KR830002907A - 2격실 전해용기 및 3격실 전해용기를 이용한 크롬산 제조방법 - Google Patents
2격실 전해용기 및 3격실 전해용기를 이용한 크롬산 제조방법Info
- Publication number
- KR830002907A KR830002907A KR1019800002115A KR800002115A KR830002907A KR 830002907 A KR830002907 A KR 830002907A KR 1019800002115 A KR1019800002115 A KR 1019800002115A KR 800002115 A KR800002115 A KR 800002115A KR 830002907 A KR830002907 A KR 830002907A
- Authority
- KR
- South Korea
- Prior art keywords
- electrolytic vessel
- chromic acid
- chamber
- compartment electrolytic
- alkali
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/22—Inorganic acids
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/14—Alkali metal compounds
- C25B1/16—Hydroxides
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B15/00—Operating or servicing cells
- C25B15/08—Supplying or removing reactants or electrolytes; Regeneration of electrolytes
- C25B15/085—Removing impurities
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 본 발명에 의한 방법을 사용하여 알칼리금속의 크롬산염을 공정중에 도입하여 크롬산을 제조하는 예를 나타낸 제조동정도.
제2도는 전체 공정중의 일부로서 불순물 제거의 예를 예시한 동정도.
Claims (1)
- 크롬광을 배소하고 고형분을 제거하여 일차로 중간체인 오염된 알칼리금속의 크롬산염을 만든 후 다시 처리하여 알칼리금속의 중크롬산용액으로부터 크롬산을 얻음에 있어서(가) 2%정도이하의 크롬산 6가 크롬으로서 존재하는 환원상태의 크롬을 함유하는 오염된 알칼리금속의 크롬산염을 불투과성인 양이온 교환막으로 음극실과 유입실로 구분된 전해용기의 유입실로 도입하고,(나) 전해질을 음극실로 도입하여,(다) 전해용기에 전해전류를 가하여 금속이온오염물을 전해용기의 양이온 교환막으로 유인함과 동시에 양극실에서 알칼리금속의 중크롬산염용액을 제조하고,(라) 음극실로 부터는 알칼리 생성물을 함유하는 전해된 음극액을 배출하며,(마) 전해용기로 부터는 거의 환원된 금속이온불순물을 가진 알칼리금속의 중크롬산염을 배출하고,(바) 중크롬산염용액을 공정의 하향류로 통과시켜 다음공정에서 크롬산을 제조함을 특징으로 하는 불순물제거가 용이한 크롬산 제조방법.※참고사항:최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US06/043,377 US4273628A (en) | 1979-05-29 | 1979-05-29 | Production of chromic acid using two-compartment and three-compartment cells |
US43377 | 1997-04-04 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR830002907A true KR830002907A (ko) | 1983-05-31 |
KR840001427B1 KR840001427B1 (ko) | 1984-09-26 |
Family
ID=21926871
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019800002115A KR840001427B1 (ko) | 1979-05-29 | 1980-05-28 | 2격실 전해조 및 3격실 전해조를 이용한 크롬산 제조방법 |
Country Status (9)
Country | Link |
---|---|
US (1) | US4273628A (ko) |
JP (1) | JPS55158281A (ko) |
KR (1) | KR840001427B1 (ko) |
AU (1) | AU534996B2 (ko) |
CA (1) | CA1164403A (ko) |
DE (1) | DE3020260A1 (ko) |
GB (1) | GB2051869B (ko) |
IT (1) | IT1145369B (ko) |
PH (1) | PH16158A (ko) |
Families Citing this family (25)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4560452A (en) * | 1983-03-07 | 1985-12-24 | The Dow Chemical Company | Unitary central cell element for depolarized, filter press electrolysis cells and process using said element |
DE3339449A1 (de) * | 1983-10-31 | 1985-05-09 | MD Verwaltungsgesellschaft Nicolaus GmbH & Co. KG, 8000 München | Verfahren zur gewinnung von lignin aus alkalischen lignin-loesungen |
AT382894B (de) * | 1985-02-27 | 1987-04-27 | Elin Union Ag | Verfahren zur elektrochemischen oxidation von schwefelsauren chrom-iii-loesungen zu chrom-vil¯sungen |
US4701246A (en) * | 1985-03-07 | 1987-10-20 | Kabushiki Kaisha Toshiba | Method for production of decontaminating liquid |
ZA877762B (en) * | 1986-10-29 | 1988-04-20 | Tenneco Canada Inc. | Electrochemical removal of chromium from chlorate solutions |
DE3829119A1 (de) * | 1988-08-27 | 1990-03-01 | Bayer Ag | Verfahren zur herstellung von alkalidichromaten und chromsaeure |
DE3911065A1 (de) * | 1989-04-06 | 1990-10-11 | Bayer Ag | Verfahren zur herstellung von alkalidichromaten und chromsaeuren durch elektrolyse |
ES2060906T3 (es) * | 1989-12-16 | 1994-12-01 | Bayer Ag | Procedimiento para la fabricacion de acido cromico. |
EP0433748B1 (de) * | 1989-12-16 | 1993-12-01 | Bayer Ag | Verfahren zur Herstellung von Chromsäure |
DE4020051A1 (de) * | 1990-06-23 | 1992-01-02 | Bayer Ag | Chromsaeure-herstellung unter verwendung von bipolaren membranen |
US5122238A (en) * | 1991-06-10 | 1992-06-16 | Occidental Chemical Corporation | Efficient electrolytic method of making chromic acid from sodium bichromate |
US6063252A (en) * | 1997-08-08 | 2000-05-16 | Raymond; John L. | Method and apparatus for enriching the chromium in a chromium plating bath |
US6468414B1 (en) | 2001-02-16 | 2002-10-22 | Hydro-Quebec | Method of purification of a redox mediator before electrolytic regeneration thereof |
GB2399349A (en) * | 2003-03-13 | 2004-09-15 | Kurion Technologies Ltd | Regeneration of chromic acid etching and pickling baths |
EP2841623B1 (en) | 2012-04-23 | 2020-10-28 | Nemaska Lithium Inc. | Processes for preparing lithium hydroxide |
US9382126B2 (en) | 2012-05-30 | 2016-07-05 | Nemaska Lithium Inc. | Processes for preparing lithium carbonate |
EP2971252B1 (en) | 2013-03-15 | 2020-12-30 | Nemaska Lithium Inc. | Processes for preparing lithium hydroxide |
WO2015058288A1 (en) * | 2013-10-23 | 2015-04-30 | Nemaska Lithium Inc. | Processes and systems for preparing lithium hydroxide |
KR102445712B1 (ko) | 2013-10-23 | 2022-09-20 | 네마스카 리튬 인코포레이션 | 리튬 카보네이트의 제조방법 |
EP3492632B1 (en) | 2014-02-24 | 2020-12-09 | Nemaska Lithium Inc. | Methods for treating lithium-containing materials |
JP7030049B2 (ja) | 2015-08-27 | 2022-03-04 | ネマスカ リチウム インコーポレーテッド | リチウム含有材料を処理するための方法 |
CA2940509A1 (en) | 2016-08-26 | 2018-02-26 | Nemaska Lithium Inc. | Processes for treating aqueous compositions comprising lithium sulfate and sulfuric acid |
KR20240075840A (ko) | 2017-11-22 | 2024-05-29 | 네마스카 리튬 인코포레이션 | 다양한 금속의 하이드록사이드와 옥사이드 및 이들의 유도체를 제조하는 방법 |
US10590548B1 (en) * | 2018-12-18 | 2020-03-17 | Prometheus Fuels, Inc | Methods and systems for fuel production |
US11920248B2 (en) | 2018-12-18 | 2024-03-05 | Prometheus Fuels, Inc | Methods and systems for fuel production |
Family Cites Families (30)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA739447A (en) * | 1966-07-26 | W. Carlin William | Electrolytic production of chromic acid | |
US2099658A (en) * | 1933-11-09 | 1937-11-16 | Gilbert | Preparation of chromic acid and sparingly soluble chromates |
US2081787A (en) * | 1936-06-15 | 1937-05-25 | Chromium Products Corp | Electrolytic process and apparatus for the production of chromic acid and caustic alkali |
US2612435A (en) * | 1948-11-13 | 1952-09-30 | Diamond Alkali Co | Method for recovery of vanadiumfree chromate and aluminate |
US2931704A (en) * | 1958-06-16 | 1960-04-05 | Columbia Southern Chem Corp | Sodium dichromate production |
US3041317A (en) * | 1960-05-02 | 1962-06-26 | Du Pont | Fluorocarbon sulfonyl fluorides |
NL278049A (ko) * | 1961-05-05 | |||
US3117023A (en) * | 1962-01-03 | 1964-01-07 | Ionics | Method of making a non-corroding electrode |
GB952251A (en) * | 1962-02-02 | 1964-03-11 | Tube Prod Ltd | Electric transformer |
US3305463A (en) * | 1962-03-16 | 1967-02-21 | Pittsburgh Plate Glass Co | Electrolytic production of dichromates |
GB1004380A (en) * | 1962-11-21 | 1965-09-15 | Ici Australia Ltd | Electrochemical cells and manufacture of electrodes therefor |
US3624053A (en) * | 1963-06-24 | 1971-11-30 | Du Pont | Trifluorovinyl sulfonic acid polymers |
US3282875A (en) * | 1964-07-22 | 1966-11-01 | Du Pont | Fluorocarbon vinyl ether polymers |
US3454478A (en) * | 1965-06-28 | 1969-07-08 | Ppg Industries Inc | Electrolytically reducing halide impurity content of alkali metal dichromate solutions |
GB1184331A (en) * | 1967-01-21 | 1970-03-11 | Concentric Pumps Ltd | Improvements relating to Fan Assemblies for Internal Combustion Engine Coolant Systems |
GB1195871A (en) * | 1967-02-10 | 1970-06-24 | Chemnor Ag | Improvements in or relating to the Manufacture of Electrodes. |
US3840443A (en) * | 1967-02-10 | 1974-10-08 | Chemnor Corp | Method of making an electrode having a coating comprising a platinum metal oxide |
US3616445A (en) * | 1967-12-14 | 1971-10-26 | Electronor Corp | Titanium or tantalum base electrodes with applied titanium or tantalum oxide face activated with noble metals or noble metal oxides |
US3784399A (en) * | 1971-09-08 | 1974-01-08 | Du Pont | Films of fluorinated polymer containing sulfonyl groups with one surface in the sulfonamide or sulfonamide salt form and a process for preparing such |
BE790369A (fr) * | 1971-10-21 | 1973-04-20 | Diamond Shamrock Corp | Procede et appareil pour la preparation d'hydroxydes de metaux alcalins de haute purete dans une cuve electrolytique. |
US3849243A (en) * | 1971-11-08 | 1974-11-19 | Du Pont | Laminates of support material and fluorinated polymer containing pendant side chains containing sulfonyl groups |
IT959730B (it) * | 1972-05-18 | 1973-11-10 | Oronzio De Nura Impianti Elett | Anodo per sviluppo di ossigeno |
US3841851A (en) * | 1974-02-12 | 1974-10-15 | E Kaiser | Process and apparatus for the gasification of organic matter |
US3909378A (en) * | 1974-06-21 | 1975-09-30 | Du Pont | Composite cation exchange membrane and use thereof in electrolysis of an alkali metal halide |
US3909381A (en) * | 1974-11-18 | 1975-09-30 | Raymond John L | Purification of chromium plating solutions by electrodialysis |
AR205953A1 (es) * | 1975-01-22 | 1976-06-15 | Diamond Shamrock Corp | Produccion de carbonatos de metales a calinos en una celula de membrana |
US4024044A (en) * | 1975-09-15 | 1977-05-17 | Diamond Shamrock Corporation | Electrolysis cathodes bearing a melt-sprayed and leached nickel or cobalt coating |
US4053371A (en) * | 1976-06-01 | 1977-10-11 | The Dow Chemical Company | Cellular metal by electrolysis |
US4101395A (en) * | 1976-08-30 | 1978-07-18 | Tokuyama Soda Kabushiki Kaisha | Cathode-structure for electrolysis |
US4104133A (en) * | 1977-07-27 | 1978-08-01 | Diamond Shamrock Corporation | Method of in situ plating of an active coating on cathodes of alkali halide electrolysis cells |
-
1979
- 1979-05-29 US US06/043,377 patent/US4273628A/en not_active Expired - Lifetime
-
1980
- 1980-05-23 CA CA000352649A patent/CA1164403A/en not_active Expired
- 1980-05-27 AU AU58789/80A patent/AU534996B2/en not_active Ceased
- 1980-05-27 IT IT48802/80A patent/IT1145369B/it active
- 1980-05-28 GB GB8017422A patent/GB2051869B/en not_active Expired
- 1980-05-28 JP JP7131980A patent/JPS55158281A/ja active Granted
- 1980-05-28 KR KR1019800002115A patent/KR840001427B1/ko active
- 1980-05-28 DE DE19803020260 patent/DE3020260A1/de active Granted
- 1980-05-28 PH PH24078A patent/PH16158A/en unknown
Also Published As
Publication number | Publication date |
---|---|
KR840001427B1 (ko) | 1984-09-26 |
US4273628A (en) | 1981-06-16 |
DE3020260A1 (de) | 1980-12-11 |
GB2051869B (en) | 1983-03-16 |
IT8048802A0 (it) | 1980-05-27 |
PH16158A (en) | 1983-07-18 |
AU534996B2 (en) | 1984-02-23 |
GB2051869A (en) | 1981-01-21 |
DE3020260C2 (ko) | 1989-11-16 |
AU5878980A (en) | 1980-12-04 |
CA1164403A (en) | 1984-03-27 |
IT1145369B (it) | 1986-11-05 |
JPS6366396B2 (ko) | 1988-12-20 |
JPS55158281A (en) | 1980-12-09 |
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