MX2014008253A - Hydrogenation catalysts with cobalt-modified supports. - Google Patents
Hydrogenation catalysts with cobalt-modified supports.Info
- Publication number
- MX2014008253A MX2014008253A MX2014008253A MX2014008253A MX2014008253A MX 2014008253 A MX2014008253 A MX 2014008253A MX 2014008253 A MX2014008253 A MX 2014008253A MX 2014008253 A MX2014008253 A MX 2014008253A MX 2014008253 A MX2014008253 A MX 2014008253A
- Authority
- MX
- Mexico
- Prior art keywords
- catalysts
- cobalt
- hydrogenation catalysts
- modified supports
- modified
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 6
- 238000005984 hydrogenation reaction Methods 0.000 title 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 abstract 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 2
- 238000001311 chemical methods and process Methods 0.000 abstract 1
- 229910017052 cobalt Inorganic materials 0.000 abstract 1
- 239000010941 cobalt Substances 0.000 abstract 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000010970 precious metal Substances 0.000 abstract 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/888—Tungsten
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/024—Multiple impregnation or coating
- B01J37/0244—Coatings comprising several layers
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/08—Silica
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- B01J23/002—Mixed oxides other than spinels, e.g. perovskite
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- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
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- B01J23/56—Platinum group metals
- B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
- B01J23/622—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead
- B01J23/626—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead with tin
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- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
- B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/898—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with vanadium, tantalum, niobium or polonium
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- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
- B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8986—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with manganese, technetium or rhenium
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- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
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- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
- B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8993—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with chromium, molybdenum or tungsten
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- B01J23/90—Regeneration or reactivation
- B01J23/96—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the noble metals
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- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/19—Catalysts containing parts with different compositions
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0205—Impregnation in several steps
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- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01J37/024—Multiple impregnation or coating
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J37/08—Heat treatment
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
- C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
- C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
- C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
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- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
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- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
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- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
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- B01J23/34—Manganese
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
The present invention relates to catalysts, to processes for making catalysts and to chemical processes employing such catalysts. The catalysts are preferably used for converting acetic acid to ethanol. The catalyst comprises a precious metal and one or more active metals on a modified support that comprises cobalt.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201261583874P | 2012-01-06 | 2012-01-06 | |
PCT/US2012/052513 WO2013103399A1 (en) | 2012-01-06 | 2012-08-27 | Hydrogenation catalysts with cobalt-modified supports |
Publications (1)
Publication Number | Publication Date |
---|---|
MX2014008253A true MX2014008253A (en) | 2014-08-08 |
Family
ID=46939985
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2014008253A MX2014008253A (en) | 2012-01-06 | 2012-08-27 | Hydrogenation catalysts with cobalt-modified supports. |
MX2014008252A MX2014008252A (en) | 2012-01-06 | 2012-08-27 | Precious metal, active metal and modified support - containing hydrogenation catalysts and acetic acid hydrogenation process using the same. |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2014008252A MX2014008252A (en) | 2012-01-06 | 2012-08-27 | Precious metal, active metal and modified support - containing hydrogenation catalysts and acetic acid hydrogenation process using the same. |
Country Status (7)
Country | Link |
---|---|
US (4) | US8865609B2 (en) |
EP (1) | EP2800625A1 (en) |
CN (2) | CN104039448B (en) |
BR (1) | BR112014015584A8 (en) |
MX (2) | MX2014008253A (en) |
TW (2) | TWI571304B (en) |
WO (5) | WO2013103399A1 (en) |
Families Citing this family (43)
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EP2800625A1 (en) | 2012-01-06 | 2014-11-12 | Celanese International Corporation | Hydrogenation catalysts with cobalt-modified supports |
WO2013103398A1 (en) | 2012-01-06 | 2013-07-11 | Celanese International Corporation | Modified catalyst supports and process for producing ethanol using the catalyst |
US8937203B2 (en) | 2012-01-06 | 2015-01-20 | Celanese International Corporation | Multifunctional hydrogenation catalysts |
US8815768B2 (en) | 2012-01-06 | 2014-08-26 | Celanese International Corporation | Processes for making catalysts with acidic precursors |
WO2013103394A1 (en) | 2012-01-06 | 2013-07-11 | Celanese International Corporation | Processes for making catalysts with metal halide precursors |
US10155908B2 (en) * | 2012-03-07 | 2018-12-18 | Research Triangle Institute | Catalyst compositions and use thereof in catalytic biomass pyrolysis |
US9266095B2 (en) | 2014-01-27 | 2016-02-23 | Celanese International Corporation | Hydrogenation catalysts with cobalt and alkaline-earth metal modified supports |
US9073815B1 (en) | 2014-04-28 | 2015-07-07 | Celanese International Corporation | Hydrogenation catalysts comprising a mixed oxide and processes for producing ethanol |
US9024088B1 (en) | 2014-04-28 | 2015-05-05 | Celanese International Corporation | Hydrogenation catalysts comprising a mixed oxide comprising nickel |
US9353035B2 (en) | 2014-04-28 | 2016-05-31 | Celanese International Corporation | Process for producing ethanol with zonal catalysts |
WO2015168021A1 (en) | 2014-04-28 | 2015-11-05 | Celanese International Corporation | Process for producing ethanol with zonal catalysts |
US9382177B2 (en) | 2014-04-28 | 2016-07-05 | Celanese International Corporation | Hydrogenation catalysts comprising a mixed oxide comprising a promoter metal |
US9670120B2 (en) | 2015-01-27 | 2017-06-06 | Celanese International Corporation | Process for producing ethanol using a solid catalyst |
US9540297B2 (en) | 2015-04-27 | 2017-01-10 | Celanese International Corporation | Ruthenium-bismuth mixed oxide hydrogenation catalysts and processes for producing ethanol |
WO2016175747A1 (en) | 2015-04-27 | 2016-11-03 | Celanese International Corporation | Hydrogenation catalysts comprising a mixed oxide having bismuth and process for producing ethanol |
WO2016175745A1 (en) | 2015-04-27 | 2016-11-03 | Celanese International Corporation | Ruthenium-bismuth mixed oxide hydrogenation catalysts and processes for producing ethanol |
TWI549749B (en) * | 2015-05-07 | 2016-09-21 | China Petrochemical Dev Corp Taipei Taiwan | A catalyst composition for preparing o-phenylphenol and a process for preparing o-phenylphenol using the catalyst composition |
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US10702856B2 (en) * | 2016-05-31 | 2020-07-07 | Sabic Global Technologies B.V. | Catalysts made with manganese tungsten oxide for the oxidative coupling of methane |
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-
2012
- 2012-08-27 EP EP12766360.7A patent/EP2800625A1/en not_active Withdrawn
- 2012-08-27 CN CN201280066042.4A patent/CN104039448B/en not_active Expired - Fee Related
- 2012-08-27 CN CN201280066038.8A patent/CN104039446B/en not_active Expired - Fee Related
- 2012-08-27 WO PCT/US2012/052513 patent/WO2013103399A1/en active Application Filing
- 2012-08-27 BR BR112014015584A patent/BR112014015584A8/en not_active IP Right Cessation
- 2012-08-27 WO PCT/US2012/052500 patent/WO2013103395A1/en active Application Filing
- 2012-08-27 MX MX2014008253A patent/MX2014008253A/en unknown
- 2012-08-27 MX MX2014008252A patent/MX2014008252A/en unknown
- 2012-08-27 US US13/595,365 patent/US8865609B2/en not_active Expired - Fee Related
- 2012-08-27 US US13/595,340 patent/US8975200B2/en not_active Expired - Fee Related
- 2012-12-20 WO PCT/US2012/070947 patent/WO2013103534A1/en active Application Filing
-
2013
- 2013-01-04 WO PCT/US2013/020329 patent/WO2013103852A1/en active Application Filing
- 2013-01-04 WO PCT/US2013/020328 patent/WO2013103851A1/en active Application Filing
- 2013-01-04 TW TW102100171A patent/TWI571304B/en not_active IP Right Cessation
- 2013-01-04 TW TW102100172A patent/TW201336813A/en unknown
-
2014
- 2014-09-16 US US14/487,581 patent/US9381500B2/en not_active Expired - Fee Related
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- 2015-02-27 US US14/634,277 patent/US9308523B2/en not_active Expired - Fee Related
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WO2013103399A1 (en) | 2013-07-11 |
US20130178661A1 (en) | 2013-07-11 |
BR112014015584A2 (en) | 2017-06-13 |
US8975200B2 (en) | 2015-03-10 |
US9381500B2 (en) | 2016-07-05 |
BR112014015584A8 (en) | 2017-07-04 |
US8865609B2 (en) | 2014-10-21 |
US20150025281A1 (en) | 2015-01-22 |
TWI571304B (en) | 2017-02-21 |
US20150165419A1 (en) | 2015-06-18 |
WO2013103851A1 (en) | 2013-07-11 |
CN104039446B (en) | 2016-12-28 |
EP2800625A1 (en) | 2014-11-12 |
TW201336813A (en) | 2013-09-16 |
US20130178664A1 (en) | 2013-07-11 |
WO2013103534A1 (en) | 2013-07-11 |
MX2014008252A (en) | 2014-08-08 |
CN104039448B (en) | 2016-11-16 |
US9308523B2 (en) | 2016-04-12 |
CN104039448A (en) | 2014-09-10 |
WO2013103852A1 (en) | 2013-07-11 |
CN104039446A (en) | 2014-09-10 |
WO2013103395A1 (en) | 2013-07-11 |
TW201334868A (en) | 2013-09-01 |
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