JPH0332575A - Grinding wheel with blow hole and manufacture thereof - Google Patents
Grinding wheel with blow hole and manufacture thereofInfo
- Publication number
- JPH0332575A JPH0332575A JP16741389A JP16741389A JPH0332575A JP H0332575 A JPH0332575 A JP H0332575A JP 16741389 A JP16741389 A JP 16741389A JP 16741389 A JP16741389 A JP 16741389A JP H0332575 A JPH0332575 A JP H0332575A
- Authority
- JP
- Japan
- Prior art keywords
- grinding wheel
- granules
- grinding
- fine powder
- pores
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000227 grinding Methods 0.000 title claims abstract description 53
- 238000004519 manufacturing process Methods 0.000 title claims description 17
- 239000008187 granular material Substances 0.000 claims abstract description 25
- 239000000843 powder Substances 0.000 claims abstract description 15
- 239000011230 binding agent Substances 0.000 claims abstract description 8
- 238000002156 mixing Methods 0.000 claims abstract description 6
- 229940057995 liquid paraffin Drugs 0.000 claims abstract description 5
- 238000010304 firing Methods 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 8
- 239000000945 filler Substances 0.000 claims description 7
- 230000001050 lubricating effect Effects 0.000 claims 1
- 239000002245 particle Substances 0.000 abstract description 3
- 238000007730 finishing process Methods 0.000 abstract description 2
- 239000011148 porous material Substances 0.000 description 22
- 239000000463 material Substances 0.000 description 9
- 238000000465 moulding Methods 0.000 description 6
- 230000000694 effects Effects 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000006061 abrasive grain Substances 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 229910003460 diamond Inorganic materials 0.000 description 2
- 239000010432 diamond Substances 0.000 description 2
- 239000010419 fine particle Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000010438 granite Substances 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 238000003754 machining Methods 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 229910005091 Si3N Inorganic materials 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 239000010953 base metal Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 239000004567 concrete Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 239000012809 cooling fluid Substances 0.000 description 1
- 239000000110 cooling liquid Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 229910000859 α-Fe Inorganic materials 0.000 description 1
Landscapes
- Polishing Bodies And Polishing Tools (AREA)
Abstract
Description
【発明の詳細な説明】
[産業上の利用分野]
本発明による有気孔研削砥石は石材、コンクリート、ア
スファルトなどの土木建設関連分野、シリコン、フェラ
イトなど電子関連分野、或いは機械、金属材料関連分野
で切断、研削に用いられるものである。[Detailed Description of the Invention] [Industrial Application Fields] The porous grinding wheel according to the present invention can be used in civil engineering and construction related fields such as stone, concrete and asphalt, electronic related fields such as silicon and ferrite, or mechanical and metal material related fields. It is used for cutting and grinding.
[従来の技術]
近年上述の各種材料の加工には超砥粒研削砥石が使用さ
れるようになってきたが多くの場合メタルボンド或いは
レジンボンドのいずれも無気孔研削砥石が使用されてい
る。[Prior Art] In recent years, superabrasive grinding wheels have come to be used for processing the various materials mentioned above, but in many cases, nonporous grinding wheels are used for either metal bond or resin bond.
[51!明が解決しようとする課題〕
メタルボンド或いはレジンボンド超砥粒研削砥石は粉末
材料を加圧、焼成して製造されるため、砥石構成要素の
一つである気孔を作ることが一般には困難であり市場で
広く使用されている超砥粒研削砥石の多くは無気孔研削
砥石である。[51! The problem that Ming is trying to solve] Since metal-bonded or resin-bonded superabrasive grinding wheels are manufactured by pressurizing and firing powder materials, it is generally difficult to create pores, which are one of the constituent elements of the grinding wheel. Most of the superabrasive grinding wheels widely used in the market are nonporous grinding wheels.
この無気孔研削砥石の問題点は気孔が無いため切り粉の
排除が困難なこと、冷却液が加工部分に浸透しに(いこ
と、加工物と結合材とが摩擦しやすいことである。この
結果として加工点の温度上昇による研削焼け、砥石口づ
まりによる研削抵抗の増大、切れ味や寿命の低下、スク
ラッチや割れの発生などで加工能率を上げることができ
ず、又加工物の品質上の問題にもつながった。さらに加
工中に目づまりを起こし作業を中断しドレッシングしな
ければならない場合も多くあった。The problems with this non-porous grinding wheel are that it is difficult to remove chips because it has no pores, that the coolant does not penetrate into the machined part, and that friction between the workpiece and the bonding material tends to occur. As a result, machining efficiency cannot be improved due to grinding burn due to increased temperature at the machining point, increased grinding resistance due to clogging of the grinding wheel, decreased sharpness and life, occurrence of scratches and cracks, and problems with the quality of the workpiece. In addition, there were many cases in which clogging occurred during processing, forcing the work to be interrupted and dressing to be performed.
[課題を解決するための手段]
上述の問題点を解決する方法として成形型に気孔形成用
突起物を植設し、この突起物によって気孔を形成する方
法が提案されている。く実開昭60−53467号公報
、実開昭62−92)58号公報)しかしこれらの方法
では型内に微細な突起物を多数植設しなければならない
上に、微細な突起物のため加圧焼成時に破損しやすい。[Means for Solving the Problems] As a method for solving the above-mentioned problems, a method has been proposed in which pore-forming protrusions are planted in a mold and pores are formed by the protrusions. However, in these methods, many fine protrusions must be implanted in the mold, and because of the fine protrusions, Easily damaged during pressure firing.
また気孔率を変えるためには突起物の大きさ、数量の異
なる各種成形型を用意する必要があり、製造技術上、製
造コスト上問題がある。また同提案には「結合材中に木
材チップ、微少炭等を分散混合し、焼成時に焼失させ所
望の気孔を形成するようにしてもよい」との記載がある
が、加圧焼成する製造方法では焼成させ形成した空洞は
成型圧力によって殆ど消滅し気孔の役目を果たさなくな
る場合が多い。Furthermore, in order to change the porosity, it is necessary to prepare various molds with different sizes and numbers of protrusions, which poses problems in terms of manufacturing technology and manufacturing costs. The same proposal also states that ``wood chips, fine charcoal, etc. may be dispersed and mixed in the binding material and burnt out during firing to form the desired pores,'' but the manufacturing method involves pressure firing. In many cases, the cavities formed by firing almost disappear due to the molding pressure and no longer play the role of pores.
本究明は上述の欠点を取り除いた新規な手段を提供する
ものである。即ち砥石構成物の一種に耐熱性の微粉末を
顆粒となし添加する。加圧、焼成の砥石製造工程では気
孔は形成されないが。The present study provides a new means that eliminates the above-mentioned drawbacks. That is, a heat-resistant fine powder is added in the form of granules to one of the components of the grinding wheel. However, pores are not formed during the pressurized and fired whetstone manufacturing process.
砥石仕上げ工程のツルーイング、ドレッシングにおいて
は表面の、使用に当たっては表面から順次、砥石構成物
の内、耐熱性微粒子よりなる顆粒を脱落せしめ気孔とす
る方法で、顆粒の大きさ、量の選択により、所望の大き
さの気孔或いはまた気孔率を具備した有気孔研削砥石を
提供することにある。In the truing and dressing process of the whetstone finishing process, the granules made of heat-resistant fine particles are removed from the surface of the whetstone in order to form pores, and by selecting the size and amount of the granules, The object of the present invention is to provide a porous grinding wheel having a desired size of pores or porosity.
[作 用]
メタルボンド、レジンボンド研削砥石を加圧、焼成法で
製造する場合、ガスの発生成いは燃焼によって有気孔研
削砥石を製造することは困難である。これはガスや燃焼
によって一時的に気孔ができても、加圧、焼成時の圧力
によって気孔が消滅するためである。本提案では耐熱性
の顆粒を用い加圧、焼成工程では無気孔研削砥石である
が、使用中に気孔が自然に形成され結果的に有気孔研削
砥石として有効に作用する製造手段をとった。その製造
工程と製造例について説明する。[Function] When manufacturing a metal bond or resin bond grinding wheel using a pressurizing or firing method, it is difficult to manufacture a porous grinding wheel by gas generation or combustion. This is because even if pores are temporarily created due to gas or combustion, they disappear due to the pressure applied during pressurization and firing. In this proposal, heat-resistant granules are used in the pressing and firing process to create a nonporous grinding wheel, but pores are naturally formed during use, resulting in a manufacturing method that effectively functions as a porous grinding wheel. The manufacturing process and manufacturing examples will be explained.
a)気孔の役割をする顆粒の製造
顆粒原料としては加圧焼成時に燃焼しないAl+lOs
、MgO,ZrO,、Sea、、StC,Si3N、な
どの微粉末を用いる。Sea。a) Production of granules that act as pores The raw material for granules is Al + lOs, which does not burn during pressure firing.
, MgO, ZrO, Sea, StC, Si3N, etc. are used. Sea.
微粉末を用いた場合を例として説明する。SeO□微粉
末を流動バラフィンと混合し、市販の顆粒装置を用い既
知の顆粒製造法によって粒径0.3w〜0.5−の顆粒
とした。顆粒の粒径は使用する超砥粒の大きさによって
変更するが、目安として超砥粒とほぼ同程度〜1/2程
度がよい。The case where fine powder is used will be explained as an example. The SeO□ fine powder was mixed with liquid paraffin and made into granules with a particle size of 0.3 w to 0.5 - by a known granule manufacturing method using a commercially available granulator. The particle size of the granules varies depending on the size of the superabrasive grains used, but as a rough guide, it is good to have approximately the same size to about 1/2 that of the superabrasive grains.
b)砥石の製造 メタルボンド研削砥石を例として説明する。b) Manufacturing of whetstones A metal bond grinding wheel will be explained as an example.
結合材としてコバルト粉末、超砥粒として40150メ
ツシユの合成ダイヤモンド、充填材として800メツシ
ユのアルミナ粉末を選び、これに上記顆粒を加え混合し
た。本例での体積混合比率は結合材65%、超砥粒2.
5%、充填材2.5%、それに顆粒30%である。これ
らの材料を通常の混合機を用い十分撹拌混合し、型に充
填し、加熱成型プレスによって、砥石チップに成型した
。混合比率は使用目的或いは加工物材種によって異なる
が、切れ味重視の場合は顆粒の比率を大きく、研削比(
寿命)を大きくする時は顆粒の比率を小さくする。成型
条件は不活性ガス雰囲気中で温度約900℃、圧力約3
00kgf/ln、時間約40分とした。成型後徐冷し
型からチップを取り出し、白金にロー付し砥石とした。Cobalt powder was selected as the binder, synthetic diamond of 40150 mesh was selected as the superabrasive, and alumina powder of 800 mesh was selected as the filler, and the above granules were added thereto and mixed. The volume mixing ratio in this example is 65% binder and 2% superabrasive.
5% filler, 2.5% filler, and 30% granules. These materials were sufficiently stirred and mixed using an ordinary mixer, filled into a mold, and molded into a grindstone chip using a hot molding press. The mixing ratio varies depending on the purpose of use or the material type of the workpiece, but if sharpness is important, the granule ratio should be increased and the grinding ratio (
When increasing the life span), reduce the granule ratio. The molding conditions are a temperature of approximately 900℃ and a pressure of approximately 3℃ in an inert gas atmosphere.
00 kgf/ln and the time was about 40 minutes. After molding, the chips were slowly cooled, taken out from the mold, and brazed with platinum to make a grindstone.
チップ製造は加熱成型法でなく冷間での成型、炉による
焼結でもよいがチップ強度はやや低くなる。製作した砥
石の概略図の一例を第1図に、チップの断面図の一例を
第2図に示す。チップ中には結合材、砥粒、充填材、顆
粒が均一に分散し、気孔はまだ形成されていない。気孔
となる空間はまだ顆粒の形で分散しており、チップ中に
は眞の空間はないので、空間のあるチップに比べ圧縮強
度は高く、加工中の圧力による弾性変形、塑性変形は少
ない。Instead of hot molding, the chip may be manufactured by cold molding or sintering in a furnace, but the chip strength will be somewhat lower. An example of a schematic diagram of the manufactured grindstone is shown in FIG. 1, and an example of a cross-sectional view of the chip is shown in FIG. The binder, abrasive grains, filler, and granules are uniformly dispersed in the chip, and pores have not yet been formed. The spaces that become pores are still dispersed in the form of granules, and there are no real spaces in the chip, so the compressive strength is higher than chips with spaces, and there is less elastic and plastic deformation due to pressure during processing.
このチップがドレッシング或いは使用された時に形成さ
れたチップ表面の気孔を第3図に示す。チップ中に分散
している顆粒は微粉末を顆粒状態に保持している流動バ
ラフィンが加熱工程で分解消失し、単に微粉の集合体に
なっている。そのためドレッシング時或いは使用時砕け
やすく、脱落しやすい。更に脱落孔は研削液による洗浄
作用により完全な気孔となる。FIG. 3 shows the pores formed on the surface of the chip when the chip was dressed or used. The granules dispersed in the chip are simply aggregates of fine powder as the liquid paraffin that holds the fine powder in a granular state decomposes and disappears during the heating process. Therefore, it tends to crumble and fall off during dressing or use. Furthermore, the drop-off pores become complete pores due to the cleaning action of the grinding fluid.
本例の如く顆粒用微粉末にSeO□等潤滑等電滑性るも
のを用いた場合、脱落微粒子が潤滑剤としても作用する
ので、加工物、目的によって顆粒用微粉末は選択される
。When a material with electrolubricity such as SeO□ is used as the fine powder for granules as in this example, the fallen fine particles also act as a lubricant, so the fine powder for granules is selected depending on the workpiece and purpose.
この形成された気孔により切り粉の目づまり、加工物と
結合材との摩擦を防止することができる。更に図の様に
気孔空間があるので砥石と加工物接触面(研削作用面)
に冷却i(研削液)が浸透しやすく、研削点の温度上昇
が防止でき、加工部品の温度上昇が小さく、研削焼け、
クラックの無い高品質部品を得ることができる。また目
づまりしにくく、研削抵抗も小さいので除去能率を高め
ることができる。The formed pores can prevent clogging of chips and friction between the workpiece and the binding material. Furthermore, as shown in the figure, there are pore spaces, so the contact surface between the grinding wheel and the workpiece (grinding surface)
Cooling fluid (grinding fluid) can easily penetrate into the surface, prevent temperature rise at the grinding point, reduce temperature rise of machined parts, and prevent grinding burn and
High quality parts without cracks can be obtained. In addition, it is less likely to clog and the grinding resistance is low, so removal efficiency can be increased.
[実 施 例]
前項で説明した方法で製造した壱気孔研削砥石と従来方
法で製造した無気孔研削砥石について花崗岩の平面研削
試験を実施しその除去能率を比較した。[Example] A granite surface grinding test was conducted on a one-pore grinding wheel manufactured by the method described in the previous section and a non-porous grinding wheel manufactured by a conventional method, and the removal efficiency was compared.
a)研削試験条件
加工物・・・・・・花崗岩
砥石・・・・・・・8インチ セグメント型有気孔及び
無気孔
・45mmX2CIM
・12個
・450rpm
・3.5m/min
セグメント寸法・
個数・
砥石回転数・・・
砥石送り速度・・
砥石押し付は力・・60kgf及び120kgf研削時
間・・・・・5分
研削液供給量・・・12L/rnin
b)試験結果(除去量)
有気孔砥石の試験中の研削台は低く良好な切れ味を示し
、除去量も従来の無気孔砥石の約163倍となった。a) Grinding test conditions Processed product: Granite grindstone: 8 inches Segment type with and without holes, 45 mm x 2 CIM, 12 pieces, 450 rpm, 3.5 m/min Segment dimensions, number of pieces, grinding wheel Rotation speed... Grinding wheel feed rate... Grinding wheel pressing force... 60 kgf and 120 kgf Grinding time... 5 minutes Grinding fluid supply amount... 12 L/rnin b) Test results (removal amount) Perforated grinding wheel The grinding table during the test showed good sharpness with a low height, and the removal amount was about 163 times that of a conventional non-porous grindstone.
[開明の効果]
これまで述べてきたように有気孔砥石の利点は
a)
b)
使用中のドレッシングが不要のためドレッシングによる
砥石の消耗がなく、またドレッシングによる無駄時間を
省くことができる。[Advantageous Effects] As described above, the advantages of a porous grindstone are a) b) No dressing is required during use, so the grindstone is not consumed by dressing, and wasted time due to dressing can be eliminated.
切れ味がよく目づまりしにくいので、除去能率が高い。It is sharp and does not clog easily, so it has high removal efficiency.
C)冷却液が加工部分へ浸透しやすく、研削温度が低く
加工部品の品質が向上する。C) The cooling liquid easily penetrates into the machined part, which lowers the grinding temperature and improves the quality of the machined parts.
の通りであるが本発明ではこの効果をもたらす気孔の大
きさ、分布を正確に制御できる製造方法を得ると共に、
潤滑剤の効果を併せ持つことを可能にした。However, the present invention provides a manufacturing method that can accurately control the size and distribution of pores that bring about this effect, and
This makes it possible to combine the effects of a lubricant.
第1図 研削砥石一実施例の側断面図
工・・・台金 2・・・砥石チップ
第2図 加圧、焼成されたチップ断面図3・・砥粒(ダ
イヤモンド) 4・・・充填材を含む結合材 5・・・
顆粒
第3図 使用中に形成された気孔を示すチップ断面図
6・顆粒の脱落により形成された気
孔Fig. 1 Side cross-sectional drawing of a grinding wheel - base metal 2... grinding wheel tip Fig. 2 Cross-sectional view of the pressurized and fired chip 3... abrasive grains (diamond) 4... filler Binding material containing 5...
Granules Figure 3 Chip cross section showing pores formed during use 6 Pores formed due to shedding of granules
Claims (3)
得た研削砥石において、耐熱性微粉末に流動バラフィン
等のバインダーを加えて顆粒となしたものを添加混合、
加圧、焼成した有気孔研削砥石。(1) In a grinding wheel obtained by mixing, pressurizing, and firing superabrasive grains, a binder, and a filler, granules obtained by adding a binder such as liquid paraffin to a heat-resistant fine powder are added and mixed;
A pressurized and fired porous grinding wheel.
研削砥石を製造する方法において、耐熱性の微粉末に流
動バラフィン等のバインダーを加えて顆粒となしたもの
をさらに添加混合し、加圧、焼成することを特徴とする
有気孔研削砥石の製造方法。(2) In a method of manufacturing a grinding wheel by mixing, pressurizing, and firing superabrasive grains, a binder, and a filler, a binder such as liquid paraffin is added to a heat-resistant fine powder to form granules. A method for manufacturing a porous grinding wheel, characterized by adding and mixing, pressurizing, and firing.
請求の範囲2に記載の有気孔研削砥石の製造方法。(3) A method for producing a porous grinding wheel according to claim 2, wherein a powder having lubricating properties is used as the heat-resistant fine powder.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1167413A JP2958349B2 (en) | 1989-06-29 | 1989-06-29 | Porous grinding wheel and its manufacturing method |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1167413A JP2958349B2 (en) | 1989-06-29 | 1989-06-29 | Porous grinding wheel and its manufacturing method |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH0332575A true JPH0332575A (en) | 1991-02-13 |
JP2958349B2 JP2958349B2 (en) | 1999-10-06 |
Family
ID=15849237
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP1167413A Expired - Fee Related JP2958349B2 (en) | 1989-06-29 | 1989-06-29 | Porous grinding wheel and its manufacturing method |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP2958349B2 (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2003053669A (en) * | 2001-08-10 | 2003-02-26 | Hitachi Zosen Corp | Grinding wheel for fluororesin bond polishing and manufacturing method therefor |
KR20030050316A (en) * | 2001-12-18 | 2003-06-25 | 박상준 | Apparatus for protecting a head and body in using TAEKWONDO |
JPWO2017119342A1 (en) * | 2016-01-06 | 2018-01-11 | バンドー化学株式会社 | Abrasive |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS50139487A (en) * | 1974-04-25 | 1975-11-07 | ||
JPS58188161U (en) * | 1982-06-09 | 1983-12-14 | 有限会社アカネ光学 | polishing tip |
JPH01177975A (en) * | 1987-12-29 | 1989-07-14 | Kawada Eng:Kk | Self-cavity generating grinding stone made in resinoid bonding system |
-
1989
- 1989-06-29 JP JP1167413A patent/JP2958349B2/en not_active Expired - Fee Related
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS50139487A (en) * | 1974-04-25 | 1975-11-07 | ||
JPS58188161U (en) * | 1982-06-09 | 1983-12-14 | 有限会社アカネ光学 | polishing tip |
JPH01177975A (en) * | 1987-12-29 | 1989-07-14 | Kawada Eng:Kk | Self-cavity generating grinding stone made in resinoid bonding system |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2003053669A (en) * | 2001-08-10 | 2003-02-26 | Hitachi Zosen Corp | Grinding wheel for fluororesin bond polishing and manufacturing method therefor |
KR20030050316A (en) * | 2001-12-18 | 2003-06-25 | 박상준 | Apparatus for protecting a head and body in using TAEKWONDO |
JPWO2017119342A1 (en) * | 2016-01-06 | 2018-01-11 | バンドー化学株式会社 | Abrasive |
Also Published As
Publication number | Publication date |
---|---|
JP2958349B2 (en) | 1999-10-06 |
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