JPS59184618A - Manufacture of fiber reinforced cylindrical plastics - Google Patents
Manufacture of fiber reinforced cylindrical plasticsInfo
- Publication number
- JPS59184618A JPS59184618A JP58059623A JP5962383A JPS59184618A JP S59184618 A JPS59184618 A JP S59184618A JP 58059623 A JP58059623 A JP 58059623A JP 5962383 A JP5962383 A JP 5962383A JP S59184618 A JPS59184618 A JP S59184618A
- Authority
- JP
- Japan
- Prior art keywords
- fiber
- cloth
- bag
- cylindrical
- laminated body
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
- Moulding By Coating Moulds (AREA)
Abstract
Description
【発明の詳細な説明】 〔技術分野〕 本発明は軽量にし”C強度及び生産性に優れ。[Detailed description of the invention] 〔Technical field〕 The present invention is lightweight and has excellent strength and productivity.
外径が順次変化する繊維強化円筒状プラスチックの製造
方法に関するものである。The present invention relates to a method of manufacturing fiber-reinforced cylindrical plastic whose outer diameter changes sequentially.
外径が順次変化する円筒形状のものであって軽量で且つ
強度が高い構造体の出現が望まれており1代表的な例と
しては交通車輌用のホイールが挙げられる。本発明では
自動車用のディスクホイールを例にして、以下説明を行
う。There is a desire for a structure that is lightweight and has high strength and has a cylindrical shape in which the outer diameter changes sequentially, and a typical example is a wheel for a traffic vehicle. The present invention will be explained below using a disc wheel for an automobile as an example.
繊維強化プラスチツク材で作られたディスクホイールは
軽(1強度が高いという特性を有していることより注目
を集めその技術開発が活発化してきているが、従来開発
されてきたリム部が繊維強化プラスチツク材で作られた
ディスクホイールはスリーピース型ホイールや分割型の
クンナーリムとアウターリムとを結合する方式%式%
その製造方法は次の様である。すなわちマトリックス樹
脂を含浸した一方向引揃えプリプレグシート又は補強用
繊維を平面状及び円形マット状クロスとしたものにマト
リックス樹脂を含浸したプリプレグなリム部形成用金型
に巻き付ける際には、第1図に示す如く上記プリプレグ
(1)を金型にその一端部に切れ目(2)を設け、この
切れ目を重ね合せながら積層したものをリム部形状に成
型し、このものを第2図に示す如(リム部(3)を2つ
合体させ、ディスク(4)にて結合する方法などが行わ
れてきた。Disc wheels made of fiber-reinforced plastic materials have attracted attention due to their light weight (1) and high strength, and the development of their technology has become active. The disc wheel made of plastic material is a three-piece type wheel or a split type wheel that combines a rim and an outer rim.The manufacturing method is as follows: a unidirectionally aligned prepreg sheet impregnated with matrix resin. Alternatively, when winding reinforcing fibers in the form of flat and circular mat-like cloths into a mold for forming a prepreg rim portion impregnated with matrix resin, the prepreg (1) is placed in the mold as shown in Figure 1. A cut (2) is provided at one end, and the stack is formed by overlapping the cuts to form a rim shape. Methods such as (4) combining have been used.
その為、成型が煩雑な工程となると共に、得られるディ
スクホイール製品間の性能のバラツキが大きくなるとい
った欠点があった。As a result, the molding process is complicated, and the performance of the resulting disc wheel products varies widely.
本発明者らは生産性良く、シかも製品性能にバラツキの
生じに(い外径が順次変化する繊維強化円筒状プラスチ
ックであるディスクホイールを得ることを目的に検討を
重ねた結果1本発明に到達したものである。The present inventors conducted repeated studies with the aim of obtaining a disk wheel made of fiber-reinforced cylindrical plastic with good productivity and a variable outer diameter that would avoid variations in product performance.As a result, the present invention was developed. It has been reached.
本発明の要旨とするところは、外径が順次変化する繊維
強化円筒状プラスチックの製造に於て、該円筒の最小外
径と同−若しくは小さい外径を有し、かつ周方向に称し
繊維配向角を有する様にクロス若しくはクロスプリプレ
グを積層した直円筒状積、屠体を該円筒用雌金型に嵌合
し。The gist of the present invention is to produce a fiber-reinforced cylindrical plastic whose outer diameter changes sequentially, which has an outer diameter that is the same as or smaller than the minimum outer diameter of the cylinder, and which has fiber orientation in the circumferential direction. A right cylindrical product made of laminated cloth or cloth prepreg so as to have corners, and a carcass are fitted into the female mold for the cylinder.
更に該直円筒状積層体の内側に、伸縮性を有するバッグ
を装填し、該バッグ内に高圧流体を流入せしめ、該直円
筒状積層体を雌金型に圧着賦型し、成型することを特徴
としている。Furthermore, a stretchable bag is loaded inside the right cylindrical laminate, high-pressure fluid is allowed to flow into the bag, and the right cylindrical laminate is pressed into a female mold and molded. It is a feature.
本発明を実施する際に用いられる1周方向に対し繊維配
向角を有するクロス若しくはクロスプリプレグとはクロ
ス若しくはクロスグリプレグ構成糸が円筒の周方向に対
し斜交して配向角を有するものである。The cloth or cloth prepreg that has a fiber orientation angle with respect to one circumferential direction used in carrying out the present invention is one in which the constituent fibers of the cloth or cloth prepreg have an orientation angle that is diagonal to the circumferential direction of the cylinder.
この場合の配向角とは円筒の周方向に対してクロス若し
くはクロスプリプレグ構成糸がなす角をいう。The orientation angle in this case refers to the angle formed by the cloth or cloth prepreg constituent yarns with respect to the circumferential direction of the cylinder.
配向角を有するクロスを第4図に示す。矢印の方向が周
方向である。この場合の配向角は45°であり、この様
な配向は経緯同密度の織物を使用することによって得ら
れるが、この外スダレ織を任意の角度で裁断することK
より所要の配向角を得ることが出来る。A cross with orientation angles is shown in FIG. The direction of the arrow is the circumferential direction. The orientation angle in this case is 45°, and such orientation can be obtained by using a fabric with the same density as the warp and weave, but it is also possible to cut this outer sudare weave at an arbitrary angle.
A desired orientation angle can be obtained.
配向角を有するクロスは第5図の様な長方形クロスの4
つの角を矢印の方向に引張ることに依り9図の様にシワ
を生ずることなく変形が可能である。この特性を活かせ
は、第3図に示したホイールのリム部を一体化したツー
ピース型ディスクホイールのリムなどの様な複雑な曲面
形状のものを外圧及び張力を加えることに依り目標とす
る形状の金型にそわせ成型することがoJ能である。配
回角は低くなるに従い、クロス若しくはクロスプリプレ
グを構成している経糸と緯糸がより円筒の周方向に沿う
様になり2周方向に於ける強度が向上する。従って配向
角を有jるクロス若しくはクロスグリプレグを利用する
場合は目標とする径及び強度、剛性などが決まれば配向
角、経糸構成、密度、積層パターンの裁断方法を考慮し
、クロス若しくはクロスプリプレグの積層構成を選定−
fることが可能である。A cross with an orientation angle is a rectangular cross 4 as shown in Figure 5.
By pulling the two corners in the direction of the arrow, it can be deformed without causing wrinkles as shown in Figure 9. Taking advantage of this characteristic, it is possible to shape objects with complex curved surfaces, such as the rim of a two-piece disc wheel with an integrated wheel rim shown in Figure 3, into a target shape by applying external pressure and tension. OJ ability is to mold according to the mold. As the distribution angle decreases, the warp and weft yarns constituting the cloth or cloth prepreg become more along the circumferential direction of the cylinder, improving the strength in the two circumferential directions. Therefore, when using cloth or cloth prepreg with an orientation angle, once the target diameter, strength, rigidity, etc. are determined, the orientation angle, warp configuration, density, and cutting method of the laminated pattern should be considered, and the cloth or cloth prepreg should be Select the laminated configuration
It is possible to f.
上記クロス若しくはクロスプリプレグを作るに際して用
いる補強用繊維としては硝子繊維。The reinforcing fiber used in making the cloth or cloth prepreg is glass fiber.
炭素繊維、シリコンカーバイド繊維、アルミナ繊維、ア
ラミツド繊維などの耐熱性で高強度な繊維を1種又は2
種以上併用することができ。One or two types of heat-resistant and high-strength fibers such as carbon fiber, silicon carbide fiber, alumina fiber, aramid fiber, etc.
More than one species can be used together.
目的に依っては熱伝導性の良好な金属繊維を併用するこ
ともできる。Depending on the purpose, metal fibers with good thermal conductivity can also be used in combination.
次に第6図を用いて2本発明の繊維強化円筒状フラスチ
ックの一つであるディスクホイールの製造方法について
さらに詳細に説明する。Next, a method for manufacturing a disk wheel, which is one of the fiber-reinforced cylindrical plastics of the present invention, will be explained in more detail with reference to FIG.
まず、ディスクホイールの必要とする強度。First, the strength required by the disc wheel.
剛性を考慮し、クロスのホイール周方向に対する配向角
、積層構成などを選定し、その後リム部形成円筒用雌金
型(6)の最小径が直円筒状積層体(51の外径に合う
様に該直円筒状積層体を作成する。これをリム部形成円
筒用雌金型(6)の内側に矢印の如く嵌合する。更に該
直円筒状積層体(5)の内側に伸縮性を有するバッグ(
7)を装填する。−その後リム部形成円筒用雌金型(6
)の上下面を蓋(9)で被う。このときバッグ(71に
取り付けである高圧流体導入口(8)を蓋(9)に設け
である挿入孔(10)に通してお(。しかる後、バッグ
(7)内に高圧流体を流入させることに依りバッグ(7
)は膨張し。Considering rigidity, select the orientation angle of the cross in the wheel circumferential direction, the laminated structure, etc., and then make the rim portion forming cylinder so that the minimum diameter of the female mold (6) matches the outer diameter of the right cylindrical laminated body (51). The right cylindrical laminate is created. This is fitted inside the rim portion forming cylinder female mold (6) as shown by the arrow. Furthermore, elasticity is applied to the inside of the right cylindrical laminate (5). Bag with (
7) Load. -Female mold for the cylinder that then forms the rim (6
) with the lid (9). At this time, the high pressure fluid inlet (8) attached to the bag (71) is passed through the insertion hole (10) provided in the lid (9). After that, the high pressure fluid is introduced into the bag (7). Depending on the bag (7
) expands.
直円筒状積層体(5)をリム部形成用雌金型(6)の内
面にしわの発生することなく圧着賦型させることができ
る。この状態で硬化成型まで行う場合はクロスプリプレ
グで直円筒状積層体(5)を作成しておぎ、硬化温度ま
で加熱することに依り行うことができる。この細砂化成
型まで行う方法はいくつか考えられるが1本発明はこれ
らに限定されるものではない。例えばマトリックス樹脂
を含浸した状態でバッグ(7)を用いて圧着賦型したク
ロスプリプレグをリム部形成円筒用雌金型(6)に装着
した状態で取り出し、これを通常のオートクレーブ成型
ないし雄の金型を別に準備しこれに依るプレス成型も可
能である。更にマトリックス樹脂の含浸されていないク
ロスをバッグ(7)を用いていったん賦型したものをリ
ム部形成円筒用金型16+に装着したままの状態で取り
出し、この内側に雄の金型を挿入しマトリックス樹脂を
クロス積層体(5)内に圧入し、加熱することに依り硬
化成型することもできる。The right cylindrical laminate (5) can be pressed and shaped without causing wrinkles on the inner surface of the female mold (6) for forming the rim portion. When performing curing molding in this state, this can be done by creating a right cylindrical laminate (5) from cross prepreg and heating it to the curing temperature. There are several methods that can be considered to carry out this fine sand formation, but the present invention is not limited to these methods. For example, a cloth prepreg impregnated with matrix resin and pressed and molded using a bag (7) is taken out from a female mold (6) for forming a rim part, and then molded in a normal autoclave or molded in a male mold. It is also possible to separately prepare a mold and use it for press molding. Furthermore, the cloth that has not been impregnated with the matrix resin is shaped using the bag (7), and then taken out while still attached to the rim part forming cylinder mold 16+, and a male mold is inserted inside this. It is also possible to harden and mold the matrix resin by press-fitting it into the cross laminate (5) and heating it.
本発明で使用する高圧流体は気体でも液体でも差支えな
いがコスト、扱い易さから空気が最も好ましい。The high-pressure fluid used in the present invention may be either gas or liquid, but air is most preferred in terms of cost and ease of handling.
以下本発明を具体的実施例に基づき説明する。 The present invention will be explained below based on specific examples.
実施例1 第6図に示す様な直円筒状積層体(5)とし℃。Example 1 A right cylindrical laminate (5) as shown in Fig. 6 was prepared at ℃.
炭素繊維の朱子織クロス(目付:400J’/m”夕に
マトリックス樹脂としてエポキシ樹脂を用い炭素繊維と
比較して40体積チになる様に含浸したものを、リム中
央部の落ち込んだ部分の配向角力45° になる様に積
層させたものを用いた。積層枚数は各断面とも15枚と
した。これをリム部形成円筒用雌金型(6)の内側に嵌
合し。A carbon fiber satin weave cloth (wetness: 400 J'/m") was impregnated with epoxy resin as a matrix resin so that it had a volume of 40% compared to carbon fiber. A material was used which was laminated so that the angular force was 45°.The number of laminated sheets was 15 for each cross section.This was fitted inside a female mold (6) for forming a rim portion cylinder.
更にその内側にシリコンゴム製円筒形のゴムバッグ(7
)を装填し、金型上下に蓋(9)を設置し、その後これ
らを硬化炉内に入れゴムバッグ(7)内に4 kf/c
r/L’の圧縮空気を流入させると共に、マトリックス
樹脂の粘度をいったん低下させプリプレグ積層体(5;
を圧着賦型する為に金型温度を40℃1.で60分保持
した後、硬化させる為に18゜℃まで上昇させ60分経
過後、硬化炉内より取り出し、徐冷した後脱型した。Furthermore, inside it is a silicone rubber cylindrical rubber bag (7
), place lids (9) on the top and bottom of the mold, then put them into a curing furnace and put them in a rubber bag (7) at 4 kf/c.
At the same time as compressed air of r/L' is introduced, the viscosity of the matrix resin is once lowered to form a prepreg laminate (5;
In order to press and form the mold, the mold temperature was set to 40℃1. After holding for 60 minutes, the temperature was raised to 18°C for curing. After 60 minutes, the mold was taken out of the curing furnace, slowly cooled, and then demolded.
得られたディスクホイールのリム部は別に作成した炭素
繊維強化プラスチック製のディスクとチタン製ボルトで
締結しディスクホイールを作成した。この様に作成した
ディスクホイールの総重量は4.5 kpであった。更
にチューブ及びタイヤを装着し、チューブ内に6 kt
/crrL”の静水圧を注入して強度テストを行った結
果問題はなかった。The rim portion of the obtained disc wheel was fastened to a carbon fiber reinforced plastic disc prepared separately using titanium bolts to produce a disc wheel. The total weight of the disc wheel thus produced was 4.5 kp. Furthermore, a tube and tire are installed, and 6 kt is placed inside the tube.
A strength test was conducted by injecting a hydrostatic pressure of /crrL'', and no problems were found.
実施例2
第6図に示す様な直円筒状クロス積層体(5)として、
炭素繊維の朱子織クロス(目付:400P/ln’ )
でリム中央部の落ち込んだ部分の配向角が45°
になる様に積層させたものを用いた。Example 2 A right cylindrical cross laminate (5) as shown in FIG.
Carbon fiber satin cloth (Weight: 400P/ln')
The orientation angle of the depressed part in the center of the rim is 45°.
A layered structure was used so that the structure was as follows.
M層枚数は各断面とも15枚とした。これをリム部形成
円筒用雌金型(6)の内側に嵌合し、更にその内側に天
然ゴム製の円筒形バッグ(7)を装填し、該円筒用雌金
型(6)の上下面に蓋(9)を設置し。The number of M layers was 15 for each cross section. This is fitted inside a female mold for forming a rim part (6), and a cylindrical bag (7) made of natural rubber is loaded inside it, and the upper and lower surfaces of the female mold for a cylinder (6) are fitted. Place the lid (9) on the
その後ゴムバッグ(7)内に1 kf/cm”の圧縮空
気を流入させ圧着賦型させた。クロス積層体(5)が装
着された状態でリム部形成用金型(6)を取り出しこの
内側に雄の金型を上下より挿入し、上方の雄型上部に設
けたマトリックス樹脂注入孔より不飽和ポリエステル樹
脂を3 k#/Cfn’の圧力で注入し、金型温度14
0℃×30分で硬化を行い徐冷抜脱型した。Thereafter, compressed air of 1 kf/cm" was flowed into the rubber bag (7) to form the rim. With the cloth laminate (5) attached, the rim forming mold (6) was taken out and the inside of the rubber bag (7) was pressed. Insert the male mold from above and below, inject unsaturated polyester resin at a pressure of 3 k#/Cfn' through the matrix resin injection hole provided in the upper part of the male mold, and bring the mold temperature to 14
Curing was performed at 0° C. for 30 minutes, followed by slow cooling and demolding.
得られたディスクホイールは別に作成した炭素繊維強化
プラスチツク製ディスクとチタン製ボルトで締結しディ
スクホイールを作成した。The obtained disc wheel was connected to a carbon fiber-reinforced plastic disc prepared separately using titanium bolts to produce a disc wheel.
このディスクホイールの総重量は4.5 kyであった
。実施例1と同様6 kf/crrL2の静水圧に依る
強度テストに於ても問題はなかった。The total weight of this disc wheel was 4.5 ky. Similar to Example 1, there were no problems in the strength test using hydrostatic pressure of 6 kf/crrL2.
本発明に依れば従来長時間を要して手作業で実施されて
いた自動車用ディスクホイールの補強繊維の積層作業が
極めて簡単に実施でき、しかもリム部を一体化して製造
でき、更圧切れ目のない連続した補強繊維がリム全体に
十分に配向されているので強度剛性の面でも優れたリム
を有するディスクホイールを得ることに成功したもので
ある。ディスクホイールは本発明の外径が順次質・化す
る繊維強化円筒状プラスチックの一例にすぎないが、他
に自動車のみならずオートハイ、自転車等のディスクホ
イール及び一般工業用の部品等にも適用できる。According to the present invention, the work of laminating reinforcing fibers for automobile disc wheels, which conventionally took a long time and was carried out by hand, can be carried out extremely easily.Moreover, the rim part can be manufactured in one piece, and additional pressure cuts can be made. Since the continuous reinforcing fibers are sufficiently oriented throughout the rim, it has been possible to successfully obtain a disc wheel having a rim that is excellent in terms of strength and rigidity. The disc wheel is just one example of the fiber-reinforced cylindrical plastic whose outer diameter is gradually improved according to the present invention, but it can also be applied not only to automobiles but also to disc wheels for automobiles, automobiles, bicycles, etc., and parts for general industrial use. can.
現在一般的に使用されているアルミニウム鋳造製のディ
スクホイールが約7.4 kp 7輪の重量であるのに
対し1本発明で得られたものは約35係の軽量化が実現
できた。これに依る燃料節約。While the weight of currently commonly used cast aluminum disc wheels is approximately 7.4 kp (7 wheels), the weight of the disc wheels obtained with the present invention has been reduced by approximately 35 parts. This saves fuel.
乗り心地向上、サスペンションの耐久性向上など極めて
広範囲にわたる効果が期待できる。It can be expected to have a wide range of effects, including improved ride comfort and suspension durability.
第1図は従来の分割型ディスクホイールを作る際の状態
図を、第2図はスリーピース型ディスクホイールの断面
図を、第3図は本発明の一例であるディスクホイールの
部分断面図を、第4.5図は本発明の繊維強化円筒状プ
ラスチックを作成する際に用いられる周方向に対し繊維
配向角を有するクロスの平面図を、第6図は本発明の一
例であるディスクホイールのリム部を作成する工程を示
す模式図を各示しだものである。
−+1 圀 脅2図
+ 3 図Fig. 1 is a state diagram when manufacturing a conventional split-type disc wheel, Fig. 2 is a sectional view of a three-piece disc wheel, Fig. 3 is a partial sectional view of a disc wheel that is an example of the present invention, and Fig. 3 is a partial sectional view of a disc wheel that is an example of the present invention. Figure 4.5 is a plan view of a cloth having a fiber orientation angle with respect to the circumferential direction used to create the fiber-reinforced cylindrical plastic of the present invention, and Figure 6 is a plan view of the rim portion of a disc wheel that is an example of the present invention. Each figure shows a schematic diagram showing the process of creating the . -+1 Kuni threat 2 figure + 3 figure
Claims (1)
に於て、該円筒の最小外径と同−若しくは小さい外径を
有し、かつ周方向に対し繊維配向角を有する様にクロス
若しくはクロスプリプレグを積層した直円筒状積層体を
該円筒用雌金型に嵌合し、更に該直円筒状積層体の内側
に、伸縮性を有するバッグを装填し、該バッグ内に高圧
流体を流入せしめ、該直円筒状積層体を雌金型に圧着賦
型l−2成型することを特徴とする外径が順次変化する
繊維強化円筒状プラスチックの製造方法。In the production of fiber-reinforced cylindrical plastics whose outer diameter changes sequentially, cloth or cross prepreg is used so that the outer diameter is the same as or smaller than the minimum outer diameter of the cylinder and the fiber orientation angle is in the circumferential direction. A right cylindrical laminate in which the right cylindrical laminate is laminated is fitted into the cylindrical female mold, a stretchable bag is loaded inside the right cylindrical laminate, and high pressure fluid is allowed to flow into the bag, A method for manufacturing a fiber-reinforced cylindrical plastic whose outer diameter sequentially changes, characterized by press-molding the right cylindrical laminate in a female mold.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP58059623A JPS59184618A (en) | 1983-04-05 | 1983-04-05 | Manufacture of fiber reinforced cylindrical plastics |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP58059623A JPS59184618A (en) | 1983-04-05 | 1983-04-05 | Manufacture of fiber reinforced cylindrical plastics |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS59184618A true JPS59184618A (en) | 1984-10-20 |
JPH0365254B2 JPH0365254B2 (en) | 1991-10-11 |
Family
ID=13118550
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP58059623A Granted JPS59184618A (en) | 1983-04-05 | 1983-04-05 | Manufacture of fiber reinforced cylindrical plastics |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS59184618A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH01197532A (en) * | 1988-01-29 | 1989-08-09 | Toa Nenryo Kogyo Kk | In-situ curing carbon fiber-reinforced soft prepreg and reinforcement of construction with carbon fiber-reinforced plastic sheet |
EP0412588A2 (en) * | 1989-06-30 | 1991-02-13 | Ligustica S.A. | Epoxy prepreg |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS4843066A (en) * | 1971-09-29 | 1973-06-22 | ||
JPS4862570A (en) * | 1971-11-06 | 1973-08-31 | ||
JPS517076A (en) * | 1974-07-09 | 1976-01-21 | Kanagawa Prefecture | |
JPS583828A (en) * | 1981-06-22 | 1983-01-10 | ピエル・ルイジ・ナバ | Concave body of reinforced resin, its manufacture and its manufacturing device |
-
1983
- 1983-04-05 JP JP58059623A patent/JPS59184618A/en active Granted
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS4843066A (en) * | 1971-09-29 | 1973-06-22 | ||
JPS4862570A (en) * | 1971-11-06 | 1973-08-31 | ||
JPS517076A (en) * | 1974-07-09 | 1976-01-21 | Kanagawa Prefecture | |
JPS583828A (en) * | 1981-06-22 | 1983-01-10 | ピエル・ルイジ・ナバ | Concave body of reinforced resin, its manufacture and its manufacturing device |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH01197532A (en) * | 1988-01-29 | 1989-08-09 | Toa Nenryo Kogyo Kk | In-situ curing carbon fiber-reinforced soft prepreg and reinforcement of construction with carbon fiber-reinforced plastic sheet |
EP0412588A2 (en) * | 1989-06-30 | 1991-02-13 | Ligustica S.A. | Epoxy prepreg |
Also Published As
Publication number | Publication date |
---|---|
JPH0365254B2 (en) | 1991-10-11 |
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