JP7500126B2 - Plastic fat composition - Google Patents
Plastic fat composition Download PDFInfo
- Publication number
- JP7500126B2 JP7500126B2 JP2020062068A JP2020062068A JP7500126B2 JP 7500126 B2 JP7500126 B2 JP 7500126B2 JP 2020062068 A JP2020062068 A JP 2020062068A JP 2020062068 A JP2020062068 A JP 2020062068A JP 7500126 B2 JP7500126 B2 JP 7500126B2
- Authority
- JP
- Japan
- Prior art keywords
- fatty acid
- oil
- acid esters
- mass
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000203 mixture Substances 0.000 title claims description 81
- 239000004033 plastic Substances 0.000 title claims description 47
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- 229930195729 fatty acid Natural products 0.000 claims description 101
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- -1 sorbitan fatty acid esters Chemical class 0.000 claims description 60
- 150000004665 fatty acids Chemical class 0.000 claims description 43
- 239000000470 constituent Substances 0.000 claims description 38
- 125000004432 carbon atom Chemical group C* 0.000 claims description 37
- 239000003925 fat Substances 0.000 claims description 35
- 235000019197 fats Nutrition 0.000 claims description 27
- 239000003995 emulsifying agent Substances 0.000 claims description 26
- 150000004671 saturated fatty acids Chemical class 0.000 claims description 22
- 150000004670 unsaturated fatty acids Chemical class 0.000 claims description 19
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Landscapes
- Grain Derivatives (AREA)
- Edible Oils And Fats (AREA)
Description
本発明は、水性成分を含有しても含気泡化に適した可塑性油脂組成物に関する。 The present invention relates to a plastic oil composition that is suitable for foaming even when it contains an aqueous component.
バター、マーガリン、ショートニングなどの可塑性油脂組成物に、液糖などの水性成分を加え起泡化(含気泡化)することにより、含気泡化された組成物(いわゆる、バタークリーム)が製造される。バタークリームは、油中水型の乳化系であるため、日持ちが良く、保形性にも優れるので、製菓および製パンのフィリング材あるいはトッピング材として広く使用されている。しかし、その反面、乳化系の外相が油脂であり、油脂含量も高いことから、水中油型であるホイップクリームと比較すると、食べたときに油っぽく、嗜好面での課題となってきた。 An aerated composition (so-called buttercream) is produced by adding an aqueous component such as liquid sugar to a plastic fat composition such as butter, margarine, or shortening and foaming (incorporating air bubbles). Because buttercream is a water-in-oil emulsion, it has a long shelf life and excellent shape retention, and is therefore widely used as a filling or topping for confectionery and bread. On the other hand, however, because the external phase of the emulsion is fat and oil and the fat content is high, it tastes oily when eaten compared to whipped cream, which is an oil-in-water type, and this has been an issue in terms of taste.
上記課題を解決するために、可塑性油脂組成物に対して4~7.5倍の水性成分を加えることにより油っぽさを低減し、口あたりの良いバタークリームとする試みや(例えば、特許文献1)、糖類および蛋白質を含む水相をホイップし、次いで25℃における保存時結晶量が15%以下の流動性のある油脂を添加して攪拌する方法(例えば、特許文献2)、が考案されている。しかし、保存時の離水が増加したり、最初の軽い口あたりが、液状油成分や増粘成分の影響で、その後劣化したりするなど、まだ課題の残るものであった。 In order to solve the above problems, attempts have been made to reduce the oiliness by adding 4 to 7.5 times the amount of aqueous components to the plastic oil composition to produce a butter cream with a good mouthfeel (e.g., Patent Document 1), and a method has been devised in which an aqueous phase containing sugars and proteins is whipped, and then a fluid oil with a crystallization amount of 15% or less when stored at 25°C is added and stirred (e.g., Patent Document 2). However, there are still problems that remain, such as increased water syneresis during storage and subsequent deterioration of the initial light mouthfeel due to the influence of liquid oil components and thickening components.
解決しようとする課題は、水性成分の割合が高くても安定で、かつ、口どけのよい、含気泡状の組成物を開発することである。 The problem to be solved is to develop an aerated foam-like composition that is stable even with a high proportion of aqueous components and that melts easily in the mouth.
本発明者らは、上記課題を解決するために鋭意検討を重ねた。その結果、特定の乳化剤を組み合わせることにより、水性成分の割合が高くても安定で、かつ、口どけのよい、含気泡状の組成物が得られることを見出した。これにより、本発明は完成するに至った。 The inventors of the present invention have conducted extensive research to solve the above problems. As a result, they have discovered that by combining specific emulsifiers, it is possible to obtain an aerated foam-like composition that is stable even when the proportion of aqueous components is high, and that melts easily in the mouth. This has led to the completion of the present invention.
すなわち本発明は以下の態様を含み得る。
[1]構成脂肪酸中に炭素数16以上の不飽和脂肪酸を有する乳化剤と、構成脂肪酸中に炭素数14以下の飽和脂肪酸を有するジグリセリン脂肪酸エステルと、を含み、油脂の含有量が70質量%以上である、可塑性油脂組成物。
[2]前記構成脂肪酸中に炭素数16以上の不飽和脂肪酸を有する乳化剤が、ソルビタン脂肪酸エステル、ショ糖脂肪酸エステル、ポリグリセリン脂肪酸エステル、から選ばれる1種以上の乳化剤である、[1]の可塑性油脂組成物。
[3]前記構成脂肪酸中に炭素数14以下の飽和脂肪酸を有するジグリセリン脂肪酸エステルが、ジグリセリンミリステート、ジグリセリンラウレート、ジグリセリンカプレート、ジグリセリンカプリレート、から選ばれる1種以上である、[1]または[2]の可塑性油脂組成物。
[4]さらに、構成脂肪酸中に炭素数16以上の飽和脂肪酸を有するプロピレングリコール脂肪酸エステルを含む、[1]~[3]の何れか1つの可塑性油脂組成物。
[5]前記可塑性油脂組成物に含まれる油脂に占めるエステル交換油脂の含有量が、50~100質量%である、[1]~[4]の何れか1つの可塑性油脂組成物。
[6]前記構成脂肪酸中に炭素数16以上の不飽和脂肪酸を有する乳化剤と、前記構成脂肪酸中に炭素数14以下の飽和脂肪酸を有するジグリセリンモノ脂肪酸エステルと、が油相に含まれる、[1]~[5]の何れか1つの可塑性油脂組成物。
[7][1]~[6]の何れか1つの可塑性油脂組成物の製造方法であって、
構成脂肪酸中に炭素数16以上の不飽和脂肪酸を有する乳化剤と、構成脂肪酸中に炭素数14以下の飽和脂肪酸を有するジグリセリン脂肪酸エステルと、を溶融した融解状態の油脂、を含む組成物を、冷却可塑化する、前記製造方法。
[8]構成脂肪酸中に炭素数16以上の不飽和脂肪酸を有する乳化剤と、構成脂肪酸中に炭素数14以下の飽和脂肪酸を有するジグリセリン脂肪酸エステルと、を含み、70質量%未満の油脂と、30質量%以上の水性成分と、を含む、含気泡組成物。
[9][1]~[6]の何れか1つの可塑性油脂組成物および水性成分を、混合含気泡化させる、[8]の含気泡組成物の製造方法。
That is, the present invention may include the following aspects.
[1] A plastic oil composition comprising an emulsifier having an unsaturated fatty acid having 16 or more carbon atoms among its constituent fatty acids, and a diglycerol fatty acid ester having a saturated fatty acid having 14 or less carbon atoms among its constituent fatty acids, and having an oil content of 70% by mass or more.
[2] The plastic oil composition of [1], wherein the emulsifier having an unsaturated fatty acid having 16 or more carbon atoms in the constituent fatty acids is one or more emulsifiers selected from sorbitan fatty acid esters, sucrose fatty acid esters, and polyglycerin fatty acid esters.
[3] The plastic oil composition of [1] or [2], wherein the diglycerol fatty acid ester having a saturated fatty acid having 14 or less carbon atoms in the constituent fatty acids is one or more selected from diglycerol myristate, diglycerol laurate, diglycerol caprate, and diglycerol caprylate.
[4] Any one of the plastic oil compositions of [1] to [3], further comprising a propylene glycol fatty acid ester having a saturated fatty acid having 16 or more carbon atoms in its constituent fatty acids.
[5] Any one of the plastic oil compositions of [1] to [4], wherein the content of transesterified oils and fats in the oils and fats contained in the plastic oil and fat composition is 50 to 100 mass%.
[6] Any one of the plastic oil compositions according to [1] to [5], wherein the oil phase contains an emulsifier having an unsaturated fatty acid with 16 or more carbon atoms among the constituent fatty acids, and a diglycerol mono-fatty acid ester having a saturated fatty acid with 14 or less carbon atoms among the constituent fatty acids.
[7] A method for producing a plastic oil composition according to any one of [1] to [6],
The method for producing the composition includes cooling and plasticizing a composition containing a molten oil or fat obtained by melting an emulsifier having unsaturated fatty acids with 16 or more carbon atoms among its constituent fatty acids and a diglycerol fatty acid ester having saturated fatty acids with 14 or less carbon atoms among its constituent fatty acids.
[8] An air-containing composition comprising an emulsifier having an unsaturated fatty acid having 16 or more carbon atoms among its constituent fatty acids, and a diglycerol fatty acid ester having a saturated fatty acid having 14 or less carbon atoms among its constituent fatty acids, and comprising less than 70% by mass of an oil or fat, and 30% by mass or more of an aqueous component.
[9] A method for producing an aerated composition according to [8], comprising mixing a plastic oil composition according to any one of [1] to [6] and an aqueous component to form aerated bubbles.
本発明によれば、水性成分の割合が高くても安定で、かつ、口どけのよい、含気泡状の組成物、および、当該含気泡組成物のベースとなる可塑性油脂組成物、が提供される。 The present invention provides an aerated foam composition that is stable and melts easily in the mouth even when the proportion of aqueous components is high, and a plastic oil composition that serves as the base for the aerated foam composition.
以下、本発明について詳細に説明する。
本発明の可塑性油脂組成物は、構成脂肪酸に炭素数16以上の不飽和脂肪酸を有する乳化剤を含有する。当該乳化剤の構成脂肪酸に占める不飽和脂肪酸の含有量は、好ましくは70~100質量%であり、より好ましくは80~100質量%である。また、当該不飽和脂肪酸は、好ましくは70質量%以上(より好ましくは80質量%以上)が1価の不飽和脂肪酸であり、好ましくはオレイン酸および/またはエルカ酸である。構成脂肪酸に炭素数16以上の不飽和脂肪酸を有する乳化剤は、好ましくは、グリセリン脂肪酸エステル、グリセリン有機酸脂肪酸エステル、ポリグリセリン脂肪酸エステル、ショ糖脂肪酸エステル、ソルビタン脂肪酸エステル、プロピレングリコール脂肪酸エステル、であり、より好ましくは、ポリグリセリン脂肪酸エステル、ショ糖脂肪酸エステル、ソルビタン脂肪酸エステル、であり、さらに好ましくは、ソルビタン脂肪酸エステルである。構成脂肪酸に炭素数16以上の不飽和脂肪酸を有する乳化剤は、2種以上が併用されてもよい。
The present invention will be described in detail below.
The plastic oil composition of the present invention contains an emulsifier having an unsaturated fatty acid having 16 or more carbon atoms in the constituent fatty acids. The content of the unsaturated fatty acid in the constituent fatty acids of the emulsifier is preferably 70 to 100% by mass, more preferably 80 to 100% by mass. The unsaturated fatty acid is preferably 70% by mass or more (more preferably 80% by mass or more) of a monovalent unsaturated fatty acid, and is preferably oleic acid and/or erucic acid. The emulsifier having an unsaturated fatty acid having 16 or more carbon atoms in the constituent fatty acids is preferably glycerin fatty acid ester, glycerin organic acid fatty acid ester, polyglycerin fatty acid ester, sucrose fatty acid ester, sorbitan fatty acid ester, propylene glycol fatty acid ester, more preferably polyglycerin fatty acid ester, sucrose fatty acid ester, sorbitan fatty acid ester, and even more preferably sorbitan fatty acid ester. Two or more kinds of emulsifiers having an unsaturated fatty acid having 16 or more carbon atoms in the constituent fatty acids may be used in combination.
また、上記構成脂肪酸に炭素数16以上の不飽和脂肪酸を有する乳化剤のHLBは、好ましくは1~8であり、より好ましくは3~6であり、さらに好ましくは4~5.5である。ここで、HLBは、親水性疎水性バランス(Hydrophile Lipophile Balance)の略であって、合成乳化剤が親水性か親油性かを知る指標となる。HLBは、0~20の値をとり、HLB値が小さい程、親油性が強いことを示す。本発明において、HLB値の算出はアトラス法の算出法を用いる。アトラス法の算出法は、
HLB=20×(1-S/A)
S:ケン化価
A:エステル中の脂肪酸の中和価
からHLB値を算出する方法を言う。また、本発明の可塑性油脂組成物に占める、構成脂肪酸に炭素数16以上の不飽和脂肪酸を有する乳化剤の含有量は、好ましくは0.05~2質量%であり、より好ましくは0.2~1.4質量%であり、さらに好ましくは0.3~1質量%である。
The HLB of the emulsifier having an unsaturated fatty acid with 16 or more carbon atoms in the constituent fatty acids is preferably 1 to 8, more preferably 3 to 6, and even more preferably 4 to 5.5. Here, HLB is an abbreviation for Hydrophile Lipophile Balance, and is an index for knowing whether a synthetic emulsifier is hydrophilic or lipophilic. HLB takes a value of 0 to 20, and the smaller the HLB value, the stronger the lipophilicity. In the present invention, the HLB value is calculated using the Atlas method. The Atlas method is as follows:
HLB=20×(1−S/A)
S: Saponification value
A: This refers to a method of calculating the HLB value from the neutralization value of the fatty acid in the ester. The content of the emulsifier having an unsaturated fatty acid with 16 or more carbon atoms in the constituent fatty acid in the plastic oil composition of the present invention is preferably 0.05 to 2 mass%, more preferably 0.2 to 1.4 mass%, and even more preferably 0.3 to 1 mass%.
本発明の可塑性油脂組成物は、構成脂肪酸に炭素数14以下の飽和脂肪酸を有するジグリセリン脂肪酸エステルを含有する。ジグリセリン脂肪酸エステルは、グリセリンの2量体に、1分子の脂肪酸がエステル結合した構造を有する。構成脂肪酸に炭素数14以下の飽和脂肪酸を含むジグリセリン脂肪酸エステルは、好ましくは、ジグリセリンミリステート、ジグリセリンラウレート、ジグリセリンカプレート、ジグリセリンカプリレート、であり、より好ましくは、ジグリセリンミリステート、ジグリセリンラウレート、であり、さらに好ましくは、ジグリセリンミリステートである。構成脂肪酸に炭素数14以下の飽和脂肪酸を有するジグリセリン脂肪酸エステルは、2種以上が併用されてもよい。 The plastic oil composition of the present invention contains a diglycerol fatty acid ester having a saturated fatty acid with 14 or less carbon atoms as a constituent fatty acid. The diglycerol fatty acid ester has a structure in which one molecule of fatty acid is ester-bonded to a glycerol dimer. The diglycerol fatty acid ester having a saturated fatty acid with 14 or less carbon atoms as a constituent fatty acid is preferably diglycerol myristate, diglycerol laurate, diglycerol caprate, or diglycerol caprylate, more preferably diglycerol myristate, diglycerol laurate, and even more preferably diglycerol myristate. Two or more diglycerol fatty acid esters having a saturated fatty acid with 14 or less carbon atoms as a constituent fatty acid may be used in combination.
また、上記構成脂肪酸に炭素数14以下の飽和脂肪酸を有するジグリセリン脂肪酸エステルは、モノ脂肪酸エステルが、好ましくは70~100質量%を占め、より好ましくは80~100質量%を占める。また、構成脂肪酸に炭素数14以下の飽和脂肪酸を有するジグリセリン脂肪酸エステルのHLBは、好ましくは6~11であり、より好ましくは7~10であり、さらに好ましくは8.4~9.4である。また、本発明の可塑性油脂組成物に占める、構成脂肪酸に炭素数14以下の飽和脂肪酸を有するジグリセリン脂肪酸エステルの含有量は、好ましくは0.02~1.2質量%であり、より好ましくは0.08~0.8質量%であり、さらに好ましくは0.1~0.6質量%である。 In addition, in the diglycerol fatty acid ester having a saturated fatty acid with 14 or less carbon atoms as a constituent fatty acid, the mono fatty acid ester preferably accounts for 70 to 100% by mass, more preferably 80 to 100% by mass. In addition, the HLB of the diglycerol fatty acid ester having a saturated fatty acid with 14 or less carbon atoms as a constituent fatty acid is preferably 6 to 11, more preferably 7 to 10, and even more preferably 8.4 to 9.4. In addition, the content of the diglycerol fatty acid ester having a saturated fatty acid with 14 or less carbon atoms as a constituent fatty acid in the plastic oil composition of the present invention is preferably 0.02 to 1.2% by mass, more preferably 0.08 to 0.8% by mass, and even more preferably 0.1 to 0.6% by mass.
本発明の可塑性油脂組成物は、本発明の効果を損なわない限り、上記の、構成脂肪酸に炭素数16以上の不飽和脂肪酸を有する乳化剤および構成脂肪酸に炭素数14以下の飽和脂肪酸を有するジグリセリン脂肪酸エステル、以外のその他乳化剤を1種または2種以上含んでもよい。その他乳化剤としては、グリセリン脂肪酸エステル、グリセリン有機酸脂肪酸エステル、ポリグリセリン脂肪酸エステル、ショ糖脂肪酸エステル、ソルビタン脂肪酸エステル、プロピレングリコール脂肪酸エステル、ポリオキシエチレンソルビタン脂肪酸エステル、レシチン、などが挙げられる。 The plastic oil composition of the present invention may contain one or more other emulsifiers other than the above-mentioned emulsifiers having unsaturated fatty acids with 16 or more carbon atoms in the constituent fatty acids and diglycerin fatty acid esters having saturated fatty acids with 14 or less carbon atoms in the constituent fatty acids, so long as the effects of the present invention are not impaired. Examples of other emulsifiers include glycerin fatty acid esters, glycerin organic acid fatty acid esters, polyglycerin fatty acid esters, sucrose fatty acid esters, sorbitan fatty acid esters, propylene glycol fatty acid esters, polyoxyethylene sorbitan fatty acid esters, lecithin, etc.
本発明の可塑性油脂組成物は、構成脂肪酸に炭素数16以上の飽和脂肪酸を有するプロピレングリコール脂肪酸エステルを含んでもよい。当該乳化剤の構成脂肪酸に占める飽和脂肪酸の含有量は、好ましくは70~100質量%であり、より好ましくは80~100質量%である。また、当該飽和脂肪酸の好ましくは70質量%以上(より好ましくは80質量%以上)が、パルミチン酸、ステアリン酸、ベヘン酸であり、より好ましくは、ステアリン酸である。構成脂肪酸に炭素数16以上の飽和脂肪酸を有するプロピレングリコール脂肪酸エステルのHLBは、好ましくは2~6であり、より好ましくは2.5~5であり、さらに好ましくは3~4.5である。構成脂肪酸に炭素数16以上の飽和脂肪酸を有するプロピレングリコール脂肪酸エステルは、2種以上が併用されてもよい。本発明の可塑性油脂組成物に占める、構成脂肪酸に炭素数16以上の飽和脂肪酸を有するプロピレングリコール脂肪酸エステルの含有量は、好ましくは0.02~1.4質量%であり、より好ましくは0.08~1.0質量%であり、さらに好ましくは0.1~0.8質量%である。 The plastic oil composition of the present invention may contain a propylene glycol fatty acid ester having a saturated fatty acid having 16 or more carbon atoms as a constituent fatty acid. The content of saturated fatty acids in the constituent fatty acids of the emulsifier is preferably 70 to 100% by mass, more preferably 80 to 100% by mass. In addition, preferably 70% by mass or more (more preferably 80% by mass or more) of the saturated fatty acids are palmitic acid, stearic acid, behenic acid, and more preferably stearic acid. The HLB of the propylene glycol fatty acid ester having a saturated fatty acid having 16 or more carbon atoms as a constituent fatty acid is preferably 2 to 6, more preferably 2.5 to 5, and even more preferably 3 to 4.5. Two or more types of propylene glycol fatty acid esters having a saturated fatty acid having 16 or more carbon atoms as a constituent fatty acid may be used in combination. The content of propylene glycol fatty acid esters having saturated fatty acids with 16 or more carbon atoms in the constituent fatty acids in the plastic oil composition of the present invention is preferably 0.02 to 1.4 mass%, more preferably 0.08 to 1.0 mass%, and even more preferably 0.1 to 0.8 mass%.
本発明の可塑性油脂組成物は、レシチンを含んでもよい。レシチンが粗製レシチンである場合、アセトン不溶物をレシチンの正味含有量として扱う。粗製レシチンのアセトン不溶物は、例えば、次のようにして求められる。試料2gをビーカーに計りとり、氷冷したアセトン300ミリリットルを加え、十分攪拌して30分間放置する。上澄み液を質量既知のガラス濾過器で吸引ろ過し、さらに氷冷したアセトン30ミリリットルで3回不溶物を洗浄して、不溶物の全量をガラス濾過器に移し入れる。ガラス濾過器に氷冷したアセトンを満たし、吸引した後、ガラス濾過機を減圧下で乾燥させ、質量を測定する。ガラス濾過機の質量の増加分が、アセトン不溶物の質量である。(不溶物の質量/試料採取量)×100がアセトン不溶物(質量%)となる。本発明の可塑性油脂組成物に占める、レシチン含有量は、好ましくは0.005~0.12質量%であり、より好ましくは0.02~0.1質量%であり、さらに好ましくは0.03~0.08質量%である。 The plastic oil composition of the present invention may contain lecithin. When the lecithin is crude lecithin, the acetone insoluble matter is treated as the net content of lecithin. The acetone insoluble matter of crude lecithin can be determined, for example, as follows. 2 g of a sample is weighed into a beaker, 300 milliliters of ice-cold acetone is added, and the mixture is thoroughly stirred and left for 30 minutes. The supernatant is suction filtered through a glass filter with a known mass, and the insoluble matter is washed three times with 30 milliliters of ice-cold acetone, and the entire amount of the insoluble matter is transferred to the glass filter. The glass filter is filled with ice-cold acetone, and after suction, the glass filter is dried under reduced pressure and the mass is measured. The increase in the mass of the glass filter is the mass of the acetone insoluble matter. (Mass of insoluble matter/amount of sample taken) x 100 is the acetone insoluble matter (mass%). The lecithin content in the plastic oil composition of the present invention is preferably 0.005 to 0.12% by mass, more preferably 0.02 to 0.1% by mass, and even more preferably 0.03 to 0.08% by mass.
本発明の可塑性油脂組成物は、連続相が油脂である可塑性油脂組成物であれば、特に限定されない。例として、ショートニング、マーガリン、ファットスプレッドなどが挙げられる。本発明の可塑性油脂組成物に占める油脂の含有量は、70質量%以上であり、好ましくは70~99.8質量%であり、より好ましくは80~99.5質量%であり、さらに好ましくは90~99.3質量%である。また、本発明の可塑性油脂組成物に占める水の含有量(含水素材に含まれる水を除く)は、好ましくは0~29.8質量%であり、より好ましくは0~19.8質量%であり、さらに好ましくは0~9.98質量%である。 The plastic oil composition of the present invention is not particularly limited as long as it is a plastic oil composition in which the continuous phase is an oil. Examples include shortening, margarine, and fat spreads. The content of the oil in the plastic oil composition of the present invention is 70% by mass or more, preferably 70 to 99.8% by mass, more preferably 80 to 99.5% by mass, and even more preferably 90 to 99.3% by mass. The content of water in the plastic oil composition of the present invention (excluding water contained in the water-containing material) is preferably 0 to 29.8% by mass, more preferably 0 to 19.8% by mass, and even more preferably 0 to 9.98% by mass.
本発明の可塑性油脂組成物に含まれる油脂は、食用に適する限り、特に限定されない。例えば、ヤシ油、パーム核油、パーム油、パーム分別油(パームオレイン、パームステアリンなど)、シア脂、シア分別油、サル脂、サル分別油、イリッペ脂、大豆油、菜種油、綿実油、サフラワー油、ひまわり油、米油、コーン油、ゴマ油、オリーブ油、乳脂、およびココアバター、ならびにこれらの混合油および加工油脂(水素添加油、エステル交換油、分別油)を、1種または2種以上、使用することができる。しかし、本発明の可塑性油脂組成物に含まれる油脂は、好ましくは50~100質量%、より好ましくは55~100質量%、さらに好ましくは60~100質量%、のエステル交換油脂を含む。 The fats and oils contained in the plastic fat composition of the present invention are not particularly limited as long as they are suitable for edible use. For example, one or more of coconut oil, palm kernel oil, palm oil, palm fractionated oil (palm olein, palm stearin, etc.), shea fat, shea fractionated oil, monkey fat, monkey fractionated oil, illipe fat, soybean oil, rapeseed oil, cottonseed oil, safflower oil, sunflower oil, rice oil, corn oil, sesame oil, olive oil, milk fat, and cocoa butter, as well as mixed oils and processed fats and oils (hydrogenated oils, interesterified oils, and fractionated oils) thereof can be used. However, the fats and oils contained in the plastic fat composition of the present invention preferably contain 50 to 100% by mass, more preferably 55 to 100% by mass, and even more preferably 60 to 100% by mass of interesterified fats and oils.
上記エステル交換油脂は、特に限定されない。しかし、好ましくはラウリン系油脂を原料油脂として含むエステル交換油脂である。ラウリン系油脂は、油脂を構成する脂肪酸全量に占めるラウリン酸の含有量が30質量%以上の油脂である。ラウリン系油脂としては、例えば、ヤシ油、パーム核油、およびババス油など、ならびに、それらの分別油など、が挙げられる。また、エステル交換油脂は、原料油脂として非ラウリン系油脂を含んでもよい。非ラウリン系油脂は、油脂を構成する脂肪酸全量に占める炭素数16以上の脂肪酸の含有量が90質量%以上の油脂である。非ラウリン系油脂としては、例えば、パーム油、パーム分別油(パームオレイン、パームステアリンなど)、大豆油、菜種油、綿実油、サフラワー油、ひまわり油、米油、コーン油、オリーブ油など、ならびに、それらの極度硬化油など、が挙げられる。エステル交換油脂は、好ましくは、ラウリン系油脂と非ラウリン系油脂とを含む混合油脂のエステル交換油脂であってもよい。当該混合油脂は、ラウリン系油脂と非ラウリン系油脂とを、好ましくは20:80~80:20、より好ましくは30:70~70:30、さらに好ましくは、35:65~65:35、の質量比で含む。ラウリン系油脂、非ラウリン系油脂は、2種以上が併用されてもよい。また、エステル交換油脂は、2種以上が併用されてもよい。エステル交換油脂のヨウ素価は、好ましくは20~60であり、より好ましくは25~50であり、さらに好ましくは30~45である。エステル交換油脂が複数使用される場合、ヨウ素価は加重平均して求められる。 The above-mentioned transesterified oils and fats are not particularly limited. However, transesterified oils and fats containing lauric oils and fats as the raw oils and fats are preferred. Lauric oils and fats are oils and fats in which the content of lauric acid in the total amount of fatty acids constituting the oils and fats is 30% by mass or more. Examples of lauric oils and fats include coconut oil, palm kernel oil, babassu oil, and the like, as well as fractionated oils thereof. Transesterified oils and fats may also contain non-lauric oils and fats as the raw oils and fats. Non-lauric oils and fats are oils and fats in which the content of fatty acids having 16 or more carbon atoms in the total amount of fatty acids constituting the oils and fats is 90% by mass or more. Examples of non-lauric oils and fats include palm oil, palm fractionated oils (palm olein, palm stearin, etc.), soybean oil, rapeseed oil, cottonseed oil, safflower oil, sunflower oil, rice oil, corn oil, olive oil, and the like, as well as their extremely hardened oils. The transesterified oil may be a transesterified oil of a mixed oil containing a lauric oil and a non-lauric oil. The mixed oil contains the lauric oil and the non-lauric oil in a mass ratio of preferably 20:80 to 80:20, more preferably 30:70 to 70:30, and even more preferably 35:65 to 65:35. Two or more types of lauric oil and non-lauric oil may be used in combination. Two or more types of transesterified oil may be used in combination. The iodine value of the transesterified oil is preferably 20 to 60, more preferably 25 to 50, and even more preferably 30 to 45. When a plurality of transesterified oils are used, the iodine value is determined by a weighted average.
上記エステル交換油脂を調製するためのエステル交換反応は、特に制限はなく、位置選択性の低いエステル交換反応である非選択的エステル交換(ランダムエステル交換)、位置選択性の高いエステル交換反応である選択的エステル交換(位置特異的エステル交換)のどちらでもよい。しかし、好ましくは非選択的エステル交換である。また、エステル交換反応の方法は、特に制限はなく、ケミカルエステル交換、酵素的エステル交換のどちらの方法でもよい。しかし、好ましくはケミカルエステル交換である。ケミカルエステル交換は、触媒としてナトリウムメチラートなどの化学触媒を用いて行われるものであり、反応は位置選択性の低い非選択的エステル交換となる。ケミカルエステル交換反応は、例えば、常法に従って、原料油脂を十分に乾燥させ、触媒を原料油脂に対して0.1~1質量%添加した後、減圧下、80~120℃で0.5~1時間攪拌しながら行うことができる。エステル交換反応終了後の油脂は、水洗にて触媒を洗い流した後、通常の食用油脂の精製工程で行われる精製処理(脱色、脱臭など)をしてもよい。 The transesterification reaction for preparing the transesterified oils and fats is not particularly limited, and may be either nonselective transesterification (random transesterification), which is a transesterification reaction with low position selectivity, or selective transesterification (position-specific transesterification), which is a transesterification reaction with high position selectivity. However, nonselective transesterification is preferred. The method of transesterification is also not particularly limited, and may be either chemical transesterification or enzymatic transesterification. However, chemical transesterification is preferred. Chemical transesterification is carried out using a chemical catalyst such as sodium methylate as a catalyst, and the reaction is a nonselective transesterification with low position selectivity. The chemical transesterification reaction can be carried out, for example, according to a conventional method, by thoroughly drying the raw oil and fat, adding 0.1 to 1 mass% of the catalyst to the raw oil and fat, and stirring at 80 to 120°C under reduced pressure for 0.5 to 1 hour. After the transesterification reaction is completed, the oil and fat may be washed with water to remove the catalyst, and then subjected to a purification process (decolorization, deodorization, etc.) that is usually performed in the refining process of edible oils and fats.
本発明の可塑性油脂組成物は、本発明の効果を損なわない程度において、通常のマーガリンやショートニングに使用される各種添加物を含んでもよい。例えば、具体的には、全脂粉乳、バターミルク、脱脂粉乳などの乳製品、ペクチン、カラギーナン、キサンタンガム、ジェランガムなどの増粘多糖類、トコフェロール、アスコルビン酸脂肪酸エステル、リグナン、コエンザイムQ、オリザノール、茶抽出物、ルチンなどの抗酸化剤、植物ステロール、食塩、色素、香料などが挙げられる。 The plastic oil composition of the present invention may contain various additives used in ordinary margarine or shortening to the extent that the effect of the present invention is not impaired. Specific examples include dairy products such as whole milk powder, buttermilk, and skim milk powder, thickening polysaccharides such as pectin, carrageenan, xanthan gum, and gellan gum, antioxidants such as tocopherol, ascorbic acid fatty acid esters, lignans, coenzyme Q, oryzanol, tea extract, and rutin, plant sterols, salt, colorings, and flavors.
本発明の可塑性油脂組成物の製造方法は、特に限定されない。マーガリンやショートニングなどの製造に通常用いられる方法により製造される。例えば、油脂と必要に応じて油溶性成分とを含む融解状態の油相を調製する。必要に応じて、水に水溶性成分を溶解ないし分散させた水相を加え、混合乳化相する。そして次に、油相または混合乳化相を、好ましくは殺菌処理する。殺菌方法は、タンクでのバッチ式であってもよく、プレート型熱交換機や掻き取り式熱交換機を用いた連続式であってもよい。次に、冷却し、結晶化させる。好ましくは冷却し、可塑化させる。冷却条件は、徐冷却より急冷却の方が好ましい。冷却条件は、好ましくは-0.5℃/分以上であり、さらに好ましくは-5℃/分以上である。冷却する機器としては、密閉型連続式チューブ冷却機、例えば、ボテーター、コンピネーター及びパーフェクターなどの急冷混捏機が挙げられる。また、開放型のダイアクーラーとコンプレクターとの組合せが挙げられる。冷却結晶化された可塑性油脂組成物は、20~35℃程度の温度で、12~48時間程度、調温(熟成)処理されてもよい。 The method for producing the plastic oil composition of the present invention is not particularly limited. It is produced by a method commonly used for producing margarine, shortening, etc. For example, a melted oil phase containing oil and fat and, if necessary, an oil-soluble component is prepared. If necessary, an aqueous phase in which a water-soluble component is dissolved or dispersed in water is added to mix and emulsify the phase. Next, the oil phase or the mixed emulsion phase is preferably sterilized. The sterilization method may be a batch type in a tank, or a continuous type using a plate-type heat exchanger or a scraping-type heat exchanger. Next, the composition is cooled and crystallized. Preferably, the composition is cooled and plasticized. The cooling conditions are preferably rapid cooling rather than gradual cooling. The cooling conditions are preferably -0.5°C/min or more, and more preferably -5°C/min or more. Examples of cooling equipment include closed-type continuous tube coolers, such as rapid cooling mixers such as votators, compinators, and perfectors. Also, a combination of an open-type diacooler and a compinator may be used. The cooled and crystallized plastic oil composition may be subjected to temperature control (aging) treatment at a temperature of about 20 to 35°C for about 12 to 48 hours.
本発明の含気泡組成物は、油脂の含有量が70質量%未満である。すなわち、本発明の含気泡組成物に占める油脂の含有量は、好ましくは19~69質量%であり、より好ましくは24~63質量%であり、さらに好ましくは24~49質量%であり、ことさらに好ましくは29~45質量%であり、最も好ましくは29~42質量%である。本発明の含気泡組成物に含まれる油脂は、好ましくは本発明の可塑性油脂組成物に含まれる油脂と同一の構成である。本発明の含気泡組成物の好ましい1態様によれば、本発明の含気泡組成物は、本発明の可塑性油脂組成物を含む。本発明の含気泡組成物に占める本発明の可塑性油脂組成物の含有量は、好ましくは20~70質量%であり、より好ましくは25~64質量%であり、さらに好ましくは25~50質量%であり、ことさらに好ましくは30~46質量%であり、最も好ましくは30~43質量%である。 The aerated composition of the present invention has a fat content of less than 70% by mass. That is, the fat content of the aerated composition of the present invention is preferably 19 to 69% by mass, more preferably 24 to 63% by mass, even more preferably 24 to 49% by mass, even more preferably 29 to 45% by mass, and most preferably 29 to 42% by mass. The fat content of the aerated composition of the present invention is preferably the same as that of the plastic fat content of the present invention. According to a preferred embodiment of the aerated composition of the present invention, the aerated composition of the present invention contains the plastic fat content of the present invention. The fat content of the plastic fat content of the present invention in the aerated composition of the present invention is preferably 20 to 70% by mass, more preferably 25 to 64% by mass, even more preferably 25 to 50% by mass, even more preferably 30 to 46% by mass, and most preferably 30 to 43% by mass.
また、本発明の含気泡組成物は、油脂の含有量を100質量部として、上記構成脂肪酸に炭素数16以上の不飽和脂肪酸を有する乳化剤を、好ましくは0.05~2質量部、より好ましくは0.2~1.4質量部、さらに好ましくは0.3~1質量部、含み、上記構成脂肪酸に炭素数14以下の飽和脂肪酸を有するジグリセリン脂肪酸エステルを、好ましくは0.02~1.2質量部、より好ましくは0.08~0.8質量部、さらに好ましくは0.1~0.6質量部、含む。また、本発明の含気泡組成物の好ましい1態様は、油脂の含有量を100質量部として、上記構成脂肪酸に炭素数16以上の飽和脂肪酸を有するプロピレングリコール脂肪酸エステルを、好ましくは0.02~1.4質量部、より好ましくは0.08~1.0質量部、さらに好ましくは0.1~0.8質量部、含み、上記レシチンを、好ましくは0.005~0.12質量部、より好ましくは0.02~0.1質量部、さらに好ましくは0.03~0.08質量部、含む。 In addition, the aerated composition of the present invention contains, based on 100 parts by mass of fat or oil, preferably 0.05 to 2 parts by mass, more preferably 0.2 to 1.4 parts by mass, and even more preferably 0.3 to 1 part by mass of an emulsifier having an unsaturated fatty acid with 16 or more carbon atoms in the constituent fatty acids, and preferably 0.02 to 1.2 parts by mass, more preferably 0.08 to 0.8 parts by mass, and even more preferably 0.1 to 0.6 parts by mass of a diglycerol fatty acid ester having a saturated fatty acid with 14 or less carbon atoms in the constituent fatty acids. In addition, one preferred embodiment of the air-containing composition of the present invention contains, based on 100 parts by mass of the oil or fat content, preferably 0.02 to 1.4 parts by mass, more preferably 0.08 to 1.0 parts by mass, and even more preferably 0.1 to 0.8 parts by mass of a propylene glycol fatty acid ester having a saturated fatty acid with 16 or more carbon atoms as the constituent fatty acid, and preferably 0.005 to 0.12 parts by mass, more preferably 0.02 to 0.1 parts by mass, and even more preferably 0.03 to 0.08 parts by mass of the lecithin.
本発明の含気泡組成物は、好ましくは、水性成分を含有する。当該水性成分は、水および/または水に可溶の可食成分であれば特に限定されない。しかし、水性成分は、好ましくは甘味を有する糖質を含む。糖質は、食物繊維を除いた炭水化物である。糖質は、甘味を有すれば特に限定されない。糖質としては、例えば、ショ糖(砂糖および粉糖)、乳糖、ブドウ糖、果糖、麦芽糖、キシロース、トレハロース、オリゴ糖、ラフィノース、はちみつ、水飴、液糖、酵素転化水飴、ショ糖結合水飴、異性化液糖、デキストリンなどの糖類や、還元澱粉糖化物、還元糖ポリデキストロース、ソルビトール、還元乳糖、パラチニット、キシリトール、マルチトール、エリスリトール、マンニトールなどの糖アルコール類など、が挙げられる。 The aerated foam composition of the present invention preferably contains an aqueous component. The aqueous component is not particularly limited as long as it is water and/or an edible component soluble in water. However, the aqueous component preferably contains a carbohydrate having a sweet taste. The carbohydrate is a carbohydrate excluding dietary fiber. The carbohydrate is not particularly limited as long as it is sweet. Examples of carbohydrates include sugars such as sucrose (sugar and powdered sugar), lactose, glucose, fructose, maltose, xylose, trehalose, oligosaccharides, raffinose, honey, starch syrup, liquid sugar, enzyme-converted starch syrup, sucrose-bound starch syrup, isomerized liquid sugar, and dextrin, and sugar alcohols such as reduced starch syrup, reduced sugar polydextrose, sorbitol, reduced lactose, palatinit, xylitol, maltitol, erythritol, and mannitol.
上記水性成分は、無水または水溶液の状態であってもよいし、当該水溶液が最外相にある乳化状態(O/WまたはW/O/W)であってもよい。本発明の含気泡組成物に占める水性成分の含有量は、無水、水溶液、乳化、の各状態の水性成分の合計として、30質量%以上であり、好ましくは30~80質量%であり、より好ましくは36~75質量%であり、さらに好ましくは50~75質量%であり、ことさらに好ましくは54~70質量%であり、最も好ましくは57~70質量%である。 The aqueous component may be in an anhydrous or aqueous solution state, or in an emulsified state (O/W or W/O/W) in which the aqueous solution is the outermost phase. The content of the aqueous component in the aerated composition of the present invention is 30% by mass or more, preferably 30 to 80% by mass, more preferably 36 to 75% by mass, even more preferably 50 to 75% by mass, even more preferably 54 to 70% by mass, and most preferably 57 to 70% by mass, as the total of the aqueous components in the anhydrous, aqueous, and emulsion states.
本発明の含気泡組成物は、本発明の効果を損なわない限り、含気泡組成物に一般的に使用される、その他の食品素材を含んでもよい。その他の食品素材としては、例えば、ホエイパウダー、チーズパウダーなどの各種乳製品、カカオマス、ココアパウダーなどのカカオ製品、レモンパウダー、イチゴパウダーなどの各種果実加工粉末、各種野菜加工粉末、抹茶粉末、コーヒー粉末などの各種粉末、食塩、などが挙げられる。 The aerated foam composition of the present invention may contain other food ingredients that are generally used in aerated foam compositions, so long as they do not impair the effects of the present invention. Examples of other food ingredients include various dairy products such as whey powder and cheese powder, cacao products such as cacao mass and cocoa powder, various processed fruit powders such as lemon powder and strawberry powder, various processed vegetable powders, various powders such as matcha powder and coffee powder, table salt, etc.
本発明の含気泡組成物の製造方法は、特に限定されない。通常の含気泡組成物の製造方法が適用できる。本発明の含気泡組成物の製造方法の好ましい態様としては、例えば、本発明の可塑性油脂組成物に水性成分を加えて、起泡化(含気泡化)する、または、起泡化(含気泡化)させた可塑性油脂組成物に水性成分を加えて撹拌混合する、態様が挙げられる。本発明の含気泡組成物の比重は、好ましくは0.4~0.8であり、より好ましくは0.5~0.7であり、さらに好ましくは0.55~0.65である。 The method for producing the aerated composition of the present invention is not particularly limited. A typical method for producing aerated compositions can be applied. A preferred embodiment of the method for producing the aerated composition of the present invention is, for example, adding an aqueous component to the plastic oil composition of the present invention to foam (incorporate air bubbles), or adding an aqueous component to the foamed (aerated) plastic oil composition and stirring and mixing. The specific gravity of the aerated composition of the present invention is preferably 0.4 to 0.8, more preferably 0.5 to 0.7, and even more preferably 0.55 to 0.65.
本発明の可塑性油脂組成物および含気泡組成物は、ショートニング、マーガリン、スプレッドあるいはバタークリームとして、例えば、パンや焼菓子とともに直接食してもよい。また、パンや焼菓子の生地に、折り込み用、あるいは、練り込み用として、使用してもよい。パンや焼菓子としては、例えば、ビスケット、クッキー、クラッカー、乾パン、プレッツェル、カットパン、ウェハース、サブレ、ラングドシャ、マカロンなどの焼菓子、バターケーキ類(パウンドケーキ、フルーツケーキ、マドレーヌ、バウムクーヘン、カステラなど)、スポンジケーキ類(ショートケーキ、ロールケーキ、トルテ、デコレーションケーキ、シフォンケーキなど)、シュー菓子、発酵菓子、パイ、ワッフルなどの洋生菓子、菓子パン、フランスパン、シュトーレン、パネトーネ、ブリオッシュ、ドーナツ、デニッシュ、クロワッサン、などが挙げられる。 The plastic fat composition and the aerated composition of the present invention may be eaten directly with bread or baked goods, for example, as shortening, margarine, spread or butter cream. They may also be used for folding or kneading into dough for bread or baked goods. Examples of bread and baked goods include baked goods such as biscuits, cookies, crackers, dry bread, pretzels, cut bread, wafers, sables, langue de chat, and macarons, butter cakes (pound cake, fruit cake, madeleine, baumkuchen, castella, etc.), sponge cakes (shortcake, roll cake, torte, decorated cake, chiffon cake, etc.), choux pastries, fermented confectioneries, Western confectioneries such as pies and waffles, sweet breads, French breads, stollen, panettone, brioche, donuts, Danish pastries, and croissants.
以下、具体的な実施例に基づいて、本発明について詳しく説明する。なお、本発明は、以下に示す実施例の内容に、何ら限定されるものではない。 The present invention will be described in detail below based on specific examples. Note that the present invention is not limited in any way to the contents of the examples shown below.
<乳化剤>
以下の乳化剤を準備した。
・ソルビタンオレイン酸エステル(商品名:ポエムO-80V、略称O-80V、HLB4.9、理研ビタミン株式会社製)
・ショ糖エルカ酸エステル(商品名:リョートーシュガーエステルER-290、略称ER-290、HLB2、三菱ケミカルフーズ株式会社製)
・ショ糖ステアリン酸エステル(商品名:リョートーシュガーエステルS-170、略称S-170、HLB1、三菱ケミカルフーズ株式会社製
・ジグリセリンモノミリステート(商品名:ポエムDM-100、略称:DM-100、ジグリセリンモノミリステート含有量81質量%、HLB8.8、理研ビタミン株式会社製)
・ジグリセリンモノパルミテート(商品名:ポエムDP-95RF、略称:DP-95RF、ジグリセリンモノパルミテート含有量85質量%、HLB8.0、理研ビタミン株式会社製)
・ジグリセリンモノパルミテートとジグリセリンモノステアレートの混合物(商品名:ポエムDS-80RF、略称:DS-80RF、ジグリセリンモノパルミテートとジグリセリンモノステアレートの合計含有量64質量%、HLB6.5、理研ビタミン株式会社製)
・プロピレングリコールモノステアレート(商品名:リケマールPS-100、略称:PS-100、ステアリン酸含有量85質量%以上、理研ビタミン株式会社製)
・大豆レシチン(商品名:レシチンDX、略称:DX、アセトン不溶分65質量%、日清オイリオグループ株式会社製)
<Emulsifier>
The following emulsifiers were prepared:
Sorbitan oleate (product name: Poem O-80V, abbreviated as O-80V, HLB 4.9, manufactured by Riken Vitamin Co., Ltd.)
Sucrose erucic acid ester (product name: Ryoto Sugar Ester ER-290, abbreviated ER-290, HLB 2, manufactured by Mitsubishi Chemical Foods Corporation)
Sucrose stearate (product name: Ryoto Sugar Ester S-170, abbreviated as S-170, HLB 1, manufactured by Mitsubishi Chemical Foods Corporation) Diglycerin monomyristate (product name: Poem DM-100, abbreviated as DM-100, diglycerin monomyristate content 81% by mass, HLB 8.8, manufactured by Riken Vitamin Co., Ltd.)
Diglycerin monopalmitate (product name: Poem DP-95RF, abbreviation: DP-95RF, diglycerin monopalmitate content 85% by mass, HLB 8.0, manufactured by Riken Vitamin Co., Ltd.)
Mixture of diglycerin monopalmitate and diglycerin monostearate (product name: Poem DS-80RF, abbreviation: DS-80RF, total content of diglycerin monopalmitate and diglycerin monostearate: 64% by mass, HLB: 6.5, manufactured by Riken Vitamin Co., Ltd.)
Propylene glycol monostearate (product name: Rikemal PS-100, abbreviation: PS-100, stearic acid content of 85% or more by mass, manufactured by Riken Vitamin Co., Ltd.)
Soy lecithin (product name: Lecithin DX, abbreviation: DX, acetone insoluble content 65% by mass, manufactured by Nisshin Oillio Group Co., Ltd.)
<食用油脂>
以下の食用油脂を準備した。
・エステル交換油脂A(40質量部のパーム核油と60質量部のパーム油からなる混合油のケミカルエステル交換油脂、略称:IE-A、日清オイリオグループ株式会社製)
・エステル交換油脂B(50質量部の極度硬化パーム核油と50質量部の極度硬化パーム油からなるケミカルエステル交換油脂、略称:IE-B、日清オイリオグループ株式会社製)
・エステル交換油脂C(パームオレインのケミカルエステル交換油脂、略称:IE-C、日清オイリオグループ株式会社製)
・極度硬化ヤシ油(略称:FHCNO、日清オイリオグループ株式会社製)
・菜種油(略称:RSO、日清オイリオグループ株式会社製)
<Edible oils and fats>
The following edible oils and fats were prepared:
-Interesterified oil A (chemically interesterified oil of a mixture of 40 parts by mass of palm kernel oil and 60 parts by mass of palm oil, abbreviated as IE-A, manufactured by Nisshin Oillio Group Co., Ltd.)
-Interesterified oil B (chemically interesterified oil consisting of 50 parts by mass of extremely hardened palm kernel oil and 50 parts by mass of extremely hardened palm oil, abbreviated as IE-B, manufactured by Nisshin Oillio Group, Ltd.)
・Interesterified oil C (chemically interesterified palm olein oil, abbreviated as IE-C, manufactured by Nisshin Oillio Group, Ltd.)
・FHCNO (Freshly hydrogenated coconut oil) (manufactured by Nisshin Oillio Group, Ltd.)
・Rapeseed oil (abbreviation: RSO, manufactured by Nisshin Oillio Group, Ltd.)
<可塑性油脂組成物の調製>
表1、2の配合に従って、可塑性油脂組成物(ショートニング)を製造した。すなわち、油脂と乳化剤とを混合融解し、常法に従ってコンビネーターを用いて急冷混捏(窒素ガス20体積%封入)を行い、例1~例10のショートニングを得た。
<Preparation of plastic oil composition>
Plastic fat compositions (shortenings) were produced according to the formulations in Tables 1 and 2. That is, fats and oils and emulsifiers were mixed and melted, and then rapidly cooled and kneaded using a combinator in the usual manner (20% by volume of nitrogen gas was enclosed), to obtain the shortenings of Examples 1 to 10.
<含気泡組成物の調製>
ホバートミキサーで、300gの例1~例10の各ショートニングを比重0.50までミキシングした。その後、540gのマルトースシロップ(Brix70、日本食品化工株式会社製)を投入し、比重0.60までミキシングし、例1~例10の含気泡組成物(バタークリーム)を得た。
<Preparation of Foam Composition>
300 g of each of the shortenings of Examples 1 to 10 was mixed in a Hobart mixer until the specific gravity reached 0.50. Then, 540 g of maltose syrup (Brix 70, manufactured by Nihon Shokuhin Kako Co., Ltd.) was added and mixed until the specific gravity reached 0.60, to obtain the aerated compositions (butter cream) of Examples 1 to 10.
<含気泡組成物の評価>
例1~例10のバタークリームについて、絞り袋から絞り出したクリームを32℃で3日間静置して、状態の変化(耐熱性)を観察した。また、熟練パネラー5名により、クリームの口どけについて評価した。評価基準は以下に示した。また、評価結果を表1、2に示した。
<Evaluation of air-containing foam composition>
For the butter creams of Examples 1 to 10, the creams squeezed out of the piping bag were left to stand at 32°C for three days, and the change in state (heat resistance) was observed. In addition, the creams were evaluated for melting in the mouth by five experienced panelists. The evaluation criteria are shown below. The evaluation results are shown in Tables 1 and 2.
(耐熱性評価基準)
◎:32℃静置前と変化がなく非常に良好
○:32℃静置前とほぼ変化がなく良好
△:32℃静置前よりややだれて(脱気して)いる
×:32℃静置前よりだれて(脱気して)、オイルオフがある
(口どけ評価基準)
各パネラーが、以下の基準で評点し、評点の合計により、以下の基準で総合評価した。
評点
口どけが非常に良好 2点
口どけが良好 1点
口どけが許容範囲 0点
口どけが悪く、不可 -1点
評点合計による口どけの総合評価
◎:8点以上 口どけが非常に優れている
○:5点以上7点以下 口どけが優れている
△:2点以上4点以下 口どけが許容範囲
×:1点以下 口どけが優れない
(Heat resistance evaluation criteria)
◎: No change from before leaving at 32°C, very good ○: Almost no change from before leaving at 32°C, good △: Slightly sagging (deaeration) compared to before leaving at 32°C ×: Sagging (deaeration) compared to before leaving at 32°C, oil loss
(Evaluation criteria for meltability)
Each panelist scored according to the following criteria, and the total scores were used to give an overall evaluation according to the following criteria.
Score Very good melting in the mouth 2 points Good melting in the mouth 1 point Melting in the mouth is within the acceptable range 0 points Poor melting in the mouth, unacceptable -1 point
Overall evaluation of melting in the mouth based on the total score ◎: 8 points or more, very good melting in the mouth ○: 5 points to 7 points, good melting in the mouth △: 2 points to 4 points, acceptable melting in the mouth ×: 1 point or less, not good melting in the mouth
Claims (7)
ジグリセリンミリステート、ジグリセリンラウレート、から選ばれる1種以上の、HLBが6~11であるジグリセリン脂肪酸エステルと、を含み、
油脂の含有量が70質量%以上である、バタークリーム用の可塑性油脂組成物であって、
前記油脂に占める、ラウリン系油脂を原料油脂として含むエステル交換油脂の含有量が55~100質量%である、前記バタークリーム用可塑性油脂組成物。 one or more emulsifiers selected from sorbitan fatty acid esters, sucrose fatty acid esters, and polyglycerin fatty acid esters, each of which has an unsaturated fatty acid having 16 or more carbon atoms in its constituent fatty acids and has an HLB of 1 to 8;
and one or more diglycerol fatty acid esters having an HLB of 6 to 11 selected from diglycerol myristate and diglycerol laurate ,
A plastic oil-and-fat composition for butter cream having an oil-and-fat content of 70% by mass or more,
The plastic oil-and-fat composition for butter cream, wherein the content of transesterified oil-and-fat containing lauric oil-and-fat as a raw material oil-and-fat in the oil-and-fat is 55 to 100 mass%.
構成脂肪酸中に炭素数16以上の不飽和脂肪酸を有する、ソルビタン脂肪酸エステル、ショ糖脂肪酸エステル、ポリグリセリン脂肪酸エステル、から選ばれる1種以上の、HLBが1~8である乳化剤と、ジグリセリンミリステート、ジグリセリンラウレート、から選ばれる1種以上の、HLBが6~11であるジグリセリン脂肪酸エステルと、を溶融した融解状態の油脂、を含む組成物を、冷却可塑化する、前記製造方法。 A method for producing a plastic oil composition for butter cream according to any one of claims 1 to 4 , comprising the steps of:
The method for producing the composition includes cooling and plasticizing a composition containing a molten oil or fat obtained by melting one or more emulsifiers having an HLB value of 1 to 8, selected from sorbitan fatty acid esters, sucrose fatty acid esters, and polyglycerol fatty acid esters, each of which has an unsaturated fatty acid having 16 or more carbon atoms in its constituent fatty acids, and one or more diglycerol fatty acid esters having an HLB value of 6 to 11, selected from diglycerol myristate and diglycerol laurate.
前記油脂に占める、ラウリン系油脂を原料油脂として含むエステル交換油脂の含有量が55~100質量%である、前記バタークリーム。 A butter cream comprising one or more emulsifiers having an HLB of 1 to 8 and selected from sorbitan fatty acid esters, sucrose fatty acid esters, and polyglycerin fatty acid esters, each of which has an unsaturated fatty acid having 16 or more carbon atoms in its constituent fatty acids, and one or more diglycerin fatty acid esters having an HLB of 6 to 11 and selected from diglycerin myristate and diglycerin laurate , and comprising less than 70% by mass of fats and oils and 30% by mass or more of an aqueous component,
The butter cream, wherein the content of transesterified fats and oils containing lauric fats and oils as raw material fats and oils is 55 to 100% by mass.
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WO2012121010A1 (en) | 2011-03-04 | 2012-09-13 | 日清オイリオグループ株式会社 | Oil or fat composition and butter cream using oil or fat composition |
JP2015107098A (en) | 2013-10-21 | 2015-06-11 | ミヨシ油脂株式会社 | Plastic oil and fat composition and plastic oil and fat composition added food |
JP2016171764A (en) | 2015-03-16 | 2016-09-29 | 理研ビタミン株式会社 | Foamable oil-in-water type emulsion composition |
JP2017012167A (en) | 2015-07-02 | 2017-01-19 | 花王株式会社 | Oil and fat composition |
JP2018046798A (en) | 2016-09-23 | 2018-03-29 | 日清オイリオグループ株式会社 | Oil and fat composition for improving texture and method for producing the same, and method for improving texture of cooking utensils |
JP2021003008A (en) | 2019-06-25 | 2021-01-14 | 日油株式会社 | Fat composition for fry batter and fried food |
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WO2012121010A1 (en) | 2011-03-04 | 2012-09-13 | 日清オイリオグループ株式会社 | Oil or fat composition and butter cream using oil or fat composition |
JP2015107098A (en) | 2013-10-21 | 2015-06-11 | ミヨシ油脂株式会社 | Plastic oil and fat composition and plastic oil and fat composition added food |
JP2016171764A (en) | 2015-03-16 | 2016-09-29 | 理研ビタミン株式会社 | Foamable oil-in-water type emulsion composition |
JP2017012167A (en) | 2015-07-02 | 2017-01-19 | 花王株式会社 | Oil and fat composition |
JP2018046798A (en) | 2016-09-23 | 2018-03-29 | 日清オイリオグループ株式会社 | Oil and fat composition for improving texture and method for producing the same, and method for improving texture of cooking utensils |
JP2021003008A (en) | 2019-06-25 | 2021-01-14 | 日油株式会社 | Fat composition for fry batter and fried food |
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