JP4832750B2 - Coated paper manufacturing method and manufacturing equipment - Google Patents

Description

The present invention relates to a manufacturing method and manufacturing equipment for coated paper.
In particular, the present invention uses a paper machine having a gap type twin wire former, and performs on-machine coating and surface finishing of the paint at a high speed of 1300 m / min or higher, more preferably 1400 m / min or higher. Thus, the present invention relates to a coated paper manufacturing method and manufacturing equipment that can efficiently produce high-quality coated paper.

  In recent years, paper machines have been increasing in width and speed in order to save labor and reduce manufacturing costs. In particular, in the wire part, the adoption of an on-top former and a shift to a twin wire former are remarkable in order to improve the deterioration of the front / back difference and the deterioration of formation due to the increase in speed from the long net former.

  In particular, there is a tendency to use a gap type gap former in which a paper jet ejected from a head box is immediately sandwiched between two wires. This gap former has the advantage that there is very little difference between the front and back because the stock is ejected upward and dehydrated from both sides.

  Although it is a gap former having such a basic advantage, in the case of producing coated paper at a high speed, various problems become apparent, and the improvement with the wire part or the gap former alone cannot be solved.

  In other words, in the gap former, the paper jet that has exited the head box is immediately subjected to strong dehydration on both wire surfaces. The higher the speed, the more the fine fibers on the surface of the wet paper that come into contact with the wire come off. There are also disadvantages such as a decrease in the retention of the raw material and a difference in the properties of the front and back surfaces depending on the difference in the dehydration ratio from both wire surfaces. Therefore, when making high-speed paper using a base paper manufactured with a paper machine having this gap former for the wire part, it is unsuitable for high-definition printing applications. However, the production of the product has caused problems such as the smoothness of the surface of the product, the deterioration of gloss after printing, and the difference between the front and back.

  Also, in wire part dewatering, measures have been tried to give microweaving to the wet paper layer with the pulse force of the dewatering blade, promote fiber dispersion, improve the formation (sheet formation), and improve printability. However, the fine pulsing force inside the wet paper causes the fine fibers inside the wet paper to slip out, resulting in a decrease in yield, and the entanglement between the fibers inside the wet paper is reduced. (Internal bond) is reduced, causing delamination during printing and a blister problem in the drying process after printing.

  In response to the recent trend of visualization and multimedia, printed materials that have been widely used as media for publishing, advertising, publicity, etc., have rapidly increased the need for higher quality such as visualization and colorization. is doing. With such changes in user requirements, the switch from conventional non-coated printing paper to printing coated paper is increasing, and the demand for printing coated paper is rapidly increasing.

  In addition, from the printing process, quality requirements for printing paper handling and stability on the printing press, which lead to improved workability and efficiency, are becoming increasingly severe.

  Thus, there is a strong demand to find a method for producing a coated paper for printing having more excellent printing characteristics while taking advantage of the high-speed operation characteristics of the gap former.

  In response to these quality requirements, thermal soft calenders that can obtain high smoothness and gloss have recently attracted attention. This thermal soft calender is a method in which a metal roll is usually heated to 100 ° C. or higher to pressurize and smooth the coated paper. This method has an advantage that a high surface smoothness and printing gloss can be obtained with a small number of nips as compared with the conventional supercalender, and the product stiffness can be maintained at a relatively high value. This is because during the passage through the nip consisting of a metal roll and an elastic roll, a latex or other thermoplastic material used as an adhesive in the coating layer is plasticized by high temperature and pressure, and the pigment in the coating layer is removed. This is because the coating layer surface can be smoothed by being effectively oriented, so that the inner base paper layer can be kept relatively bulky with a small number of nips.

  However, in the advent of high-speed paper machines with higher speeds of 1300 m / min, and more preferably over 1400 m / min, even if the thermal soft calender is used, sufficient flattening processing cannot be performed, increasing the number of stages and stacks. Therefore, there is a problem that the capital investment cost becomes enormous.

Moreover, although it is known by the technique of patent document 1 using a thermal soft calender, it cannot be said that it is sufficient planarization processing.
Japanese Patent Laid-Open No. 11-100807

  Therefore, the main problem of the present invention is to obtain a coated paper exhibiting the printability required for particularly severe coated paper in recent years, even if the papermaking speed is 1300 m / min or more.

  The present inventor firstly, in a coated paper manufacturing method comprising a combination of a papermaking facility using a gap former and a thermal soft calender, a raw material in which dehydration at the wire part immediately after the gap former is discharged from the head box. By using a forming (suction) roll gently, the fine fibers are kept in the wet paper, and / or by dehydrating with a blade using a dehydrating means to prevent a decrease in the internal bond. The lower layer aqueous coating solution is blade-coated on both sides of the coated paper, and then the upper layer aqueous coating solution is blade coated on the coated paper, that is, the coating is performed on-machine with four heads. By doing so, it is possible to obtain extremely high-quality coated paper (especially desirably, undercoating applied by a film transfer method prior to the coating process) Thirdly, by performing the flattening process with a thermal soft calender, the printability required for conventional coated paper is exhibited while the papermaking speed is 1300 m / min or more. The present inventors have found that it is possible to obtain coated paper and obtain excellent operational stability, and have completed the present invention.

That is, the present invention that has solved the above problems is as follows.
<Invention of Claim 1>
A method for producing coated paper, wherein the following continuous steps are incorporated in order in an on-machine, and the papermaking speed is 1300 m / min or more.
A paper making process using a gap type twin wire former that forms a paper layer by ejecting paper from the head box between two looped wires.
Forming a wet paper with a dewatering means using a suction (forming) roll and / or a blade in the wire part;
The lower layer aqueous coating liquid mainly composed of an adhesive and a pigment on the coated paper , the blade thickness is 0.50 to 0.70 mm, and the blade edge portion is composed of a thermal spray material mainly composed of tungsten or alumina oxide. A first coating step in which coating is performed with a blade having a Vickers hardness of 1100 to 2000 Hv and drying is sequentially performed on one side and the other side;
Using a jet fountain application type blade coater, an upper layer aqueous coating liquid mainly composed of an adhesive and a pigment is applied to the coated paper after the first coating process , and the blade edge portion of the blade is 30 to 50 degrees. The blade thickness is 0.45 to 0.60 mm, the blade edge portion is sprayed with a thermal spray material mainly composed of tungsten or alumina, and has a Vickers hardness of 1000 to 1700 Hv. was applied in one blade, the second coating step for drying it, in order to one surface and the other surface,
A step of flattening with a thermal soft calender composed of a combination of metal rolls and elastic rolls configured in multiple stages having at least two nips.

<Invention of Claim 2>
The manufacturing method of the coated paper of Claim 1 which has an undercoat coating liquid application | coating process apply | coated by a film transfer system prior to a said 1st coating process.

<Invention of Claim 3 >
The thermal soft calender is composed of 6 to 10 stages, and the surface roughness of the metal roll with which one side to be flattened is in contact is 2.5 to 4.5 μm (JIS B 0601), and the other side is in contact with the elastic roll. The method for producing a coated paper according to claim 1 or 2 , wherein the Shore D hardness is 90 or more, and paper is passed between a roll pair of a metal roll and an elastic roll.
<Invention of Claim 4>
The method for producing a coated paper according to any one of claims 1 to 3, wherein the jet fountain-applied blade coater has a fountain angle of 40 to 60 degrees.

<Invention of Claim 5 >
A coated paper manufacturing facility in which the following continuous means are incorporated in order in an on-machine.
Means for paper making with a gap type twin wire former that forms a paper layer by ejecting paper from the head box between two looped wires,
Means for forming wet paper with a dewatering means by suction (forming) rolls and / or blades in the wire part;
The lower layer aqueous coating liquid mainly composed of an adhesive and a pigment on the coated paper , the blade thickness is 0.50 to 0.70 mm, and the blade edge portion is composed of a thermal spray material mainly composed of tungsten or alumina oxide. A first coating means for performing coating with a blade having a Vickers hardness of 1100 to 2000 Hv and drying the coating sequentially on one side and the other side;
The upper layer aqueous coating liquid mainly composed of an adhesive and a pigment is applied to the coated paper after the first coating step using a jet fountain application type blade coater, the fountain angle is 40 to 60 degrees, Vickers hardness of 1000 to 1700 Hv with a bevel angle of 30 to 50 degrees, a blade thickness of 0.45 to 0.60 mm, and a cutting edge portion sprayed with a thermal spray material mainly composed of tungsten or alumina oxide. having, coated with a single blade having no backing material, the second coating unit for performing drying, a drying them, in order to one surface and the other surface of this,
Means for flattening with a thermal soft calender composed of a combination of metal rolls and elastic rolls configured in multiple stages having at least two nips.

  With the method for producing coated paper according to the present invention, extremely high operability can be secured and glossiness, smoothness, printability, etc. can be ensured when high speed papermaking at 1300 m / min or higher (design speed of 1800 m / min or higher) is performed. High quality coated paper can be manufactured with an integrated paper making machine (online machine) from papermaking raw materials to products.

The present invention is, for example, coated paper having a base paper weight of 28 to 80 g / m ² (particularly 39 to 48 g / m ² ) and a product paper weight of 40 to 105 g / m ² (particularly 54 to 64 g / m ² ). Alternatively, it is intended to produce finely coated paper continuously and consistently from papermaking to winding at a papermaking speed of 1300 m / min or higher, for example, an average papermaking speed of 1600 m / min and a designed papermaking speed of 1800 m / min. Yes.

First, an overall outline of an embodiment of the present invention will be described with reference to FIGS.
A paper machine for making paper with a gap type twin wire former 10 that forms a paper layer by ejecting a paper material J from a head box 3 between two looped wires (between the first wire 1 and the second wire 2). Is installed. In the wire part, the paper material J is discharged between the wires between the suction (forming) roll 4A and the opposite roll 4B to form a paper layer. The paper layer is composed of the suction (forming) roll 4A, the blade 5, While passing through the suction couch roll 6, the suction box 7, etc., it is dehydrated to about 20%, for example.

  Here, as the dehydrating mechanism, the combination of the roll means and the blade dewatering means is shown in the illustrated example, but preferably both, but only one is possible.

  The head box 3 is installed upward in a state inclined vertically or downstream, and as shown in an enlarged view in FIG. 5, when the paper discharge direction line is a horizontal line, the discharge angle θ is 50 degrees to 90 degrees. Is desirable. Under the high-speed papermaking intended by the present invention, it is desirable that the head box is an upward head in which the influence of the fiber weight is small in terms of formation, Z-axis strength, front / back difference, fiber orientation angle, and the like. In the gap type twin wire former, if the head box is horizontal, it is difficult to obtain the desired characteristics under high-speed papermaking.

The paper layer in the wire part is transferred to the press part and further dewatered. In the press part in the embodiment, each of the first press 21 and the second press 22 has shoe presses 21a and 22a, and the paper layer is nipped straight in order to eliminate open draw and prevent paper breakage. It is as. In contrast to the double felt first press 21, the second press 22 employs a belt on the bottom side to improve dehydration and prevent rewetting. When the basis weight is as high as 60 g / m ² or more and the dewatering amount is increased, double felt is desirable.

The wet paper having a water content of about 50% passing through the press part is transferred to a single-deck type pre-dryer part and dried. The illustrated pre-dryer part is a single deck dryer of a no-open draw type, and has an appropriate number of rolls including a heating roll 31 on the upper side and a vacuum roll 32 on the lower side. The single-deck type dryer is excellent in quality and operation in terms of high-speed papermaking of 1300 m / min or more, which is a subject of the present invention, with less paper breakage and high-efficiency drying without reducing bulk. A method of drying by a double deck method is also conceivable, but there are problems in terms of operability such as canvas marks in high-speed papermaking, paper breaks in high-speed drying, wrinkles, and paper splicing.
In the initial stage of the dryer, it is desirable to make the grouping fine for draw adjustment, and to install the suction box 33 for improving the paper passing property and the sheet running property.

  The paper sheet dried in the pre-dryer part is coated on both sides with a sizing agent such as starch and an undercoat coating liquid such as a pigment coating liquid in a size press 40 using a film transfer (method) with the after-dryer part. Is done. As the size press 40, a gate roll coater 40A or the like may be used in addition to the illustrated rod metering size press coater.

For the undercoat coating solution, as described above, in addition to starch, starch derivatives such as oxidized starch, esterified starch, enzyme-modified starch, and etherified starch, and natural adhesives such as soybean protein, yeast protein, and cellulose derivatives are used. On the other hand, if necessary, pigments may be added, such as kaolin, clay, barium sulfate, light calcium carbonate, heavy calcium carbonate, aluminum hydroxide, satin white, titanium dioxide, sulfurous acid. Ordinary coated paper pigments such as calcium, zinc sulfate, and plastic pigment are blended according to the properties of each pigment. Further, as adhesives, acrylic polymer latexes such as conjugated diene copolymer latexes such as styrene / butadiene copolymers and methyl methacrylate / butadiene copolymers, and polymers and copolymers of acrylic and / or methacrylic acid esters. Ordinary coated paper adhesives such as synthetic resin adhesives such as alkali-insensitive or alkali-sensitive synthetic resin emulsions such as vinyl acetate copolymer latexes such as ethylene / vinyl acetate copolymers can be used. If necessary, various auxiliary agents such as a dispersant, a flow modifier, an antifoaming agent, a dye, a lubricant, a water-resistant agent, and a water retention agent can be blended. The coating amount of the primer, 3~15g / m ² is preferred.

  As the film transfer system coating means, a gate roll coater, shim sizer, blade metering size press, rod metering size press, or the like can be used. A rod metering size press is particularly desirable. When this rod metering size press coater is used, it is desirable to use a rod having a smooth surface in order to avoid streak in operation. By making the diameter of the rod 15 to 50 mm, more preferable operability and quality can be obtained. If the rod has a diameter of less than 15 mm, the film forming ability tends to be low and the surface shape tends to be inferior. If the rod is larger than 50 mm, the effect does not change, so there is no need to make it particularly large. As the rod, a grooved rod, a wire wire winding rod, or the like can also be used.

  After applying the undercoat coating liquid, it is desirable to install an air turn bar 41 and an auxiliary drying device 42 using infrared rays in advance so as not to cause surface contamination in the after dryer.

  In the illustrated single deck after-dryer part, the sizing agent and the pigment coating solution are dried.

  Thereafter, an aqueous coating liquid mainly composed of an adhesive and a pigment (such as clay) is applied at the coater part. In this case, a high-quality coated paper having high smoothness and glossiness is required under the condition of a papermaking speed of 1300 m / min or more, so that the aqueous coating liquid can be obtained as a blade coating. Adopted from the viewpoint of paper quality.

  However, prior to blade coating of the aqueous coating liquid, it is desirable to smooth the surface to which the sizing agent has been applied with the pre-calender 50 in order to ensure higher smoothness. In the pre-calender 50 of the embodiment, the upper side is a metal roll 51 and the lower side is an elastic roll 52.

The coater part according to the present invention includes a first coating process that is responsible for lower layer coating on both sides of the coated paper and a second coating process that is responsible for upper layer coating on both sides of the coated paper. Accordingly, a four-head coating machine is provided.
That is, the lower layer first coating machine 61A on the coated paper upper surface, the gas type air dryer 62, the first canvas dryer 63, the lower layer second coating machine 64A, the gas type air dryer 66, the second canvas. Dryer 67, first upper layer coating machine 61B on the upper surface of the coated paper, gas type air dryer 62, first canvas dryer 63, second upper layer coating machine 64B on the lower surface, gas type air dryer 66, second A canvas dryer 67 is installed in order. Desirably, a first infrared drying device 68 capable of controlling the temperature in the width direction is provided downstream of the first coating machines 61A and 61B in order to prevent uneven drying in the width direction. In addition, it is desirable to provide a second infrared drying device 69 capable of controlling the temperature in the width direction mainly for adjusting the moisture content at the subsequent stage of the second coating machines 64A and 64B. If necessary, it is also possible to provide a third infrared drying device 69A downstream of the gas air dryer 66.

In the first coating machine 61A, 61B and the second coating machine 64A, 64B, in the case of high-speed papermaking, when a coating amount of 7 g / m ² or more on one side is required, high-speed liquid supply is possible as an applicator. A jet fountain system is desirable, and scraping is by a blade. If a coating amount of less than 7 g / m ^{2 on} one side is required, a short dwell blade coater modified for high speed may be used. If necessary, the first coating machine 61A, 61B may be a short dwell blade coater improved for high speed, even if the coating amount is 7 g / m ² or more on one side.

  In blade coating, in order to eliminate coating unevenness in the flow direction and width direction in the case of roll coating, as shown in FIG. 11, the fountain angle of the applicator 90 when the jet fountain type coating is employed. α is 30 to 90 degrees, and more preferably 40 to 60 degrees. When the fountain angle α is out of the above range, rough skin or uneven application occurs. The blade edge portion preferably has a bevel angle θ of 30 to 50 degrees. The thickness of the blade is preferably 0.45 to 0.60 mm. In order to have high hardness, the blade edge part is made of a thermal spray material mainly composed of tungsten or alumina oxide, for example, a structure in which tungsten is thermally sprayed on a base material constituting the blade edge part of the blade, and Vickers of 1000 to 1700 Hv. What has hardness is a condition for excellent coating properties.

  In this case, it is desirable to provide cooling means such as water shower cooling in order to prevent burning of the blade at a high production speed when a new blade is touched after replacing the blade.

  Finally, an on-machine calendar 70 composed of a thermal soft calendar is installed, and calendar processing is performed. The illustrated calendar 70 is a 7-nip one-stack type, and has a Janus type inclined arrangement in which the influence of the roll weight is reduced. Of course, an optical load type vertical arrangement may be used.

  The calendar 70 determines the final smoothness and gloss. Therefore, various considerations are necessary from this viewpoint and from the viewpoint of high speed.

  The number of stages of the calendar 70 is not limited as long as it has at least two nips. However, it is desirable to perform the flattening process with a thermal soft calendar composed of a combination of metal rolls M and elastic rolls D formed in a plurality of stages. In particular, a multi-nip calender, more preferably a 6-, 8-, or 10-stage multi-nip calender is optimal. FIG. 5 shows an example of a 10-stage multi-nip calendar. Furthermore, a multi-nip calender that can adjust the nip pressure independently at all stages is optimal.

  On the other hand, the heat soft calender may be heated by circulating a heat medium such as oil, but this limits the surface temperature of about 180 ° C. In order to make paper at high speed, as shown in FIGS. 7 to 9, the metal roll M is equipped with an internal heating device by electromagnetic induction that can control the division temperature in the width direction. Those having a surface temperature of 230 ° C. or higher, particularly 230 to 500 ° C. are desirable. In the specific example, the induction coil 71 is wound around the iron core 72 in the shell 74 to heat the heat medium passing through the jacket chamber 73.

  The surface of the metal roll M is 250 ° C. to 380 ° C., particularly more than 300 ° C. and 380 ° C. or less, so that the paper does not collapse over the entire layer at the lowest possible nip pressure. Therefore, it is possible to perform an operation that can prevent a decrease in bulk and suppress a decrease in opacity. In short, it is a form in which an extremely hot iron is applied in a short time.

  As described above, in order to control the surface temperature of the metal roll, in addition to the method of circulating hot water or oil inside the metal roll, an induction coil is provided around the iron core provided inside as the non-rotating part, and its induction By passing an alternating current through the coil, a magnetic flux is generated in the coil, an induced current is induced inside the outer shell (outer cylinder) as a rotating part, and the outer shell (outer cylinder) itself is self-heated by the resistance heat. The “internal heating device using electromagnetic induction” that causes (induction heat generation) is particularly excellent for the high-temperature treatment of the present invention. Further, according to the internal heating device using this electromagnetic induction action, the induction coil is divided (for example, divided into 3 to 6) in the width direction of the roll (longitudinal direction of the roll itself), and based on the temperature signal from the temperature sensor provided in the shell. By controlling the amount of alternating current flowing through the corresponding induction coil, there is an advantage that temperature control of the surface in the width direction of the roll can be performed with high accuracy.

  In this case, in particular, a structure in which a large number of 10 to 90 jacket paths extending in the longitudinal direction are provided inside the shell at intervals in the circumferential direction, these are connected to each other, and a heat medium is sealed inside. However, it is superior in that it absorbs heat generated by self-heating of the shell and can make the heat uniform over the entire roll surface.

  According to the present invention, when the surface treatment is performed at a high temperature, not only the surface layer portion of the paper but also the temperature of the inner layer portion is increased, and as a result, the paper is liable to be crushed not only in the surface layer portion but also in all layers, thereby reducing the bulk. To do. However, when the paper is passed for a short time with a much higher high-temperature treatment, heat transfer to the inner layer portion can be prevented as much as possible, thereby preventing a decrease in bulk.

  On the other hand, as the surface temperature of the metal roll increases, stress in the thickness direction is generated in the shell of the metal roll, and the roll profile tends to collapse, thereby reducing the controllability of the paper thickness profile. In addition, when depending on the internal heating device by electromagnetic induction action, the temperature responsiveness per hour of the metal roll surface temperature cannot be said to be good, and furthermore the temperature responsiveness in the width direction is poor due to this, the temperature This causes a decrease in yield due to poor controllability. Therefore, it is desirable that near the metal roll M, at least one of an external heating device using an electromagnetic induction function capable of controlling the division temperature in the roll width direction and a cooling facility capable of controlling the cooling temperature in the roll width direction are provided.

  Explaining this example with reference to FIG. 8, the metal roll M includes a shell 74, an induction coil 71, an iron core 72, a temperature sensor 75, an AC power source 76, and a jacket path 73. For this metal roll M, an external heating device 77 by an external electromagnetic induction action that can be divided and controlled in the width direction is provided in the vicinity of the metal roll M to form a high temperature nip region of the base paper in each stage.

  The external heating device 77 applies the principle to electromagnetic induction heating. As shown in the drawing, an AC current (for example, a high frequency of 3 to 20 kHz) from an AC power source (inverter) 77B is passed through the work coil 77A to generate a magnetic field. Thus, an eddy current is generated on the surface portion of the shell 74 to cause self-heating. The distance between the work coil 77A and the surface of the shell 74 is desirably 2 to 20 mm, particularly about 2 to 5 mm. Moreover, it is desirable for the unit work coil to be disposed obliquely so as to intersect the axis of the metal roll M in order to make the heating profile uniform. The zone control pitch in the roll width direction is about 75 to 150 mm, and the rated power per zone can be 4 to 20 kW.

  As an example of the cooling equipment 78 capable of controlling the cooling temperature in the roll width direction, as shown in FIG. 9, the air from the fan 78a is sent to the header 78b, and the inside of the temperature control chamber 78d is passed through the adjustment plate 78c in which the communication holes are formed. The coil 78e provided in the temperature adjusting chamber 78d is cooled by the temperature adjusting means 78f to control the temperature of the air passing through the dispersion plate 78g having small holes.

  The nip pressure in the calendar 70 is preferably 200 KN / m to 450 KN / m, particularly 300 KN / m to 450 KN / m. The paper smoothed by the calendar 70 is finally taken up by the reel 80, and a winder (not shown) for finishing the take-up for subdivision is installed in the final part of the machine.

  Instead of the multi-nip calender shown in FIG. 5, as shown in FIG. 6, for example, a soft calender 70 </ b> A made up of metal rolls M and elastic rolls D made up of four stacks in one nip may be used.

The effect of the present invention will be clarified by examples.
Paper quality was evaluated by changing factors such as the wire part type, head box arrangement angle, suction form, coating form, thermal soft calender and paper making speed of the present invention. Also, it should be noted that each example is not a new line for each factor but a test example by a test plant.

The paper quality evaluation is as follows.
1. Formation evaluation: The formation evaluation specified in the examples is evaluated by using a sheet formation tester manufactured by Toyo Seiki Co., Ltd., and taking the variation in transmitted light amount as a time-series signal. In this measuring machine, 28 points can be measured in the range of unevenness wavelength of about 0.16 to 80 mm, but in the example, 14 points in the range of 4.0 to 80 mm are subjected to watermark registration in the sensory test. Since there is a close relationship with the formation that appears as a large shading, the sum of the fluctuation rates in this range was measured. When the unevenness index is less than 6%, the formation is very uniform, the uneven glossiness of the coated paper due to the formation unevenness hardly occurs, the formation of the coating layer becomes uniform, and printing at the time of printing Unevenness, uneven printing gloss, etc. are eliminated, and printability is improved.
2. Paper breakage: This is an evaluation of the number of paper breaks due to the difference in drying method by performing a test operation for 3 hours at a papermaking speed of 1500 m / min and a constant drying temperature using a dryer. ○: No paper break, Δ: 1 time, ×: 1 time or more.
3. Wrinkle: Using an actual dryer, a test operation was performed for 3 hours at a paper making speed of 1300 m / min and a constant drying temperature, and the occurrence of wrinkles due to the difference in the drying method was evaluated. ○: Wrinkled 0 times, Δ: Wrinkled 1 time, ×: Wrinkled 1 time or more.
4). Specific volume: Measured according to JIS P 8118.
5). Gloss: Measured according to JIS P 8142 at an angle of 75 degrees.
6). Gloss unevenness: A4 size test paper was prepared, and five grades were visually evaluated by five women and five men. An evaluation of 3 or higher was regarded as an acceptable level.
7). Unevenness of printing: Forty-six plate size test papers were prepared, printed on a Roland offset press, left in a constant room for 24 hours, and then the sample black, magenta, cyan, yellow four-color overprint solid printing section Evaluation was made on a five-point scale by five women and five men. An evaluation of 3 or higher was regarded as an acceptable level.
8). Yellow change: A4 size test paper was prepared, and five grades were visually evaluated by five women and five men. An evaluation of 3 or higher was regarded as an acceptable level.
9. Productivity: Five operators evaluate the test machine by observing the stability of the wet end in each example, dewaterability at the press part, drainage, and the occurrence of streaks with five operators. did. An evaluation of 3 or higher was regarded as an acceptable level.
10. Comprehensive evaluation: All quality items were comprehensively evaluated in four stages. A: Good production efficiency / quality, B: No production efficiency / quality problems, B: Some problems, x: Problems.

The base paper conditions are as follows.
<Creation of paper base>
A base paper having a basis weight (absolutely dry) of 60 g / m ² was prepared by blending the following pulp and internal chemicals to prepare a paper substrate.
<Pulp formulation>
LBKP (watering degree 350 mlcsf): 30 parts by weight NBKP (watering degree 420 mlcsf): 70 parts by weight The paper base was prepared with the above-described pulp blending and the following internal chemical compounding.
<Combination of internal chemicals>
-Light calcium carbonate: 10 parts by weight (average particle size: 3.4 μ, calcite system)
・ Commercial alkyl ketene dimer internal sizing agent (AKD): 0.03 part by weight ・ Commercial cationized starch: 0.2 part by weight ・ Commercial cationic polyacrylamide yield improver: 0.03 part by weight <Coating paper Create>
A coating solution having the following composition was applied on the above-mentioned paper base with a blade coater, and 9 g / cm ² on one side was applied and dried.
<Contains topcoat coating solution>
It is as follows.
(Pigment)
Spindle type light calcium carbonate (TP121, 3.4 μm manufactured by Okutama Kogyo): 30 parts by weight Commercially available kaolin (Amazon 88, average particle size: 0.8 μm): 70 parts by weight (binder and additive)
・ Commercially available phosphoric acid esterified starch (MS4400 manufactured by Nippon Shokuhin Kako): 1 part by weight ・ Styrene butadiene latex (manufactured by Nippon Synthetic Rubber 0617): 12 parts by weight ・ Commercially available polyacrylic acid dispersant: 0.1 part by weight : 0.3 part by weight · Sodium hydroxide: 0.15 part by weight

"Discussion"
It can be seen that, according to the present invention, compared to the comparative example, the high-quality paper can be obtained while being high-speed papermaking.

It is an outline explanatory view showing the 1st zone of the example of equipment composition of a paper machine. It is a schematic explanatory drawing which shows the 2nd zone of the equipment structural example of a paper machine. It is an outline explanatory view showing the 3rd zone of the example of equipment composition of a paper machine. It is a schematic explanatory drawing which shows the 4th zone of the equipment structural example of a paper machine. It is a schematic explanatory drawing which shows the 5th zone of the equipment structural example of a paper machine. It is a schematic explanatory drawing which shows the modification in the 5th zone of the equipment structural example of a paper machine. It is outline | summary explanatory drawing which shows the ejection of the paper stock of a head box. It is a schematic explanatory drawing which shows a heating metal roll. It is a schematic explanatory drawing which shows the example of an internal heating apparatus by an electromagnetic induction effect | action. It is an outline explanatory view showing an example of cooling equipment. It is outline | summary explanatory drawing which shows the example of a blade coating machine.

  DESCRIPTION OF SYMBOLS 1 ... 1st wire, 2 ... 2nd wire, 3 ... Head box, 5 ... Blade, 10 ... Twin wire former, 21 ... 1st press, 22 ... 2nd press 22, 40 ... Size press, 41 ... Air turn bar, 50 ... Precalender, 51 ... Metal roll, 52 ... Elastic roll, 61A, 61B ... First coating machine, 64A, 64B ... Second coating machine 64, 70 ... On-machine calendar, M ... Metal roll, D ... Elasticity Roll, 80 ... reel, 90 ... applicator, 91 ... blade.

Claims (5)

A method for producing coated paper, wherein the following continuous steps are incorporated in order in an on-machine, and the papermaking speed is 1300 m / min or more.
A paper making process using a gap type twin wire former that forms a paper layer by ejecting paper from the head box between two looped wires.
Forming a wet paper with a dewatering means using a suction (forming) roll and / or a blade in the wire part;
The lower layer aqueous coating liquid mainly composed of an adhesive and a pigment on the coated paper , the blade thickness is 0.50 to 0.70 mm, and the blade edge portion is composed of a thermal spray material mainly composed of tungsten or alumina oxide. A first coating step in which coating is performed with a blade having a Vickers hardness of 1100 to 2000 Hv and drying is sequentially performed on one side and the other side;
Using a jet fountain application type blade coater, an upper layer aqueous coating liquid mainly composed of an adhesive and a pigment is applied to the coated paper after the first coating process , and the blade edge portion of the blade is 30 to 50 degrees. The blade thickness is 0.45 to 0.60 mm, the blade edge portion is sprayed with a thermal spray material mainly composed of tungsten or alumina, and has a Vickers hardness of 1000 to 1700 Hv. was applied in one blade, the second coating step for drying it, in order to one surface and the other surface,
A step of flattening with a thermal soft calender composed of a combination of metal rolls and elastic rolls configured in multiple stages having at least two nips.   The manufacturing method of the coated paper of Claim 1 which has an undercoat coating liquid application | coating process apply | coated by a film transfer system prior to a said 1st coating process. The thermal soft calender is composed of 6 to 10 stages, and the surface roughness of the metal roll with which one side to be flattened is in contact is 2.5 to 4.5 μm (JIS B 0601), and the other side is in contact with the elastic roll. The method for producing a coated paper according to claim 1 or 2 , wherein the Shore D hardness is 90 or more, and paper is passed between a roll pair of a metal roll and an elastic roll. The method for producing a coated paper according to any one of claims 1 to 3, wherein the jet fountain-applied blade coater has a fountain angle of 40 to 60 degrees. A coated paper manufacturing facility in which the following continuous means are incorporated in order in an on-machine.
Means for paper making with a gap type twin wire former that forms a paper layer by ejecting paper from the head box between two looped wires,
Means for forming wet paper with a dewatering means by suction (forming) rolls and / or blades in the wire part;
The lower layer aqueous coating liquid mainly composed of an adhesive and a pigment on the coated paper , the blade thickness is 0.50 to 0.70 mm, and the blade edge portion is composed of a thermal spray material mainly composed of tungsten or alumina oxide. A first coating means for performing coating with a blade having a Vickers hardness of 1100 to 2000 Hv and drying the coating sequentially on one side and the other side;
The upper layer aqueous coating liquid mainly composed of an adhesive and a pigment is applied to the coated paper after the first coating step using a jet fountain application type blade coater, the fountain angle is 40 to 60 degrees, Vickers hardness of 1000 to 1700 Hv with a bevel angle of 30 to 50 degrees, a blade thickness of 0.45 to 0.60 mm, and a cutting edge portion sprayed with a thermal spray material mainly composed of tungsten or alumina oxide. having, coated with a single blade having no backing material, the second coating unit for performing drying, a drying them, in order to one surface and the other surface of this,
Means for flattening with a thermal soft calender composed of a combination of metal rolls and elastic rolls configured in multiple stages having at least two nips.

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