9g的水中並且能夠在室溫下泡脹48h。原液的黏度為50000cp至75000cp。 The mixture was thickened with 270 g of a stock solution consisting of methyl hydroxyethyl cellulose under stirring. To prepare the stock solution, 29.1 g of methyl hydroxyethyl cellulose (solid content 100%) was stirred into 970.9 g of water and allowed to swell for 48 h at room temperature. The viscosity of the stock solution is from 50,000 cp to 75,000 cp.
在添加原液之後,攪拌混合物。接著,混合物用泡沫混合器起泡成2升的泡沫。 After the stock solution was added, the mixture was stirred. Next, the mixture was foamed into a 2 liter foam using a foam mixer.
泡沫用200μm的刮刀施加到由藉由克重為30g/m2的聚氨酯熔融紡絲而成的纖維構成的不織織物上並且在對流加熱爐中在130℃至150℃時乾燥15s至90s。產生克重為27g/qm的泡沫覆層。作為用於不織織物的載體材料,能夠使用克重為20g/qm的由聚丙烯構成的紡黏不織織物。不織織物能夠從中無損地脫離的其他載體也是適合的。襯布能夠作為縫合襯布用外層面料加工。 The foam was applied to a nonwoven fabric composed of fibers melt-spun by a polyurethane having a basis weight of 30 g/m 2 using a 200 μm doctor blade and dried at 130 ° C to 150 ° C for 15 s to 90 s in a convection oven. A foam coating having a basis weight of 27 g/qm was produced. As the carrier material for the nonwoven fabric, a spunbonded nonwoven fabric composed of polypropylene having a basis weight of 20 g/qm can be used. Other carriers from which the nonwoven fabric can be detached without damage are also suitable. The lining can be processed as an outer layer fabric for the stitching lining.
實例3:借助刮塗方法製備根據本發明的可縫合的襯布 Example 3: Preparation of a sewable interlining according to the present invention by means of a knife coating method
413g的基於丙烯醯胺、乙烯和N-羥甲基丙烯醯胺的含水的醋酸乙烯酯-聚合物分散體(固體含量55%)與318g的基於硬酯酸銨的起泡劑(固體含量30%)和103g的基於聚氫甲基矽氧烷的乳濁液(固體含量44%)以及與g的水在攪拌條件下混合。所給出的固體含量是重量份額,所述重量份額能夠在液體成分蒸發之後藉由稱量重量確定。混合物在攪拌條件下用154g的由甲基羥乙基纖維素構成的原液增稠。為了製備原液,29.1g的甲基羥乙基纖維素(固體含量100%)拌入970.9g的水中並且能夠在室溫下泡脹48h。原液的黏度為50000cp至75000cp。 413 g of aqueous vinyl acetate-polymer dispersion based on acrylamide, ethylene and N-methylol acrylamide (solids content 55%) and 318 g of ammonium stearate-based foaming agent (solids content 30 %) and 103 g of a polyhydrogen methyloxane-based emulsion (solid content 44%) and water mixed with g under stirring. The solids content given is the weight fraction which can be determined by weighing the weight after evaporation of the liquid component. The mixture was thickened with 154 g of a stock solution consisting of methyl hydroxyethyl cellulose under stirring. To prepare the stock solution, 29.1 g of methyl hydroxyethyl cellulose (solid content 100%) was stirred into 970.9 g of water and allowed to swell for 48 h at room temperature. The viscosity of the stock solution is from 50,000 cp to 75,000 cp.
在添加原液之後,攪拌混合物。接著,混合物用泡沫混合器起泡成2升的泡沫。 After the stock solution was added, the mixture was stirred. Next, the mixture was foamed into a 2 liter foam using a foam mixer.
泡沫用200μm的刮刀施加到由藉由克重為50g/m2的聚氨酯熔融紡絲而 成的纖維構成的不織織物上並且在對流加熱爐中在130℃至150℃時乾燥15s至90s。產生克重為15g/qm的泡沫覆層。作為用於不織織物的載體材料,能夠使用克重為20g/qm的由聚丙烯構成的紡黏不織織物。不織織物能夠從中無損地脫離的其他載體也是適合的。襯布能夠作為縫合襯布用外層面料加工。 The foam was applied to a nonwoven fabric composed of fibers melt-spun by a polyurethane having a basis weight of 50 g/m 2 using a 200 μm doctor blade and dried at 130 ° C to 150 ° C for 15 s to 90 s in a convection oven. A foam coating having a basis weight of 15 g/qm was produced. As the carrier material for the nonwoven fabric, a spunbonded nonwoven fabric composed of polypropylene having a basis weight of 20 g/qm can be used. Other carriers from which the nonwoven fabric can be detached without damage are also suitable. The lining can be processed as an outer layer fabric for the stitching lining.
實例4:借助刮塗方法製備根據本發明的可黏合的襯布 Example 4: Preparation of a bondable interlining according to the invention by means of a knife coating method
413g的基於丙烯醯胺、乙烯和N-羥甲基丙烯醯胺的含水的醋酸乙烯酯-聚合物分散體(固體含量55%)與318g的基於硬酯酸銨的起泡劑(固體含量30%)和103g的基於聚氫甲基矽氧烷的乳濁液(固體含量44%)與130g的基於熔點為110℃(+/-10℃)的聚氨酯(固體含量100%)的熱熔膠粉末以及與12g的水在攪拌條件下混合。所給出的固體含量是重量份額,所述重量份額能夠在液體成分蒸發之後藉由稱量重量確定。 413 g of aqueous vinyl acetate-polymer dispersion based on acrylamide, ethylene and N-methylol acrylamide (solids content 55%) and 318 g of ammonium stearate-based foaming agent (solids content 30 %) and 103 g of polyhydrogen methyloxane-based emulsion (solid content 44%) and 130 g of hot melt adhesive based on polyurethane (solid content 100%) having a melting point of 110 ° C (+/- 10 ° C) The powder was mixed with 12 g of water under stirring. The solids content given is the weight fraction which can be determined by weighing the weight after evaporation of the liquid component.
混合物在攪拌條件下用154g由甲基羥乙基纖維素構成的原液增稠。為了製備原液,29.1g的甲基羥乙基纖維素(固體含量100%)拌入970.9g的水中並且能夠在室溫下泡脹48h。原液的黏度為50000cp至75000cp。 The mixture was thickened with 154 g of a stock solution consisting of methyl hydroxyethyl cellulose under stirring. To prepare the stock solution, 29.1 g of methyl hydroxyethyl cellulose (solid content 100%) was stirred into 970.9 g of water and allowed to swell for 48 h at room temperature. The viscosity of the stock solution is from 50,000 cp to 75,000 cp.
在添加原液之後,攪拌混合物。接著,混合物用泡沫混合器起泡成2升的泡沫。 After the stock solution was added, the mixture was stirred. Next, the mixture was foamed into a 2 liter foam using a foam mixer.
泡沫用200μm的刮刀施加到由藉由克重為45g/m2的聚氨酯熔融紡絲而成的纖維構成的不織織物上並且在對流加熱爐中在130℃至150℃時乾燥15s至90s。產生克重為20g/qm的泡沫覆層。作為用於不織織物的載體材料,能夠使用克重為20g/qm的由聚丙烯構成的紡黏不織織物。不織織物能夠從中無損地脫離的其他載體也是適合的。襯布能夠作為縫合襯布用外層面料加工。 The foam was applied to a nonwoven fabric composed of fibers melt-spun by a polyurethane having a basis weight of 45 g/m 2 using a 200 μm doctor blade and dried at 130 ° C to 150 ° C for 15 s to 90 s in a convection oven. A foam coating having a basis weight of 20 g/qm was produced. As the carrier material for the nonwoven fabric, a spunbonded nonwoven fabric composed of polypropylene having a basis weight of 20 g/qm can be used. Other carriers from which the nonwoven fabric can be detached without damage are also suitable. The lining can be processed as an outer layer fabric for the stitching lining.
實例5:借助泡沫浸漬製備根據本發明的可縫合的襯布 Example 5: Preparation of a sewable interlining according to the invention by means of foam impregnation
在由克重為50g/m2的聚氨酯熔融紡絲而成的纖維構成的不織織物上用泡沫混合物進行浸漬。泡沫混合物由113g的水、194g/L的基於丙烯酸共聚物的含水的聚合物分散體(固體含量45%),4g/L的基於二異辛基磺化琥珀酸鈉的交聯劑(固體含量71%),2g/L的基於烷烴磺酸鈉鹽的交聯劑(固體含量70%),7g/L的基於矽樹脂油的潤滑劑(固體含量40%)和680g/L的基於烷烴(十八烷)的相變材料(固體含量45%)。潮濕的不織 布在帶式乾燥機在150℃至180℃時乾燥20s至60s。產生克重為55g/qm的膜。不織織物能夠作為縫合襯布用外層面料加工。 The nonwoven fabric composed of fibers melt-spun from a polyurethane having a basis weight of 50 g/m 2 was impregnated with a foamed mixture. Foam mixture consisting of 113 g of water, 194 g/L of an aqueous copolymer dispersion based on acrylic copolymer (solid content 45%), 4 g/L of cross-linking agent based on diisooctylsulfonated succinate (solid content) 71%), 2 g/L of alkanesulfonate-based crosslinker (solids content 70%), 7 g/L of terpene resin based lubricant (40% solids) and 680 g/L of alkanes ( Phase change material of octadecane (solid content 45%). The wet non-woven fabric is dried in a belt dryer at 150 ° C to 180 ° C for 20 s to 60 s. A film having a basis weight of 55 g/qm was produced. The non-woven fabric can be processed as an outer fabric of a stitched lining.
實例6:製備以熱熔膠覆層的可黏合的根據本發明的襯布 Example 6: Preparation of a bondable interlining according to the invention with a hot melt adhesive coating
根據2)製備的襯布以輪轉絲網印刷用3.5g的(固體的)印刷漿借助穿孔的網格範本點狀地印刷(CP 180)並且接著撒5g的熔化範圍為75℃至135℃的共聚醯胺-熱熔膠粉末並且在乾燥機中在180℃乾燥30s至60s,所述印刷漿由343g的水,608g/L的基於聚酯型聚氨酯的含水的聚合物分散體(固體含量49%),8g/L的基於聚二甲基矽氧烷乳濁液/助劑的消泡劑(固體含量33%),10g/L的基於非離子表面活性劑的乳化劑(固體含量83%),19g/L的基於聚乙二醇的助流劑(Laufhilfsmittel)(固體含量100%),2g/L的25%的氨水和10g/L的基於由聚丙烯酸酯構成的配製品的增稠劑(固體含量80%)構成。 The lining prepared according to 2) was printed in a rotary screen with 3.5 g of (solid) printing paste by means of a perforated grid pattern (CP 180) and then sprinkled with 5 g of a copolymerization range of 75 ° C to 135 ° C. The guanamine-hot melt powder and dried in a dryer at 180 ° C for 30 s to 60 s, the printing paste consists of 343 g of water, 608 g / L of a polyurethane-based aqueous polymer dispersion (solid content 49%) ), 8 g/L of anti-foaming agent based on polydimethyl methoxyane emulsion/auxiliary (solid content 33%), 10 g/L of nonionic surfactant-based emulsifier (solid content 83%) 19 g/L of polyethylene glycol-based glidant (100% solids content), 2 g/L of 25% ammonia water and 10 g/L of thickener based on a formulation composed of polyacrylate (solid content 80%) constitutes.
對照實例1:防絨的襯布,,對應於習知技術的克重57g/m2的穩定的織物 Comparative Example 1: a fleece-resistant interlining, a stable fabric having a basis weight of 57 g/m 2 corresponding to the prior art
防絨性的檢驗根據中國標準測試方法GB/T 12705.2-2009“Textile-Methods of testing the down-proof properties of fabrics-Part 2 Tumble test”進行 The inspection of the fleece resistance is carried out according to the Chinese Standard Test Method GB/T 12705.2-2009 "Textile-Methods of testing the down-proof properties of fabrics-Part 2 Tumble test".
穿透的微粒的小於15的數量視為是可接受的。顯示出:根據本發明的襯布像出自對照實例1的防絨的織物那樣具有相對良好的防絨性。然而,所述襯布是明顯不那麼滑的,這簡化了其的可加工性。 A number of penetrating particles of less than 15 is considered acceptable. It is shown that the lining cloth according to the present invention has relatively good anti-textile properties like the anti-textile fabric of Comparative Example 1. However, the interlining is significantly less slippery, which simplifies its workability.
最大拉力和最大拉伸強度的檢驗作為抗撕裂強度的量度根據DIN EN ISO 29073-03:1992借助於下列變數進行:拉伸方向:紡織品的縱向方向、橫向方向 Tests for maximum tensile strength and maximum tensile strength as a measure of the tear strength according to DIN EN ISO 29073-03:1992 by means of the following variables: direction of stretching: longitudinal direction, transverse direction of the textile
檢驗儀器:Zwick公司,型號BZ 1.0/TH1S. Inspection equipment: Zwick, model BZ 1.0/TH1S.
在表1中列舉的結果顯示出:根據實例1的根據本發明的襯布在最大拉力值良好的情況下具有高的最大拉伸強度。出自對照實例1的襯布在縱向方向和橫向方向上顯示出明顯更小的最大拉伸強度從而能夠視為不那麼有彈性或不那麼穩定的。 The results exemplified in Table 1 show that the lining according to the present invention according to Example 1 has a high maximum tensile strength with a good maximum tensile value. The lining from Comparative Example 1 exhibited a significantly smaller maximum tensile strength in the longitudinal direction and the transverse direction so as to be considered less elastic or less stable.
拉彈特性的檢驗根據DIN 538352:1981-08作為遲滯測量借助於下列變數進行:拉伸方向:紡織品的縱向方向、橫向方向 The test of the tensile properties is carried out according to DIN 538352:1981-08 as a hysteresis measurement by means of the following variables: direction of stretching: longitudinal direction, transverse direction of the textile
樣本長度:150mm Sample length: 150mm
樣本寬度:50mm Sample width: 50mm
自由的襯布長度:100mm Free lining length: 100mm
檢驗儀器:Zwick公司,型號BZ 1.0/TH1S. Inspection equipment: Zwick, model BZ 1.0/TH1S.
預加力:0.05N Pre-energizing: 0.05N
迴圈:5 Loop: 5
每個迴圈的速度:50mm/min。 Speed per loop: 50mm/min.
1)上反轉點:25%的伸長 1) Upper reversal point: 25% elongation
2)下反轉點:0.05N的力 2) Lower reversal point: 0.05N force
檢驗氛圍:22℃/50%的相對濕度 Test atmosphere: 22 ° C / 50% relative humidity
在表2中示出測量結果。 The measurement results are shown in Table 2.
出自對照實例1的襯布不顯示出拉彈特性。因此,所述襯布能夠視為是不那麼有彈性或不那麼穩定的。而根據實例1和實例2的根據本發明的襯布顯示出拉彈特性。所述襯布能夠在縱向方向和橫向方向上無損地拉伸直至25%的伸長的上反轉點並且在此具有小於10%的殘餘伸長和小於12%的永久伸長。 The lining from Comparative Example 1 did not exhibit the elastic properties. Thus, the interlining can be considered to be less elastic or less stable. The lining according to the present invention according to Examples 1 and 2 exhibited tensile properties. The interlining can be stretched non-destructively in the longitudinal and transverse directions up to a 25% elongational upper reversal point and here has a residual elongation of less than 10% and a permanent elongation of less than 12%.
透氣性的檢驗根據DIN EN ISO 9237:1995-12借助於下列變更進行:檢驗壓力:200Pa The test for gas permeability is carried out according to DIN EN ISO 9237:1995-12 with the aid of the following changes: Inspection pressure: 200 Pa
檢驗結果:以dm3/s×m2表示 Test result: expressed in dm 3 /s×m 2
檢驗儀器:Textex FX 3300 Inspection equipment: Textex FX 3300
樣本寬度:10cm Sample width: 10cm
根據DIN 50014/ISO 554:透氣性在200Pa的檢驗壓力下確定。 According to DIN 50014 / ISO 554: gas permeability is determined at a test pressure of 200 Pa.
襯布未縫合並且在與外層面料縫合之後檢驗。 The lining was unstitched and inspected after suturing with the outer fabric.
測量在從不織織物中除去載體材料之後進行。 The measurement is carried out after removing the carrier material from the nonwoven fabric.
所得出的透氣性的測量值越小,外層面料/襯布複合結構的熱作用越高。 The smaller the measured value of the gas permeability obtained, the higher the thermal effect of the outer fabric/liner composite structure.
根據DIN EN ISO 5077:2008-04與DIN EN ISO 3759:2011-08和DIN EN ISO 6330:2012測量皺縮。在40℃下洗滌一次。 The shrinkage is measured according to DIN EN ISO 5077:2008-04 and DIN EN ISO 3759:2011-08 and DIN EN ISO 6330:2012. Wash once at 40 °C.
表4顯示出,根據實例1和實例2的根據本發明的襯布的皺縮非常小。就此而言這是令人驚訝的,因為在使用基於具有低的軟化溫度和/或玻璃化轉變溫度的醋酸乙烯酯共聚物和/或聚丙烯酸酯和/或聚氨酯的泡沫覆層和熱塑性纖維時,在洗滌時提高的皺縮特性本是意料之中的。根據本發明,出自對照實例1的、不具有軟化溫度和/或玻璃化轉變溫度低的成分的襯布具有小的皺縮。 Table 4 shows that the shrinkage of the interlining according to the present invention according to Examples 1 and 2 is very small. This is surprising in this respect, since when using foam coatings and thermoplastic fibers based on vinyl acetate copolymers and/or polyacrylates and/or polyurethanes having a low softening temperature and/or glass transition temperature The increased shrinkage characteristics during washing are intended to be expected. According to the present invention, the interlining from Comparative Example 1 which does not have a component having a softening temperature and/or a low glass transition temperature has a small shrinkage.
為了檢驗在熱處理時的黏接趨勢,襯布的2層相互疊置並且在剝離紙之間用Kannegiesser公司的型號為Multistar DX 1000/C/T/TA的熱熔黏合機在120℃的溫度和0.5bar的壓力下並且5.7m/min的速度下黏合12s。 In order to check the adhesion tendency during heat treatment, the two layers of the interlining were superposed on each other and between the release papers using a Kennegiesser model of the Multistar DX 1000/C/T/TA hot melt adhesive at a temperature of 120 ° C and 0.5 Bonded for 12 s under bar pressure and at a speed of 5.7 m/min.
接著,確定襯布/襯布複合結構的分離力。 Next, the separation force of the lining/liner composite structure is determined.
分離力的檢驗根據DIN 54310:1980-07借助於下列變數進行:拉伸方向:紡織品的縱向方向 The test of the separation force is carried out according to DIN 54310:1980-07 by means of the following variables: direction of stretching: longitudinal direction of the textile
樣本長度:150mm Sample length: 150mm
樣本寬度:50mm Sample width: 50mm
紡絲長度:150mm Spinning length: 150mm
測量路徑:100mm Measuring path: 100mm
檢驗儀器:Zwick公司,型號BZ 1.0/TH1S. Inspection equipment: Zwick, model BZ 1.0/TH1S.
預加力:0.1N Pre-energizing: 0.1N
試驗速度:150mm/min Test speed: 150mm/min
檢驗氛圍:22℃/50%的相對濕度 Test atmosphere: 22 ° C / 50% relative humidity
分離力的檢驗值越高,襯布在溫度作用下就越強烈地熱黏接。樣本的具有撕裂部(Abriss)的間隙值表示完全黏接,所述黏接不能夠無損地分離。在沒有撕裂部的平均值中給出無損的可分離性。 The higher the test value of the separation force, the stronger the heat bonding of the lining under the action of temperature. The gap value of the sample with the tears indicates complete bonding, which cannot be separated without damage. Non-destructive separability is given in the mean without the tear.
表5的結果顯示出:根據實例1的根據本發明的襯布在所給出的熱作用下僅微弱黏接,使得所述襯布能夠再次無損地分離。 The results of Table 5 show that the lining according to the invention according to Example 1 is only weakly bonded under the given heat, so that the lining can be separated again without damage.
就此而言這是令人驚訝的,因為在使用基於軟化溫度和/或玻璃化轉變溫度低的醋酸乙烯酯共聚物和/或聚丙烯酸酯和/或聚氨酯的泡沫覆層和熱塑性纖維時,在熱處理情況下提高的黏接趨勢本是意料之中的。 This is surprising in this respect, since when foam coatings and thermoplastic fibers based on a softening temperature and/or a low glass transition temperature of vinyl acetate copolymer and/or polyacrylate and/or polyurethane are used, The improved bonding tendency under heat treatment was originally expected.
檢驗儀器:DSC1(Mettler Toledo) Inspection equipment: DSC1 (Mettler Toledo)
加熱速率(K/min):10 Heating rate (K/min): 10
Claims (15)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
??102017001102.8 | 2017-02-07 | ||
DE102017001102.8A DE102017001102A1 (en) | 2017-02-07 | 2017-02-07 | Bi-elastic down density nonwoven insert |
Publications (1)
Publication Number | Publication Date |
---|---|
TW201829867A true TW201829867A (en) | 2018-08-16 |
Family
ID=61187285
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
TW107103188A TW201829867A (en) | 2017-02-07 | 2018-01-30 | Bi-elastic down-proof non-woven insert |
Country Status (3)
Country | Link |
---|---|
DE (1) | DE102017001102A1 (en) |
TW (1) | TW201829867A (en) |
WO (1) | WO2018145935A1 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109501417A (en) * | 2018-11-07 | 2019-03-22 | 晟合新材料科技(嘉善)有限公司 | A kind of composite material and its preparation method and application |
CN113545538A (en) * | 2020-04-24 | 2021-10-26 | 财团法人纺织产业综合研究所 | Down-containing textile |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2019173913A1 (en) * | 2018-03-12 | 2019-09-19 | Heat-Mx Worldwide | Method for improving dryness of insulation material and articles comprising improved insulation materials |
DE102019106995A1 (en) * | 2019-03-19 | 2020-09-24 | Carl Freudenberg Kg | Thermally fixable textile fabric |
WO2023242627A1 (en) * | 2022-06-14 | 2023-12-21 | 新丽企业股份有限公司 | Elastic thermal insulation composite material |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3132324A1 (en) | 1981-08-17 | 1983-03-03 | Hasso von 4000 Düsseldorf Blücher | "WATER- AND AIR-TIGHT MOISTURE-CONTROLLING TEXTILE MATERIAL" |
US5035240A (en) * | 1988-05-13 | 1991-07-30 | Minnesota Mining And Manufacturing Company | Elastomeric filtration materials |
AU643014B2 (en) | 1990-07-31 | 1993-11-04 | Kimberly-Clark Worldwide, Inc. | Elastomeric saturated nonwoven material |
US5509142A (en) | 1993-06-30 | 1996-04-23 | Kimberly-Clark Corporation | Raised arm coveralls |
DE20310279U1 (en) * | 2003-07-03 | 2004-11-11 | Sanders Gmbh | Cover for feather bedding and pillows, filled with down feathers, is a dense nonwoven of micro-fibers which is permeable to air and vapor but impenetrable for feathers and allergens |
JP4705401B2 (en) | 2005-04-14 | 2011-06-22 | 旭化成せんい株式会社 | Nonwoven fabric for feather collection bags |
JP5009055B2 (en) * | 2007-06-06 | 2012-08-22 | 日本バイリーン株式会社 | Feather inner fabric, feather inner bag, and downproof structure using the same |
JP5009056B2 (en) | 2007-06-06 | 2012-08-22 | 日本バイリーン株式会社 | Down proof structure |
JP5112220B2 (en) * | 2008-08-22 | 2013-01-09 | 日本バイリーン株式会社 | Nonwoven fabric for feather bags and down-proof structure using the same |
WO2012132033A1 (en) * | 2011-03-30 | 2012-10-04 | 蝶理株式会社 | Stretch inner fabric for down, stretch inner bag for down and down-proof structural body using same |
DE102014014387B4 (en) | 2014-10-02 | 2016-05-25 | Carl Freudenberg Kg | Bi-elastic insert |
EP3165654A1 (en) * | 2015-11-09 | 2017-05-10 | Carl Freudenberg KG | Use of endless filament non-woven fabrics for preventing the escape of down in down- filled textile products |
-
2017
- 2017-02-07 DE DE102017001102.8A patent/DE102017001102A1/en not_active Withdrawn
-
2018
- 2018-01-29 WO PCT/EP2018/052063 patent/WO2018145935A1/en active Application Filing
- 2018-01-30 TW TW107103188A patent/TW201829867A/en unknown
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109501417A (en) * | 2018-11-07 | 2019-03-22 | 晟合新材料科技(嘉善)有限公司 | A kind of composite material and its preparation method and application |
CN113545538A (en) * | 2020-04-24 | 2021-10-26 | 财团法人纺织产业综合研究所 | Down-containing textile |
Also Published As
Publication number | Publication date |
---|---|
DE102017001102A1 (en) | 2018-08-09 |
WO2018145935A1 (en) | 2018-08-16 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
TW201829867A (en) | Bi-elastic down-proof non-woven insert | |
JP7171840B2 (en) | Silk performance garments and products and methods of making them | |
US12129596B2 (en) | Silk coated fabrics and products and methods of preparing the same | |
CN104302199A (en) | Thermo-fusible sheet material | |
JP6526833B2 (en) | Heat-adhesive flat structure | |
CN107028256A (en) | Garment bands including polymer composition | |
JP2004502041A (en) | Preferred woven fabric / elastomer composites for transfer or film-coating | |
JP5112183B2 (en) | Nonwoven fabric for feather bags and clothing using the same | |
TWI321454B (en) | Fixierbarer einlagestoff aus vliesstoff zur verwendung in der textilindustrie | |
JP4300772B2 (en) | Long-fiber nonwoven fabric, artificial leather, and method for producing long-fiber nonwoven fabric | |
JP2005068571A (en) | Garment stuffed with feather | |
US20240229313A9 (en) | Durable pilling resistant nonwoven insulation | |
JP2002540317A (en) | Spunlaced poly (vinyl alcohol) cloth | |
CN106192162A (en) | The production technology of men's clothing leisure lining cloth | |
CN101784721B (en) | Leather-like sheet and process for producing same | |
JP7372257B2 (en) | Moisture-permeable and waterproof fabric and textile products using the same | |
JPH0827671A (en) | Production of fiber structure having mite repellent effect | |
JP2023064999A (en) | Inner cotton | |
JP4477472B2 (en) | Nonwoven manufacturing method | |
Schenk | Study of the Impact of the Nonwoven Substrate Formation on Artificial Leather. | |
JP3756050B2 (en) | Manufacturing method of clothing | |
JP2021161590A (en) | Inner cotton | |
WO2018051661A1 (en) | Fiber product | |
WO2019245470A2 (en) | A novel nonwoven interlining and production method | |
EP3601653A1 (en) | A non-woven apparel fabric, and a process for manufacturing the same |