JPH05345708A - Hair-fixing agent composition - Google Patents
Hair-fixing agent compositionInfo
- Publication number
- JPH05345708A JPH05345708A JP27288492A JP27288492A JPH05345708A JP H05345708 A JPH05345708 A JP H05345708A JP 27288492 A JP27288492 A JP 27288492A JP 27288492 A JP27288492 A JP 27288492A JP H05345708 A JPH05345708 A JP H05345708A
- Authority
- JP
- Japan
- Prior art keywords
- hair
- guar gum
- hair styling
- copolymer
- foam
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Abstract
Description
【0001】[0001]
【産業上の利用分野】本発明は整髪料組成物に関し、さ
らに詳しくは泡特性、整髪性及び風合いに優れる泡状整
髪料に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a hair styling composition, and more particularly to a foam hair styling material having excellent foaming properties, hair styling properties and texture.
【0002】[0002]
【従来の技術及び発明が解決しようとする課題】近年、
泡状整髪料はその簡便性と仕上り感の軽さが人気を呼
び、その市場占有率を上げている。このような製品の泡
状エアゾール組成物としては、一般にポリビニルピロリ
ドン、ビニルピロリドン・酢酸ビニル共重合体、酢酸ビ
ニル・クロトン酸共重合体、カルボキシル化酢酸ビニル
共重合体、ビニルメチルエーテル・マレイン酸ハーフエ
ステル共重合体、アクリル系樹脂(アニオン性、両性)
等の皮膜形成性ポリマーを水、エタノール、油剤、界面
活性剤等に溶かし、さらに液化石油ガス等の噴射剤を配
合したものが用いられている。泡状整髪料とは、上記組
成物を手、櫛等を用いて髪に塗布して整髪し、ヘアスタ
イルを保持するものである。2. Description of the Related Art In recent years,
Foamed hair styling products are gaining popularity because of their simplicity and light finish, and are increasing their market share. Foam aerosol compositions for such products generally include polyvinylpyrrolidone, vinylpyrrolidone / vinyl acetate copolymer, vinyl acetate / crotonic acid copolymer, carboxylated vinyl acetate copolymer, vinyl methyl ether / maleic acid half. Ester copolymer, acrylic resin (anionic, amphoteric)
A film-forming polymer such as is dissolved in water, ethanol, an oil agent, a surfactant or the like, and further mixed with a propellant such as liquefied petroleum gas is used. The foamy hair styling agent is one in which the above composition is applied to the hair using a hand, a comb or the like to style the hair and maintain the hairstyle.
【0003】かかる泡状整髪料には充分な整髪性に加え
て、泡のキメ、もち、のびの良さといった優れた泡特性
と整髪した髪のつや、柔らかさ、しっとり感といった風
合いとが要求される。In addition to sufficient hair styling properties, such a foamy hair styling material is required to have excellent foaming properties such as texture, stickiness, and spreadability of the hair, and shine, softness, and moisturizing feel of the hair styling. It
【0004】しかし、これらすべてを満足する泡状整髪
料はいまだ得られてはいない。例えば、セット基剤とし
て硬い被膜を形成し得るポリマーを選択した場合、整髪
性は良好だが仕上りがごわごわして風合いが悪く、それ
に加え泡質もキメ、もち、のび等の点で満足は得られな
い。一方、ポリマー被膜を柔らかいものとするために種
々の油剤、界面活性剤等を配合した場合、仕上りは柔ら
かいが、セット力、もちが低下してヘアスタイルが崩
れ、整髪料の本来の目的は達成できない。However, a foamy hair styling material satisfying all of these has not been obtained yet. For example, when a polymer capable of forming a hard film is selected as the set base, the hair styling property is good, but the finish is stiff and the texture is poor, and in addition, the foam quality is satisfactory in terms of texture, stickiness, and spreadability. Absent. On the other hand, when various oil agents, surfactants, etc. are blended in order to make the polymer coating soft, the finish is soft, but the setting power and moisturizing deteriorate and the hairstyle collapses, achieving the original purpose of the hair styling product. Can not.
【0005】そこで、整髪性とともに、泡特性、風合い
等の点でも十分満足のいく泡状整髪料の開発が強く望ま
れていた。Therefore, there has been a strong demand for the development of a foamy hair styling material which is sufficiently satisfactory in terms of the hair styling property as well as the foam characteristics and the texture.
【0006】[0006]
【課題を解決するための手段】本発明者らは、かかる実
情に鑑み鋭意検討した結果、後述するように特定のポリ
マー種を組合せたものに噴射剤を配合させた整髪料が良
好な整髪性、泡特性及び風合いを示すことを見出し、本
発明を完成するに至った。Means for Solving the Problems As a result of intensive studies in view of the above circumstances, the present inventors have found that a hair styling product in which a propellant is blended with a combination of specific polymer species has a good hair styling property as described later. The present invention has been completed based on the finding that it exhibits foam characteristics and texture.
【0007】すなわち、本発明は、下記(a)、(b)
及び(c): (a)被膜形成性ポリマー (b)未変性グアーガム、グアーガムの非イオン性誘導
体及びグアーガムのカチオン性誘導体から選ばれる1種
又は2種以上 (c)噴射剤 を含有することを特徴とする整髪料組成物を提供するも
のである。That is, the present invention provides the following (a) and (b)
And (c): (a) a film-forming polymer (b) containing one or more kinds selected from unmodified guar gum, a nonionic derivative of guar gum and a cationic derivative of guar gum, and (c) a propellant. The present invention provides a characteristic hair styling composition.
【0008】なお、西独国特許出願3632030A号
公報にはフィルム形成性樹脂に、アニオン性又はカチオ
ン性ポリマーを含有する整髪料が開示されているが、こ
の整髪料は、泡特性及び風合いの点で満足のいくもので
はなかった。[0008] Incidentally, West German Patent Application No. 363,030A discloses a hair styling composition containing an anionic or cationic polymer in a film-forming resin. This hair styling composition has a foaming property and a texture. It was not satisfactory.
【0009】本発明に使用される成分(a)の被膜形成
性ポリマーとしては、例えばアニオン性、カチオン性、
ノニオン性、両性の各ポリマーが挙げられ、具体的には
以下の(1)〜(8)に示すものなどが挙げられる。Examples of the film-forming polymer of the component (a) used in the present invention include anionic, cationic,
Examples include nonionic and amphoteric polymers, and specific examples include those shown in the following (1) to (8).
【0010】(1)ポリビニルピロリドン系高分子化合
物 ・ポリビニルピロリドン;市販品としてルビスコールK
12,K30(以上BASF社製)、PVP K15,
K30(以上GAF社製)などが挙げられる。 ・ビニルピロリドン/酢酸ビニル共重合体;市販品とし
てルビスコールVA28,VA73(以上BASF社
製)、PVP/VA E−735,S−630(以上G
AF社製)などが挙げられる。 ・ビニルピロリドン/酢酸ビニル/プロピオン酸ビニル
三元共重合体;市販品としてルビスコールVAP343
(BASF社製)などが挙げられる。 ・ビニルピロリドン/アルキルアミノアクリレート(四
級塩化)共重合体;市販品としてルビフレックス(BA
SF社製)、コポリマー845,937,958、ガフ
カット755N(以上GAF社製)などが挙げられる。 ・ビニルピロリドン/アクリレート/(メタ)アクリル
酸共重合体;市販品としてルビフレックスVBM35
(BASF社製)などが挙げられる。 ・ビニルピロリドン/アルキルアミノアクリレート/ビ
ニルカプロラクタム共重合体;市販品としてコポリマー
VC−713(GAF社製)などが挙げられる。(1) Polyvinylpyrrolidone type polymer compound: polyvinylpyrrolidone; Rubiscol K as a commercial product
12, K30 (above BASF), PVP K15,
Examples include K30 (all manufactured by GAF). -Vinylpyrrolidone / vinyl acetate copolymer; as commercially available products, Rubiscol VA28, VA73 (above BASF), PVP / VA E-735, S-630 (above G
Manufactured by AF) and the like. -Vinylpyrrolidone / vinyl acetate / vinyl propionate terpolymer; rubiscol VAP343 as a commercial product
(Manufactured by BASF) and the like.・ Vinylpyrrolidone / alkylamino acrylate (quaternary chloride) copolymer; Rubiflex (BA
SF), copolymers 845, 937, 958, Gaffcut 755N (all manufactured by GAF) and the like. -Vinylpyrrolidone / acrylate / (meth) acrylic acid copolymer; Rubiflex VBM35 as a commercial product
(Manufactured by BASF) and the like. -Vinylpyrrolidone / alkylaminoacrylate / vinylcaprolactam copolymer; as a commercial item, copolymer VC-713 (manufactured by GAF) and the like can be mentioned.
【0011】(2)酸性ビニルエーテル系高分子化合物 ・メチルビニルエーテル/無水マレイン酸アルキルハー
フエステル共重合体;市販品としてガントレッツES−
225,ES−425,SP−215(以上GAF社
製)などが挙げられる。 (3)酸性ポリ酢酸ビニル系高分子化合物 ・酢酸ビニル/クロトン酸共重合体;市販品としてレジ
ン28−1310(ナショナル・スターチ社製)、ルビ
セットCA66(BASF社製)などが挙げられる。 ・酢酸ビニル/クロトン酸/ネオデカン酸ビニル共重合
体;市販品としてレジン28−2930(ナショナル・
スターチ社製)などが挙げられる。 ・酢酸ビニル/クロトン酸/プロピオン酸ビニル共重合
体;市販品としてルビセットCAP(BASF社製)な
どが挙げられる。(2) Polymeric compound of acidic vinyl ether-Methyl vinyl ether / maleic anhydride alkyl half ester copolymer; Gantrez ES- as a commercial product
225, ES-425, SP-215 (all manufactured by GAF). (3) Acidic polyvinyl acetate polymer compound-Vinyl acetate / crotonic acid copolymer; examples of commercially available products include Resin 28-1310 (manufactured by National Starch) and Rubyset CA66 (manufactured by BASF).・ Vinyl acetate / crotonic acid / vinyl neodecanoate copolymer; Resin 28-2930 (National
Starch) and the like. -Vinyl acetate / crotonic acid / vinyl propionate copolymer; commercially available products include Rubiset CAP (manufactured by BASF).
【0012】(4)酸性アクリル系高分子化合物 ・(メタ)アクリル酸/(メタ)アクリル酸エステル共
重合体;市販品としてプラスサイズL53P(互応化学
(株)製)、ダイヤホールド(三菱油化(株)製)など
が挙げられる。 ・アクリル酸/アクリル酸アルキルエステル/アルキル
アクリルアミド共重合体;市販品としてウルトラホール
ド8(BASF社製)、アンフォマーV−42(ナショ
ナル・スターチ社製)などが挙げられる。 (5)両性アクリル系高分子化合物 ・N−メタクリロイルエチル−N,N−ジメチルアンモ
ニウム・α−N−メチルカルボキシベタイン/メタクリ
ル酸ブチル共重合体;市販品としてユカフォーマーM−
75,SM(以上三菱油化(株)製)などが挙げられ
る。 ・アクリル酸ヒドロキシプロピル/メタクリル酸ブチル
アミノエチル/アクリル酸オクチルアミド共重合体;市
販品としてアンフォマー28−4910(ナショナル・
スターチ社製)などが挙げられる。(4) Acidic acrylic polymer compound (meth) acrylic acid / (meth) acrylic acid ester copolymer; plus size L53P (manufactured by Mutual Chemical Co., Ltd.) as a commercial product, DIAHOLD (Mitsubishi Petrochemical Co., Ltd.) (Manufactured by Co., Ltd.) and the like. -Acrylic acid / acrylic acid alkyl ester / alkyl acrylamide copolymer; examples of commercially available products include Ultrahold 8 (manufactured by BASF) and Amphomer V-42 (manufactured by National Starch). (5) Amphoteric acrylic polymer compound-N-methacryloylethyl-N, N-dimethylammonium-α-N-methylcarboxybetaine / butyl methacrylate copolymer; Yukaformer M- as a commercial product
75, SM (all manufactured by Mitsubishi Petrochemical Co., Ltd.) and the like.・ Hydroxypropyl acrylate / butylaminoethyl methacrylate / octylamide acrylate copolymer; Amphomer 28-4910 (National
Starch) and the like.
【0013】(6)塩基性アクリル系高分子化合物 ・アクリルアミド・アクリルエステル系四元共重合体;
特開平2−180911号公報に記載されているもの等
が挙げられる。 (7)セルロース誘導体 ・カチオン性セルロース誘導体;市販品としてセルコー
トH−100,L−200(ナショナル・スターチ社
製)などが挙げられる。 (8)キチン・キトサン誘導体 ・ヒドロキシプロピルキトサン;市販品としてキトフィ
ルマー(一丸ファルコス社製)などが挙げられる。 ・カルボキシメチルキチン ・カルボキシメチルキトサン(6) Basic acrylic polymer compound: acrylamide-acrylic ester quaternary copolymer;
The thing etc. which are described in Unexamined-Japanese-Patent No. 2-180911 are mentioned. (7) Cellulose derivative-Cationic cellulose derivative; commercially available products such as Cellcoat H-100 and L-200 (manufactured by National Starch). (8) Chitin / chitosan derivative-Hydroxypropyl chitosan; examples of commercially available products include chitofilmer (manufactured by Ichimaru Falcos).・ Carboxymethyl chitin ・ Carboxymethyl chitosan
【0014】これらの皮膜形成性ポリマーのうち、特に
ビニルピロリドン/ジメチルアミノエチルメタクリレー
ト四級塩化共重合体、セチルジメチル−(2−ヒドロキ
シエチル)アンモニウムリン酸、ヒドロキシエチルセル
ロースヒドロキシプロピルトリメチルアンモニウムクロ
リドエーテル等のカチオンポリマーが好ましく、就中、
ビニルピロリドン/ジメチルアミノエチルメタクリレー
ト四級塩化共重合体が好ましい。Among these film-forming polymers, vinylpyrrolidone / dimethylaminoethyl methacrylate quaternary chloride copolymer, cetyldimethyl- (2-hydroxyethyl) ammonium phosphate, hydroxyethylcellulose hydroxypropyltrimethylammonium chloride ether, etc. Cationic polymers are preferred, especially
A vinylpyrrolidone / dimethylaminoethyl methacrylate quaternary chlorinated copolymer is preferred.
【0015】成分(a)は本発明組成物中0.1〜10
重量%使用されることが好ましい。The component (a) is 0.1 to 10 in the composition of the present invention.
It is preferably used in weight percent.
【0016】本発明に使用される成分(b)のグアーガ
ム(一般名:ガラクトマンナン)は、一年性の豆科植物
であるグアー豆の胚乳部分より得られる水溶性の天然多
糖類であって、マンノース主鎖とガラクトース側鎖とが
2:1の割合でβ−グルコシド結合しているものであ
る。The component (b), guar gum (generic name: galactomannan) used in the present invention is a water-soluble natural polysaccharide obtained from the endosperm portion of guar beans, which is an annual legume plant. , The main chain of mannose and the side chain of galactose are β-glucoside linked at a ratio of 2: 1.
【0017】グアーガムは、未変性のもの及び各種の変
性誘導体が知られているが、本発明においては未変性グ
アーガム、グアーガムの非イオン性誘導体及びカチオン
性誘導体から選ばれる1種又は2種以上が使用される。Although unmodified guar gum and various modified derivatives are known, in the present invention, one or more selected from unmodified guar gum, nonionic derivative and cationic derivative of guar gum. used.
【0018】これらの具体例としては、未変性グアーガ
ム(MEYHALL社製、MEYPRO−GAT12
0)、ヒドロキシプロピル化グアーガム(非イオン性誘
導体:MEYHALL社製、JAGUAR−HP−1
1)、ヒドロキシプロピルトリメチルアンモニウムクロ
ライドグアーガム(カチオン性誘導体:MEYHALL
社製、JAGUAR−C−13−S)等が挙げられ、好
ましくはグアーガムのカチオン性誘導体が挙げられる。Specific examples of these include unmodified guar gum (manufactured by MEYHALL, MEYPRO-GAT12).
0), hydroxypropylated guar gum (nonionic derivative: manufactured by MEYHALL, JAGUAR-HP-1)
1), hydroxypropyltrimethylammonium chloride guar gum (cationic derivative: MEYHALL
Manufactured by JAGUAR-C-13-S) and the like, and preferably a cationic derivative of guar gum.
【0019】成分(b)は、本発明組成物中0.005
〜5重量%使用されることが好ましい。The component (b) is 0.005 in the composition of the present invention.
It is preferable to use -5% by weight.
【0020】本発明に使用される成分(c)の噴射剤と
しては、液化石油ガス(LPG)、ジメチルエーテル、
メチルエチルエーテル、ジエチルエーテル等が好まし
い。As the propellant of the component (c) used in the present invention, liquefied petroleum gas (LPG), dimethyl ether,
Methyl ethyl ether, diethyl ether and the like are preferable.
【0021】成分(c)は、本発明組成物中1〜15重
量%使用されることが好ましい。Component (c) is preferably used in the composition of the present invention in an amount of 1 to 15% by weight.
【0022】本発明の整髪料組成物には、その使用目的
に応じて更に、保湿剤、薬剤、紫外線吸収剤、防腐剤、
酸化防止剤、前記以外の高分子、顔料、分散剤、金属イ
オン封鎖剤、低級アルコール、生薬抽出物、ムコ多糖
類、アミノ酸類、蛋白質類、色素、香料等の任意成分を
添加することができる。これらの任意成分は水に溶解、
分散させてから配合することが好ましい。The hair styling composition of the present invention further comprises a moisturizing agent, a drug, an ultraviolet absorber, an antiseptic, and a preservative, depending on the purpose of use.
Antioxidants, polymers other than the above, pigments, dispersants, sequestering agents, lower alcohols, crude drug extracts, mucopolysaccharides, amino acids, proteins, pigments, fragrances and other optional components can be added. .. These optional ingredients are soluble in water,
It is preferable to mix after dispersing.
【0023】本発明の整髪料組成物の調製方法は特に限
定されないが、成分(a)及び成分(b)を水又は低級
アルコールに溶解し混合したものに成分(c)を添加、
混合することにより調製する方法が好ましい。The method for preparing the hair styling composition of the present invention is not particularly limited, but the component (c) is added to a mixture of the components (a) and (b) dissolved in water or a lower alcohol, and mixed,
A method of preparing by mixing is preferable.
【0024】本発明の整髪料組成物は、毛髪に直接つけ
て、すすがない剤として用いることが好ましく、用途に
応じて種々の形態とすることができ、例えばセットロー
ション、ブロースタイリングローション、スタイリング
剤、ヘアトリートメント剤、ヘアミスト剤、ヘアムース
剤、ヘアクリーム等として提供することができる。The hair styling composition of the present invention is preferably applied directly to the hair and used as a soot-free agent, and can be made into various forms depending on the application, for example, set lotion, blow styling lotion, styling. Agent, hair treatment agent, hair mist agent, hair mousse agent, hair cream and the like.
【0025】[0025]
【発明の効果】本発明の整髪料組成物は、髪のくせづけ
易さ、セットのもちといった整髪性、泡のキメ、もち、
のびの良さといった泡特性、さらに髪のつや、柔かさ、
しっとり感といった風合いに優れるものである。EFFECTS OF THE INVENTION The hair styling composition of the present invention is characterized by easiness of curling hair, hair styling property such as moisturizing of hair, texture of foam, and moisturizing effect.
Foam characteristics such as good spreadability, gloss of hair, softness,
It has an excellent moist feel.
【0026】[0026]
【実施例】以下に本発明を実施例により具体的に説明す
るが、本発明はこれらに限定されるものではない。EXAMPLES The present invention will now be described in detail with reference to examples, but the present invention is not limited thereto.
【0027】実施例1 表1〜表14に示す組成について、まず噴射剤以外のも
のを混合・溶解して原液となし、次いでこれに噴射剤を
添加し、耐圧容器に封入して整髪料組成物を調製した。Example 1 With respect to the compositions shown in Tables 1 to 14, first, a material other than a propellant was mixed and dissolved to form a stock solution, and then a propellant was added to this, which was then sealed in a pressure resistant container to prepare a hairdressing composition. The thing was prepared.
【0028】今迄にコールドパーマ、ブリーチ等の美容
処理を行ったことのない日本人女性の毛髪約20g(約
15〜20cm)を束ね、シャンプーで洗浄後タオルドラ
イを行い、上記整髪料組成物をそれぞれ均一に塗布し、
さらにドライヤー乾燥を行った後、泡特性(泡のキメの
良さ、泡もちの良さ、泡ののび)、整髪性(髪のくせづ
け易さ、髪のセット力)、風合い(髪のつや、髪の柔ら
かさ、髪のしっとり感)等について10人の専門パネリ
ストが下記評価基準により評価した。その平均値を併せ
て表1〜表14に示す。About 20 g (about 15 to 20 cm) of hair of a Japanese woman who has not been subjected to cosmetic treatment such as cold perm or bleach has been bundled, washed with shampoo and towel dried, and the above hairdressing composition is prepared. Evenly,
After further drying with a dryer, foam characteristics (good texture of foam, goodness of foam, spread of foam), hair styling (easiness of curling hair, setting power of hair), texture (luster of hair, hair) Softness, moist feeling of hair, etc.) was evaluated by 10 professional panelists according to the following evaluation criteria. The average values are also shown in Tables 1 to 14.
【0029】(評価基準) ◎:非常に優れている ○:優れている △:やや優れている ×:良くない(Evaluation Criteria) ⊚: Very good ∘: Excellent Δ: Slightly excellent ×: Not good
【0030】[0030]
【表1】 [Table 1]
【0031】[0031]
【表2】 [Table 2]
【0032】[0032]
【表3】 [Table 3]
【0033】[0033]
【表4】 [Table 4]
【0034】[0034]
【表5】 [Table 5]
【0035】[0035]
【表6】 [Table 6]
【0036】[0036]
【表7】 [Table 7]
【0037】[0037]
【表8】 [Table 8]
【0038】[0038]
【表9】 [Table 9]
【0039】[0039]
【表10】 [Table 10]
【0040】[0040]
【表11】 [Table 11]
【0041】[0041]
【表12】 [Table 12]
【0042】[0042]
【表13】 [Table 13]
【0043】[0043]
【表14】 [Table 14]
【0044】 *1) GAF社製、GAFQUAT755N *2) BASF社製、LUVIQUAT MONO CP *3) NATIONAL STARCH AND CHE
MICAL社製、CELQUAT H−100 *4) 三菱油化(株)製、ユカフォーマーM−75 *5) GAF社製、ルビスコールK30 *6) 互応化学(株)製、プラスサイズL53P *7) MEYHALL社製、JAGUAR−C−13−S *8) MEYHALL社製、MEYPRO−GAT120 *9) MEYHALL社製、JAGUAR−HP−11 *11)MEYHALL社製、JAGUAR−CMHP *12)MEYHALL社製、MEYPRO−LOCUST
M−175 *13)UNION CARBIDE社製、POLYMER
JR400* 1) GAF, GAFQUAT755N * 2) BASF, LUVIQUAT MONO CP * 3) NATUALAL STARCH AND CHE
MICAL, CELQUAT H-100 * 4) Mitsubishi Petrochemical Co., Ltd., Yucaformer M-75 * 5) GAF, Rubiscol K30 * 6) Mutsou Kagaku Co., Ltd., plus size L53P * 7) MEYHALL Company, JAGUAR-C-13-S * 8) MEYHALL, MEYPRO-GAT120 * 9) MEYHALL, JAGUAR-HP-11 * 11) MEYHALL, JAGUAR-CMHP * 12) MEYHALL, MEYPRO -LOCUST
M-175 * 13) made by UNION CARBIDE, POLYMER
JR400
【0045】表1〜表14から明らかなように、本発明
品はいずれもおおむね、良好な泡特性、整髪性及び風合
いを示した。As is clear from Tables 1 to 14, all the products of the present invention generally showed good foam characteristics, hair styling properties and texture.
【0046】実施例2 表15に示す組成の泡状整髪料を実施例1と同様にして
調製した。Example 2 A foamy hair styling composition having the composition shown in Table 15 was prepared in the same manner as in Example 1.
【0047】[0047]
【表15】 [Table 15]
【0048】上記本発明品はいずれも良好な泡特性、整
髪性及び風合いを示すものであった。The above-mentioned products of the present invention all showed good foam properties, hair styling properties and texture.
【0049】実施例3 表16に示す組成の泡状染毛整髪料を実施例1と同様に
して調製した。Example 3 A foam hair dye having the composition shown in Table 16 was prepared in the same manner as in Example 1.
【0050】[0050]
【表16】 [Table 16]
【0051】上記本発明品はいずれも良好な泡特性、整
髪性及び風合いを示すものであった。The above-mentioned products of the present invention all showed good foam characteristics, hair styling properties and texture.
Claims (3)
体及びグアーガムのカチオン性誘導体から選ばれる1種
又は2種以上 (c)噴射剤 を含有することを特徴とする整髪料組成物。1. The following (a), (b) and (c): (a) a film-forming polymer (b) one selected from unmodified guar gum, a nonionic derivative of guar gum and a cationic derivative of guar gum, or A hairdressing composition comprising two or more (c) propellants.
ポリマーである請求項1記載の整髪料組成物。2. The hair styling composition according to claim 1, wherein the film-forming polymer (a) is a cationic polymer.
ロリドン/ジメチルアミノエチルメタクリレート四級塩
化共重合体である請求項1記載の整髪料組成物。3. The hair styling composition according to claim 1, wherein the film-forming polymer (a) is a vinylpyrrolidone / dimethylaminoethyl methacrylate quaternary chlorinated copolymer.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP27288492A JP2627706B2 (en) | 1992-04-15 | 1992-10-12 | Hairdressing composition |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP4-95404 | 1992-04-15 | ||
JP9540492 | 1992-04-15 | ||
JP27288492A JP2627706B2 (en) | 1992-04-15 | 1992-10-12 | Hairdressing composition |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH05345708A true JPH05345708A (en) | 1993-12-27 |
JP2627706B2 JP2627706B2 (en) | 1997-07-09 |
Family
ID=26436643
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP27288492A Expired - Fee Related JP2627706B2 (en) | 1992-04-15 | 1992-10-12 | Hairdressing composition |
Country Status (1)
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JP (1) | JP2627706B2 (en) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH07291840A (en) * | 1994-04-25 | 1995-11-07 | L'oreal Sa | Method of using guar gum in temporary shaping of keratinous fiber |
FR2729563A1 (en) * | 1995-01-20 | 1996-07-26 | Oreal | Use of guar gum as sole shaping and holding agent in compsn. |
WO1996023482A1 (en) * | 1995-02-02 | 1996-08-08 | L'oreal | Cosmetic composition containing non-ionic guar gum and a non-cross linked anionic polymer |
WO1998050007A1 (en) * | 1997-05-05 | 1998-11-12 | The Procter & Gamble Company | Styling shampoo compositions containing cationic styling polymers |
US6010690A (en) * | 1998-03-05 | 2000-01-04 | Bristol-Myers Squibb Company | Alkaline hair conditioning compositions containing cationic guar |
JP2012502907A (en) * | 2008-09-16 | 2012-02-02 | ルブリゾル アドバンスド マテリアルズ, インコーポレイテッド | Cationic polymers and their application to fixatives |
EP3773424A4 (en) * | 2018-03-30 | 2022-04-20 | ISP Investments LLC | Hair styling compositions comprising polygalactomanans, and method for using the same |
-
1992
- 1992-10-12 JP JP27288492A patent/JP2627706B2/en not_active Expired - Fee Related
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH07291840A (en) * | 1994-04-25 | 1995-11-07 | L'oreal Sa | Method of using guar gum in temporary shaping of keratinous fiber |
EP0682936A1 (en) * | 1994-04-25 | 1995-11-22 | L'oreal | Use of a guar gum in a non permanent shaping process of keratinic fibers |
FR2729563A1 (en) * | 1995-01-20 | 1996-07-26 | Oreal | Use of guar gum as sole shaping and holding agent in compsn. |
WO1996023482A1 (en) * | 1995-02-02 | 1996-08-08 | L'oreal | Cosmetic composition containing non-ionic guar gum and a non-cross linked anionic polymer |
FR2730162A1 (en) * | 1995-02-02 | 1996-08-09 | Oreal | COSMETIC COMPOSITION BASED ON NON-IONIC GUAR GUM AND NON-RETICLE ANIONIC POLYMER |
US6221347B1 (en) | 1995-02-02 | 2001-04-24 | L'oreal | Cosmetic composition based on nonionic guar gum and on non-crosslinked anionic polymer |
WO1998050007A1 (en) * | 1997-05-05 | 1998-11-12 | The Procter & Gamble Company | Styling shampoo compositions containing cationic styling polymers |
US6010690A (en) * | 1998-03-05 | 2000-01-04 | Bristol-Myers Squibb Company | Alkaline hair conditioning compositions containing cationic guar |
JP2012502907A (en) * | 2008-09-16 | 2012-02-02 | ルブリゾル アドバンスド マテリアルズ, インコーポレイテッド | Cationic polymers and their application to fixatives |
EP3773424A4 (en) * | 2018-03-30 | 2022-04-20 | ISP Investments LLC | Hair styling compositions comprising polygalactomanans, and method for using the same |
Also Published As
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