KR20120138265A - Sterilzation treatment apparatus for water of aquarium for living fish - Google Patents

Sterilzation treatment apparatus for water of aquarium for living fish Download PDF

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Publication number
KR20120138265A
KR20120138265A KR1020110057607A KR20110057607A KR20120138265A KR 20120138265 A KR20120138265 A KR 20120138265A KR 1020110057607 A KR1020110057607 A KR 1020110057607A KR 20110057607 A KR20110057607 A KR 20110057607A KR 20120138265 A KR20120138265 A KR 20120138265A
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South Korea
Prior art keywords
seawater
alloy
live fish
metal
sterilization
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KR1020110057607A
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Korean (ko)
Inventor
한신호
남문현
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한국산업기술대학교산학협력단
남문현
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Priority to KR1020110057607A priority Critical patent/KR20120138265A/en
Publication of KR20120138265A publication Critical patent/KR20120138265A/en

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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01KANIMAL HUSBANDRY; AVICULTURE; APICULTURE; PISCICULTURE; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
    • A01K63/00Receptacles for live fish, e.g. aquaria; Terraria
    • A01K63/04Arrangements for treating water specially adapted to receptacles for live fish
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01KANIMAL HUSBANDRY; AVICULTURE; APICULTURE; PISCICULTURE; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
    • A01K63/00Receptacles for live fish, e.g. aquaria; Terraria
    • A01K63/003Aquaria; Terraria
    • A01K63/006Accessories for aquaria or terraria
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/42Treatment of water, waste water, or sewage by ion-exchange

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  • Life Sciences & Earth Sciences (AREA)
  • Environmental Sciences (AREA)
  • Marine Sciences & Fisheries (AREA)
  • Animal Husbandry (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Farming Of Fish And Shellfish (AREA)

Abstract

PURPOSE: A sterilization device for a live fish aquarium is provided to prevent a scale sticking prevention effect and to sterilize fungus, moss, and bacteria. CONSTITUTION: A sterilization device for a live fish aquarium comprises a water tub(10), a pump(20), a recycle pipe(30), an alloy filter unit(40), and a metal ion filter unit(50). The water tub stores seawater. The pump inhales seawater so that the seawater inside the tank can circulate. One side of the recycle pipe is combined with the pump and the other side thereof is connected to one side of the water tub to circulate seawater inhaled by the pump. The alloy filter unit sterilizes seawater by redox reaction of a metal alloy unit. The metal ion filter unit removes metal ions generated from the alloy filter unit.

Description

Sterilizer for Live Fish Tank {STERILZATION TREATMENT APPARATUS FOR WATER OF AQUARIUM FOR LIVING FISH}

The present invention relates to an apparatus for sterilizing a live fish tank, and more particularly, to an apparatus for sterilizing a live fish tank using a redox principle to remove various algae, bacteria, and bacteria that may occur in the live fish tank. It is about.

In general, seafood is rich in nutrients such as DHA and EPA, but since seafood and sea water contain bacteria, microorganisms, some fish species and pathogens such as cholera, it is identified as one of the main causes of marine ecosystem destruction and food poisoning. Therefore, bacterial food poisoning accidents are frequently generated due to unsanitary treatment in fish sashimi using coastal seawater.

There are various sterilization methods in consideration of the use and condition of water. Among them, sterilization method by the chemicals used at home is generally widely used due to low cost and certainty and rapid effect, but serious side effects occur due to the harmfulness of the drug itself There is a problem.

Another method is known as ozone sterilization, ultraviolet sterilization and chlorine sterilization, but these methods have serious problems in terms of installation cost, disinfection effect and side effects.

In other words, the ozone sterilization method and the ultraviolet sterilization method do not leave any residual seawater with sterilization effect, so there is no safety against contamination after sterilization and the treatment cost is high. In addition, chlorination sterilizes the taste and smell, and chemical reactions between the organism and chlorine in water produce trihalomethane, which is harmful to the human body.

In addition, in this reality, the alternative method is to lower the water temperature in the aquarium to prevent bacterial growth or to frequently change the aquarium's seawater, but even in the summer when the temperature is high, it is not enough precautions. Seawater can also be contaminated, so sterilization of aquariums, tanks, etc. is essential.

That is, in tanks, it is used while continuously circulating a certain amount of seawater, so it must be sterilized for circulating seawater. If sterilization is not done for circulating seawater, moss, algae, fungus, etc. are generated, odors are generated, and dissolved oxygen There is also a problem in that the environment is reduced to the inhabitants.

The present invention is to solve the above-mentioned problems of the prior art, by applying a sterilization system using the redox principle of the metal to the water tank sterilization effect of various fungi, sterilization effect of algae, moss and mold, prevention of scale adhesion It is an object of the present invention to provide a sterilization apparatus of a live fish tank that provides an effect.

Another object of the present invention is to apply a sterilization system using the redox principle of the metal to the tank to increase the replacement cycle of seawater in the tank can reduce the cost and labor associated with the replacement of live fish tanks The purpose is to provide.

Still another object of the present invention is to provide a sterilization apparatus for a live fish tank by ionization according to oxidation of a metal alloy made of copper (Cu) and zinc (Zn) in using the redox principle of the metal alloy. The purpose is.

According to the present invention, the object and the tank for storing the seawater therein; A pump for sucking the sea water so that the sea water in the water tank circulates; A circulation pipe having one side coupled to the pump and the other side connected to one side of the tank to circulate the seawater sucked by the pump; And a metal alloy part composed of a plurality of metals having different standard reduction potentials, and disposing the metal alloy part to contact the sea water transported through the circulation pipe to sterilize the sea water by redox reaction of the metal alloy part. An alloy filter unit; It is achieved by a sterilization treatment apparatus of a live fish tank comprising a metal ion filter unit for removing the metal ions generated in the alloy filter unit.

Here, the metal alloy portion is characterized in that the hollow is formed to widen the contact area with the water transported through the circulation pipe.

In addition, the metal ion filter unit is characterized in that consisting of a chelate resin.

The metal alloy portion is formed of an alloy containing copper (Cu) and zinc (Zn).

Sterilization apparatus of a live fish tank according to the present invention having the configuration as described above sterilizes various fungi, algae, moss and mold of the tank, aquarium, etc., using the redox principle, and prevents adhesion of scale in the circulation pipe do.

In other words, by using the sterilization apparatus of the live fish tank according to the present invention in the coastal sashimi and inland fat sashimi using live fish tank can reconsider the sanitary credibility of sashimi can increase the income of fishermen and improve the public health.

In addition, it is possible to increase the replacement cycle of seawater in the tank, thereby reducing the cost and labor associated with seawater replacement.

In other words, it is possible to reduce the economic burden due to the burden of seawater purchase and the reduction of logistics costs for transporting supplemental water in the case of inland water, and labor for water quality maintenance.

1 is a conceptual diagram of a sterilization apparatus of a live fish tank according to the present invention,
Figure 2 is a view showing the alloy filter portion of the live fish tank sterilization treatment apparatus according to the present invention,
Figure 3 is a view showing a second embodiment of the alloy filter portion of the live fish tank sterilization apparatus according to the present invention,
4 is a view showing another form of the metal alloy portion according to the second embodiment of the alloy filter portion of FIG.
5 is a view showing the reaction of the metal ions discharged from the alloy filter unit of the sterilization apparatus of a live fish tank according to the present invention.

Hereinafter, with reference to the accompanying drawings will be described in detail embodiments according to the present invention. Here, in describing the embodiments according to the present invention, the same reference numerals are used for the same components, and description thereof may be omitted as necessary.

Referring to Figure 1, the live fish tank sterilization apparatus according to the present invention includes a water tank 10, a pump 20, a circulation pipe 30, an alloy filter unit 40 and a metal ion filter unit 50 do.

Here, the tank 10 for storing the sea water therein is mainly used in the live fish tank using sea water, but is not necessarily limited thereto, and may be applied to cooling towers, fish farms, household water, ponds and other live fish tanks. Of course.

The pump 20 sucks the seawater in the water tank 10 so that the seawater in the water tank 10 is circulated and is transported through the circulation pipe 30.

The circulation pipe 30 is coupled to one side of the pump 20 and the other side is connected to one side of the water tank 10 and serves as a passage through which seawater in the water tank 10 sucked by the pump 20 is circulated.

First Embodiment

Referring to FIG. 2, the alloy filter part 40 includes a metal alloy part 41, a coupling part 42, a stopper part 43, and an O ring 46.

Here, the coupling portion 42 is formed so that the alloy filter portion 40 is detachably coupled to the circulation pipe 30, along the circulation pipe 30 at the time of coupling the circulation pipe 30 and the coupling portion 42 The O-ring 46 may be disposed between the stopper 43 and the circulation pipe 30 to prevent the seawater from being transferred to the outside.

As shown in FIG. 2, the metal alloy portion 41 is disposed to protrude into the circulation pipe 30 so that metal ions are released to seawater transferred through the circulation pipe.

Here, the alloy filter 40 is to use a sterilization mechanism using the redox principle.

In other words, Redox is a compound word of reduction and oxidation and it uses the redox principle that occurs naturally between metal alloy and water.

In particular, the metal alloy portion 41 of the alloy filter portion 40 may be zinc (Zinc) and copper (Copper) alloy. That is, when zinc and copper alloys with different ionization tendency come into contact with contaminated seawater, each metal has a different potential due to the inherent properties of the metal. At this time, oxidation and reduction occur naturally due to the potential difference, and there is an effect of sterilizing bacteria by metal ions of zinc and copper generated in this process.

Here, copper (Cu) is an essential nutrient for mammals including humans, but is mostly ingested from food, but in other organisms such as microorganisms, the demand is very low at 1 to 10 levels. Will be removed.

Therefore, when the redox reaction energy is increased, the sterilization effect of various fungi, the sterilization effect of algae, moss and mold, and the effect of preventing the adhesion of scales will be described in detail with reference to FIG. 5.

The principle of sterilization by redox reaction is as follows.

Cu / Zn 0- > Cu +2 / Zn +2 + 2e - Reduction

H 2 O + 2e - -> OH - + .H oxidation

H 2 O + .H-> .OH + H 2

Therefore, the sterilization treatment apparatus 1 of the live fish tank according to the present invention has a sterilizing action due to hemolysis due to the electronic ion exchange with the cells of the microorganism and an electrochemical action by the redox reaction.

That is, in the process of redox reaction, the metal emits electrons (e-) through oxidation. First, the electrons act on cells of bacteria such as bacteria to hemolyze the cell wall to kill the bacteria. Secondly, the released electrons interact with seawater to produce hydrogen radicals (.H), and hydrogen radicals react with seawater to produce hydroxyl radicals (.OH). It reaches about 800 times (Cl). Third, a hydroxyl group (OH-) is produced in the reaction process, and the pH increases due to the hydroxyl group. When the pH is 9.5 or more, it becomes an environmental condition that various bacteria are difficult to inhabit, so that effective sterilization is possible because it makes strong sterilization and the culture environment of bacteria difficult during the redox reaction.

In addition, one metal alloy portion 41 is disposed to protrude into the circulation pipe 30, and the other metal alloy portion 41 is arranged side by side alternately, to the seawater to be transferred through the circulation pipe 30 The ionization rate of metal ion can be raised.

In addition, the coupling part 42 of the alloy filter part 40 is inserted into the coupling hole 31 formed in the circulation pipe 30 to be coupled to the circulation pipe 30. That is, a thread is formed on the outer circumferential surface of the coupling portion 42 and the inner surface of the coupling hole 31 to detachably screw for maintenance, repair and replacement.

On the other hand, the sterilization treatment apparatus 1 of the live fish tank according to the present invention has an effect of preventing the scale by the redox reaction, and looks at the principle of the scale prevention by the redox reaction.

2 (HCO3 -) + Ca 2 + -> CaCO 3 + H 2 O + CO 2

The metal ion is Ca + 2 or Mg + 2 and compete with consequently interfere with the generation and crystal growth of CaCO 3 or MgCO 3. So, to remove the scale-forming material, such as Mg 2 +, Na 2 +, SiO 2 2 +.

The anti-scaling effect is one of the great effects of the redox reaction, and in general, the scale is charged by the circulation pipe 30 for various reasons in the flow of the fluid, and the scale particles such as fine calcium carbonate are attracted to the charge and the circulation pipe ( 30). That is, scale is formed in this process.

However, in the process of redox reaction, charge (e-), which is the nucleus of scale formation, is provided in the solution so that the scale to be attached to the circulating pipe 30 forms crystals in water to coarse particles. By playing a role it essentially prevents the attachment to the circulation pipe (30).

Hereinafter, the correlation between the sterilizing power and the metal ion concentration according to the metal content will be described.

Copper zinc alloys (copper: zinc ratio = 10: 0, 9: 1, 8: 2, 7: 3, 6: 4) prepared to test the sterilization power and metal ion concentration according to the metal content are as wide as possible 5 g of the copper / zinc alloy sample thus processed was placed in 1 L of seawater and tested for pH, general bacteria, copper and zinc ion concentration at 1, 2, 4, and 8 days with stirring. .

The experimental results are shown in Table 1 below.

Figure pat00001

TABLE 1 Changes in pH, general bacterial counts, and copper and zinc ion concentrations over different periods of treatment of seawater with copper / zinc alloys.

According to this result, the bactericidal power of the bacteria was the most excellent bactericidal power of the alloy with a weight ratio of copper and zinc 7: 3. That is, according to the experimental results shown in Table 1 below, the alloy filter portion 40 of the sterilization apparatus 1 of the live fish tank according to the present invention is a metal alloy formed by utilizing an alloy containing copper: zinc 7: 3. It is preferable to include the portion 41 in view of effectiveness.

However, the concentration of metal ions may exceed 1 mg / L on a drinking water basis. In this case, metal ions should be removed.

At this time, in order to remove the copper and zinc ions eluted from the copper / zinc metal alloy remaining in the sea water, the sterilization apparatus 1 of the live fish tank according to the present invention includes a metal ion filter unit (50).

That is, since the metal ions in the sea water may act as a poison, the metal ions can be safely removed using the metal ion filter unit 50.

Here, the ion exchange resin can be used as the metal ion filter unit 50.

In this case, the ion exchange resin used may catch salts of seawater when using general ion exchange resins, and may reduce salinity of seawater. Therefore, chelate resins that selectively hold copper and zinc and pass salts of seawater are used. It is preferable.

Therefore, ions remaining as stable residual fungicide in water are filtered by the metal ion filter unit 50.

In order to comparatively measure the sterilizing power of the sterilization treatment apparatus 1 of the live fish tank according to the present invention, the alloy filter portion 40 and the metal ion filter portion 50 having a copper / zinc ratio of 7: 3 are applied to the general seawater. After inoculating E. coli, bacteriological experiments were performed over 1 day, 2 days, 4 days and 8 days.

Figure pat00002

<Table 2> Bacterial Determination of Metal Alloy Sterilization System and General Seawater for Seawater E. Coli.

Referring to Table 2, E. coli was not detected due to the sterilizing action of the sterilization apparatus 1 of the live fish tank according to the present invention.

On the contrary, when only the sea water was circulated, the number of bacteria was gradually reduced, but it was judged that it was killed by lack of nutrients.

Therefore, it can be seen that the sterilization treatment apparatus 1 of the live fish tank according to the present invention has a very effective sterilization effect when looking at the results of Table 2.

Second Embodiment

Hereinafter, a second embodiment of the alloy filter part 40a of the present invention will be described in detail with reference to the accompanying drawings. In addition, in describing the second embodiment of the alloy filter part 40a of the present invention, the same reference numerals are used for the same components as those of the first embodiment, and the description thereof may be omitted.

Figure 3 is a view showing a second embodiment of the alloy filter portion 40a of the sterilization apparatus of a live fish tank according to the present invention, Figure 4 is a metal according to a second embodiment of the alloy filter portion 40a of FIG. Another figure of the alloy part 41a is shown.

In the second embodiment, a hollow is formed inside the metal alloy portion 41a in order to widen the contact area with the seawater transferred through the circulation pipe 30 and to smoothly transport the seawater.

3 to 4, the metal alloy portion 41a has a hollow 47 formed therein so that the seawater conveyed through the circulation pipe 30 can be easily transported, and through the circulation pipe 30. The formation of metal ions is facilitated by increasing the contact area with the seawater to be transported.

Here, although the hollow is formed inside the metal alloy portion 41a as an example, the present invention is not limited thereto, and the metal alloy portion 41a may be widened so as to widen the contact area with the seawater transferred through the circulation pipe 30. Of course, the internal shape of the can be formed in a honeycomb shape and the like.

In addition, as shown in FIGS. 3 to 4, a thread is formed on the outer circumferential surface of the metal alloy portion 41a and the inner circumferential surface of the circulation pipe 30 to detachably screw for maintenance, repair, and replacement.

Sterilization apparatus 1 of the live fish tank according to the present invention may further include a filtration system (60).

Here, the filtration system 60 removes large particles of foreign matter such as excretion of fish in the tank, and is preferably disposed in the circulation pipe 30 between the pump 20 and the alloy filter unit 40. .

In more detail, the sterilization apparatus 1 of a live fish tank according to the present invention may be mainly used in a live fish tank.

Live fish tanks can be operated for a long time without discharging waste water or replenishing new water, unlike fish farms in fish farms where untreated animal waste and fish excretion seawater are dissolved, and live fish tanks do not feed live fish. Pollution load is smaller than in fish farms. Therefore, in the case of live fish tanks, a small and simple filtration system 60 that handles low pollutant loads can be used.

However, as described above, since the sterilization apparatus 1 of the live fish tank according to the present invention can be used in fish farms and the like, in this case, a filtration system capable of filtering the unreduced feed waste and the excretion of the fish ( 60) is used.

While the invention has been shown and described with reference to certain preferred embodiments thereof, it is to be understood that the invention is not limited to the disclosed embodiments. Those skilled in the art will appreciate that various modifications, additions and substitutions are possible, without departing from the scope of the appended claims, The genius will be so self-evident. Accordingly, the true scope of the present invention should be determined by the technical idea of the appended claims.

1: Sterilization apparatus of live fish tank 10: Tank
20: pump 30: circulation pipe
40: alloy filter portion 50: metal ion filter portion
60: filtration system

Claims (4)

A tank for storing seawater therein;
A pump for sucking the sea water so that the sea water in the water tank circulates;
A circulation pipe having one side coupled to the pump and the other side connected to one side of the tank to circulate the seawater sucked by the pump;
And a metal alloy part composed of a plurality of metals having different standard reduction potentials, and disposing the metal alloy part to contact the sea water transported through the circulation pipe to sterilize the sea water by redox reaction of the metal alloy part. An alloy filter unit;
Sterilization treatment apparatus of a live fish tank comprising a metal ion filter to remove the metal ions produced by the alloy filter.
The method of claim 1,
The metal alloy portion is a sterilization treatment apparatus for a live fish tank, characterized in that the hollow is formed to widen the contact area with the water transported through the circulation pipe.
The method according to claim 1 or 2,
The metal ion filter unit of the live fish tank sterilization treatment, characterized in that consisting of a chelating resin.
The method of claim 3,
The metal alloy portion sterilization apparatus of a live fish tank, characterized in that formed of an alloy containing copper (Cu) and zinc (Zn).
KR1020110057607A 2011-06-14 2011-06-14 Sterilzation treatment apparatus for water of aquarium for living fish KR20120138265A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101458177B1 (en) * 2013-06-25 2014-11-04 아산텍 주식회사 Water-treatment system usning alloy catalyst reactor system
CN104686411A (en) * 2015-01-07 2015-06-10 中国水产科学研究院东海水产研究所 Ground-based copper alloy culture pond and usage method
KR20160043238A (en) * 2014-10-10 2016-04-21 주식회사 대창 Direct-coupled seawater purify filter coupled to the seawater supply pipe of inland fish farm water tank
CN109631858A (en) * 2019-02-22 2019-04-16 中国人民解放军海军大连舰艇学院 A kind of portable float-type automatic tide gauge

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101458177B1 (en) * 2013-06-25 2014-11-04 아산텍 주식회사 Water-treatment system usning alloy catalyst reactor system
KR20160043238A (en) * 2014-10-10 2016-04-21 주식회사 대창 Direct-coupled seawater purify filter coupled to the seawater supply pipe of inland fish farm water tank
CN104686411A (en) * 2015-01-07 2015-06-10 中国水产科学研究院东海水产研究所 Ground-based copper alloy culture pond and usage method
CN109631858A (en) * 2019-02-22 2019-04-16 中国人民解放军海军大连舰艇学院 A kind of portable float-type automatic tide gauge

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