JP6918453B2 - How to prevent water separation from food - Google Patents

How to prevent water separation from food Download PDF

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JP6918453B2
JP6918453B2 JP2016164050A JP2016164050A JP6918453B2 JP 6918453 B2 JP6918453 B2 JP 6918453B2 JP 2016164050 A JP2016164050 A JP 2016164050A JP 2016164050 A JP2016164050 A JP 2016164050A JP 6918453 B2 JP6918453 B2 JP 6918453B2
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water separation
food
welan gum
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water
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JP2017042164A (en
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正治 佐賀
正治 佐賀
允 小野寺
允 小野寺
泰之 佐藤
泰之 佐藤
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San Ei Gen FFI Inc
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Description

本発明は、ウェランガムを含有することにより、保水性・保湿性が維持され、離水という品質上望ましくない現象が実質的に生じない食品に関する。 The present invention relates to a food containing welan gum, which maintains water retention and moisture retention, and substantially does not cause a quality-undesired phenomenon of water separation.

本発明に係る食品は、離水が有意に抑制されるために、長期に亘る保存によっても瑞々しさを保持し、食品本来の食感を損なわないという面で有益である。 Since the food according to the present invention is significantly suppressed from water separation, it is beneficial in that it retains its freshness even after long-term storage and does not impair the original texture of the food.

カラギーナン及び寒天等を含有するゼリー、水ようかん等の食品は、缶又はカップに充填密封され、殺菌して市場に流通・供給されるが、冷蔵や常温保存中、或いは冷凍解凍時に該食品から経時的に水分が流出するいわゆる「離水」が起こる。このため、こうした食品を長期間保存すると食品に含まれる水分含量が減少して食感が損なわれる、味が変化する等の問題がある。また、保存期間が長期でなくても製造直後から離水は起こるため、製造後すぐに消費者に販売された場合でも、消費者が缶を開けたときや蓋をはがした際に、離水した水分が手につく、飛び散る等の問題があった。更に、ペクチン等を含有するジャム類や、寒天・ゼラチン等をゲル化剤として用いたヨーグルト等では、商品として容器に入ったそのままの状態でも離水は生じているが、特に容器を開けて一部をすくい取った後により著しく離水し、経時的な品質劣化を惹起するとともに、風味や外観が損なわれて飲食者に好ましくない印象を与え、嗜好意欲を減退させてしまうという問題があった。 Foods such as jelly and water yokan containing carrageenan and agar are filled and sealed in cans or cups, sterilized, and distributed and supplied to the market. So-called "water separation" occurs in which water flows out. Therefore, when such foods are stored for a long period of time, there are problems that the water content contained in the foods is reduced, the texture is impaired, and the taste is changed. In addition, even if the storage period is not long, water separation occurs immediately after production, so even if the product is sold to consumers immediately after production, water separation occurs when the consumer opens the can or removes the lid. There were problems such as water getting on the hands and splashing. Furthermore, with jams containing pectin, etc., and yogurt, etc. using agar, gelatin, etc. as a gelling agent, water separation occurs even when the product is in the container as it is, but especially when the container is opened, a part of it is separated. After scooping out the water, the water is separated more significantly, causing quality deterioration over time, and the flavor and appearance are impaired, giving an unfavorable impression to the food and drink, and reducing the motivation for taste.

上記のような多糖類で水分を保持する食品以外であっても、経時的な水分の喪失が続くことにより、食感が固くなる、乾燥したものとなるほかにも、当該食品の周囲へ浸潤するなどの問題が生じている。 Even if the food is not a food that retains water with the above-mentioned polysaccharides, the texture becomes hard and dry due to the continued loss of water over time, and infiltrates the surroundings of the food. There is a problem such as

「ゲル」又は「ゲル組成物」は、通常その内部に大量の液体を保持するものであるため、経時的に離水が生じるが、特にゲル化して成形した後に切断・破断等による構造破壊が一部にでもあると、離水の程度がより大きくなる。このようなゲル又はゲル組成物の離水による品質低下を抑制するために、従来ゲル化剤の配合量を多くする方法や、イオタカラギーナン、グァーガム、ペクチン、タマリンド等を併用する方法等が提案されている。 Since a "gel" or "gel composition" usually holds a large amount of liquid inside, water separation occurs over time, but structural destruction due to cutting, breaking, etc. is particularly severe after gelation and molding. If it is also in the part, the degree of water separation will be greater. In order to suppress the deterioration of quality of the gel or gel composition due to water separation, a method of increasing the amount of the gelling agent to be blended, a method of using iota carrageenan, guar gum, pectin, tamarind, etc. together have been proposed. There is.

しかしながら、これらのいずれの方法によっても、離水を十分に抑制することはできておらず、しかも食品に添加すると弾力性が出てしまうなど、本来の食品等の性状に悪影響を与え、本来の食感が損なわれる。また、食品から離水した水分が表面を覆うために、食品に含まれる香気成分本来の効果が弱まることがある。さらに、離水した水分がこぼれて周辺を汚してしまう等の問題もある。 However, none of these methods can sufficiently suppress water separation, and when added to foods, elasticity is exerted, which adversely affects the properties of the original foods and the original foods. The feeling is impaired. In addition, since the water separated from the food covers the surface, the original effect of the aroma component contained in the food may be weakened. Further, there is a problem that the separated water spills and pollutes the surrounding area.

また、十分な離水の抑制手段がないために、水分を保持した食品、ゲル化剤を用いたデザート食品等の工業製品は長期保存ができず、経時的に進行する離水が商品の寿命さえも決定する大きな要因ともなっていた。 In addition, industrial products such as foods that retain water and dessert foods that use gelling agents cannot be stored for a long period of time due to lack of sufficient means of suppressing water separation, and the water separation that progresses over time extends the life of the product. It was also a big factor in deciding.

このため、上記のような食品において、離水を防止・抑制する簡便な方法が種々提案されている。 Therefore, various simple methods for preventing / suppressing water separation have been proposed for the above-mentioned foods.

具体的には、サイリウムシードガムを含有することによる冷凍解凍ゼリーの離水抑制方法(特許文献1)、ラムザンガムを含有する冷菓用安定剤(特許文献2)、ネイティブジェランガムを含むことによる離水の抑制されたゲル組成物(特許文献3)、セルロース系粉末を含む具材と、パン又は飯が接触している加工食品(特許文献4)などが開示されているが、改善の余地が残されているのが実情である。 Specifically, a method for suppressing water separation of frozen and thawed jelly by containing psyllium seed gum (Patent Document 1), a stabilizer for frozen desserts containing ramzan gum (Patent Document 2), and suppressing water separation by containing native gellan gum. A gel composition (Patent Document 3), a processed food in which bread or rice is in contact with an ingredient containing a cellulose-based powder (Patent Document 4), etc. are disclosed, but there is still room for improvement. Is the reality.

特開2011−142906号公報Japanese Unexamined Patent Publication No. 2011-142906 特開2007−159570号公報Japanese Unexamined Patent Publication No. 2007-159570 特開平10−150933号公報Japanese Unexamined Patent Publication No. 10-150933 特開2011−254770号公報Japanese Unexamined Patent Publication No. 2011-254770

本発明は、かかる事情に鑑みて開発されたもので、食品全般において、本来の弾性、強度等の特性を変更することなく、食品の保存(常温、冷蔵及び冷凍解凍)時に生じる離水を有意に防止・抑制した食品を提供することを目的とする。 The present invention has been developed in view of such circumstances, and significantly reduces water separation that occurs during food storage (normal temperature, refrigeration, freezing and thawing) without changing the original properties such as elasticity and strength in foods in general. The purpose is to provide foods that have been prevented or suppressed.

また本発明は、食品の内部に液体を安定に閉じこめ、長期保存によっても実質的に離水を生じさせない方法、つまり食品の離水を抑制する方法を提供することを目的とする。 Another object of the present invention is to provide a method for stably confining a liquid inside a food and substantially preventing water separation even by long-term storage, that is, a method for suppressing water separation of the food.

本発明者らは、上記課題を解決すべく鋭意研究を重ねていたところ、ウェランガムを添加することにより食品本来の弾力、固さ、強度、食感といった各食品の特性を損ねることなく、離水という望ましくない現象が抑制されることを見出し、本発明を完成するに至った。 As a result of intensive research to solve the above problems, the present inventors have conducted water separation without impairing the original elasticity, hardness, strength, texture and other characteristics of each food by adding welan gum. We have found that undesired phenomena are suppressed, and have completed the present invention.

すなわち、本発明はウェランガムを含有する離水の抑制された食品に関する。 That is, the present invention relates to a food containing welan gum and having suppressed water separation.

また本発明は、ウェランガムを添加することを特徴とする食品の離水抑制方法にも関する。 The present invention also relates to a method for suppressing water separation of foods, which comprises adding welan gum.

本発明で対象となる食品は、多量の液体を含むが自重では流れ出さず、形を保っているものをいう。具体的には、海苔の佃煮、ツナマヨネーズ(おにぎりやサンドイッチの具材)、ピザソースやウスターソースのようなソース類、ヨーグルト、水ようかん、フルーツゼリー、プリン、ジャム、ハンバーグ、餃子の具材、春巻きの具材、野菜炒め、ホイップクリーム等が例示できる。 The food object of the present invention is a food containing a large amount of liquid, but does not flow out under its own weight and maintains its shape. Specifically, boiled seaweed, tuna mayonnaise (rice balls and sandwich ingredients), sauces such as pizza sauce and Worcestershire sauce, yogurt, water yokan, fruit jelly, pudding, jam, hamburger, dumpling ingredients, spring roll ingredients Examples include wood, fried vegetables, and whipped cream.

また本発明で「離水」とは、食品中に一旦保持された液体がその後経時的に食品からにじみ出てくる現象をいう。 Further, in the present invention, "water separation" refers to a phenomenon in which a liquid once held in a food oozes out from the food over time.

なお上記「食品」及び「離水」をはじめ本発明の説明中でいう「液体」とは、水を含む水性成分をいい、「水」及び「水に、糖類・多糖類・保存料・香料・色素・調味料・乳化剤等の水に溶解もしくは乳化し得るものを溶解・乳化させたもの」の双方を含む。 The "liquid" referred to in the description of the present invention including the above "food" and "water separation" means an aqueous component containing water, and "water" and "water, sugars, polysaccharides, preservatives, fragrances, etc." Includes both pigments, seasonings, emulsifiers, and other substances that can be dissolved or emulsified in water and dissolved and emulsified.

本発明の離水の抑制された食品は、ウェランガムを含有することを特徴とするものである。
ウェランガムは、スフィンゴモナス属細菌(Sphingomonas sp.)の培養液から得られた多糖類を主成分とするものである。簡便には、一般に流通している市販製品を利用することが可能であり、具体的には三栄源エフ・エフ・アイ株式会社のビストップ(登録商標)W等が例示できる。
The food with suppressed water separation of the present invention is characterized by containing welan gum.
Welan gum is mainly composed of a polysaccharide obtained from a culture solution of a bacterium belonging to the genus Sphingomonas (Sphingomonas sp.). It is possible to easily use a commercially available product that is generally distributed, and specifically, Bistop (registered trademark) W of Saneigen FFI Co., Ltd. can be exemplified.

本発明は、ウェランガムが食品に含まれる液体をその内部に安定に閉じこめる特性を有するという知見に基づくものである。従って、本発明の離水が問題となる食品であれば制限はなく適用することができる。 The present invention is based on the finding that welan gum has a property of stably confining a liquid contained in a food material therein. Therefore, any food of the present invention in which water separation is a problem can be applied without limitation.

より具体的に、本発明が適用される食品としては、水畜産加工品(例えば、ソーセージ、ハム、豚カツ、ハンバーグ、つみれ等)、肉まん・餃子・春巻き・シュウマイやコロッケ等の具材、おにぎりやサンドイッチの具材(例:ツナマヨネーズ)、野菜炒め、だし巻き、練りわさび・練りカラシ・練りショウガ等の練り製品、ヨーグルト、水ようかん等の寒天製品、イチゴジャム・マーマレード等のジャム類、ワインゼリー・コーヒーゼリー・フルーツゼリー等のゼリー類やホイップクリーム、海苔の佃煮、塩辛等に使用する調味液やタレ、ピザソースやウスターソースのようなソース類が例示される。これらはいずれも食品製造後や保存時等の離水が問題となるものであって、これにより視覚的及び味覚的に商品価値が低下するものである。 More specifically, the foods to which the present invention is applied include processed aquatic products (for example, sausages, hams, pork cutlets, hamburgers, tsumire, etc.), meat buns, dumplings, spring rolls, ingredients such as shumai and croquettes, and rice balls. Sandwich ingredients (eg tuna mayonnaise), fried vegetables, dashi rolls, kneaded wasabi, kneaded rice balls, kneaded ginger and other kneaded products, yogurt, water yokan and other agar products, strawberry jam, marmalade and other jams, wine jelly and coffee Examples include jellies such as jelly and fruit jelly, whipped cream, seasoning liquids and sauces used for boiled seaweed, salted spicy sauce, and sauces such as pizza sauce and Worcestershire sauce. In all of these, water separation after food production or storage is a problem, which visually and tastefully reduces the commercial value.

本発明にかかる食品は、該食品本来の弾力性、強度、味や風味といった特性を損なうことなく、食品の保存(常温、冷蔵及び冷凍解凍)時に生じる離水を有意に抑制することにより、該食品等の品質を良好に保持することができるものである点で有用である。 The food according to the present invention is the food by significantly suppressing water separation that occurs during storage (normal temperature, refrigeration and freezing and thawing) of the food without impairing the original elasticity, strength, taste and flavor of the food. It is useful in that it can maintain good quality such as.

本発明にかかる離水の抑制された食品に含まれるウェランガムの量は、対象とする食品等の種類によって適宜調節すればよく、必要に応じて従来使用されている他のゲル化剤等と併用することもできる。具体的なウェランガムの添加量は、添加する食品に対し通常0.01〜1.5質量%、好ましくは0.05〜0.5質量%の範囲から適宜選択される。 The amount of welan gum contained in the food with suppressed water separation according to the present invention may be appropriately adjusted according to the type of the target food or the like, and may be used in combination with other conventionally used gelling agents or the like as necessary. You can also do it. The specific amount of welan gum added is appropriately selected from the range of usually 0.01 to 1.5% by mass, preferably 0.05 to 0.5% by mass with respect to the food to be added.

また本発明は、ウェランガムを添加することを特徴とする食品の離水抑制方法に関する。 The present invention also relates to a method for suppressing water separation of foods, which comprises adding welan gum.

かかる方法は、食品の製造工程において原料の一種としてウェランガムを添加・配合することによって達成される。従って、別の局面から見れば、当該方法は前述の離水の抑制された食品の製造方法ともいえる。 Such a method is achieved by adding and blending welan gum as a kind of raw material in the food manufacturing process. Therefore, from another aspect, the method can be said to be the above-mentioned method for producing a food product in which water separation is suppressed.

以下、本発明の内容を以下の実施例、比較例等を用いて具体的に説明するが、本発明はこれらに何ら限定されるものではない。なお、処方中、特に記載がない限り、「%」は「質量%」、「部」は「質量部」であり、文中「*」印のものは、三栄源エフ・エフ・アイ株式会社製、文中「※」は三栄源エフ・エフ・アイ株式会社の登録商標であることを示す。 Hereinafter, the contents of the present invention will be specifically described with reference to the following examples, comparative examples, etc., but the present invention is not limited thereto. In the prescription, unless otherwise specified, "%" is "mass%", "part" is "part by mass", and those marked with "*" in the text are manufactured by Saneigen FFI Co., Ltd. , "*" In the text indicates that it is a registered trademark of Saneigen FFI Co., Ltd.

実験例1 海苔の佃煮
次の処方に基づき、海苔の佃煮を調製した。使用した増粘剤の種類と添加量を、表1に示す。また、得られた海苔の佃煮の粘度、離水の程度及び食感についての評価結果も表1に示す。
Experimental Example 1 Nori tsukudani Based on the following formulation, nori tsukudani was prepared. Table 1 shows the types and amounts of thickeners used. Table 1 also shows the evaluation results of the viscosity of the obtained seaweed boiled in soy sauce, the degree of water separation, and the texture.

<処方>
濃口醤油 39.0
水あめ 20.0
砂糖 11.0
生海苔 58.3
L−グルタミン酸ナトリウム 0.3
増粘剤 表1参照
煮詰めて全量 100.0 部
<Prescription>
Dark soy sauce 39.0
Syrup 20.0
Sugar 11.0
Raw seaweed 58.3
Sodium L-glutamate 0.3
Thickener See Table 1
Boil down and total 100.0 copies

<調製方法>
1) 生海苔以外の原料に増粘剤を加え、80℃にて10分間攪拌した。
2) 生海苔を加え、よく混ぜながら全量が100部になるまで弱火で煮詰めた。
<Preparation method>
1) A thickener was added to a raw material other than raw seaweed, and the mixture was stirred at 80 ° C. for 10 minutes.
2) Add raw seaweed, mix well and boil down over low heat until the total amount reaches 100 parts.

<評価方法>
・粘度:デジタル型粘度計(B型回転粘度計)にて、測定温度20℃、回転数60rpm、1分後の粘度を測定した。
・離水:φ150mmのろ紙(No.2)の円内(φ70mm)に、調製した試料(海苔の佃煮)10gを均一に広げた。その後、室温で1時間静置し、目視にてろ紙の濡れ具合(水の滲み出る量)にて評価した(「+(少ない)〜+++(多い)」)。
<Evaluation method>
-Viscosity: With a digital viscometer (B-type rotational viscometer), the measurement temperature was 20 ° C., the rotation speed was 60 rpm, and the viscosity after 1 minute was measured.
-Water separation: 10 g of the prepared sample (boiled seaweed) was uniformly spread in a circle (φ70 mm) of a filter paper (No. 2) having a diameter of 150 mm. Then, it was allowed to stand at room temperature for 1 hour, and visually evaluated by the wetness of the filter paper (the amount of water exuding) (“+ (less) to +++ (more)”).

Figure 0006918453
Figure 0006918453

<評価>
表1の結果より、ウェランガムを海苔の佃煮に添加した場合、従来使用されているキサンタンガム、タマリンドシードガムより低添加量で同等の離水抑制効果を得ることができた。さらに、ウェランガムを添加したものでは、ヌメリが殆どない優れた食感となっていた。
<Evaluation>
From the results in Table 1, when welan gum was added to the boiled seaweed, the same water separation suppressing effect could be obtained with a lower amount of addition than the conventionally used xanthan gum and tamarind seed gum. Furthermore, the one to which welan gum was added had an excellent texture with almost no slime.

実験例2 ツナマヨネーズ(おにぎりの具材)
次の処方に基づき、おにぎりの具材であるツナマヨネーズを調製した。使用した増粘剤の種類と添加量を表2に示す。また、得られたツナマヨネーズの離水率と食感についても、表2に示す。
Experimental example 2 Tuna mayonnaise (rice ball ingredients)
Based on the following prescription, tuna mayonnaise, which is an ingredient for rice balls, was prepared. Table 2 shows the types of thickeners used and the amounts added. Table 2 also shows the water separation rate and texture of the obtained tuna mayonnaise.

<処方>
マヨネーズ(市販品) 58.0
ツナ缶詰(液切りなし) 40.0
(はごろもフーズ シーチキン L フレーク)
醤油 1.5
増粘剤 表2参照
イオン交換水にて全量 100.0 %
<Prescription>
Mayonnaise (commercially available) 58.0
Canned tuna (without draining) 40.0
(Hagoromo Foods Sea Chicken L Flakes)
Soy sauce 1.5
Thickener See Table 2
Total amount 100.0% with ion-exchanged water

<調製方法>
1) 全原料をよく混合した。
<Preparation method>
1) All raw materials were mixed well.

<評価方法>
離水率:2枚重ねたろ紙(No.2、10cm四方)の上にツナマヨネーズ10gをのせ、さらに上から2枚重ねたろ紙にて挟み、全体をラップで包んだ。その後、室温条件下1時間及び17時間静置し、下式により離水率を算出した。

離水率(%)=(試料を除去した後のろ紙の質量−評価前のろ紙の質量)/ろ紙にのせた試料の質量(10g)×100(以下、同じ)

また、得られたツナマヨネーズを12時間冷蔵保管した後に食感を評価した。これらの結果を表2に示す。
<Evaluation method>
Water separation rate: 10 g of tuna mayonnaise was placed on two layers of filter paper (No. 2, 10 cm square), sandwiched between two layers of filter paper from the top, and the whole was wrapped in a wrap. Then, it was allowed to stand for 1 hour and 17 hours under room temperature conditions, and the water separation rate was calculated by the following formula.

Water separation rate (%) = (mass of filter paper after removing sample-mass of filter paper before evaluation) / mass of sample placed on filter paper (10 g) x 100 (hereinafter the same)

In addition, the texture of the obtained tuna mayonnaise was evaluated after refrigerating for 12 hours. These results are shown in Table 2.

Figure 0006918453
Figure 0006918453

<評価>
表2の結果より、ウェランガムをツナマヨネーズに添加した場合、キサンタンガムよりも優れた離水抑制効果が得られることがわかった。ウェランガムの添加量が多くなってもヌメリはほとんど感じられず、キサンタンガムを添加したものよりもほぐれやすい食感となっていた。
<Evaluation>
From the results in Table 2, it was found that when welan gum was added to tuna mayonnaise, a superior water separation suppressing effect was obtained as compared with xanthan gum. Even if the amount of welan gum added was large, slime was hardly felt, and the texture was easier to loosen than that with xanthan gum added.

実験例3 ピザソース
次の処方に基づき、ピザソースを調製した。使用した増粘剤の種類と添加量を、表3に示す。得られたピザソースの粘度と冷凍解凍前後の離水の程度、食感の評価についても表3に示す。
Experimental Example 3 Pizza sauce A pizza sauce was prepared based on the following prescription. Table 3 shows the types and amounts of thickeners used. Table 3 also shows the viscosity of the obtained pizza sauce, the degree of water separation before and after freezing and thawing, and the evaluation of texture.

<処方>
トマトペースト 30.0
トマト加工品 1.0
(Clear Tomato Concentrate 60°BX*)
サラダ油 2.0
醸造酢(酸度10%) 2.0
果糖ぶどう糖液糖 3.0
ガーリックペースト 1.0
食塩 1.0
増粘剤 表3参照
イオン交換水にて全量 100 %
<Prescription>
Tomato paste 30.0
Processed tomato product 1.0
(Clear Tomato Concentrate 60 ° BX *)
Salad oil 2.0
Brewed vinegar (acidity 10%) 2.0
Fructose-glucose liquid sugar 3.0
Garlic paste 1.0
Salt 1.0
Thickener See Table 3 Total amount 100% with ion-exchanged water

<調製方法>
1) イオン交換水にサラダ油、果糖ぶどう糖液糖、増粘剤を加え、85℃にて10分間撹拌した。
2) 残りの全原料を加え、さらに85℃にて5分間撹拌した。
3) 全量補正後、容器に充填した。
4) 85℃にて30分間ボイル殺菌した。
5) 20℃まで冷却した。
<Preparation method>
1) Salad oil, high fructose corn syrup, and thickener were added to ion-exchanged water, and the mixture was stirred at 85 ° C. for 10 minutes.
2) All the remaining raw materials were added, and the mixture was further stirred at 85 ° C. for 5 minutes.
3) After the total amount was corrected, the container was filled.
4) Boil sterilized at 85 ° C. for 30 minutes.
5) Cooled to 20 ° C.

<評価方法>
・粘度:デジタル型粘度計(B型回転粘度計)にて、測定温度20℃、回転数60rpm、1分後の粘度を測定した。
・冷凍解凍前の離水の測定:φ150mmのろ紙(No.2)の円内(φ58mm)に試料10gを乗せ、均一に広げた。その後、室温で1時間静置し、離水の状態を目視で観察した。離水は「+(少ない)〜+++(多い)」で評価した。
・冷凍解凍後の離水の測定:上記と同様にろ紙に試料をのせ、−40℃で急速凍結(1時間)した。その後、室温で1時間静置し、目視により滲み出た水の量で離水を評価した(「+(少ない)〜+++(多い)」)。
<Evaluation method>
-Viscosity: With a digital viscometer (B-type rotational viscometer), the measurement temperature was 20 ° C., the rotation speed was 60 rpm, and the viscosity after 1 minute was measured.
-Measurement of water separation before freezing and thawing: 10 g of a sample was placed in a circle (φ58 mm) of a filter paper (No. 2) having a diameter of 150 mm and spread uniformly. Then, it was allowed to stand at room temperature for 1 hour, and the state of water separation was visually observed. Water separation was evaluated as "+ (less) to +++ (more)".
-Measurement of water separation after freezing and thawing: The sample was placed on a filter paper in the same manner as above, and rapidly frozen (1 hour) at -40 ° C. Then, it was allowed to stand at room temperature for 1 hour, and the water separation was evaluated by the amount of water exuded visually (“+ (less) to +++ (more)”).

Figure 0006918453
Figure 0006918453

<評価>
表3の結果より、ピザソースに添加した場合、ウェランガムは食感のヌメリを抑えながらも、冷凍解凍の前後においても離水抑制効果が高いことがわかった。
<Evaluation>
From the results in Table 3, it was found that when added to the pizza sauce, welan gum has a high effect of suppressing water separation before and after freezing and thawing, while suppressing the sliminess of the texture.

実験例4 ヨーグルト
次の処方に基づき、ヨーグルトを調製した。使用した増粘剤の種類と添加量を表4に示す。得られたヨーグルトの粘度と離水の程度、食感の評価についても表4に示す。
Experimental Example 4 Yogurt Yogurt was prepared based on the following formulation. Table 4 shows the types and amounts of thickeners used. Table 4 also shows the evaluation of the viscosity, the degree of water separation, and the texture of the obtained yogurt.

<発酵乳ベース部処方>
全脂粉乳 23.0
スターター 3.0
イオン交換水にて全量100.0 %
<ヨーグルト処方>
発酵乳ベース部 50.0
砂糖 12.0
乳酸 適量
増粘剤 表4参照
イオン交換水にて全量 100.0 %
<Prescription of fermented milk base>
Full-fat milk powder 23.0
Starter 3.0
Total amount 100.0% with ion-exchanged water
<Yogurt prescription>
Fermented milk base 50.0
Sugar 12.0
Appropriate amount of lactic acid
Thickener See Table 4
Total amount 100.0% with ion-exchanged water

<調製方法>
1)イオン交換水に全脂粉乳を加え、70℃にて10分間撹拌した。
2)全量補正後、ホモジナイザーにて均質化した(一段目10MPa、二段目5MPa)。
3)90℃にて10分間殺菌した。
4)45℃まで冷却した。
5)スターターを添加した。
6)42℃の恒温器内で、pH4.5±0.1まで発酵させた。
7)TKロボミックスにて、3,000rpmで3分間カード破砕した。
8)10℃にて冷蔵保管した(発酵乳ベース部の調製完了)。
9)80℃のイオン交換水に砂糖、増粘剤を加え、80℃にて10分間撹拌溶解した。
10)全量補正後、10℃まで冷却した。
11)8で得た発酵乳ベース部を加え、乳酸溶液にてpH4.2に調整した。
12)耐熱容器に充填し、85℃にて30分間ボイル殺菌を行った。
13)室温まで冷却した。
<Preparation method>
1) Full-fat milk powder was added to ion-exchanged water, and the mixture was stirred at 70 ° C. for 10 minutes.
2) After total amount correction, homogenization was performed with a homogenizer (1st stage 10 MPa, 2nd stage 5 MPa).
3) Sterilized at 90 ° C. for 10 minutes.
4) Cooled to 45 ° C.
5) A starter was added.
6) Fermentation was carried out to pH 4.5 ± 0.1 in an incubator at 42 ° C.
7) The card was crushed at 3,000 rpm for 3 minutes with TK Robomix.
8) Refrigerated at 10 ° C (completion of preparation of fermented milk base).
9) Sugar and a thickener were added to ion-exchanged water at 80 ° C., and the mixture was stirred and dissolved at 80 ° C. for 10 minutes.
10) After total amount correction, the mixture was cooled to 10 ° C.
11) The fermented milk base portion obtained in 8 was added, and the pH was adjusted to 4.2 with a lactic acid solution.
12) It was filled in a heat-resistant container and sterilized by boiling at 85 ° C. for 30 minutes.
13) Cooled to room temperature.

Figure 0006918453
Figure 0006918453

<評価方法>
・離水:冷却後に離水を目視にて評価した。
「−(全くない)〜+(少ない)〜+++(多い)」
<Evaluation method>
-Water separation: Water separation was visually evaluated after cooling.
"-(None) ~ + (less) ~ +++ (more)"

<評価>
表4の結果より、ヨーグルトに添加した場合、離水の抑制効果が高く、滑らかで濃厚な食感になった。
<Evaluation>
From the results in Table 4, when added to yogurt, the effect of suppressing water separation was high, and a smooth and rich texture was obtained.

実験例5 ゼリー
次の処方に従い、ゼリーを調製した。ゼリーに添加した増粘剤とその添加量は、表5に示す。得られたゼリーの離水率、ゼリー強度を下記評価方法に従い測定した。ゼリーの食感とあわせて表5に示す。
Experimental Example 5 Jelly A jelly was prepared according to the following formulation. The thickener added to the jelly and the amount of the thickener added are shown in Table 5. The water separation rate and jelly strength of the obtained jelly were measured according to the following evaluation method. Table 5 shows the texture of the jelly.

<処方>
1 砂糖 15.0
2 ゲル化剤 1.2
(ゲルアップ※WM−1(F)*)
3 増粘剤 表5参照
4 50%クエン酸溶液 適量
5 5倍濃縮コンコード透明果汁 1.0
6 香料(グレープESS NO.80*) 0.1
イオン交換水にて、全量 100.0%
<Prescription>
1 sugar 15.0
2 Gelling agent 1.2
(Gel up * WM-1 (F) *)
3 Thickener See Table 5 4 50% citric acid solution Appropriate amount 5 5 times concentrated Concord clear juice 1.0
6 Fragrance (Grape ESS NO.80 *) 0.1
With ion-exchanged water, the total amount is 100.0%

<調製方法>
1) イオン交換水の一部に攪拌しながら1〜3を添加し、80℃10分間攪拌溶解した。
2) 4〜6を添加してpHを3.8に調整し、イオン交換水にて全量補正した。
3) プラスチックカップに充填後、85℃で30分間殺菌し、冷却した。
<Preparation method>
1) Additions 1 to 3 were added to a part of the ion-exchanged water with stirring, and the mixture was stirred and dissolved at 80 ° C. for 10 minutes.
2) The pH was adjusted to 3.8 by adding 4 to 6, and the total amount was corrected with ion-exchanged water.
3) After filling a plastic cup, it was sterilized at 85 ° C. for 30 minutes and cooled.

<評価方法>
・ゼリー強度:テクスチャーアナライザー(Stable Micro systems社製)にて断面積1cmの円柱プランジャーを1mm/secで押込み時の破断強度を測定。
・離水:室温で3日間保存したゼリーの離水率を測定。
離水率(%)=離水量(g)÷カップ充填し冷却したゼリーの重量(g)×100
<Evaluation method>
-Jelly strength: Measure the breaking strength when pushing a cylindrical plunger with a cross-sectional area of 1 cm 2 at 1 mm / sec with a texture analyzer (manufactured by Stable Micro systems).
・ Water separation: Measure the water separation rate of jelly stored at room temperature for 3 days.
Water separation rate (%) = Water separation amount (g) ÷ Weight of jelly filled and cooled in a cup (g) x 100

Figure 0006918453
Figure 0006918453

<結果>
表5に示した結果より、ウェランガムを添加したゼリーでは、ブランク品と変わりないゼリー強度を有するゼリーが得られ、離水やヌメリの発生も抑制されていた。一方、グァーガムとイオタカラギーナンを増粘剤として添加したゼリーでは、離水は抑えられたもののゼリー強度の低下によって食感が劣化し、ブランク品以上のヌメリを生じており、ゼリーとしての品質が向上しているとは言い難いものであった。
<Result>
From the results shown in Table 5, in the jelly to which welan gum was added, a jelly having the same jelly strength as the blank product was obtained, and water separation and the occurrence of slime were suppressed. On the other hand, in the jelly to which guar gum and iota carrageenan were added as thickeners, although water separation was suppressed, the texture deteriorated due to the decrease in jelly strength, and the jelly became more slimy than the blank product, and the quality as jelly improved. It was hard to say that it was.

実験例6 鶏つくね
次の処方に基づき、鶏つくねを調製した。得られた鶏つくねの加熱歩留りと食感の評価を行い、その結果を表6に示す。
Experimental Example 6 Chicken meatballs Chicken meatballs were prepared based on the following prescription. The heating yield and texture of the obtained chicken meatballs were evaluated, and the results are shown in Table 6.

<処方>
1 鶏胸肉ミンチ(皮付き 3mmミンチ) 75.0
2 鶏モモ肉ミンチ(皮付き 3mmミンチ) 11.5
3 豚脂 4.5
4 調味料(サンライク※和風だしL*) 1.0
5 生ジンジャーペースト 1.0
6 砂糖 0.5
7 食塩 0.5
8 調味料(サンライク※チキンエキス2822E*) 0.5
9 調味料(サンライク※アジビーフ1936P*) 0.5
10 保存料(サンキプロ※No.94*) 0.5
11 増粘剤 表6参照
イオン交換水にて全量 100.0%
<Prescription>
1 Minced chicken breast (3mm minced with skin) 75.0
2 Minced chicken thigh (3mm minced with skin) 11.5
3 Lard 4.5
4 Seasoning (Sun-like * Japanese-style soup stock L *) 1.0
5 Raw ginger paste 1.0
6 sugar 0.5
7 salt 0.5
8 Seasoning (Sun-like * Chicken extract 2822E *) 0.5
9 Seasoning (Sunlike * Ajibeef 1936P *) 0.5
10 Preservative (Sankipro * No.94 *) 0.5
11 Thickener See Table 6 Total amount 100.0% with ion-exchanged water

<調製方法>
1) 全ての材料をよく混合し、各25gの球状に成型した。
2) 95℃で6分間のボイル加熱を行った。
3) 室温になるまで静置した。
<Preparation method>
1) All materials were mixed well and molded into spheres of 25 g each.
2) Boil heating was performed at 95 ° C. for 6 minutes.
3) It was allowed to stand until it reached room temperature.

<評価方法>
・加熱歩留り(%)=ボイル後重量(g)÷ボイル前重量(g)× 100
<Evaluation method>
・ Heating yield (%) = post-boil weight (g) ÷ pre-boil weight (g) x 100

Figure 0006918453
Figure 0006918453

<結果>
上記結果より、ウェランガムを添加すると、キサンタンガムと同様に加熱時の離水を抑制し、歩留りが向上し、ほぐれ易い食感、又は軟らかい食感となることがわかった。その一方で、ウェランガムの添加量が増えるとヌメリが生じてくることがわかった。一方、ブランクの鶏つくねでは、ヌメリは生じていなかったが、硬くしまった食感となっていた。キサンタンガムを添加した比較例13の鶏つくねでは、ヌメリを生じ軟らかい食感となっていた。
<Result>
From the above results, it was found that the addition of welan gum suppresses water separation during heating, improves the yield, and gives a texture that is easy to loosen or a soft texture, similar to xanthan gum. On the other hand, it was found that slime was generated when the amount of welan gum added was increased. On the other hand, the blank chicken meatballs did not have slime, but had a hard texture. In the chicken meatball of Comparative Example 13 to which xanthan gum was added, slimy meat was produced and the texture was soft.

実験例7 調味液
次の処方に基づき、調味液を調製した。得られた調味液の粘度、離水率と食感を測定・評価し、表7に示す。
Experimental Example 7 Seasoning liquid A seasoning liquid was prepared based on the following formulation. The viscosity, water separation rate and texture of the obtained seasoning liquid were measured and evaluated, and are shown in Table 7.

<処方>
1 砂糖 30.6
2 発酵乳酸ナトリウム50%溶液 30.0
3 糖アルコール 18.0
(アマミール 三菱商事フードテック社)
4 料理酒 5.0
5 醤油 3.0
6 食塩 1.5
7 増粘剤 表7参照
イオン交換水にて全量 100.0%
<Prescription>
1 sugar 30.6
2 Fermented sodium lactate 50% solution 30.0
3 Sugar alcohol 18.0
(Amamir Mitsubishi Corporation Food Tech)
4 Cooking sake 5.0
5 Salty sauce 3.0
6 salt 1.5
7 Thickener See Table 7.
Total amount 100.0% with ion-exchanged water

<調製方法>
1) 処方中の2、3をイオン交換水に添加し、攪拌しながら1、7を加え、80℃にて10分間攪拌した。
2) 残りの材料を加え、さらに80℃にて5分間攪拌した。
3) 全量補正後、冷却した。
<Preparation method>
1) A few of the formulations were added to ion-exchanged water, 1 and 7 were added with stirring, and the mixture was stirred at 80 ° C. for 10 minutes.
2) The remaining material was added, and the mixture was further stirred at 80 ° C. for 5 minutes.
3) After total amount correction, it was cooled.

<評価方法>
・粘度:デジタル粘度計(B型回転粘度計)にて、測定温度20℃、回転数6rpm、1分後の粘度を測定した。
・離水率:2枚重ねたろ紙(No.2、15cm四方)のФ72mmの円内に、調味液を10gのせ均一に広げた。その後、室温で6時間静置し、実験例2と同じ方法で離水率を算出した。
<Evaluation method>
-Viscosity: With a digital viscometer (B-type rotational viscometer), the measurement temperature was 20 ° C., the rotation speed was 6 rpm, and the viscosity after 1 minute was measured.
-Water separation rate: 10 g of seasoning liquid was spread evenly in a circle of Ф72 mm of two layers of filter paper (No. 2, 15 cm square). Then, it was allowed to stand at room temperature for 6 hours, and the water separation rate was calculated by the same method as in Experimental Example 2.

Figure 0006918453
Figure 0006918453

<評価>
上記結果より、ウェランガムを使用した調味液では、多糖類を併用して添加した調味液よりも低添加量で、離水抑制効果が発揮されていた。また、ヌメリもほとんど生じていなかった。
<Evaluation>
From the above results, the seasoning liquid using welan gum exhibited the effect of suppressing water separation with a lower addition amount than the seasoning liquid added in combination with polysaccharides. In addition, there was almost no slime.

実験例8 餃子
次の表8にある処方に基づき、餃子の具材を調製し、餃子の皮で包み餃子を調製した。焼きあがった餃子から中身の具材を取り出し、加熱による歩留りと食感の評価を行った。結果を表9に示す。
Experimental Example 8 Dumplings Based on the formulation shown in Table 8 below, the ingredients for dumplings were prepared and wrapped in dumpling skin to prepare dumplings. The ingredients inside were taken out from the baked dumplings, and the yield and texture were evaluated by heating. The results are shown in Table 9.

Figure 0006918453

キャベツ*1:3分間ボイル後にみじん切りし、質量が30質量%減少するまで脱水処理を行った。
Figure 0006918453

Cabbage * 1 : After boiling for 3 minutes, it was chopped and dehydrated until the mass was reduced by 30% by mass.

<調製方法>
1)1〜18をよく混合した。
2)各10gの球状に成型し、餃子の皮に包んだ。
3)ホットプレートにて焦げ目がつくまで焼成し、湯を200g投入して蓋をし、3分間蒸し焼きにした。
<Preparation method>
1) 1 to 18 were mixed well.
2) It was molded into a spherical shape of 10 g each and wrapped in dumpling skin.
3) Bake on a hot plate until browned, add 200 g of hot water, cover and steam for 3 minutes.

<評価方法>
焼きあがった餃子から中身の具材だけを取り出し、加熱歩留りと食感の評価を行った。
・加熱歩留まり(%)=具材の加熱後重量(g)÷具材の加熱前重量(g)×100
<Evaluation method>
Only the ingredients inside were taken out from the baked dumplings, and the heating yield and texture were evaluated.
-Heating yield (%) = weight after heating of ingredients (g) ÷ weight before heating of ingredients (g) x 100

Figure 0006918453
Figure 0006918453

<結果>
ウェランガムを具材に添加した餃子では、ブランクやキサンタンガムを添加した比較例16よりも歩留りが向上しており、ヌメリもなくほぐれ易い食感となっていた。一方のブランク品は、ヌメリは生じていなかったがしまったような硬めの食感となっていた。また、キサンタンガムを添加した比較例16の餃子の具材は、ブランク品に比べわずかに歩留りが向上していたが、ヌメリがあり、べちゃっとした食感となっていた。
<Result>
The dumplings to which welan gum was added to the ingredients had a higher yield than Comparative Example 16 to which blanks and xanthan gum were added, and had a texture that was easy to loosen without sliminess. On the other hand, the blank product had a hard texture as if it had no slime. In addition, the gyoza ingredients of Comparative Example 16 to which xanthan gum was added had a slightly improved yield as compared with the blank product, but had a slimy texture and a sticky texture.

実験例9 野菜炒め
次の処方に基づき、野菜炒め用の調味液を調製した。得られた調味液を用いて野菜炒めを調製し、調理後に発生する離水の量を測定した。
<処方>
1 濃口醤油 8.7
2 みりん風調味料 5.0
3 砂糖 4.7
4 清酒 2.4
5 食塩 2.0
6 L−グルタミン酸ナトリウム 0.3
7 クエン酸 0.2
8 カラメル色素 0.1
9 調味料 0.05
(ペパーSP−61524*)
10 保存料 0.5
(サンキーパー※S−3*)
11 ウェランガム 0.3
(ビストップ※W*)
イオン交換水にて全量 100.0 部
Experimental Example 9 Stir-fried vegetables A seasoning liquid for stir-fried vegetables was prepared based on the following formulation. Stir-fried vegetables were prepared using the obtained seasoning liquid, and the amount of water separation generated after cooking was measured.
<Prescription>
1 Dark soy sauce 8.7
2 Mirin-style seasoning 5.0
3 sugar 4.7
4 Sake 2.4
5 salt 2.0
6 Sodium L-glutamate 0.3
7 Citric acid 0.2
8 Caramel color 0.1
9 Seasoning 0.05
(Pepper SP-61524 *)
10 Preservative 0.5
(Sunkeeper * S-3 *)
11 Welan Gum 0.3
(Bistop * W *)
Total amount of 100.0 parts with ion-exchanged water

<調製方法>
1)適量のイオン交換水に11を加え、85℃にて10分間攪拌溶解した。
2)残りの原料を加え、さらに5分間の攪拌溶解をした。
3)全量補正し、85℃達温にてホットパック充填した。
4)室温まで冷却し、野菜炒め用の調味液とした。
5)もやしと4で得た調味液を8:2の割合で混合し、中火で2分間炒めた。
6)容器に移し、粗熱を除去した。
<Preparation method>
1) 11 was added to an appropriate amount of ion-exchanged water, and the mixture was stirred and dissolved at 85 ° C. for 10 minutes.
2) The remaining raw materials were added, and the mixture was further stirred and dissolved for 5 minutes.
3) The whole amount was corrected and filled with a hot pack at a temperature of 85 ° C.
4) The mixture was cooled to room temperature and used as a seasoning liquid for stir-frying vegetables.
5) The bean sprouts and the seasoning liquid obtained in 4 were mixed at a ratio of 8: 2 and fried on medium heat for 2 minutes.
6) Transferred to a container to remove rough heat.

<評価>
調製した野菜炒めをバットに移し、冷蔵(10℃)にて12時間保管したものを、角度10°に傾けたバットに移し、30分静置後の離水率(野菜炒め全量に対する離水の割合)を算出した。
<結果>
ウェランガムを添加した野菜炒め用の調味液を用いた野菜炒めでは、離水率は1.0%であった。一方、ウェランガムを添加しないブランク品の離水率は、4.0%であった。この結果より、野菜炒め用の調味液にウェランガムを添加することで、野菜炒めからの離水を抑制する効果を発揮することが確認できた。
<Evaluation>
Transfer the prepared stir-fried vegetables to a vat, store in a refrigerator (10 ° C) for 12 hours, transfer to a vat tilted at an angle of 10 °, and let stand for 30 minutes. Was calculated.
<Result>
In the stir-fried vegetables using the seasoning liquid for stir-frying vegetables to which welan gum was added, the water separation rate was 1.0%. On the other hand, the water separation rate of the blank product to which welan gum was not added was 4.0%. From this result, it was confirmed that the addition of welan gum to the seasoning liquid for stir-fried vegetables exerts the effect of suppressing water separation from stir-fried vegetables.

実験例10 ソース
次の表10の処方に基づいて、ソースを調製した。
Experimental Example 10 Sauce A sauce was prepared based on the formulation shown in Table 10 below.

Figure 0006918453
Figure 0006918453

<調製方法>
1)イオン交換水の一部と1を混合し、これに10、11を加え、85℃にて10分間攪拌した。
2)残りの全原料を加え、さらに5分間撹拌した。
3)耐熱容器に充填し、85℃にて30分間殺菌した。
4)室温まで冷却し、ソースを得た。
<Preparation method>
1) A part of ion-exchanged water and 1 were mixed, 10 and 11 were added thereto, and the mixture was stirred at 85 ° C. for 10 minutes.
2) All the remaining ingredients were added and stirred for an additional 5 minutes.
3) It was filled in a heat-resistant container and sterilized at 85 ° C. for 30 minutes.
4) The sauce was obtained by cooling to room temperature.

<評価方法>
・離水:ろ紙の中心にφ58mmの円を描き、その円内に試料10gをのせ均一に伸ばした。室温にて3時間静置し、外観を目視で観察。離水面積をプラニメーター(小泉測機製作所 KP−13)にて測定。
・粘度:B形回転粘度計にて、60 rpm、20℃、1分後の粘度を測定。
<Evaluation method>
-Water separation: A circle of φ58 mm was drawn in the center of the filter paper, and 10 g of the sample was placed in the circle and spread evenly. Let stand at room temperature for 3 hours and visually observe the appearance. Measure the water separation area with a planimeter (Koizumi Sokki Seisakusho KP-13).
-Viscosity: Measure the viscosity after 1 minute at 60 rpm and 20 ° C with a B-type rotational viscometer.

<結果>
比較例の加工デンプンのみを添加したソースの離水面積は、7,700mmであり、粘度は1,100mPa・sであった。ソースの外観は照り艶に乏しく、食したところ、ソースの辛味酸味があまり感じられなかった。
一方、加工デンプンの一部をウェランガムに置き換えた実施例では、離水面積は3,160mmと比較例の半分以下に抑えられていながらも、粘度は1,020mPa・sと大きな差はなかった。また、外観も照り艶がよく、食したときの辛味や酸味が強く感じられた。
以上より、ウェランガムをソースに添加した場合、ソースからの離水を顕著に抑制することが確認できた。また、外観もよく、フレーバーリリースが向上することも確認できた。

<Result>
The water separation area of the sauce to which only the modified starch of the comparative example was added was 7,700 mm 2 , and the viscosity was 1,100 mPa · s. The appearance of the sauce was not shiny, and when I ate it, I could not feel the spicy and sour taste of the sauce.
Meanwhile, in the embodiment is replaced with a portion of modified starch to welan, syneresis area while been reduced to less than half of the comparative example 3,160Mm 2, the viscosity was not significant difference between 1,020mPa · s. In addition, the appearance was bright and glossy, and the spiciness and sourness when eaten were strongly felt.
From the above, it was confirmed that when welan gum was added to the sauce, water separation from the sauce was remarkably suppressed. It was also confirmed that the appearance was good and the flavor release was improved.

Claims (5)

ウェランガムを含有する離水の抑制された食品(ただし、カードラン、ウェランガム、スクレログルカン、及び塩化カリウムを含有するゼリーを除く)であって、
前記食品が、ピザソスである、食品。
Foods containing welan gum with suppressed water separation (excluding curdlan, welan gum, scleroglucan, and jelly containing potassium chloride).
Said food is a Pizaso over vinegar, food.
ウェランガムをピザソースに対して0.01〜1.5質量%含有する請求項1記載の食品。 The food product according to claim 1, which contains welan gum in an amount of 0.01 to 1.5% by mass based on the pizza sauce. ウェランガムを添加することを特徴とする食品(ただし、カードラン、ウェランガム、スクレログルカン、及び塩化カリウムを含有するゼリーを除く)の離水抑制方法であり、
前記食品が、ピザソースである離水抑制方法
A method for suppressing water separation of foods characterized by the addition of welan gum (excluding curdlan, welan gum, scleroglucan, and jelly containing potassium chloride).
A method for suppressing water separation in which the food is a pizza sauce .
ウェランガムをピザソースに対して0.01〜1.5質量%含有させる請求項3記載の食品の離水抑制方法。 The method for suppressing water separation of foods according to claim 3, wherein the welan gum is contained in an amount of 0.01 to 1.5% by mass based on the pizza sauce. ウェランガムを含有する食品用離水抑制剤であって、
前記食品が、ピザソースであり、
ヌメリの発生を抑制することを特徴とする、食品用離水抑制剤(ただし、カードラン、ウェランガム、スクレログルカン、及び塩化カリウムを含有するゼリー用離水抑制剤を除く)。
A water separation inhibitor for foods containing welan gum,
The food is a pizza sauce
A water separation inhibitor for foods, which is characterized by suppressing the generation of slime (excluding a water separation inhibitor for jelly containing curdlan, welan gum, scleroglucan, and potassium chloride).
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