JP5453665B2 - Aerosol product for nozzle cleaning of warm water cleaning toilet seats - Google Patents
Aerosol product for nozzle cleaning of warm water cleaning toilet seats Download PDFInfo
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- JP5453665B2 JP5453665B2 JP2007220093A JP2007220093A JP5453665B2 JP 5453665 B2 JP5453665 B2 JP 5453665B2 JP 2007220093 A JP2007220093 A JP 2007220093A JP 2007220093 A JP2007220093 A JP 2007220093A JP 5453665 B2 JP5453665 B2 JP 5453665B2
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- 238000004140 cleaning Methods 0.000 title claims description 63
- 239000000443 aerosol Substances 0.000 title claims description 43
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims description 25
- 239000006260 foam Substances 0.000 claims description 43
- -1 polyoxyethylene Polymers 0.000 claims description 42
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 20
- 239000012459 cleaning agent Substances 0.000 claims description 19
- 239000011550 stock solution Substances 0.000 claims description 17
- 239000003380 propellant Substances 0.000 claims description 14
- 230000005484 gravity Effects 0.000 claims description 13
- 238000002347 injection Methods 0.000 claims description 13
- 239000007924 injection Substances 0.000 claims description 13
- 239000002904 solvent Substances 0.000 claims description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 9
- 150000008051 alkyl sulfates Chemical class 0.000 claims description 8
- 239000004359 castor oil Substances 0.000 claims description 7
- 235000019438 castor oil Nutrition 0.000 claims description 7
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 7
- 239000003995 emulsifying agent Substances 0.000 claims description 6
- 238000004945 emulsification Methods 0.000 claims description 5
- 150000003973 alkyl amines Chemical class 0.000 claims description 4
- 230000001804 emulsifying effect Effects 0.000 claims description 3
- 229930182478 glucoside Natural products 0.000 claims description 3
- 125000005210 alkyl ammonium group Chemical group 0.000 claims description 2
- 235000011130 ammonium sulphate Nutrition 0.000 claims description 2
- 230000000052 comparative effect Effects 0.000 description 23
- 238000005406 washing Methods 0.000 description 12
- 239000004033 plastic Substances 0.000 description 11
- 229920003023 plastic Polymers 0.000 description 11
- 230000000694 effects Effects 0.000 description 8
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 4
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 4
- 239000003915 liquefied petroleum gas Substances 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 2
- GQPLMRYTRLFLPF-UHFFFAOYSA-N Nitrous Oxide Chemical compound [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- 210000000436 anus Anatomy 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 239000002781 deodorant agent Substances 0.000 description 2
- 239000001282 iso-butane Substances 0.000 description 2
- 150000002736 metal compounds Chemical class 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 239000001294 propane Substances 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- IJALWSVNUBBQRA-UHFFFAOYSA-N 4-Isopropyl-3-methylphenol Chemical compound CC(C)C1=CC=C(O)C=C1C IJALWSVNUBBQRA-UHFFFAOYSA-N 0.000 description 1
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 1
- 235000017166 Bambusa arundinacea Nutrition 0.000 description 1
- 235000017491 Bambusa tulda Nutrition 0.000 description 1
- 241000195940 Bryophyta Species 0.000 description 1
- 240000001548 Camellia japonica Species 0.000 description 1
- 241000207199 Citrus Species 0.000 description 1
- 241000951471 Citrus junos Species 0.000 description 1
- 235000005979 Citrus limon Nutrition 0.000 description 1
- 244000131522 Citrus pyriformis Species 0.000 description 1
- 241001672694 Citrus reticulata Species 0.000 description 1
- 240000000560 Citrus x paradisi Species 0.000 description 1
- 241000237502 Ostreidae Species 0.000 description 1
- 244000082204 Phyllostachys viridis Species 0.000 description 1
- 235000015334 Phyllostachys viridis Nutrition 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 241001122767 Theaceae Species 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 239000011425 bamboo Substances 0.000 description 1
- 229960000686 benzalkonium chloride Drugs 0.000 description 1
- UREZNYTWGJKWBI-UHFFFAOYSA-M benzethonium chloride Chemical compound [Cl-].C1=CC(C(C)(C)CC(C)(C)C)=CC=C1OCCOCC[N+](C)(C)CC1=CC=CC=C1 UREZNYTWGJKWBI-UHFFFAOYSA-M 0.000 description 1
- 229960001950 benzethonium chloride Drugs 0.000 description 1
- CADWTSSKOVRVJC-UHFFFAOYSA-N benzyl(dimethyl)azanium;chloride Chemical compound [Cl-].C[NH+](C)CC1=CC=CC=C1 CADWTSSKOVRVJC-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- KYKAJFCTULSVSH-UHFFFAOYSA-N chloro(fluoro)methane Chemical compound F[C]Cl KYKAJFCTULSVSH-UHFFFAOYSA-N 0.000 description 1
- 235000020971 citrus fruits Nutrition 0.000 description 1
- 239000011538 cleaning material Substances 0.000 description 1
- 235000018597 common camellia Nutrition 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 239000002563 ionic surfactant Substances 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- XUGNVMKQXJXZCD-UHFFFAOYSA-N isopropyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC(C)C XUGNVMKQXJXZCD-UHFFFAOYSA-N 0.000 description 1
- NFIDBGJMFKNGGQ-UHFFFAOYSA-N isopropylmethylphenol Natural products CC(C)CC1=CC=CC=C1O NFIDBGJMFKNGGQ-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 235000011929 mousse Nutrition 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000001272 nitrous oxide Substances 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 235000020636 oyster Nutrition 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 235000013616 tea Nutrition 0.000 description 1
Landscapes
- Bidet-Like Cleaning Device And Other Flush Toilet Accessories (AREA)
- Detergent Compositions (AREA)
Description
本発明は、温水洗浄便座のノズル洗浄用エアゾール製品に関する。 The present invention relates to a nozzle cleaning aerosol products of bidet.
便座に備えられたノズルから温水を噴出して肛門部分を洗浄する温水洗浄便座が知られている。このような温水洗浄便座は、当初、病院や福祉施設に導入され、次いでホテルやオフィス等に設置され、近年では一般家庭に広く普及している。
この温水洗浄便座にあるノズルは、使用時に肛門部分の下方に迫り出して温水を上方に噴出するので、水垢や汚物等で汚れやすい。そこでノズルを清潔に保つために温水洗浄便座にはノズルの自動洗浄装置が備えられており、使用前後にノズルを水洗いするようにしているが十分に洗浄することは難しく、長期間の使用により汚れが付いたり、さらに汚れが原因となってカビの発生を引き起こすなどの問題があった。
このような問題を解消するため、ノズルを清掃するためのブラシを備えたクリーナー（例えば、特許文献１参照。）、ノズルに向かって洗浄料等を噴射するエアゾール洗浄剤（例えば、特許文献２参照。）などが提案されている。
There is known a warm water flush toilet seat that ejects warm water from a nozzle provided in a toilet seat to wash the anus. Such warm water flush toilet seats were initially introduced in hospitals and welfare facilities, then installed in hotels, offices, and the like, and in recent years have become widespread in ordinary households.
The nozzle in this warm water flush toilet seat squeezes down below the anus when in use and spouts warm water upward, so it is easily soiled with scales and dirt. Therefore, in order to keep the nozzle clean, the toilet seat for washing with hot water is equipped with an automatic cleaning device for the nozzle, and the nozzle is washed before and after use, but it is difficult to wash sufficiently, and it becomes dirty due to long-term use. There were problems such as sticking out and causing mold generation due to dirt.
In order to solve such a problem, a cleaner (for example, refer to Patent Document 1) having a brush for cleaning the nozzle, an aerosol cleaning agent for injecting a cleaning material or the like toward the nozzle (for example, refer to Patent Document 2). Etc.) have been proposed.
ところが特許文献１に記載されたクリーナーは、ノズルの細部や格納部周辺の清掃ができず、作業にも手間がかかるという問題があった。また特許文献２に記載されたエアゾール洗浄剤は、特許文献１よりも使い勝手はよく、洗浄剤をムース状に噴射するものであるが、ノズルがプラスチック製の略円柱状を呈していることから、噴射された洗浄剤がノズルに付着しないですぐに流れ落ちてしまい十分な洗浄効果を得ることはできなかった。
そこで本発明は、温水洗浄便座のノズルに噴射した際に、ノズル全体に洗浄剤がしっかりと行き渡り、細部にわたり洗浄効果を十分に得ることができる、温水洗浄便座のノズル洗浄用エアゾール製品を提供するものである。
However, the cleaner described in Patent Document 1 has a problem in that it cannot clean the details of the nozzles and the vicinity of the storage unit, and takes time and effort. In addition, the aerosol cleaner described in Patent Document 2 is easier to use than Patent Document 1 and injects the cleaner in a mousse shape, but because the nozzle has a substantially cylindrical shape made of plastic, The sprayed cleaning agent did not adhere to the nozzle and immediately flowed down, and a sufficient cleaning effect could not be obtained.
The present invention, when injected into the nozzle of the bidet, the detergent is firmly spreads throughout the nozzle, it is possible to obtain a sufficient cleaning effect every detail, providing a nozzle cleaning aerosol products of bidet To do.
本発明者らは、上記課題を解決するために鋭意検討した結果、洗浄剤を特定の泡比重を有する泡として、温水洗浄便座のノズル（以下、「洗浄ノズル」とも言う）に付着させることで洗浄ノズルがプラスチック製の略円柱状を呈しているにもかかわらず、その全体に泡状の洗浄剤がしっかりと行き渡り、細部にわたり十分な洗浄効果が得られることを見出し本発明に至った。
すなわち、本発明は以下の（１）〜（３）によって達成されるものである。
As a result of intensive studies to solve the above problems, the present inventors have attached the cleaning agent as a foam having a specific foam specific gravity to a nozzle of a warm water cleaning toilet seat (hereinafter also referred to as “cleaning nozzle”). Despite the fact that the cleaning nozzle has a substantially cylindrical shape made of plastic, the present inventors have found that a foam-like cleaning agent spreads firmly over the entire surface and that a sufficient cleaning effect can be obtained in every detail.
That is, the present invention is achieved by the following (1) to (3).
（１）少なくともアルコールを含む溶剤、洗浄剤および乳化、可溶化剤を配合した原液と、噴射剤とを、噴射装置を備えたエアゾール容器に充填した温水洗浄便座のノズル洗浄用エアゾール製品であって、
前記原液中、前記乳化、可溶化剤は０．１〜５質量％含有され、エアゾール製品中、前記原液が容積比で６０〜９０％であり、
前記噴射剤は、ガス圧が０．２９ＭＰａ／２５℃以上であり、エアゾール製品中、前記噴射剤が容積比で１０〜４０％であり、
噴射により洗浄剤を含む泡が形成され、前記泡が０．０２ｇ／ｍＬ以下の泡比重を有し、かつ泡膨張率が１５０％〜２５０％であることを特徴とする温水洗浄便座のノズル洗浄用エアゾール製品。
（２）前記乳化、可溶化剤として、ポリオキシエチレン硬化ヒマシ油、ポリオキシエチレンアルキルアミン、ポリオキシエチレンラウリルエーテル硫酸トリエタノールアミン、アルキルヒドロキシスルホベタインからなる群から選ばれたものを用いることを特徴とする（１）記載の温水洗浄便座のノズル洗浄用エアゾール製品。
（３）前記洗浄剤として、アルキルグルコシド、アルキル硫酸塩、アルキル硫酸アミン、アルキル硫酸アンモニウム、ポリオキシエチレンアルキル硫酸塩、ポリオキシエチレンアルキル硫酸アミン、ポリオキシエチレンアルキルエーテル酢酸塩からなる群から選ばれたものを用いることを特徴とする（１）または（２）記載の温水洗浄便座のノズル洗浄用エアゾール製品。
(1) An aerosol product for cleaning a nozzle of a warm water cleaning toilet seat in which an aerosol container equipped with an injection device is filled with a stock solution containing at least an alcohol-containing solvent, a cleaning agent and an emulsifying and solubilizing agent, and a propellant. ,
In the stock solution, the emulsification and solubilizing agent is contained in an amount of 0.1 to 5% by mass, and in the aerosol product, the stock solution is 60 to 90% by volume,
The propellant has a gas pressure of 0.29 MPa / 25 ° C. or more, and in the aerosol product, the propellant is 10 to 40% by volume,
Nozzle cleaning of a warm water cleaning toilet seat characterized in that foam containing a cleaning agent is formed by jetting, the foam has a foam specific gravity of 0.02 g / mL or less, and a foam expansion coefficient of 150% to 250%. For aerosol products.
(2) As the emulsification and solubilizing agent, one selected from the group consisting of polyoxyethylene hydrogenated castor oil, polyoxyethylene alkylamine, polyoxyethylene lauryl ether sulfate triethanolamine, and alkylhydroxysulfobetaine is used. An aerosol product for cleaning the nozzle of a warm water cleaning toilet seat as described in (1).
(3) The cleaning agent was selected from the group consisting of alkyl glucoside, alkyl sulfate, alkyl sulfate amine, alkyl ammonium sulfate, polyoxyethylene alkyl sulfate, polyoxyethylene alkyl sulfate amine, and polyoxyethylene alkyl ether acetate. An aerosol product for cleaning a nozzle of a warm water cleaning toilet seat according to (1) or (2), wherein the product is used.
本発明は、洗浄剤を特定の泡比重を有する泡として、温水洗浄便座のノズルに付着させることで洗浄ノズルがプラスチック製の略円柱状を呈しているにもかかわらず、すぐに流れ落ちることなくその全体に泡状の洗浄剤をしっかりと行き渡らせ、十分な泡の膨張により細部にわたり洗浄効果を十分に得ることができる。 The present invention allows the cleaning agent to adhere to the nozzle of the warm water cleaning toilet seat as a foam having a specific foam specific gravity, so that the cleaning nozzle has a substantially cylindrical shape made of plastic, but does not immediately flow down. A foam-like cleaning agent can be firmly distributed throughout, and a sufficient cleaning effect can be obtained in every detail by sufficient foam expansion.
本発明の温水洗浄便座のノズル洗浄用エアゾール製品（以下、「ノズル洗浄用エアゾール製品」とも言う）は、溶剤、洗浄剤、乳化剤等を主成分として配合した原液と噴射剤とを噴射装置を備えたエアゾール缶に充填することで製造できる。
ここでエアゾール缶内における原液と噴射剤の割合は、容積比で原液６０〜９０％に対して噴射剤１０〜４０％として配合すればよい。
そして本発明の噴射により形成される泡を所定の泡比重、さらに泡膨張率とするには、原液と噴射剤とを適切な乳化、可溶化剤を用いて均一な系としたうえで、噴射剤の割合を多くし（好ましくは３０〜４０％）、圧の高い噴射剤（好ましくは０．２９ＭＰａ／２５℃以上）を用いて所定の泡比重、泡膨張率が得られるように調製すればよい。
本発明のノズル洗浄用エアゾール製品は、噴射により形成される洗浄剤を含む泡の泡比重が０．０２ｇ／ｍＬ以下、好ましくは０．０１〜０．０２ｇ／ｍＬとするのがよい。
泡比重が０．０２ｇ／ｍＬよりも大きくなると、泡の膨張率が十分に得られず、
洗浄ノズル表面での泡の広がりも十分に得られない。
さらに泡膨張率が１５０％以上、好ましくは１８０〜２５０％とするのがよい。
上記の泡膨張率を有することで、洗浄ノズル細部や格納部内部まで洗浄剤を含んだ泡が到達して洗浄効果を得ることができる。
A nozzle cleaning aerosol product (hereinafter also referred to as a “nozzle cleaning aerosol product”) of a warm water cleaning toilet seat according to the present invention includes an injection device including a stock solution containing a solvent, a cleaning agent, an emulsifier and the like as main components and a propellant. It can be manufactured by filling an aerosol can.
Here, the ratio of the stock solution and the propellant in the aerosol can may be blended as 10 to 40% of the propellant with respect to 60 to 90% of the stock solution in volume ratio.
And in order to make the foam formed by the injection of the present invention have a predetermined foam specific gravity and further a foam expansion rate, the stock solution and the propellant are made into a uniform system using an appropriate emulsification and solubilizing agent, and then injected. If the ratio of the agent is increased (preferably 30 to 40%) and a high pressure propellant (preferably 0.29 MPa / 25 ° C. or higher) is used to obtain a predetermined foam specific gravity and foam expansion coefficient, Good.
The aerosol product for nozzle cleaning of the present invention has a foam specific gravity of 0.02 g / mL or less, preferably 0.01 to 0.02 g / mL, including a cleaning agent formed by jetting.
When the specific gravity of the foam is larger than 0.02 g / mL, the expansion rate of the foam is not sufficiently obtained,
It is not possible to obtain a sufficient bubble spread on the surface of the cleaning nozzle.
Furthermore, the foam expansion coefficient is 150% or more, preferably 180 to 250%.
By having the above-mentioned bubble expansion rate, the foam containing the cleaning agent reaches the details of the cleaning nozzle and the inside of the storage portion, and a cleaning effect can be obtained.
本発明のノズル洗浄用エアゾール製品に用いる原液の主成分である洗浄剤としては、例えば、アルキルグルコシド、アルキル硫酸塩、アルキル硫酸アミン、アルキル硫酸アンモニム、ポリオキシエチレンアルキル硫酸塩、ポリオキシエチレンアルキル硫酸アミン、ポリオキシエチレンアルキルエーテル酢酸塩等が挙げられる。
これらは原液中に０．１〜５質量％、好ましくは０．３〜２質量％として配合できる。
原液の他の主成分である溶剤として、例えば、精製水、脱イオン水等の水、エタノール、プロピルアルコール、イソプロピルアルコール等のアルコール、ミリスチン酸イソプロピル、パルミチン酸イソプロピル等の脂肪酸エステル等が挙げられる。
中でも、水とエタノールとの混合溶剤が適しており、容積比で水６５〜９５％に対してエタノール５〜３５％として配合するのがよい。
Examples of the cleaning agent that is the main component of the stock solution used in the nozzle cleaning aerosol product of the present invention include alkyl glucoside, alkyl sulfate, alkyl sulfate amine, alkyl sulfate ammonium, polyoxyethylene alkyl sulfate, and polyoxyethylene alkyl sulfate. Examples thereof include amines and polyoxyethylene alkyl ether acetates.
These can be blended in the stock solution as 0.1 to 5% by mass, preferably 0.3 to 2% by mass.
Examples of the solvent that is the other main component of the stock solution include water such as purified water and deionized water, alcohols such as ethanol, propyl alcohol, and isopropyl alcohol, and fatty acid esters such as isopropyl myristate and isopropyl palmitate.
Especially, the mixed solvent of water and ethanol is suitable, and it is good to mix | blend as ethanol 5-35% with respect to 65-95% of water by volume ratio.
原液のその他の主成分である乳化、可溶化剤としては、例えば、ポリオキシエチレン硬化ヒマシ油、ポリオキシエチレンアルキルアミン等の非イオン界面活性剤、ポリオキシエチレンラウリルエーテル硫酸トリエタノールアミン等の陰イオン界面活性剤、アルキルヒドロキシスルホベタイン等の両性界面活性剤等が挙げられる。
これらは原液中に０．１〜５質量％、好ましくは０．１〜１質量％として配合できる。
これらの中でも、本発明の泡比重、膨張率を達成するうえで、ポリオキシエチレン硬化ヒマシ油が好ましい。具体的には、ポリオキシエチレン（５）〜（１００）硬化ヒマシ油が挙げられる。
Other emulsifying and solubilizing agents that are the main components of the stock solution include, for example, nonionic surfactants such as polyoxyethylene hydrogenated castor oil and polyoxyethylene alkylamine, and negative ions such as polyoxyethylene lauryl ether sulfate triethanolamine. Examples include ionic surfactants and amphoteric surfactants such as alkylhydroxysulfobetaines.
These can be blended in the stock solution as 0.1 to 5% by mass, preferably 0.1 to 1% by mass.
Among these, polyoxyethylene hydrogenated castor oil is preferable in achieving the foam specific gravity and expansion rate of the present invention. Specific examples include polyoxyethylene (5) to (100) hydrogenated castor oil.
噴射剤としては、例えば、プロパン、ｎ−ブタン、イソブタン等の液化石油ガス、ジメチルエーテル、ＣＦＣ、ＨＣＦＣ、ＨＦＣ等のクロロフロロカーボン等の液化ガス、窒素、炭酸ガス、圧縮空気、亜酸化窒素等の圧縮ガスの１種又は２種以上を用いることができる。
これらの中でも、本発明の泡比重、膨張率を達成するうえで、プロパン、ｎ−ブタン、イソブタン等の液化石油ガスが好ましい。また液化石油ガスの圧としては、０．２９ＭＰａ／２５℃以上が好ましく、０．３９〜０．４９ＭＰａ／２５℃がより好ましい。
本発明のノズル洗浄用エアゾール製品の原液には、洗浄剤等の主成分の他にも、チャ、カキ、ツバキ、タケ、グレープフルーツ、ユズ、ミカン、レモン等の各種植物抽出物、銀や銅等の金属化合物、そのイオン等の消臭、防臭剤、イソプロピルメチルフェノール、塩化ベンザルコニム、塩化ベンゼトニウム、銀や銅等の金属化合物、そのイオン等の抗菌、殺菌剤、フッ素系界面活性剤、ポリエーテル変性シリコーン等の被膜形成剤、クエン酸等の防錆剤、ＢＨＡ、ＢＨＴ等の酸化防止剤、フローラル、ブーケ、シトラス等の香料等を配合してもよい。
Examples of the propellant include liquefied petroleum gas such as propane, n-butane, and isobutane, liquefied gas such as dimethyl ether, chlorofluorocarbon such as CFC, HCFC, and HFC, compression of nitrogen, carbon dioxide, compressed air, nitrous oxide, and the like. One kind or two or more kinds of gases can be used.
Among these, liquefied petroleum gas such as propane, n-butane, and isobutane is preferable for achieving the foam specific gravity and expansion rate of the present invention. Moreover, as a pressure of liquefied petroleum gas, 0.29 MPa / 25 degreeC or more is preferable, and 0.39-0.49 MPa / 25 degreeC is more preferable.
In addition to the main components such as cleaning agents, the stock solution of the nozzle cleaning aerosol product of the present invention includes various plant extracts such as tea, oysters, camellia, bamboo, grapefruit, yuzu, mandarin orange and lemon, silver and copper, etc. Metal compounds, deodorants such as ions, deodorants, isopropylmethylphenol, benzalkonium chloride, benzethonium chloride, metal compounds such as silver and copper, antibacterial agents such as ions, bactericides, fluorosurfactants, polyether modified A film forming agent such as silicone, a rust inhibitor such as citric acid, an antioxidant such as BHA and BHT, and a fragrance such as floral, bouquet and citrus may be blended.
本発明のノズル洗浄用エアゾール製品の外観形状としては、特に限定されないが、例えば、図１（A）に示すようなものが挙げられる。
図１（A）において、ノズル洗浄用エアゾール製品１は、エアゾール容器２と、レバー（操作手段）３を有するキャップ４を有し、キャップの噴射口に脱着可能なロングノズル５を、必要に応じて使用することができる。
本発明のノズル洗浄用エアゾール製品１は、図１（A）に示したようにロングノズル５を着脱可能に備えており、このようなロングノズルを用いて噴射することで、便座の洗浄ノズル細部や格納部内部まで洗浄剤を含む液を到着させて、より優れた洗浄効果を得ることができる。このようなロングノズル５としては、例えば、直径０．５〜３ｍｍは、長さ５０〜１５０ｍｍ、材質としては、プラスチックが適しており、ポリプロピレン、ポリエチレンが好適である。
また本発明のノズル洗浄用エアゾール製品の噴射装置としては、噴口径０．３〜１．５ｍｍのボタン（レバー）、ステム径０．３〜１．２ｍｍ（孔数１〜３）、アンダータップ０．３〜２．２ｍｍのバルブを備えたものがよく、ベーパータップはあってもなくてもよい。
このような噴射装置を用いて、約１５ｇ／１０秒以上、好ましくは２０ｇ〜４０ｇ／１０秒の噴射量が得られるようにするのがよい。
Although it does not specifically limit as an external appearance shape of the aerosol product for nozzle cleaning of this invention, For example, what is shown to FIG. 1 (A) is mentioned.
In FIG. 1 (A), the nozzle cleaning aerosol product 1 has an aerosol container 2 and a cap 4 having a lever (operating means) 3, and a long nozzle 5 that can be attached to and detached from the injection port of the cap. Can be used.
As shown in FIG. 1 (A), the nozzle cleaning aerosol product 1 of the present invention is equipped with a long nozzle 5 in a detachable manner, and by using such a long nozzle, the details of the cleaning nozzle for the toilet seat are provided. Further, a liquid containing a cleaning agent can reach the inside of the storage unit, and a more excellent cleaning effect can be obtained. As such a long nozzle 5, for example, a diameter of 0.5 to 3 mm is 50 to 150 mm in length, and plastic is suitable as a material, and polypropylene and polyethylene are suitable.
The nozzle cleaning aerosol spray device of the present invention includes a nozzle (lever) having a nozzle diameter of 0.3 to 1.5 mm, a stem diameter of 0.3 to 1.2 mm (number of holes 1 to 3), and an under tap 0. It is preferable to have a valve with a diameter of 3 to 2.2 mm, with or without a vapor tap.
Using such an injection device, it is preferable to obtain an injection amount of about 15 g / 10 seconds or more, preferably 20 g to 40 g / 10 seconds.
温水洗浄便座の洗浄ノズルを洗浄するに際しては、本発明のノズル洗浄用エアゾール製品を前記洗浄ノズルに向かって、例えば、１〜５ｃｍの距離から、１〜２秒間程度噴射して、１分以上、好ましくは４〜６分程度放置すればよい。これにより本発明の特定の泡による作用により、洗浄ノズル表面の全体を覆って、付着した汚れを浮かせて、汚れを除去することができる。
また、本発明のノズル洗浄用エアゾール製品には、図１（A）に示すようなエアゾール１本体に、さらに図１（B）に示すようなブラシ６が付属していても良い。
洗浄ノズルの汚れが頑固な場合には、図１（B）に示したようなブラシ６やトイレットペーパー等で擦ったり、ふき取ればより簡単に汚れを除去することができる。
なおブラシの刷毛は、複数列を配し、相互にずらして設けるとよく、洗浄ノズルの噴水口等の細部の汚れを効率的に除去するのに好適である。
上記のようにブラシを付属させる他にも、刷毛をロングノズル先端に設けたり、ブラシの柄部分を中空環状としてロングノズルのようにして噴射装置に取り付けたりして、ブラシ先端部の開口より洗浄剤を含む泡を噴射、形成させるようにしてもよい。またロングノズルを切替バルブを介して噴射装置と連結させることにより、通常噴射との選択ができるようにもできる。
When washing the washing nozzle of the warm water washing toilet seat, the nozzle washing aerosol product of the present invention is sprayed from the distance of 1 to 5 cm for about 1 to 2 seconds, for example, 1 minute or more, Preferably, it may be left for about 4 to 6 minutes. As a result, due to the action of the specific foam of the present invention, it is possible to cover the entire surface of the cleaning nozzle, float the adhered dirt, and remove the dirt.
Further, in the nozzle cleaning aerosol product of the present invention, a brush 6 as shown in FIG. 1 (B) may be further attached to the aerosol 1 main body as shown in FIG. 1 (A).
If the cleaning nozzle is stubbornly soiled, it can be more easily removed by rubbing or wiping with a brush 6 or toilet paper as shown in FIG.
The brush brushes are preferably arranged in a plurality of rows and shifted from each other, which is suitable for efficiently removing dirt on details such as the fountain opening of the cleaning nozzle.
In addition to attaching the brush as described above, the brush is provided at the tip of the long nozzle, or the brush handle is attached to the spraying device like a long nozzle with a hollow ring, and washed from the opening of the brush tip. Bubbles containing an agent may be jetted and formed. Further, it is possible to select normal injection by connecting the long nozzle to the injection device via the switching valve.
以下、実施例により本発明を詳細に説明するが、本発明はこれらに限定されるものではない。
〔実施例１〕
本発明のノズル洗浄用エアゾール製品として、下記表１に示す組成の原液と噴射剤とを図１に示す外観形状の容器に２００ｍＬ充填した本発明のノズル洗浄用エアゾール製品を調製し試験に用いた。
なお、噴射装置は、噴口径０．８ｍｍ、ステム径０．６ｍｍ、アンダータップ径２．２ｍｍ（孔数１）、ベーパータップなしである。またロングノズルは、直径１．５ｍｍ、長さ１３４ｍｍのポリプロピレン製である。
噴射剤である液化石油ガスは、０．３９ＭＰａ／２５℃の圧のものを用いた。また噴射量は約２．７ｇ／秒とした。
EXAMPLES Hereinafter, although an Example demonstrates this invention in detail, this invention is not limited to these.
[Example 1]
As the nozzle cleaning aerosol product of the present invention, the nozzle cleaning aerosol product of the present invention in which 200 mL of a stock solution and a propellant having the composition shown in Table 1 below were filled in a container having an external shape shown in FIG. 1 was prepared and used for the test. .
The injection device has an injection hole diameter of 0.8 mm, a stem diameter of 0.6 mm, an under tap diameter of 2.2 mm (number of holes 1), and no vapor tap. The long nozzle is made of polypropylene having a diameter of 1.5 mm and a length of 134 mm.
The liquefied petroleum gas which is a propellant used was a pressure of 0.39 MPa / 25 ° C. The injection amount was about 2.7 g / sec.
〔実施例２〕
乳化剤として、ポリオキシエチレン（30）硬化ヒマシ油を、ポリオキシエチレンラウリルエーテル硫酸トリエタノールアミンに代えた以外は実施例１と同様のエアゾール製品を用いた。
〔実施例３〕
乳化剤として、ポリオキシエチレン（30）硬化ヒマシ油を、ポリオキシエチレンアルキルアミンに代えた以外は実施例１と同様のエアゾール製品を用いた。
[Example 2]
As an emulsifier, the same aerosol product as in Example 1 was used except that polyoxyethylene (30) hydrogenated castor oil was replaced with polyoxyethylene lauryl ether sulfate triethanolamine.
Example 3
As an emulsifier, the same aerosol product as in Example 1 was used except that polyoxyethylene (30) hydrogenated castor oil was replaced with polyoxyethylene alkylamine.
〔比較例１〕
アイメディア（株）製の「温水洗浄便座のノズルクリーナー」を用いた。
〔比較例２〕
木村石鹸工業（株）製の「トイレのノズル洗浄剤」を用いた。
〔比較例３〕
（株）東京企画販売の「ノズルフレッシャー」を用いた。
[Comparative Example 1]
“Nozzle Cleaner for Warm Water Washing Toilet” manufactured by Eyemedia Co., Ltd. was used.
[Comparative Example 2]
“Toilet nozzle cleaning agent” manufactured by Kimura Soap Industry Co., Ltd. was used.
[Comparative Example 3]
“Nozzle Fresher” from Tokyo Planning and Sales Co., Ltd. was used.
〔試験１〕
図２に示すように、洗浄ノズルに見立てたφ２ｃｍ、長さ１３ｃｍの円柱状プラスチック（表面に同心円状の１ｃｍ間隔の目盛をふったもの）に検体を１ｇ噴射し、円柱状プラスチック表面上での泡の広がりを測定した。結果を下記表２に示す。
[Test 1]
As shown in FIG. 2, 1 g of the sample was injected onto a cylindrical plastic (diameter with a concentric 1 cm interval on the surface) of φ2 cm and a length of 13 cm as if it was a cleaning nozzle, Foam spread was measured. The results are shown in Table 2 below.
同じ量の内容物を噴射した際、実施例１は、比較例１〜３よりも、広範囲に円柱状プラスチックの横側から下側まで泡が行きわたることが確認された。
実施例１は泡が円柱状プラスチック表面の全体に沿って広がるのに対し、比較例１〜３は泡が上側表面の上に盛り上がっていくものであった。また、円柱状プラスチックに噴射した際に、実施例１は、比較例１〜３と比較して、内容物が表面にまとわりつきながら発泡するため、横側から下側まで泡が行きわたると考えられる。
When injecting the same amount of contents, it was confirmed that in Example 1, bubbles spread over a wider range from the lateral side to the lower side of the columnar plastic than in Comparative Examples 1 to 3.
In Example 1, the bubbles spread along the entire cylindrical plastic surface, while in Comparative Examples 1 to 3, the bubbles swelled on the upper surface. Moreover, when injecting to a columnar plastic, since Example 1 foams while the contents cling to the surface compared with Comparative Examples 1 to 3, it is considered that bubbles spread from the lateral side to the lower side. .
〔試験２〕
図３に示すように、φ１．５ｃｍ、高さ２０ｃｍのプラスチックの筒（一方をプラスチック板でふさいだもの）の中に開いている側から検体を１ｇ噴射し、噴射直後から体積膨張が停止するまでの体積変化、及び時間を測定した。結果を下記表３に示す。
[Test 2]
As shown in FIG. 3, 1 g of the sample is injected from the open side into a plastic cylinder (one side covered with a plastic plate) having a diameter of 1.5 cm and a height of 20 cm, and the volume expansion stops immediately after the injection. The volume change until and the time were measured. The results are shown in Table 3 below.
比較例１〜３は内容物が泡状で噴射されるから体積膨張はほとんどないのに対して、実施例１〜３は噴射後から体積膨張がはっきりと確認される。
実施例１〜３は１５０％以上の膨張率があること、且つ膨張するまでの時間が１秒以上であり、内容物がゆっくりと発泡することですみずみまで泡が行き渡ると考える。
In Comparative Examples 1 to 3, since the contents are jetted in the form of foam, there is almost no volume expansion, whereas in Examples 1 to 3, volume expansion is clearly confirmed after jetting.
Examples 1 to 3 have an expansion rate of 150% or more, and the time until expansion is 1 second or more, and it is considered that bubbles are spread throughout the contents as the contents are slowly foamed.
〔試験３〕
泡比重計量カップ（１１８．８３ｍＬ）とフタの重量を測りとり、次にカップに検体を噴射して前記カップ内に泡を満たし、泡の見かけ量が最大の時点で、素早くフタで前記カップ上面を横切るように塞ぎ、余分な泡を取り除いた。そして総重量を計り、前記カップとフタの重量をひくことで泡の重量を算出した。測定は２５℃条件下で行い、さらに図１（Ａ）のロングノズルを付けた場合と付けない場合の双方について評価した。結果を以下の表４に示す。
[Test 3]
Weigh the specific gravity foam cup (118.83 mL) and lid, then inject the sample into the cup to fill the cup with foam, and when the apparent amount of foam is maximum, quickly cover the top of the cup with the lid And the excess foam was removed. Then, the total weight was measured, and the weight of the foam was calculated by subtracting the weight of the cup and lid. The measurement was performed under the condition of 25 ° C., and further, both the case where the long nozzle of FIG. The results are shown in Table 4 below.
実施例１〜３はすべて泡比重０．０２ｇ／ｍＬ以下であった。またロングノズルの有無で泡比重に大きな違いはなかった。 Examples 1 to 3 all had a foam specific gravity of 0.02 g / mL or less. Moreover, there was no big difference in foam specific gravity with and without the long nozzle.
〔試験４〕
実施例１及び比較例１〜３の検体を、実際に便座の洗浄ノズルに適用し泡の付着状態を観察した。
詳細には、実施例１及び比較例１〜３の検体を、便座の洗浄ノズルに、１秒間噴射して、噴射５秒後の泡状態を観察した。
実施例１、比較例１、比較例２及び比較例３の観察結果の写真を、それぞれ、図４〜７に示す。
実施例１は洗浄ノズル全体に泡がまとわりついているのに対して、比較例１〜３は流れ落ちて洗浄ノズルには半分以下しか残っていなかった。
[Test 4]
The specimens of Example 1 and Comparative Examples 1 to 3 were actually applied to a toilet seat washing nozzle and the state of foam adhesion was observed.
Specifically, the specimens of Example 1 and Comparative Examples 1 to 3 were jetted for 1 second to the toilet seat washing nozzle, and the foam state after 5 seconds of jetting was observed.
Photographs of observation results of Example 1, Comparative Example 1, Comparative Example 2, and Comparative Example 3 are shown in FIGS.
In Example 1, bubbles were clinging to the entire cleaning nozzle, while Comparative Examples 1 to 3 flowed down and remained less than half in the cleaning nozzle.
〔試験５〕
便座の洗浄ノズルに対する実使用場面での洗浄効果（汚れ除去効果）について試験を行った。
詳細には、イナックス社製の便座の洗浄ノズル（長径１２．５ｍｍ、短径１０．５ｍｍ、長さ１３０ｍｍのプラスチック製の楕円柱形状）を約３０度上方に向けて固定し（実際の製品を再現）、蛍光ペンで洗浄ノズル全体を着色し模擬汚れとし、約５ｃｍの距離から実施例１及び比較例２の検体をロングノズル付きで、それぞれ０．５ｇを噴射した。
各検体の噴射前の模擬汚れの付いた洗浄ノズルの上下、エアゾール噴射後に泡が形成された所謂泡洗浄中の洗浄ノズル（泡の形成状態）の上および斜め上方、エアゾール噴射約１分後の洗浄ノズルの上下を観察し、カラー写真撮影した。なお、該写真を本願の図面として添付を試みたが、モノクロ写真とした場合に、模擬汚れである蛍光ペンの色の有無を正しく示すことができなくなったため、該観察状況を図８（実施例１）及び図９（比較例２）に図示した。図面で黒く影を付した所が模擬汚れである。
実施例１は、泡が、洗浄ノズルの下側にも形成され、それが流れ落ちずに付着されていた。１分後には泡も殆ど消えて、模擬汚れは殆どなくなっていた。これに対し、比較例２は形成された泡が、洗浄ノズルの上側にはあったが、横側から下側について泡はすぐに流れ落ちてしまっていた。１分後には、模擬汚れは、洗浄ノズルの上側では５０〜６０％程度なくなっていたが、横側から下側はそのまま残っていた。
比較例１及び比較例３についても同様の試験を行ったところ、比較例２と同様の結果となった。
[Test 5]
The cleaning effect (stain removal effect) in the actual use scene for the toilet nozzle was tested.
In detail, the cleaning nozzle of the toilet seat made by Inax (a plastic elliptical column shape having a major axis of 12.5 mm, a minor axis of 10.5 mm, and a length of 130 mm) is fixed upward by about 30 degrees (the actual product is Reproduction), the entire cleaning nozzle was colored with a fluorescent pen to make a simulated stain, and 0.5 g of each of the specimens of Example 1 and Comparative Example 2 was sprayed from a distance of about 5 cm with a long nozzle.
Above and below the washing nozzle with simulated dirt before jetting of each specimen, above and diagonally above the so-called washing nozzle (foam formation state) during foam washing after foaming, about 1 minute after aerosol jetting The top and bottom of the cleaning nozzle were observed and color photographs were taken. Attempts were made to attach the photograph as a drawing of the present application. However, when the photograph is a monochrome photograph, it is no longer possible to correctly indicate the presence or absence of the color of the highlighter which is simulated dirt. 1) and FIG. 9 (Comparative Example 2). The black shaded area in the drawing is simulated dirt.
In Example 1, a foam was also formed on the lower side of the washing nozzle, and it adhered without flowing down. After 1 minute, the bubbles almost disappeared, and the simulated dirt was almost gone. In contrast, in Comparative Example 2, the formed foam was on the upper side of the cleaning nozzle, but the foam immediately flowed down from the lateral side to the lower side. After 1 minute, the simulated dirt had disappeared by about 50 to 60% on the upper side of the cleaning nozzle, but remained from the side to the lower side.
When the same test was performed for Comparative Example 1 and Comparative Example 3, the same result as Comparative Example 2 was obtained.
１ ノズル洗浄用エアゾール製品
２ エアゾール容器
３ レバー（操作手段）
４ キャップ
５ ロングノズル
６ ブラシ
1 Nozzle cleaning aerosol product 2 Aerosol container 3 Lever (operating means)
4 Cap 5 Long nozzle 6 Brush
Claims (3)
前記原液中、前記乳化、可溶化剤は０．１〜５質量％含有され、エアゾール製品中、前記原液が容積比で６０〜９０％であり、
前記噴射剤は、ガス圧が０．２９ＭＰａ／２５℃以上であり、エアゾール製品中、前記噴射剤が容積比で１０〜４０％であり、
噴射により洗浄剤を含む泡が形成され、前記泡が０．０２ｇ／ｍＬ以下の泡比重を有し、かつ泡膨張率が１５０％〜２５０％であることを特徴とする温水洗浄便座のノズル洗浄用エアゾール製品。 An aerosol product for cleaning a nozzle of a warm water cleaning toilet seat in which an aerosol container equipped with an injection device is filled with a stock solution containing at least an alcohol-containing solvent, a cleaning agent and an emulsifying and solubilizing agent, and a propellant,
In the stock solution, the emulsification and solubilizing agent is contained in an amount of 0.1 to 5% by mass, and in the aerosol product, the stock solution is 60 to 90% by volume,
The propellant has a gas pressure of 0.29 MPa / 25 ° C. or more, and in the aerosol product, the propellant is 10 to 40% by volume,
Nozzle cleaning of a warm water cleaning toilet seat characterized in that foam containing a cleaning agent is formed by jetting, the foam has a foam specific gravity of 0.02 g / mL or less, and a foam expansion coefficient of 150% to 250%. For aerosol products.
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| JP4996000B2 (en) * | 1998-04-07 | 2012-08-08 | 株式会社ダイゾー | Aerosol products |
| JP2001019942A (en) * | 1999-07-09 | 2001-01-23 | Fumakilla Ltd | Foam aerosol |
| JP2001072999A (en) * | 1999-09-07 | 2001-03-21 | Shoowa Kk | Detergent composition and external detergent for item to be washed |
| JP2001226695A (en) * | 2000-02-14 | 2001-08-21 | Shoowa Kk | Liquid composition and spraying agent |
| JP3828921B2 (en) * | 2005-09-28 | 2006-10-04 | 木村石鹸工業株式会社 | Cleaning composition and cleaning agent for cleaning nozzle cleaner of warm water cleaning toilet seat |
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