KR960001326A - Flameproof treatment method of fabric - Google Patents

Flameproof treatment method of fabric Download PDF

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Publication number
KR960001326A
KR960001326A KR1019950016883A KR19950016883A KR960001326A KR 960001326 A KR960001326 A KR 960001326A KR 1019950016883 A KR1019950016883 A KR 1019950016883A KR 19950016883 A KR19950016883 A KR 19950016883A KR 960001326 A KR960001326 A KR 960001326A
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South Korea
Prior art keywords
fabric
flame retardant
phosphonium
fiber
fibers
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KR1019950016883A
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Korean (ko)
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KR100390564B1 (en
Inventor
핑 레이 샤오
자키카니 모우센
Original Assignee
로저 고든 매즈웍 새비지
알브라이트 앤드 윌슨 유케이 리미티드
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Application filed by 로저 고든 매즈웍 새비지, 알브라이트 앤드 윌슨 유케이 리미티드 filed Critical 로저 고든 매즈웍 새비지
Publication of KR960001326A publication Critical patent/KR960001326A/en
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Publication of KR100390564B1 publication Critical patent/KR100390564B1/en

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Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
    • D06M15/423—Amino-aldehyde resins
    • D06M15/43—Amino-aldehyde resins modified by phosphorus compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/282—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
    • D06M13/285—Phosphines; Phosphine oxides; Phosphine sulfides; Phosphinic or phosphinous acids or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K21/00—Fireproofing materials
    • C09K21/06—Organic materials
    • C09K21/12—Organic materials containing phosphorus
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
    • D06M15/423—Amino-aldehyde resins
    • D06M15/43—Amino-aldehyde resins modified by phosphorus compounds
    • D06M15/431—Amino-aldehyde resins modified by phosphorus compounds by phosphines or phosphine oxides; by oxides or salts of the phosphonium radical

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Fireproofing Substances (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Treatment Of Fiber Materials (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

Abstract

In the flame-retardant treatment of fabrics, there is provided a means for increased "loading" of phosphorus compounds (up to 25% moisture is retained after impregnation and drying of the fabric). This in turn enables a phosphonium compound "add-on" of 50% to 73% (relative to the weight of the fabric) and gives a correspondingly higher degree of flame-retardant properties.

Description

직물의 방염 처리 방법Flameproof treatment method of fabric

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (14)

직물에 방염 특성을 부여하는 직물 처리 방법에 있어서, 다음 단계를 포함함을 특징으로 하는 직물의 방염 처리방법: (a)직물을 폴리(히드록시오르가노) 포스포늄 화합물의 수용액으로 함침시키는 단계 ; (b)함침시킨 직물을 잔여 수분 함량이 13-25%이도록 건조시키는 단계; (c)직물 섬유 내에 기계적으로 고정된, 경화되고 물에 불용성인 중합체를 제조하기 위해 건조시킨 함침직물을 암모니아로 경화시키는 단계; (d)산화시키기 전 적어도 한 시간 동안 직물을 배칭(batching)시키는 단계; (e)3가 인을 5가 인으로 전환시키기 위해 경화시킨 중합체를 산화시키는 단계; (f)직물을 세척 및 건조시키는 단계.A fabric treatment method for imparting flame retardant properties to fabrics, the method comprising: (a) impregnating a fabric with an aqueous solution of a poly (hydroxyorgano) phosphonium compound; (b) drying the impregnated fabric to a residual moisture content of 13-25%; (c) curing the dried impregnated fabric with ammonia to produce a cured and water insoluble polymer that is mechanically fixed in the fabric fibers; (d) batching the fabric for at least one hour prior to oxidation; (e) oxidizing the cured polymer to convert trivalent phosphor to pentavalent phosphorus; (f) washing and drying the fabric. 제1항에 있어서, 폴리(히드록시오르가노) 포스포늄 화합물은 기본적으로테트라키스(히드록시알킬) 포스포늄 염으로 이루어짐을 특징으로 하는 직물의 방염 처리 방법.The method of claim 1, wherein the poly (hydroxyorgano) phosphonium compound consists essentially of a tetrakis (hydroxyalkyl) phosphonium salt. 제1항에 있어서, 폴리(히드록시오르가노)포스포늄 화합물은테트라키스(히드록시알킬) 포스포늄 염과 질소-함유화합물의 축합물을 포함함을 특징으로 하는 직물의 방염처리 방법.The method of claim 1, wherein the poly (hydroxyorgano) phosphonium compound comprises a condensate of a tetrakis (hydroxyalkyl) phosphonium salt with a nitrogen-containing compound. 제2항 또는 3항에 있어서,테트라키스(히드록시알킬) 포스포늄 염은테트라키스(히드록시메틸) 포스포늄 클로라이드임을 특징으로 하는 직물의 방염처리 방법.The process of claim 2 or 3 wherein the tetrakis (hydroxyalkyl) phosphonium salt is tetrakis (hydroxymethyl) phosphonium chloride. 제3항에 잇어서, 질소-함유 화합물은 우레아임을 특징으로 하는 직물의 방염처리 방법.The method of claim 3, wherein the nitrogen-containing compound is urea. 제1항-5항 중 어느 한 항에 있어서, (b)단계에서 함침 직물은 잔여 수분 함량이 17-23% 범위 이내이도록 건조시킴을 특징으로 하는 직물의 방염처리 방법.6. The method of claim 1, wherein the impregnated fabric is dried in step (b) such that the residual moisture content is within the range of 17-23%. 제1항-6항 중 어느 한 항에 있어서, 산화단계 (e)는 습윤제의 존재 하에 관산화수소를 사용하여 수행함을 특징으로 하는 직물의 방염처리 방법.The flame retardant treatment method according to claim 1, wherein the oxidation step (e) is carried out using hydrogen peroxide in the presence of a humectant. 제7항에 있어서, (e) 단계에서 사용하는 과산화수소의 양은 직물 중량의 25%까지임을 특징으로 하는 직물의 방염처리 방법.8. The method of flame retardant fabric according to claim 7, wherein the amount of hydrogen peroxide used in step (e) is up to 25% of the weight of the fabric. 상기 전 항 중 어느 한 항에 이써서, 단계 (a)후 포스포늄 화합물의 "부착량"은 직물 중량의 50-73%임을 특징으로 하는 직물의 방염처리 방법.Process according to any one of the preceding claims, wherein after step (a) the "adhesion amount" of the phosphonium compound is 50-73% of the weight of the fabric. 상기 전 항 중 어느 한 항에 있어서, 처리 직물은 기본적으로 셀룰로오스 섬유,예를 들면 면 섬유로 이루어짐을 특징으로 하는 직물의 방염처리 방법.The flame retardant treatment method according to any one of the preceding claims, wherein the treated fabric consists essentially of cellulose fibers, for example cotton fibers. 제1-9항 중 어느 한 항에 있어서, 처리 직물을 셀룰로오스 섬유와 비-셀룰로오스 섬유를 포함함을 특징으로 하는 직물의 방염처리 방법.The flame retardant treatment method according to any one of claims 1-9, wherein the treated fabric comprises cellulose fibers and non-cellulose fibers. 제11항에 있어서, 비-셀룰로오스 섬유는 폴리아미드 섬유, 아크릴 섬유, 아라미드 섬유, 폴리에스테르섬유 또는 폴리벤즈이미다졸 섬유임을 특징으로 하는 직물의 방염처리 방법.12. The method for flame retardant fabric according to claim 11, wherein the non-cellulose fiber is polyamide fiber, acrylic fiber, aramid fiber, polyester fiber or polybenzimidazole fiber. 제11항에 또는 12항에 있어서, 직물은 60%면 섬유와 40% 폴리에스테르 섬유를 포함함을 특징으로 하는 직물의 방염처리 방법.13. The method of claim 11 or 12 wherein the fabric comprises 60% cotton fibers and 40% polyester fibers. 상기 전 항 중 어느 한 항에 있어서, (a)단계에서 수용액은 하나 이상의 일차, 이차 또는 삼차 지방족 아민 또한 함유하되, 이 아민은 용액에 가해지 전 양성자 첨가 및 중화된 것임을 특징으로 하는 직물의 방염처리 방법.The flame retardant of any one of the preceding claims, wherein in step (a) the aqueous solution also contains one or more primary, secondary or tertiary aliphatic amines, the amines being protonated and neutralized before being added to the solution. Way. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019950016883A 1994-06-22 1995-06-22 Flame-retardant treatment of fabrics KR100390564B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB9412484A GB9412484D0 (en) 1994-06-22 1994-06-22 Flame-retardant treatment of fabrics
GB9412484.9 1994-06-22

Publications (2)

Publication Number Publication Date
KR960001326A true KR960001326A (en) 1996-01-25
KR100390564B1 KR100390564B1 (en) 2003-09-13

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US (1) US5571288A (en)
EP (1) EP0688898B1 (en)
JP (1) JP3721211B2 (en)
KR (1) KR100390564B1 (en)
CN (1) CN1076769C (en)
AT (1) ATE199749T1 (en)
AU (1) AU682955B2 (en)
BR (1) BR9502871A (en)
CA (1) CA2152319C (en)
CZ (1) CZ291356B6 (en)
DE (1) DE69520305T2 (en)
DK (1) DK0688898T3 (en)
ES (1) ES2157274T3 (en)
FI (1) FI112954B (en)
GB (2) GB9412484D0 (en)
GR (1) GR3036014T3 (en)
HK (1) HK1005064A1 (en)
HU (1) HU218421B (en)
IN (1) IN191142B (en)
MY (1) MY113072A (en)
NO (1) NO308865B1 (en)
NZ (1) NZ272308A (en)
PL (1) PL184152B1 (en)
PT (1) PT688898E (en)
RU (1) RU2127341C1 (en)
SI (1) SI0688898T1 (en)
TW (1) TW387956B (en)
ZA (1) ZA954850B (en)

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CA2792073C (en) 2010-05-11 2014-07-22 Milliken & Company Flame resistant textile materials providing protection from near infrared radiation
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AT510909B1 (en) * 2010-12-20 2013-04-15 Chemiefaser Lenzing Ag FLAME-RESISTANT CELLULOSIC MAN-MADE FIBERS
GB2497974A (en) 2011-12-23 2013-07-03 Rhodia Operations Applying acetoacetamide to textiles, to remove formaldehyde by-product of fire retardant treatment
EP2614734A1 (en) * 2012-01-10 2013-07-17 Manufactures Industrials de Tortella, SA Flame-retardant waterproof stretchable natural fabric and a pillow or mattress protector/encasement using said fabric
US9453112B2 (en) * 2013-06-04 2016-09-27 Milliken & Company Phosphorus-containing polymer, article, and processes for producing the same
CN105603742B (en) * 2016-01-26 2017-12-29 北京化工大学 A kind of method of the flame-retardant modified synthetic textiles of protein
BR112019002870B1 (en) * 2016-09-01 2022-05-17 Rhodia Operations Low formaldehyde flame retardant treated fabrics
JP6917690B2 (en) * 2016-09-29 2021-08-11 エア・ウォーター炭酸株式会社 Cooling clothes for hot work
KR101985106B1 (en) * 2017-11-10 2019-06-03 다이텍연구원 Flameproof method of blended yarn goods having aramid fibers, and Blended yarn goods manufactured of the same
KR102050566B1 (en) * 2018-12-27 2019-12-13 다이텍연구원 Flameproof method of cellulose fabric, and RAYON goods manufactured of cellulose fabric of the same

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Also Published As

Publication number Publication date
KR100390564B1 (en) 2003-09-13
ES2157274T3 (en) 2001-08-16
JPH0813345A (en) 1996-01-16
FI953138A (en) 1995-12-23
PL184152B1 (en) 2002-09-30
EP0688898B1 (en) 2001-03-14
JP3721211B2 (en) 2005-11-30
EP0688898A1 (en) 1995-12-27
CA2152319A1 (en) 1995-12-23
GB2290562B (en) 1998-03-11
PL309215A1 (en) 1995-12-27
AU2180095A (en) 1996-01-04
HU9501837D0 (en) 1995-08-28
BR9502871A (en) 1996-01-30
CZ291356B6 (en) 2003-02-12
ZA954850B (en) 1996-05-02
IN191142B (en) 2003-09-27
FI953138A0 (en) 1995-06-22
TW387956B (en) 2000-04-21
NZ272308A (en) 1996-10-28
PT688898E (en) 2001-07-31
CN1124803A (en) 1996-06-19
GB2290562A (en) 1996-01-03
US5571288A (en) 1996-11-05
DE69520305D1 (en) 2001-04-19
ATE199749T1 (en) 2001-03-15
NO308865B1 (en) 2000-11-06
NO952489L (en) 1995-12-27
GB9412484D0 (en) 1994-08-10
HK1005064A1 (en) 1998-12-18
DK0688898T3 (en) 2001-04-23
NO952489D0 (en) 1995-06-21
MY113072A (en) 2001-11-30
HU218421B (en) 2000-08-28
CA2152319C (en) 2007-04-24
RU95114529A (en) 1997-06-10
GR3036014T3 (en) 2001-09-28
AU682955B2 (en) 1997-10-23
FI112954B (en) 2004-02-13
SI0688898T1 (en) 2001-10-31
HUT72102A (en) 1996-03-28
CN1076769C (en) 2001-12-26
GB9511343D0 (en) 1995-08-02
DE69520305T2 (en) 2001-09-06
RU2127341C1 (en) 1999-03-10
CZ164195A3 (en) 1996-05-15

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