JPS63309173A - Tobacco filter - Google Patents
Tobacco filterInfo
- Publication number
- JPS63309173A JPS63309173A JP14517987A JP14517987A JPS63309173A JP S63309173 A JPS63309173 A JP S63309173A JP 14517987 A JP14517987 A JP 14517987A JP 14517987 A JP14517987 A JP 14517987A JP S63309173 A JPS63309173 A JP S63309173A
- Authority
- JP
- Japan
- Prior art keywords
- filter
- cellulose acetate
- titanium white
- fibers
- cigarette
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 235000002637 Nicotiana tabacum Nutrition 0.000 title description 12
- 244000061176 Nicotiana tabacum Species 0.000 title 1
- 229920002301 cellulose acetate Polymers 0.000 claims description 27
- 239000000835 fiber Substances 0.000 claims description 27
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 17
- 235000019504 cigarettes Nutrition 0.000 claims description 17
- 239000000779 smoke Substances 0.000 claims description 17
- 235000010215 titanium dioxide Nutrition 0.000 claims description 17
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 12
- 241000208125 Nicotiana Species 0.000 description 11
- 238000004519 manufacturing process Methods 0.000 description 8
- SNICXCGAKADSCV-JTQLQIEISA-N (-)-Nicotine Chemical compound CN1CCC[C@H]1C1=CC=CN=C1 SNICXCGAKADSCV-JTQLQIEISA-N 0.000 description 6
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
- 238000001914 filtration Methods 0.000 description 6
- SNICXCGAKADSCV-UHFFFAOYSA-N nicotine Natural products CN1CCCC1C1=CC=CN=C1 SNICXCGAKADSCV-UHFFFAOYSA-N 0.000 description 6
- 229960002715 nicotine Drugs 0.000 description 6
- 238000000034 method Methods 0.000 description 5
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 4
- 239000000796 flavoring agent Substances 0.000 description 4
- 235000019634 flavors Nutrition 0.000 description 4
- 229910052719 titanium Inorganic materials 0.000 description 4
- 239000010936 titanium Substances 0.000 description 4
- URAYPUMNDPQOKB-UHFFFAOYSA-N triacetin Chemical compound CC(=O)OCC(OC(C)=O)COC(C)=O URAYPUMNDPQOKB-UHFFFAOYSA-N 0.000 description 4
- 238000009423 ventilation Methods 0.000 description 4
- 230000009977 dual effect Effects 0.000 description 3
- 238000009987 spinning Methods 0.000 description 3
- HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 230000003749 cleanliness Effects 0.000 description 2
- 238000000578 dry spinning Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 235000013773 glyceryl triacetate Nutrition 0.000 description 2
- 239000001087 glyceryl triacetate Substances 0.000 description 2
- 230000000391 smoking effect Effects 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229960002622 triacetin Drugs 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical group CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 1
- IKHGUXGNUITLKF-XPULMUKRSA-N acetaldehyde Chemical compound [14CH]([14CH3])=O IKHGUXGNUITLKF-XPULMUKRSA-N 0.000 description 1
- -1 acetone Chemical compound 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 229930013930 alkaloid Natural products 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000000892 gravimetry Methods 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 210000003734 kidney Anatomy 0.000 description 1
- 238000004811 liquid chromatography Methods 0.000 description 1
- 210000004185 liver Anatomy 0.000 description 1
- 210000004072 lung Anatomy 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical class C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- UUWCBFKLGFQDME-UHFFFAOYSA-N platinum titanium Chemical compound [Ti].[Pt] UUWCBFKLGFQDME-UHFFFAOYSA-N 0.000 description 1
- 239000011550 stock solution Substances 0.000 description 1
- 210000002784 stomach Anatomy 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Cigarettes, Filters, And Manufacturing Of Filters (AREA)
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
(産業上の利用分野)
本発明はたばこ煙のフィルター用セルロース・アセテー
ト繊維に関するもので、詳しくは、セルロース・アセテ
ート繊維にチタン白又はその他の染、顔料を添加してい
ない繊維によって構成することを特徴とするたばこ煙フ
ィルターに関する。Detailed Description of the Invention (Field of Industrial Application) The present invention relates to cellulose acetate fibers for filtering tobacco smoke, and more specifically, the present invention relates to cellulose acetate fibers for filtering tobacco smoke. The present invention relates to a cigarette smoke filter characterized in that it is constructed of non-woven fibers.
(従来の技術及びその問題点)
たばこ煙中には、アセトアルデヒド、ホルムアルデヒド
、アクロレイン等のアルデヒド類、アセトン等のケトン
顛、その他フェノール性化合物等が含まれ、香喫味をさ
またげる原因となっている。(Prior Art and its Problems) Cigarette smoke contains aldehydes such as acetaldehyde, formaldehyde, and acrolein, ketones such as acetone, and other phenolic compounds, which are responsible for disturbing the flavor of tobacco smoke.
また、それ以外にニコチン等のアルカロイド類。In addition, alkaloids such as nicotine.
有機酸、ベンツビレ7等タールと呼ばれる物質が含まれ
、喫煙者の肺、肝臓、腎臓及び胃などに負担をかけ、健
康上好ましくないことは周知の通りである。It is well known that it contains organic acids and a substance called Bentsville 7 grade tar, which puts a burden on smokers' lungs, liver, kidneys, and stomach, and is not good for their health.
従来、たばこ本来の香喫味を損うことなく、これらの有
害成分の除去のために種々の試みがなされている。すな
わち1例えば、セルロースアセテート繊維のトウから製
造されたフィルターやセルロースアセテート繊維のトウ
等を用いて活性炭等のたばこ煙有害物質除去のための添
加剤を含ませて製造したデュアルフィルター、トリプル
フィルター等(第1図に示す)がたばこ煙フィルターと
して用いられている。このたばこ煙フィルター用セルロ
ースアセテート繊維には、チタン白等が0.5〜1.5
wt%添加されている。チタン白添加の理由は、主に
、セルロースアセテート繊維トウを用いたたばこ煙フィ
ルターの喫煙口を白くするためで、これは喫煙者に白さ
による清潔感を与えることで、フィルター付シガレット
の商品価値を高めている。Conventionally, various attempts have been made to remove these harmful components without impairing the original aroma and taste of tobacco. Namely, 1. For example, filters manufactured from cellulose acetate fiber tow, dual filters, triple filters, etc. manufactured using cellulose acetate fiber tow containing additives such as activated carbon for removing harmful substances from tobacco smoke ( (shown in Figure 1) is used as a cigarette smoke filter. This cellulose acetate fiber for cigarette smoke filters contains 0.5 to 1.5 titanium white, etc.
wt% is added. The reason for adding titanium white is mainly to whiten the smoking mouth of cigarette smoke filters that use cellulose acetate fiber tow.This whiteness gives smokers a sense of cleanliness and increases the commercial value of filter cigarettes. is increasing.
しかしながら、チタン白等はセルロースアセテート繊維
に添加することにより、確かに、白さによる清潔感を与
え、その商品価値を高めているが。However, when titanium white is added to cellulose acetate fibers, it certainly gives a sense of cleanliness due to its whiteness and increases its commercial value.
本来のフィル、ターとしての機能すなわち、たばこの香
喫味及び有害成分の除去についての効果は不明確であり
、さらには、第1図に示すデュアルフィルター、トリプ
ルフィルターにおける内部要素の素材としてはチタン白
による白さは必要のないものである。Its original function as a filter, that is, its effect on tobacco flavor and removal of harmful components, is unclear.Furthermore, titanium white is used as the material for the internal elements of the dual filter and triple filter shown in Figure 1. This whiteness is unnecessary.
(問題を解決するための手段)
本発明者等は、上記に鑑み、チタン白等の添加されてい
ないセルロース・アセテート繊維の製造及びそれによる
たばこ煙フィルターを製造し研究した結果、製造工程に
おいては、チタン白等の添加剤がないことにより、濾過
工程の軽減及び繊維ガイド工程の摩擦摩耗の低減に効果
があることを見い出し、さらに、たばこ煙フィルターで
は、チタン白添加フィルターに比べ、そのタール分、ニ
コチン分についての濾過性能は同等であるが、香喫味に
優れていることを見い出し本発明をなすに至った。(Means for Solving the Problem) In view of the above, the inventors of the present invention have conducted research on the production of cellulose acetate fibers to which no titanium white or the like is added, and the tobacco smoke filters made from the same. , found that the absence of additives such as titanium white was effective in reducing the filtration process and the friction and wear in the fiber guide process.Furthermore, cigarette smoke filters have a lower tar content than titanium white-added filters. Although the filtration performance for nicotine content is the same, the present inventors have discovered that the aroma and taste are superior.
本発明に使用するセルロースアセテート繊維は、公知の
方法によシ製造することが出来るが特に含水アセトン溶
液よりの乾式紡糸によシ得られたものカ好ましい。セル
ロースアセテ−tt−含水アセトンに溶解する際チタン
白等の顔料など全添加せずに紡糸溶液を作シ乾式紡糸す
ることによシチタン白の含有しないセルロースアセテー
ト繊維ヲ得ることが出来る。The cellulose acetate fibers used in the present invention can be produced by known methods, but those obtained by dry spinning from a hydrous acetone solution are particularly preferred. When cellulose acetate is dissolved in hydrated acetone, a spinning solution is prepared without adding any pigments such as titanium white, and cellulose acetate fibers containing no titanium white can be obtained by dry spinning.
このようにして得られたチタン白を含有しないセルロー
スアセテート繊維を開繊してバインダーとして例えばト
リアセチンなどを添加して円柱状に巻き上げる方法で作
ることが出来る。又活性炭などの吸着物質を添加したフ
ィルターも同様にして公知の方法で作ることが出来る。The cellulose acetate fibers thus obtained, which do not contain titanium white, are opened, a binder such as triacetin is added thereto, and the fibers are rolled up into a cylindrical shape. Also, a filter to which an adsorbent such as activated carbon is added can be similarly produced by a known method.
例えば、20〜100メツシエの活性炭をチタン白金含
有しないセルロースアセテート繊維にまぶしトウ状にし
たものと別のセルロースアセテート繊維単独部分と組み
合せる方法、lO〜40メツシーの活性炭を2つのセル
ロースアセテートフィルターの間に設けた空間に充填す
る方法などで作ることが出来る。For example, 20 to 100 mesh of activated carbon is sprinkled on cellulose acetate fibers that do not contain titanium platinum and formed into a tow, and combined with another cellulose acetate fiber alone, and 10 to 40 mesh of activated carbon is placed between two cellulose acetate filters. It can be made by filling the space provided in the
(実施例) 以下の実施例によって本発明の詳細な説明する。(Example) The following examples provide a detailed explanation of the invention.
なお、例中において、通気抵抗、−石チン及びタール除
去率は業界で通常用いられているもので、次のような方
法で求めた。In addition, in the examples, the ventilation resistance, the stone removal rate, and the tar removal rate are those commonly used in the industry, and were determined by the following methods.
通気抵抗は17.5 M/秒で通気したときのフィルタ
ー又はフィルター付たばこの抵抗を水柱amで表示した
。The ventilation resistance was expressed as the resistance of the filter or filter-equipped cigarette when aerated at 17.5 M/sec in water column am.
タール除去率およびニコチン除去率はフィルターチップ
をたばこに付けて喫煙した時、フィルターを通過した煙
中及びフィルターに捕捉されたニコチン及びタール量を
夫々液体クロマトグラフィー及び重量法で定量し、その
内フィルターに捕捉されたそれぞれの割合を重量%で示
した。Tar removal rate and nicotine removal rate are determined by attaching a filter tip to a cigarette and smoking, and quantifying the amount of nicotine and tar in the smoke that passed through the filter and captured by the filter using liquid chromatography and gravimetry, respectively. The respective proportions captured in the samples are shown in weight %.
実施例1
セルロースアセテート’tア七トンに溶解し、濾過し、
紡糸原液とする。通常は溶解時にチタンを0.5〜1.
5 wt%添加するが、本発明では添加していないもの
である。このときチタン添加の有無によシ、濾過圧に差
が認められ、チタン添加のない場合にはその濾過工程の
軽減を図ることが可能であった。Example 1 Cellulose acetate was dissolved in acetate, filtered,
Use as spinning stock solution. Usually, 0.5 to 1.0% of titanium is added during melting.
Although 5 wt% is added, it is not added in the present invention. At this time, a difference in filtration pressure was observed depending on whether or not titanium was added, and in the case where titanium was not added, it was possible to reduce the filtration process.
この紡糸原液を用い、単繊維3デニール、総デニール3
6000デニールのチタン白を含まないセルロースアセ
テートトウを製造した。Using this spinning dope, single fiber 3 denier, total denier 3
A 6000 denier titanium white free cellulose acetate tow was produced.
こ(Dチタン白を含まないセルロースアセテートトウを
たばこ用フィルター製造機によシ開懺し、繊維のバイン
ダーとして可塑剤トリアセチンを6重量%添加し、巻取
紙にて円柱状に巻いて得られるプラグ長さ102Xに切
断し、円周24.7%のフィルタープラグを製造した。This plug length is obtained by opening cellulose acetate tow that does not contain D titanium white using a cigarette filter manufacturing machine, adding 6% by weight of the plasticizer triacetin as a fiber binder, and wrapping it into a cylindrical shape with wrapping paper. A filter plug with a circumference of 24.7% was produced by cutting to a size of 102×.
同時に、単繊維3デニール、総デニール36000デニ
ールでチタン白0.5重量%を含むセルロースアセテー
トトウによシ上記と同様にしてフィルタープラグを製造
し、これを比較例とした。At the same time, a filter plug was manufactured in the same manner as above using cellulose acetate tow having a single fiber of 3 denier, a total denier of 36,000 denier, and containing 0.5% by weight of titanium white, and this was used as a comparative example.
フィルターグラブ製造を比較し九ところ、製造時のトウ
毛羽が表−1に示す如く少なくなった。When comparing the manufacturing of filter gloves, it was found that the amount of tow fluff during manufacturing was reduced as shown in Table 1.
表−1
この結果は、チタン白等を含まない場合、セルロースア
セテート繊維の強伸度が向上することと表面平滑性が良
くなり、プラグ製造機における摩擦抵抗の減少によるも
のである。フィルタープラグの製造工程において、毛羽
の減少は製造作業の効率化を図ることができる。Table 1 This result is due to the fact that when titanium white etc. are not included, the strength and elongation of the cellulose acetate fibers are improved, the surface smoothness is improved, and the frictional resistance in the plug manufacturing machine is reduced. In the filter plug manufacturing process, the reduction of fuzz can improve the efficiency of manufacturing operations.
さらに、このフィルタープラグを17〜に切断し、たば
こ煙フィルターとして使用する場合の通気抵抗および繊
維の充填量を測定した。次に、市販たばこ「ロングピー
ス」(商品名)のフィルタ一部分全除去し、その代シに
上記方法で製造したフィルターを装着し、ニコチン、タ
ール除去率の測定、及び香喫味の測定を実施した。表−
2にその結果を示した。この表より明らかな如く、チッ
プの通気抵抗、トウの充填量を同じにすると、ニコチン
及びタールの除去率はほとんど同じであるが、チタン白
を含有しない繊維から製造したたばこ煙フィルター〇香
喫味良好とする人が多かった。Furthermore, this filter plug was cut into pieces of 17 to 17 mm, and the ventilation resistance and fiber filling amount when used as a tobacco smoke filter were measured. Next, a part of the filter of a commercially available cigarette "Long Piece" (trade name) was completely removed, and the filter manufactured by the above method was installed in its place, and the nicotine and tar removal rate and flavor were measured. . Table -
2 shows the results. As is clear from this table, when the airflow resistance of the chip and the filling amount of tow are the same, the removal rate of nicotine and tar is almost the same, but the tobacco smoke filter made from fibers that do not contain titanium white has a good flavor and taste. There were many people who said that.
実施例2
市販たばこ「キャビン」(商品名)のフィルターの内容
要素部(たばこと活性炭顆粒間のセルロースアセテート
部)を除去し、その代りに実施例1において作成したフ
ィルタープラグを用い、同一通気抵抗、同一長さに調整
し几ものを装置し、たばこの香喫味をテストした。その
結果を表−3に示す。表−3から、チタン白を含有しな
いセルロースアセテートよシ製造したたばこ煙フィルタ
ーが香喫味をよくすることが認められる。Example 2 The content element part (cellulose acetate part between the tobacco and activated carbon granules) of the filter of the commercially available cigarette "Cabin" (trade name) was removed, and the filter plug prepared in Example 1 was used instead, and the same ventilation resistance was obtained. We adjusted the length to the same length, set up a precise device, and tested the aroma and taste of cigarettes. The results are shown in Table-3. From Table 3, it is recognized that the cigarette smoke filter made from cellulose acetate that does not contain titanium white improves the aroma and taste.
(発明の効果)
セルロースアセテート繊維から成る之ばこ煙フィルター
においてチタン白を含有しないセルロースアセテート繊
維を使用することによりその製造工程のロスの軽減を図
ることができしかも香喫味に優れたたばこ煙フィルター
が得られた。(Effects of the Invention) A cigarette smoke filter made of cellulose acetate fibers that can reduce losses in the manufacturing process by using cellulose acetate fibers that do not contain titanium white, and that also has an excellent aroma and taste. was gotten.
第1図はたばこフィルターの構成を示す図である。
a・・プレーンフィルター、b・・・デュアルフィルタ
ー、C・・・) IJ fルフィルター、1・・・セル
ロースアセテート、2・・・たばこ、3・・・セルロー
スアセテート繊維と活性炭等をまぶした部分、4・・・
活性炭。FIG. 1 is a diagram showing the structure of a cigarette filter. a...Plain filter, b...Dual filter, C...) IJ filter, 1...Cellulose acetate, 2...Tobacco, 3...Part covered with cellulose acetate fiber and activated carbon, etc. , 4...
activated carbon.
Claims (1)
ターにおいて、該フィルターを構成する繊維にチタン白
を含まない繊維を使用することを特徴とするたばこ煙フ
ィルター。A cigarette smoke filter made of cellulose acetate fibers, characterized in that the fibers constituting the filter do not contain titanium white.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP14517987A JPS63309173A (en) | 1987-06-12 | 1987-06-12 | Tobacco filter |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP14517987A JPS63309173A (en) | 1987-06-12 | 1987-06-12 | Tobacco filter |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS63309173A true JPS63309173A (en) | 1988-12-16 |
Family
ID=15379255
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP14517987A Pending JPS63309173A (en) | 1987-06-12 | 1987-06-12 | Tobacco filter |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS63309173A (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2010514437A (en) * | 2006-12-29 | 2010-05-06 | フィリップ・モーリス・プロダクツ・ソシエテ・アノニム | Smoking article having a concentric hollow core in a tobacco rod and a capsule containing a flavorant and an aerosol former in a filter system |
WO2012090659A1 (en) * | 2010-12-27 | 2012-07-05 | 日本たばこ産業株式会社 | Cigarette filter and cigarette provided with same |
JP2019015009A (en) * | 2017-07-11 | 2019-01-31 | 株式会社ダイセル | Cellulose acetate tow band, and method for manufacturing cellulose acetate tow band |
JP2020007686A (en) * | 2018-07-12 | 2020-01-16 | 株式会社ダイセル | Cellulose acetate fiber, cellulose acetate tow band, and method for manufacturing cellulose acetate tow band |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5238098A (en) * | 1975-09-19 | 1977-03-24 | Daicel Chem Ind Ltd | Cigarette filters |
JPS5272900A (en) * | 1975-12-12 | 1977-06-17 | Daicel Chem Ind Ltd | Tobacco filter |
JPS6098978A (en) * | 1983-11-02 | 1985-06-01 | 三菱レイヨン株式会社 | Production of colored tobacco filter |
JPS60146027A (en) * | 1984-01-05 | 1985-08-01 | 三菱レイヨン株式会社 | Production of cellulose acetate fiber for colored tobacco filter |
-
1987
- 1987-06-12 JP JP14517987A patent/JPS63309173A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5238098A (en) * | 1975-09-19 | 1977-03-24 | Daicel Chem Ind Ltd | Cigarette filters |
JPS5272900A (en) * | 1975-12-12 | 1977-06-17 | Daicel Chem Ind Ltd | Tobacco filter |
JPS6098978A (en) * | 1983-11-02 | 1985-06-01 | 三菱レイヨン株式会社 | Production of colored tobacco filter |
JPS60146027A (en) * | 1984-01-05 | 1985-08-01 | 三菱レイヨン株式会社 | Production of cellulose acetate fiber for colored tobacco filter |
Cited By (8)
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JP2010514437A (en) * | 2006-12-29 | 2010-05-06 | フィリップ・モーリス・プロダクツ・ソシエテ・アノニム | Smoking article having a concentric hollow core in a tobacco rod and a capsule containing a flavorant and an aerosol former in a filter system |
WO2012090659A1 (en) * | 2010-12-27 | 2012-07-05 | 日本たばこ産業株式会社 | Cigarette filter and cigarette provided with same |
JP2019015009A (en) * | 2017-07-11 | 2019-01-31 | 株式会社ダイセル | Cellulose acetate tow band, and method for manufacturing cellulose acetate tow band |
CN110678586A (en) * | 2017-07-11 | 2020-01-10 | 株式会社大赛璐 | Cellulose acetate tow band and method for producing cellulose acetate tow band |
US20200131670A1 (en) * | 2017-07-11 | 2020-04-30 | Daicel Corporation | Cellulose acetate band, and method for producing cellulose acetate band |
KR20220107074A (en) * | 2017-07-11 | 2022-08-01 | 주식회사 다이셀 | Cellulose acetate tow band, and method for producing cellulose acetate tow band |
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JP2020007686A (en) * | 2018-07-12 | 2020-01-16 | 株式会社ダイセル | Cellulose acetate fiber, cellulose acetate tow band, and method for manufacturing cellulose acetate tow band |
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