JPH09253446A - Method for removing carbon dioxide in gas - Google Patents

Method for removing carbon dioxide in gas

Info

Publication number
JPH09253446A
JPH09253446A JP8062635A JP6263596A JPH09253446A JP H09253446 A JPH09253446 A JP H09253446A JP 8062635 A JP8062635 A JP 8062635A JP 6263596 A JP6263596 A JP 6263596A JP H09253446 A JPH09253446 A JP H09253446A
Authority
JP
Japan
Prior art keywords
gas
aqueous solution
amine compound
absorption
gas containing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP8062635A
Other languages
Japanese (ja)
Other versions
JP3761960B2 (en
Inventor
Hitomi Suzuki
仁美 鈴木
Tomio Mimura
富雄 三村
Kan Iwaki
貫 岩木
Shigeaki Mitsuoka
薫明 光岡
Yuji Tanaka
裕士 田中
Masaki Iijima
正樹 飯島
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kansai Electric Power Co Inc
Mitsubishi Heavy Industries Ltd
Original Assignee
Kansai Electric Power Co Inc
Mitsubishi Heavy Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kansai Electric Power Co Inc, Mitsubishi Heavy Industries Ltd filed Critical Kansai Electric Power Co Inc
Priority to JP06263596A priority Critical patent/JP3761960B2/en
Priority to NO19971133A priority patent/NO319385B1/en
Priority to US08/816,646 priority patent/US5904908A/en
Priority to EP97301767A priority patent/EP0796646B1/en
Priority to CA002200130A priority patent/CA2200130C/en
Priority to DK97301767T priority patent/DK0796646T3/en
Priority to DE69726039T priority patent/DE69726039T2/en
Publication of JPH09253446A publication Critical patent/JPH09253446A/en
Priority to US09/106,267 priority patent/US6051161A/en
Application granted granted Critical
Publication of JP3761960B2 publication Critical patent/JP3761960B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1493—Selection of liquid materials for use as absorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1456—Removing acid components
    • B01D53/1475—Removing carbon dioxide
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/40—Capture or disposal of greenhouse gases of CO2

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Gas Separation By Absorption (AREA)
  • Treating Waste Gases (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Carbon And Carbon Compounds (AREA)

Abstract

PROBLEM TO BE SOLVED: To remove CO2 efficiently from gas containing CO2 by contacting the gas containing CO2 with an aqueous solution containing at least one kind of amine compound which is expressed by a specified formula. SOLUTION: Gas containing CO2 is brought into contact with an aqueous solution containing at least one kind of amine compound expressed by a formula (where, R<1> -R<8> can be the same or different and is hydrogen atom or 1-4 C alkyl group, and m is 0 or 1). As practical examples of the amine compound, 2- aminopropionic amide, 2-amino-2-methyl propionic amide, 3-amino-3-methyl butylic amide, 2-amino-2-methyl-N-methyl propionic amide, etc., are named. The concentration of the aqueous solution of the amine compound to be contacted with the gas containing CO2 is usually about 15-65wt.%, preferably about 30-50wt.%. Moreover, the temperature of the aqueous solution in contact with the gas containing CO2 is usually about 30-70 deg.C.

Description

【発明の詳細な説明】Detailed Description of the Invention

【０００１】[0001]

【産業上の利用分野】本発明は燃焼排ガスなどのＣＯ2
（二酸化炭素）含有ガス中に含まれるＣＯ2を除去する
方法に関し、さらに詳しくは、特定のアミン化合物を含
有する水溶液を用いて、ガス中のＣＯ2 を効率よく除去
する方法に関する。FIELD OF THE INVENTION The present invention relates to CO 2 such as combustion exhaust gas.
The present invention relates to a method for removing CO 2 contained in a (carbon dioxide) -containing gas, and more particularly to a method for efficiently removing CO 2 in a gas using an aqueous solution containing a specific amine compound.

【０００２】[0002]

【従来の技術】従来より天然ガス、合成ガスなどの化学
プラントで製造される各種産業ガスや燃焼排ガスなどの
ガス（処理対象ガス）中に含まれる酸性ガス、特にＣＯ
2 を回収・除去する方法が研究され、種々の方法が提案
されてきた。燃焼排ガスを例にとると、燃焼排ガス中の
ＣＯ2 をアルカノールアミン水溶液等と接触させて除去
し、回収する方法及び回収されたＣＯ2 を大気へ放出す
ることなく貯蔵する方法が精力的に研究されている。2. Description of the Related Art Acidic gas, particularly CO, contained in gases (processing gas) such as various industrial gases and combustion exhaust gas conventionally produced in chemical plants such as natural gas and synthetic gas.
Methods for collecting and removing 2 have been studied, and various methods have been proposed. Taking flue gas as an example, we are vigorously researching how to remove CO 2 in flue gas by contacting it with an alkanolamine aqueous solution, etc., and to collect and store the recovered CO 2 without releasing it to the atmosphere. Has been done.

【０００３】アルカノールアミンとしては、モノエタノ
ールアミン、ジエタノールアミン、トリエタノールアミ
ン、メチルジエタノールアミン、ジイソプロパノールア
ミン、ジグリコールアミンなどを挙げることができる
が、通常モノエタノールアミン（ＭＥＡ）が好んで用い
られる。しかし、ＭＥＡに代表される上記のようなアル
カノールアミン水溶液を燃焼排ガスなどのガス中のＣＯ
2 を吸収・除去する吸収剤として用いても、所定濃度の
アミン水溶液の所定量当たりのＣＯ2 の吸収量、所定濃
度のアミン水溶液の単位アミンモル当たりのＣＯ2 の吸
収量、所定濃度におけるＣＯ2 の吸収速度、さらには吸
収後のアルカノールアミン水溶液の再生に要する熱エネ
ルギなどに照らして、必ずしも満足のできるものではな
い。Examples of the alkanolamine include monoethanolamine, diethanolamine, triethanolamine, methyldiethanolamine, diisopropanolamine, diglycolamine and the like. Usually, monoethanolamine (MEA) is preferably used. However, the above-mentioned alkanolamine aqueous solution represented by MEA is used to remove CO in gas such as combustion exhaust gas.
Be used as an absorbent for absorbing and removing 2, absorption of CO 2 per predetermined amount of the aqueous amine solution having a predetermined concentration, the amount of absorption of CO 2 per unit amine molar amine aqueous solution having a predetermined concentration, CO at a given concentration of 2 It is not always satisfactory in light of the absorption rate of the above, and further the thermal energy required for the regeneration of the aqueous alkanolamine solution after absorption.

【０００４】ところで、各種混合ガスからアミン化合物
を用いて酸性ガスを分離する技術は数多く知られてお
り、例えば次のようなものがある。特開昭５３−１００
１８０号公報には、（１）環の一部分であって、かつ第
二炭素原子もしくは第三炭素原子のどちらかに結合され
た少なくとも１個の第二アミノ基、または第三炭素原子
に結合された第一アミノ基を含有する立体障害アミン少
なくとも５０モル％と第三アミノアルコール少なくとも
約１０モル％とよりなるアミン混合物及び（２）酸性ガ
スに対する物理的吸収剤である前記アミン混合物用の溶
媒からなるアミン−溶媒液体吸収剤に通常ガス状の混合
物を接触させることからなる酸性ガスの除去法が記載さ
れている。立体障害アミンとしては２−ピペリジンエタ
ノール〔２−（２−ヒドロキシエチル）−ピペリジン〕
及び３−アミノ−３−メチル−１−ブタノールなどが、
また溶媒としては２５重量％までの水を含んでもよいス
ルホキシド化合物などが、さらに処理ガスの例としては
「高濃度の二酸化炭素及び硫化水素、例えば３５％のＣ
Ｏ2 及び１０〜１２％のＨ2 Ｓを有する通常ガス状の混
合物」が例示され、また実施例にはＣＯ2 そのものが使
用されている。By the way, there are many known techniques for separating an acidic gas from various mixed gases using an amine compound, and there are the following techniques, for example. JP-A-53-100
No. 180, (1) at least one secondary amino group which is part of a ring and is bound to either a secondary carbon atom or a tertiary carbon atom, or to a tertiary carbon atom. An amine mixture comprising at least 50 mol% of a sterically hindered amine containing a primary amino group and at least about 10 mol% of a tertiary amino alcohol, and (2) a solvent for said amine mixture which is a physical absorbent for acid gases. A method for the removal of acid gases is described which comprises contacting the amine-solvent liquid absorbent with a normally gaseous mixture. As the sterically hindered amine, 2-piperidine ethanol [2- (2-hydroxyethyl) -piperidine]
And 3-amino-3-methyl-1-butanol and the like,
Further, the solvent may be a sulfoxide compound which may contain up to 25% by weight of water, and an example of the processing gas may be “high concentration carbon dioxide and hydrogen sulfide, for example 35% C.
O normally gaseous mixture with 2 and 10 to 12% of H 2 S "is illustrated, also in the embodiment CO 2 itself is used.

【０００５】特開昭６１−７１８１９号公報には、立体
障害アミン及びスルホランなどの非水溶媒を含む酸性ガ
ススクラッピング用組成物が記載されている。また本公
報にはＣＯ2 の吸収に対し、立体障害アミンの有利性を
反応式を用いて説明している。JP-A-61-71819 describes a composition for acidic gas scraping containing a sterically hindered amine and a non-aqueous solvent such as sulfolane. Further, this publication describes the advantage of sterically hindered amines with respect to CO 2 absorption by using a reaction formula.

【０００６】ケミカルエンジニアリングサイエンス（ C
hemical Engineering Science ) ，４１巻，４号，９９
７〜１００３頁には、ヒンダードアミンである２−アミ
ノ−２−メチル−１−プロパノール（ＡＭＰ）水溶液の
炭酸ガス吸収挙動が開示されている。吸収させるガスと
しては大気圧のＣＯ2 及びＣＯ2 と窒素との混合物が用
いられている。Chemical Engineering Science (C
hemical Engineering Science), 41, No. 4, 99
Pages 7 to 1003 disclose carbon dioxide absorption behavior of an aqueous solution of 2-amino-2-methyl-1-propanol (AMP) which is a hindered amine. As the gas to be absorbed, CO 2 at atmospheric pressure and a mixture of CO 2 and nitrogen are used.

【０００７】ケミカルエンジニアリングサイエンス（ C
hemical Engineering Science ) ，４１巻，２号，４０
５〜４０８頁には、常温付近において、ＡＭＰのような
ヒンダードアミンとＭＥＡのような直鎖アミンの各水溶
液のＣＯ2 やＨ2 Ｓに対する吸収速度が報告されてい
る。Chemical Engineering Science (C
hemical Engineering Science), 41, No. 2, 40
On pages 5 to 408, absorption rates of CO 2 and H 2 S of aqueous solutions of hindered amines such as AMP and linear amines such as MEA are reported near room temperature.

【０００８】米国特許３，６２２，２６７号明細書には
メチルジエタノールアミン及びモノエチルモノエタノー
ルアミンを含有する水性混合物を用い、原油などの部分
酸化ガスなどの合成ガスに含まれる高分圧のＣＯ2 、例
えば４０気圧の３０％ＣＯ2含有合成ガスを精製する技
術が開示されている。US Pat. No. 3,622,267 uses an aqueous mixture containing methyldiethanolamine and monoethylmonoethanolamine and has a high partial pressure of CO 2 contained in a synthesis gas such as a partial oxidizing gas such as crude oil. , For example, a technique for purifying a syngas containing 30% CO 2 at 40 atm is disclosed.

【０００９】ドイツ公開特許１，５４２，４１５号公報
にはＣＯ2 、Ｈ2 Ｓ、ＣＯＳの吸収速度の向上のためモ
ノアルキルアルカノールアミンなどを物理または化学吸
収剤に添加する技術が開示されている。同様にドイツ公
開特許１，９０４，４２８号公報には、モノメチルエタ
ノールアミンがメチルジエタノールアミンの吸収速度を
向上させる目的で添加される技術が開示されている。German Laid-Open Patent 1,542,415 discloses a technique of adding a monoalkylalkanolamine or the like to a physical or chemical absorbent in order to improve the absorption rate of CO 2 , H 2 S and COS. . Similarly, DE-A-1,904,428 discloses a technique in which monomethylethanolamine is added for the purpose of improving the absorption rate of methyldiethanolamine.

【００１０】米国特許４，３３６，２３３号明細書に
は、天然ガス、合成ガス、ガス化石炭ガスの精製にピペ
ラジンの０．８１〜１．３モル／リットル水溶液が洗浄
液として、またピペラジンがメチルジエタノールアミ
ン、トリエタノールアミン、ジエタノールアミン、モノ
メチルエタノールアミンなどの溶媒と共に水溶液で洗浄
液として使用される技術が開示されている。In US Pat. No. 4,336,233, 0.81 to 1.3 mol / liter aqueous solution of piperazine is used as a cleaning liquid for the purification of natural gas, synthetic gas and gasified coal gas, and piperazine is methyl. A technique is disclosed in which an aqueous solution is used as a cleaning liquid together with a solvent such as diethanolamine, triethanolamine, diethanolamine, and monomethylethanolamine.

【００１１】同様に特開昭５２−６３１７１号公報に
は、第三級アルカノールアミン、モノアルキルアルカノ
ールアミンなどにピペラジンまたはヒドロキシエチルピ
ペラジンなどのピペラジン誘導体を促進剤として加えた
ＣＯ2 吸収剤が開示されている。Similarly, JP-A-52-63171 discloses a CO 2 absorbent obtained by adding a piperazine or a derivative of piperazine such as hydroxyethylpiperazine to tertiary alkanolamine, monoalkylalkanolamine and the like. ing.

【００１２】[0012]

【発明が解決しようとする課題】前述のように各種ＣＯ
2 含有ガスからＣＯ2 を効率よく除去する方法が望まれ
ている。特に、一定濃度のＣＯ2 吸収剤（アミン化合
物）を含む水溶液でガスを処理する場合、吸収剤単位モ
ル当たりのＣＯ2 吸収量、水溶液の単位体積当たりのＣ
Ｏ2 の吸収量及び吸収速度の大きい吸収剤を選択するこ
とが当面の大きな課題である。さらにはＣＯ2 の吸収
後、ＣＯ2 を分離し、吸収液を再生させる際に必要な熱
エネルギの少ない吸収剤が望まれる。一種類のアミン化
合物のみの使用ではこれらの全ての望ましい要件を満た
すことは困難であるとしても、幾つかの要件を満足する
化合物が見出されれば、他のアミン化合物との混合等に
より更に好ましい要件に近づける可能性もある。したが
って、例えば吸収剤単位モル当たりのＣＯ2 吸収量が大
きいものであければ吸収速度等は別途改善される可能性
がある。As mentioned above, various CO
A method for efficiently removing CO 2 from a 2- containing gas has been desired. In particular, when the gas is treated with an aqueous solution containing a constant concentration of CO 2 absorbent (amine compound), the amount of CO 2 absorbed per unit mole of the absorbent and the C per unit volume of the aqueous solution.
A major problem for the time being is to select an absorbent having a large absorption amount and absorption rate of O 2 . Further, after absorbing CO 2, an absorbent that separates CO 2 and regenerates the absorbing liquid requires less heat energy is desired. Although it is difficult to satisfy all of these desirable requirements by using only one kind of amine compound, if a compound satisfying some requirements is found, more preferable requirements such as mixing with other amine compounds are required. There is also a possibility to approach. Therefore, for example, if the CO 2 absorption amount per unit mol of the absorbent is large, the absorption rate and the like may be improved separately.

【００１３】本発明はこのような従来技術の実状に鑑
み、吸収剤単位モル当たりのＣＯ2 吸収量が大きいうえ
に吸収したＣＯ2 を容易に放出する特性を備えた新規な
アミン化合物を用いた、効率のよいＣＯ2 含有ガスから
のＣＯ2 除去方法を提供することを目的とする。In view of the above-mentioned state of the art, the present invention uses a novel amine compound having a large amount of CO 2 absorbed per mol of the absorbent and having a characteristic of easily releasing the absorbed CO 2 . Another object of the present invention is to provide an efficient method for removing CO 2 from a CO 2 -containing gas.

【００１４】[0014]

【課題を解決するための手段】本発明者らは前記課題を
解決すべく、燃焼排ガス中のＣＯ2 を除去に用いられる
吸収剤について鋭意検討した結果、特定のアミン化合物
の水溶液がＣＯ2 吸収能力が大きく、しかもＣＯ2 の脱
離が容易であることを見出し、本発明を完成した。すな
わち、本発明は次の（１）乃至（４）の態様を有するも
のである。In order to solve the above problems, the inventors of the present invention have made extensive studies on an absorbent used for removing CO 2 in combustion exhaust gas. As a result, an aqueous solution of a specific amine compound absorbs CO 2 The present inventors have completed the present invention by finding that they have a large capacity and that CO 2 is easily desorbed. That is, the present invention has the following aspects (1) to (4).

【００１５】（１）ＣＯ2 を含有するガスを下記一般式
〔１〕で表されるアミン化合物の１種以上を含有する水
溶液に接触させることを特徴とするガス中のＣＯ2 の除
去方法である。(1) A method for removing CO 2 from a gas, which comprises contacting a gas containing CO 2 with an aqueous solution containing at least one amine compound represented by the following general formula [1]: is there.

【化２】 （式中、Ｒ1 〜Ｒ8 は、それぞれ同一でも異なっていて
もよい水素原子又は炭素数１〜４のアルキル基を表し、
ｍは０又は１を表す。）Embedded image (In the formula, R 1 to R 8 each represent a hydrogen atom which may be the same or different, or an alkyl group having 1 to 4 carbon atoms,
m represents 0 or 1. )

【００１６】（２）ＣＯ2 を含有するガスを一般式
〔１〕で表されるアミン化合物の１種以上及びＣＯ2 吸
収能力の大きい他のアミン化合物の１種以上を含有する
水溶液に接触させることを特徴とするガス中のＣＯ2 の
除去方法。(2) Contacting a gas containing CO 2 with an aqueous solution containing at least one amine compound represented by the general formula [1] and at least one other amine compound having a large CO 2 absorption capacity. A method for removing CO 2 in a gas, comprising:

【００１７】（３）前記水溶液中の一般式〔１〕で表さ
れるアミン化合物の濃度が１５〜６５重量％の範囲であ
ることを特徴とする前記（１）又は（２）のガス中のＣ
Ｏ2 の除去方法。 （４）前記ＣＯ2 を含有するガスが大気圧下の燃焼排ガ
スであることを特徴とする前記（１）〜（３）のいずれ
かのガス中のＣＯ2 の除去方法。(3) In the gas of the above (1) or (2), the concentration of the amine compound represented by the general formula [1] in the aqueous solution is in the range of 15 to 65% by weight. C
O 2 removal method. (4) The method for removing CO 2 from the gas according to any one of (1) to (3), wherein the gas containing CO 2 is combustion exhaust gas under atmospheric pressure.

【００１８】[0018]

【発明の実施の形態】本発明で用いられる一般式〔１〕
で表されるアミン化合物において、Ｒ1 〜Ｒ 8 は、それ
ぞれ同一でも異なっていてもよい水素原子又は炭素数１
〜４のアルキル基を表し、炭素数１〜４のアルキル基と
してはメチル基、エチル基、プロピル基、イソプロピル
基、ブチル基、イソブチル基、ｓｅｃ−ブチル基、ｔｅ
ｒｔ−ブチル基を例示することができる。中でもＲ1 ＋
Ｒ2 ，Ｒ5 ＋Ｒ6 のそれぞれの炭素数の合計が４以下で
あり、Ｒ3 ＋Ｒ4 ，Ｒ7 ＋Ｒ8 のそれぞれの炭素数の合
計が２以下であるような組み合わせが好ましい。一般式
〔１〕で表されるアミン化合物は各々単独で用いられる
ほか、２種以上を混合して用いることも可能である。BEST MODE FOR CARRYING OUT THE INVENTION General formula [1] used in the present invention
In the amine compound represented by1~ R 8Is it
Hydrogen atom or carbon number 1 which may be the same or different
Represents an alkyl group having 1 to 4 carbon atoms and an alkyl group having 1 to 4 carbon atoms.
Is methyl, ethyl, propyl, isopropyl
Group, butyl group, isobutyl group, sec-butyl group, te
An example is an rt-butyl group. Above all R1+
RTwo, RFive+ R6The total carbon number of each is 4 or less
Yes, RThree+ RFour, R7+ R8The sum of the carbon numbers of
A combination having a total of 2 or less is preferable. General formula
The amine compound represented by [1] is used alone
Besides, it is also possible to use a mixture of two or more kinds.

【００１９】一般式〔１〕で表されるアミン化合物の具
体的例としては、２−アミノプロピオンアミド〔Ｈ2 Ｎ
ＣＨ（ＣＨ3 ）ＣＯＮＨ2 〕、２−アミノ−２−メチル
プロピオンアミド〔Ｈ2 ＮＣ（ＣＨ3 ）2 ＣＯＮ
Ｈ2 〕、３−アミノ−３−メチルブチルアミド〔Ｈ2 Ｎ
Ｃ（ＣＨ3 ）2 ＣＨ2 ＣＯＮＨ2 〕、２−アミノ−２−
メチル−Ｎ−メチルプロピオンアミド〔Ｈ2 ＮＣ（ＣＨ
3 ）2 ＣＯＮＨ（ＣＨ3 ）〕、３−アミノ−３−メチル
−Ｎ−メチルブチルアミド〔Ｈ2 ＮＣ（ＣＨ3 ）2 ＣＨ
2 ＣＯＮＨ（ＣＨ3 ）〕、３−アミノ−３−メチル−
Ｎ，Ｎ−ジメチルブチルアミド〔Ｈ2 ＮＣ（ＣＨ3 ）2
ＣＨ2 ＣＯＮ（ＣＨ3 ）2 〕、２−エチルアミノアセト
アミド〔（Ｈ5 Ｃ2 ）ＮＨＣＨ2 ＣＯＮＨ2 〕、２−
（ｔ−ブチルアミノ）アセトアミド〔（ｔｅｒｔ−Ｈ9
Ｃ4 ）ＮＨＣＨ2 ＣＯＮＨ2 〕、２−ジメチルアミノ−
Ｎ，Ｎ−ジメチルアセトアミド〔（ＣＨ3 ）2 ＮＣＨ2
ＣＯＮ（ＣＨ 3 ）2 〕、２−エチルアミノ−２−メチル
プロピオンアミド〔（Ｈ5 Ｃ2 ）ＮＨＣ（ＣＨ3 ）2 Ｃ
ＯＮＨ2 〕、３−エチルアミノプロピオンアミド〔（Ｈ
5 Ｃ2）ＮＨＣＨ2 ＣＨ2 ＣＯＮＨ2 〕、３−エチルア
ミノブチルアミド〔（Ｈ5 Ｃ2）ＮＨＣＨ（ＣＨ3 ）Ｃ
Ｈ2 ＣＯＮＨ2 〕、３−エチルアミノ−３−メチルブチ
ルアミド〔（Ｈ5 Ｃ2 ）ＮＨＣ（ＣＨ3 ）2 ＣＨ2 ＣＯ
ＮＨ2 〕、２−ジエチルアミノアセトアミド〔（Ｈ5 Ｃ
2 ）2 ＮＣＨ2 ＣＯＮＨ2 〕、２−ジエチルアミノプロ
ピオンアミド〔（Ｈ5 Ｃ2 ）2 ＮＣＨ（ＣＨ3 ）ＣＯＮ
Ｈ2 〕、２−ジエチルアミノ−２−メチルプロピオンア
ミド〔（Ｈ5 Ｃ2 ）2 ＮＣ（ＣＨ3 ）2 ＣＯＮＨ2 〕、
３−ジエチルアミノ−３−メチルブチルアミド〔（Ｈ5
Ｃ2 ）2 ＮＣ（ＣＨ3 ）2 ＣＨ2 ＣＯＮＨ2 〕などが挙
げられる。Component of amine compound represented by the general formula [1]
As a physical example, 2-aminopropionamide [HTwoN
CH (CHThree) CONHTwo], 2-amino-2-methyl
Propionamide [HTwoNC (CHThree)TwoCON
HTwo], 3-amino-3-methylbutyramide [HTwoN
C (CHThree)TwoCHTwoCONHTwo], 2-amino-2-
Methyl-N-methylpropionamide [HTwoNC (CH
Three)TwoCONH (CHThree)], 3-amino-3-methyl
-N-methylbutyramide [HTwoNC (CHThree)TwoCH
TwoCONH (CHThree)], 3-amino-3-methyl-
N, N-dimethylbutyramide [HTwoNC (CHThree)Two
CHTwoCON (CHThree)Two], 2-ethylaminoaceto
Amide [(HFiveCTwo) NHCHTwoCONHTwo], 2-
(T-Butylamino) acetamide [(tert-H9
CFour) NHCHTwoCONHTwo], 2-dimethylamino-
N, N-dimethylacetamide [(CHThree)TwoNCHTwo
CON (CH Three)Two], 2-ethylamino-2-methyl
Propionamide [(HFiveCTwo) NHC (CHThree)TwoC
ONHTwo], 3-ethylaminopropionamide [(H
FiveCTwo) NHCHTwoCHTwoCONHTwo], 3-ethyla
Minobutyramide [(HFiveCTwo) NHCH (CHThree) C
HTwoCONHTwo], 3-ethylamino-3-methylbuty
Lamide [(HFiveCTwo) NHC (CHThree)TwoCHTwoCO
NHTwo], 2-diethylaminoacetamide [(HFiveC
Two)TwoNCHTwoCONHTwo], 2-diethylaminopro
Pionamide [(HFiveCTwo)TwoNCH (CHThree) CON
HTwo], 2-diethylamino-2-methylpropiona
Mid [[HFiveCTwo)TwoNC (CHThree)TwoCONHTwo],
3-diethylamino-3-methylbutyramide [(HFive
CTwo)TwoNC (CHThree)TwoCHTwoCONHTwo] And so on
I can do it.

【００２０】本発明のＣＯ2 含有ガスとの接触に用いる
前記アミン化合物の水溶液（以下、吸収液とも称す）の
濃度は通常１５〜６５重量％、好ましくは３０〜５０重
量％である。また、ＣＯ2 含有ガスとの接触時の吸収液
の温度は通常３０〜７０℃の範囲である。また本発明で
用いる吸収液には、必要に応じて腐蝕防止剤、劣化防止
剤などが加えられる。The concentration of the aqueous solution of the amine compound (hereinafter, also referred to as absorbing solution) used for the contact with the CO 2 -containing gas of the present invention is usually 15 to 65% by weight, preferably 30 to 50% by weight. The temperature of the absorbing liquid at the time of contact with the CO 2 -containing gas is usually in the range of 30 to 70 ° C. In addition, a corrosion inhibitor, a deterioration inhibitor, etc. may be added to the absorbent used in the present invention, if necessary.

【００２１】更に吸収液のＣＯ2 吸収量や吸収速度など
のＣＯ2 吸収能力を増すために、前記一般式〔１〕で表
されるアミン化合物に加えて他のＣＯ2 吸収能力の大き
いアミン化合物の１種又は２種以上を混合して用いても
よい。ここで使用する他のアミン化合物の好ましい例と
してはモノエタノールアミン、２−メチルアミノエタノ
−ル、２−エチルアミノエタノ−ル、２−イソプロピル
アミノエタノール、２−ｎ−ブチルアミノエタノ−ル、
ピペラジン、２−メチルピペラジン、２，５−ジメチル
ピペラジン、ピペリジン、２−ピペリジンエタノールな
どを挙げることができる。これらの他のアミン化合物を
使用するときは、これらが一般式〔１〕のアミン化合物
と共に水に可溶である限り、これら他のアミン化合物の
単独の濃度が通常１．５〜５０重量％の範囲、好ましく
は５〜４０重量％の範囲である。In addition to the amine compound represented by the above general formula [1], other amine compounds having a large CO 2 absorption capacity in order to further increase the CO 2 absorption capacity such as CO 2 absorption amount and absorption rate of the absorbing liquid. 1 type or 2 types or more may be mixed and used. Preferable examples of the other amine compound used here include monoethanolamine, 2-methylaminoethanol, 2-ethylaminoethanol, 2-isopropylaminoethanol, 2-n-butylaminoethanol,
Examples thereof include piperazine, 2-methylpiperazine, 2,5-dimethylpiperazine, piperidine, 2-piperidine ethanol and the like. When these other amine compounds are used, the concentration of these other amine compounds alone is usually 1.5 to 50% by weight, as long as they are soluble in water together with the amine compound of the general formula [1]. The range is preferably 5 to 40% by weight.

【００２２】本発明における処理対象ガスとしては天然
ガス、合成ガスなどの化学プラントで製造される各種産
業ガス、燃焼排ガスなどが挙げられるが、特に大気圧下
のガス、取りわけ大気圧下の燃焼排ガスに好適に適用で
きる。なお、本発明における大気圧下とは、燃焼排ガス
を供給するためブロワなどを作用させる程度の大気圧近
傍の圧力範囲は含まれるものである。Examples of the gas to be treated in the present invention include various industrial gases such as natural gas and synthetic gas produced in chemical plants, combustion exhaust gas, and the like. Particularly, gas under atmospheric pressure, especially combustion under atmospheric pressure It can be suitably applied to exhaust gas. The term "atmospheric pressure" in the present invention includes a pressure range in the vicinity of atmospheric pressure at which a blower or the like acts to supply combustion exhaust gas.

【００２３】以下、燃焼排ガスを処理対象ガスとする場
合を例にとって本発明を説明する。本発明の方法により
燃焼排ガス中のＣＯ2 を除去する際に採用できるプロセ
スは特に限定されないが、その１例について図１によっ
て説明する。図１では主要設備のみ示し、付属設備は省
略した。図１において、１は脱ＣＯ2 塔、２は下部充填
部、３は上部充填部またはトレイ、４は脱ＣＯ2 塔燃焼
排ガス供給口、５は脱ＣＯ2 燃焼排ガス排出口、６は吸
収液供給口、７はノズル、８は必要に応じて設けられる
燃焼排ガス冷却器、９はノズル、１０は充填部、１１は
加湿冷却水循環ポンプ、１２は補給水供給ライン、１３
はＣＯ2 を吸収した吸収液排出ポンプ、１４は熱交換
器、１５は吸収液再生（以下、「再生」とも略称）塔、
１６はノズル、１７は下部充填部、１８は再生加熱器
（リボイラ）、１９は上部充填部、２０は還流水ポン
プ、２１はＣＯ2分離器、２２は回収ＣＯ2 排出ライ
ン、２３は再生塔還流冷却器、２４はノズル、２５は再
生塔還流水供給ライン、２６は燃焼排ガス供給ブロワ、
２７は冷却器である。The present invention will be described below with reference to the case where combustion exhaust gas is used as the gas to be treated. The process that can be used for removing CO 2 in the combustion exhaust gas by the method of the present invention is not particularly limited, but one example thereof will be described with reference to FIG. In FIG. 1, only the main equipment is shown, and the auxiliary equipment is omitted. In FIG. 1, 1 is a CO 2 removal tower, 2 is a lower packing section, 3 is an upper packing section or tray, 4 is a CO 2 removal tower combustion exhaust gas supply port, 5 is a CO 2 removal exhaust gas exhaust port, and 6 is an absorption liquid. Supply port, 7 is a nozzle, 8 is a combustion exhaust gas cooler provided as needed, 9 is a nozzle, 10 is a filling part, 11 is a humidification cooling water circulation pump, 12 is a makeup water supply line, 13
Is an absorption liquid discharge pump that has absorbed CO 2 , 14 is a heat exchanger, 15 is an absorption liquid regeneration (hereinafter also referred to as “regeneration”) column,
16 is a nozzle, 17 is a lower filling part, 18 is a regenerative heater (reboiler), 19 is an upper filling part, 20 is a reflux water pump, 21 is a CO 2 separator, 22 is a recovered CO 2 discharge line, and 23 is a regeneration tower. A reflux condenser, 24 a nozzle, 25 a regeneration tower reflux water supply line, 26 a combustion exhaust gas supply blower,
27 is a cooler.

【００２４】図１において、燃焼排ガスは燃焼排ガス供
給ブロワ２６により燃焼排ガス冷却器８に押込められ、
ノズル９からの加湿冷却水と充填部１０で接触し、加湿
冷却され、脱ＣＯ2 塔燃焼排ガス供給口４を通って脱Ｃ
Ｏ2 塔１へ導かれる。燃焼排ガスと接触した加湿冷却水
は燃焼排ガス冷却器８の下部に溜り、ポンプ１１により
ノズル９へ循環使用される。加湿冷却水は燃焼排ガスを
加湿冷却することにより徐々に失われるので、補給水供
給ライン１２により補充される。In FIG. 1, the combustion exhaust gas is pushed into the combustion exhaust gas cooler 8 by the combustion exhaust gas supply blower 26,
The humidified cooling water from the nozzle 9 comes into contact with the filling section 10, is humidified and cooled, and is decarbonized through the CO 2 tower combustion exhaust gas supply port 4.
It is led to the O 2 tower 1. The humidified cooling water that has come into contact with the combustion exhaust gas collects in the lower part of the combustion exhaust gas cooler 8 and is circulated to the nozzle 9 by the pump 11. Since the humidified cooling water is gradually lost by humidifying and cooling the combustion exhaust gas, it is replenished by the makeup water supply line 12.

【００２５】脱ＣＯ2 塔１に押込められた燃焼排ガスは
ノズル７から供給される一定濃度の吸収液と下部充填部
２で向流接触させられ、燃焼排ガス中のＣＯ2 は吸収液
供給口６からの吸収液により吸収除去され、脱ＣＯ2 燃
焼排ガスは上部充填部３へと向う。脱ＣＯ2 塔１に供給
される吸収液はＣＯ2 を吸収し、その吸収による反応熱
のため、通常吸収液供給口６における温度よりも高温と
なり、ＣＯ2 を吸収した吸収液は吸収液排出ポンプ１３
により熱交換器１４に送られ、加熱され、吸収液再生塔
１５へ導かれる。吸収液の温度調節は熱交換器１４ある
いは必要に応じて熱交換器１４と吸収液供給口６の間に
設けられる冷却器２７により行うことができる。The combustion exhaust gas pushed into the CO 2 removal tower 1 is brought into countercurrent contact with the absorption liquid having a constant concentration supplied from the nozzle 7 in the lower filling section 2, and CO 2 in the combustion exhaust gas is supplied to the absorption liquid supply port. The absorbed liquid from 6 absorbs and removes the CO 2 -exhausted exhaust gas to the upper filling part 3. The absorption liquid supplied to the CO 2 removal tower 1 absorbs CO 2, and due to the heat of reaction due to the absorption, the temperature becomes higher than the temperature at the absorption liquid supply port 6 normally, and the absorption liquid absorbing CO 2 is discharged into the absorption liquid. Pump 13
Is sent to the heat exchanger 14, heated, and guided to the absorbent regenerator 15. The temperature of the absorbing liquid can be adjusted by the heat exchanger 14 or, if necessary, by the cooler 27 provided between the heat exchanger 14 and the absorbing liquid supply port 6.

【００２６】吸収液再生塔１５では、再生加熱器１８に
よる加熱で吸収液が再生され、熱交換器１４及び必要に
応じて設けられた冷却器２７により冷却され、脱ＣＯ2
塔１の吸収液供給口６へ戻される。吸収液再生塔１５の
上部において、吸収液から分離されたＣＯ2 はノズル２
４より供給される還流水と接触し、再生塔還流冷却器２
３により冷却され、ＣＯ2 分離器２１にてＣＯ2 に同伴
した水蒸気が凝縮した還流水と分離され、回収ＣＯ2 排
出ライン２２よりＣＯ2 回収工程へ導かれる。還流水の
一部は還流水ポンプ２０で吸収液再生塔１５へノズル２
４を介して還流され、他の一部は再生塔還流水供給ライ
ン２５より脱ＣＯ2 塔１の上部に供給される。In the absorption liquid regenerator 15, the absorption liquid is regenerated by heating by the regeneration heater 18, cooled by the heat exchanger 14 and the cooler 27 provided as necessary, and CO 2 is removed.
It is returned to the absorption liquid supply port 6 of the tower 1. In the upper part of the absorption liquid regeneration tower 15, the CO 2 separated from the absorption liquid is discharged from the nozzle 2
4 in contact with the reflux water supplied from the regeneration tower reflux condenser 2
After being cooled by 3, the water vapor entrained in CO 2 is separated from the condensed reflux water by the CO 2 separator 21, and is guided to the CO 2 recovery process from the recovered CO 2 discharge line 22. A part of the reflux water is fed to the absorption liquid regeneration tower 15 by the reflux water pump 20 and the nozzle 2
It is recirculated through 4 and the other part is supplied to the upper part of the CO 2 removal column 1 through the regeneration tower reflux water supply line 25.

【００２７】[0027]

【実施例】以下、実施例により本発明を具体的に説明す
る。The present invention will be described below in detail with reference to examples.

【００２８】（実施例１、比較例１）恒温槽内に設置し
たガラス製反応容器にジエチルアミノアセトアミド〔Ｄ
ＥＡＡＡ：（Ｈ5 Ｃ2 ）2 ＮＣＨ2 ＣＯＮＨ2 〕の１モ
ル／リットル（１３重量％）水溶液５０ミリリットルを
入れ、吸収液とした。温度４０℃で攪拌下しながら、Ｃ
Ｏ2 ガスを大気圧下１リットル／分の流速で、バブルを
発生しやすいようにフィルタを通して１時間この吸収液
に通した。(Example 1, Comparative Example 1) Diethylaminoacetamide [D] was placed in a glass reaction container installed in a constant temperature bath.
50 ml of a 1 mol / liter (13% by weight) aqueous solution of EAAA: (H 5 C 2 ) 2 NCH 2 CONH 2 ] was added to obtain an absorbing solution. While stirring at a temperature of 40 ° C, C
O 2 gas was passed through the absorbent at a flow rate of 1 liter / min under atmospheric pressure for 1 hour through a filter so that bubbles were easily generated.

【００２９】１時間後、吸収液に含まれるＣＯ2 をＣＯ
2 分析計（全有機炭素計）を用いて測定し、吸収量（モ
ルＣＯ2 ／モル吸収液）を求めた。次に吸収液の入った
容器を１００℃に加熱し、１００℃における吸収液から
のＣＯ2 の脱着のしやすさを調べた。その方法は１００
℃に加熱された吸収液を経時的に少量ずつサンプリング
し、吸収液中のＣＯ2 をＣＯ2 分析計を用いて測定する
ことによって行った。比較例として、化学式が類似した
アミノアルコールの２−ジエチルアミノエタノール〔Ｄ
ＥＡＥ：（Ｈ5 Ｃ2 ）2 ＮＣＨ2 ＣＨ2 ＯＨ〕１モル／
リットル（１２重量％）水溶液による吸収、脱着試験を
行った。その結果を表１及び図２に示した。After 1 hour, the CO 2 contained in the absorbing solution was reduced to CO 2 .
2 The amount of absorption (mol CO 2 / mol absorption liquid) was determined by measurement using an analyzer (total organic carbon meter). Next, the container containing the absorbing solution was heated to 100 ° C., and the easiness of desorption of CO 2 from the absorbing solution at 100 ° C. was examined. The method is 100
The absorption liquid heated to ℃ was sampled little by little over time, and CO 2 in the absorption liquid was measured by using a CO 2 analyzer. As a comparative example, 2-diethylaminoethanol [D, an amino alcohol having a similar chemical formula, is used.
EAE: (H 5 C 2 ) 2 NCH 2 CH 2 OH] 1 mol /
Absorption and desorption tests with a liter (12% by weight) aqueous solution were performed. The results are shown in Table 1 and FIG.

【００３０】[0030]

【表１】 [Table 1]

【００３１】表１及び図２の結果から明らかなように、
本発明で使用するアミン化合物の一つであるジエチルア
ミノアセトアミド（ＤＥＡＡＡ）の水溶液をＣＯ2 ガス
の吸収液として用いることにより、ＤＥＡＥ水溶液を用
いる場合よりもモル当たりのＣＯ2 吸収量は若干低くな
るが、吸収液からＣＯ2 が脱着しやすいので、ＣＯ2の
放散量はＤＥＡＥ水溶液を用いた場合よりも大きくな
り、効率的なＣＯ2 除去が行えることが分かる。As is clear from the results shown in Table 1 and FIG.
When an aqueous solution of diethylaminoacetamide (DEAAA), which is one of the amine compounds used in the present invention, is used as the CO 2 gas absorbing solution, the CO 2 absorption amount per mole becomes slightly lower than when using the DEAE aqueous solution. Since CO 2 is easily desorbed from the absorption liquid, the amount of CO 2 emitted is larger than that when the DEAE aqueous solution is used, and it can be seen that CO 2 can be efficiently removed.

【００３２】ＤＥＡＡＡの水溶液の代わりに２−（ｔ−
ブチルアミノ）アセトアミド〔ｔ−ＢＡＡＡ：（ｔｅｒ
ｔ−Ｈ9 Ｃ4 ）ＮＨＣＨ2 ＣＯＮＨ2 〕の１モル／リッ
トル（１０重量％）水溶液又は２−ジメチルアミノ−
Ｎ，Ｎ−ジメチルアセトアミド〔ＤＭＡＤＭＡＡ：（Ｃ
Ｈ3 ）2 ＮＣＨ2 ＣＯＮＨ（ＣＨ3 ）2 〕の１モル／リ
ットル（１３重量％）水溶液を用いた他は実施例１と同
様にしてＣＯ2 ガスの吸収及び脱着試験を行った。比較
例として２−エチルアミノエタノール（ＥＡＥ）の１モ
ル／リットル（９重量％）水溶液による吸収、脱着試験
を行った。その結果を表２に示した。Instead of an aqueous solution of DEAAA, 2- (t-
Butylamino) acetamide [t-BAAA: (ter
t-H 9 C 4 ) NHCH 2 CONH 2 ] in 1 mol / liter (10% by weight) aqueous solution or 2-dimethylamino-
N, N-dimethylacetamide [DDMAMA: (C
A CO 2 gas absorption and desorption test was conducted in the same manner as in Example 1 except that a 1 mol / liter (13 wt%) aqueous solution of H 3 ) 2 NCH 2 CONH (CH 3 ) 2 ] was used. As a comparative example, an absorption / desorption test was conducted using a 1 mol / liter (9% by weight) aqueous solution of 2-ethylaminoethanol (EAE). The results are shown in Table 2.

【００３３】[0033]

【表２】 [Table 2]

【００３４】表２の結果から明らかなように、本発明で
使用するアミン化合物である２−（ｔ−ブチルアミノ）
アセトアミド（ｔ−ＢＡＡＡ）又は２−ジメチルアミノ
−Ｎ，Ｎ−ジメチルアセトアミド（ＤＭＡＤＭＡＡ）の
水溶液をＣＯ2 ガスの吸収液として用いることにより、
ＥＡＥ水溶液を用いる場合よりもモル当たりのＣＯ2吸
収量は若干低くなるが、吸収液からＣＯ2 が脱着しやす
いので、ＣＯ2 の放散量はＥＡＥ水溶液を用いた場合よ
りも大きくなり、効率的なＣＯ2 除去が行えることが分
かる。As is clear from the results of Table 2, the amine compound used in the present invention, 2- (t-butylamino).
By using an aqueous solution of acetamide (t-BAAA) or 2-dimethylamino-N, N-dimethylacetamide (DMADMAA) as a CO 2 gas absorbing solution,
Although the CO 2 absorption amount per mole is slightly lower than that when using the EAE aqueous solution, CO 2 is easily desorbed from the absorbing solution, so the CO 2 emission amount is larger than when the EAE aqueous solution is used, and it is more efficient. It can be seen that effective CO 2 removal can be performed.

【００３５】[0035]

【発明の効果】以上詳細に述べたように、本発明の方法
に従って一般式〔１〕で表されるアミン化合物の水溶液
を吸収液として使用することにより、従来使用されてい
た吸収液を用いる場合よりも、吸収剤化合物単位モル当
たりのＣＯ2 放散量を増し、より効率的にＣＯ2 の除去
を行うことができるようになった。また、一般式〔１〕
で表されるアミン化合物はＣＯ2 吸収後の吸収液の加熱
により、容易にＣＯ2 が脱着することから、再生熱エネ
ルギも少なくて済むので、総合的にＣＯ2 の回収エネル
ギの小さいプロセスが構成できる。As described above in detail, according to the method of the present invention, when the aqueous solution of the amine compound represented by the general formula [1] is used as the absorbing liquid, the conventional absorbing liquid is used. The amount of CO 2 released per unit mol of the absorbent compound can be increased, and CO 2 can be removed more efficiently. The general formula [1]
In the amine compound represented by, CO 2 is easily desorbed by heating the absorbing solution after CO 2 absorption, so that the heat energy for regeneration can be small, and thus a process in which the recovery energy of CO 2 is small is constituted. it can.

【図面の簡単な説明】[Brief description of drawings]

【図１】本発明の方法を適用する燃焼排ガス中のＣＯ2
を除去するプロセスの１例を示すフロー図。FIG. 1 CO 2 in combustion exhaust gas to which the method of the present invention is applied
Flow diagram showing an example of a process for removing the.

【図２】実施例１及び比較例１のＣＯ2 脱着試験におけ
る吸収液中のＣＯ2 濃度の経時変化を示すグラフ。FIG. 2 is a graph showing the change over time in the CO 2 concentration in the absorbent in the CO 2 desorption test of Example 1 and Comparative Example 1.

───────────────────────────────────────────────────── フロントページの続き (72)発明者 三村 富雄 大阪府大阪市北区中之島３丁目３番22号 関西電力株式会社内 (72)発明者 岩木 貫 広島県広島市西区観音新町四丁目６番22号 三菱重工業株式会社広島研究所内 (72)発明者 光岡 薫明 広島県広島市西区観音新町四丁目６番22号 三菱重工業株式会社広島研究所内 (72)発明者 田中 裕士 広島県広島市西区観音新町四丁目６番22号 三菱重工業株式会社広島研究所内 (72)発明者 飯島 正樹 東京都千代田区丸の内二丁目５番１号 三 菱重工業株式会社内 ─────────────────────────────────────────────────── ─── Continuation of the front page (72) Inventor Tomio Mimura 3-22 Nakanoshima, Kita-ku, Osaka City, Osaka Prefecture 3-22 Kansai Electric Power Co., Inc. No. 22 Mitsubishi Heavy Industries Ltd. Hiroshima Research Institute (72) Inventor Kaoru Mitsuoka 4-6-22 Kannon Shinmachi Nishi-ku, Hiroshima City Hiroshima Prefecture Mitsubishi Heavy Industries Ltd. Hiroshima Research Institute (72) Inventor Hiroshi Tanaka Kannon, Hiroshima City Hiroshima 4-6-22 Shinmachi Mitsubishi Heavy Industries, Ltd. Hiroshima Research Institute (72) Inventor Masaki Iijima 2-5-1 Marunouchi, Chiyoda-ku, Tokyo Sanryo Heavy Industries Co., Ltd.

Claims (4)

【特許請求の範囲】[Claims] 【請求項１】 ＣＯ2 を含有するガスを下記一般式
〔１〕で表されるアミン化合物の１種以上を含有する水
溶液に接触させることを特徴とするガス中のＣＯ 2 の除
去方法。 【化１】 （式中、Ｒ1 〜Ｒ8 は、それぞれ同一でも異なっていて
もよい水素原子又は炭素数１〜４のアルキル基を表し、
ｍは０又は１を表す。）1. COTwoThe gas containing
Water containing at least one amine compound represented by [1]
CO in gas characterized by being brought into contact with a solution TwoExcluding
How to leave. [Chemical 1](Where R1~ R8Are the same or different
Represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms,
m represents 0 or 1. ) 【請求項２】 ＣＯ2 を含有するガスを一般式〔１〕で
表されるアミン化合物の１種以上及びＣＯ2 吸収能力の
大きい他のアミン化合物の１種以上を含有する水溶液に
接触させることを特徴とするガス中のＣＯ2 の除去方
法。 2. Contacting a gas containing CO 2 with an aqueous solution containing at least one amine compound represented by the general formula [1] and at least one other amine compound having a large CO 2 absorption capacity. A method for removing CO 2 from a gas, the method comprising: 【請求項３】 前記水溶液中の一般式〔１〕で表される
アミン化合物の濃度が１５〜６５重量％の範囲であるこ
とを特徴とする請求項１又は２に記載のガス中のＣＯ2
の除去方法。3. The CO 2 in the gas according to claim 1 or 2, wherein the concentration of the amine compound represented by the general formula [1] in the aqueous solution is in the range of 15 to 65% by weight.
Removal method. 【請求項４】 前記ＣＯ2 を含有するガスが大気圧下の
燃焼排ガスであることを特徴とする請求項１〜３のいず
れかに記載のガス中のＣＯ2 の除去方法。4. A method for removing CO 2 in the gas according to any one of claims 1 to 3, wherein the gas containing the CO 2 is a combustion exhaust gas under atmospheric pressure.
JP06263596A 1996-03-19 1996-03-19 Method for removing carbon dioxide in gas Expired - Fee Related JP3761960B2 (en)

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NO19971133A NO319385B1 (en) 1996-03-19 1997-03-12 Carbon dioxide removal process present in gases and absorbent
US08/816,646 US5904908A (en) 1996-03-19 1997-03-13 Method for the removal of carbon dioxide present in gases
CA002200130A CA2200130C (en) 1996-03-19 1997-03-17 Method for the removal of carbon dioxide present in gases and absorbent
EP97301767A EP0796646B1 (en) 1996-03-19 1997-03-17 Method for the removal of carbon dioxide present in gases and absorbent
DK97301767T DK0796646T3 (en) 1996-03-19 1997-03-17 Process for the removal of carbon dioxide in gases and absorbent
DE69726039T DE69726039T2 (en) 1996-03-19 1997-03-17 Process for removing carbon dioxide and absorbent present in gases
US09/106,267 US6051161A (en) 1996-03-19 1998-06-29 Method for the removal of carbon dioxide present in gases and absorbent

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DE69726039T2 (en) 2004-08-26
EP0796646B1 (en) 2003-11-12
CA2200130A1 (en) 1997-09-19
US5904908A (en) 1999-05-18
CA2200130C (en) 2000-12-05
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DK0796646T3 (en) 2004-02-16
US6051161A (en) 2000-04-18
NO971133D0 (en) 1997-03-12
NO971133L (en) 1997-09-22

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