JPH0717767B2 - Method for manufacturing epoxy resin laminate - Google Patents
Method for manufacturing epoxy resin laminateInfo
- Publication number
- JPH0717767B2 JPH0717767B2 JP63296539A JP29653988A JPH0717767B2 JP H0717767 B2 JPH0717767 B2 JP H0717767B2 JP 63296539 A JP63296539 A JP 63296539A JP 29653988 A JP29653988 A JP 29653988A JP H0717767 B2 JPH0717767 B2 JP H0717767B2
- Authority
- JP
- Japan
- Prior art keywords
- epoxy resin
- water
- dried
- nonwoven fabric
- glass
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003822 epoxy resin Substances 0.000 title claims description 16
- 229920000647 polyepoxide Polymers 0.000 title claims description 16
- 238000004519 manufacturing process Methods 0.000 title claims description 9
- 238000000034 method Methods 0.000 title description 2
- 239000011521 glass Substances 0.000 claims description 19
- 239000004745 nonwoven fabric Substances 0.000 claims description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
- 238000001035 drying Methods 0.000 claims description 9
- 239000007822 coupling agent Substances 0.000 claims description 5
- 238000005470 impregnation Methods 0.000 claims 2
- 238000010030 laminating Methods 0.000 claims 1
- 238000009413 insulation Methods 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 238000010521 absorption reaction Methods 0.000 description 5
- 238000005406 washing Methods 0.000 description 5
- 239000002966 varnish Substances 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 239000003365 glass fiber Substances 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- KUBDPQJOLOUJRM-UHFFFAOYSA-N 2-(chloromethyl)oxirane;4-[2-(4-hydroxyphenyl)propan-2-yl]phenol Chemical compound ClCC1CO1.C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 KUBDPQJOLOUJRM-UHFFFAOYSA-N 0.000 description 1
- ULKLGIFJWFIQFF-UHFFFAOYSA-N 5K8XI641G3 Chemical compound CCC1=NC=C(C)N1 ULKLGIFJWFIQFF-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 229930185605 Bisphenol Natural products 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 229920000137 polyphosphoric acid Polymers 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- FZHAPNGMFPVSLP-UHFFFAOYSA-N silanamine Chemical compound [SiH3]N FZHAPNGMFPVSLP-UHFFFAOYSA-N 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000013585 weight reducing agent Substances 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K1/00—Printed circuits
- H05K1/02—Details
- H05K1/03—Use of materials for the substrate
- H05K1/0313—Organic insulating material
- H05K1/0353—Organic insulating material consisting of two or more materials, e.g. two or more polymers, polymer + filler, + reinforcement
- H05K1/0366—Organic insulating material consisting of two or more materials, e.g. two or more polymers, polymer + filler, + reinforcement reinforced, e.g. by fibres, fabrics
Landscapes
- Reinforced Plastic Materials (AREA)
- Laminated Bodies (AREA)
Description
【発明の詳細な説明】 産業上の利用分野 本発明は、絶縁板、プリント回路用基板などとして用い
られるエポキシ樹脂積層板、殊にガラス不織布を基材と
する積層板の製造法に関する。Description: FIELD OF THE INVENTION The present invention relates to a method for producing an epoxy resin laminated plate used as an insulating plate, a printed circuit board or the like, particularly a laminated plate based on a nonwoven glass fabric.
従来の技術 前記基材として用いられるガラス不織布の製造に際して
は、ストランドの製造時に、サイズ剤として、ポリアミ
ド樹脂、ブタジエン、アクリロニトリル、、ポリビニル
アルコール、酢酸ビニル、メタアクリレート、でん粉等
が用いられ、さらにストランドをカット後水に分散させ
る際には、分散剤としてポリアクリル酸ソーダ、ポリエ
チレンオキシド、ポリリン酸等の界面活性剤、および粘
剤として酢酸ビニル、ポリビニルアルコール、でん粉等
が用いられ、分散させた繊維を抄紙後エポキシ樹脂等の
接着剤を吹きつける等、そのガラス繊維の表面にはいろ
いろな物質が付着していることになる。In the production of the glass nonwoven fabric used as the above-mentioned substrate, a polyamide resin, butadiene, acrylonitrile, polyvinyl alcohol, vinyl acetate, methacrylate, starch or the like is used as a sizing agent in the production of strands, and further strands are used. When dispersed in water after cutting, surfactants such as sodium polyacrylate, polyethylene oxide, polyphosphoric acid as a dispersant, and vinyl acetate, polyvinyl alcohol, starch etc. as a sticking agent are used, and dispersed fibers After the papermaking, various substances are attached to the surface of the glass fiber, such as spraying an adhesive such as an epoxy resin.
しかしながら、従来の積層板の製造においては、ガラス
不織布になにも処理をせずにエポキシ樹脂を含浸乾燥さ
せるか、カップリング剤処理を行った後、エポキシ樹脂
を含浸乾燥させる方法でプリプレグを得、これを積層成
形している。However, in the production of conventional laminates, a prepreg is obtained by a method of impregnating and drying an epoxy resin without any treatment on a glass nonwoven fabric, or after performing a coupling agent treatment and then impregnating and drying the epoxy resin. , This is laminated.
発明が解決しようとする課題 ところが、ガラス不織布の製造で分散剤として使用した
界面活性剤は、成形した積層板が吸湿するとイオン化し
て、積層板の絶縁抵抗を下げる大きな要因となる。DISCLOSURE OF THE INVENTION Problems to be Solved by the Invention However, the surfactant used as the dispersant in the production of the glass nonwoven fabric is ionized when the molded laminate sheet absorbs moisture, and becomes a major factor of lowering the insulation resistance of the laminate sheet.
本発明はこの知見に基づき、吸湿後の絶縁抵抗の低下が
少ないガラス不織布基材エポキシ樹脂積層板を提供する
ことを目的とする。The present invention is based on this finding, and an object thereof is to provide a glass non-woven fabric-based epoxy resin laminate having less decrease in insulation resistance after moisture absorption.
課題を解決するための手段 上記目的を達成するために、本発明は、ガラス不織布を
水洗乾燥し、この後エポキシ樹脂を含浸乾燥してプリプ
レグを得る。または、ガラス不織布を水洗乾燥し、カッ
プリング剤で処理後にエポキシ樹脂を含浸乾燥してプリ
プレグを得る。そして、これらプリプレグを積層成形す
るものである。Means for Solving the Problems In order to achieve the above object, in the present invention, a glass nonwoven fabric is washed with water and dried, and then impregnated with an epoxy resin and dried to obtain a prepreg. Alternatively, the glass nonwoven fabric is washed with water, dried, treated with a coupling agent, impregnated with an epoxy resin and dried to obtain a prepreg. Then, these prepregs are laminated and molded.
作用 ガラス不織布の水洗により、これに付着している水溶性
物質、特にイオン性物質が除去される。これにより、積
層板中の吸湿によりイオン化する物質の量が減じられ、
吸湿による絶縁抵抗の低下を抑制することができる。Action By washing the glass non-woven fabric with water, water-soluble substances, especially ionic substances, attached to it are removed. This reduces the amount of substances that ionize due to moisture absorption in the laminate,
It is possible to suppress a decrease in insulation resistance due to moisture absorption.
ガラス不織布を水洗後の乾燥は、水分を除去してガラス
繊維とエポキシ樹脂の接着力を低下させないためである
が、水洗乾燥後にカップリング剤処理を施しておくこと
により、接着力は向上する。The drying of the glass non-woven fabric after washing with water does not remove water to reduce the adhesive strength between the glass fiber and the epoxy resin. However, the adhesive strength is improved by applying a coupling agent treatment after washing with water and drying.
実施例 本発明の実施例を説明する。Example An example of the present invention will be described.
エポキシ樹脂として以下のものを用意する。The following epoxy resins are prepared.
ビスフェノール型エポキシ樹脂（油化シェル製、EPON−
1001）100重量部、ジシアンジアミド４重量部、２−エ
チル−４メチルイミダゾール0.3重量部を配合した後、
水酸化アルミニウム20重量部をよく混合し、固形分50重
量％のワニスとした。Bisphenol type epoxy resin (made by Yuka Shell, EPON-
1001) After blending 100 parts by weight, 4 parts by weight of dicyandiamide, 0.3 part by weight of 2-ethyl-4methylimidazole,
20 parts by weight of aluminum hydroxide was mixed well to form a varnish having a solid content of 50% by weight.
実施例１ ガラス不織布（日本バイリーン製EP−4075）を80℃の温
水に10分間浸漬し、水洗した後、120℃のオーブンで10
分間乾燥した。さらに５分間乾燥し、重量減少のないこ
とを確認した後、上記のワニスを含浸、乾燥させ、樹脂
量75重量％のプリプレグを作製した。Example 1 A glass non-woven fabric (EP-4075 manufactured by Nippon Vilene) was immersed in warm water at 80 ° C for 10 minutes, washed with water, and then dried in an oven at 120 ° C for 10 minutes.
Dry for minutes. After further drying for 5 minutes and confirming that there was no weight reduction, the above varnish was impregnated and dried to prepare a prepreg having a resin amount of 75% by weight.
このプリプレグを８枚積層し、加熱加圧して1.6mmの積
層板を得た。Eight prepregs were laminated and heated and pressed to obtain a 1.6 mm laminated plate.
実施例２ 実施例１と同様にガラス不織布を水洗乾燥した。さら
に、アミノシラン系カッピリング剤（日本ユニカ製Ａ−
1100）１重量％を含む水／メタノール混合溶液を含浸さ
せた後、120℃で10分間乾燥した。Example 2 A glass nonwoven fabric was washed with water and dried in the same manner as in Example 1. Furthermore, an aminosilane-based capping agent (A-
1100) was impregnated with a water / methanol mixed solution containing 1% by weight, and then dried at 120 ° C. for 10 minutes.
その後実施例１と同じ条件でプリプレグを得、これを加
熱加圧して1.6mm厚の積層板を得た。Thereafter, a prepreg was obtained under the same conditions as in Example 1, and this was heated and pressed to obtain a laminated plate having a thickness of 1.6 mm.
実施例３ 実施例１と同じガラス不織布を25℃の水に40分間浸漬
し、水洗した後、実施例１と同様にしてプリプレグを
得、これを加熱加圧して1.6mm厚の積層板を得た。Example 3 The same glass non-woven fabric as in Example 1 was immersed in water at 25 ° C. for 40 minutes and washed with water, and then a prepreg was obtained in the same manner as in Example 1, which was heated and pressed to obtain a laminated plate having a thickness of 1.6 mm. It was
実施例４ 実施例１と同じガラス不織布に80℃の温水を毎分10ず
つノズルから噴霧して、水洗、乾燥した後、実施例１と
同様にしてプリプレグを得、これを加熱加圧して1.6mm
の積層板を得た。Example 4 The same glass non-woven fabric as in Example 1 was sprayed with hot water at 80 ° C. at a rate of 10 per minute from a nozzle, washed with water and dried, and then prepreg was obtained in the same manner as in Example 1 and heated and pressed to give 1.6. mm
A laminated plate of was obtained.
比較例１ 実施例１と同様のガラス不織布を水洗、乾燥工程を行わ
ずに、直接ワニスを実施例１と同じ条件で含浸、乾燥さ
せ、プリプレグを得た。これを加熱加圧して1.6mm厚の
積層板を得た。Comparative Example 1 A glass woven fabric similar to that of Example 1 was directly impregnated with a varnish under the same conditions as in Example 1 without washing and drying, and dried to obtain a prepreg. This was heated and pressed to obtain a laminated plate having a thickness of 1.6 mm.
比較例２ 実施例１と同様のガラス不織布な水洗、乾燥工程を行わ
ずに、直接、実施例２と同様の方法でカップリング剤処
理を施し、この後同様にワニスを含浸させ、プリプレグ
を得た。これを加熱加圧して1.6mm厚の積層板を得た。Comparative Example 2 A glass nonwoven fabric similar to that of Example 1 was directly treated with a coupling agent in the same manner as in Example 2 without performing washing and drying steps, and then impregnated with a varnish in the same manner to obtain a prepreg. It was This was heated and pressed to obtain a laminated plate having a thickness of 1.6 mm.
上記で得た各積層板を、JIS−C 6481 5.11に基づき試験
片に加工し、常態およびプレッシャークッカーにより12
1℃2atmにて２時間、４時間、６時間の処理を行いそれ
ぞれ絶縁抵抗を測定した。結果を第１図に示す。Each laminated plate obtained above was processed into a test piece based on JIS-C 6481 5.11, and 12
Insulation resistance was measured by treating at 1 ° C. and 2 atm for 2 hours, 4 hours, and 6 hours. The results are shown in Fig. 1.
発明の効果 上述のように、本発明は、ガラス不織布に付着している
水溶性物質を除去してからエポキシ樹脂を含乾燥して得
たプリプレグを用い、積層板を製造している。これによ
り、積層板中の吸湿によるイオン化物質が減じられ、吸
湿による絶縁抵抗の低下を抑制した積層板を得ることが
できる。EFFECTS OF THE INVENTION As described above, according to the present invention, a laminated board is manufactured by using a prepreg obtained by removing a water-soluble substance adhering to a glass non-woven fabric and then containing an epoxy resin for drying. As a result, the ionized substance due to moisture absorption in the laminate is reduced, and it is possible to obtain a laminate in which a decrease in insulation resistance due to moisture absorption is suppressed.
第１図は積層板のプレッシャークッカー処理による絶縁
抵抗の変化を示す曲線図である。FIG. 1 is a curve diagram showing changes in insulation resistance of a laminated plate due to pressure cooker treatment.
Claims (2)
て得たプリプレグを積層形成する積層板の製造法におい
て、 エポキシ樹脂の含浸に先立ち、ガラス不織布を水洗し乾
燥することを特徴とするエポキシ樹脂積層板の製造法。1. A method for producing a laminated plate for laminating and forming a prepreg obtained by impregnating and drying an epoxy resin on a glass nonwoven fabric, wherein the glass nonwoven fabric is washed with water and dried prior to impregnation with the epoxy resin. Laminated board manufacturing method.
布を水洗し乾燥し、更にカップリング剤処理することを
特徴とする請求項１記載のエポキシ樹脂積層板の製造
法。2. The method for producing an epoxy resin laminate according to claim 1, wherein the glass nonwoven fabric is washed with water, dried and treated with a coupling agent prior to the impregnation with the epoxy resin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63296539A JPH0717767B2 (en) | 1988-11-24 | 1988-11-24 | Method for manufacturing epoxy resin laminate |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63296539A JPH0717767B2 (en) | 1988-11-24 | 1988-11-24 | Method for manufacturing epoxy resin laminate |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH02141231A JPH02141231A (en) | 1990-05-30 |
| JPH0717767B2 true JPH0717767B2 (en) | 1995-03-01 |
Family
ID=17834837
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63296539A Expired - Lifetime JPH0717767B2 (en) | 1988-11-24 | 1988-11-24 | Method for manufacturing epoxy resin laminate |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0717767B2 (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4842003B2 (en) * | 2006-04-18 | 2011-12-21 | 株式会社岡村製作所 | Chair |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59130365A (en) * | 1983-01-17 | 1984-07-26 | 日立化成工業株式会社 | Production of glass fiber fabric |
| JPS61106208A (en) * | 1984-10-30 | 1986-05-24 | Shin Kobe Electric Mach Co Ltd | Manufacture of prepreg for laminated sheet |
| JPS6354441A (en) * | 1986-08-22 | 1988-03-08 | Mitsubishi Rayon Co Ltd | Production of fiber-reinforced thermoplastic prepreg |
-
1988
- 1988-11-24 JP JP63296539A patent/JPH0717767B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JPH02141231A (en) | 1990-05-30 |
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