KR940007016A - 축합헤테로사이클 유도체 및 그것을 함유한 농업용 또는 원예용 살균제 - Google Patents

축합헤테로사이클 유도체 및 그것을 함유한 농업용 또는 원예용 살균제 Download PDF

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KR940007016A
KR940007016A KR1019930017947A KR930017947A KR940007016A KR 940007016 A KR940007016 A KR 940007016A KR 1019930017947 A KR1019930017947 A KR 1019930017947A KR 930017947 A KR930017947 A KR 930017947A KR 940007016 A KR940007016 A KR 940007016A
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group
ethyl
carbonyl
structural formula
benzo
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KR0139185B1 (ko
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마사루 시바타
시게카즈 이토
준에츠 사카이
시게루 하야시
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모치즈키 노부히코
구미아이 가가쿠고교 가부시키가이샤
이하라케미칼고교 가부시키가이샤
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Abstract

본 발명은 하기 구조식으로 표시되는 축합헤테로싸이클 유도체
(상기 구조식에서 R1은 저급알킬기, 알케닐기등을 표시하고, R2, R3, R4, R5, 및 R6는 각각 수소원자, 저급알킬등을 표시하고, W는 -OC(O)-, -SC(O)-,등을 표시하고, Z는 2-인돌일기을 표시한다)를 제공하는 것이다. 또한 본 발명은 살균제로서 효과가 있는 것으로 알려진 축합유도체를 함유하는 농업용 및 원예용 살균제를 제공하는 것이다. 본 발명에 따른 농업용 또는 원예용 살균제를 비균, 광합성식물엔 해가 없이 노균병 및 잎마름병에 뛰어난 살균효과를 나타낸다.

Description

축합헤테로사이클 유도체 및 그것을 함유한 농업용 또는 원예용 살균제
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (8)

  1. 하기 구조식으로 표시되는 축합헤테로싸이클 유도체
    상기 구조식에서 R1은 할로겐원자, 시아노기, 및 메톡시기중에서 선택된 적어도 하나 이상의 치환기를 선택적으로 가진 C1∼C6알킬기, C2∼C6알케닐기, C2∼C6알키닐기 적어도 하나이상의 메틸기를 선택적으로 가진 C3∼C8 사이클로알케닐기, 적어도 하나이상의 메틸기를 선택적으로 가진 C2∼C6사이클릭에테르기, 메틸기, 메톡시기, 및 니트로기로 구성되는 기중에서 선택된 적어도 하나이상의 치환기를 선택적으로 가진 C7∼C10아랄킬기, 할로겐원자, 메틸기, 메톡시기, 니트로기, 및 메톡시카르보닐기중에서 선택된 적어도 하나이상의 치환기를 선택적으로 가진 페닐기, 디메틸아미노기 또는 에톡시 카르보닐기를 표시하고, R2, R3, R4, R5및 R6는 각각 수소원자, 적어도 하나이상의 할로겐기를 선택적으로 가진 C1-C6알킬기, C3-C6사이클로알킬기, C7-C10아랄킬기; 페닐기, 시아노기, 아실기, C1∼C6알콕시기, 또는 C1∼C6알콕시카르보닐기를 표시하고, R2는 R3와 함께 C3-C6알킬고리를 형성해도 되며, Z는 다음 구조식으로 표시된다;
    상기 구조식에서 X는 구조식에서 R1은 적어도 하나이상의 할로겐원자를 선택적으로 가진 C1∼C6알킬기, C2∼C6알키닐기, 메톡시기, 트리플루오로메톡시기, 하이드록실기, 메톡시카르보닐기, 메탈카르보닐옥시기, 아미노기, 디메틸아미노기, 니트로기, 메틸티오기, 메틸설피닐기, 메틸설포닐기, 페닐기, 아세틸기, 포르밀기, 또는 시아노기를 표시하고, n은 1,2 또는 3의 정수이고; A는 O,S,N, 또는 다음 구조식으로 표시되고,
    상기 구조식에서, R7은 수소원자, 메틸기, 아세틸기 또는 벤조일기를 나타내며; W는 -C(0)-, -SO2-, -NHC(O)-, -N(CH3)C(O)-, -OC(O)-, -SC(O)-, -OC(S)- 또는 -SC(S)-를 표시한다.
  2. 제1항에 있어서, 상기 구조식에서 R1은 C2∼C6 곧거나 또는 분기된 알킬기, C3 곧거나 또는 분기된 알케닐기, C5-C6사이클로알키기, 또는 페닐기를 표시하고, R2는 수소원자를 표시하고, R3는 에틸기, 이소프로필기, 또는 sec-부틸기를 표시하고, R4는 수소원자, 메틸기, 에틸기, 또는 페닐기를 표시하고, R5는 수소원자, 또는 메틸기를 표시하고, R6는 수소원자를 표시하고, Z는 벤조퓨란기, 벤조티오펜기, 인돌기, 또는 2,3-디하이드로벤조퓨란기등의 치환된 헤테로사이클기를 표시하며, 상기 2,3-디하이드로벤조퓨란은 플로우드 원자, 클로로원자, 니트로원자, 시아노기, 및 메틸기등 중에서 선택된 하나 또는 두개의 치환기를 가지는 것이며, W는 -OC(O)-를 표시하며 아미노산이 L-이성체인 것을 특징으로 하는 축합헤테로사이클 유도체.
  3. 제1항에 있어서, 상기 구조식에서 R1은 이소프로필기 tert-부틸기, sec-부틸기, 사이클로펜틸기, 이소프로페닐기, 또는 페닐기를 표시하고, R2는 수소원자를 표시하고, R3는 에틸기, 이소프로필기, 또는 sec-부틸기를 표시하고, R4는 메틸기를 표시하고, R6는 수소원자를 표시하고, R6는 수소원자를 표시하고, Z는 벤조퓨란기 또는 벤조티오펜기등의 치환 헤테로사이클로를 표시하고, 상기 벤조티오펜기는 플루오르원소, 클로로원소, 니트로기, 시아노기 및 메틸기로 구성된 기에서 선택된 하나 또는 두개의 치환기를 가지며, W는 -OC(CO)-를 표시하며, 아미노산은 L-이성체인 것을 특징으로 하는 축합헤테로싸이클 유도체.
  4. 제1항에 있어서, 상기 유도체에 N1-[1-(5-클로로-2-벤조프라닐)에틸]-N2-사이클로펜틸톡시카르보닐-L-발린아마이드, N1-[1-(5-클로로-2-벤조프라닐)에틸-N2-이소프로필옥시카르보닐-L-발린아마이드, N1-[1-(5-클로로-2-벤조프라닐)에틸]-N2-이소프로필옥시카르보닐-L-발린아마이드, N2-이소프로필옥시카르보닐-N1-[1-(5-니트로-2-벤조(퓨라닐)에틸]-L-빌린아마이드, N1-[1-(5-플루오르-2-벤조[b]티에닐)에틸]-N2-이소프로필옥시카르보닐-L-발린아마니드, N1-[1-(6-플루오르-2-벤조[b]테이닐)에틸]-N2-이소프로필옥시카르보닐-L-발린아마이드 또는 N1-[1-(5-클로로-2-벤조퓨라닐)에틸]-L-발린아마이드 N2-sec-부틸시카르보닐-N′-[1-(5-클로로-2-벤조프라닐)에틸]-L-발란아마이드 또는 N1-[1-(5-클로로-2-벤조퓨라닐)에틸]-N2-페녹시카르보닐-L-발란아마이드를 포함하는 것을 특징으로 하는 축합헤테로싸이클 유도체.
  5. 하기 구조식으로 표시되는 축합헤테로싸이클 유도체의 제조방법에 있어서,
    (상기 구조식에서, R1, R2, R3, R4, R5, R6, W 및 Z는 제1항에 정의된 것과 동일함) 하기 구조식으로 표시되는 아미노산 유도체.
    (상기에서, R1, R2, R3, 및 W는 제1항에서와 동일함)를 반응시키거나 또는 다음 구조식로 표시되는 아민유도체.
    (상기에서, R4, R5, R6및 Z는 제1항에서 정의된 것과 동일함)의 동량이상으로 활성화 되는 아미노산 유도체와 반응시키는 단계로 구성된 것을 특징으로 축합헤테로싸이클 유도체의 제조방법.
  6. 하기 구조식으로 표시되는 축합헤테로싸이클 유도체의 제조방법에 있어서,
    (상기 구조식에서, R1, R2, R3, R4, R5, R6, W 및 Z는 제1항에 정의된 것과 동일함) 하기 구조식으로 표시되는 아민유도체.
    (상기 구조식에서 R1, R2, R3, R4, R5, R6, W 및 Z는 제1항에 정의된 것과 동일함)와 반응시키거나, 또는 하기구조식으로 표시되는
    R1-W-Y
    (상기에서 R1및 W는 제1항에서 정의된 것과 동일하며, Y는 할로겐원자, 또는 R1OC(O)O-또는 R1C(O)O-로 표시됨)화합물의 동량이상으로 가지며 비유기산 또는 유기산을 가진 아민유도체의 염과 반응시키는 단계로 구성된 것을 특징으로 하는 축합헤테로싸이클 유도체 제조방법.
  7. 살균제 및 희석제로서의 효과를 가진 제1항에서 설명된 축합헤테로싸이클 유도체의 효과량을 함유하는 것을 특징으로 하는 농업용 또는 원예용 살균제.
  8. 식물에 대해 살균제로서의 효과를 가진 제1항에서 설명된 축합헤테로싸이클 유도체의 효과량을 투여하는 단계로 구성된 것을 특징으로 하는 농업 또는 원예의 비균 및 광합성식물에 해를 끼치는 균의 예방방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019930017947A 1992-09-07 1993-09-07 축합 헤테로 고리형 유도체, 이의 제조방법 및 이를 함유한 농원예용 살균제 KR0139185B1 (ko)

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CN1154964A (zh) 1997-07-23
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