JPH0578228A - Hair-dye composition - Google Patents
Hair-dye compositionInfo
- Publication number
- JPH0578228A JPH0578228A JP24123591A JP24123591A JPH0578228A JP H0578228 A JPH0578228 A JP H0578228A JP 24123591 A JP24123591 A JP 24123591A JP 24123591 A JP24123591 A JP 24123591A JP H0578228 A JPH0578228 A JP H0578228A
- Authority
- JP
- Japan
- Prior art keywords
- hair
- acid
- red
- dye composition
- yellow
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/4906—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom
- A61K8/4913—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom having five membered rings, e.g. pyrrolidone carboxylic acid
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/4973—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with oxygen as the only hetero atom
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
- A61Q5/065—Preparations for temporary colouring the hair, e.g. direct dyes
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/42—Colour properties
- A61K2800/43—Pigments; Dyes
- A61K2800/432—Direct dyes
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Emergency Medicine (AREA)
- Cosmetics (AREA)
Abstract
Description
【0001】[0001]
【産業上の利用分野】本発明は染毛剤組成物に関し、更
に詳細には手袋等の道具を用いず、素手で使用し得る染
毛剤であって、毛髪に塗布してから洗い流すまでの放置
時間が短く、操作の簡便な染毛剤組成物に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a hair dye composition, and more particularly to a hair dye that can be used with bare hands without using tools such as gloves, which is used from application to hair to washing. The present invention relates to a hair dye composition which has a short standing time and is easy to operate.
【0002】[0002]
【従来の技術】酸性染料を配合した染毛剤は、他の染毛
剤に比べて毛髪損傷性が少ないことから家庭で、また美
容院で広く使用されている。しかしながら、当該酸性染
料配合染毛剤は、道具を用いず、素手で塗布した場合、
著しく手肌を汚すものである。従って、美容師が施術す
る場合は予めはえぎわにプロテクトクリーム等を塗布し
て地肌に染毛剤が付着しないよう注意しながら、手袋や
コーム等の道具を使用して塗布し、加温して10〜30
分間放置することにより高い染毛効果を得ている。一
方、家庭で染毛する場合は、手袋やコーム等の道具を使
用して、手肌が汚れない様に注意し、かつ塗布後10〜
30分放置することにより行なわれている。2. Description of the Related Art Hair dyes containing acid dyes are widely used at home and in beauty salons because they have less hair damage than other hair dyes. However, the acid dye-containing hair dye, when applied with bare hands without using a tool,
It significantly stains the skin of the hands. Therefore, when a beautician applies a treatment, apply a protective cream or the like on the edges in advance to prevent the hair dye from adhering to the skin, apply it with a tool such as a glove or comb, and heat it. 10-30
A high hair dyeing effect is obtained by leaving it for a minute. On the other hand, when dyeing hair at home, use a tool such as a glove or comb to be careful not to stain your skin, and after applying 10
It is performed by leaving it for 30 minutes.
【0003】このように従来の酸性染料配合染毛剤は、
手肌を汚す、操作が煩雑等の欠点を有するため、近年こ
れを解決すべく種々の検討がなされてきた。その一つと
して、酸性染料濃度の低い染毛剤をヘアリンスと同様の
用法で使用することにより、白髪を徐々に目立たなくさ
せる手段が開発された。この染毛剤は、素手で使用して
も汚れが少ないこと、染毛剤を塗布してから洗い流すま
での放置時間が約5分と比較的短いこと等の利点を有し
ている。As described above, the conventional acid dye-containing hair dye is
Since it has drawbacks such as soiling the hand skin and complicated operation, various studies have been made in recent years to solve the problems. As one of them, a means for gradually making the gray hair less noticeable has been developed by using a hair dye having a low acid dye concentration in the same manner as hair rinse. This hair dye has advantages that it is less contaminated even when it is used with bare hands, and that the standing time from application of the hair dye to washing is about 5 minutes, which is relatively short.
【0004】[0004]
【発明が解決しようとする課題】しかしながら、この染
毛剤も放置時間が約5分必要であることから、通常のヘ
アリンス剤に比べ、未だその簡便性において充分満足で
きるものではなかった。従って本発明の目的は素手で使
用しても手肌の汚れが少なく、より短い放置時間で徐々
に白髪が目立たなくなる等の染毛効果に優れた染毛剤組
成物を提供することにある。However, since this hair dye also requires a leaving time of about 5 minutes, it is still not sufficiently satisfactory in its simplicity as compared with a usual hair rinse agent. Therefore, it is an object of the present invention to provide a hair dye composition which has less stains on the skin even when it is used with bare hands and has an excellent hair dyeing effect such that gray hair gradually becomes inconspicuous in a shorter standing time.
【0005】[0005]
【課題を解決するための手段】かかる実状において本発
明者らは鋭意検討した結果、全く意外にも低濃度の酸性
染料と有機溶剤を含み、pHを2.0〜4.5に調整し、
更に一定の緩衝能を付与した染毛剤組成物が、手肌に対
する汚れが少なく、120秒以下という短い放置時間
で、徐々に白髪を目立たなくする効果に優れていること
を見出し、本発明を完成させた。[Means for Solving the Problems] As a result of intensive investigations conducted by the present inventors in such an actual situation, surprisingly, a low concentration of an acid dye and an organic solvent are contained, and the pH is adjusted to 2.0 to 4.5.
Further, it has been found that a hair dye composition having a certain buffering ability has less stains on the skin of the hands and is excellent in the effect of gradually making the gray hair inconspicuous with a short standing time of 120 seconds or less, and the present invention Completed
【0006】すなわち、本発明は次の成分(A)及び
(B) (A)酸性染料 0.01〜0.2重量% (B)有機溶剤 0.5〜50重量% を含有し、pHが2.0〜4.5であり、緩衝能が0.0
1〜0.2グラム当量/lであることを特徴とする染毛
剤組成物を提供するものである。That is, the present invention contains the following components (A) and (B) (A) acid dye 0.01 to 0.2% by weight (B) organic solvent 0.5 to 50% by weight and pH 2.0 to 4.5 and a buffer capacity of 0.0
The present invention provides a hair dye composition characterized in that it is 1 to 0.2 gram equivalent / l.
【0007】本発明の染毛剤組成物の(A)成分である
酸性染料としては、ニトロ染料、アゾ染料、ニトロソ染
料、トリフェニルメタン染料、キサンテン染料、キノリ
ン染料、アントラキノン染料、インジゴ染料等が挙げら
れ、具体的には、赤色2号、赤色3号、赤色102号、
赤色104号、赤色105号、赤色106号、黄色4
号、黄色5号、緑色3号、青色1号、青色2号、赤色2
01号、赤色227号、赤色220号、赤色230号、
赤色231号、赤色232号、橙色205号、橙色20
7号、黄色202号、黄色203号、緑色201号、緑
色204号、緑色205号、青色202号、青色203
号、青色205号、かっ色201号、赤色401号、赤
色502号、赤色503号、赤色504号、赤色506
号、橙色402号、黄色402号、黄色403号、黄色
406号、黄色407号、緑色401号、緑色402
号、紫色401号、黒色401号等が用いられる。この
うち、染毛力の観点より好ましい酸性染料は、黄色4
号、緑色204号、赤色2号、赤色102号、緑色3
号、青色1号、青色205号、黄色403号、赤色10
6号、赤色201号、橙色205号、黒色401号、緑
色201号又は紫色401号であり、就中黒色401
号、紫色401号、橙色205号、黄色403号又は赤
色106号が特に好ましい。なお、これらの酸性染料は
1種又は2種以上を混合して用いることができる。Examples of the acidic dye which is the component (A) of the hair dye composition of the present invention include nitro dyes, azo dyes, nitroso dyes, triphenylmethane dyes, xanthene dyes, quinoline dyes, anthraquinone dyes and indigo dyes. Specifically, Red No. 2, Red No. 3, Red No. 102,
Red No. 104, Red No. 105, Red No. 106, Yellow 4
No., Yellow No. 5, Green No. 3, Blue No. 1, Blue No. 2, Red 2
01, red 227, red 220, red 230,
Red 231, Red 232, Orange 205, Orange 20
No. 7, Yellow No. 202, Yellow No. 203, Green No. 201, Green No. 204, Green No. 205, Blue No. 202, Blue No. 203
No. 205, Blue No. 205, Brown No. 201, Red No. 401, Red No. 502, Red No. 503, Red No. 504, Red No. 506.
No., Orange No. 402, Yellow No. 402, Yellow No. 403, Yellow No. 406, Yellow No. 407, Green No. 401, Green No. 402
No. 401, purple No. 401, black No. 401, etc. are used. Among these, the acidic dye which is preferable from the viewpoint of hair dyeing power is yellow 4
No. 2, Green No. 204, Red No. 2, Red No. 102, Green No. 3
No. Blue No. 1, Blue No. 205, Yellow No. 403, Red No. 10
No. 6, Red No. 201, Orange No. 205, Black No. 401, Green No. 201 or Purple No. 401, among which Black 401
No. 401, purple No. 401, orange No. 205, yellow No. 403 or red No. 106 are particularly preferable. In addition, these acidic dyes can be used 1 type or in mixture of 2 or more types.
【0008】上記酸性染料の配合量は、組成物中0.0
1〜0.2重量%(以下、単に%で示す)であるが、染
毛力と手肌の汚れの抑制を両立させる観点より、0.0
2〜0.1%、特に0.03〜0.08%が好ましい。
酸性染料の配合量が0.01%未満であると短かい放置
時間で充分な染毛効果は得られず、0.2%を超えると
手肌の汚れが著しく、実使用上問題がある。The amount of the above-mentioned acid dye is 0.0 in the composition.
The amount is 1 to 0.2% by weight (hereinafter, simply indicated as%), but from the viewpoint of achieving both hair dyeing power and suppression of hand skin stains, 0.0
2 to 0.1%, particularly 0.03 to 0.08% is preferable.
When the content of the acid dye is less than 0.01%, a sufficient hair dyeing effect cannot be obtained after a short standing time, and when it exceeds 0.2%, the hand skin is significantly soiled, which is a problem in practical use.
【0009】(B)成分である有機溶剤としては、次式
(1)で表わされる化合物、次式(2)で表わされるN
−アルキルピロリドン又は炭素数1〜4のアルキレンカ
ーボネートが挙げられる。As the organic solvent which is the component (B), a compound represented by the following formula (1) and N represented by the following formula (2) are given.
-Alkylpyrrolidone or alkylene carbonates having 1 to 4 carbon atoms.
【0010】[0010]
【化1】 [Chemical 1]
【0011】[0011]
【化2】 [Chemical 2]
【0012】これらの有機溶剤の具体例としては、例え
ばエタノール、イソプロパノール、n−プロパノール、
n−ブタノール、イソブタノール、エチレングリコー
ル、プロピレングリコール、1,3−ブタンジオール、
ベンジルアルコール、シンナミルアルコール、フェネチ
ルアルコール、p−アニシルアルコール、p−メチルベ
ンジルアルコール、フェノキシエタノール、2−ベンジ
ルオキシエタノール、メチルカルビトール、エチルカル
ビトール、プロピルカルビトール、ブチルカルビトー
ル、トリエチレングリコールモノエチルエーテル、トリ
エチレングリコールモノブチルエーテル、グリセリン、
N−メチルピロリドン、N−オクチルピロリドン、N−
ラウリルピロリドン等が挙げられる。Specific examples of these organic solvents include ethanol, isopropanol, n-propanol,
n-butanol, isobutanol, ethylene glycol, propylene glycol, 1,3-butanediol,
Benzyl alcohol, cinnamyl alcohol, phenethyl alcohol, p-anisyl alcohol, p-methylbenzyl alcohol, phenoxyethanol, 2-benzyloxyethanol, methyl carbitol, ethyl carbitol, propyl carbitol, butyl carbitol, triethylene glycol mono. Ethyl ether, triethylene glycol monobutyl ether, glycerin,
N-methylpyrrolidone, N-octylpyrrolidone, N-
Examples thereof include laurylpyrrolidone.
【0013】かかる有機溶剤の配合量は0.5〜50
%、特に1〜35%が好ましい。0.5%未満では短か
い放置時間で充分な染毛効果が得られず、50%を超え
て配合しても、効果の向上は認められない。The amount of such organic solvent compounded is 0.5 to 50.
%, Particularly 1 to 35% is preferable. If it is less than 0.5%, a sufficient hair dyeing effect cannot be obtained even after a short standing time, and if it exceeds 50%, no improvement in the effect is observed.
【0014】本発明染毛剤組成物のpH(10%水溶液と
して測定)は2.0〜4.5であり、より好ましくは
2.5〜4.5、特に好ましくは2.5〜4.0であ
る。pHが4.5を超えると染毛剤を毛髪に塗布した後の
放置時間が短縮されず好ましくなく、pHが2.0未満で
あると酸成分による手肌への刺激が問題となる。The pH of the hair dye composition of the present invention (measured as a 10% aqueous solution) is 2.0 to 4.5, more preferably 2.5 to 4.5, and particularly preferably 2.5 to 4. It is 0. If the pH exceeds 4.5, it is not preferable because the standing time after applying the hair dye to the hair is not shortened, and if the pH is less than 2.0, irritation to the hand skin due to the acid component becomes a problem.
【0015】また、本発明染毛剤組成物は、本組成物の
10%水溶液の緩衝能が0.01〜0.2グラム当量/
lを示すことが必要である。ここで、本発明における緩
衝能とは、25℃における染毛剤組成物の10%水溶液
のpHを初期の値から1上昇させるのに要する塩基の濃度
を尺度として次式により求められる値である。Further, the hair dye composition of the present invention has a buffering capacity of 0.01 to 0.2 gram equivalent /% in a 10% aqueous solution of the composition.
It is necessary to indicate l. Here, the buffering capacity in the present invention is a value obtained by the following equation using the concentration of the base required to raise the pH of the 10% aqueous solution of the hair dye composition at 25 ° C. by 1 from the initial value as a scale. ..
【0016】[0016]
【数1】 [Equation 1]
【0017】当該緩衝能が0.01グラム当量/l未満
であると短かい放置時間で充分な効果が得られず、0.
2グラム当量/lを超えると、染毛効果の目立った向上
は見られず、緩衝能を付与するpH緩衝剤やその他の配合
成分が溶解しにくくなる等の理由から好ましくない。な
お、好ましい緩衝能は0.01〜0.05グラム当量/
lである。When the buffering capacity is less than 0.01 gram equivalent / l, a sufficient effect cannot be obtained even after a short standing time, and it is not possible to obtain
When it exceeds 2 gram equivalent / l, the hair dyeing effect is not noticeably improved, and it is not preferable because the pH buffering agent which imparts the buffering capacity and other components are not easily dissolved. The preferable buffer capacity is 0.01 to 0.05 gram equivalent /
It is l.
【0018】このような緩衝能は、染毛剤組成物にpH緩
衝剤、界面活性剤、キレート剤、染料、防腐剤等を添加
することによって付与することができる。このうち、pH
緩衝剤としては、pH2.0〜4.5の範囲で緩衝作用を
有する有機酸又は無機酸及び/又はその塩を用いること
ができる。有機酸としては、例えばクエン酸、グリコー
ル酸、コハク酸、酒石酸、乳酸、フマル酸、リンゴ酸、
レブリン酸、酪酸、吉草酸、シュウ酸、マレイン酸、フ
マル酸、マンデル酸等を挙げることができ、無機酸とし
ては、例えばリン酸、硫酸、硝酸等を挙げることができ
る。また、これらの酸の塩としては、例えばナトリウム
塩、カリウム塩、アンモニウム塩、トリエタノールアミ
ン塩などのアルカノールアミン塩等を挙げることができ
る。緩衝能を与える化合物の配合量は特に規定されるも
のではなく、緩衝能を与える化合物の種類によって異な
る。例えば、主に緩衝能を与える化合物として、クエン
酸ナトリウム塩を用いた場合は、約2〜2.5重量%以
上の濃度で配合される。Such buffering ability can be imparted by adding a pH buffering agent, a surfactant, a chelating agent, a dye, a preservative and the like to the hair dye composition. Of these, pH
As the buffering agent, an organic acid or an inorganic acid and / or a salt thereof having a buffering action in the range of pH 2.0 to 4.5 can be used. Examples of the organic acid include citric acid, glycolic acid, succinic acid, tartaric acid, lactic acid, fumaric acid, malic acid,
Examples thereof include levulinic acid, butyric acid, valeric acid, oxalic acid, maleic acid, fumaric acid and mandelic acid, and examples of the inorganic acid include phosphoric acid, sulfuric acid, nitric acid and the like. Examples of salts of these acids include sodium salts, potassium salts, ammonium salts, alkanolamine salts such as triethanolamine salts, and the like. The compounding amount of the compound that provides the buffering capacity is not particularly limited, and varies depending on the type of the compound that provides the buffering capacity. For example, when a citric acid sodium salt is mainly used as a compound that provides a buffering capacity, it is mixed at a concentration of about 2 to 2.5% by weight or more.
【0019】また、本発明の染毛剤組成物には、本発明
の効果を損なわない範囲で各種界面活性剤、カチオン性
重合体、油性成分、ヒドロキシエチルセルロースやキサ
ンタンガム等の増粘剤、シリコーン誘導体、香料、防腐
剤、紫外線吸収剤、酸化防止剤、殺菌剤等を配合しても
よい。ここで界面活性剤としてはオレフィンスルホン
酸、アルカンスルホン酸、脂肪酸アルキルエーテルカル
ボン酸、N−アシルアミノ酸等のアニオン界面活性剤;
アミドベタイン、カルボベタイン、ヒドロキシスルホベ
タイン等の両性界面活性剤;モノもしくはジアルキル第
4級アンモニウム塩等のカチオン界面活性剤;ポリオキ
シアルキレンアルキルエーテル等の非イオン界面活性剤
のいずれも用いることができる。また、カチオン性重合
体としてはカチオン化セルロース、カチオン化澱粉、カ
チオン化グァガム、ジアリル4級アンモニウム塩重合
物、ジアリル4級アンモニウム塩/アクリルアミド共重
合物、ヒドロキシエチルセルロースジメチルジアリル4
級アンモニウム共重合物等が挙げられる。また、油性成
分としては脂肪酸エステル類、直鎖又は分岐鎖のアルキ
ルグリセリルエーテル、分岐の高級アルコール等が挙げ
られる。Further, the hair dye composition of the present invention contains various surfactants, cationic polymers, oily components, thickeners such as hydroxyethyl cellulose and xanthan gum, and silicone derivatives within a range that does not impair the effects of the present invention. , A fragrance, an antiseptic, an ultraviolet absorber, an antioxidant, a bactericide and the like may be added. Here, as the surfactant, anionic surfactants such as olefin sulfonic acid, alkane sulfonic acid, fatty acid alkyl ether carboxylic acid and N-acyl amino acid;
Any of amphoteric surfactants such as amidobetaine, carbobetaine and hydroxysulfobetaine; cationic surfactants such as mono- or dialkyl quaternary ammonium salts; nonionic surfactants such as polyoxyalkylene alkyl ethers can be used. .. Examples of the cationic polymer include cationized cellulose, cationized starch, cationized guar gum, diallyl quaternary ammonium salt polymer, diallyl quaternary ammonium salt / acrylamide copolymer, hydroxyethyl cellulose dimethyl diallyl 4
Examples thereof include quaternary ammonium copolymers. Examples of the oily component include fatty acid esters, straight chain or branched chain alkyl glyceryl ether, and branched higher alcohols.
【0020】本発明染毛剤組成物は上記成分を混合して
常法により製造でき、その使用方法は通常のヘアリンス
に極めて類似している。すなわち、本発明染毛剤組成物
を、道具を用いず素手で取り、毛髪に塗布した後、12
0秒以下の時間放置した後、すすげばよい。約5〜10
回の使用で、白髪が目立たなくなる等の染毛効果が得ら
れる。染毛効果の観点から、放置時間は30秒〜120
秒が好ましい。放置時間を120秒以上とした場合で
も、白髪が目立たなくなる染毛効果の大幅な向上は見ら
れない。The hair dye composition of the present invention can be prepared by a conventional method by mixing the above components, and the method of using the composition is very similar to the usual hair rinse. That is, after taking the hair dye composition of the present invention with bare hands without using a tool and applying it to the hair, 12
After leaving it for a time of 0 seconds or less, it is sufficient to squeeze. About 5-10
With repeated use, a hair dyeing effect such as white hair becoming less noticeable can be obtained. From the viewpoint of hair dyeing effect, leaving time is 30 seconds to 120
Seconds are preferred. Even when the standing time is 120 seconds or more, no significant improvement in the hair dyeing effect that makes gray hair inconspicuous is not seen.
【0021】[0021]
【発明の効果】本発明染毛剤組成物を用いれば、道具を
使用せず素手で毛髪に塗布し、120秒以下の短時間放
置した後洗い流すだけで、徐々に白髪を目立たなくする
ことができる。By using the hair dye composition of the present invention, it is possible to gradually make the white hair inconspicuous by applying it to the hair with bare hands without using a tool, leaving it for a short time of 120 seconds or less, and then washing it off. it can.
【0022】[0022]
【実施例】次に実施例を挙げて本発明を更に詳細に説明
するが、本発明はこれに限定されるものではない。The present invention will be described in more detail with reference to examples, but the present invention is not limited thereto.
【0023】実施例1〜3 乾燥した白髪の毛束約10gをシャンプーした後、水を
切り(水を切った後の毛束の重量は17g)これに表1
の組成物各3gを素早く均一に塗布した後、35℃にて
一定時間放置し、すすいだ。乾燥した後、シャンプー
し、同様な操作を繰り返し、毛髪の染まり及び手肌の汚
れを評価した。なお、染まり(ΔE)及び手肌の汚れは
以下の如くして評価した。 (1)染まり(ΔE) 染色毛束を色差計(ミノルタ社製CR200)でL,
a,b値を測定し、未染色毛との色差(ΔE)を求め、
染まりを評価した。なお、ΔEはその数値が大きい程染
まりがよいことを表わす。 (2)手肌の汚れ 10名のパネラーにより、組成物を手に取り、その後石
鹸により洗浄し、手の汚れを調べた。その評価は以下の
基準によった。 ○:2回の石鹸洗浄により、手の汚れが落ちた。 ×:2回の石鹸洗浄によっても、手の汚れが落ちなかっ
た。Examples 1 to 3 About 10 g of a dried white hair bundle was shampooed and then drained (the weight of the bundle of hair after draining was 17 g).
3 g of each of the above compositions was rapidly and uniformly applied, and then left at 35 ° C. for a certain period of time and rinsed. After drying, shampooing and similar operation were repeated to evaluate hair dyeing and hand skin stains. The stain (ΔE) and the stain on the hand skin were evaluated as follows. (1) Dyeing (ΔE) The dyed hair bundle was set to L with a color difference meter (CR200 manufactured by Minolta),
The a and b values are measured to obtain the color difference (ΔE) from undyed hair,
The stain was evaluated. In addition, ΔE represents that the larger the value, the better the dyeing. (2) Dirt on hand skin The composition was picked up by 10 panelists and then washed with soap to examine the dirt on the hands. The evaluation was based on the following criteria. ◯: Dirt on hands was removed by washing with soap twice. X: Dirt on hands was not removed even by washing with soap twice.
【0024】[0024]
【表1】 [Table 1]
【0025】表1より本発明品は短かい放置時間で良好
な染毛効果を示し、手肌の汚れも石鹸洗浄で容易に落ち
ることがわかる。It can be seen from Table 1 that the product of the present invention exhibits a good hair-dyeing effect after a short standing time and stains on the skin of hands are easily removed by washing with soap.
【0026】比較例4 前頭部の白髪率が約10%である40歳台女性モニター
10名に対して、シャンプーした後、美容師が比較例1
(表1)を約15g塗布し、35℃で30秒間放置した
後、すすぎ、更にドライヤーで乾燥させた。同様な操作
を更に4回繰り返した後、10名のパネラーにより白髪
の目立ちを、目視で評価した。その結果を表2に示す。Comparative Example 4 After shampooing 10 female monitors in the 40's having a white hair ratio of about 10% on the forehead, a hairdresser gave Comparative Example 1
About 15 g of (Table 1) was applied, left at 35 ° C. for 30 seconds, rinsed, and then dried with a drier. After repeating the same operation four more times, the conspicuousness of white hair was visually evaluated by 10 panelists. The results are shown in Table 2.
【0027】実施例4 前頭部の白髪率が約10%である40歳台女性モニター
10名に対して、シャンプーした後、美容師が本発明例
1(表1)を約15g塗布し、35℃で30秒間放置し
た後、すすぎ、更にドライヤーで乾燥させた。同様な操
作を更に4回繰り返した後、10名のパネラーにより白
髪の目立ちを目視で評価した。その結果を表2に示す。Example 4 After shampooing 10 female monitors in the 40's with a white hair ratio of about 10% on the forehead, a hairdresser applied about 15 g of Inventive Example 1 (Table 1), After leaving it at 35 ° C. for 30 seconds, it was rinsed and dried with a dryer. After repeating the same operation four more times, the conspicuousness of white hair was visually evaluated by 10 panelists. The results are shown in Table 2.
【0028】実施例5 前頭部の白髪率が約10%である40歳台女性モニター
10名に対して、シャンプーした後、美容師が下記に示
す染毛剤組成物を約15g塗布し、35℃で90秒間放
置した後、すすぎ、更にドライヤーで乾燥させた。同様
な操作を更に4回繰り返した後、10名のパネラーによ
り白髪の目立ちを目視で評価した。その結果を表2に示
す。また、染毛剤塗布後の美容師の手の汚れは、石鹸洗
浄によって落ちた。なお、調製方法は実施例1〜3と同
様に行ない、pHは4.0、緩衝能は0.024グラム当
量/lであった。 配合成分 配合量(%) (1)1,3−ブタンジオール 20 (2)N−メチルピロリドン 10 (3)クエン酸 6 (4)黒色401号 0.006 (5)紫色401号 0.003 (6)赤色106号 0.004 (7)橙色205号 0.035 (8)キサンタンガム 1.0 (9)NaOH 適量 (10)精製水 バランスExample 5 After shampooing 10 female monitors in the 40's having a white hair ratio of about 10% on the forehead, a hairdresser applied about 15 g of the hair dye composition shown below, After leaving it at 35 ° C. for 90 seconds, it was rinsed and dried with a dryer. After repeating the same operation four more times, the conspicuousness of white hair was visually evaluated by 10 panelists. The results are shown in Table 2. Further, the stains on the hand of the hairdresser after applying the hair dye were removed by washing with soap. The preparation method was the same as in Examples 1 to 3, and the pH was 4.0 and the buffer capacity was 0.024 gram equivalent / l. Blending component Blending amount (%) (1) 1,3-butanediol 20 (2) N-methylpyrrolidone 10 (3) Citric acid 6 (4) Black 401 No. 0.006 (5) Purple 401 No. 0.003 ( 6) Red No. 106 0.004 (7) Orange No. 205 0.035 (8) Xanthan gum 1.0 (9) NaOH appropriate amount (10) Purified water balance
【0029】[0029]
【表2】 [Table 2]
【0030】実施例6〜8 下記組成物は、頭髪に塗布してからすすぐまでの時間が
60秒(35℃)の条件で、約5回の使用によって、白
髪が目立たなくなる等の良好な染毛効果に示した。ま
た、染毛剤塗布時の手の汚れは石鹸洗浄によって落ち
た。なお、いずれの組成物も調製方法は実施例1〜3と
同様に行ない、pHは3.5であった。また実施例6及び
8の組成物の緩衝能は0.025グラム当量/lであ
り、実施例7の組成物の緩衝能は0.037グラム当量
/lであった。Examples 6 to 8 The following compositions were excellently dyed such that white hair became inconspicuous after being used about 5 times under the condition that the time from application to hair to rinsing was 60 seconds (35 ° C.). Showed in hair effect. Also, stains on hands when applying the hair dye were removed by washing with soap. The composition of each composition was prepared in the same manner as in Examples 1 to 3, and the pH was 3.5. The buffer capacity of the compositions of Examples 6 and 8 was 0.025 gram equivalent / l, and the buffer capacity of the composition of Example 7 was 0.037 gram equivalent / l.
【0031】(実施例6) 配合成分 配合量(%) (1)エタノール 20 (2)ベンジルアルコール 5 (3)乳酸 5 (4)黒色401号 0.004 (5)紫色401号 0.005 (6)黄色403号 0.009 (7)橙色205号 0.030 (8)ヒドロキシエチルセルロース 1.5 (9)NaOH 適量 (10)精製水 バランス(Example 6) Blending component blending amount (%) (1) Ethanol 20 (2) Benzyl alcohol 5 (3) Lactic acid 5 (4) Black 401 0.004 (5) Purple 401 0.005 ( 6) Yellow No. 403 0.009 (7) Orange No. 205 0.030 (8) Hydroxyethyl cellulose 1.5 (9) NaOH proper amount (10) Purified water balance
【0032】(実施例7) 配合成分 配合量(%) (1)エタノール 20 (2)2−ベンジルオキシエタノール 5 (3)乳酸 7 (4)黒色401号 0.005 (5)紫色401号 0.005 (6)橙色205号 0.045 (7)ポリマーJR−400*1 0.3 (8)アミソフトLS−11*2 0.3 (9)ヒドロキシエチルセルロース 1.7 (10)NaOH 適量 (11)精製水 バランス *1:UCC社製,カチオン化セルロース *2:味の素(株)製,ラウロイルグルタメートモノナトリウム塩(Example 7) Blending ingredients Blending amount (%) (1) Ethanol 20 (2) 2-Benzyloxyethanol 5 (3) Lactic acid 7 (4) Black 401 0.005 (5) Purple 401 0 0.005 (6) Orange No. 205 0.045 (7) Polymer JR-400 * 1 0.3 (8) Amisoft LS-11 * 2 0.3 (9) Hydroxyethyl cellulose 1.7 (10) NaOH proper amount (11) ) Purified water balance * 1: UCC, cationized cellulose * 2: Ajinomoto Co., lauroyl glutamate monosodium salt
【0033】(実施例8) 配合成分 配合量(%) (1)1,3−ブタンジオール 25 (2)ベンジルアルコール 5 (3)乳酸 7 (4)黒色401号 0.015 (5)紫色401号 0.030 (6)橙色205号 0.020 (7)ポリエーテル変性シリコーン*3 0.5 (8)ジメチルポリシロキサン*4 0.3 (9)キサンタンガム 1.0 (10)NaOH 適量 (11)精製水 バランス *3:信越化学(株)製,KF352A *4:400万センチストークス(Example 8) Blending component blending amount (%) (1) 1,3-butanediol 25 (2) benzyl alcohol 5 (3) lactic acid 7 (4) black 401 0.015 (5) purple 401 No. 0.030 (6) Orange No. 205 0.020 (7) Polyether-modified silicone * 3 0.5 (8) Dimethylpolysiloxane * 4 0.3 (9) Xanthan gum 1.0 (10) NaOH proper amount (11 ) Purified water balance * 3: Shin-Etsu Chemical Co., Ltd., KF352A * 4: 4 million centistokes
Claims (3)
1〜0.2グラム当量/lであることを特徴とする染毛
剤組成物。1. The following components (A) and (B) (A) Acid dye: 0.01 to 0.2% by weight (B) Organic solvent: 0.5 to 50% by weight, and a pH of 2.0. ~ 4.5 and a buffer capacity of 0.0
A hair dye composition, which is 1 to 0.2 gram equivalent / l.
1〜0.2グラム当量/lであることを特徴とする染毛
剤組成物。2. The following components (A) and (B) (A) one or more acid dyes selected from Black No. 401, Purple No. 401, Orange No. 205, Yellow No. 403 and Red No. 106. 0.01 to 0.2 wt% (B) Organic solvent 0.5 to 50 wt% is contained, pH is 2.0 to 4.5 and buffer capacity is 0.0.
A hair dye composition, which is 1 to 0.2 gram equivalent / l.
布し、2分以内にすすぎ処理を行なうことを特徴とする
染毛方法。3. A hair dyeing method comprising applying the hair dye composition according to claim 1 to hair and rinsing the hair within 2 minutes.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP3241235A JPH0737370B2 (en) | 1991-09-20 | 1991-09-20 | Hair dye composition |
GB9218896A GB2259717B (en) | 1991-09-20 | 1992-09-07 | Hair dye composition |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP3241235A JPH0737370B2 (en) | 1991-09-20 | 1991-09-20 | Hair dye composition |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH0578228A true JPH0578228A (en) | 1993-03-30 |
JPH0737370B2 JPH0737370B2 (en) | 1995-04-26 |
Family
ID=17071216
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP3241235A Expired - Fee Related JPH0737370B2 (en) | 1991-09-20 | 1991-09-20 | Hair dye composition |
Country Status (2)
Country | Link |
---|---|
JP (1) | JPH0737370B2 (en) |
GB (1) | GB2259717B (en) |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH05238923A (en) * | 1992-02-28 | 1993-09-17 | Kao Corp | Hair dyeing composition |
JPH08268849A (en) * | 1996-05-02 | 1996-10-15 | Shiseido Co Ltd | Acidic hair-dyeing agent composition for head hair |
WO1999013840A1 (en) * | 1996-03-18 | 1999-03-25 | Lion Corporation | Hair dye composition |
JPH11269048A (en) * | 1998-03-20 | 1999-10-05 | Kao Corp | Hair dye composition |
JP2002020247A (en) * | 2000-07-05 | 2002-01-23 | Hoyu Co Ltd | Hair dye composition |
JP2002060327A (en) * | 2000-08-22 | 2002-02-26 | Hoyu Co Ltd | Foamy hair dye composition |
JP2002104942A (en) * | 2000-09-22 | 2002-04-10 | Kaminomoto Co Ltd | Acidic hair dye composition |
US6776803B2 (en) | 2001-02-15 | 2004-08-17 | Kao Corporation | Hair dye compositions |
JP2005239663A (en) * | 2004-02-27 | 2005-09-08 | Kao Corp | Hair cosmetic |
JP2008208033A (en) * | 2007-02-23 | 2008-09-11 | Mitsubishi Pencil Co Ltd | Hair dye and applicator for hair using the same |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4421031A1 (en) * | 1994-06-16 | 1995-12-21 | Henkel Kgaa | Direct hair dye |
DE19926377A1 (en) * | 1999-06-10 | 2000-12-14 | Henkel Kgaa | Agent for dyeing keratin fibers |
US20010042276A1 (en) * | 2000-03-30 | 2001-11-22 | Shiseido Co., Ltd. | Hair dye fixatives, hair dyes and hair dyeing methods |
JP2003530335A (en) * | 2000-04-07 | 2003-10-14 | ザ、プロクター、エンド、ギャンブル、カンパニー | Hair coloring method |
FR2882520B1 (en) * | 2005-02-25 | 2007-05-25 | Oreal | KERATIN FIBER DYEING COMPOSITION COMPRISING DIRECT SULFONAMIDOXANTHENIC DYE AND METHOD OF DYING USING THE SAME |
GB2506692A (en) * | 2012-10-08 | 2014-04-09 | Hds Ltd | Further methods and compounds for reducing allergic reactions to hair dyes |
DE102016209468A1 (en) | 2016-05-31 | 2017-11-30 | Henkel Ag & Co. Kgaa | Hair-sparing agents and methods of oxidative hair dyeing or bleaching with selected dicarboxylic acids |
DE102016202649A1 (en) | 2016-02-22 | 2017-08-24 | Henkel Ag & Co. Kgaa | Hair dyes containing substantive dyes and inorganic buffer systems |
JP2017193513A (en) * | 2016-04-22 | 2017-10-26 | ロレアル | Composition for dyeing keratin fibers |
GB201800877D0 (en) | 2018-01-19 | 2018-03-07 | Perachem Ltd | Method and composition |
GB201817000D0 (en) | 2018-10-18 | 2018-12-05 | Perachem Ltd | Method and composition |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH02262509A (en) * | 1989-03-31 | 1990-10-25 | Serutetsuku Lab Kk | Hair dyeing agent |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH1022007A (en) * | 1996-07-01 | 1998-01-23 | Joji Kawai | Multifunction connector |
JP3834702B2 (en) * | 1996-08-08 | 2006-10-18 | 東洋アルミニウム株式会社 | Cover tape for polystyrene embossed carrier tape |
-
1991
- 1991-09-20 JP JP3241235A patent/JPH0737370B2/en not_active Expired - Fee Related
-
1992
- 1992-09-07 GB GB9218896A patent/GB2259717B/en not_active Expired - Fee Related
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH02262509A (en) * | 1989-03-31 | 1990-10-25 | Serutetsuku Lab Kk | Hair dyeing agent |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH05238923A (en) * | 1992-02-28 | 1993-09-17 | Kao Corp | Hair dyeing composition |
JPH0737371B2 (en) * | 1992-02-28 | 1995-04-26 | 花王株式会社 | Hair dye composition |
WO1999013840A1 (en) * | 1996-03-18 | 1999-03-25 | Lion Corporation | Hair dye composition |
JPH08268849A (en) * | 1996-05-02 | 1996-10-15 | Shiseido Co Ltd | Acidic hair-dyeing agent composition for head hair |
JPH11269048A (en) * | 1998-03-20 | 1999-10-05 | Kao Corp | Hair dye composition |
JP2002020247A (en) * | 2000-07-05 | 2002-01-23 | Hoyu Co Ltd | Hair dye composition |
JP2002060327A (en) * | 2000-08-22 | 2002-02-26 | Hoyu Co Ltd | Foamy hair dye composition |
JP2002104942A (en) * | 2000-09-22 | 2002-04-10 | Kaminomoto Co Ltd | Acidic hair dye composition |
US6776803B2 (en) | 2001-02-15 | 2004-08-17 | Kao Corporation | Hair dye compositions |
JP2005239663A (en) * | 2004-02-27 | 2005-09-08 | Kao Corp | Hair cosmetic |
JP2008208033A (en) * | 2007-02-23 | 2008-09-11 | Mitsubishi Pencil Co Ltd | Hair dye and applicator for hair using the same |
Also Published As
Publication number | Publication date |
---|---|
GB2259717A (en) | 1993-03-24 |
JPH0737370B2 (en) | 1995-04-26 |
GB9218896D0 (en) | 1992-10-21 |
GB2259717B (en) | 1995-05-24 |
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