JPH02218798A - Colored liquid washing and bleaching composition - Google Patents
Colored liquid washing and bleaching compositionInfo
- Publication number
- JPH02218798A JPH02218798A JP3957889A JP3957889A JPH02218798A JP H02218798 A JPH02218798 A JP H02218798A JP 3957889 A JP3957889 A JP 3957889A JP 3957889 A JP3957889 A JP 3957889A JP H02218798 A JPH02218798 A JP H02218798A
- Authority
- JP
- Japan
- Prior art keywords
- carbon atoms
- weight
- formula
- alkyl group
- general formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 18
- 239000007788 liquid Substances 0.000 title claims description 16
- 238000004061 bleaching Methods 0.000 title description 4
- 238000005406 washing Methods 0.000 title 1
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 27
- 239000000049 pigment Substances 0.000 claims abstract description 13
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 claims abstract description 11
- 150000001412 amines Chemical class 0.000 claims abstract description 10
- 150000001875 compounds Chemical class 0.000 claims abstract description 10
- 239000000126 substance Substances 0.000 claims abstract description 10
- 150000004671 saturated fatty acids Chemical class 0.000 claims abstract description 9
- RBTKNAXYKSUFRK-UHFFFAOYSA-N heliogen blue Chemical compound [Cu].[N-]1C2=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=NC([N-]1)=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=N2 RBTKNAXYKSUFRK-UHFFFAOYSA-N 0.000 claims abstract description 8
- 125000004432 carbon atom Chemical group C* 0.000 claims description 44
- -1 alkali metal hypochlorite Chemical class 0.000 claims description 29
- 229910052783 alkali metal Inorganic materials 0.000 claims description 20
- 239000007844 bleaching agent Substances 0.000 claims description 13
- 238000004140 cleaning Methods 0.000 claims description 12
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims description 12
- FSYKKLYZXJSNPZ-UHFFFAOYSA-N N-methylaminoacetic acid Natural products C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 claims description 8
- 108010077895 Sarcosine Proteins 0.000 claims description 8
- 229940043230 sarcosine Drugs 0.000 claims description 8
- 125000002947 alkylene group Chemical group 0.000 claims description 6
- 239000002280 amphoteric surfactant Substances 0.000 claims description 6
- 229960003237 betaine Drugs 0.000 claims description 6
- 230000001747 exhibiting effect Effects 0.000 claims description 5
- 238000002845 discoloration Methods 0.000 abstract description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract description 2
- 229910052802 copper Inorganic materials 0.000 abstract description 2
- 239000010949 copper Substances 0.000 abstract description 2
- 150000003839 salts Chemical class 0.000 abstract 3
- 239000003513 alkali Substances 0.000 abstract 2
- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 abstract 1
- 238000004040 coloring Methods 0.000 description 8
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 238000005562 fading Methods 0.000 description 6
- 239000003086 colorant Substances 0.000 description 4
- 239000012459 cleaning agent Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- 239000005708 Sodium hypochlorite Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000004042 decolorization Methods 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- SYELZBGXAIXKHU-UHFFFAOYSA-N dodecyldimethylamine N-oxide Chemical compound CCCCCCCCCCCC[N+](C)(C)[O-] SYELZBGXAIXKHU-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- ONHFWHCMZAJCFB-UHFFFAOYSA-N myristamine oxide Chemical compound CCCCCCCCCCCCCC[N+](C)(C)[O-] ONHFWHCMZAJCFB-UHFFFAOYSA-N 0.000 description 1
- ONLRKTIYOMZEJM-UHFFFAOYSA-N n-methylmethanamine oxide Chemical compound C[NH+](C)[O-] ONLRKTIYOMZEJM-UHFFFAOYSA-N 0.000 description 1
- 229930014626 natural product Natural products 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 235000003441 saturated fatty acids Nutrition 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- BTURAGWYSMTVOW-UHFFFAOYSA-M sodium dodecanoate Chemical compound [Na+].CCCCCCCCCCCC([O-])=O BTURAGWYSMTVOW-UHFFFAOYSA-M 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
- 229940082004 sodium laurate Drugs 0.000 description 1
- 229940079862 sodium lauryl sarcosinate Drugs 0.000 description 1
- 235000019795 sodium metasilicate Nutrition 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- ADWNFGORSPBALY-UHFFFAOYSA-M sodium;2-[dodecyl(methyl)amino]acetate Chemical compound [Na+].CCCCCCCCCCCCN(C)CC([O-])=O ADWNFGORSPBALY-UHFFFAOYSA-M 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は着色安定性の優れた着色液体洗浄漂白剤組成物
に関するものである。DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application] The present invention relates to a colored liquid cleaning bleach composition with excellent color stability.
従来より、次亜塩素酸アルカリ金属塩を主基剤とする洗
浄漂白剤組成物は多く知られている。BACKGROUND ART Conventionally, many cleaning bleach compositions containing an alkali metal hypochlorite as a main base have been known.
次亜塩素酸アルカリ金属塩は強力な酸化剤であり、特に
便器用洗浄剤においてはこの酸化剤の他に強酸、強アル
カリが併用されるので、その取扱いには充分な注意が必
要である。このため、使用者の安全を考慮し、洗浄剤の
通用部位を明確にするために洗浄剤を着色することが行
われている。Alkali metal hypochlorite is a strong oxidizing agent, and strong acids and strong alkalis are used in conjunction with this oxidizing agent, especially in toilet bowl cleaners, so great care must be taken when handling it. For this reason, in consideration of the safety of the user, cleaning agents are colored in order to clearly identify the areas to which the cleaning agent is applied.
しかしながら、塩素系などの酸化漂白剤においては着色
剤が経時的に退色し易いため、着色剤の選定が特に重要
であり、例えば次亜塩素酸塩と苛性アルカリとからなる
系に特定の銅フタロシアニン系顔料を配合して着色する
方法が報告されている。（特開昭５３−８６０４ ）し
かしながら、特開昭５３−８６０４の発明では、ＣｉＪ
＋ｉ−＋５Ｃ１ａＮｓＣｕ （ｎはＯ〜６の整数を示す
。）の銅フタロシアニン系顔料を使用しており、ｎが８
以上のものは脱色及び退色がひどく使用できないとして
いる。しかし、ｎが８以上のものは分散安定性が優れて
いることから、これらの銅フタロアミン系顔料を使用し
、しかも脱色及び退色のない技術の開発が望まれていた
。However, with oxidative bleaches such as chlorine-based bleaches, the colorant tends to fade over time, so the selection of the colorant is particularly important. A method of coloring by blending pigments has been reported. (JP 53-8604) However, in the invention of JP 53-8604, CiJ
A copper phthalocyanine pigment of +i-+5C1aNsCu (n is an integer from O to 6) is used, and n is 8.
The above materials are considered unusable due to severe bleaching and discoloration. However, since those with n of 8 or more have excellent dispersion stability, it has been desired to develop a technique that uses these copper phthaloamine pigments and does not cause decolorization or fading.
本発明者らは、酸化漂白剤系において上記−般式で表さ
れるｎが８以上の銅フタロシアニン系顔料を使用すべく
鋭意検討した結果、一般式（１）で表されるアミンオキ
サイド化合物及び飽和脂肪酸またはアルキルサルコシン
のアルカリ金属塩を含有する系においてはｎが８未満の
ものより８以上のものの方が安定であり、退色のないこ
とを見出した。The present inventors have conducted intensive studies to use a copper phthalocyanine pigment represented by the above formula (1) in which n is 8 or more in an oxidative bleach system. It has been found that in systems containing saturated fatty acids or alkali metal salts of alkyl sarcosine, those with n of 8 or more are more stable than those with n less than 8, and do not fade.
更に、驚くべきことに上記成分の他に一般式（３） 、
（４）で表されるベタイン型両性界面活性剤を含有す
る系ではさらに退色防止能が向上することを見出し本発
明を完成するに到った。Furthermore, surprisingly, in addition to the above components, general formula (3),
The present inventors have discovered that a system containing the betaine type amphoteric surfactant represented by (4) further improves the ability to prevent fading, and has completed the present invention.
すなわち、本発明は、
（ａ）次亜塩素酸アルカリ金属塩を０．５〜１０重量％
（ｂ）アルカリ性を呈する物質を０．１〜１０重量％（
ｃ）一般式 Ｒ，ＲＺＲｆｆＮ→０（１）（式中Ｒ，
は炭素数８〜２０のアルキル基を、Ｒ２＋Ｒ３は炭素数
１〜３のアルキル基を示す。）で表されるアミンオキサ
イド化合物を０．１〜５重量％
（ｄ）炭素数８〜１８の飽和脂肪酸または炭素数１０〜
１８のアルキルサルコシンのアルカリ金属塩を０．１〜
６重量％
（ｅ）一般式 ＣｉＪ＋ １−Ｃ１，、ＮａＣｕ
（２）（式中口は８〜１６の整数を示す。）
で表される銅フタロシアニン系顔料を０．０００１〜０
．０１重量％
含有することを特徴とする着色液体洗浄漂白剤組成物を
提供するものである。That is, the present invention provides: (a) 0.5 to 10% by weight of an alkali metal hypochlorite salt;
(b) 0.1 to 10% by weight of a substance exhibiting alkalinity (
c) General formula R, RZRffN→0(1) (in the formula R,
represents an alkyl group having 8 to 20 carbon atoms, and R2+R3 represents an alkyl group having 1 to 3 carbon atoms. ) 0.1 to 5% by weight of amine oxide compound represented by (d) Saturated fatty acid having 8 to 18 carbon atoms or 10 to 18 carbon atoms
18 alkyl sarcosine alkali metal salt from 0.1 to
6% by weight (e) General formula CiJ+ 1-C1,, NaCu
(2) (The middle part of the formula indicates an integer from 8 to 16.) Copper phthalocyanine pigment represented by 0.0001 to 0
．． 01% by weight of a colored liquid cleaning bleach composition.
さらに本発明は、
（ａ）次亜塩素酸アルカリ金属塩を０．５〜１０重量％
（ｂ）アルカリ性を呈する物質を０．１〜１０重量％（
ｃ）一般式 Ｒ，Ｒ，Ｒ，Ｎ→０（１）（式中Ｒ５は
炭素数８〜２０のアルキル基を、Ｒ１＋Ｒ１は炭素数１
〜３のアルキル基を示す。）で表されるアミンオキサイ
ド化合物を０．１〜５重量％
（ｄ）炭素数８〜１８の飽和脂肪酸または炭素数１０〜
１８のアルキルサルコシンのアルカリ金属塩を０．１〜
６重量％
（ｅ）一般式 ＣｚｚＨ＋ｈ−ＣＩ−ＮａＣｕ
（２）（式中ｎは８〜１６の整数を示す、）
で表される銅フタロシアニン系顔料をｏ、ｏｏｏｉ〜０
．０１重量％
げ）一般式
（式中、Ｒ４は炭素数８〜２２のアルキル基、Ｒｓ、Ｒ
ｈは炭素数１〜４のアルキル基、Ｒ１は炭素数１〜５の
アルキレン基を示す。）、
または一般式、
Ｒ９
（式中、Ｒ８は炭素数８〜２２のアルキル基、Ｒ９＋Ｒ
２、は炭素数１〜２のアルキル基、Ｒ１１は炭素数２〜
３のアルキレン基を示す。）
で表されるベタイン型両性界面活性剤の一種またはそれ
以上を０．１〜１０重量％
含有することを特徴とする着色液体洗浄漂白剤組成物を
提供するものである。Furthermore, the present invention provides: (a) 0.5 to 10% by weight of an alkali metal hypochlorite salt;
(b) 0.1 to 10% by weight of a substance exhibiting alkalinity (
c) General formula R, R, R, N → 0 (1) (in the formula, R5 is an alkyl group having 8 to 20 carbon atoms, and R1+R1 is an alkyl group having 1 carbon number
~3 represents an alkyl group. ) 0.1 to 5% by weight of amine oxide compound represented by (d) Saturated fatty acid having 8 to 18 carbon atoms or 10 to 18 carbon atoms
18 alkyl sarcosine alkali metal salt from 0.1 to
6% by weight (e) General formula CzzH+h-CI-NaCu
(2) (in the formula, n represents an integer of 8 to 16), a copper phthalocyanine pigment represented by o, oooi to 0
．． 01% by weight) General formula (wherein, R4 is an alkyl group having 8 to 22 carbon atoms, Rs, R
h represents an alkyl group having 1 to 4 carbon atoms, and R1 represents an alkylene group having 1 to 5 carbon atoms. ), or the general formula, R9 (wherein, R8 is an alkyl group having 8 to 22 carbon atoms, R9+R
2 is an alkyl group having 1 to 2 carbon atoms, and R11 is an alkyl group having 2 to 2 carbon atoms.
3 shows the alkylene group. The present invention provides a colored liquid cleaning bleach composition characterized by containing 0.1 to 10% by weight of one or more betaine type amphoteric surfactants represented by the following formulas.
本発明に使用される次亜塩素酸アルカリ金属塩（ａ）と
しては、通常次亜塩素酸ナトリウムが用いられる。As the alkali metal hypochlorite salt (a) used in the present invention, sodium hypochlorite is usually used.
アルカリ性を呈する物質ら）としては、水酸化ナトリウ
ム、炭酸ナトリウム、メタ珪酸ナトリウム、三燐酸ナト
リウム等が挙げられ、これらのうち水酸化ナトリウムが
好ましい。Examples of alkaline substances include sodium hydroxide, sodium carbonate, sodium metasilicate, sodium triphosphate, and among these, sodium hydroxide is preferred.
アミンオキサイド化合物（ｃ）を示す一般式（１）にお
いて、Ｒ１の炭素数８〜２０のアルキル基としてはオク
チル基、デシル基、ドデシル基、テトラデシル基、ヘキ
サデシル基、オクタデシル基などが挙げられる９これら
のうち、好ましくはドデシル基及びテトラデシル基であ
り、天然物から誘導された炭素数の異なるアルキル基の
混合物でもかまわない＊ Ｒ２，Ｌの炭素数１〜３のア
ルキル基としてはメチル基、エチル基、プロピル基など
が挙げられる。In the general formula (1) representing the amine oxide compound (c), examples of the alkyl group having 8 to 20 carbon atoms for R1 include octyl group, decyl group, dodecyl group, tetradecyl group, hexadecyl group, octadecyl group, etc. 9 Among these, dodecyl and tetradecyl groups are preferred, and mixtures of alkyl groups with different numbers of carbon atoms derived from natural products may also be used.* Examples of the alkyl groups with 1 to 3 carbon atoms for R2 and L include methyl and ethyl groups. , propyl group, etc.
アミンオキサイド化合物（ｃ）の具体的な例としては、
ラウリルジメチルアミンオキサイド、ミリスチルジメチ
ルアミンオキサイド及びヤシジメチルアミンオキサイド
などが挙げられる。Specific examples of the amine oxide compound (c) include:
Examples include lauryl dimethylamine oxide, myristyl dimethylamine oxide, and coconut dimethylamine oxide.
炭素数８〜１８の飽和脂肪酸または炭素数１０〜１８の
アルキルサルコシンのアルカリ金属塩（ｄ）としては、
通常ラウリン酸ナトリウム、ラウリルサルコシン酸ナト
リウムなど、及びこれら２種以上の混合物が用いられる
。As the alkali metal salt (d) of a saturated fatty acid having 8 to 18 carbon atoms or an alkyl sarcosine having 10 to 18 carbon atoms,
Usually, sodium laurate, sodium lauryl sarcosinate, etc., and mixtures of two or more of these are used.
ベタイン型両性界面活性剤げ）のうち、一般式（３）に
おいては、Ｒ４は炭素数８〜２２のアルキル基であり、
特に炭素数１２〜１８のアルキル基が好ましい＃ Ｒ
５＋Ｒ６は炭素数１〜４のアルキル基であり、このうち
炭素数１のメチル基が好ましい。Among betaine type amphoteric surfactants), in general formula (3), R4 is an alkyl group having 8 to 22 carbon atoms,
Particularly preferred is an alkyl group having 12 to 18 carbon atoms #R
5+R6 is an alkyl group having 1 to 4 carbon atoms, and among these, a methyl group having 1 carbon number is preferable.
Ｒ７は炭素数１〜５のアルキレン基であり、メチレン基
、プロピレン基、ブチレン基、ベンチレン基などが挙げ
られる。R7 is an alkylene group having 1 to 5 carbon atoms, and examples include a methylene group, a propylene group, a butylene group, and a bentylene group.
また、一般式（４）においては、Ｒ１１は炭素数８〜２
２のアルキル基であり、特に炭素数１２〜１日のアルキ
ル基が好ましいｅ Ｒ９＋ＲＩＯは炭素数１〜２のアル
キル基であり、このうち炭素数１のメチル基が好ましい
。Ｒ１１は炭素数２〜３のアルキレン基であり、エチレ
ン基、プロピレン基が挙げられる。In addition, in general formula (4), R11 has 8 to 2 carbon atoms.
R9+RIO is an alkyl group having 1 to 2 carbon atoms, and an alkyl group having 12 to 1 carbon atoms is particularly preferable. R11 is an alkylene group having 2 to 3 carbon atoms, and examples thereof include an ethylene group and a propylene group.
本発明の着色液体洗浄漂白剤組成物における次亜塩素酸
アルカリ金属塩（ａ）の含有量は、通常０．５〜１０重
量％、好ましくは２〜７重量％の範囲である。次亜塩素
酸アルカリ金属塩の含有量が０．５重量％未満になると
漂白刃が不足し、１０重量％を越える含有量は実際上必
要としない。The content of the alkali metal hypochlorite (a) in the colored liquid cleaning bleach composition of the present invention is usually in the range of 0.5 to 10% by weight, preferably 2 to 7% by weight. If the content of alkali metal hypochlorite is less than 0.5% by weight, the bleaching blade will be insufficient, and a content exceeding 10% by weight is not actually required.
アルカリ性を呈する物ｔ （ｂ）の含有量は、通常０．
１〜５重量％、好ましくは０．５〜５重量％の範囲であ
る。The content of the substance exhibiting alkalinity t (b) is usually 0.
It ranges from 1 to 5% by weight, preferably from 0.5 to 5% by weight.
アミンオキサイド化合物（ｃ）の含有量は、通常０．１
〜５重量％、好ましくは０．１〜３重量％の範囲である
。アミンオキサイド化合物（ｃ）の含有量が０．１重量
％未満になると退色がひどくなり、また５重量％を越え
ると次亜塩素酸アルカリ金属塩の安定性が損なわれる。The content of the amine oxide compound (c) is usually 0.1
-5% by weight, preferably 0.1-3% by weight. When the content of the amine oxide compound (c) is less than 0.1% by weight, discoloration becomes severe, and when it exceeds 5% by weight, the stability of the alkali metal hypochlorite is impaired.
炭素数８〜１８の飽和脂肪酸または炭素数１０〜１日の
アルキルサルコシンのアルカリ金属塩（ｄ）の含有量と
しては、通常０．１〜６重量％、好ましくは０．１〜４
重量％の範囲である。炭素数８〜１８の飽和脂肪酸また
は炭素数１０〜１８のアルキルサルコシンのアルカリ金
属塩（ｄ）の含有量が０．１重量％未満になると顔料の
退色が起こり、また６重量％を越えると顔料の分散性及
び次亜塩素酸アルカリ金属塩の安定性が悪くなる。The content of the alkali metal salt (d) of saturated fatty acid having 8 to 18 carbon atoms or alkyl sarcosine having 10 to 1 carbon atoms is usually 0.1 to 6% by weight, preferably 0.1 to 4% by weight.
% by weight. If the content of the alkali metal salt (d) of saturated fatty acid having 8 to 18 carbon atoms or alkyl sarcosine having 10 to 18 carbon atoms is less than 0.1% by weight, the pigment will discolor, and if it exceeds 6% by weight, the pigment will fade. The dispersibility of the alkali metal hypochlorite and the stability of the alkali metal hypochlorite deteriorate.
銅フタロシアニン系顔料（ｅ）は洗浄剤を所望の色に着
色するためにｏ、ｏｏｏｉ〜０．０１重量％の範囲で使
用される。その使用量が０．０００１重量％未満では着
色の効果が少な（、一方０．０１重量％を越える場合に
は分散安定性が低下する。なお、ｎがＯ〜７の銅フタロ
シアニン系顔料は本発明の系では脱色または退色が激し
く使用できない。The copper phthalocyanine pigment (e) is used in an amount of o, oooi to 0.01% by weight in order to color the cleaning agent in a desired color. If the amount used is less than 0.0001% by weight, the coloring effect will be small (on the other hand, if it exceeds 0.01% by weight, the dispersion stability will decrease. The system of the invention cannot be used because of severe bleaching or fading.
ベタイン型両性界面活性剤（ｆ）の含有量としては０．
０１〜ｉｏ重量％、好ましくは０．０３〜５重量％の範
囲である。ベタイン型両性界面活性剤（ｆ）の含有量が
、０．０１重量％未満になると退色防止効果を向上する
ことができず、又１０重量％を越える含有量は実際上必
要としない。The content of betaine type amphoteric surfactant (f) is 0.
It ranges from 0.01 to io weight %, preferably from 0.03 to 5 weight %. If the content of the betaine type amphoteric surfactant (f) is less than 0.01% by weight, the anti-fading effect cannot be improved, and a content exceeding 10% by weight is not actually required.
本発明の着色液体洗浄漂白剤組成物には、更に通常用い
られるような添加剤、例えば他の界面活性剤、キレート
剤、香料などの成分を配合することができる。The colored liquid cleaning bleach composition of the present invention may further contain commonly used additives such as other surfactants, chelating agents, fragrances, and the like.
本発明によれば、長期にわたって着色安定性に優れた着
色液体洗浄漂白剤組成物が得られる。According to the present invention, a colored liquid cleaning bleach composition having excellent coloring stability over a long period of time can be obtained.
次に実施例を挙げて本発明を説明するが、本発明はこれ
らの実施例に限定されるものではない。Next, the present invention will be explained with reference to Examples, but the present invention is not limited to these Examples.
１〜３ び ｌ〜６
表−１に示す組成の各着色液体洗浄漂白剤組成物を調製
し、それぞれの日光曝露下及び４０°Ｃでの着色の安定
性について評価した。1-3 and 1-6 Colored liquid cleaning bleach compositions having the compositions shown in Table 1 were prepared, and the stability of coloring under sunlight exposure and at 40°C was evaluated.
〈着色の安定性〉
着色の安定性を以下に示す式により、退色率を求めて評
価した。<Stability of Coloring> Stability of coloring was evaluated by calculating the rate of discoloration using the formula shown below.
−Ｂ
退色率（％）＝ Ｘ１００
Ａ：保存前の着色剤の濃度
Ｂ：保存後の着色剤の濃度
なお、退色率の測定はポリプロピレンの不透明容器を用
い、−カ月間保存して行った。-B Fading rate (%) = X100 A: Concentration of colorant before storage B: Concentration of colorant after storage The fading rate was measured using an opaque polypropylene container and stored for - months.
４〜７ び ７〜８
表−２に示す各着色液体洗浄漂白剤組成物を調製し、そ
れぞれの日光曝露下での着色の安定性について実施例１
〜３及び比較例１〜６と同様に評価した。4-7 and 7-8 Each colored liquid cleaning bleach composition shown in Table 2 was prepared, and the stability of coloring under sunlight exposure was evaluated in Example 1.
- 3 and Comparative Examples 1 to 6 were evaluated.
この結果を表−２に示す。The results are shown in Table-2.
８〜ｌＯび ９〜１３
表−３に示す各着色液体洗浄漂白剤組成物を調製し、４
０’Ｃで一カ月間保存し、その後一般家庭の水洗便器（
白色）にそれぞれを３０ｇ塗布し、液の着色具合を以下
の基準によって評価した。8 to 10 and 9 to 13 Each colored liquid cleaning bleach composition shown in Table 3 was prepared, and 4
Store it at 0'C for one month, then store it in an ordinary household flush toilet (
30g of each was applied onto a white surface, and the degree of coloring of the liquid was evaluated according to the following criteria.
Ｏ：液のついた部分が良くわかる。O: Parts with liquid are clearly visible.
（はっきり着色している。） Δ：液のついた部分がやや良くわかる。(It is clearly colored.) Δ: Parts with liquid can be seen somewhat clearly.
（若干着色している。） ×：液のついた部分がわからない。(It is slightly colored.) ×: The part with the liquid cannot be seen.
（退色している。） この結果を表−３に示す。(The color has faded.) The results are shown in Table 3.
Claims (1)
量％ （ｂ）アルカリ性を呈する物質を０．１〜１０重量％（
ｃ）一般式Ｒ＿１Ｒ＿２Ｒ＿３Ｎ→Ｏ（１）（式中Ｒ＿
１は炭素数８〜２０のアルキル基を、Ｒ＿２、Ｒ＿３は
炭素数１〜３のアルキル基を示す。）で表されるアミン
オキサイド化合物を０．１〜５重量％ （ｄ）炭素数８〜１８の飽和脂肪酸または炭素数１０〜
１８のアルキルサルコシンのアルカリ金属塩を０．１〜
６重量％ （ｅ）一般式Ｃ＿３＿２Ｈ＿１＿６＿−＿ｎＣｌ＿ｎＮ
＿８Ｃｕ（２）（式中ｎは８〜１６の整数を示す。） で表される銅フタロシアニン系顔料を０．０００１〜０
．０１重量％ 含有することを特徴とする着色液体洗浄漂白剤組成物。 ２、（ａ）次亜塩素酸アルカリ金属塩を０．５〜１０重
量％ （ｂ）アルカリ性を呈する物質を０．１〜１０重量％（
ｃ）一般式Ｒ＿１Ｒ＿２Ｒ＿３Ｎ→Ｏ（１）（式中Ｒ＿
１は炭素数８〜２０のアルキル基を、Ｒ＿２、Ｒ＿３は
炭素数１〜３のアルキル基を示す。）で表されるアミン
オキサイド化合物を０．１〜５重量％ （ｄ）炭素数８〜１８の飽和脂肪酸または炭素数１０〜
１８のアルキルサルコシンのアルカリ金属塩を０．１〜
６重量％ （ｅ）一般式Ｃ＿３＿２Ｈ＿１＿６＿−＿ｎＣｌ＿ｎＮ
＿８Ｃｕ（２）（式中ｎは８〜１６の整数を示す。） で表される銅フタロシアニン系顔料を０．０００１〜０
．０１重量％ （ｆ）一般式 ▲数式、化学式、表等があります▼（３） （式中、Ｒ＿４は炭素数８〜２２のアルキル基、Ｒ＿５
、Ｒ＿６は炭素数１〜４のアルキル基、Ｒ＿７は炭素数
１〜５のアルキレン基を示す。）、 または一般式、 ▲数式、化学式、表等があります▼（４） （式中、Ｒ＿８は炭素数８〜２２のアルキル基、Ｒ＿９
、Ｒ＿１＿０は炭素数１〜２のアルキル基、Ｒ＿１＿１
は炭素数２〜３のアルキレン基を示す。） で表されるベタイン型両性界面活性剤の一種またはそれ
以上を０．１〜１０重量％ 含有することを特徴とする着色液体洗浄漂白剤組成物。[Claims] 1. (a) 0.5 to 10% by weight of an alkali metal hypochlorite (b) 0.1 to 10% by weight of a substance exhibiting alkalinity (
c) General formula R_1R_2R_3N→O(1) (in the formula R_
1 represents an alkyl group having 8 to 20 carbon atoms, and R_2 and R_3 represent an alkyl group having 1 to 3 carbon atoms. ) 0.1 to 5% by weight of amine oxide compound represented by (d) Saturated fatty acid having 8 to 18 carbon atoms or 10 to 18 carbon atoms
18 alkyl sarcosine alkali metal salt from 0.1 to
6% by weight (e) General formula C_3_2H_1_6_-_nCl_nN
A copper phthalocyanine pigment represented by _8Cu(2) (in the formula, n represents an integer of 8 to 16) from 0.0001 to 0.
．． A colored liquid cleaning bleach composition characterized in that it contains 0.01% by weight. 2. (a) 0.5 to 10% by weight of alkali metal hypochlorite (b) 0.1 to 10% by weight of a substance exhibiting alkalinity (
c) General formula R_1R_2R_3N→O(1) (in the formula R_
1 represents an alkyl group having 8 to 20 carbon atoms, and R_2 and R_3 represent an alkyl group having 1 to 3 carbon atoms. ) 0.1 to 5% by weight of amine oxide compound represented by (d) Saturated fatty acid having 8 to 18 carbon atoms or 10 to 18 carbon atoms
18 alkyl sarcosine alkali metal salt from 0.1 to
6% by weight (e) General formula C_3_2H_1_6_-_nCl_nN
A copper phthalocyanine pigment represented by _8Cu(2) (in the formula, n represents an integer of 8 to 16) from 0.0001 to 0.
．． 01% by weight (f) General formula ▲ Numerical formulas, chemical formulas, tables, etc. are available ▼ (3) (In the formula, R_4 is an alkyl group having 8 to 22 carbon atoms, R_5
, R_6 represents an alkyl group having 1 to 4 carbon atoms, and R_7 represents an alkylene group having 1 to 5 carbon atoms. ), or general formula, ▲Mathematical formula, chemical formula, table, etc.▼(4) (In the formula, R_8 is an alkyl group having 8 to 22 carbon atoms, R_9
, R_1_0 is an alkyl group having 1 to 2 carbon atoms, R_1_1
represents an alkylene group having 2 to 3 carbon atoms. 1. A colored liquid cleaning bleach composition containing 0.1 to 10% by weight of one or more of the betaine type amphoteric surfactants represented by the following.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1039578A JP2633007B2 (en) | 1989-02-20 | 1989-02-20 | Colored liquid cleaning bleach composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1039578A JP2633007B2 (en) | 1989-02-20 | 1989-02-20 | Colored liquid cleaning bleach composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH02218798A true JPH02218798A (en) | 1990-08-31 |
| JP2633007B2 JP2633007B2 (en) | 1997-07-23 |
Family
ID=12556965
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1039578A Expired - Lifetime JP2633007B2 (en) | 1989-02-20 | 1989-02-20 | Colored liquid cleaning bleach composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2633007B2 (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2271119A (en) * | 1992-09-16 | 1994-04-06 | Kao Corp | Color liquid cleaning and bleaching composition |
| EP0651051A3 (en) * | 1993-10-29 | 1996-02-28 | Clorox Co | Gelled hypochlorite-based cleaner. |
| US5804545A (en) * | 1993-11-24 | 1998-09-08 | West Argo, Inc. | Stable alkaline chlorine compositions |
| JP2003055698A (en) * | 2001-08-10 | 2003-02-26 | Kobayashi Pharmaceut Co Ltd | Slime remover |
| JP2008266552A (en) * | 2007-01-09 | 2008-11-06 | Kao Corp | Liquid detergent composition |
| JP2019081834A (en) * | 2017-10-30 | 2019-05-30 | 株式会社ニイタカ | Alkaline detergent composition |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5488889A (en) * | 1977-11-18 | 1979-07-14 | Unilever Nv | Colored liquid bleaching composition |
| JPS61264098A (en) * | 1985-05-16 | 1986-11-21 | 花王株式会社 | Colored detergent composition |
-
1989
- 1989-02-20 JP JP1039578A patent/JP2633007B2/en not_active Expired - Lifetime
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5488889A (en) * | 1977-11-18 | 1979-07-14 | Unilever Nv | Colored liquid bleaching composition |
| JPS61264098A (en) * | 1985-05-16 | 1986-11-21 | 花王株式会社 | Colored detergent composition |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2271119A (en) * | 1992-09-16 | 1994-04-06 | Kao Corp | Color liquid cleaning and bleaching composition |
| GB2271119B (en) * | 1992-09-16 | 1996-07-10 | Kao Corp | Colored liquid cleaning and bleaching composition |
| EP0651051A3 (en) * | 1993-10-29 | 1996-02-28 | Clorox Co | Gelled hypochlorite-based cleaner. |
| TR28429A (en) * | 1993-10-29 | 1996-06-13 | Clorox Co | Cleansing gel with enhanced bleaching feature. |
| US5804545A (en) * | 1993-11-24 | 1998-09-08 | West Argo, Inc. | Stable alkaline chlorine compositions |
| JP2003055698A (en) * | 2001-08-10 | 2003-02-26 | Kobayashi Pharmaceut Co Ltd | Slime remover |
| JP2008266552A (en) * | 2007-01-09 | 2008-11-06 | Kao Corp | Liquid detergent composition |
| JP2019081834A (en) * | 2017-10-30 | 2019-05-30 | 株式会社ニイタカ | Alkaline detergent composition |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2633007B2 (en) | 1997-07-23 |
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