JPS6058238A - Cleaning method utilizing ultraviolet ray - Google Patents

Cleaning method utilizing ultraviolet ray

Info

Publication number
JPS6058238A
JPS6058238A JP58165149A JP16514983A JPS6058238A JP S6058238 A JPS6058238 A JP S6058238A JP 58165149 A JP58165149 A JP 58165149A JP 16514983 A JP16514983 A JP 16514983A JP S6058238 A JPS6058238 A JP S6058238A
Authority
JP
Japan
Prior art keywords
cleaned
ultraviolet
ultraviolet rays
chamber
vibrators
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP58165149A
Other languages
Japanese (ja)
Other versions
JPS6235811B2 (en
Inventor
Kazuya Tanaka
一也 田中
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ushio Denki KK
Ushio Inc
Original Assignee
Ushio Denki KK
Ushio Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ushio Denki KK, Ushio Inc filed Critical Ushio Denki KK
Priority to JP58165149A priority Critical patent/JPS6058238A/en
Publication of JPS6058238A publication Critical patent/JPS6058238A/en
Publication of JPS6235811B2 publication Critical patent/JPS6235811B2/ja
Granted legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B08CLEANING
    • B08BCLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B7/00Cleaning by methods not provided for in a single other subclass or a single group in this subclass
    • B08B7/0035Cleaning by methods not provided for in a single other subclass or a single group in this subclass by radiant energy, e.g. UV, laser, light beam or the like
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B08CLEANING
    • B08BCLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B7/00Cleaning by methods not provided for in a single other subclass or a single group in this subclass
    • B08B7/0035Cleaning by methods not provided for in a single other subclass or a single group in this subclass by radiant energy, e.g. UV, laser, light beam or the like
    • B08B7/0057Cleaning by methods not provided for in a single other subclass or a single group in this subclass by radiant energy, e.g. UV, laser, light beam or the like by ultraviolet radiation

Landscapes

  • Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
  • Drying Of Semiconductors (AREA)
  • Cleaning Or Drying Semiconductors (AREA)
  • Cleaning In General (AREA)

Abstract

PURPOSE:To make it possible to simultaneously and certainly clean both surfaces of an object to be washed, by forming the support jig of the object to be cleaned irradiated with ultraviolet rays from a material pervious to ultraviolet rays. CONSTITUTION:An ultraviolet lamps 4 with mirrors 5 are provided to the upper and lower parts of the irradiation chamber 3 in the irradiation box 2 mounted in an apparatus case 1 to irradiate the center of the chamber 3 and the upper and under surfaces of the box 2 is cooled by fixed cooling water paths 6. A large number of objects to be cleaned, for example, a quartz vibrators 7 are arranged on a support jig 8 made of quartz and supported at the central part of the chamber 3. O2-containing gas is supplied to the chamber 3 through the sucking orifice 9 of the box 2 to exhaust internal gas from an exhaust orifice 10 along with a contaminant. When the lamps 4 are lighted, both upper and lower surfaces of the vibrators 7 are irradiated with ultraviolet rays and nascent oxygen is formed in the vicinity of said vibrators 7 to decompose a contaminant but, because the support jig 8 is pervious to ultraviolet rays, rays from the lamps 4 are not blocked by said support jig 8. Therefore, the surfaces of the vibrators 7 are uniformly irradiated to be uniformly cleaned.

Description

【発明の詳細な説明】 本発明は紫外線による洗浄方法に関するものである。[Detailed description of the invention] The present invention relates to a cleaning method using ultraviolet rays.

紫外線ラングより発生するオゾンを利用して汚染物を分
解洗浄することが行われているが、この紫外線う/ブ、
例えば低圧水、銀ラングを点灯する線が外部に放出され
、従として185nmの紫外線が、更には他の波長のも
のがわずかに放出される。
Ozone generated by ultraviolet rays is used to decompose and clean pollutants, but this
For example, low-pressure water, a line lighting a silver rung, is emitted to the outside, and as a result, 185 nm ultraviolet light is emitted, as well as a small amount of other wavelengths.

そして、波長185 nmの紫外線によってオゾンが生
成し、次にこのオゾンが波長254nmにより分解され
て発生基の酸素が生成し、この発生基の酸素が有機汚染
物を分解してカス状態で飛散させることが知られている
Then, ozone is generated by ultraviolet light with a wavelength of 185 nm, and then this ozone is decomposed by a wavelength of 254 nm to generate oxygen, which is a generating group, and this oxygen, which is a generating group, decomposes organic pollutants and scatters them in the form of scum. It is known.

この紫外線洗浄方法は各種の被洗浄体に適用されるが、
その一つに水晶振動子がある。水晶振動子はその共鳴周
波数を利用して時間の基準を定めるものであり、いろい
ろな曲品に利用されているが、水晶振動子の表面が汚染
されると共鳴周波数に狂いが生じる。従ってその表面は
7R浄でなければならないが、紫外線で洗浄することに
より高い清浄度が得られ、また、後工程で蒸着される金
用膜の密着性を向上させることができる。
This ultraviolet cleaning method can be applied to various objects to be cleaned.
One of them is a crystal oscillator. Crystal resonators use their resonant frequencies to determine time standards, and are used in a variety of musical pieces, but if the surface of the crystal resonator becomes contaminated, the resonant frequencies will be distorted. Therefore, the surface must be 7R clean, but high cleanliness can be obtained by cleaning with ultraviolet rays, and the adhesion of the gold film deposited in the subsequent process can be improved.

ところで従来は、被洗浄体は金網やステンレス、マn−
5−1−もL″卯射餉ル上4昌1肴り好ft禍、叙り入
古持具で支持さ7していた。この様な支持具で支持され
ていても、紫外線ランプの照射室の上面に設置されC1
被洗浄体の上面のみを洗浄する場合はとくに支障はない
。しかし、被洗浄体の両面を洗浄する必委があるときは
、紫外線ランプが照射室の上面にのみ設置されていると
、−面を洗浄した後に反転して他面を洗浄しなければな
らず、操作が煩雑で、洗浄時間が長くなり、また反転操
作の最中に洗浄の終った一面が他面の汚染物などのため
に再び汚染されるなどの問題点がある。従って、紫外線
ランプを照射室の上下両面や左右両側面に設置して被洗
浄体の両面を同時に照射することが考えられるが、この
場合に支持具が前述の通りの紫外線を透過しない材質か
らなると、支持具をどの様な形状にしても、被洗浄体の
ある部分は支持具によって遮ぎられて紫外線が完全には
照射されず、その部分の洗浄が不完全となる不具合があ
った。
By the way, in the past, the object to be cleaned was wire mesh, stainless steel, or manual cleaning.
5-1- was also supported by an old holder, which was damaged due to the large size of the L'' lamp. C1 installed on the top of the irradiation chamber
There is no particular problem when cleaning only the upper surface of the object to be cleaned. However, when it is necessary to clean both sides of the object to be cleaned, if the ultraviolet lamp is installed only on the top of the irradiation chamber, it is necessary to clean the negative side and then turn over and clean the other side. However, there are problems in that the operation is complicated, the cleaning time is long, and one side that has been cleaned becomes contaminated again due to contaminants on the other side during the reversing operation. Therefore, it is conceivable to install ultraviolet lamps on both the upper and lower sides of the irradiation chamber or on both the left and right sides of the irradiation chamber and irradiate both sides of the object to be cleaned at the same time, but in this case, if the support is made of a material that does not transmit ultraviolet rays, Regardless of the shape of the support, a certain part of the object to be cleaned is blocked by the support and is not completely irradiated with ultraviolet rays, resulting in incomplete cleaning of that part.

そこで本発明は、被洗浄体の両面を確実に洗浄できる紫
外線洗浄方法を提供することを目的とし、その構成は、
紫外線ランプの光でオゾンを発生させ、このオゾンの分
解により生成される発生基の酸素により被洗浄体の表面
に付着する有機汚染物などを分解して洗浄する紫外線洗
浄方法であって、紫外線透過性物質よシなる支持具に支
持された被洗浄体に紫外線を照射する工程を含むことを
特徴とする。
Therefore, an object of the present invention is to provide an ultraviolet cleaning method that can reliably clean both sides of an object to be cleaned, and its configuration is as follows:
This is an ultraviolet cleaning method in which ozone is generated by the light of an ultraviolet lamp, and organic contaminants adhering to the surface of the object to be cleaned are decomposed and cleaned by the generated oxygen generated by the decomposition of this ozone. The method is characterized in that it includes a step of irradiating ultraviolet rays onto an object to be cleaned supported on a support such as a sexual substance.

以下に図面に基いて本発明の一実施例を具体的に説明す
る。
An embodiment of the present invention will be specifically described below based on the drawings.

第1図は本発明の実施例に使用される装置の断面図を示
すが、装置箱1には照射箱2が内蔵されて二重構造をな
し、発生したオゾンが外部に漏洩しないようになってい
る。照射箱2の内部が照射室6であるが、この照射室6
の上方と下方にはそれぞれ紫外線ランプ4としてU字状
の650W高出力低圧水銀灯が2本づつ配設されている
。上下の紫外線ランプ4の背後にはそれぞれミラー5が
配置され、紫外線ランプ4の光は上下両方から照射室5
の中央に向けて照射される。照射箱2の上面と下面には
冷却水路6が固着されて冷却されている。被洗浄体7は
直径7障程度の水晶振動子であり、支持具8上に多数配
列されて照射室6の中央部に支持されるが、支持具8は
石英ガラス製であシ、第2図に示す様に水晶振動子の大
きさに相応する孔8aがあけられ、孔周縁の爪8bによ
って水晶振動子が支持される。支持具8の材質は石英ガ
ラスに限られるものではなく、サファイヤ、テフロン、
LiF、MgFなどの如く紫外線を透過させる性質を有
するものであればよく、形状も図例に限られるものでは
なく、単に板状をなすものでもよい。そして照射箱2の
側方にけ酸素を含むガスを照射室5に供給する吸入孔9
と、内部のガスを分解された汚染物とともに排出する排
気孔10解室で処理された後に大気中に放出される。
FIG. 1 shows a cross-sectional view of a device used in an embodiment of the present invention.A device box 1 has an irradiation box 2 built into it, forming a double structure to prevent generated ozone from leaking outside. ing. The inside of the irradiation box 2 is an irradiation chamber 6;
Two U-shaped 650W high-output low-pressure mercury lamps are disposed above and below as ultraviolet lamps 4, respectively. Mirrors 5 are arranged behind the upper and lower ultraviolet lamps 4, and the light from the ultraviolet lamps 4 enters the irradiation chamber 5 from both the upper and lower sides.
is irradiated towards the center of the Cooling channels 6 are fixed to the upper and lower surfaces of the irradiation box 2 for cooling. The objects to be cleaned 7 are crystal oscillators with a diameter of about 7 mm, and are arranged in large numbers on a support 8 and supported in the center of the irradiation chamber 6.The support 8 is made of quartz glass, and a second As shown in the figure, a hole 8a corresponding to the size of the crystal resonator is drilled, and the crystal resonator is supported by claws 8b at the periphery of the hole. The material of the support 8 is not limited to quartz glass, but may also include sapphire, Teflon,
Any material may be used as long as it has the property of transmitting ultraviolet rays, such as LiF, MgF, etc., and the shape is not limited to that shown in the figure, and may be simply plate-shaped. A suction hole 9 is placed on the side of the irradiation box 2 and supplies gas containing oxygen to the irradiation chamber 5.
Then, the gas inside is discharged into the atmosphere after being processed in an exhaust hole 10 discharging chamber along with decomposed pollutants.

しかして、紫外線ランプ4を点灯すると水晶振動子の上
下両面に紫外線が照射されるが、照射室6内に酸素を含
むガスが供給されているので、発生基の酸素が上下両面
の近傍で生成され、これによって汚染物は分解されるが
、支持具8が紫外線透過性物質でおる石英ガラスよυな
るため、紫外線ランプ4よりの光はこれに遮ぎられるこ
となく、水晶振動子の表面に万遍なく照射されて一様に
洗浄される。従って清浄度は向上し、共鳴周波数はより
正確となるとともに、後工程で蒸−11される金属膜の
密着力も大きくなる。
When the ultraviolet lamp 4 is turned on, the upper and lower surfaces of the crystal resonator are irradiated with ultraviolet rays, but since oxygen-containing gas is supplied to the irradiation chamber 6, the oxygen generating group is generated near the upper and lower surfaces. This decomposes the contaminants, but since the support 8 is made of quartz glass covered with an ultraviolet-transparent material, the light from the ultraviolet lamp 4 is not blocked by it and is transmitted onto the surface of the crystal resonator. It is evenly irradiated and cleaned evenly. Therefore, the cleanliness is improved, the resonant frequency becomes more accurate, and the adhesion of the metal film to be vapor-deposited in a subsequent step is also increased.

そして、被洗浄体Z自体が紫外線透過性の場合は、第6
図〜第6図に示すように、水平ないし傾斜状態で1k1
1隔をあけ、紫外線透過性物質からなる支持具8で支持
してもよく、更には垂直状態に並べて支持してもよい。
If the object to be cleaned Z itself is transparent to ultraviolet rays, the sixth
As shown in Figures to Figure 6, 1k1 in horizontal or inclined condition.
They may be supported by supports 8 made of an ultraviolet-transparent material with one space between them, or they may be arranged vertically and supported.

これらの場合も紫外線が支椋bl a l/ 薔vL 
手+ 7− ? b hど話路a lk 7にIIH1
t、f ’Xれ、一様に洗浄することができる。
In these cases as well, ultraviolet rays are
Hand + 7-? b hd channel a lk 7 to IIH1
t, f'X can be cleaned uniformly.

以上説明した様に、本発明の紫外線洗浄方法は、紫外線
透過性物質よシなる支持具に支持された被洗浄体に紫外
線を照射する工程を含むため、支持具に遮ぎられること
なく紫外線が一様に照射されるので、本発明に従えば、
被洗浄体の両面を確実に洗浄できる紫外線洗浄方法を提
供することができる。
As explained above, the ultraviolet cleaning method of the present invention includes the step of irradiating the object to be cleaned supported by a support such as an ultraviolet-transparent material, so that the ultraviolet rays are not blocked by the support. Since the irradiation is uniform, according to the present invention,
It is possible to provide an ultraviolet cleaning method that can reliably clean both sides of an object to be cleaned.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は本発明の実施例に使用される装置の断面図、第
2図は支持具の要部斜視図、第6図は被洗浄体の支持態
様を示す正面図、第4図は同じく平面図、第5図は他の
支持態様を示す正面図、第6図は同じく平面図である。 1・・・装置箱 2・・・照射箱 5・・・照射室4・
・・紫外線ランプ 5・・・ミラー 6・・・冷却水路
7・・・被洗浄体(水晶振動子) 8・・・支持具9・
・・吸入孔 10・・・排気孔
Figure 1 is a sectional view of the device used in the embodiment of the present invention, Figure 2 is a perspective view of the main parts of the support, Figure 6 is a front view showing how the object to be cleaned is supported, and Figure 4 is the same. A plan view, FIG. 5 is a front view showing another support mode, and FIG. 6 is a plan view. 1... Equipment box 2... Irradiation box 5... Irradiation chamber 4.
...Ultraviolet lamp 5...Mirror 6...Cooling channel 7...Object to be cleaned (crystal oscillator) 8...Support 9.
...Suction hole 10...Exhaust hole

Claims (1)

【特許請求の範囲】[Claims] 紫外線ラングの光でオゾンを発生させ、このオゾンの分
解により生成される発生基の酸素により被洗浄体の表面
に付着する有機汚染物などを分解して洗浄する紫外線洗
浄方法であって、紫外線透過性物質よりなる支持具に支
持された被洗浄体に紫外線を照射する工程を含む紫外線
洗浄方法。
This is an ultraviolet cleaning method in which ozone is generated using ultraviolet light, and organic contaminants adhering to the surface of the object to be cleaned are decomposed and cleaned by the generated radical oxygen generated by the decomposition of this ozone. An ultraviolet cleaning method comprising the step of irradiating an object to be cleaned supported by a support made of a synthetic substance with ultraviolet rays.
JP58165149A 1983-09-09 1983-09-09 Cleaning method utilizing ultraviolet ray Granted JPS6058238A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP58165149A JPS6058238A (en) 1983-09-09 1983-09-09 Cleaning method utilizing ultraviolet ray

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP58165149A JPS6058238A (en) 1983-09-09 1983-09-09 Cleaning method utilizing ultraviolet ray

Publications (2)

Publication Number Publication Date
JPS6058238A true JPS6058238A (en) 1985-04-04
JPS6235811B2 JPS6235811B2 (en) 1987-08-04

Family

ID=15806808

Family Applications (1)

Application Number Title Priority Date Filing Date
JP58165149A Granted JPS6058238A (en) 1983-09-09 1983-09-09 Cleaning method utilizing ultraviolet ray

Country Status (1)

Country Link
JP (1) JPS6058238A (en)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63121A (en) * 1987-06-17 1988-01-05 Wakomu:Kk Vapor washing/drying apparatus
JPS63202921A (en) * 1987-02-18 1988-08-22 Nec Kyushu Ltd Cleaner for semiconductor wafer
EP0661110A1 (en) * 1993-11-26 1995-07-05 Ushiodenki Kabushiki Kaisha Process for oxidation of an article surface
WO1999044760A1 (en) * 1998-03-03 1999-09-10 Applied Materials, Inc. In situ cleaning of the surface inside a vacuum processing chamber
SG96163A1 (en) * 1995-10-30 2003-05-23 Towa Corp Resin sealing/molding apparatus sealing electronic parts
WO2003076086A1 (en) * 2002-03-12 2003-09-18 Carl Zeiss Smt Ag Method and device for the decontamination of optical surfaces
CN104259128A (en) * 2014-08-01 2015-01-07 苏州普京真空技术有限公司 Crystal oscillator wafer cleaning method
CN112718692A (en) * 2020-12-09 2021-04-30 四川富乐德科技发展有限公司 Method for cleaning LiF crystal of OLED crucible part

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109482577A (en) * 2018-12-19 2019-03-19 烟台和锦电子有限公司 A kind of quartz-crystal resonator shell oil removing cleaning device and its application method

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63202921A (en) * 1987-02-18 1988-08-22 Nec Kyushu Ltd Cleaner for semiconductor wafer
JPS63121A (en) * 1987-06-17 1988-01-05 Wakomu:Kk Vapor washing/drying apparatus
EP0661110A1 (en) * 1993-11-26 1995-07-05 Ushiodenki Kabushiki Kaisha Process for oxidation of an article surface
SG96163A1 (en) * 1995-10-30 2003-05-23 Towa Corp Resin sealing/molding apparatus sealing electronic parts
WO1999044760A1 (en) * 1998-03-03 1999-09-10 Applied Materials, Inc. In situ cleaning of the surface inside a vacuum processing chamber
US6098637A (en) * 1998-03-03 2000-08-08 Applied Materials, Inc. In situ cleaning of the surface inside a vacuum processing chamber
WO2003076086A1 (en) * 2002-03-12 2003-09-18 Carl Zeiss Smt Ag Method and device for the decontamination of optical surfaces
CN104259128A (en) * 2014-08-01 2015-01-07 苏州普京真空技术有限公司 Crystal oscillator wafer cleaning method
CN112718692A (en) * 2020-12-09 2021-04-30 四川富乐德科技发展有限公司 Method for cleaning LiF crystal of OLED crucible part

Also Published As

Publication number Publication date
JPS6235811B2 (en) 1987-08-04

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