PE20070917A1 - Proceso de lixiviacion en presencia de acido clorhidrico para la recuperacion de un metal valioso de una mena - Google Patents
Proceso de lixiviacion en presencia de acido clorhidrico para la recuperacion de un metal valioso de una menaInfo
- Publication number
- PE20070917A1 PE20070917A1 PE2006001513A PE2006001513A PE20070917A1 PE 20070917 A1 PE20070917 A1 PE 20070917A1 PE 2006001513 A PE2006001513 A PE 2006001513A PE 2006001513 A PE2006001513 A PE 2006001513A PE 20070917 A1 PE20070917 A1 PE 20070917A1
- Authority
- PE
- Peru
- Prior art keywords
- metal
- hcl
- sulphite
- sulphate
- solution
- Prior art date
Links
- 229910052751 metal Inorganic materials 0.000 title abstract 8
- 239000002184 metal Substances 0.000 title abstract 8
- 238000002386 leaching Methods 0.000 title abstract 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 title 2
- 238000000034 method Methods 0.000 title 1
- 238000011084 recovery Methods 0.000 title 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 abstract 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract 4
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 abstract 4
- 229910021653 sulphate ion Inorganic materials 0.000 abstract 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 3
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 abstract 2
- 229910052782 aluminium Inorganic materials 0.000 abstract 2
- 229910001510 metal chloride Inorganic materials 0.000 abstract 2
- 229910052759 nickel Inorganic materials 0.000 abstract 2
- 239000007787 solid Substances 0.000 abstract 2
- 238000004326 stimulated echo acquisition mode for imaging Methods 0.000 abstract 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 abstract 2
- 229910052719 titanium Inorganic materials 0.000 abstract 2
- 239000010936 titanium Substances 0.000 abstract 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract 1
- -1 SULPHITE IONS Chemical class 0.000 abstract 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical class OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 abstract 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 abstract 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 1
- 229910052728 basic metal Inorganic materials 0.000 abstract 1
- 150000003818 basic metals Chemical class 0.000 abstract 1
- 229910052804 chromium Inorganic materials 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 239000010949 copper Substances 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 229910052745 lead Inorganic materials 0.000 abstract 1
- 229910052748 manganese Inorganic materials 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 abstract 1
- 229920001296 polysiloxane Polymers 0.000 abstract 1
- 229910052700 potassium Inorganic materials 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
- 229910052725 zinc Inorganic materials 0.000 abstract 1
- 239000011701 zinc Substances 0.000 abstract 1
- 239000011787 zinc oxide Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/04—Extraction of metal compounds from ores or concentrates by wet processes by leaching
- C22B3/06—Extraction of metal compounds from ores or concentrates by wet processes by leaching in inorganic acid solutions, e.g. with acids generated in situ; in inorganic salt solutions other than ammonium salt solutions
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B23/00—Obtaining nickel or cobalt
- C22B23/04—Obtaining nickel or cobalt by wet processes
- C22B23/0407—Leaching processes
- C22B23/0415—Leaching processes with acids or salt solutions except ammonium salts solutions
- C22B23/0423—Halogenated acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F5/00—Compounds of magnesium
- C01F5/40—Magnesium sulfates
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B19/00—Obtaining zinc or zinc oxide
- C22B19/20—Obtaining zinc otherwise than by distilling
- C22B19/22—Obtaining zinc otherwise than by distilling with leaching with acids
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B23/00—Obtaining nickel or cobalt
- C22B23/04—Obtaining nickel or cobalt by wet processes
- C22B23/0453—Treatment or purification of solutions, e.g. obtained by leaching
- C22B23/0461—Treatment or purification of solutions, e.g. obtained by leaching by chemical methods
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/04—Extraction of metal compounds from ores or concentrates by wet processes by leaching
- C22B3/06—Extraction of metal compounds from ores or concentrates by wet processes by leaching in inorganic acid solutions, e.g. with acids generated in situ; in inorganic salt solutions other than ammonium salt solutions
- C22B3/10—Hydrochloric acid, other halogenated acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/44—Treatment or purification of solutions, e.g. obtained by leaching by chemical processes
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
- C22B7/04—Working-up slag
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Environmental & Geological Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Inorganic Chemistry (AREA)
- Geochemistry & Mineralogy (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Manufacture And Refinement Of Metals (AREA)
Abstract
QUE COMPRENDE: a) LIXIVIAR LA MENA EN PRESENCIA DE HCl PARA FORMAR UNA SAL SOLUBLE DE METAL-CLORURO EN UNA SOLUCION DE LIXIVIACION; b) ANADIR ACIDO SULFURICO Y/O DIOXIDO DE AZUFRE A LA SOLUCION DE LIXIVIACION; c) RECUPERAR UN SULFATO DE METAL SOLIDO O UN SULFITO DE METAL DE LA SOLUCION DE LIXIVIACION; d) REGENERAR EL HCl; e) TRANSFERIR EN FORMA CONTINUA, MEDIANTE CALENTAMIENTO, POR LO MENOS UNA PORCION DE HCl EN SOLUCION HACIA UNA FASE DE VAPOR; Y, f) RECICLAR EL HCl EN LA FASE DE VAPOR A (a). (b) Y (d) SE HACEN SIMULTANEAMENTE. EL ACIDO SULFURICO Y/O EL DIOXIDO DE AZUFRE SE ANADEN DURANTE (a) PARA FORMAR LA SAL SOLUBLE DE METAL-CLORURO Y UNA SAL DE SULFATO DE METAL SOLIDO O DE SULFITO DE METAL EN UNA SOLUCION DE LIXIVIACION; Y ESTA ULTIMA SAL SE RECUPERA POSTERIORMENTE Y SE GENERA SIMULTANEAMENTE UNA SOLUCION DE HCl CON ALTO CONTENIDO DE IONES CLORURO Y BAJO CONTENIDO DE IONES SULFATO O SULFITO. EL SULFATO O SULFITO DE METAL ES MeSOx. yH2O, DONDE: Me ES METAL, x ES 3 o 4, E y ES 0 o MAS. LA MENA ES UNA DE METAL BASICO, ESENCIALMENTE OXIDADA O DE SILICE, DE PREFERENCIA DE OXIDO DE ZINC, DE NIQUEL LATERITICO, SAPROLITICA O LIMONITIZADA, Y DE SULFURO, TITANIO O ALUMINIO. EL METAL LIXIVIADO ES Zn, Cu, Ti, Al, Cr, Ni, Co, Mn, Fe, Pb, Na, K, Ca Y METALES DEL GRUPO DE PLATINO
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ZA200509582 | 2005-11-28 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PE20070917A1 true PE20070917A1 (es) | 2007-10-02 |
Family
ID=38218344
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PE2006001513A PE20070917A1 (es) | 2005-11-28 | 2006-11-28 | Proceso de lixiviacion en presencia de acido clorhidrico para la recuperacion de un metal valioso de una mena |
Country Status (12)
| Country | Link |
|---|---|
| EP (1) | EP1954843B1 (es) |
| JP (1) | JP5563763B2 (es) |
| KR (1) | KR101329838B1 (es) |
| CN (1) | CN101336306B (es) |
| AR (1) | AR058245A1 (es) |
| AU (1) | AU2006329687B2 (es) |
| BR (1) | BRPI0619012B1 (es) |
| PE (1) | PE20070917A1 (es) |
| RU (1) | RU2424332C2 (es) |
| UA (1) | UA93991C2 (es) |
| WO (1) | WO2007074360A2 (es) |
| ZA (1) | ZA200802808B (es) |
Families Citing this family (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009039579A1 (en) * | 2007-09-26 | 2009-04-02 | Bhp Billiton Ssm Development Pty Ltd | Acid recovery from metal sulfates |
| CN101225470B (zh) * | 2008-01-31 | 2010-06-09 | 曹国华 | 盐酸法从红土镍矿提取镍钴的方法 |
| FI121180B (fi) * | 2008-11-03 | 2010-08-13 | Outotec Oyj | Menetelmä nikkelilateriittimalmin käsittelemiseksi |
| CN101575672B (zh) * | 2009-03-11 | 2011-01-12 | 中南大学 | 一种低品位氧化铜钴矿中铜、钴镍的分离提取方法 |
| FR2948385B1 (fr) * | 2009-07-27 | 2011-09-23 | Commissariat Energie Atomique | Procede de recuperation selective de l'americium a partir d'une phase aqueuse nitrique |
| WO2011132740A1 (ja) * | 2010-04-21 | 2011-10-27 | Uehara Haruo | レアメタル回収方法及びその装置 |
| WO2011132282A1 (ja) * | 2010-04-22 | 2011-10-27 | Uehara Haruo | リチウム回収装置及びその方法 |
| KR101281367B1 (ko) * | 2011-12-28 | 2013-07-02 | 재단법인 포항산업과학연구원 | 니켈 함유 원료로부터 Ｓｉ를 제거하는 방법 |
| JP5365708B2 (ja) * | 2012-01-17 | 2013-12-11 | 住友金属鉱山株式会社 | 硫化水素ガス製造プラント及び廃硫化水素ガスの回収利用方法 |
| JP2015518414A (ja) * | 2012-03-29 | 2015-07-02 | オーバイト アルミナ インコーポレイテッドＯｒｂｉｔｅ Ａｌｕｍｉｎａｅ Ｉｎｃ． | フライアッシュ処理プロセス |
| EP2875160A1 (en) * | 2012-07-23 | 2015-05-27 | Vale S.A. | Recovery of base metals from sulphide ores and concentrates |
| CA2821467C (en) | 2013-07-18 | 2019-12-24 | Nichromet Extraction Inc. | Method for gold recovery on particules |
| JP5682683B2 (ja) * | 2013-09-06 | 2015-03-11 | 住友金属鉱山株式会社 | 硫化水素ガス製造プラント及び廃硫化水素ガスの回収利用方法 |
| PE20210787A1 (es) | 2014-05-12 | 2021-04-22 | Summit Mining Int Inc | Proceso de lixiviado de salmuera para la recuperacion de metales valiosos de materiales de oxido |
| KR20160031617A (ko) | 2014-09-12 | 2016-03-23 | 삼성디스플레이 주식회사 | 폐액 내의 은 이온 및 인산 회수 방법 |
| US11427886B2 (en) | 2015-04-21 | 2022-08-30 | Excir Works Corp. | Methods for simultaneous leaching and extraction of precious metals |
| KR101707089B1 (ko) * | 2015-11-23 | 2017-02-15 | 주식회사 엑스메텍 | 친환경 아연제련 공법 |
| WO2019122985A1 (en) * | 2017-12-22 | 2019-06-27 | Arcelormittal | Method for the treatment of iron-containing sludge |
| US11034619B2 (en) * | 2019-08-22 | 2021-06-15 | Innovator Energy, LLC | Intrinsic CO2 capture process for the production of metal oxides, cement, CO2 air capture or a combination thereof |
| KR102211250B1 (ko) * | 2020-01-28 | 2021-02-03 | (주)로우카본 | 고유황유(hsfo)의 황산화물 저감을 위한 탈황제의 제조 방법 및 이를 이용한 탈황제 |
| CN112080636B (zh) * | 2020-08-17 | 2022-11-15 | 广东邦普循环科技有限公司 | 一种利用红土镍矿生产电池级硫酸镍盐的方法 |
| MX2023002015A (es) * | 2020-08-18 | 2023-04-11 | Enviro Metals Llc | Refinamiento metálico. |
| CN112080651B (zh) * | 2020-09-23 | 2022-07-19 | 攀钢集团研究院有限公司 | 高钙低钠铵复合焙烧提钒的方法 |
| CN112591831A (zh) * | 2020-12-04 | 2021-04-02 | 兰州有色冶金设计研究院有限公司 | 一种强酸性矿山尾液无害化处理方法 |
| CA3214613A1 (en) | 2021-03-22 | 2022-09-29 | Sublime Systems, Inc. | Decarbonized cement blends |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61136920A (ja) * | 1984-12-05 | 1986-06-24 | Nippon Kokan Kk <Nkk> | 合成ルチル製造方法 |
| BR9205481A (pt) * | 1991-11-22 | 1994-04-26 | Tech Resources Pty Ltd | Processo e aparelho para formar um lixiviante aquoso de cloreto |
| US5650057A (en) * | 1993-07-29 | 1997-07-22 | Cominco Engineering Services Ltd. | Chloride assisted hydrometallurgical extraction of metal |
| US6395242B1 (en) * | 1999-10-01 | 2002-05-28 | Noranda Inc. | Production of zinc oxide from complex sulfide concentrates using chloride processing |
| JP3665817B2 (ja) * | 2001-08-02 | 2005-06-29 | 独立行政法人産業技術総合研究所 | 銅鉱石からそれに含まれる有価金属を分離する方法 |
| AUPS167402A0 (en) * | 2002-04-11 | 2002-05-16 | Platinum Australia Limited | Method for extracting pgms |
| US7329396B2 (en) * | 2003-05-16 | 2008-02-12 | Jaguar Nickel Inc. | Process for the recovery of value metals from material containing base metal oxides |
| KR20070005669A (ko) * | 2004-03-25 | 2007-01-10 | 인텍 엘티디 | 산화된 금속함유 재료로부터 금속을 회수하는 방법 |
| EP1809777B1 (en) * | 2004-10-21 | 2009-03-11 | Anglo Operations Limited | Leaching process in the presence of hydrochloric acid for the recovery of a value metal from an ore |
| WO2006101866A1 (en) | 2005-03-18 | 2006-09-28 | 3M Innovative Properties Company | Solid cleaners for heated food preparation surfaces |
| JP5374041B2 (ja) * | 2005-03-22 | 2013-12-25 | アングロ オペレーションズ リミティッド | 鉱石（ｏｒａ）からの有価金属回収のための塩酸存在下での浸出方法 |
-
2006
- 2006-11-28 BR BRPI0619012-0B1A patent/BRPI0619012B1/pt not_active IP Right Cessation
- 2006-11-28 PE PE2006001513A patent/PE20070917A1/es active IP Right Grant
- 2006-11-28 ZA ZA200802808A patent/ZA200802808B/xx unknown
- 2006-11-28 AU AU2006329687A patent/AU2006329687B2/en not_active Ceased
- 2006-11-28 UA UAA200808327A patent/UA93991C2/uk unknown
- 2006-11-28 EP EP06848866A patent/EP1954843B1/en active Active
- 2006-11-28 WO PCT/IB2006/003380 patent/WO2007074360A2/en active Application Filing
- 2006-11-28 KR KR1020087015408A patent/KR101329838B1/ko active IP Right Grant
- 2006-11-28 AR ARP060105255A patent/AR058245A1/es active IP Right Grant
- 2006-11-28 CN CN2006800518461A patent/CN101336306B/zh not_active Expired - Fee Related
- 2006-11-28 JP JP2008542854A patent/JP5563763B2/ja not_active Expired - Fee Related
- 2006-11-28 RU RU2008125977/02A patent/RU2424332C2/ru not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| RU2424332C2 (ru) | 2011-07-20 |
| AU2006329687B2 (en) | 2011-01-06 |
| WO2007074360A2 (en) | 2007-07-05 |
| CN101336306B (zh) | 2012-05-30 |
| WO2007074360A3 (en) | 2007-10-18 |
| UA93991C2 (uk) | 2011-03-25 |
| RU2008125977A (ru) | 2010-01-10 |
| KR20080075203A (ko) | 2008-08-14 |
| JP2009517548A (ja) | 2009-04-30 |
| JP5563763B2 (ja) | 2014-07-30 |
| ZA200802808B (en) | 2009-10-28 |
| EP1954843B1 (en) | 2013-01-02 |
| AU2006329687A1 (en) | 2007-07-05 |
| EP1954843A2 (en) | 2008-08-13 |
| BRPI0619012B1 (pt) | 2014-01-21 |
| CN101336306A (zh) | 2008-12-31 |
| KR101329838B1 (ko) | 2013-11-14 |
| AR058245A1 (es) | 2008-01-23 |
| BRPI0619012A2 (pt) | 2011-09-20 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG | Grant, registration |