JP4116937B2 - Oxidative hair dye or decolorant composition - Google Patents
Oxidative hair dye or decolorant composition Download PDFInfo
- Publication number
- JP4116937B2 JP4116937B2 JP2003190835A JP2003190835A JP4116937B2 JP 4116937 B2 JP4116937 B2 JP 4116937B2 JP 2003190835 A JP2003190835 A JP 2003190835A JP 2003190835 A JP2003190835 A JP 2003190835A JP 4116937 B2 JP4116937 B2 JP 4116937B2
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- JP
- Japan
- Prior art keywords
- agent
- amino
- composition
- hair
- group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- 239000000203 mixture Substances 0.000 title claims description 51
- 239000000118 hair dye Substances 0.000 title claims description 22
- 230000001590 oxidative effect Effects 0.000 title claims description 19
- 239000003712 decolorant Substances 0.000 title 1
- 239000003795 chemical substances by application Substances 0.000 claims description 87
- 229920001296 polysiloxane Polymers 0.000 claims description 67
- -1 hydroxyethylammonium ion Chemical class 0.000 claims description 31
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 16
- 239000007800 oxidant agent Substances 0.000 claims description 14
- 239000000975 dye Substances 0.000 claims description 13
- 229920000642 polymer Polymers 0.000 claims description 13
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 12
- 125000002091 cationic group Chemical group 0.000 claims description 11
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 10
- 238000004043 dyeing Methods 0.000 claims description 10
- 229920006317 cationic polymer Polymers 0.000 claims description 9
- 125000003277 amino group Chemical group 0.000 claims description 8
- 239000001913 cellulose Substances 0.000 claims description 8
- 229920002678 cellulose Polymers 0.000 claims description 8
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 7
- 229920001577 copolymer Polymers 0.000 claims description 7
- 239000000982 direct dye Substances 0.000 claims description 7
- 238000007254 oxidation reaction Methods 0.000 claims description 7
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 claims description 6
- 125000001841 imino group Chemical group [H]N=* 0.000 claims description 6
- 230000003647 oxidation Effects 0.000 claims description 6
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims description 5
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 5
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 5
- 239000003093 cationic surfactant Substances 0.000 claims description 4
- 238000006116 polymerization reaction Methods 0.000 claims description 4
- 229920002472 Starch Polymers 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- 239000002736 nonionic surfactant Substances 0.000 claims description 3
- 239000008107 starch Substances 0.000 claims description 3
- 235000019698 starch Nutrition 0.000 claims description 3
- 229920002907 Guar gum Polymers 0.000 claims description 2
- 239000000665 guar gum Substances 0.000 claims description 2
- 235000010417 guar gum Nutrition 0.000 claims description 2
- 229960002154 guar gum Drugs 0.000 claims description 2
- 239000004615 ingredient Substances 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 12
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 10
- 239000000839 emulsion Substances 0.000 description 10
- 230000000694 effects Effects 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 8
- 239000002453 shampoo Substances 0.000 description 8
- 239000000243 solution Substances 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- 125000000217 alkyl group Chemical group 0.000 description 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 6
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 6
- 238000004042 decolorization Methods 0.000 description 5
- GQOKIYDTHHZSCJ-UHFFFAOYSA-M dimethyl-bis(prop-2-enyl)azanium;chloride Chemical compound [Cl-].C=CC[N+](C)(C)CC=C GQOKIYDTHHZSCJ-UHFFFAOYSA-M 0.000 description 5
- 230000003700 hair damage Effects 0.000 description 5
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- FDCJDKXCCYFOCV-UHFFFAOYSA-N 1-hexadecoxyhexadecane Chemical compound CCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCC FDCJDKXCCYFOCV-UHFFFAOYSA-N 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- 239000004205 dimethyl polysiloxane Substances 0.000 description 4
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 4
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 description 4
- 238000004945 emulsification Methods 0.000 description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 4
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 4
- 229920002545 silicone oil Polymers 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 3
- 229910019142 PO4 Inorganic materials 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 229910021529 ammonia Inorganic materials 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 230000003750 conditioning effect Effects 0.000 description 3
- 239000007854 depigmenting agent Substances 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 150000002430 hydrocarbons Chemical group 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 230000005923 long-lasting effect Effects 0.000 description 3
- JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 3
- 235000021317 phosphate Nutrition 0.000 description 3
- 239000002243 precursor Substances 0.000 description 3
- 239000008213 purified water Substances 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- KJCVRFUGPWSIIH-UHFFFAOYSA-N 1-naphthol Chemical compound C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 description 2
- CDAWCLOXVUBKRW-UHFFFAOYSA-N 2-aminophenol Chemical compound NC1=CC=CC=C1O CDAWCLOXVUBKRW-UHFFFAOYSA-N 0.000 description 2
- OSCJHTSDLYVCQC-UHFFFAOYSA-N 2-ethylhexyl 4-[[4-[4-(tert-butylcarbamoyl)anilino]-6-[4-(2-ethylhexoxycarbonyl)anilino]-1,3,5-triazin-2-yl]amino]benzoate Chemical compound C1=CC(C(=O)OCC(CC)CCCC)=CC=C1NC1=NC(NC=2C=CC(=CC=2)C(=O)NC(C)(C)C)=NC(NC=2C=CC(=CC=2)C(=O)OCC(CC)CCCC)=N1 OSCJHTSDLYVCQC-UHFFFAOYSA-N 0.000 description 2
- OBCSAIDCZQSFQH-UHFFFAOYSA-N 2-methyl-1,4-phenylenediamine Chemical compound CC1=CC(N)=CC=C1N OBCSAIDCZQSFQH-UHFFFAOYSA-N 0.000 description 2
- CUZKCNWZBXLAJX-UHFFFAOYSA-N 2-phenylmethoxyethanol Chemical compound OCCOCC1=CC=CC=C1 CUZKCNWZBXLAJX-UHFFFAOYSA-N 0.000 description 2
- PLIKAWJENQZMHA-UHFFFAOYSA-N 4-aminophenol Chemical compound NC1=CC=C(O)C=C1 PLIKAWJENQZMHA-UHFFFAOYSA-N 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- LUSZGTFNYDARNI-UHFFFAOYSA-N Sesamol Chemical compound OC1=CC=C2OCOC2=C1 LUSZGTFNYDARNI-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 125000002947 alkylene group Chemical group 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 239000001099 ammonium carbonate Substances 0.000 description 2
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 239000000981 basic dye Substances 0.000 description 2
- 239000007853 buffer solution Substances 0.000 description 2
- 150000001768 cations Chemical group 0.000 description 2
- 229940082500 cetostearyl alcohol Drugs 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 239000006071 cream Substances 0.000 description 2
- 125000004966 cyanoalkyl group Chemical group 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 description 2
- 239000000986 disperse dye Substances 0.000 description 2
- 229960000735 docosanol Drugs 0.000 description 2
- 239000002552 dosage form Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 2
- 230000007794 irritation Effects 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- TWNIBLMWSKIRAT-VFUOTHLCSA-N levoglucosan Chemical group O[C@@H]1[C@@H](O)[C@H](O)[C@H]2CO[C@@H]1O2 TWNIBLMWSKIRAT-VFUOTHLCSA-N 0.000 description 2
- 230000003020 moisturizing effect Effects 0.000 description 2
- 239000001005 nitro dye Substances 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 229910000027 potassium carbonate Inorganic materials 0.000 description 2
- 235000011181 potassium carbonates Nutrition 0.000 description 2
- 108090000623 proteins and genes Chemical class 0.000 description 2
- 102000004169 proteins and genes Human genes 0.000 description 2
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 2
- 229960001755 resorcinol Drugs 0.000 description 2
- 210000004761 scalp Anatomy 0.000 description 2
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 2
- 238000006467 substitution reaction Methods 0.000 description 2
- OULAJFUGPPVRBK-UHFFFAOYSA-N tetratriacontyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO OULAJFUGPPVRBK-UHFFFAOYSA-N 0.000 description 2
- MGSRCZKZVOBKFT-UHFFFAOYSA-N thymol Chemical compound CC(C)C1=CC=C(C)C=C1O MGSRCZKZVOBKFT-UHFFFAOYSA-N 0.000 description 2
- FFJCNSLCJOQHKM-CLFAGFIQSA-N (z)-1-[(z)-octadec-9-enoxy]octadec-9-ene Chemical compound CCCCCCCC\C=C/CCCCCCCCOCCCCCCCC\C=C/CCCCCCCC FFJCNSLCJOQHKM-CLFAGFIQSA-N 0.000 description 1
- XGNXYCFREOZBOL-UHFFFAOYSA-N 1,3-benzodioxol-5-amine Chemical compound NC1=CC=C2OCOC2=C1 XGNXYCFREOZBOL-UHFFFAOYSA-N 0.000 description 1
- VIXBPSTZNCRCJE-UHFFFAOYSA-N 1,3-bis[4-amino-n-(2-hydroxyethyl)anilino]propan-2-ol Chemical compound C1=CC(N)=CC=C1N(CCO)CC(O)CN(CCO)C1=CC=C(N)C=C1 VIXBPSTZNCRCJE-UHFFFAOYSA-N 0.000 description 1
- WZCQRUWWHSTZEM-UHFFFAOYSA-N 1,3-phenylenediamine Chemical compound NC1=CC=CC(N)=C1 WZCQRUWWHSTZEM-UHFFFAOYSA-N 0.000 description 1
- FBMQNRKSAWNXBT-UHFFFAOYSA-N 1,4-diaminoanthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C(N)=CC=C2N FBMQNRKSAWNXBT-UHFFFAOYSA-N 0.000 description 1
- FRASJONUBLZVQX-UHFFFAOYSA-N 1,4-dioxonaphthalene Natural products C1=CC=C2C(=O)C=CC(=O)C2=C1 FRASJONUBLZVQX-UHFFFAOYSA-N 0.000 description 1
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 description 1
- BOKGTLAJQHTOKE-UHFFFAOYSA-N 1,5-dihydroxynaphthalene Chemical compound C1=CC=C2C(O)=CC=CC2=C1O BOKGTLAJQHTOKE-UHFFFAOYSA-N 0.000 description 1
- OQWWMUWGSBRNMA-UHFFFAOYSA-N 1-(2,4-diaminophenoxy)ethanol Chemical compound CC(O)OC1=CC=C(N)C=C1N OQWWMUWGSBRNMA-UHFFFAOYSA-N 0.000 description 1
- PIDZGPMVKVVCGG-UHFFFAOYSA-N 1-(3,4-diamino-1h-pyrazol-5-yl)ethanol Chemical compound CC(O)C1=NNC(N)=C1N PIDZGPMVKVVCGG-UHFFFAOYSA-N 0.000 description 1
- RECMXJOGNNTEBG-UHFFFAOYSA-N 1-phenylmethoxyethanol Chemical compound CC(O)OCC1=CC=CC=C1 RECMXJOGNNTEBG-UHFFFAOYSA-N 0.000 description 1
- CSHOPPGMNYULAD-UHFFFAOYSA-N 1-tridecoxytridecane Chemical compound CCCCCCCCCCCCCOCCCCCCCCCCCCC CSHOPPGMNYULAD-UHFFFAOYSA-N 0.000 description 1
- XAWPKHNOFIWWNZ-UHFFFAOYSA-N 1h-indol-6-ol Chemical compound OC1=CC=C2C=CNC2=C1 XAWPKHNOFIWWNZ-UHFFFAOYSA-N 0.000 description 1
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- 229940113489 2,4-diaminophenoxyethanol Drugs 0.000 description 1
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- SYEYEGBZVSWYPK-UHFFFAOYSA-N 2,5,6-triamino-4-hydroxypyrimidine Chemical compound NC1=NC(N)=C(N)C(O)=N1 SYEYEGBZVSWYPK-UHFFFAOYSA-N 0.000 description 1
- MJAVQHPPPBDYAN-UHFFFAOYSA-N 2,6-dimethylbenzene-1,4-diamine Chemical compound CC1=CC(N)=CC(C)=C1N MJAVQHPPPBDYAN-UHFFFAOYSA-N 0.000 description 1
- LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 description 1
- KWSVXCAQFTWTEF-UHFFFAOYSA-N 2-(2,5-diaminophenyl)ethanol Chemical compound NC1=CC=C(N)C(CCO)=C1 KWSVXCAQFTWTEF-UHFFFAOYSA-N 0.000 description 1
- OWMQBFHMJVSJSA-UHFFFAOYSA-N 2-(2-amino-4-nitroanilino)ethanol Chemical compound NC1=CC([N+]([O-])=O)=CC=C1NCCO OWMQBFHMJVSJSA-UHFFFAOYSA-N 0.000 description 1
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- LMKFATMCEGPAPC-UHFFFAOYSA-N 2-[4-amino-n-(2-hydroxyethyl)-2-nitroanilino]ethanol Chemical compound NC1=CC=C(N(CCO)CCO)C([N+]([O-])=O)=C1 LMKFATMCEGPAPC-UHFFFAOYSA-N 0.000 description 1
- ISCYHXYLVTWDJT-UHFFFAOYSA-N 2-[4-amino-n-(2-hydroxyethyl)anilino]ethanol Chemical compound NC1=CC=C(N(CCO)CCO)C=C1 ISCYHXYLVTWDJT-UHFFFAOYSA-N 0.000 description 1
- HCPJEHJGFKWRFM-UHFFFAOYSA-N 2-amino-5-methylphenol Chemical compound CC1=CC=C(N)C(O)=C1 HCPJEHJGFKWRFM-UHFFFAOYSA-N 0.000 description 1
- ALQKEYVDQYGZDN-UHFFFAOYSA-N 2-amino-6-methylphenol Chemical compound CC1=CC=CC(N)=C1O ALQKEYVDQYGZDN-UHFFFAOYSA-N 0.000 description 1
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- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 1
- MGLZGLAFFOMWPB-UHFFFAOYSA-N 2-chloro-1,4-phenylenediamine Chemical compound NC1=CC=C(N)C(Cl)=C1 MGLZGLAFFOMWPB-UHFFFAOYSA-N 0.000 description 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- PMUNIMVZCACZBB-UHFFFAOYSA-N 2-hydroxyethylazanium;chloride Chemical compound Cl.NCCO PMUNIMVZCACZBB-UHFFFAOYSA-N 0.000 description 1
- ZTMADXFOCUXMJE-UHFFFAOYSA-N 2-methylbenzene-1,3-diol Chemical compound CC1=C(O)C=CC=C1O ZTMADXFOCUXMJE-UHFFFAOYSA-N 0.000 description 1
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Landscapes
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- Compositions Of Macromolecular Compounds (AREA)
Description
【０００１】
【発明の属する技術分野】
本発明は、毛髪の染色力・脱色力に優れると共に、毛髪に持続性のあるしっとり感とまとまり易さを付与し、また、毛髪の損傷度によらずほぼ均等な色に染色(脱色)することができ、シャンプー堅牢性（特に化学処理等により損傷の進んだ部分）にも優れる酸化染毛剤又は脱色剤組成物に関する。
【０００２】
【従来の技術】
毛髪の脱色及び染色には、アルカリ剤、酸化剤等の共存下での酸化反応によって毛髪を脱色ないし染色する、酸化性の染毛剤又は脱色剤が広く使用されている。
【０００３】
しかし、酸化性の染毛剤又は脱色剤は、毛髪損傷を引き起こし易く、水洗、シャンプー又は乾燥時に、髪の絡まり、硬さ、ごわつき等を生じたり、髪の色、ツヤがなくなったり、まとまりが悪くなったりしてしまう。
【０００４】
そこで、これらの問題に対処するため、コンディショニング作用を持つ添加剤を使用することが行われている。例えば、アミノ変性シリコーンオイル等のシリコーン誘導体の添加により、毛髪を深みのある色調に染色すること（特許文献１参照）、アミノ基を有するポリオルガノシロキサンの添加により、毛髪に柔軟な感触を与え、毛髪のセット性を改善すること（特許文献２参照）、高重合シリコーン又はその誘導体の添加により、毛髪の損傷を防止し、感触を良好にすること（特許文献３及び４参照）などが報告されている。
【０００５】
しかしながら、酸化性の染毛剤又は脱色剤には、より高いコンディショニング作用が求められているのが現状であり、さらには染色性又は脱色性の面でも改善が求められている。
【０００６】
【特許文献１】
特開昭57-192310号公報
【特許文献２】
特開平9-59136号公報
【特許文献３】
特開昭63-313717号公報
【特許文献４】
特開平4-59721号公報
【０００７】
【発明が解決しようとする課題】
本発明は、毛髪の染色力・脱色力に優れると共に、毛髪に持続性のあるしっとり感とまとまり易さを付与し、また、毛髪の損傷度によらずほぼ均等な色に染色(脱色)することができ、シャンプー堅牢性（特に化学処理等により損傷の進んだ部分）にも優れる酸化染毛剤又は脱色剤組成物を提供することを目的とする。
【０００８】
【課題を解決するための手段】
本発明者は、酸化染毛剤又は脱色剤組成物において、モノエタノールアミン、炭酸塩、特定のシリコーン類及びカチオン性ポリマーを併用することにより、上記課題を解決できることを見出した。
【０００９】
本発明は、次の成分(A)〜(F)
(A)モノエタノールアミン又はヒドロキシエチルアンモニウムイオン
(B)炭酸イオン又は炭酸水素イオン
(C)アミノ変性シリコーン又はメチルポリシロキサン類
(D)カチオン性ポリマー
(E)酸化染料中間体又は直接染料（脱色剤の場合はいずれも含有しない）
(F)酸化剤
を含有する酸化染毛剤又は脱色剤組成物を提供するものである。
【００１０】
また本発明は、上記組成中、成分(A)、(B)及び(E)を含有する第１剤並びに成分(F)を含有する第２剤、又は更に粉末状酸化剤である第３剤（成分(C)及び(D)はそれぞれ第１剤、第２剤及び第３剤のいずれか１以上に含有し、また脱色の場合は成分(E)はいずれにも含有しない）を、使用直前に混合し、毛髪に適用し、所定時間放置後、洗い流す毛髪の染色又は脱色方法を提供するものである。
【００１１】
【発明の実施の形態】
本発明の酸化染毛剤又は脱色剤組成物は、アルカリ剤を含有する第１剤と酸化剤を含有する第２剤よりなる二剤型として、又は、更に第３剤として過硫酸塩等の造粒物からなる粉末状酸化剤を組み合わせてなる三剤型の形態をとる。以下、本発明において「全組成物」とは、二剤型の場合には第１剤及び第２剤を混合した使用直前の組成物全体をいい、三剤型の場合は、第１剤、第２剤及び第３剤を混合した使用直前の組成物全体をいう。
【００１２】
〔成分(A)：モノエタノールアミン又はヒドロキシエチルアンモニウムイオン〕成分(A)のモノエタノールアミン又はヒドロキシエチルアンモニウムイオンは、第１剤に含まれ、全組成物中にモノエタノールアミン量に換算して0.1〜10重量％、特に0.2〜５重量％含有するのが好ましい。ヒドロキシエチルアンモニウムイオン源としては、モノエタノールアミンのほか、塩酸モノエタノールアミン等が挙げられる。モノエタノールアミンとヒドロキシエチルアンモニウムイオンとは、共存して緩衝系を形成していることが好ましい。
【００１３】
〔成分(B)：炭酸イオン又は炭酸水素イオン〕
成分(B)の炭酸イオン又は炭酸水素イオンは、第１剤に含まれる。炭酸イオン源又は炭酸水素イオン源としては、炭酸アンモニウム、炭酸水素アンモニウム、炭酸ナトリウム、炭酸水素ナトリウム、炭酸カリウム、炭酸水素カリウム、炭酸グアニジン等が挙げられる。炭酸イオンと炭酸水素イオンとは、共存して緩衝系を形成していることが好ましい。成分(B)の含有量は、成分(A)の含有量とのモル比が(A)／(B)＝0.1〜10となるように調整するのが好ましい。
【００１４】
〔成分(C)：アミノ変性シリコーン又はメチルポリシロキサン類〕
成分(C)のアミノ変性シリコーン又はメチルポリシロキサン類は、第１剤、第２剤及び第３剤のいずれか１以上に含まれる。
【００１５】
（アミノ変性シリコーン）
アミノ変性シリコーンとしては、アミノ基又はアンモニウム基を有していればよく、末端水酸基の全て又は一部がメチル基等で封鎖されたアミノ変性シリコーンオイル、末端が封鎖されていないアモジメチコーンのどちらでもよい。例えば、好ましいアミノ変性シリコーンとしては、以下の一般式(1)で表されるものが挙げられる。
【００１６】
【化１】
〔式中、Ｒ0は水酸基、水素原子又はＲを示し、Ｒは置換又は非置換の炭素数１〜20の一価炭化水素基を示し、ＡはＲ、基−Ｒ′−(ＮＨＣＨ2ＣＨ2)nＮＨ2、基ＯＲ又は水酸基を示し、Ｒ′は炭素数１〜８の二価炭化水素基を示し、ｎは０〜３の数を示し、ｐ及びｑはその和が数平均で10以上1000未満、好ましくは30以上1000未満、更に好ましくは40以上800未満となる数を示す。アミノ当量は200g/mol〜３万g/mol、好ましくは500g/mol〜１万g/mol、更に好ましくは600g/mol〜5000g/molである。〕
【００１８】
アミノ変性シリコーンの好適な市販品の具体例としては、SF8451C（東レ・ダウコーニング・シリコーン社，粘度600mm2/s，アミノ当量1700g/mol）、SF8452C（東レ・ダウコーニング・シリコーン社，粘度700mm2/s，アミノ当量6400g/mol）、SF8457C（東レ・ダウコーニング・シリコーン社，粘度1200mm2/s，アミノ当量1800g/mol）、KF8003（GE東芝シリコーン社，粘度1850mm2/s，アミノ当量2000g/mol）、KF867（GE東芝シリコーン社，粘度1300mm2/s，アミノ当量1700g/mol）等のアミノ変性シリコーンオイルや、SM8704C（東レ・ダウコーニング・シリコーン社，アミノ当量1800g/mol）等のアモジメチコーンエマルションが挙げられる。また、アミノ変性シリコーンオイルは、エマルションの形で配合してもよい。アミノ変性シリコーンのエマルションは、機械的乳化（アミノ変性シリコーンと水との高剪断機械混合）、化学的乳化（アミノ変性シリコーンを水及び乳化剤で乳化）、若しくはこれらの組み合わせによって、又は乳化重合によっても調製することができる。
【００１９】
（メチルポリシロキサン類）
メチルポリシロキサン類としては、ジメチルポリシロキサン（INCI名：ジメチコーン）、メチルフェニルポリシロキサン、ヒドロキシ末端基を有するジメチルポリシロキサン（INCI名：ジメチコノール）、WO96/31188に記載されているわずかに架橋されたシリコーンガム等が挙げられる。メチルポリシロキサン類としては、数平均重合度が1000以上のものが好ましく、更には1500以上、特に2000以上20000未満のものが好ましい。
【００２０】
数平均重合度が1000以上である高重合シリコーンの市販品の具体例としては、SH200-1,000,000cs（東レ・ダウコーニング・シリコーン社）、TSF451-100MA（GE東芝シリコーン社）、BY11-026（東レ・ダウコーニング・シリコーン社；高重合シリコーンの低粘度シリコーンによる希釈溶液）、KF9008（信越シリコーン社；高重合シリコーンの環状シリコーンによる希釈溶液）、BY22-050A（東レ・ダウコーニング・シリコーン社；高重合シリコーンのカチオンエマルション）、BY22-060（東レ・ダウコーニング・シリコーン社；高重合シリコーンを低粘度シリコーンで希釈した溶液のカチオンエマルション）、BY22-020（東レ・ダウコーニング・シリコーン社；高重合シリコーンを流動パラフィンで希釈した溶液のカチオンエマルション）、KM904（信越シリコーン社；高重合シリコーンを低粘度シリコーンで希釈した溶液のカチオンエマルション）等が挙げられる。
【００２１】
アミノ変性シリコーン及びメチルポリシロキサン類は、成分(C)として２種以上を併用することもでき、なかでも、毛髪の均一な脱色・染色、湿潤時の柔らかさ、滑らかさ及び指の通り易さ、乾燥時の色の鮮明さや深み、ツヤ、柔らかさ、滑らかさ、ボリューム感（ボディ）、まとまり易さ及び保湿性という効果、並びにこれらの効果の持続性をより大きく与えるために、アミノ変性シリコーンと数平均重合度が1000以上のメチルポリシロキサン類（特にジメチルポリシロキサン）を併用するのが好ましい。成分(C)の含有量は、全組成物中の0.01〜30重量％が好ましく、更には0.05〜20重量％、特に0.1〜10重量％が好ましい。また、成分(C)に加え、任意成分としての他のシリコーン類を含めた各シリコーン類の含有比率は、次式で表される換算アミノ当量が、500〜10万g/molとなる範囲が好ましく、更には1000〜８万g/mol、特に2000〜５万g/molとなる範囲が好ましい。
【００２２】
換算アミノ当量（g/mol）＝〔全組成物１ｇ中の全シリコーン類の総重量（g/g）〕／〔全組成物１ｇ中のアミノ変性シリコーンのアミノ基、イミノ基及びアンモニウム基の総モル数（mol/g）〕。
【００２３】
ここで、「全組成物１ｇ中の全シリコーン類の総重量（g/g）」、並びに「全組成物１ｇ中のアミノ変性シリコーンのアミノ基、イミノ基及びアンモニウム基の総モル数（mol/g）」は、以下のようにして求める。
【００２４】
まず、第１剤と第２剤（三剤式の場合には、更に第３剤）の各々からシリコーン類を分画し、各剤中の全シリコーン類の総重量（ｇ）及びアミノ変性シリコーンのアミノ基、イミノ基及びアンモニウム基の総モル数（mol）を定量する。次に全組成物における各剤の混合比率を勘案し、全組成物１ｇ中の全シリコーン類の総重量（g/g）、並びに全組成物１ｇ中のアミノ変性シリコーンのアミノ基、イミノ基及びアンモニウム基の総モル数（mol/g）を算出する。最後に前記の換算アミノ当量算出式を用いて、換算アミノ当量（g/mol）を算出する。
【００２５】
〔成分(D)：カチオン性ポリマー〕
成分(D)のカチオン性ポリマーは、第１剤、第２剤及び第３剤のいずれか１以上に含まれる。カチオン性ポリマーとは、カチオン基又はカチオン基にイオン化され得る基を有するポリマーをいい、全体としてカチオン性となる両性ポリマーも含まれる。すなわち、カチオン性ポリマーとしては、ポリマー鎖の側鎖にアミノ基又はアンモニウム基を含むか、又はジアリル４級アンモニウム塩を構成単位として含む水溶液のもの、例えばカチオン化セルロース誘導体、カチオン性澱粉、カチオン化グアーガム誘導体、ジアリル４級アンモニウム塩の重合体又は共重合体、４級化ポリビニルピロリドン誘導体等が挙げられる。これらのうち、特にシャンプー時の柔らかさ、滑らかさ及び指の通り易さ、乾燥時のまとまり易さ及び保湿性という効果及び剤の安定性の点から、ジアリル４級アンモニウム塩を構成単位として含むポリマー、４級化ポリビニルピロリドン誘導体、カチオン化セルロース誘導体が好ましく、ジアリル４級アンモニウム塩の重合体又は共重合体、カチオン化セルロース誘導体がより好ましく、ジアリル４級アンモニウム塩の重合体又は共重合体が最も好ましい。
【００２６】
ジアリル４級アンモニウム塩の重合体の骨格としては、次の一般式(2)又は(3)で示されるものが好ましい。
【００２７】
【化２】
〔式中、Ｒ1及びＲ2は同一でも異なってもよく、水素原子、炭素数１〜18のアルキル基、アリール基（フェニル基等）、ヒドロキシアルキル基、アミドアルキル基、シアノアルキル基、アルコキシアルキル基又はカルボアルコキシアルキル基を示し、Ｒ3及びＲ4は同一でも異なってもよく、水素原子、炭素数１〜３のアルキル基又はフェニル基を示し、Ｘ-は陰イオン（塩化物イオン、臭化物イオン、ヨウ化物イオン、硫酸アニオン、スルホン酸アニオン、メチル硫酸アニオン、リン酸アニオン、硝酸アニオン等）を示す。〕
【００２９】
ジアリル４級アンモニウム塩と共重合体を構成するモノマーとしては、アクリル酸、メタクリル酸又はこれらの塩、アクリルアミドが挙げられ、特にアクリル酸、メタクリル酸又はこれらの塩が好ましい。アクリル酸、メタクリル酸又はこれらの塩とジアリル４級アンモニウム塩との共重合体は、ジアリル４級アンモニウム塩の構成比率が高く、全体としてカチオン性ポリマーとなる。
【００３０】
ジアリル４級アンモニウム塩の重合体又は共重合体の具体例としては、塩化ジメチルジアリルアンモニウム重合体（ポリクオタニウム-6，例えばマーコート100；ONDEO Nalco社）、塩化ジメチルジアリルアンモニウム／アクリル酸共重合体（ポリクオタニウム-22，例えばマーコート280，同295；ONDEO Nalco社）、塩化ジメチルジアリルアンモニウム／アクリルアミド共重合体（ポリクオタニウム-7，例えばマーコート550；ONDEO Nalco社）等が挙げられ、なかでもマーコート280、同295が好ましい。
【００３１】
４級化ポリビニルピロリドン誘導体としては、次の一般式(4)で表されるものが好ましい。
【００３２】
【化３】
〔式中、Ｒ5は水素原子又は炭素数１〜３のアルキル基、Ｒ6、Ｒ7及びＲ8は同一でも異なってもよく、水素原子、炭素数１〜４のアルキル基、ヒドロキシアルキル基、アミドアルキル基、シアノアルキル基、アルコキシアルキル基又はカルボアルコキシアルキル基を示し、Ｙは酸素原子又はイミノ基を示し、ｒは１〜10の整数を示し、ｓとｔはその和が20〜8000となる数を示し、Ｘ-は前記と同じ意味を示す。〕
【００３４】
本発明で用いられる４級化ポリビニルピロリドン誘導体の分子量としては１万〜200万、特に５万〜150万が好ましい。市販品としては、ガフコート734、同755、同755N（以上、アイエスピー・ジャパン社）等が挙げられる。
【００３５】
カチオン化セルロース誘導体としては、例えば次の一般式(5)で表されるものが好ましい。
【００３６】
【化４】
〔式中、Ａはアンヒドログルコース単位の残基を示し、ｆは50〜２万の整数を示し、Ｒ9は、それぞれ次の一般式(6)で表される置換基を示す。〕
【００３８】
【化５】
〔式中、Ｒ10及びＲ11は炭素数２又は３のアルキレン基を示し、ｇは０〜10の整数を示し、ｈは０〜３の整数を示し、ｉは０〜10の整数を示し、Ｒ12は炭素数１〜３のアルキレン基又はヒドロキシアルキレン基を、Ｒ13、Ｒ14及びＲ15は同一でも異なってもよく、炭素数10までのアルキル基、アリール基又はアラルキル基を示し、また式中の窒素原子を含む複素環を形成してもよい。Ｘ-は前記と同じ意味を示す。〕
【００４０】
カチオン化セルロース誘導体のカチオン置換度、すなわちアンヒドログルコース単位当りのｈの平均値は、0.01〜１、特に0.02〜0.5が好ましい。また、ｇ＋ｉの合計は平均１〜３である。カチオン置換度は、0.01未満では十分でなく、また１を超えてもかまわないが反応収率の点より１以下が好ましい。ここで用いるカチオン化セルロース誘導体の分子量は10万〜300万が好ましい。市販品としては、レオガードＧ、同ＧＰ（以上、ライオン社）、ポリマーJR-125、同JR-400、同JR-30M、同LR-400、同LR-30M（以上、ユニオンカーバイド社）等が挙げられる。その他のカチオン化セルロース誘導体としてはヒドロキシエチルセルロースジメチルジアリルアンモニウムクロリドが挙げられ、市販品としてはセルコートH-100、同L-200（以上、ナショナルスターチアンドケミカル社）等が挙げられる。
【００４１】
これらカチオン性ポリマーは、成分(D)として２種以上を併用してもよく、またその含有量は、全組成物中の0.001〜20重量％が好ましく、更には0.01〜10重量％、特に0.05〜５重量％が好ましい。
【００４２】
〔成分(E)：酸化染料中間体又は直接染料〕
本発明の組成物が、脱色剤組成物である場合には、染料は含有せず、染毛剤組成物である場合には、第１剤に酸化染料中間体又は直接染料を含有する。
【００４３】
（酸化染料中間体）
酸化染料中間体としては、通常染毛剤に使用されている公知のプレカーサー及びカプラーを用いることができる。プレカーサーとしては、例えばパラフェニレンジアミン、トルエン-2,5-ジアミン、2-クロロ-パラフェニレンジアミン、N-メトキシエチル-パラフェニレンジアミン、N,N-ビス(2-ヒドロキシエチル)-パラフェニレンジアミン、2-(2-ヒドロキシエチル)-パラフェニレンジアミン、2,6-ジメチル-パラフェニレンジアミン、4,4′-ジアミノジフェニルアミン、1,3-ビス(N-(2-ヒドロキシエチル)-N-(4-アミノフェニル)アミノ)-2-プロパノール、PEG-3,3,2′-パラフェニレンジアミン、パラアミノフェノール、パラメチルアミノフェノール、3-メチル-4-アミノフェノール、2-アミノメチル-4-アミノフェノール、2-(2-ヒドロキシエチルアミノメチル)-4-アミノフェノール、オルトアミノフェノール、2-アミノ-5-メチルフェノール、2-アミノ-6-メチルフェノール、2-アミノ-5-アセタミドフェノール、3,4-ジアミノ安息香酸、5-アミノサリチル酸、2,4,5,6-テトラアミノピリミジン、2,5,6-トリアミノ-4-ヒドロキシピリミジン、4,5-ジアミノ-1-(4′-クロロベンジル)ピラゾール、4,5-ジアミノ-1-ヒドロキシエチルピラゾールとこれらの塩等が挙げられる。
【００４４】
また、カプラーとしては、例えばメタフェニレンジアミン、2,4-ジアミノフェノキシエタノール、2-アミノ-4-(2-ヒドロキシエチルアミノ)アニソール、2,4-ジアミノ-5-メチルフェネトール、2,4-ジアミノ-5-(2-ヒドロキシエトキシ)トルエン、2,4-ジメトキシ-1,3-ジアミノベンゼン、2,6-ビス(2-ヒドロキシエチルアミノ)トルエン、2,4-ジアミノ-5-フルオロトルエン、1,3-ビス(2,4-ジアミノフェノキシ)プロパン、メタアミノフェノール、2-メチル-5-アミノフェノール、2-メチル-5-(2-ヒドロキシエチルアミノ)フェノール、2,4-ジクロロ-3-アミノフェノール、2-クロロ-3-アミノ-6-メチルフェノール、2-メチル-4-クロロ-5-アミノフェノール、N-シクロペンチル-メタアミノフェノール、2-メチル-4-メトキシ-5-(2-ヒドロキシエチルアミノ)フェノール、2-メチル-4-フルオロ-5-アミノフェノール、レゾルシン、2-メチルレゾルシン、4-クロロレゾルシン、1-ナフトール、1,5-ジヒドロキシナフタレン、1,7-ジヒドロキシナフタレン、2,7-ジヒドロキシナフタレン、2-イソプロピル-5-メチルフェノール、4-ヒドロキシインドール、5-ヒドロキシインドール、6-ヒドロキシインドール、7-ヒドロキシインドール、6-ヒドロキシベンゾモルホリン、3,4-メチレンジオキシフェノール、2-ブロモ-4,5-メチレンジオキシフェノール、3,4-メチレンジオキシアニリン、1-(2-ヒドロキシエチル)アミノ-3,4-メチレンジオキシベンゼン、2,6-ジヒドロキシ-3,4-ジメチルピリジン、2,6-ジメトキシ-3,5-ジアミノピリジン、2,3-ジアミノ-6-メトキシピリジン、2-メチルアミノ-3-アミノ-6-メトキシピリジン、2-アミノ-3-ヒドロキシピリジン、2,6-ジアミノピリジンとこれらの塩等が挙げられる。
【００４５】
プレカーサーとカプラーは、それぞれ２種以上を併用してもよく、その含有量は、それぞれ全組成物中の0.01〜５重量％、特に0.1〜４重量％が好ましい。
【００４６】
（直接染料）
直接染料としては、ニトロ染料、分散染料、塩基性染料等が挙げられる。
【００４７】
ニトロ染料としては、2-ニトロ-パラフェニレンジアミン、2-アミノ-6-クロロ-4-ニトロフェノール、3-ニトロ-パラヒドロキシエチルアミノフェノール、4-ニトロ-オルトフェニレンジアミン、4-アミノ-3-ニトロフェノール、4-ヒドロキシプロピルアミノ-3-ニトロフェノール、HCブルーNo.2、HCオレンジNo.1、HCレッドNo.1、HCイエローNo.2、HCイエローNo.4、HCイエローNo.5、HCレッドNo.3、N,N-ビス-(2-ヒドロキシエチル)-2-ニトロ-パラフェニレンジアミン等が挙げられ、分散染料としては、ディスパーズバイオレット１、ディスパーズブルー１、ディスパーズブラック９等が挙げられ、塩基性染料としては、ベーシックブルー99、ベーシックブラウン16、ベーシックブラウン17、ベーシックレッド76、ベーシックレッド51、ベーシックイエロー57、ベーシックイエロー87、ベーシックオレンジ31等が挙げられる。
【００４８】
直接染料は、２種以上を併用してもよく、酸化染料中間体と併用してもよい。またその含有量は、全組成中に0.001〜５重量％、特に0.01〜３重量％が好ましい。
【００４９】
〔成分(F)：酸化剤〕
酸化剤は、第２剤に含まれる（成分(F)としての酸化剤には、第３剤に使用される過硫酸塩は含まない）。酸化剤としては、過酸化水素、及び過酸化水素発生剤である過酸化尿素、過酸化メラミン、過ホウ酸ナトリウム、過ホウ酸カリウム、過炭酸ナトリウム、過炭酸カリウム等が挙げられ、特に過酸化水素が好ましい。酸化剤の含有量は、十分な脱色・染毛効果、及び毛髪損傷や頭皮刺激の低減の点から、過酸化水素換算量として、全組成物中の0.1〜10重量％、特に１〜５重量％が好ましい。
【００５０】
〔アンモニア〕
本発明の組成物には、更に成分(A)以外のアルカリ剤として、第１剤に、アンモニアを含有させることができる。アンモニアの含有量は、十分な脱色・染毛効果の点、及び毛髪損傷や頭皮刺激の低減の点から、全組成物中の0.01〜２重量％が好ましく、更には0.1〜１重量％、特に0.1〜0.5重量％が好ましい。
【００５１】
〔高級アルコール〕
本発明の組成物には、感触改善、安定性の観点から、第１剤、第２剤及び第３剤のいずれか１以上に、高級アルコールを含有させることが好ましい。これらは、界面活性剤と構造体を形成して分離を防ぐと共に、すすぎ時の感触を改善する効果がある。
【００５２】
高級アルコールとしては、炭素数８〜22、特に16〜22のものが好ましく、具体的には、セチルアルコール、ステアリルアルコール、ベヘニルアルコール等、及びこれらの混合物が挙げられる。特に感触面からベヘニルアルコールが好ましい。
【００５３】
高級アルコールは、２種以上を併用してもよく、またその含有量は、全組成物中の0.01〜20重量％、特に0.1〜10重量％が好ましい。
【００５４】
〔界面活性剤〕
本発明の酸化染毛剤又は脱色剤組成物は、乳化物であることが好ましく、シリコーン類や高級アルコール類の乳化のため、第１剤及び第２剤のいずれか一方又は両方に、界面活性剤を含有させることが好ましい。界面活性剤としては、安定性の観点より、非イオン界面活性剤、例えば炭素数12〜22の直鎖又は分岐鎖のアルキル基を有するアルコキシ化（例えばエトキシ化又はプロポキシ化）高級アルコール、具体的には、ポリオキシエチレン（２〜40）アルキルエーテル等を全組成物中に１〜40重量％程度、好ましくは２〜20重量％程度用いることができる。また、感触面を考慮すれば、更にモノ長鎖アルキルトリメチルアンモニウム塩等のカチオン界面活性剤を併用することが好ましい。ここで、モノ長鎖アルキルトリメチルアンモニウム塩としては、感触、乳化性能の面から、塩化ベヘニルトリメチルアンモニウムが好ましい。これらの使用比率は、（カチオン界面活性剤）／（非イオン界面活性剤＋カチオン界面活性剤）の重量比が、0.8以下、更に0.6以下、特に0.4以下であるのが好ましい。
【００５５】
界面活性剤と高級アルコールの重量比を、10：１〜１：10、好ましくは４：１〜１：８、特に１：１〜１：４とすると、混合前の第１剤又は第２剤をクリーム状にすることができる。
【００５６】
〔媒体〕
本発明の組成物には、媒体として、水及び必要により有機溶剤が使用される。有機溶剤としては、エタノール、2-プロパノール等の低級アルカノール類、ベンジルアルコール、ベンジルオキシエタノール等の芳香族アルコール類、プロピレングリコール、1,3-ブタンジオール、ジエチレングリコール、グリセリン等のポリオール類、エチルセロソルブ、ブチルセロソルブ、ベンジルセロソルブ等のセロソルブ類、エチルカルビトール、ブチルカルビトール等のカルビトール類が挙げられる。
【００５７】
〔剤型等〕
本発明の組成物は、現在広く利用されている酸化染毛剤又は脱色剤と同様に、アルカリ剤を含有する第１剤と過酸化水素等の酸化剤を含有する第２剤よりなる二剤型として、又は脱色力向上のため、更に第３剤として過硫酸塩（過硫酸アンモニウム、過硫酸カリウム、過硫酸ナトリウム等）等の造粒物からなる粉末状酸化剤を組み合わせてなる三剤型として提供される。第１剤及び第２剤の剤形は、例えば、液状、乳液状、クリーム状、ゲル状、ペースト状、ムース状などとすることができ、エアゾール形態とすることもできる。第１剤と第２剤（三剤型の場合は更に第３剤）を混合し、毛髪に塗布したときに液だれしにくいような粘度になることが望ましく、25℃、ヘリカルスタンド付きＢ型回転粘度計（B8R型粘度計，TOKIMEC社）で測定した粘度が2000〜10万mm2/sが好ましい。ここで、粘度は、ローターT-Cを用い、10rpm、１分間回転させた後の値とする。
【００５８】
〔pH〕
本発明の組成物のpH（25℃）は、脱色・染毛効果と皮膚刺激性の点から、使用時（混合時）において、８〜12、特に８〜10が好ましい。pH調整剤としては、前記のアルカリ剤のほか、水酸化ナトリウム、水酸化カリウム等の無機塩基、塩酸、リン酸等の無機酸、クエン酸、グリコール酸、乳酸等の有機酸、塩化アンモニウム等の塩酸塩、リン酸二水素一カリウム、リン酸一水素二ナトリウム等のリン酸塩等が挙げられる。
【００５９】
〔その他任意成分〕
本発明の組成物には、上記成分のほかに通常化粧品原料として用いられる他の成分を加えることができる。このような任意成分としては、成分(C)以外のシリコーン類（環状ポリシロキサン、フッ素変性シリコーン、アルコール変性シリコーン、ポリエーテル変性シリコーン、エポキシ変性シリコーン、アルキル変性シリコーン等）、炭化水素類、動植物油脂、高級脂肪酸類、成分(D)以外の天然又は合成の高分子、エーテル類、蛋白誘導体、加水分解蛋白、アミノ酸類、防腐剤、キレート剤、安定化剤、酸化防止剤、植物性抽出物、生薬抽出物、ビタミン類、香料、紫外線吸収剤が挙げられる。
【００６０】
〔処理法〕
本発明の組成物を用いて毛髪を染色又は脱色処理するには、例えば本発明の組成物の第１剤と第２剤（三剤型の場合は更に第３剤）を使用直前に混合した後、毛髪に適用し、所定時間放置後、洗い流し、乾燥すればよい。毛髪への適用温度は15〜45℃、適用時間は３〜45分間、特に５〜30分間が好ましい。この場合、まず酸化染毛剤又は脱色剤組成物を水で軽く洗い流した後、アニオン界面活性剤を含有するシャンプーを用いて洗髪し、次いで水洗すると、カチオン性ポリマーは適度に流出し、シリコーン類は適度に毛髪に残留し、良好なコンディショニング効果を示す。シャンプーとしては、ラウリルエトキシ（１〜３）硫酸ナトリウム等のアニオン界面活性剤を５〜20重量％程度含有する一般的な水性シャンプーが好適である。
【００６１】
【実施例】
実施例１
常法に従い、下記組成の第１剤及び第２剤からなる染毛剤組成物を調製した。
【００６２】
・第１剤（液状） （重量％）
モノエタノールアミン 6.0
炭酸カリウム 0.5
塩化ジメチルジアリルアンモニウム重合体液（40重量％）*1 1.0
アモジメチコーン（40重量％エマルジョン）*2 1.0
イソステアリルペンタエリスリルグリセリルエーテル 4.0
イソステアリルグリセリルエーテル 1.5
ポリオキシエチラン(20)オクチルドデシルエーテル 16.0
ポリオキシエチレン(9)オレイルエーテル 8.0
ポリオキシエチレン(3)トリデシルエーテル 14.0
塩化ステアリルトリメチルアンモニウム液（28重量％） 7.5
2-ベンジルオキシエタノール 15.0
95度エタノール 3.0
エデト酸四ナトリウム 0.1
アスコルビン酸 0.3
亜硫酸ナトリウム 0.5
トルエン-2,5-ジアミン 0.3
オルトアミノフェノール 0.5
レゾルシン 0.3
香料 適量
精製水 バランス
【００６３】
*1：マーコート100（ONDEO Nalco社）
*2：シリコーンSM8704C（東レ・ダウコーニング・シリコーン社）
【００６４】
・第２剤（液状） （重量％）
過酸化水素水（35重量％） 16.2
1-ヒドロキシエタン-1,1-ジホスホン酸液（60重量％） 0.1
塩化ステアリルトリメチルアンモニウム液（63重量％） 3.5
イソステアリルペンタエリスリルグリセリルエーテル 2.0
ポリオキシエチレン(40)セチルエーテル 0.5
ポリオキシエチレン(2)セチルエーテル 0.5
セトステアリルアルコール 3.0
リン酸 pH3.5とする量
精製水 バランス
【００６５】
第１剤と第２剤の混合比 １：1.5
混合後のpH 10
換算アミノ当量 1800（g/mol）
【００６６】
実施例２
常法に従い、下記組成の第１剤及び第２剤からなる染毛剤組成物を調製した。
【００６７】
*1：マーコート550（ONDEO Nalco社）
*2：マーコート280（ONDEO Nalco社）
*3：シリコーンSM8704C（東レ・ダウコーニング・シリコーン社）
【００６９】
・第２剤（クリーム状） （重量％）
過酸化水素水（35重量％） 16.2
8-キノリノール硫酸塩 0.04
ポリオキシエチレン(40)セチルエーテル 1.0
ポリオキシエチレン(2)セチルエーテル 1.0
セトステアリルアルコール 3.5
リン酸 pH3.5とする量
精製水 バランス
【００７０】
第１剤と第２剤の混合比 １：１
混合後のpH 10
換算アミノ当量 26550（g/mol）
【００７１】
実施例１及び２の染毛剤は、パーマ処理で損傷した部分と、未処理部分をほぼ均等な色に染める。また、パーマ処理した部分のシャンプー堅牢性に優れ、シャンプーを繰り返しても、未処理部分との色の差は広がらない。また、毛髪にしっとり感やまとまり易さを付与し、その効果も持続する。
【００７２】
【発明の効果】
本発明の酸化染毛剤又は脱色剤組成物は、毛髪の染色力・脱色力に優れると共に、毛髪に持続性のあるしっとり感とまとまり易さを付与し、また、毛髪の損傷度によらずほぼ均等な色に染色(脱色)することができ、シャンプー堅牢性（特に化学処理等により損傷の進んだ部分）にも優れる。[0001]
BACKGROUND OF THE INVENTION
The present invention is excellent in dyeing power and decoloring power of hair, imparts a long lasting moist feeling and ease of uniting to hair, and dyes (decolors) almost uniform color regardless of the degree of hair damage. The present invention also relates to an oxidative hair dye or a decoloring agent composition that is excellent in fastness to shampoo (particularly a portion that has been damaged by chemical treatment or the like).
[0002]
[Prior art]
For decolorization and dyeing of hair, an oxidative hair dye or decoloring agent that decolorizes or dyes hair by an oxidation reaction in the presence of an alkali agent, an oxidizing agent or the like is widely used.
[0003]
However, oxidative hair dyes or depigmenting agents are liable to cause damage to the hair, causing entanglement, hardness, or stiffness of hair when washed with water, shampooing or drying, and causing hair color and gloss to be lost or clumping. It gets worse.
[0004]
Therefore, in order to cope with these problems, an additive having a conditioning action is used. For example, by adding a silicone derivative such as amino-modified silicone oil, the hair is dyed in a deep color tone (see Patent Document 1), and by adding a polyorganosiloxane having an amino group, the hair is softly touched, It has been reported that hair setability is improved (see Patent Document 2), hair damage is prevented by adding highly polymerized silicone or a derivative thereof, and touch is improved (see Patent Documents 3 and 4). ing.
[0005]
However, the present condition is that a higher conditioning action is required for the oxidative hair dye or decoloring agent, and further improvement is also required in terms of dyeability or decoloring property.
[0006]
[Patent Document 1]
JP-A-57-192310 [Patent Document 2]
Japanese Patent Laid-Open No. 9-59136 [Patent Document 3]
Japanese Patent Laid-Open No. 63-313717 [Patent Document 4]
JP-A-4-59721
[Problems to be solved by the invention]
The present invention is excellent in dyeing power and decoloring power of hair, imparts a long lasting moist feeling and ease of uniting to hair, and dyes (decolors) almost uniform color regardless of the degree of hair damage. It is an object of the present invention to provide an oxidative hair dye or a decoloring agent composition that is excellent in shampoo fastness (particularly a portion that has been damaged by chemical treatment or the like).
[0008]
[Means for Solving the Problems]
The present inventor has found that the above-mentioned problems can be solved by using monoethanolamine, carbonate, specific silicones and a cationic polymer in combination in an oxidative hair dye or a decoloring agent composition.
[0009]
The present invention includes the following components (A) to (F)
(A) Monoethanolamine or hydroxyethylammonium ion
(B) Carbonate ion or bicarbonate ion
(C) Amino-modified silicone or methylpolysiloxane
(D) Cationic polymer
(E) Oxidative dye intermediate or direct dye (not included in the case of decolorizing agent)
(F) An oxidative hair dye or a decoloring agent composition containing an oxidant is provided.
[0010]
The present invention also provides a first agent containing components (A), (B) and (E) and a second agent containing component (F), or a third agent which is further a powdery oxidizing agent in the above composition. (Components (C) and (D) are contained in one or more of the first agent, second agent and third agent, respectively, and in the case of decolorization, none of component (E) is contained) It provides a method for dyeing or decoloring hair that is mixed immediately before, applied to hair, left for a predetermined time, and then washed away.
[0011]
DETAILED DESCRIPTION OF THE INVENTION
The oxidative hair dye or depigmenting agent composition of the present invention is a two-component type comprising a first agent containing an alkaline agent and a second agent containing an oxidizing agent, or further as a third agent such as persulfate. It takes the form of a three-part type in which a powdered oxidant composed of a granulated product is combined. Hereinafter, the “total composition” in the present invention refers to the whole composition immediately before use in which the first agent and the second agent are mixed in the case of the two-agent type, and in the case of the three-agent type, the first agent, The entire composition immediately before use in which the second agent and the third agent are mixed.
[0012]
[Component (A): Monoethanolamine or hydroxyethylammonium ion] The monoethanolamine or hydroxyethylammonium ion of component (A) is contained in the first agent and converted to the amount of monoethanolamine in the entire composition. It is preferable to contain 0.1 to 10% by weight, particularly 0.2 to 5% by weight. Examples of the hydroxyethylammonium ion source include monoethanolamine, monoethanolamine hydrochloride and the like. It is preferable that monoethanolamine and hydroxyethylammonium ion coexist to form a buffer system.
[0013]
[Component (B): Carbonate ion or bicarbonate ion]
The carbonate ion or hydrogen carbonate ion of component (B) is included in the first agent. Examples of the carbonate ion source or the bicarbonate ion source include ammonium carbonate, ammonium bicarbonate, sodium carbonate, sodium bicarbonate, potassium carbonate, potassium bicarbonate, guanidine carbonate and the like. It is preferable that carbonate ions and hydrogen carbonate ions coexist to form a buffer system. The content of the component (B) is preferably adjusted so that the molar ratio with the content of the component (A) is (A) / (B) = 0.1-10.
[0014]
[Component (C): amino-modified silicone or methylpolysiloxane]
The component (C) amino-modified silicone or methylpolysiloxane is contained in any one or more of the first agent, the second agent, and the third agent.
[0015]
(Amino-modified silicone)
The amino-modified silicone may have an amino group or an ammonium group, and may be either an amino-modified silicone oil in which all or part of the terminal hydroxyl group is blocked with a methyl group or the like, or amodimethicone in which the terminal is not blocked. . For example, preferable amino-modified silicones include those represented by the following general formula (1).
[0016]
[Chemical 1]
[Wherein R 0 represents a hydroxyl group, a hydrogen atom or R, R represents a substituted or unsubstituted monovalent hydrocarbon group having 1 to 20 carbon atoms, A represents R, a group —R ′-(NHCH 2 CH 2 ) n NH 2 , a group OR or a hydroxyl group, R ′ represents a divalent hydrocarbon group having 1 to 8 carbon atoms, n represents a number of 0 to 3, and p and q are sums of numbers averaged The number is from 10 to less than 1000, preferably from 30 to less than 1000, and more preferably from 40 to less than 800. The amino equivalent is 200 g / mol to 30,000 g / mol, preferably 500 g / mol to 10,000 g / mol, more preferably 600 g / mol to 5000 g / mol. ]
[0018]
Specific examples of suitable commercially available amino-modified silicones include SF8451C (Toray Dow Corning Silicone, viscosity 600 mm 2 / s, amino equivalent 1700 g / mol), SF8452C (Toray Dow Corning Silicone, viscosity 700 mm 2 / s, amino equivalent weight 6400g / mol), SF8457C (Dow Corning Toray silicone Co., viscosity 1200 mm 2 / s, amino equivalent weight 1800g / mol), KF8003 (GE Toshiba silicones Co., viscosity 1850 mm 2 / s, an amino equivalent of 2000 g / mol), amino modified silicone oils such as KF867 (GE Toshiba Silicone, viscosity 1300 mm 2 / s, amino equivalent 1700 g / mol), and amojime such as SM8704C (Toray Dow Corning Silicone, amino equivalent 1800 g / mol) A corn emulsion is mentioned. The amino-modified silicone oil may be blended in the form of an emulsion. Emulsions of amino-modified silicones can be obtained by mechanical emulsification (high shear mechanical mixing of amino-modified silicone and water), chemical emulsification (emulsification of amino-modified silicone with water and emulsifier), or combinations thereof, or by emulsion polymerization. Can be prepared.
[0019]
(Methylpolysiloxanes)
As methylpolysiloxanes, dimethylpolysiloxane (INCI name: dimethicone), methylphenylpolysiloxane, dimethylpolysiloxane having hydroxy end groups (INCI name: dimethiconol), slightly crosslinked as described in WO96 / 31188 Silicone gum etc. are mentioned. The methylpolysiloxanes preferably have a number average degree of polymerization of 1000 or more, more preferably 1500 or more, and particularly preferably 2000 or more and less than 20000.
[0020]
Specific examples of commercially available highly polymerized silicones with a number average degree of polymerization of 1000 or more include SH200-1,000,000cs (Toray Dow Corning Silicone), TSF451-100MA (GE Toshiba Silicone), BY11-026 (Toray)・ Dow Corning Silicone; diluted solution of highly polymerized silicone with low viscosity silicone), KF9008 (Shin-Etsu Silicone; diluted solution of highly polymerized silicone with cyclic silicone), BY22-050A (Toray Dow Corning Silicone; highly polymerized) Silicone cationic emulsion), BY22-060 (Toray Dow Corning Silicone; Cationic emulsion of high-polymerized silicone diluted with low-viscosity silicone), BY22-020 (Toray Dow Corning Silicone; high-polymerized silicone) Cationic emulsion of solution diluted with liquid paraffin), KM904 (Shin-Etsu Silicone Co., Ltd .; Takashige) And a cationic emulsion of a solution obtained by diluting a synthetic silicone with a low-viscosity silicone).
[0021]
Amino-modified silicones and methylpolysiloxanes can be used in combination of two or more as component (C). Among them, uniform decoloration / dyeing of hair, softness when wet, smoothness and ease of fingering In order to give the effect of vividness and depth of color when dry, gloss, softness, smoothness, volume (body), ease of uniting and moisturizing effect, and the sustainability of these effects, amino-modified silicone And methylpolysiloxanes having a number average degree of polymerization of 1000 or more (particularly dimethylpolysiloxane) are preferably used in combination. The content of component (C) is preferably from 0.01 to 30% by weight, more preferably from 0.05 to 20% by weight, particularly preferably from 0.1 to 10% by weight, based on the total composition. In addition to the component (C), the content ratio of each silicone including other silicones as an optional component has a range in which the converted amino equivalent represented by the following formula is 500 to 100,000 g / mol. Further, a range of 1000 to 80,000 g / mol, particularly 2000 to 50,000 g / mol is preferable.
[0022]
Equivalent amino equivalent (g / mol) = [total weight of all silicones in 1 g of total composition (g / g)] / [total of amino group, imino group and ammonium group of amino-modified silicone in 1 g of total composition Number of moles (mol / g)].
[0023]
Here, “total weight (g / g) of all silicones in 1 g of total composition” and “total number of moles of amino groups, imino groups and ammonium groups of amino-modified silicone in 1 g of total composition (mol / mol) g) ”is obtained as follows.
[0024]
First, silicones are fractionated from each of the first agent and the second agent (in the case of a three-agent type, the third agent), and the total weight (g) of all silicones in each agent and amino-modified silicone The total number of moles (mol) of the amino group, imino group and ammonium group is determined. Next, considering the mixing ratio of each agent in the whole composition, the total weight (g / g) of all silicones in 1 g of the whole composition, and the amino group, imino group of amino-modified silicone in 1 g of the whole composition, and Calculate the total number of moles of ammonium groups (mol / g). Finally, the converted amino equivalent (g / mol) is calculated using the converted amino equivalent calculation formula.
[0025]
[Component (D): Cationic polymer]
The cationic polymer of component (D) is contained in any one or more of the first agent, the second agent, and the third agent. The cationic polymer refers to a polymer having a cationic group or a group that can be ionized into a cationic group, and includes an amphoteric polymer that becomes cationic as a whole. That is, as the cationic polymer, an aqueous solution containing an amino group or an ammonium group in the side chain of the polymer chain or containing a diallyl quaternary ammonium salt as a structural unit, such as a cationized cellulose derivative, a cationic starch, a cationization Examples include guar gum derivatives, diallyl quaternary ammonium salt polymers or copolymers, and quaternized polyvinylpyrrolidone derivatives. Among these, diallyl quaternary ammonium salt is included as a structural unit particularly in terms of softness during shampooing, smoothness and ease of fingering, ease of packing during drying and moisturizing effect, and stability of the agent. Polymers, quaternized polyvinyl pyrrolidone derivatives, and cationized cellulose derivatives are preferable, diallyl quaternary ammonium salt polymers or copolymers, and cationized cellulose derivatives are more preferable, diallyl quaternary ammonium salt polymers or copolymers. Most preferred.
[0026]
As the skeleton of the diallyl quaternary ammonium salt polymer, one represented by the following general formula (2) or (3) is preferable.
[0027]
[Chemical formula 2]
[In the formula, R 1 and R 2 may be the same or different, and are a hydrogen atom, an alkyl group having 1 to 18 carbon atoms, an aryl group (such as a phenyl group), a hydroxyalkyl group, an amidoalkyl group, a cyanoalkyl group, an alkoxy group. Represents an alkyl group or a carboalkoxyalkyl group, R 3 and R 4 may be the same or different, each represents a hydrogen atom, an alkyl group having 1 to 3 carbon atoms or a phenyl group, and X − represents an anion (chloride ion, Bromide ion, iodide ion, sulfate anion, sulfonate anion, methyl sulfate anion, phosphate anion, nitrate anion, etc.). ]
[0029]
Examples of the monomer constituting the copolymer with the diallyl quaternary ammonium salt include acrylic acid, methacrylic acid or salts thereof, and acrylamide, and acrylic acid, methacrylic acid or salts thereof are particularly preferable. A copolymer of acrylic acid, methacrylic acid or a salt thereof and a diallyl quaternary ammonium salt has a high constituent ratio of diallyl quaternary ammonium salt, and becomes a cationic polymer as a whole.
[0030]
Specific examples of the polymer or copolymer of diallyl quaternary ammonium salt include dimethyldiallylammonium chloride polymer (Polyquaternium-6, such as Marquat 100; ONDEO Nalco), dimethyldiallylammonium chloride / acrylic acid copolymer (polyquaternium). -22, such as Marquat 280, 295; ONDEO Nalco), dimethyldiallylammonium chloride / acrylamide copolymer (Polyquaternium-7, such as Marquat 550; ONDEO Nalco), etc. preferable.
[0031]
As the quaternized polyvinylpyrrolidone derivative, those represented by the following general formula (4) are preferable.
[0032]
[Chemical 3]
[Wherein, R 5 is a hydrogen atom or an alkyl group having 1 to 3 carbon atoms, R 6 , R 7 and R 8 may be the same or different, and are a hydrogen atom, an alkyl group having 1 to 4 carbon atoms, or a hydroxyalkyl group. , An amidoalkyl group, a cyanoalkyl group, an alkoxyalkyl group or a carboalkoxyalkyl group, Y represents an oxygen atom or an imino group, r represents an integer of 1 to 10, and s and t represent a sum of 20 to 8000. X − represents the same meaning as described above. ]
[0034]
The molecular weight of the quaternized polyvinylpyrrolidone derivative used in the present invention is preferably 10,000 to 2,000,000, particularly preferably 50,000 to 1,500,000. Examples of commercially available products include Guff Coat 734, 755, and 755N (hereinafter referred to as IP Japan).
[0035]
As the cationized cellulose derivative, for example, those represented by the following general formula (5) are preferable.
[0036]
[Formula 4]
[Wherein, A represents a residue of an anhydroglucose unit, f represents an integer of 50 to 20,000, and R 9 represents a substituent represented by the following general formula (6). ]
[0038]
[Chemical formula 5]
[Wherein R 10 and R 11 represent an alkylene group having 2 or 3 carbon atoms, g represents an integer of 0 to 10, h represents an integer of 0 to 3, and i represents an integer of 0 to 10] , R 12 represents an alkylene group having 1 to 3 carbon atoms or a hydroxyalkylene group, R 13 , R 14 and R 15 may be the same or different and each represents an alkyl group, aryl group or aralkyl group having up to 10 carbon atoms, Moreover, you may form the heterocyclic ring containing the nitrogen atom in a formula. X − has the same meaning as described above. ]
[0040]
The cation substitution degree of the cationized cellulose derivative, that is, the average value of h per anhydroglucose unit is preferably 0.01 to 1, particularly 0.02 to 0.5. Moreover, the sum total of g + i is 1-3 on average. If the degree of cation substitution is less than 0.01, it is not sufficient and may exceed 1, but 1 or less is preferable from the viewpoint of reaction yield. The molecular weight of the cationized cellulose derivative used here is preferably 100,000 to 3,000,000. Commercially available products include Leo Guard G, GP (Lion), Polymer JR-125, JR-400, JR-30M, LR-400, LR-30M (Union Carbide). Can be mentioned. Examples of other cationized cellulose derivatives include hydroxyethyl cellulose dimethyl diallylammonium chloride, and examples of commercially available products include Cellcoat H-100 and L-200 (National Starch and Chemical Co., Ltd.).
[0041]
These cationic polymers may be used in combination of two or more as component (D), and the content thereof is preferably 0.001 to 20% by weight, more preferably 0.01 to 10% by weight, particularly 0.05. ~ 5 wt% is preferred.
[0042]
[Component (E): Oxidative dye intermediate or direct dye]
When the composition of the present invention is a depigmenting agent composition, it contains no dye, and when it is a hair dye composition, the first agent contains an oxidation dye intermediate or a direct dye.
[0043]
(Oxidized dye intermediate)
As the oxidation dye intermediate, known precursors and couplers usually used in hair dyes can be used. Examples of the precursor include paraphenylenediamine, toluene-2,5-diamine, 2-chloro-paraphenylenediamine, N-methoxyethyl-paraphenylenediamine, N, N-bis (2-hydroxyethyl) -paraphenylenediamine, 2- (2-hydroxyethyl) -paraphenylenediamine, 2,6-dimethyl-paraphenylenediamine, 4,4'-diaminodiphenylamine, 1,3-bis (N- (2-hydroxyethyl) -N- (4 -Aminophenyl) amino) -2-propanol, PEG-3,3,2'-paraphenylenediamine, paraaminophenol, paramethylaminophenol, 3-methyl-4-aminophenol, 2-aminomethyl-4-aminophenol , 2- (2-hydroxyethylaminomethyl) -4-aminophenol, orthoaminophenol, 2-amino-5-methylphenol, 2-amino-6-methylphenol, 2-amino-5-acetami Phenol, 3,4-diaminobenzoic acid, 5-aminosalicylic acid, 2,4,5,6-tetraaminopyrimidine, 2,5,6-triamino-4-hydroxypyrimidine, 4,5-diamino-1- (4 '-Chlorobenzyl) pyrazole, 4,5-diamino-1-hydroxyethylpyrazole and salts thereof.
[0044]
Examples of couplers include metaphenylenediamine, 2,4-diaminophenoxyethanol, 2-amino-4- (2-hydroxyethylamino) anisole, 2,4-diamino-5-methylphenetole, and 2,4-diamino. -5- (2-hydroxyethoxy) toluene, 2,4-dimethoxy-1,3-diaminobenzene, 2,6-bis (2-hydroxyethylamino) toluene, 2,4-diamino-5-fluorotoluene, 1 , 3-Bis (2,4-diaminophenoxy) propane, metaaminophenol, 2-methyl-5-aminophenol, 2-methyl-5- (2-hydroxyethylamino) phenol, 2,4-dichloro-3- Aminophenol, 2-chloro-3-amino-6-methylphenol, 2-methyl-4-chloro-5-aminophenol, N-cyclopentyl-metaaminophenol, 2-methyl-4-methoxy-5- (2- Hydroxyethylamino) phenol, 2-methyl-4-fluoro-5-a Nophenol, resorcin, 2-methylresorcin, 4-chlororesorcin, 1-naphthol, 1,5-dihydroxynaphthalene, 1,7-dihydroxynaphthalene, 2,7-dihydroxynaphthalene, 2-isopropyl-5-methylphenol, 4 -Hydroxyindole, 5-hydroxyindole, 6-hydroxyindole, 7-hydroxyindole, 6-hydroxybenzomorpholine, 3,4-methylenedioxyphenol, 2-bromo-4,5-methylenedioxyphenol, 3,4 -Methylenedioxyaniline, 1- (2-hydroxyethyl) amino-3,4-methylenedioxybenzene, 2,6-dihydroxy-3,4-dimethylpyridine, 2,6-dimethoxy-3,5-diaminopyridine 2,3-diamino-6-methoxypyridine, 2-methylamino-3-amino-6-methoxypyridine, 2-amino-3-hydroxypyridine, 2,6-diaminopyridine and these Salts and the like.
[0045]
Two or more precursors and couplers may be used in combination, and the content thereof is preferably 0.01 to 5% by weight, particularly preferably 0.1 to 4% by weight, based on the total composition.
[0046]
(Direct dye)
Examples of direct dyes include nitro dyes, disperse dyes, and basic dyes.
[0047]
Nitro dyes include 2-nitro-paraphenylenediamine, 2-amino-6-chloro-4-nitrophenol, 3-nitro-parahydroxyethylaminophenol, 4-nitro-orthophenylenediamine, 4-amino-3- Nitrophenol, 4-hydroxypropylamino-3-nitrophenol, HC Blue No.2, HC Orange No.1, HC Red No.1, HC Yellow No.2, HC Yellow No.4, HC Yellow No.5, HC Red No. 3, N, N-bis- (2-hydroxyethyl) -2-nitro-paraphenylenediamine, etc., and disperse dyes include Disperse Violet 1, Disperse Blue 1, Disperse Black 9 As basic dyes, basic blue 99, basic brown 16, basic brown 17, basic red 76, basic red 51, basic yellow 57, basic yellow 87, Basic Orange 31, etc.
[0048]
Two or more direct dyes may be used in combination, or may be used in combination with an oxidation dye intermediate. The content thereof is preferably 0.001 to 5% by weight, particularly 0.01 to 3% by weight in the total composition.
[0049]
[Component (F): Oxidizing agent]
The oxidizing agent is included in the second agent (the oxidizing agent as component (F) does not include the persulfate used in the third agent). Examples of the oxidizing agent include hydrogen peroxide and hydrogen peroxide generators such as urea peroxide, melamine peroxide, sodium perborate, potassium perborate, sodium percarbonate, and potassium percarbonate. Hydrogen is preferred. The content of the oxidizing agent is 0.1 to 10% by weight, particularly 1 to 5% by weight in the total composition as hydrogen peroxide equivalent from the viewpoint of sufficient decolorization and hair dyeing effect and reduction of hair damage and scalp irritation. % Is preferred.
[0050]
〔ammonia〕
In the composition of the present invention, ammonia can be contained in the first agent as an alkaline agent other than the component (A). The content of ammonia is preferably 0.01 to 2% by weight in the total composition, more preferably 0.1 to 1% by weight, particularly from the viewpoint of sufficient decolorization and hair dyeing effects, and reduction of hair damage and scalp irritation. 0.1 to 0.5% by weight is preferred.
[0051]
[Higher alcohol]
The composition of the present invention preferably contains a higher alcohol in any one or more of the first agent, the second agent, and the third agent from the viewpoint of improvement in feel and stability. These have the effect of forming a structure with a surfactant to prevent separation and improving the feel during rinsing.
[0052]
As the higher alcohol, those having 8 to 22 carbon atoms, particularly 16 to 22 carbon atoms are preferable, and specific examples thereof include cetyl alcohol, stearyl alcohol, behenyl alcohol, and the like, and mixtures thereof. In particular, behenyl alcohol is preferable in terms of touch.
[0053]
Two or more higher alcohols may be used in combination, and the content thereof is preferably 0.01 to 20% by weight, particularly 0.1 to 10% by weight, based on the total composition.
[0054]
[Surfactant]
The oxidative hair dye or decoloring agent composition of the present invention is preferably an emulsion, and in order to emulsify silicones and higher alcohols, either or both of the first agent and the second agent have a surface activity. It is preferable to contain an agent. As the surfactant, from the viewpoint of stability, a nonionic surfactant, for example, an alkoxylation (for example, ethoxylation or propoxylation) higher alcohol having a linear or branched alkyl group having 12 to 22 carbon atoms, specifically, In this case, polyoxyethylene (2-40) alkyl ether or the like can be used in the total composition at about 1 to 40% by weight, preferably about 2 to 20% by weight. In consideration of the feel, it is preferable to further use a cationic surfactant such as a mono long chain alkyltrimethylammonium salt. Here, as the mono long-chain alkyltrimethylammonium salt, behenyltrimethylammonium chloride is preferable from the viewpoint of feel and emulsification performance. The weight ratio of (cationic surfactant) / (nonionic surfactant + cationic surfactant) is preferably 0.8 or less, more preferably 0.6 or less, and particularly preferably 0.4 or less.
[0055]
When the weight ratio of the surfactant to the higher alcohol is 10: 1 to 1:10, preferably 4: 1 to 1: 8, particularly 1: 1 to 1: 4, the first agent or the second agent before mixing. Can be creamed.
[0056]
[Medium]
In the composition of the present invention, water and, if necessary, an organic solvent are used as a medium. Examples of organic solvents include lower alcohols such as ethanol and 2-propanol, aromatic alcohols such as benzyl alcohol and benzyloxyethanol, polyols such as propylene glycol, 1,3-butanediol, diethylene glycol, and glycerin, ethyl cellosolve, Examples thereof include cellosolves such as butyl cellosolve and benzyl cellosolve, and carbitols such as ethyl carbitol and butyl carbitol.
[0057]
[Dosage form etc.]
The composition of the present invention is a two-component composition comprising a first agent containing an alkaline agent and a second agent containing an oxidizing agent such as hydrogen peroxide, as well as the currently used oxidative hair dye or decoloring agent. As a three-part type that combines a powdered oxidizer consisting of a granulated product such as persulfate (ammonium persulfate, potassium persulfate, sodium persulfate, etc.) as a third agent for improving the decolorizing power as a mold Provided. The dosage forms of the first agent and the second agent can be, for example, liquid, emulsion, cream, gel, paste, mousse, etc., and can also be aerosol. It is desirable to mix the first agent and the second agent (or the third agent in the case of the three-agent type), and to make the viscosity difficult to spill when applied to the hair, 25 ° C, type B with helical stand The viscosity measured by a rotational viscometer (B8R type viscometer, TOKIMEC) is preferably 2,000 to 100,000 mm 2 / s. Here, the viscosity is a value after rotating at 10 rpm for 1 minute using a rotor TC.
[0058]
[PH]
The pH (25 ° C.) of the composition of the present invention is preferably 8 to 12, particularly 8 to 10 at the time of use (during mixing) from the viewpoint of decolorization / hair dyeing effect and skin irritation. As the pH adjuster, in addition to the above alkaline agents, inorganic bases such as sodium hydroxide and potassium hydroxide, inorganic acids such as hydrochloric acid and phosphoric acid, organic acids such as citric acid, glycolic acid and lactic acid, ammonium chloride and the like Examples thereof include phosphates such as hydrochloride, monopotassium dihydrogen phosphate, and disodium monohydrogen phosphate.
[0059]
[Other optional ingredients]
In addition to the above components, other components that are usually used as cosmetic raw materials can be added to the composition of the present invention. Examples of such optional components include silicones other than component (C) (cyclic polysiloxane, fluorine-modified silicone, alcohol-modified silicone, polyether-modified silicone, epoxy-modified silicone, alkyl-modified silicone, etc.), hydrocarbons, animal and vegetable oils and fats Higher fatty acids, natural or synthetic polymers other than component (D), ethers, protein derivatives, hydrolyzed proteins, amino acids, preservatives, chelating agents, stabilizers, antioxidants, plant extracts, Examples include herbal extracts, vitamins, fragrances, and UV absorbers.
[0060]
[Treatment method]
In order to dye or decolorize hair using the composition of the present invention, for example, the first agent and the second agent (or the third agent in the case of the three-component type) of the composition of the present invention are mixed immediately before use. Then, it may be applied to the hair, left for a predetermined time, rinsed and dried. The application temperature to the hair is preferably 15 to 45 ° C., and the application time is preferably 3 to 45 minutes, particularly 5 to 30 minutes. In this case, the oxidative hair dye or decoloring agent composition is first washed lightly with water, then washed with a shampoo containing an anionic surfactant, and then washed with water. Remains moderately in the hair and exhibits a good conditioning effect. As the shampoo, a general aqueous shampoo containing about 5 to 20% by weight of an anionic surfactant such as sodium lauryl ethoxy (1-3) sulfate is suitable.
[0061]
【Example】
Example 1
According to a conventional method, a hair dye composition comprising a first agent and a second agent having the following composition was prepared.
[0062]
・ First agent (liquid) (wt%)
Monoethanolamine 6.0
Potassium carbonate 0.5
Dimethyldiallylammonium chloride polymer solution (40% by weight) * 1 1.0
Amodimethicone (40% emulsion) * 2 1.0
Isostearyl pentaerythryl glyceryl ether 4.0
Isostearyl glyceryl ether 1.5
Polyoxyethylene (20) octyldodecyl ether 16.0
Polyoxyethylene (9) oleyl ether 8.0
Polyoxyethylene (3) tridecyl ether 14.0
Stearyltrimethylammonium chloride solution (28% by weight) 7.5
2-Benzyloxyethanol 15.0
95 degree ethanol 3.0
Edetate tetrasodium 0.1
Ascorbic acid 0.3
Sodium sulfite 0.5
Toluene-2,5-diamine 0.3
Orthoaminophenol 0.5
Resorcin 0.3
Perfume appropriate amount purified water balance [0063]
* 1: Marcote 100 (ONDEO Nalco)
* 2: Silicone SM8704C (Toray Dow Corning Silicone)
[0064]
・ Second agent (liquid) (wt%)
Hydrogen peroxide solution (35% by weight) 16.2
1-hydroxyethane-1,1-diphosphonic acid solution (60% by weight) 0.1
Stearyltrimethylammonium chloride solution (63% by weight) 3.5
Isostearyl pentaerythryl glyceryl ether 2.0
Polyoxyethylene (40) cetyl ether 0.5
Polyoxyethylene (2) cetyl ether 0.5
Cetostearyl alcohol 3.0
Phosphoric acid pH 3.5 purified water balance [0065]
Mixing ratio of 1st agent and 2nd agent 1: 1.5
PH 10 after mixing
Equivalent amino equivalent 1800 (g / mol)
[0066]
Example 2
According to a conventional method, a hair dye composition comprising a first agent and a second agent having the following composition was prepared.
[0067]
* 1: Marcote 550 (ONDEO Nalco)
* 2: Marcote 280 (ONDEO Nalco)
* 3: Silicone SM8704C (Toray Dow Corning Silicone)
[0069]
・ Second agent (cream) (wt%)
Hydrogen peroxide solution (35% by weight) 16.2
8-quinolinol sulfate 0.04
Polyoxyethylene (40) cetyl ether 1.0
Polyoxyethylene (2) cetyl ether 1.0
Cetostearyl alcohol 3.5
Amount of purified water to make phosphate pH 3.5 Balance [0070]
Mixing ratio of the first agent and the second agent 1: 1
PH 10 after mixing
Equivalent amino equivalent 26550 (g / mol)
[0071]
The hair dyes of Examples 1 and 2 dye the part damaged by the permanent treatment and the untreated part into a substantially uniform color. In addition, the shampoo of the perm-treated part is excellent in fastness, and even if the shampoo is repeated, the color difference from the untreated part does not widen. In addition, the hair is given a moist feeling and ease of uniting, and the effect is maintained.
[0072]
【The invention's effect】
The oxidative hair dye or depigmenting composition of the present invention is excellent in dyeing and decoloring power of hair, imparts a long lasting moist feeling and ease of uniting to hair, and does not depend on the degree of damage to hair. It can be dyed (decolored) to an almost uniform color and is excellent in shampoo fastness (particularly damaged by chemical treatment).
Claims (4)
(A)モノエタノールアミン又はヒドロキシエチルアンモニウムイオン
(B)炭酸イオン又は炭酸水素イオン
(C)アミノ変性シリコーン及び数平均重合度1000以上のメチルポリシロキサン類
(D)カチオン化セルロース誘導体、カチオン性澱粉、カチオン化グアーガム誘導体、ジアリル４級アンモニウム塩の重合体又は共重合体及び４級化ポリビニルピロリドン誘導体から選ばれるカチオン性ポリマー
(E)酸化染料中間体又は直接染料
(F)酸化剤
を含有し、次式
換算アミノ当量（g/mol）＝〔全組成物１ｇ中の全シリコーン類の総重量（g/g）〕／〔全組成物１ｇ中のアミノ変性シリコーンのアミノ基、イミノ基及びアンモニウム基の総モル数（mol/g）〕
で表される換算アミノ当量が1000 〜５万g/molである酸化染毛剤組成物。Next ingredient (A) ~ (F)
(A) Monoethanolamine or hydroxyethylammonium ion
(B) Carbonate ion or bicarbonate ion
(C) amino-modified silicone and methylpolysiloxane having a number average polymerization degree of 1000 or more
(D) Cationic polymer selected from cationic cellulose derivatives, cationic starch, cationic guar gum derivatives, diallyl quaternary ammonium salt polymers or copolymers, and quaternized polyvinylpyrrolidone derivatives
(E) oxidation dye intermediate or a direct dye fees
(F) Oxidizing agent, amino equivalent in terms of the following formula (g / mol) = [total weight of all silicones in 1 g of total composition (g / g)] / [amino-modified silicone in 1 g of total composition The total number of moles of amino group, imino group and ammonium group (mol / g)]
In represented in terms amino equivalent of 1,000 to 50,000 g / mol and is oxidizing hair dye sets Narubutsu.
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| JP2003190835A JP4116937B2 (en) | 2003-07-03 | 2003-07-03 | Oxidative hair dye or decolorant composition |
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| Application Number | Priority Date | Filing Date | Title |
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| JP2003190835A JP4116937B2 (en) | 2003-07-03 | 2003-07-03 | Oxidative hair dye or decolorant composition |
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| Publication Number | Publication Date |
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| JP2005023024A JP2005023024A (en) | 2005-01-27 |
| JP4116937B2 true JP4116937B2 (en) | 2008-07-09 |
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| JP2003190835A Expired - Fee Related JP4116937B2 (en) | 2003-07-03 | 2003-07-03 | Oxidative hair dye or decolorant composition |
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Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006232721A (en) * | 2005-02-24 | 2006-09-07 | Kao Corp | Hair treatment |
| JP2006347971A (en) * | 2005-06-17 | 2006-12-28 | Shiseido Co Ltd | Hair bleaching agent composition and hair dye composition |
| FR2925307B1 (en) * | 2007-12-21 | 2009-12-18 | Oreal | METHOD FOR DIRECT LIGHTENING OR OXIDATION COLORING IN THE PRESENCE OF A PARTICULAR ORGANIC AMINE AND DEVICE |
| BRPI0907074A2 (en) * | 2008-12-19 | 2013-05-07 | Oreal | keratin fiber bleaching or coloring process, anhydrous composition and multi-compartment device |
| JP2010215528A (en) * | 2009-03-13 | 2010-09-30 | Hoyu Co Ltd | Powder composition for hair color adjustment |
| WO2010137105A1 (en) * | 2009-05-25 | 2010-12-02 | Kawata Tsutomu | Color tone change inhibitor for oxidative hair dye |
| JP5563276B2 (en) * | 2009-10-27 | 2014-07-30 | ホーユー株式会社 | Hair dyeing and decoloring composition |
| JP5792735B2 (en) * | 2009-10-29 | 2015-10-14 | ザ プロクター アンド ギャンブルカンパニー | Hair conditioning composition comprising a cationic surfactant system, a direct dye, and a nonionic thickener |
| JP2012097025A (en) * | 2010-11-01 | 2012-05-24 | Hoyu Co Ltd | Hair cosmetic composition |
| JP5759149B2 (en) * | 2010-11-18 | 2015-08-05 | 株式会社マンダム | First agent composition and multi-component bleaching or oxidative hair dye |
| JP6196753B2 (en) * | 2011-05-18 | 2017-09-13 | ホーユー株式会社 | Oxidative hair dye composition |
| JP5236105B2 (en) * | 2012-08-09 | 2013-07-17 | ホーユー株式会社 | Hair cosmetic composition |
| TWI702965B (en) * | 2014-06-06 | 2020-09-01 | 日商花王股份有限公司 | Hair dye composition |
| EP3056304A1 (en) | 2015-02-16 | 2016-08-17 | Uvån Holding AB | A nozzle and a tundish arrangement for the granulation of molten material |
| JP2021521256A (en) * | 2018-05-03 | 2021-08-26 | エイチエフシー・プレステージ・インターナショナル・ホールディング・スウィッツァーランド・エスアーエールエル | Multi-component composition |
| DE102018222024A1 (en) * | 2018-12-18 | 2020-06-18 | Henkel Ag & Co. Kgaa | Process for coloring keratinous material with coloring agent and acidic aftertreatment agent |
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| JP2005023024A (en) | 2005-01-27 |
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