KR100931422B1 - Refrigerator - Google Patents

Abstract

In the present invention, when the vacuum insulator is manufactured, as shown in Fig. 6, material particles 31b, foreign matters 31c, or wrinkles 31d having large diameters or particles are formed on the surface of the core material. If the shell material is damaged or elapsed for a long time, the gas permeation amount is increased from the damaged portion, which may cause a decrease in the degree of vacuum.

The outer cover material which installs a vacuum insulator between the outer box and the inner box, and coat | covers the core material of the said vacuum insulator consists of at least a surface protection film, a metal vapor deposition film, a metal foil, and an inner layer film, An organic material layer was interposed between the inner layer film and the surface of the core material, and a vacuum insulating material having a total value of 40 μm or more in total from the core material surface to the metal foil was provided in the foamed heat insulating material. In addition, a vacuum insulator having a thinner thickness of the inner layer film covering the inner surface of the metal foil of the shell material by coating an organic material layer on the surface of the core material mainly composed of glass fibers was installed in the foam insulation.

Description

Refrigerator {REFRIGERATOR}

1 is a longitudinal sectional view of a refrigerator showing an embodiment of the present invention;

2 is a schematic cross-sectional view of a vacuum insulator showing an embodiment of the present invention.

3 is an enlarged cross-sectional schematic diagram of a vacuum insulator showing an embodiment of the present invention;

Figure 4 is a manufacturing process diagram of the core material showing an embodiment of the present invention.

5 is a schematic cross-sectional view of a vacuum insulator showing an embodiment of the present invention.

6 is an enlarged cross-sectional schematic diagram of a core material showing a conventional problem.

Figure 7 is a schematic perspective view of the assembly of the shell material and the core material showing a conventional problem.

8 is a partially enlarged cross-sectional schematic diagram of a vacuum insulator showing a conventional problem.

<Explanation of symbols for main parts of the drawings>

1: refrigerator box member

2: outer box

3: insulation

4: inner box

8, 9: cooler

10: compressor

11: vacuum insulation

12: surface protection film

13: metal deposition film

14: support layer

15: metal foil

16: inner layer film

17 core material

18: organic material layer (film or coating) on the core material side

19: organic material layer (film or coating) on the skin material side

20: shell material

21: upper mold

22: lower mold

23: release film

24: core material

The present invention relates to a vacuum insulator and a refrigerator having a vacuum insulator.

It is known that a vacuum heat insulating material is comprised by covering the core material which consists of heat insulating materials with an outer cover material, and pressure-sealing sealing the inside.

Patent Document 1 discloses that an outer cover material is composed of a surface protective film, a metal layer, and an inner layer film, and the inner layer film is 50 µm or more and 150 µm or less. Since this inner layer film is comprised from resin which can be thermally welded, and thermal conductivity differs by this thickness, it is assumed that the thermal conductivity does not affect the thermal insulation performance of a vacuum heat insulating material, ie, 50 micrometers-150 micrometers.

On the other hand, Patent Document 2 is a vacuum insulator in which the front-side film and the back-side film of the outer cover material are joined to the periphery of the core material. Is disclosed. The above separation distance is determined in consideration of the gas barrier properties of the outer cover material and the thermal insulation between the front film and the back film.

[Patent Document 1]

Japanese Patent Laid-Open No. 8-303685

[Patent Document 2]

Japanese Patent Laid-Open No. 10-185417

In the said prior art, the problem resulting from the flatness of the surface of a vacuum heat insulating material, and the prevention of the damage of an outer skin material by a core material at the time of manufacture of a vacuum heat insulating material were not considered. When using the core material which consists of inorganic fiber type materials especially, there exists a problem in surface property compared with the case where a hard foam synthetic rubber is used for a core material. When assembling a core material made of an inorganic fiber-based material to an outer shell material, the following problems arise. This problem will be described below with reference to FIGS. 6 to 8.

6 shows an enlarged cross-sectional view of the core material. On the surface 31a of the core material 31, material particles 31b, foreign matters 31c, or wrinkles 31d having large diameters or particles among the materials constituting the core material are formed, and the material particles 31b or foreign matters ( 31c) or the crease 31d protrudes from the surface 31a by T ₁ , T _2, or T ₃ , so that the gas permeation amount is increased from this damaged portion if the shell material is damaged or elapsed for a long time. There was no consideration.

7 is an assembled perspective view of the core material and the shell material. As shown in Fig. 7, when the core material 31 is inserted into the outer shell material 32 on which the three sides are heat-welded, there is a fine debris 36 falling from the core material at the inlet of the outer shell material. The fine debris 36 adheres to 32a which becomes a heat welding part at the time of sealing under reduced pressure after insertion. At this time, the gas permeation amount of the heat welding portion 32a is increased.

That is, as shown in Fig. 8, when the fine debris 36 dropped from the core material is held by the heat welding portion of the outer cover material, the sealing dimension of the heat welding portion becomes T ₁₀ smaller than the predetermined size. The gas permeation amount from the clamping portion is increased. In the above-described prior art, no consideration has been given to such preventive measures.

In view of the above, it is an object of the present invention to provide a refrigerator employing a vacuum insulator that can maintain excellent heat insulation performance for a long time even when material particles or the like appear on the surface of a core material made of an inorganic fiber material. Moreover, it aims at providing the structure of the vacuum heat insulating material by which fine debris etc. are not pinched in the heat | fever welding part of an outer skin material, and the refrigerator using the same.

In order to achieve the above object, the present invention is a vacuum insulator installed in a foam insulation filled between the outer box and the inner box or a refrigerator in which the vacuum insulation is installed,

This vacuum heat insulating material is equipped with the core material of inorganic fiber, and the outer cover material which coat | covers this core material,

This outer shell material includes a surface protective film constituting the outermost surface, a metal layer having gas barrier properties, a thermal welding layer for sealing the inside by thermally welding the outer shell material,

An organic material layer is provided between the heat welding layer and the surface of the core material.

The layer thickness from the surface of the core material to the metal layer is set to 40 µm or more.

A resin layer is provided on the outer layer of the metal layer, and the resin layer is provided with a metal deposition layer in which a metal is deposited.

In addition, an organic material layer is coated on the surface of the core material, or the layer thickness of the heat-welding layer covering the inner surface of the metal layer of the outer cover material is covered with an organic material layer film to have a layer thickness of 25 μm or less.

Hereinafter, an embodiment of the present invention will be described with reference to the drawings.

1 is a longitudinal sectional view of a refrigerator showing an embodiment of the present invention.

As shown in FIG. 1, the refrigerator box member 1 includes an outer box 2 and an inner box 4, and a foamed heat insulating material 3 such as urethane filled between the outer box 2 and the inner box 4; It consists of). The refrigerator box member 1 partitions the refrigerator compartment (vegetable compartment) 5, the ice-making compartment (selection chamber) 6, and the freezing compartment 7 in its inside. Reference numeral 8 denotes a cooler for cooling the refrigerating chamber (vegetable chamber) 5 to a predetermined temperature, and reference numeral 9 denotes a cooler for cooling the ice making chamber (selection chamber) 6 and the freezing chamber 7 to a predetermined temperature. The coolers 8 and 9 evaporate the refrigerant circulated in the compressor 10 and are kept at a relatively low temperature in the refrigerator to maintain a predetermined low temperature. Therefore, from the energy-saving point of view of the refrigerator, the vacuum insulator 11 having a lower thermal conductivity than the foam insulator 3 such as urethane is contained in the foam insulator 3 on the rear projection surface of the coolers 8 and 9 having relatively large heat leakage in the refrigerator. Is installing.

2 is a schematic cross-sectional view of a vacuum insulator showing an embodiment of the present invention. As shown in FIG. 2, the vacuum insulator 11 is provided with a core material 17 inside the cover material 20 having a gas barrier property, and the inside of the cover material 20 and the core material 17 is installed. It is comprised so that pressure reduction may be carried out at predetermined vacuum degree and the heat insulation performance as vacuum heat insulation may be provided. The outer shell material 20 has a surface protective film 12 formed of nylon resin, polyethylene terephthalate resin, or the like on the outer surface thereof, and has a metal foil 15 such as aluminum having good gas barrier property therein, and further on the inner side thereof. The inner layer film 16 which can be heat-sealed, such as a high density polyethylene resin and a polyacrylonitrile resin, is integrally comprised. That is, the surface protection film 12 is formed of nylon resin and polyethylene terephthalate resin having strength to protect the surface of the shell material 20, and the metal foil 15 to maintain the degree of vacuum inside the shell material 20. It is formed by a metal such as aluminum having excellent gas barrier properties, and the inner layer film 16 is disposed as a heat-welding layer that can be heat-sealed to seal the inside of the outer shell material 20, and is made of a high density polyethylene resin or a polyacrylonitrile resin. And the like.

In the present embodiment, a metal deposition film 13 in which a metal such as aluminum is deposited on the support layer 14 such as polyethylene terephthalate resin or polypropylene resin is interposed between the surface protection film 12 and the metal foil 15. It is said that strength and gas barrier property are more favorable.

3 is an enlarged cross-sectional schematic diagram of a vacuum insulator showing an embodiment of the present invention. The thickness (T ₆₎ of the inner layer film 16 as shown in Figure 3, the thickness of the organic material layer film or organic material layer coating to be described later (T ₅₎ and to fit the material particles or debris or wrinkles appear on the surface material cores (in this Representative of material particles, foreign matters, or wrinkles, and the following descriptions are referred to as material particles, etc.) are set to dimensions that do not damage the metal foil 15 such as aluminum having good gas barrier properties. That is, as shown in FIG. 3, when the maximum protrusion dimension of the material particles 17f and the like appearing on the surface 17a of the core material 17 is T ₄ , the metal foil 15a at the corresponding position of the protrusion such as the material particles is shown. Even if this strain is locally deformed, the thickness T ₆ of the inner layer film 16 and the organic material layer film or organic material so that the elongation rate of the locally deformed portion 15a is within the allowable range of the tensile elongation rate of the metal foil 15 itself. The total thickness T ₇ of the thickness T ₅ of the layer coating is set.

In other words, the material particles 17f and the like appearing on the surface of the core material locally compressively deform the organic material layer film or the organic material layer coating by atmospheric pressure or pressurization pressure at the time of manufacture, and then further, the inner layer film 16 is locally The total thickness T ₇ of the thickness T ₅ and the thickness T ₆ is set so that the gas barrier property of the metal foil 15 is not damaged even by compressive deformation.

Moreover, according to the experiments of the inventors, as described later, it was found that the gas barrier property of the metal foil 15 was not impaired even in the long term if the total thickness T ₇ was 40 µm or more.

Reference numeral 18 in FIG. 2 denotes an organic material layer film or organic material layer coating covering the surface of the core material 17, and the thickness is set to be T ₅ described above.

In the case where the organic material layer 18 on the core material side is an organic material layer film, as shown in Fig. 4, the artificial mineral fiber thermal insulation material impregnated with a binder, which is a raw material of the core material, is produced when the core material 17 described later is manufactured. The release film 23 for mold release from the metal mold | die at the time of heat compression becomes unnecessary.

In addition, by covering the surface of the core material 17 with the organic material layer film or the organic material layer coating in this way, from the core material 17 at the time of assembling the core material to the shell material as shown in Figs. The fall of the fine debris 36 can be prevented, and the increase in the gas permeation amount can be prevented.

FIG. 5 shows an example of covering with an organic layer film or an organic layer coating to cover the inner surface of the inner layer film 16 of the outer shell 20. Reference numeral 19 is an organic material layer film or an organic material layer coating that covers the inner surface of the inner layer film 16 of the outer cover material, and the thickness T ₅ is set as described above.

Here, the example of manufacture of the core material 17 is demonstrated with FIG. 4 is a manufacturing process diagram of the core material of the present embodiment. Reference numeral 24 blends a binder material such as soda silicate or phenol resin powder to the artificial mineral fiber thermal insulation material (JIS A9504), which is a raw material of the core material 17 (17 in FIGS. 2 and 3), and a urethane fine powder. It is a core material raw material, it polymerizes several sheets of the core material raw material 24, and heat-compresses with the upper metal mold | die 21 and the lower metal mold | die 22, and it is set as predetermined thickness. In the case of heat-compression with a mold, if a binder material or the like adheres to the mold, the core material becomes difficult to release, so that the release film 23 is inserted between the raw material of the core material and the mold, but without using the release film 23 described above. If an organic material layer film is useful, the release film 23 becomes unnecessary, which is advantageous in terms of manufacturing cost.

Binder Stock Concentration (weight /%) Initial thermal conductivity (㎽ / m · K) Handling  Silicate Soda 3 3 1.9 Good 5 2.1 Good 10 3.0 Surface slightly cracked 20 9.6 Surface crack  Silicate Soda No. 2 3 2.0 Good 5 2.5 Good 10 3.1 Surface crack 20 12.3 Whole solidification  Silicate Soda No. 1 3 2.0 Good 5 2.8 Good 10 5.3 The whole hardens a little and breaks 20 12.9 Whole solidification

Binder Stock Concentration (weight /%) Initial thermal conductivity (㎽ / m · K) Handling  Silicate Soda 3 One 1.9 A little soft 2 1.8 A little soft 3 1.9 Good 4 1.9 Good 5 2.1 A little hard

According to the experiments of the inventors, in the case of using "artificial mineral fiber thermal insulation material" (JIS A9504) as the raw material of the core material 17 and "sodium silicate (sodium silicate)" (JIS K1408) as the binder, Table 1 and Table 2 It was like That is, the initial thermal conductivity of the vacuum insulation material of a predetermined size when the binder stock solution is made of soda silicate Nos. 1, 2, and 3 as concentrations of 3%, 5%, 10%, and 20% by weight percent, As shown in Table 1, soda silicate 3 was the best. In addition, the initial thermal conductivity was better in that the concentration of sodium silicate was 5% or less. As a result of detailed experiments with Sodium Silicate No. 3, as shown in Table 2, the initial thermal conductivity was initially 1% to 5%. The thermal conductivity was almost good. Moreover, when the density | concentration of soda silicate is less than 2%, it became too soft and the fault was caused to the handleability as a core material raw material.

Here, an example of the largest projecting dimension T ₄ such as the raw material particles 17f appearing on the surface 17a of the core material 17 shown in FIG. 3 will be described with reference to Table 3. FIG.

division Maximum projected dimensions of material particles, etc. T ₄ of Figure 3 Dimension (μm) Flame Insertion Method (%) Rotary method (%) A More than 20 2 One B 10 to 20 10 2 C Less than 10 88 97

Although Table 3 uses the above-mentioned "artificial mineral fiber thermal insulation material" as a raw material of the core material 17, the size distribution of raw material particles etc. differs also by the manufacturing method of this "artificial mineral fiber thermal insulation material". As a manufacturing method, the flame insertion method and the rotary method are known well normally. Here, about both the flame insertion method and the rotary method, it divides into three divisions A, B, and C, and the ratio is represented by percentage (%).

T ₄ described above Dimensions and a film showing less than 10 ㎛ in Category C, T ₄ The dimensions and that of 10 ㎛ to 20 ㎛ in Category B, T ₄ The dimension exceeding 20 micrometers is shown as division A. FIG. As shown in Table 3, in the flame inserting method and the rotary method, the largest projecting dimension T ₄ of the material particles or the like has the largest division C of less than 10 m. In addition, the distribution of A, B, and C is simple and the manufacturing process is simple, compared with the inexpensive flame insertion method, It is thought that the thing with few unevenness | corrugation can be manufactured in the case of the rotary method.

However, even if the flame insertion method can be used as the core material belonging to category B, it is advantageous in consideration of production efficiency and production cost. That is, if the T ₄ dimension of 20 micrometers or less is used for the "artificial mineral fiber thermal insulation material" manufactured by the flame insertion method which can manufacture easily and cheaply, a manufacturing cost of a vacuum heat insulating material can be aimed at.

Therefore, Table 4 demonstrates the Example which does not impair the gas barrier property of the metal foil 15 also in the long term about the core material of the division B of the raw material produced by the flame insertion method.

First embodiment Second embodiment Third embodiment  Cortex ash Surface Protection Film Metal Evaporation Film Support Layer Metal Foil Inner Layer Film 15 μm 3 μm 10 μm 6 μm 20 μm Nylon Al PET Al foil high density PE 15 μm 3 μm 10 μm 6 μm 25 μm Nylon Al PET Al foil high density PE 15 μm 3 μm 10 μm 6 μm 15 μm Nylon Al PET Al foil high density PE Organic film 20 μm PET 25 μm PET 15 μm PET Welding width 10 mm 10 mm 10 mm Core ash Raw material Glass wool Glass wool Glass wool Manufacturing method of raw materials Flame Insertion Flame Insertion Flame Insertion Method of Extrusion of Material Particles (T ₄ Dimensions in Fig. 3) 10 to 20 μm 10 to 20 μm 10 to 20 μm Thermal conductivity Initial value (㎽ / m · K) 5 to 6 5 to 6 5 to 6 After heating at 60 ℃ for 4 months (㎽ / m · K)  7 to 8  7 to 8  9 to 11

In the first embodiment of Table 4, a 15 µm nylon resin was used as the surface protection film described above, an aluminum metal deposited film was 3 µm, and a 10 µm polyethylene terephthalate resin was used as the support layer of the aluminum metal deposited film. The aluminum metal foil was 6 micrometers and 20 micrometers high density polyethylene resin was used as an inner film. In addition, a polyethylene terephthalate resin having a thickness of 20 µm was used as the organic film covering the core material separately from the outer cover material.

In addition, as a verification that the gas barrier property was not impaired in the long term, the initial value of the thermal conductivity and the value after leaving the sample in air at 60 ° C. for 4 months were measured so as to judge the deterioration of the thermal conductivity over time. The measurement was measured at an average temperature of 24 ° C. using a heat conductivity measuring device HC-071 manufactured by EKO INSTRUMENTS CO., LTD.

The 2nd Example used the high-density polyethylene resin of 25 micrometers as an inner layer film, and used the 25-micrometer polyethylene terephthalate resin as an organic material film, and made it the same conditions as the 1st Example.

As shown in Table 4, the measured values after heating at 60 ° C. for 4 months were 7 to 8 μs / m · K for the first and second examples, and 9 to 1 μs / m · K for the first comparative example. It was good in comparison. When a vacuum insulator is used for the refrigerator as a boundary that can withstand long-term use, it can be said that both of the first embodiments 1 and 2 are satisfactory, with 8 kW / m · K being a target.

Moreover, by providing an organic material layer, it became possible to make the layer thickness of the inner film which is a heat welding layer thin. In this example, it was confirmed that it can be 25 micrometers or less, or 20 micrometers or less.

As described above, according to the present embodiment, the outer cover 20, the surface protection film 12, the metal deposition film 13, the metal foil 15, and the inner layer film covering the core material 17 of the vacuum insulator 11 are described. (16), material particles having large diameters or particles appearing on the core material surface of the vacuum insulator by interposing the organic material layer 18 between the inner layer film 16 and the surface of the core material 17. Since the metal foil 15 having the gas barrier property is not damaged even if foreign matters or wrinkles are generated, a refrigerator including a vacuum insulator having excellent thermal conductivity even after a long period of time can be provided.

When the total thickness of the inner layer film and the organic material film is equal to or larger than 40 µm as in the first embodiment, the gas barrier properties can be achieved even if a large-diameter material or large particle or foreign matter or wrinkles appearing on the core material surface of the vacuum insulator. Since the metal foil which has is not damaged, it can provide the refrigerator structure containing the vacuum heat insulating material which is excellent in thermal conductivity even if it elapses for a long time. Moreover, even if the metal foil 15 is damaged in any case, since it has the metal vapor deposition film 13 as an outer cover, it can maintain the vacuum degree even after a long period of time, and therefore provides the refrigerator containing the vacuum heat insulating material which is excellent in thermal conductivity. can do.

In addition, the organic material layer was coated on the surface of the core material 17 to reduce the thickness of the inner layer film covering the inner surface of the metal foil 15 of the outer cover material 20. This layer is a layer necessary for thermal welding when sealing the inside of the shell material, but does not have a strength enough to protect the metal foil having gas barrier properties from the unevenness of the surface of the core material, and itself does not have sufficient gas barrier property. . Therefore, since the gas permeation amount from the inner layer film 16, which is a heat welding layer, can be reduced by coating the organic material layer, a refrigerator including a vacuum insulator having a high vacuum degree for a long time can be provided.

In addition, since the organic material layer coated on the surface of the core material covers the fine debris of the glass fiber to be dropped from the core material when the core material 17 is inserted into the outer cover material 20, the fine waste material is applied to the outer cover material 20. Since it is not attached to the inlet, it is possible to provide a refrigerator including a high vacuum insulation material for a long time.

Moreover, since the thickness of the inner layer film 16 which covers the surface of the core material 17 with the organic material layer film and coat | covers the inner surface of the metal foil 15 of the outer cover material 20 was made thin, when manufacturing the core material 17, Since the release film 23 for releasing from the metal mold | die at the time of heat-compressing the glass wool which impregnated the binder used as the raw material of a core material can be eliminated, the refrigerator containing a vacuum heat insulating material advantageous in manufacturing cost can be provided.

In addition, since the surface of the core material 17 is double-coated with the organic material layer film and the inner layer film 16 of the outer material, the film layer is obtained even if a material particle having a large diameter or particles appearing on the surface of the core material, or a foreign substance or wrinkles. This hard to be damaged can provide a refrigerator including a vacuum insulation. In addition, since the inner surface of the inner layer film 16 was covered with the organic layer film or the organic layer coating, the core material 17 and the inner layer film 16 covering the inner surface of the metal foil 15 did not directly contact each other. The synthesis of the ash and the inner layer film is not a problem. Therefore, the core material or the inner film raw material can be arbitrarily selected, and a refrigerator including a vacuum insulator, which is advantageous in terms of manufacturing cost, can be provided.

According to the present invention, it is possible to provide a refrigerator employing a vacuum insulator capable of maintaining excellent heat insulation performance for a long time even when material particles or the like are formed on the surface of a core material made of an inorganic fiber material. Moreover, the structure of the vacuum heat insulating material by which fine debris etc. are not pinched in the heat welding part of an outer skin material, and the refrigerator using the same can be provided.

Claims (6)

The core material made of inorganic fibers is a vacuum insulating material which is covered with an outer shell material having gas barrier properties and is formed by depressurizing the inside, The outer shell material is a surface protective film for protecting the surface, a gas barrier layer located inside the surface protection film and formed of metal, and an inner layer film located inside the gas barrier layer and weldable to seal the inside of the outer shell material. With Between the sheath material and the core material, an organic material layer covering the core material and covering the inner surface of the inner layer film to compress the core material is interposed. The total thickness of the thickness of the said inner layer film and the thickness of the said organic material layer was 40 micrometers or more and 50 micrometers or less, The vacuum heat insulating material characterized by the above-mentioned. The vacuum insulator of claim 1, wherein the organic material layer has a thickness that maintains the gas barrier property of the gas barrier layer even when locally compressively deformed. delete delete The vacuum insulator according to claim 1 or 2, wherein the organic material layer is an organic material layer covering the core material separately from the shell material. The vacuum insulator according to claim 1 or 2, wherein polyethylene terephthalate resin having a thickness of 20 µm or more and 25 µm or less is used as the organic material layer.

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