KR20240006874A - Multi-tone effect with Linen-like Polyester Composite Yarn And Method preparing same - Google Patents
Multi-tone effect with Linen-like Polyester Composite Yarn And Method preparing same Download PDFInfo
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- 229920000728 polyester Polymers 0.000 title claims abstract description 108
- 239000002131 composite material Substances 0.000 title claims abstract description 44
- 230000000694 effects Effects 0.000 title claims abstract description 34
- 238000000034 method Methods 0.000 title claims description 9
- 238000002844 melting Methods 0.000 claims abstract description 69
- 230000008018 melting Effects 0.000 claims abstract description 54
- 229920001225 polyester resin Polymers 0.000 claims abstract description 27
- 239000004645 polyester resin Substances 0.000 claims abstract description 27
- 238000010438 heat treatment Methods 0.000 claims abstract description 16
- 238000004519 manufacturing process Methods 0.000 claims description 8
- 230000004927 fusion Effects 0.000 claims description 7
- 125000002091 cationic group Chemical group 0.000 abstract description 5
- 238000004043 dyeing Methods 0.000 abstract 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 238000009941 weaving Methods 0.000 description 5
- 229920000742 Cotton Polymers 0.000 description 4
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 229920000139 polyethylene terephthalate Polymers 0.000 description 4
- 239000005020 polyethylene terephthalate Substances 0.000 description 4
- 150000002009 diols Chemical class 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 239000012209 synthetic fiber Substances 0.000 description 3
- 229920002994 synthetic fiber Polymers 0.000 description 3
- 210000002268 wool Anatomy 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- -1 polyethylene terephthalate Polymers 0.000 description 2
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 description 1
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009954 braiding Methods 0.000 description 1
- 235000009120 camo Nutrition 0.000 description 1
- 235000005607 chanvre indien Nutrition 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000011487 hemp Substances 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- YXTFRJVQOWZDPP-UHFFFAOYSA-M sodium;3,5-dicarboxybenzenesulfonate Chemical compound [Na+].OC(=O)C1=CC(C(O)=O)=CC(S([O-])(=O)=O)=C1 YXTFRJVQOWZDPP-UHFFFAOYSA-M 0.000 description 1
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- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G1/00—Producing crimped or curled fibres, filaments, yarns, or threads, giving them latent characteristics
- D02G1/02—Producing crimped or curled fibres, filaments, yarns, or threads, giving them latent characteristics by twisting, fixing the twist and backtwisting, i.e. by imparting false twist
- D02G1/0206—Producing crimped or curled fibres, filaments, yarns, or threads, giving them latent characteristics by twisting, fixing the twist and backtwisting, i.e. by imparting false twist by false-twisting
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/28—Formation of filaments, threads, or the like while mixing different spinning solutions or melts during the spinning operation; Spinnerette packs therefor
- D01D5/30—Conjugate filaments; Spinnerette packs therefor
- D01D5/34—Core-skin structure; Spinnerette packs therefor
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/14—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyester as constituent
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/22—Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
- D02G3/34—Yarns or threads having slubs, knops, spirals, loops, tufts, or other irregular or decorative effects, i.e. effect yarns
- D02G3/346—Yarns or threads having slubs, knops, spirals, loops, tufts, or other irregular or decorative effects, i.e. effect yarns with coloured effects, i.e. by differential dyeing process
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/22—Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
- D02G3/36—Cored or coated yarns or threads
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- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02J—FINISHING OR DRESSING OF FILAMENTS, YARNS, THREADS, CORDS, ROPES OR THE LIKE
- D02J13/00—Heating or cooling the yarn, thread, cord, rope, or the like, not specific to any one of the processes provided for in this subclass
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/04—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/14—Dyeability
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
Abstract
본 발명은 카티온 가염성 폴리에스테르 태세사(TTD)와 저융점 폴리에스테르 수지를 포함하는 저융점 폴리에스테르사를 가열하면서 가연하여 카티온 가염성 폴리에스테르 태세사와 저융점 폴리에스테르사를 부분융착시켜 형성되어 천연 린넨과 같이 부드러우면서 샤리한 질감을 갖고 카티온 가염성 태세사를 통한 멀티 톤 효과로 천연 린넨과 같은 외관을 멀티 톤 효과를 갖는 린넨라이크 폴리에스테르 복합사에 관한 것이다.In the present invention, a low melting point polyester yarn containing a cationically dyeable polyester yarn (TTD) and a low melting point polyester resin is twisted while heating to partially fuse the cationically dyeable polyester yarn and the low melting point polyester yarn. This relates to a linen-like polyester composite yarn that is formed and has a soft and sharp texture like natural linen and has a multi-tone effect through cationic dyeing tack yarn and a multi-tone effect like natural linen.
Description
본 발명은 멀티 톤 효과를 갖는 린넨라이크 폴리에스테르 복합사에 관한 것으로 린넨과 같이 표면 질감이 샤리하면서도 소프트하고 표면 형태가 천연 린넨과 유사한 형태를 가지는 멀티 톤 효과를 갖는 린넨라이크 폴리에스테르 복합사 및 그의 제조방법에 관한 것이다.The present invention relates to a linen-like polyester composite yarn with a multi-tone effect. The present invention relates to a linen-like polyester composite yarn with a multi-tone effect, which has a surface texture that is sharp and soft like linen and has a surface shape similar to natural linen, and a linen-like polyester composite yarn with a multi-tone effect. It is about manufacturing method.
2이상의 실을 합사방식을 통한 복합사는 합성섬유가 가지고 있는 장점과 방적사가 갖고 있는 장점을 하나의 실에 결집시키고자 하는 광범위한 노력으로 개발되어 왔다.Composite yarns, made by plying two or more yarns, have been developed through extensive efforts to combine the strengths of synthetic fibers and spun yarns into one yarn.
종래에는 단순히 합성섬유의 필라멘트와 천연섬유의 방적사를 가연하는 형태의 합사방법으로 복합사를 제조하였으나, 점차 합사기술의 발달과 소비자의 다양한 욕구를 충족하기 위해 많은 사가공 기술이 개발되었다.Conventionally, composite yarns were manufactured by simply twisting filaments of synthetic fibers and spun yarns of natural fibers, but with the gradual development of braiding technology and to meet the diverse needs of consumers, many yarn processing technologies have been developed.
대한민국 공개특허 제2001-0063955호에서는 섬도가 50~100데니어인 아세테이트사와 폴리에스테르 불균일 연신사를 공기교락시켜서 제조한 폴리에스테르/아세테이트 복합사를 개시하고 있다. 대한민국 특허공개공보 제2006-78217호, 일본국 특개평 제1025636호 및 일본국 특개평 제11181643호에는 폴리아미드계 복합사의 제조방법에 대하여 개시하고 있다.Republic of Korea Patent Publication No. 2001-0063955 discloses a polyester/acetate composite yarn manufactured by air entanglement of acetate yarn with a fineness of 50 to 100 denier and polyester non-uniformly drawn yarn. Korean Patent Publication No. 2006-78217, Japanese Patent Laid-Open No. 1025636, and Japanese Patent Laid-Open No. 11181643 disclose a method of manufacturing polyamide-based composite yarn.
최근에는 모, 면, 마와 같이 천연소재와 같은 외관과 질감을 갖는 제품이 선호되면서 천연소재와 유사한 외관과 질감을 가지면서 합성섬유의 신축성이나 우수한 물성이 접목된 복합사가 많이 개발되고 제품화되고 있다.Recently, as products with the same appearance and texture as natural materials such as wool, cotton, and hemp are preferred, many composite yarns that have an appearance and texture similar to natural materials but combine the elasticity and excellent physical properties of synthetic fibers are being developed and commercialized. .
대한민국 등록특허 제1981757호는 신축성이 우수한 면조 복합사에 관한 발명으로 서로 다른 신축성을 갖는 심사와 효과사를 공기교락으로 합사한 후 가연공정으로 통해 제조하는 면조 복합사가 개시되어 있으며, 등록특허 제1855799호는 울라이크 폴리에스테르 복합사에 관한 것으로 폴리에스테르 POY 필라멘트, 잠재권축필라멘트 및 폴리에스테르방적사를 원사로 공급하여 인터레이스함으로써 최종 제조된 사의 형태가 양모섬유와 비슷한 외관을 가지도록 한 폴리에스테르복합사가 개시되었고, 공개특허 제2014-0070681호는 린넨-라이크 폴리에스테르 가연사에 관한 것으로 폴리에스터 원사를 특정한 조건에서 융착 가연사로 가공해 수분의 흡수와 발산성이 좋고 시원한 느낌이 드는 린넨-라이크 폴리에스테르 가연사가 개시되어 있다.Republic of Korea Patent No. 1981757 is an invention regarding cotton gin composite yarn with excellent elasticity. It discloses a cotton gin composite yarn manufactured by plying fine and effect yarns with different elasticities through air entanglement and then through a false twist process. Registered Patent No. 1855799 The issue relates to wool-like polyester composite yarn, which is a polyester composite yarn that supplies polyester POY filament, latent crimp filament, and polyester spun yarn as yarn and interlaces them so that the final manufactured yarn has an appearance similar to wool fiber. Publication Patent No. 2014-0070681 relates to linen-like polyester false twist yarn, which is a linen-like polyester false twist yarn that has good moisture absorption and dissipation properties and provides a cool feeling by processing polyester yarn into fusion false twist yarn under specific conditions. The company has been opened.
상기와 같이 면이나 울과 같은 외관 및 질감을 가자는 복합사는 실제 천연소재와 유사성이 높았으나, 린넨라이크 복합사는 린넨 특유의 시원한 촉감은 어느정도 재현할 수 있으나, 천연 린넨과 같이 부드러우면서 샤리한 질감을 발현하는데는 부족하였다.As mentioned above, composite yarns that have the appearance and texture of cotton or wool are highly similar to actual natural materials, but linen-like composite yarns can reproduce the unique cool feel of linen to some extent, but are soft and sharp like natural linen. It was insufficient to express texture.
본 발명은 상기와 같은 종래기술의 문제점을 해결하기 위해 발명된 것으로 카티온 가염성 폴리에스테르 태세사와 저융점 폴리에스테르사를 활용하여 천연 린넨과 같이 부드러우면서 샤리한 질감을 발현할 수 있는 멀티 톤 효과를 갖는 린넨라이크 폴리에스테르 복합사를 제공하는 것을 목적으로 한다.The present invention was invented to solve the problems of the prior art as described above, and is a multi-tone product that can express a soft and sharp texture like natural linen by utilizing cationically dyeable polyester yarn and low melting point polyester yarn. The purpose is to provide an effective linen-like polyester composite yarn.
또한, 본 발명은 멀티 톤 효과를 갖는 린넨라이크 폴리에스테르 복합사를 제조할 수 있는 멀티 톤 효과를 갖는 린넨라이크 폴리에스테르 복합사 제조방법을 제공하는 것을 목적으로 한다.In addition, the purpose of the present invention is to provide a method for producing a linen-like polyester composite yarn with a multi-tone effect, which can produce a linen-like polyester composite yarn with a multi-tone effect.
본 발명은 카티온 가염성 폴리에스테르 태세사(TTD)와 저융점 폴리에스테르 수지를 포함하는 저융점 폴리에스테르사를 가열하면서 가연하여 카티온 가염성 폴리에스테르 태세사와 저융점 폴리에스테르사를 부분융착시켜 형성되는 것을 특징으로 하는 멀티 톤 효과를 갖는 린넨라이크 폴리에스테르 복합사를 제공한다.In the present invention, a low melting point polyester yarn containing a cationically dyeable polyester yarn (TTD) and a low melting point polyester resin is twisted while heating to partially fuse the cationically dyeable polyester yarn and the low melting point polyester yarn. Provided is a linen-like polyester composite yarn with a multi-tone effect, characterized in that it is formed.
또한, 상기 저융점 폴리에스테르 수지는 융점이 150 내지 200℃이거나 또는 연화점이 100 내지 130℃인 것을 특징으로 하는 멀티 톤 효과를 갖는 린넨라이크 폴리에스테르 복합사를 제공한다.In addition, the low melting point polyester resin provides a linen-like polyester composite yarn with a multi-tone effect, characterized in that the melting point is 150 to 200 ° C. or the softening point is 100 to 130 ° C.
또한, 상기 가열은 저융점 폴리에스테르 수지의 융점의 -20~+30℃ 범위 또는 연화점의 +30~80℃ 범위의 온도로 가열하는 것을 특징으로 하는 멀티 톤 효과를 갖는 린넨라이크 폴리에스테르 복합사를 제공한다.In addition, the heating is a linen-like polyester composite yarn with a multi-tone effect, characterized in that it is heated to a temperature in the range of -20 to +30 ℃ of the melting point of the low melting point polyester resin or +30 to 80 ℃ of the softening point. to provide.
또한, 상기 카티온 가염성 폴리에스테르 태세사(TTD)와 저융점 폴리에스테르사는 중량비 7:3~9:1로 형성되는 것을 특징으로 하는 멀티 톤 효과를 갖는 린넨라이크 폴리에스테르 복합사를 제공한다.In addition, a linen-like polyester composite yarn with a multi-tone effect is provided, wherein the cationically dyeable polyester tethered yarn (TTD) and the low-melting point polyester yarn are formed at a weight ratio of 7:3 to 9:1.
또한, 본 발명은 카티온 가염성 폴리에스테르 태세사(TTD)와 저융점 폴리에스테르 수지를 포함하는 저융점 폴리에스테르사를 공급하는 사공급단계; 및, 상기 카티온 가염성 폴리에스테르 태세사(TTD)와 저융점 폴리에스테르사를 가열하면서 가연하여 카티온 가염성 폴리에스테르 태세사와 저융점 폴리에스테르사를 부분융착시키는 가연융착단계를 포함하는 것을 특징으로 하는 멀티 톤 효과를 갖는 린넨라이크 폴리에스테르 복합사 제조방법을 제공한다.In addition, the present invention includes a yarn supply step of supplying a low-melting point polyester yarn containing a cationically dyeable polyester tethered yarn (TTD) and a low-melting point polyester resin; And, a blow-twisting step of partially fusing the cationically dyeable polyester tethered yarn (TTD) and the low-melting point polyester yarn by heating the cationically dyeable polyester tethered yarn (TTD) and the low-melting point polyester yarn. Provides a method for manufacturing linen-like polyester composite yarn with a multi-tone effect.
상기와 같은 본 발명에 따른 멀티 톤 효과를 갖는 린넨라이크 폴리에스테르 복합사는 카티온 가염성 폴리에스테르 태세사와 저융점 폴리에스테르사를 가연하면서 부분융착하여 천연 린넨과 같이 부드러우면서 샤리한 질감을 나타내는 효과가 있다.The linen-like polyester composite yarn with the multi-tone effect according to the present invention as described above has the effect of showing a soft and sharp texture like natural linen by partially fusing cationically dyeable polyester yarn and low-melting point polyester yarn while twisting. There is.
또한, 본 발명은 카티온 가염성 폴리에스테르 태세사가 함유되어 표면 굵기 차이로 인한 투톤 효과에 더불어 카티온 가염성으로 인해 쓰리톤 이상의 멀티 톤 효과로 천연 린넨과 같은 외관을 갖는 효과가 있다.In addition, the present invention contains cationically dyeable polyester fiber yarn, which has the effect of having a natural linen-like appearance through a two-tone effect due to a difference in surface thickness and a multi-tone effect of three or more tones due to cationic dyeability.
도 1은 본 발명에 따른 멀티 톤 효과를 갖는 린넨라이크 폴리에스테르 복합사의 공정도를 나타낸 도면이다.Figure 1 is a diagram showing a process diagram of a linen-like polyester composite yarn with a multi-tone effect according to the present invention.
이하 본 발명에 첨부된 도면을 참조하여 본 발명의 바람직한 일실시예를 상세히 설명하기로 한다. 우선, 도면들 중, 동일한 구성요소 또는 부품들은 가능한 동일한 참조부호를 나타내고 있음에 유의하여야 한다. 본 발명을 설명함에 있어, 관련된 공지기능 혹은 구성에 대한 구체적인 설명은 본 발명의 요지를 모호하지 않게 하기 위하여 생략한다.Hereinafter, a preferred embodiment of the present invention will be described in detail with reference to the drawings attached to the present invention. First of all, it should be noted that among the drawings, identical components or parts are indicated by the same reference numerals whenever possible. In describing the present invention, detailed descriptions of related well-known functions or configurations are omitted in order to not obscure the gist of the present invention.
본 명세서에서 사용되는 정도의 용어 '약', '실질적으로' 등은 언급된 의미에 고유한 제조 및 물질 허용오차가 제시될 때 그 수치에서 또는 그 수치에 근접한 의미로 사용되고, 본 발명의 이해를 돕기 위해 정확하거나 절대적인 수치가 언급된 개시 내용을 비양심적인 침해자가 부당하게 이용하는 것을 방지하기 위해 사용된다.As used herein, the terms 'about', 'substantially', etc. are used to mean at or close to the numerical value when manufacturing and material tolerances inherent in the stated meaning are presented, and are used to enhance the understanding of the present invention. Precise or absolute figures are used to assist in preventing unscrupulous infringers from taking unfair advantage of stated disclosures.
본 발명은 카티온 가염성 폴리에스테르 태세사(TTD)와 저융점 폴리에스테르 수지를 포함하는 저융점 폴리에스테르사로 형성되는 멀티 톤 효과를 갖는 린넨라이크 폴리에스테르 복합사에 관한 것이다.The present invention relates to a linen-like polyester composite yarn with a multi-tone effect formed from a cationically dyeable polyester tethered yarn (TTD) and a low-melting point polyester yarn containing a low-melting point polyester resin.
본 발명에 따른 멀티 톤 효과를 갖는 린넨라이크 폴리에스테르 복합사는 도 1에서와 같이 사공급단계, 가연융착단계를 포함하여 제조된다.The linen-like polyester composite yarn with a multi-tone effect according to the present invention is manufactured including a yarn supply step and a false twist fusion step as shown in FIG. 1.
상기 사공급단계는 카티온 가염성 폴리에스테르 태세사(TTD)와 저융점 폴리에스테르사를 공급하는 단계이다.The yarn supply step is a step of supplying cationically dyeable polyester yarn (TTD) and low melting point polyester yarn.
상기 폴리에스테르 태세사(TTD)는 원사의 굵고(Thick) 가는 부분(Thin)이 반복되어 표면 요철감 및 드라이한 터치를 발현하는 실로 방적사나 슬럽사와 같은 질감을 나타내며, 투톤 효과를 부여하는 특징이 있다.The polyester tethered yarn (TTD) is a yarn in which the thick and thin parts of the yarn are repeated to create surface irregularities and a dry touch, and has a texture similar to spun yarn or slub yarn, and has the characteristic of giving a two-tone effect. there is.
상기 카티온 가염성 폴리에스테르 태세사는 카티온 가염성 폴리에스테르 수지로 제조되는 실로 상기 카티온 가염성 폴리에스테르 수지는 현재 카티온 가염성 위해 제조되는 폴리에스테르 수지는 어느 것이나 사용할 수 있을 것이다.The cationically dyeable polyester thread is manufactured from a cationically dyeable polyester resin, and the cationically dyeable polyester resin may be any polyester resin currently manufactured for cationically dyeable.
상기 카티온 가염성 폴리에스테르 수지의 일례로 테레프탈산인 산성분과 에틸렌글리콜인 디올성분 및 5-설포이소프탈산나트륨을 공중합시켜 형성되는 카티온 가염성 폴리에스테르 수지를 사용할 수 있다.An example of the cationically saltable polyester resin may be a cationically saltable polyester resin formed by copolymerizing an acid component of terephthalic acid, a diol component of ethylene glycol, and sodium 5-sulfoisophthalate.
상기 저융점 폴리에스테르사는 저융점 폴리에스테르 수지를 포함하는 실로 상기 저융점 폴리에스테르 수지는 통상적인 폴리에틸렌테레프탈레이트 수지의 융점인 약 250~270℃ 보다 낮은 융점을 갖는 폴리에스테르 수지이다.The low melting point polyester yarn is a yarn containing a low melting point polyester resin. The low melting point polyester resin is a polyester resin having a melting point lower than the melting point of a typical polyethylene terephthalate resin, which is about 250 to 270°C.
상기 저융점 폴리에스테르 수지는 융점이 150 내지 200℃이거나 또는 연화점이 100 내지 130℃인 것이 바람직한 것으로 상기 온도 범위를 벗어날 경우 공정성 및 복합사의 물성이 저하될 수 있다.The low-melting point polyester resin preferably has a melting point of 150 to 200°C or a softening point of 100 to 130°C. If the temperature exceeds the above range, processability and physical properties of the composite yarn may deteriorate.
상기 저융점 폴리에스테르사는 시스-코어형으로 제조되는 것이 바람직한 것으로 코어부는 융점이 250~270℃의 폴리에틸렌테레프탈레이트 수지를 포함하는 통상적인 폴리에스테르 수지로 형성되며, 시스부는 상기에서 설명된 저융점 폴리에스테르 수지로 형성될 수 있을 것이다.The low melting point polyester yarn is preferably manufactured in a cis-core type. The core part is made of a typical polyester resin containing a polyethylene terephthalate resin with a melting point of 250 to 270°C, and the cis part is made of the low melting point polyester yarn described above. It may be formed from an ester resin.
상기 저융점 폴리에스테르 수지는 산성분의 테레프탈산(TPA)과 디올성분의 에틸렌글로콜로 형성되는 폴리에스테르 수지 제조시에 산성분으로 이소프탈산(IPA)을 첨가하여 공중합하거나, 또는 디올성분으로 2-메틸-1,3-프로판디올(MPO)을 첨가하여 공중합하여 제조할 수 있는 것으로 본 발명에서는 융점 또는 연화점이 상기 범위인 저융점 폴리에스테르 수지는 어느 것이나 사용할 수 있을 것이다.The low melting point polyester resin is copolymerized by adding isophthalic acid (IPA) as an acidic component during the production of a polyester resin formed of terephthalic acid (TPA) as an acidic component and ethylene glycol as a diol component, or as a diol component with 2- It can be manufactured by copolymerization with the addition of methyl-1,3-propanediol (MPO), and any low melting point polyester resin with a melting point or softening point within the above range can be used in the present invention.
상기 가연융착단계는 상기 카티온 가염성 폴리에스테르 태세사(TTD)와 저융점 폴리에스테르사를 가열하면서 가연하여 카티온 가염성 폴리에스테르 태세사와 저융점 폴리에스테르사를 부분융착시키는 단계이다.The false melting step is a step of partially fusing the cationically dyeable polyester yarn (TTD) and the low melting point polyester yarn by blow twisting the cationically dyeable polyester yarn (TTD) and the low melting point polyester yarn while heating.
상기 가연융착단계에서 상기 가열은 저융점 폴리에스테르사를 형성하는 저융점 폴리에스테르 수지의 융점 또는 연화점에 따라 조절되어야 하는 것으로 가열 시의 온도가 너무 높으면 융착부과 과다하게 발생하거나, 저융점 폴리에스테르사의 형상이 유지되지 못하여 린넨라이크 폴리에스테르 복합사의 외관 및 촉감이 저하될 수 있으며, 온도가 너무 낮으면 용융이 약하여 융착부 형성이 원활하지 않을 수 있다.In the false melting step, the heating must be adjusted according to the melting point or softening point of the low melting point polyester resin forming the low melting point polyester yarn. If the temperature during heating is too high, excessive fusion may occur or the low melting point polyester yarn may be damaged. If the shape is not maintained, the appearance and feel of the linen-like polyester composite yarn may deteriorate, and if the temperature is too low, melting may be weak and the formation of the fusion zone may not be smooth.
상기 가열은 저융점 폴리에스테르 수지의 융점의 -10~+20 범위 또는 연화점의 +30~50℃ 범위의 온도에서 가열하는 것이 바람직할 것이다.The heating may be preferably performed at a temperature in the range of -10 to +20°C of the melting point of the low melting point polyester resin or in the range of +30 to 50°C of the softening point.
상기 카티온 가염성 폴리에스테르 태세사(TTD)와 저융점 폴리에스테르사는 중량비 7:3~9:1로 형성되는 것이 바람직한 것으로 태세사의 함량이 70중량% 미만이면 멀티 톤 효과 및 외관이 린넨과 같은 감성이 사라질 수 있으며, 태세사의 함량이 90중량%를 초과하면 저융점 폴리에스테르사의 함량이 너무 낮아져 린넨 특유의 촉감이 발현되지 못할 수 있다.The cationically dyeable polyester yarn (TTD) and the low melting point polyester yarn are preferably formed in a weight ratio of 7:3 to 9:1. If the content of the cationic dyeable polyester yarn (TTD) is less than 70% by weight, the multi-tone effect and appearance are similar to linen. Sensitivity may disappear, and if the content of fine yarn exceeds 90% by weight, the content of low-melting polyester yarn may become too low and the unique feel of linen may not be expressed.
상기와 같이 카티온 가염성 폴리에스테르 태세사(TTD)와 저융점 폴리에스테르사를 활용하여 사공급단계, 가연융착단계를 포함하여 제조되는 멀티 톤 효과를 갖는 린넨라이크 폴리에스테르 복합사는 카티온 가염성 폴리에스테르 태세사와 저융점 폴리에스테르사를 가연하면서 부분융착하여 천연 린넨과 같이 부드러우면서 샤리한 질감을 나타내며, 카티온 가염성 폴리에스테르 태세사의 표면 굵기 차이 및 카티온 가염성으로 인한 멀티 톤 효과로 천연 린넨과 같은 외관을 갖다.As described above, linen-like polyester composite yarn with a multi-tone effect, which is manufactured using cationically dyeable polyester yarn (TTD) and low melting point polyester yarn, including the yarn supply stage and the false fusion stage, is cationically dyeable. Polyester tethered yarn and low-melting point polyester yarn are partially fused while twisting to create a soft and shiny texture like natural linen, and the multi-tone effect due to the difference in surface thickness of cationic dyeable polyester tethered yarn and cationic dyeability. Has the same appearance as natural linen.
이하 본 발명에 따른 멀티 톤 효과를 갖는 린넨라이크 폴리에스테르 복합사를 제조하기 위한 방법의 실시예를 나타내지만, 본 발명이 실시예로 한정되는 것은 아니다.Below, an example of a method for producing a linen-like polyester composite yarn with a multi-tone effect according to the present invention is shown, but the present invention is not limited to the example.
실시예Example 1 내지 4 1 to 4
카티온 가염성 폴리에스테르 태세사(TTD)와 융점 160℃의 저융점 폴리에스테르 수지를 포함하는 저융점 폴리에스테르사(LM PET)를 공급하고, 꼬임수 800T/M으로 가연하면서 가열하여 부분융착시키는 가연융착단계를 실시하여 본 발명에 따른 멀티 톤 효과를 갖는 린넨라이크 폴리에스테르 복합사를 제조하였다.We supply low melting point polyester yarn (LM PET) containing cationically dyeable polyester tethered yarn (TTD) and low melting point polyester resin with a melting point of 160℃, and partially fuse them by heating and twisting at a twist number of 800T/M. A false fusion step was performed to produce a linen-like polyester composite yarn with a multi-tone effect according to the present invention.
각 실시예에 따른 카티온 가염성 폴리에스테르 태세사(TTD)와 저융점 폴리에스테르사의 혼합비 및 가열 온도를 표 1에 나타내었다.The mixing ratio and heating temperature of cationically dyeable polyester tethered yarn (TTD) and low melting point polyester yarn according to each example are shown in Table 1.
비교예 1Comparative Example 1
실시예 3과 동일하게 제조하였으나, 저배향 폴리에스테르 원사만을 사용하여 폴리에스테르 복합사를 제조하였다.Polyester composite yarn was manufactured in the same manner as in Example 3, but using only low-orientation polyester yarn.
비교예 2Comparative Example 2
실시예 3과 동일하게 제조하였으나, 폴리에스테르 태세사(TTD)만을 사용하여 폴리에스테르 복합사를 제조하였다.Polyester composite yarn was manufactured in the same manner as in Example 3, but only using polyester tethered yarn (TTD).
상기에서 제조된 실시예 및 비교예에서 제조된 폴리에스테르 복합사의 사가공 공정성을 평가하였으며, 폴리에스테르 복합사를 제직하여 평직으로 제조하여 제직공정성, 원단의 외관, 촉감, 드레이프트성을 평가하여 표 1에 나타내었다.The yarn processing fairness of the polyester composite yarn prepared in the Examples and Comparative Examples prepared above was evaluated, and the polyester composite yarn was woven into a plain weave to evaluate the weaving fairness, appearance, feel, and drapability of the fabric, and Table 1 shown in
상기 사가공성, 제직공정성, 원단의 외관, 촉감, 드레이프트성은 전문가 5인이 평가하여 매우우수(◎), 우수(○), 보통(△), 불량(X)으로 평가하였다.The yarn processing, weaving process, appearance, feel, and drapability of the fabric were evaluated by five experts and were rated as excellent (◎), excellent (○), average (△), and poor (X).
표 1에서와 같이 본 발명의 멀티 톤 효과를 갖는 린넨라이크 폴리에스테르 복합사인 실시예 1,2는 사가공성, 제직공정성, 원단의 외관, 촉감, 드레이프트성에서 모두 우수한 것으로 평가되었으나, 실시예 4와 같이 저융점 폴리에스테르사의 함량이 높아질 경우 드레이프트성이 저하될 수 있는 것으로 저융점 폴리에스테르사는 40중량% 미만으로 함유되는 것이 바람직할 것이다.As shown in Table 1, Examples 1 and 2, which are linen-like polyester composite yarns with a multi-tone effect of the present invention, were evaluated as excellent in all yarn processing, weaving processability, appearance, touch, and drapability of the fabric, but Example 4 and Likewise, if the content of low-melting polyester yarn increases, the drapability may decrease, so it is preferable that the low-melting point polyester yarn is contained in less than 40% by weight.
또한, 가열 시에 온도가 너무 높으면 사가공 및 제직 공정성이 저하될 수 있으며, 드레이프트성이 저하될 수 있는 것으로 실시예 1,2와 같이 저융점 폴리에스테르사를 형성하는 저융점 폴리에스테르 수지의 융점 -20~+30℃ 범위에서 가열하는 것이 바람직할 것이다.In addition, if the temperature is too high during heating, the yarn processing and weaving process may be reduced, and the drapability may be reduced. The melting point of the low melting point polyester resin forming the low melting point polyester yarn as in Examples 1 and 2 Heating in the range of -20 to +30°C would be desirable.
또한, 비교예 1,2와 같이 저배향 폴리에스테르 원사 또는 폴리에스테르 태세사만으로 복합사를 형성할 경우 촉감 및 드레이프트성이 저하되는 것을 알 수 있다.In addition, as in Comparative Examples 1 and 2, it can be seen that when a composite yarn is formed only with low-orientation polyester yarn or polyester tack yarn, the feel and drapability are deteriorated.
Claims (5)
It is formed by heating and twisting a low melting point polyester yarn containing a cationically dyeable polyester yarn (TTD) and a low melting point polyester resin, and partially fusing the cationically dyeable polyester yarn and the low melting point polyester yarn. Linen-like polyester composite yarn with a characteristic multi-tone effect.
상기 저융점 폴리에스테르 수지는 융점이 150 내지 200℃이거나 또는 연화점이 100 내지 130℃인 것을 특징으로 하는 멀티 톤 효과를 갖는 린넨라이크 폴리에스테르 복합사.
According to paragraph 1,
The low melting point polyester resin is a linen-like polyester composite yarn with a multi-tone effect, characterized in that the melting point is 150 to 200 ℃ or the softening point is 100 to 130 ℃.
상기 가열은 저융점 폴리에스테르 수지의 융점의 -20~+30℃ 범위 또는 연화점의 +30~80℃ 범위의 온도로 가열하는 것을 특징으로 하는 멀티 톤 효과를 갖는 린넨라이크 폴리에스테르 복합사.
According to paragraph 1,
A linen-like polyester composite yarn with a multi-tone effect, characterized in that the heating is performed at a temperature in the range of -20 to +30 ℃ of the melting point of the low melting point polyester resin or to a temperature in the range of +30 to 80 ℃ of the softening point.
상기 카티온 가염성 폴리에스테르 태세사(TTD)와 저융점 폴리에스테르사는 중량비 7:3~9:1로 형성되는 것을 특징으로 하는 멀티 톤 효과를 갖는 린넨라이크 폴리에스테르 복합사.
According to paragraph 1,
A linen-like polyester composite yarn with a multi-tone effect, characterized in that the cationically dyeable polyester tethered yarn (TTD) and the low melting point polyester yarn are formed at a weight ratio of 7:3 to 9:1.
상기 카티온 가염성 폴리에스테르 태세사(TTD)와 저융점 폴리에스테르사를 가열하면서 가연하여 카티온 가염성 폴리에스테르 태세사와 저융점 폴리에스테르사를 부분융착시키는 가연융착단계를 포함하는 것을 특징으로 하는 멀티 톤 효과를 갖는 린넨라이크 폴리에스테르 복합사 제조방법.A yarn supply step of supplying low-melting point polyester yarn containing cationically dyeable polyester tethered yarn (TTD) and low-melting point polyester resin; and,
A false twist fusion step of partially fusing the cationically dyeable polyester yarn (TTD) and the low melting point polyester yarn by heating the cationically dyeable polyester yarn (TTD) and the low melting point polyester yarn. Method for manufacturing linen-like polyester composite yarn with multi-tone effect.
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