KR20000038750A - Synthetic resin product containing shellfish shell powder and method for preparing thereof - Google Patents
Synthetic resin product containing shellfish shell powder and method for preparing thereof Download PDFInfo
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- KR20000038750A KR20000038750A KR1019980053851A KR19980053851A KR20000038750A KR 20000038750 A KR20000038750 A KR 20000038750A KR 1019980053851 A KR1019980053851 A KR 1019980053851A KR 19980053851 A KR19980053851 A KR 19980053851A KR 20000038750 A KR20000038750 A KR 20000038750A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B9/00—Making granules
- B29B9/12—Making granules characterised by structure or composition
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B13/00—Conditioning or physical treatment of the material to be shaped
- B29B13/10—Conditioning or physical treatment of the material to be shaped by grinding, e.g. by triturating; by sieving; by filtering
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B9/00—Making granules
- B29B9/10—Making granules by moulding the material, i.e. treating it in the molten state
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B9/00—Making granules
- B29B9/16—Auxiliary treatment of granules
- B29B2009/168—Removing undesirable residual components, e.g. solvents, unreacted monomers; Degassing
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2023/00—Use of polyalkenes or derivatives thereof as moulding material
- B29K2023/04—Polymers of ethylene
- B29K2023/06—PE, i.e. polyethylene
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2103/00—Use of resin-bonded materials as moulding material
- B29K2103/04—Inorganic materials
- B29K2103/08—Mineral aggregates, e.g. sand, clay or the like
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/0005—Condition, form or state of moulded material or of the material to be shaped containing compounding ingredients
- B29K2105/0011—Biocides
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/712—Containers; Packaging elements or accessories, Packages
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Abstract
Description
본 발명은 합성수지 제품 및 그 제조 방법에 관한 것으로 특히, 합성수지 분말에 패류(貝類)껍질 분말과 은(Ag)이온 무기 항균제를 혼합하여 상기 합성수지 제품에서 원적외선 방사효과와 항균 및 방취효과 등을 얻을수 있도록 된 패류껍질 분말을 함유한 합성수지 제품 및 그 제조 방법에 관한 것이다.The present invention relates to a synthetic resin product and a method for manufacturing the same, in particular, to obtain a far-infrared radiation effect and antibacterial and deodorizing effect in the synthetic resin product by mixing shellfish shell powder and silver (Ag) inorganic antibacterial agent in the synthetic resin powder The present invention relates to a synthetic resin product containing shellfish shell powder and a method for producing the same.
일반적으로 합성수지는 사출 성형에 의해 여러 가지의 물건을 만들 수 있는 물질 이다.Generally, synthetic resin is a material that can make various kinds of products by injection molding.
그러나, 상기 종래의 합성수지는 물건의 형상을 유지하는 기능 외에 사용자가 원하는 다른 기능을 구비하지 못하였다.However, the conventional synthetic resin did not have other functions desired by the user other than the function of maintaining the shape of the object.
이러한 종래의 문제점 등을 해결 보완하기 위한 본 발명의 목적은,An object of the present invention for solving and solving such a conventional problem,
원적외선의 방사효과와 항균 및 방취효과가 합성수지 제품에 나타나도록 하여 합성수지 제품을 사용하는 사용자의 위생 및 건강을 증진시킬수 있도록 하는 목적을 제공한다.It aims to improve the hygiene and health of users who use synthetic resin products by showing the radiation effect of far infrared rays, antibacterial and deodorant effect on synthetic resin products.
상기 목적을 달성하기 위해 본 발명은,The present invention to achieve the above object,
합성수지 물질에 원적외선을 방사하는 패류(貝類)껍질 분말과 항균 및 방취작용을 하는 은(Ag)이온 무기 항균제를 혼합시켜 합성수지 제품을 사출 성형하면 본발명의 목적을 달성할수 있게 된다.It is possible to achieve the object of the present invention by injection molding a synthetic resin product by mixing the shell material with far-infrared rays and synthetic silver antimicrobial and silver ion inorganic antimicrobial agents.
본발명의 합성수지에 포함되는 혼합물 및 혼합비율을 상세히 설명하면 다음과 같다.Referring to the mixture and the mixing ratio contained in the synthetic resin of the present invention in detail.
사용자가 원하는 제품의 형상을 형성하는 합성수지 물질에 첨가되는 원적외선을 방사는 패류껍질 분말과,Shellfish shell powder that emits far-infrared rays added to the synthetic resin material forming the shape of the product desired by the user,
상기 패류껍질 분말과 함께 첨가되는 항균성 및 방취성을 갖는 은 이온 무기항균제로 이루어진 것이다.It is made of a silver ion inorganic antibacterial agent having antibacterial and deodorant added with the shellfish shell powder.
그리고, 상기 혼합물들의 혼합비율은 96.9 ~ 77 중량%의 합성수지 물질과,And, the mixing ratio of the mixture is 96.9 ~ 77% by weight of the synthetic resin material,
3 ~ 20 중량%의 패류껍질 분말과,Shellfish powder of 3 to 20% by weight,
0.1 ~ 3 중량%의 은 이온 무기 항균제로 이루어진 것이다.0.1 to 3% by weight of silver ion inorganic antibacterial agent.
따라서, 상기와 같이된 합성수지 제품은 패류껍질 분말에서 방사되는 원적외선의Therefore, the synthetic resin product as described above of the far infrared rays emitted from the shell shell powder
방사율(EMISSIVITY)이 90%이상이므로 인체에 좋은 영향을 미치게 되어 혈액순환Emissivity (EMISSIVITY) is more than 90% has a good effect on the human body blood circulation
촉진과 신진대사의 활성화를 얻을수 있게 된다.You will gain facilitation and metabolism.
또한, 상기 은이온 무기항균제에 의해 살균작용 및 항균작용이 뛰어난 합성수지제품을 얻을수 있게 된다.In addition, the silver ion inorganic antimicrobial agent can be obtained a synthetic resin product excellent in sterilization and antibacterial action.
그리고, 사용자가 제조하고자 원하는 합성수지 제품은 식품 포장재, 농업용 필름, 의류용과 산업용의 각종 필름을 포함한 필름 제품, 합성수지 주방용기, 물병, 식음료 용기 등의 주방 용품, 볼펜 케이스 등의 필기도구 성형물, 비닐지, 전자제품 성형물, 운송용 기계부품 성형물, 의료용품 성형물, 바닥재, 장판지, 냉장고용 성형물 등이다.The synthetic resin products that the user wants to manufacture include food packaging materials, agricultural films, film products including various films for clothing and industrial use, kitchen utensils such as synthetic resin kitchen containers, water bottles, food and beverage containers, writing utensils such as ballpoint pen cases, and plastic paper. , Molded articles for electronic products, molded parts for transportation machinery, molded articles for medical supplies, flooring, cardboard, and molded articles for refrigerators.
또한, 상기 합성수지 물질은 석유 화학 합성 수지이며, 제품에 따라 상기 합성수지 물질의 성분이 다르다. 이 때 주로 쓰이는 합성수지 원료는 PE, PET, PP, NY, PVC 등이 있다.In addition, the synthetic resin material is a petrochemical synthetic resin, and the components of the synthetic resin material vary depending on the product. At this time, the synthetic resin raw materials are mainly PE, PET, PP, NY, PVC, and the like.
한편, 본발명 합성수지의 제조방법을 설명하면 다음과 같다On the other hand, the manufacturing method of the present invention synthetic resin is as follows.
원적외선을 방사하는 패류껍질을 채취하여 깨끗하게 세척한 뒤 분쇄기에서 분쇄 하는 분쇄과정과,The crushing process of collecting shell shells emitting far infrared rays, washing them cleanly, and then crushing them in a crusher;
상기 분쇄과정에서 분쇄된 패류껍질 분말을 열처리하기 위해 패류껍질을 소성로에서 소성하는 소성과정과,A firing process of firing shellfish shells in a kiln to heat-treat the shellfish shell powder pulverized in the grinding process;
상기 소성과정에서 소성된 패류껍질을 일정크기의 입자로 밀링하기 위한 밀링과정과,A milling process for milling the shell shell fired in the firing process into particles of a predetermined size;
상기 밀링과정에서 분쇄된 패류껍질 분말을 항균력과 살균력이 높은 은(Ag)이온 무기 항균제와 함께 합성수지 물질에 혼합하는 혼합과정과,A mixing process of mixing the shellfish shell powder pulverized in the milling process with a synthetic resin material with silver (Ag) inorganic antimicrobial agent having high antibacterial and bactericidal properties,
상기 혼합과정에서 혼합된 혼합물을 적정의 용융 온도로 가열하여 압출 성형하는 성형과정으로 이루어진 것이다.It consists of a molding process of extrusion molding by heating the mixture mixed in the mixing process to a suitable melting temperature.
상기와 같이된 본 발명 패류껍질 분말을 함유한 합성수지 제품의 제조 방법을 구체적으로 설명한다.The manufacturing method of the synthetic resin product containing the shellfish powder of this invention as mentioned above is demonstrated concretely.
먼저, 패류껍질 채취단계에서 제품 제조자는 원적외선을 방사하는 패류껍질을 채취한 뒤 깨끗하게 세척을 한다.First, in the shell shell collection step, the product manufacturer collects shell shells that emit far infrared rays and cleans them.
상기의 패류껍질은 연체동물중 패각(貝殼)을 갖추고 있는 동물을 통틀어 이야기 하는 것이다.The shellfish mentioned above is the whole story of animals with shells.
다음에 분쇄단계에서는 패류껍질을 분쇄기에 의하여 적정의 크기로 분쇄한다.Next, in the crushing step, the shells are crushed to a proper size by a crusher.
그리고, 소성(FIRING)단계에서는 상기 패류껍질을 열처리하기 위해 분쇄된 패류 껍질 분말을 소성로에서 적정의 온도로 소성시킨다.In the firing step, the shellfish shell powder pulverized to heat-treat the shellfish is calcined at an appropriate temperature in a firing furnace.
또한, 밀링단계에서는 소성된 패류껍질 분말을 미립자로 다시 분쇄하는 밀링 작업을 하게 되는바, 상기의 패류껍질은 석회질이므로 잘 부스러지기 때문에 원활한 밀링작업이 가능하게 되며 아울러 작업성 및 분산성이 우수하게 된다.In addition, in the milling step, a milling operation is performed to grind the fired shellfish powder back into fine particles. Since the shellfish is limed, it is brittle, so that smooth milling operation is possible and workability and dispersibility are excellent. do.
예를 들어 상기의 밀링단계에서는 패류껍질 분말을 약 2,000매쉬 이하가 되도록 밀링하는 것이 바람직스럽다.For example, in the milling step, it is preferable to mill the shellfish powder to about 2,000 mesh or less.
또한, 혼합단계에서는 상기 합성수지 물질 96.9-77중량%와 패류껍질 분말 3-20중량% 그리고 은 이온 무기항균제 0.1-3중량%를 혼합기에서 혼합시킨다.In the mixing step, 96.9-77% by weight of the synthetic resin material, 3-20% by weight of shellfish shell powder, and 0.1-3% by weight of silver ion inorganic antibacterial agent are mixed in a mixer.
그리고, 상기 혼합단계에서 혼합된 합성수지 물질과 패류껍질 분말 및 무기 항균제의 혼합물을 압출기에서 용융,압출, 사출, 회전, 진공 및 중공시켜 사용자가 원하는 제품을 성형한다.Then, the mixture of the synthetic resin material, shellfish shell powder and the inorganic antimicrobial agent mixed in the mixing step is melted, extruded, injected, rotated, vacuumed and hollow in an extruder to form a product desired by the user.
한편, 패류껍질 분말과 은 이온 무기항균제의 혼합물 20 ~ 50 중량%와 합성수지 수지 50 ~ 80 중량% 비율로 용융 압출하여 마스터 배치(M.B)를 만들수도 있다Meanwhile, a master batch (M.B) may be made by melt extrusion at a ratio of 20 to 50% by weight of a shellfish shell powder and a silver ion inorganic antibacterial agent and 50 to 80% by weight of a synthetic resin.
즉, 패류껍질 분말을 분쇄기에서 2,000 매쉬 이하로 분쇄한뒤 소성로에서 패류껍질 분말을 3 ~ 10시간 동안 소성시킨다.That is, the shell shell powder is pulverized to 2,000 mesh or less in the pulverizer and the shell shell powder is calcined in the kiln for 3 to 10 hours.
이어서 상기 패류껍질 분말과 무기 항균제를 분쇄기에서 일정크기로 분쇄한다.Subsequently, the shellfish powder and the inorganic antimicrobial agent are pulverized to a certain size in a pulverizer.
그리고, 상기의 분쇄된 패류껍질 분말과 무기항균제를 혼합기에서 합성수지분말과 30 : 70 중량%의 비율로 혼합하여 마스터 배치(M.B.)를 만든다.Then, the pulverized shellfish shell powder and the inorganic antimicrobial agent are mixed with a synthetic resin powder in a ratio of 30: 70 wt% in a mixer to make a master batch (M.B.).
다음에 혼합기에서 상기 마스터 배치와 합성수지 물질을 18 : 82 중량%의 비율로 혼합하여 건조시킨다.The master batch and the synthetic resin material are then mixed in a mixer in a ratio of 18: 82 wt% and dried.
이어서 상기 패류껍질 분말과 무기 항균제의 혼합물 및 합성수지 물질을 상기 합성수지 물질의 용융 온도로 가열하여 용융 압출시킨다.Subsequently, the shellfish powder and the mixture of the inorganic antimicrobial agent and the synthetic resin material are heated and melt-extruded to the melting temperature of the synthetic resin material.
그리고, 상기 용융된 합성수지 물질과 패류껍질 분말 및 무기 항균제의 혼합물을 압출기에서 압출, 사출, 회전, 진공 및 중공시켜 사용자가 원하는 제품을 성형한다.Then, the mixture of the molten synthetic resin material, shellfish shell powder and inorganic antimicrobial agent is extruded, injected, rotated, vacuumed and hollowed in an extruder to form a product desired by a user.
또한, 상기 패류껍질 분말과 은 이온 무기항균제의 혼합물과 합성수지 물질을 혼합한뒤 중압 방법에 의해 합성수지 제품을 만들수도 있다.In addition, it is also possible to make a synthetic resin product by a medium pressure method after mixing the mixture of the shell shell powder, silver ion inorganic antibacterial agent and the synthetic resin material.
상술한 바와 같이 구성되고 제조된 본 발명에 따른 패류껍질 분말을 함유한 합성 수지 제품의 효과는 다음과 같다.Effects of the synthetic resin product containing shellfish powder according to the present invention constructed and prepared as described above are as follows.
상기의 패류껍질분말과 은이온 무기항균제가 첨가된 합성수지 제품의 경우 항균, 방취작용에 의해 신선도 유지와 위생적인 효과를 얻을수 있다.In the case of the above-mentioned shellfish shell powder and silver ion inorganic antibacterial agent, synthetic resin products can maintain freshness and hygienic effect by antibacterial and deodorizing action.
또한, 상기의 합성수지 제품에 포함된 패류껍질 분말의 원적외선 방사에 의해 제품의 보온,보냉 또는 자외선 차단효과 및 유해전자파 방지효과가 우수하게 된다.In addition, by the far-infrared radiation of shellfish shell powder contained in the synthetic resin product it is excellent in the thermal insulation, cold insulation or ultraviolet ray blocking effect and harmful electromagnetic waves of the product.
그리고, 상기 패류껍질의 원적외선 방사 효과로 혈액 순환 촉진 및 신진대사, 각종 질병 예방에 뛰어난 효과가 있다.In addition, the far-infrared radiation effect of the shell shell has an excellent effect on promoting blood circulation, metabolism, and various diseases.
또한, 상기 은 이온 무기항균제의 살균 및 항균작용에 의해 합성수지 제품에 세균이 기생하는 것을 막을수 있고 세균을 살균할 수 있는 매우 뛰어난 효과가 있다.In addition, by the sterilization and antimicrobial action of the silver ion inorganic antimicrobial agent can prevent the parasitic bacteria in the synthetic resin product and has a very excellent effect to sterilize the bacteria.
그리고, 상기의 효과 이외에도 정전기 방지, 악취 제거등의 효과가 있다.In addition to the above effects, there are effects such as antistatic and odor removal.
또한, 야채 수송용 상자를 본발명의 합성수지로 제작하였을 경우 패류껍질 분말로부터 방사되는 원적외선과 상기 은 이온 무기항균제의 항균성으로 인해 장시간 신선도를 유지할 수 있다.In addition, when the vegetable transport box is made of synthetic resin of the present invention, the freshness can be maintained for a long time due to the far infrared rays emitted from the shell shell powder and the antimicrobial activity of the silver ion inorganic antimicrobial agent.
한편, 본 발명에 따른 패류껍질 분말을 포함한 합성수지 제품의 제조방법에 의하면 분쇄과정,소성과정,밀링과정,혼합과정,성형과정에 의해 용융 압출하여 패류껍질을 포함한 합성수지 제품을 용이하게 제조할 수 있는 매우 뛰어난 효과가 있다.On the other hand, according to the method of manufacturing a synthetic resin product including shellfish shell powder according to the present invention by melting and extruding by the grinding process, baking process, milling process, mixing process, molding process can be easily manufactured synthetic resin products including shellfish shell It is very effective.
특히, 상기의 패류껍질은 지금까지 전량 재활용이 되지 않아 환경을 오염시키는 문제점이 있었는바, 본발명에 의해 상기의 패류껍질을 이용함으로서 환경오염을 방지할 수 있는 효과도 있다.In particular, the shellfish has not been recycled in its entirety until now there has been a problem to contaminate the environment, by using the shell shell according to the present invention there is an effect that can prevent the environmental pollution.
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Cited By (10)
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KR20010103109A (en) * | 2001-10-09 | 2001-11-23 | 이정석 | the Method for Fabricating the Functional Complexed Resin |
KR20020045307A (en) * | 2000-12-08 | 2002-06-19 | 석미수 | Method of fabricating a mixture of a mixed inorganic ion antibiotics and a mineral, and method of fabricating multi functional goods and multi functional goods fabricated therefrom |
KR100552606B1 (en) * | 2002-04-16 | 2006-02-20 | 김봉헌 | The manufacturing method of new materials using a gem stone and a sea shell or a oyster shell |
KR100687617B1 (en) * | 2005-01-14 | 2007-02-27 | 이용재 | Manufacturing method of mother-of-pearl bar |
KR101678314B1 (en) * | 2015-09-25 | 2016-11-21 | (주)드림라임 | Manufacturing Method of Antibacterial Masterbatch Using Ionized Calcium Powder |
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KR20020045307A (en) * | 2000-12-08 | 2002-06-19 | 석미수 | Method of fabricating a mixture of a mixed inorganic ion antibiotics and a mineral, and method of fabricating multi functional goods and multi functional goods fabricated therefrom |
KR20010103109A (en) * | 2001-10-09 | 2001-11-23 | 이정석 | the Method for Fabricating the Functional Complexed Resin |
KR100552606B1 (en) * | 2002-04-16 | 2006-02-20 | 김봉헌 | The manufacturing method of new materials using a gem stone and a sea shell or a oyster shell |
KR100687617B1 (en) * | 2005-01-14 | 2007-02-27 | 이용재 | Manufacturing method of mother-of-pearl bar |
KR101678314B1 (en) * | 2015-09-25 | 2016-11-21 | (주)드림라임 | Manufacturing Method of Antibacterial Masterbatch Using Ionized Calcium Powder |
KR101693502B1 (en) * | 2015-09-25 | 2017-01-06 | 정성효 | Method of Producing antibacterial film of an antibacterial master batch containing ionized calcium powder as a raw material |
KR20180045753A (en) * | 2016-10-26 | 2018-05-04 | 주식회사 애드그린 | Eco-friendly antibiotic composition using bio-PE, eco-friendly antibiotic film and food container using the same |
KR102063170B1 (en) * | 2019-05-23 | 2020-01-08 | 김미순 | Method for manufacturing environment-friendly film using shellfish shell and recycled resin and environment-friendly film manufactured by the method |
KR102166172B1 (en) * | 2020-03-24 | 2020-10-15 | (주) 휴코스 | An Eco-friedly Ornament-plate with Surfaced by Low Pressure Melamine impregnated paper having Antibiosis Effect |
KR102226396B1 (en) * | 2020-04-29 | 2021-03-12 | 월포스 주식회사 | Manufacturing method of melamine resin molded article |
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