JPH06327419A - Defoaming agent for food - Google Patents
Defoaming agent for foodInfo
- Publication number
- JPH06327419A JPH06327419A JP5140178A JP14017893A JPH06327419A JP H06327419 A JPH06327419 A JP H06327419A JP 5140178 A JP5140178 A JP 5140178A JP 14017893 A JP14017893 A JP 14017893A JP H06327419 A JPH06327419 A JP H06327419A
- Authority
- JP
- Japan
- Prior art keywords
- silicon dioxide
- defoaming agent
- fatty acid
- acid ester
- oil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Landscapes
- General Preparation And Processing Of Foods (AREA)
Abstract
Description
【0001】[0001]
【産業上の利用分野】本発明は、ピックル液及びその他
の食品、さらにこれら食品の製造時に安全かつ優れた消
泡効果を示す食品用消泡剤に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a pickle solution and other foods, and further relates to a food defoaming agent which exhibits a safe and excellent defoaming effect during the production of these foods.
【0002】[0002]
【従来の技術】食品の製造工程中には、攪拌や充填、蒸
煮等製造工程中に発泡を伴なうものが多く見られる。そ
の結果、生産効率の低下や最終製品の外観・品質不良を
招く恐れがあり、製造業者にとって重大な問題となって
いる。その対策として代表的なものに消泡剤の利用があ
る。しかし、食品に使用するため安全面が重視されねば
ならず、使用できる消泡剤の種類、添加量に制約があ
る。2. Description of the Related Art Many food products are accompanied by foaming during the manufacturing process, such as stirring, filling and steaming. As a result, there is a possibility that production efficiency may decrease and the appearance and quality of the final product may deteriorate, which is a serious problem for manufacturers. As a typical countermeasure, there is the use of an antifoaming agent. However, since it is used for food, safety must be emphasized, and there are restrictions on the type and amount of defoaming agent that can be used.
【0003】従来の食品用消泡剤としては、酸敗油やシ
リコーン樹脂、グリセリン脂肪酸エステル等が用いられ
ているが、各々問題点があるのが現状である。As conventional antifoaming agents for foods, rancid oil, silicone resin, glycerin fatty acid ester and the like are used, but at present there are problems.
【0004】[0004]
【発明が解決しようとする課題】このうち酸敗油におい
てはそれ自身では効果が不充分な上、酸価・過酸化物価
も高く、衛生上の問題もある。シリコーン樹脂において
は、そのままでは水に分散せず、また乳化液状態で使用
する場合も、食品衛生上の制限がある上高価である。グ
リセリン脂肪酸エステルにおいても、単独での使用では
消泡力が不充分であり、シリコーン樹脂等を配合してい
るのが現状である。Among these, the acidified oil is not sufficiently effective by itself, and the acid value and the peroxide value are also high, which causes a sanitary problem. Silicone resins do not disperse in water as they are, and even when used in an emulsion state, they are expensive due to food hygiene restrictions. Even in the case of glycerin fatty acid ester, the defoaming power is insufficient when used alone, and it is the current situation that silicone resin and the like are blended.
【0005】本発明の目的は従来の各種消泡剤の問題点
を解決し、少量で優れた効果を発揮し、食品添加物のみ
からなる事、さらに製造工程が容易で、物性の安定度に
優れた消泡剤を提供することである。The object of the present invention is to solve the problems of various conventional defoaming agents, to exert excellent effects even in a small amount, to be composed only of food additives, and to facilitate the manufacturing process and to stabilize the physical properties. It is to provide an excellent antifoaming agent.
【0006】[0006]
【課題を解決するための手段】本発明者は、鋭意研究の
結果、微粒二酸化ケイ素、食用油脂、グリセリン脂肪酸
エステル、リン脂質を配合することによって得られる組
成物が、安定性に優れしかもその製造が容易であり、か
つピックル液をはじめとする食品の製造工程において消
泡効果が著しいことを見出し、本発明を完成するに至っ
た。As a result of earnest research, the present inventor has found that a composition obtained by incorporating fine silicon dioxide, edible oil and fat, glycerin fatty acid ester and phospholipid is excellent in stability and can be produced. It was found that the defoaming effect is remarkable and that the defoaming effect is remarkable in the production process of foods including pickle liquid, and the present invention has been completed.
【0007】本発明で用いる微粒二酸化ケイ素とは、平
均粒子径15μm以下、二酸化ケイ素含量99.0%以上のも
のをいう。二酸化ケイ素は最終食品の完成前に除去され
なければならないが、微粒二酸化ケイ素はその必要性が
ない。The fine-grained silicon dioxide used in the present invention is one having an average particle diameter of 15 μm or less and a silicon dioxide content of 99.0% or more. Silicon dioxide must be removed prior to completion of the final food product, whereas finely divided silicon dioxide is not necessary.
【0008】本発明で用いるグリセリン脂肪酸エステル
とは、反応品、蒸留品及び飽和脂肪酸、不飽和脂肪酸の
いずれでもよいが特にオレイン酸に富むものが好まし
く、上記から選ばれる1種又は2種以上の混合物が使用
できる。The glycerin fatty acid ester used in the present invention may be any of reaction products, distilled products, saturated fatty acids and unsaturated fatty acids, but those rich in oleic acid are particularly preferable, and one or more selected from the above may be used. Mixtures can be used.
【0009】本発明で用いるリン脂質とは、大豆レシチ
ン、卵黄レシチン等の動植物レシチンをいい、特定のレ
シチンに限られるものではない。また分別レシチン、水
添レシチンのような加工レシチンも利用しうる。分別レ
シチンにおいては、精製度合によりペースト状、塊状、
粉末状等種々のタイプのレシチンがあり、好ましくはペ
ースト状レシチンであるが、他のタイプのレシチンも使
用可能である。The phospholipid used in the present invention refers to animal and plant lecithin such as soybean lecithin and egg yolk lecithin, and is not limited to a specific lecithin. Also, processed lecithin such as fractionated lecithin and hydrogenated lecithin can be used. For fractionated lecithin, paste, lump, and
There are various types of lecithin such as powder, preferably pasty lecithin, but other types of lecithin can also be used.
【0010】本発明で用いる食用油脂とは、常温下で液
状の食用可能な油脂であればよく、例えば大豆油、菜種
油、コーン油、綿実油、サフラワー油、オリーブ油など
が利用できる。またそれらを原料とした分別油、エステ
ル交換油などに代表される加工油脂も使用可能である。The edible oil / fat used in the present invention may be any edible oil / fat which is liquid at room temperature, and examples thereof include soybean oil, rapeseed oil, corn oil, cottonseed oil, safflower oil and olive oil. In addition, processed oils and fats represented by fractionated oils, transesterified oils and the like using them as raw materials can also be used.
【0011】本発明の組成比率は、微粒二酸化ケイ素1
〜15重量%、好ましくは3〜10重量%、グリセリン脂肪
酸エステル30重量%以上、かつグリセリン脂肪酸エステ
ルと食用油脂の比率が35:65〜90:10、レシチン1〜40
重量%、好ましくは10〜30重量%の範囲である。The composition ratio of the present invention is as follows:
-15% by weight, preferably 3-10% by weight, 30% by weight or more of glycerin fatty acid ester, and the ratio of glycerin fatty acid ester and edible oil / fat is 35: 65-90: 10, lecithin 1-40.
%, Preferably 10 to 30% by weight.
【0012】上記範囲外では充分な消泡効果を得ること
ができない。さらに微粒二酸化ケイ素においては、1重
量%未満では製剤の安定性が不充分であり、また15重量
%以上では製剤がペースト状となり作業性及び分散性が
低下する。本発明の消泡剤は0.01〜10重量%程度添加す
ることにより良好な消泡力を示す。Outside the above range, a sufficient defoaming effect cannot be obtained. Further, in the case of fine silicon dioxide, if the amount is less than 1% by weight, the stability of the preparation is insufficient, and if it is more than 15% by weight, the preparation becomes a paste and the workability and dispersibility are deteriorated. The defoaming agent of the present invention exhibits good defoaming power when added in an amount of 0.01 to 10% by weight.
【0013】[0013]
【実施例】以下に本発明の実施例を示す。EXAMPLES Examples of the present invention will be shown below.
【0014】・実施例1 硬化牛脂脂肪酸モノグリセリド40%、菜種油40%、リン
脂質15%、微粒二酸化ケイ素5%を均一に混合溶解し、
液状の消泡剤を得た。Example 1 Hardened beef tallow fatty acid monoglyceride 40%, rapeseed oil 40%, phospholipids 15%, fine particle silicon dioxide 5% were uniformly mixed and dissolved,
A liquid defoamer was obtained.
【0015】・実施例2 菜種油脂肪酸モノグリセリド40%、菜種油40%、リン脂
質15%、微粒二酸化ケイ素5%を均一に混合溶解し、液
状の消泡剤を得た。Example 2 40% of rapeseed oil fatty acid monoglyceride, 40% of rapeseed oil, 15% of phospholipid and 5% of finely divided silicon dioxide were uniformly mixed and dissolved to obtain a liquid defoaming agent.
【0016】・実施例3 菜種油脂肪酸モノグリセリド40%、大豆油40%、リン脂
質15%、微粒二酸化ケイ素5%を均一に混合溶解し、液
状の消泡剤を得た。Example 3 40% of rapeseed oil fatty acid monoglyceride, 40% of soybean oil, 15% of phospholipid and 5% of finely divided silicon dioxide were uniformly mixed and dissolved to obtain a liquid defoaming agent.
【0017】・実施例4 硬化牛脂脂肪酸モノグリセリド40%、菜種油25%、リン
脂質30%、微粒二酸化ケイ素5%を均一に混合溶解し、
液状の消泡剤を得た。Example 4 Hardened beef tallow fatty acid monoglyceride 40%, rapeseed oil 25%, phospholipid 30%, fine particle silicon dioxide 5% were uniformly mixed and dissolved,
A liquid defoamer was obtained.
【0018】・実施例5 硬化牛脂脂肪酸モノグリセリド40%、大豆油40%、リン
脂質10%、微粒二酸化ケイ素10%を均一に混合溶解し、
液状の消泡剤を得た。Example 5 Hardened beef tallow fatty acid monoglyceride 40%, soybean oil 40%, phospholipids 10%, fine particle silicon dioxide 10% are uniformly mixed and dissolved,
A liquid defoamer was obtained.
【0019】・比較例1 菜種油脂肪酸モノグリセリド40%、菜種油20%、大豆油
20%、リン脂質20%を均一に混合溶解し、消泡剤を得
た。Comparative Example 1 Rapeseed oil fatty acid monoglyceride 40%, rapeseed oil 20%, soybean oil
20% and phospholipid 20% were uniformly mixed and dissolved to obtain an antifoaming agent.
【0020】・比較例2 菜種油脂肪酸モノグリセリド40%、菜種油20%、リン脂
質10%、微粒二酸化ケイ素30%を均一に混合溶解し、消
泡剤を得た。Comparative Example 2 A defoaming agent was obtained by uniformly mixing and dissolving 40% rapeseed oil fatty acid monoglyceride, 20% rapeseed oil, 10% phospholipid, and 30% finely divided silicon dioxide.
【0021】・比較例3 硬化牛脂脂肪酸モノグリセリド50%、大豆油40%、微粒
二酸化ケイ素10%を均一に混合溶解し、液状の消泡剤を
得た。Comparative Example 3 50% hardened beef tallow fatty acid monoglyceride, 40% soybean oil, and 10% finely divided silicon dioxide were uniformly mixed and dissolved to obtain a liquid defoaming agent.
【0022】・比較例4 硬化牛脂脂肪酸モノグリセリド30%、菜種油15%、リン
脂質50%、微粒二酸化ケイ素5%を均一に混合溶解し、
液状の消泡剤を得た。Comparative Example 4 30% of hardened beef tallow fatty acid monoglyceride, 15% of rapeseed oil, 50% of phospholipids and 5% of fine silicon dioxide were uniformly mixed and dissolved,
A liquid defoamer was obtained.
【0023】・比較例5 硬化牛脂脂肪酸モノグリセリド20%、菜種油30%、大豆
油30%、リン脂質15%、微粒二酸化ケイ素5%を均一に
混合溶解し、液状の消泡剤を得た。Comparative Example 5 Hardened beef tallow fatty acid monoglyceride 20%, rapeseed oil 30%, soybean oil 30%, phospholipids 15%, and fine silicon dioxide 5% were uniformly mixed and dissolved to obtain a liquid defoaming agent.
【0024】・消泡試験1 大豆たん白 300gを5℃冷水に分散させ、ピロリン酸ナ
トリウム、亜硝酸ナトリウム、アスコルビン酸ナトリウ
ム、グルタミン酸ナトリウム、食塩、砂糖さらに上記組
成の消泡剤10g添加し、ホモミキサー(特殊機化工業
製)で10000rpm、5分間ミキシングし、ピックル液10リ
ットルを調整した。ミキシング終了直後の泡量を観察
し、結果は5段階評価とした。Defoaming Test 1 300 g of soybean protein was dispersed in cold water at 5 ° C., and sodium pyrophosphate, sodium nitrite, sodium ascorbate, sodium glutamate, salt, sugar and 10 g of a defoaming agent having the above composition were added, and homogenized. A mixer (made by Tokushu Kika Kogyo Co., Ltd.) was mixed at 10,000 rpm for 5 minutes to prepare 10 liters of pickle liquid. The amount of bubbles immediately after mixing was observed, and the results were evaluated on a 5-point scale.
【0025】・消泡試験2 10%卵白粉末溶液を1000ml調整し、上記組成の消泡剤を
500ppm投入し、ミキサーにて高速2分間攪拌を行った。
攪拌終了直後の泡の高さ(mm)を測定した。Defoaming test 2 1000 ml of a 10% egg white powder solution was prepared and a defoaming agent having the above composition was prepared.
500 ppm was added, and the mixture was stirred at high speed for 2 minutes.
The height (mm) of bubbles was measured immediately after the end of stirring.
【0026】前記の消泡剤組成物の安定性及び消泡試験
1、2の試験結果を表1に示す。The stability of the above antifoam composition and the test results of antifoam tests 1 and 2 are shown in Table 1.
【0027】[0027]
【表1】 [Table 1]
【0028】表1の結果より、本発明消泡剤は安定性、
消泡効果共に優れていることがわかる。From the results shown in Table 1, the antifoaming agent of the present invention is stable,
It can be seen that both the defoaming effect is excellent.
【0029】[0029]
【発明の効果】本発明の食品用消泡剤はピックル液その
他の食品製造時に優れた消泡効果を発揮し、しかも人体
に対し安全なものである。さらに、安定で作業性の良好
な液体消泡剤が容易な製造方法で得られる。Industrial Applicability The food defoaming agent of the present invention exhibits an excellent defoaming effect during the production of pickled liquid and other foods, and is safe for the human body. Furthermore, a stable and good workability liquid defoaming agent can be obtained by an easy manufacturing method.
Claims (4)
ル、リン脂質、食用油脂を有効成分として含有すること
を特徴とする液体消泡剤。1. A liquid defoaming agent comprising silicon dioxide, glycerin fatty acid ester, phospholipid, and edible oil and fat as active ingredients.
の微粒二酸化ケイ素である請求項1記載の液体消泡剤。2. The liquid defoaming agent according to claim 1, which is fine silicon dioxide having an average particle diameter of 15 μm or less.
である請求項1又は2記載の液体消泡剤。3. The content of finely divided silicon dioxide is 1 to 15% by weight.
The liquid defoaming agent according to claim 1 or 2.
セリン脂肪酸エステル30重量%以上で、かつグリセリン
脂肪酸エステルと食用油脂との比率が35:65〜90:10で
あり、リン脂質1〜40重量%の組成比率を有効成分とし
た食品用消泡剤。4. Fine particle silicon dioxide 1 to 15% by weight, glycerin fatty acid ester 30% by weight or more, and the ratio of glycerin fatty acid ester to edible oil and fat is 35:65 to 90:10, and phospholipids 1 to 40% by weight. Defoaming agent for foods with a composition ratio of 10% as an active ingredient.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP5140178A JPH06327419A (en) | 1993-05-19 | 1993-05-19 | Defoaming agent for food |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP5140178A JPH06327419A (en) | 1993-05-19 | 1993-05-19 | Defoaming agent for food |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH06327419A true JPH06327419A (en) | 1994-11-29 |
Family
ID=15262714
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP5140178A Withdrawn JPH06327419A (en) | 1993-05-19 | 1993-05-19 | Defoaming agent for food |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH06327419A (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1040858A2 (en) * | 1999-04-01 | 2000-10-04 | Medtronic, Inc. | Antifoam compositions |
JP2011168653A (en) * | 2010-02-16 | 2011-09-01 | Lion Corp | Method for producing liquid composition |
CN104685006A (en) * | 2012-09-27 | 2015-06-03 | 东洋铝株式会社 | Metallic color pigment and colored article |
JP7121376B1 (en) * | 2021-12-27 | 2022-08-18 | 株式会社Nkホールディングス | Quality adjustment method for whey protein-containing food |
-
1993
- 1993-05-19 JP JP5140178A patent/JPH06327419A/en not_active Withdrawn
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1040858A2 (en) * | 1999-04-01 | 2000-10-04 | Medtronic, Inc. | Antifoam compositions |
EP1040858A3 (en) * | 1999-04-01 | 2001-01-24 | Medtronic, Inc. | Antifoam compositions |
JP2011168653A (en) * | 2010-02-16 | 2011-09-01 | Lion Corp | Method for producing liquid composition |
CN104685006A (en) * | 2012-09-27 | 2015-06-03 | 东洋铝株式会社 | Metallic color pigment and colored article |
US10150846B2 (en) | 2012-09-27 | 2018-12-11 | Toyo Aluminium Kabushiki Kaisha | Colored metallic pigment and colored article |
JP7121376B1 (en) * | 2021-12-27 | 2022-08-18 | 株式会社Nkホールディングス | Quality adjustment method for whey protein-containing food |
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Legal Events
Date | Code | Title | Description |
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A300 | Withdrawal of application because of no request for examination |
Free format text: JAPANESE INTERMEDIATE CODE: A300 Effective date: 20000801 |