JP3865032B2 - Makeup cosmetics - Google Patents

Description

【００６５】
参考例５〜８、比較例２に示す処方の水中油型乳化ファンデーションを、表２に示す１〜６を均一に混合し、これに混合粉砕した７〜１２を加えて均一に分散させ、これに加熱溶解した１３〜２６を加えて均一に乳化することにより調製した。そして上記の評価について評価試験を行ない、その結果を「表２」に示した。
【００６６】
【表２】

【００６７】
上記の結果から本発明のメーキャップ化粧料はすべての評価項目において優れた効果を有していることが分かる。以下に本発明のその他の実施例を挙げる。
【００６８】
[実施例９] 固形パウダリーファンデーション
（１）タルク １５．０ 重量％
（２）セリサイト ２０．０
（３）マイカ １０．０
（４）ＰＭＭＡ球状粉末 １．０
（５）メチルシロキサン網状重合粉末 １．０
（６）窒化ホウ素 ９．０
（７）二酸化チタン １２．０
（８）酸化鉄 ６．０
（９）雲母チタン １．５
（１０）流動パラフィン 残 余
（１１）コハク酸ジエトキシエチル １０．０
（１２）セスキオレイン酸ソルビタン ２．０
（１３）防腐剤 適 量
（１４）香料 適 量
（製法及び評価）
１〜９の各成分を混合粉砕したところへ、１０〜１４の各成分を混合したものを加えて攪拌混合し、容器に成型して固形パウダリーファンデーションを得た。得られた固形パウダリーファンデーションは、使用感触、化粧もち効果、二次付着防止効果が優れていた。
【００６９】

（製法及び評価）
１２〜１９の各成分を均一に混合溶解させたものへ、１〜７の各成分を混合粉砕したものを加えて分散させた。次に均一に混合攪拌した８〜１１を加えて乳化し、容器に充填して油中水型乳化ファンデーションを得た。得られた油中水型乳化ファンデーションは、使用感触、化粧もち効果、二次付着防止効果が優れていた。
【００７０】

（製法及び評価）
１〜７の各成分を混合粉砕したところへ、８〜１３の各成分を混合したものを加えて混合攪拌し、容器に充填して白粉を得た。得られた白粉は、使用感触、化粧もち効果、二次付着防止効果が優れていた。
【００７１】

（製法及び評価）
１〜７の各成分を混合粉砕したところへ、８〜１３の各成分を混合したものを加えて攪拌混合し、中皿に成型してアイシャドーを得た。得られたアイシャドーは、使用感触、化粧もち効果、二次付着防止効果が優れていた。
【００７２】
[実施例１３] 口紅
（１）カルナバロウ １．０ 重量％
（２）キャンデリラロウ ２．０
（３）セレシン １０．０
（４）スクワラン 残 余
（５）トリイソオクタン酸グリセリン ９．０
（６）ジイソステアリン酸グリセリン １３．０
（７）コハク酸ジエトキシエチル ５．０
（８）シリコーン樹脂 ８．０
（９）ヒドロキシプロピル−β−シクロデキストリン １．０
（１０）マカデミアナッツ油脂肪酸コレステリル ３．５
（１１）合成ケイ酸ナトリウムマグネシウム ０．５
（１２）疎水性シリカ ０．５
（１３）精製水 ２．０
（１４）窒化ホウ素 １０．０
（１５）色剤 適 量
（１６）防腐剤 適 量
（１７）香料 適 量
（製法及び評価）
６０℃に加熱した１０に１１〜１２を分散させ、これに均一溶解した９と１３を加えて十分に攪拌する。別に加熱溶解させておいた１〜８に、これを加えて十分攪拌し、さらに１４〜１７を加えて分散攪拌し、その後容器に充填して口紅を得た。得られた口紅は、使用感触、化粧もち効果、二次付着防止効果が優れていた。
【００７３】
【発明の効果】
本発明によれば、メーキャップ化粧料にコハク酸ジエトキシエチルと窒化ホウ素粉末とを配合すると、使用感触、化粧もち効果、二次付着防止効果に優れたメーキャップ化粧料が提供される。[0001]
BACKGROUND OF THE INVENTION
The present invention relates to makeup cosmetics. More specifically, the present invention relates to a makeup cosmetic that is excellent in use feeling at the time of applying the cosmetic, has a good makeup, and has improved secondary adhesion to clothes and the like.
[0002]
[Prior art]
In addition to the “aesthetic role” that makes makeup appear more beautiful, makeup cosmetics have “functionality” such as makeup and secondary adhesion prevention, and “sensory role” that gives comfort.
[0003]
In order to enhance "functionality", it is generally known to add a silicone compound, but there was a tendency to impair "sensory roles" such as stickiness, tingling, and reduced lubricity during application. .
[0004]
In order to fulfill the “sensory role”, generally, spherical powder is blended to improve lubricity, and adhesion is enhanced by blending plate-like powders such as mica, talc and kaolin. However, when a large amount of spherical powder is blended, there is a drawback that the adhesion to the skin is lowered, and the moldability when the powder is pressed is deteriorated.
[0005]
Furthermore, when a large amount of plate-like powder such as mica, talc, and kaolin is blended, there is a problem that the lubricity is lowered, or the catalytic activity on the surface of the powder causes deterioration of fragrances and oils, resulting in odor changes. It was.
[0006]
[Problems to be solved by the invention]
Thus, in makeup cosmetics, it is very difficult to simultaneously provide a satisfactory feeling of use and an excellent makeup-holding effect, and also to prevent secondary adhesion, and makeup cosmetics having these two characteristics at the same time are provided. It has been demanded.
[0007]
As a result of intensive studies in view of the above-mentioned problems, the present inventors have made makeup cosmetics. Diethoxyethyl succinate The present invention has been completed by finding that a makeup cosmetic excellent in use feeling, makeup moisturizing effect, and secondary adhesion preventing effect can be obtained by blending and boron nitride powder.
[0008]
An object of the present invention is to provide a makeup cosmetic that is excellent in imparting a sufficiently satisfactory use feeling and having an excellent makeup and moisturizing effect, and further in preventing secondary adhesion.
[0009]
[Means for Solving the Problems]
That is, the present invention Diethoxyethyl succinate and boron nitride powder The makeup cosmetics characterized by containing this.
[0012]
DETAILED DESCRIPTION OF THE INVENTION
Hereinafter, the configuration of the present invention will be described in detail.
[0015]
When diethoxyethyl succinate is used in the present invention, In particular, a makeup cosmetic excellent in use feeling, makeup moisturizing effect and secondary adhesion preventing effect can be obtained.
[0016]
Diethoxyethyl succinate The blending amount of is not particularly limited, but is preferably 0.001 to 20.0% by weight, more preferably 0.1 to 10.0% by weight, based on the total amount of the makeup cosmetic. If it is less than 0.001% by weight, the effect is not exhibited, and if it exceeds 20.0% by weight, it becomes sticky after use.
[0017]
The boron nitride powder used in the present invention is a boron nitride powder usually used as a cosmetic raw material, and is generally a powder synthesized by the following method.
(1) Baking boron at about 1500 ° C. in a nitrogen stream.
(2) Baking ammonia and boron oxide, ammonium chloride and borax, or boric acid and urea at about 800 to 1600 ° C.
Crystal structures include hexagonal, wurtzite, rhombohedral, cubic, and the like. Cubic and wurtzite forms are mainly used as abrasives, and hexagonal forms are used as lubricants. The rhombohedral shape is synthesized only by a special manufacturing method. Among these, hexagonal boron nitride is preferable because it is easy to synthesize, can be easily sized by pulverization, etc., and has the best feeling when used in cosmetics.
[0018]
The boron nitride powder used in the present invention is obtained by stirring and washing a powder having the crystal structure as described above in a water-soluble organic solvent such as lower alcohol or acetone, an aqueous solution thereof, or an aqueous surfactant solution, at a low temperature (60 ° C. or lower). Desirable)-Obtained by drying under a low oxygen atmosphere (in a nitrogen stream or in a vacuum). The boron nitride powder thus obtained may be directly incorporated into cosmetics, or may be surfaced with substances such as higher fatty acids, oils and fats, waxes, silicone compounds, fluorine compounds, hydrocarbons, surfactants, dextrin fatty acid esters, etc. Processing may be performed.
[0019]
The average particle size of the boron nitride powder is not particularly limited, but is preferably a spherical equivalent average particle size of 0.1 to 30 μm. If it is smaller than 0.1 μm, the lubricity is impaired, and if it is larger than 30 μm, it feels rough and is not preferable.
[0020]
The compounding amount of boron nitride can be selected in a wide range of 0.1 to 99% by weight in the makeup cosmetic according to the target product. When the content is 0.1% by weight or less, the above-described effects cannot be obtained sufficiently, which is not preferable.
[0021]
In addition to the essential components described above, the makeup cosmetics of the present invention include other components usually used in cosmetics, such as powder components, liquid fats and oils, solid fats and oils, waxes, hydrocarbons, higher fatty acids, higher alcohols, esters, Silicone, anionic surfactant, cationic surfactant, amphoteric surfactant, nonionic surfactant, moisturizer, water-soluble polymer, thickener, film agent, UV absorber, sequestering agent, lower alcohol, Add polyhydric alcohol, sugar, amino acid, organic amine, polymer emulsion, pH adjuster, skin nutrient, vitamin, antioxidant, antioxidant aid, fragrance, water, etc. as needed and aim Depending on the dosage form, it can be produced by a conventional method. Specific ingredients that can be blended are listed below, but the makeup cosmetics of the present invention can be prepared by blending the above essential blending ingredients and one or more of the following ingredients.
[0022]
Examples of the powder component include inorganic powders (for example, talc, kaolin, mica, sericite, muscovite, phlogopite, synthetic mica, saucite, biotite, permiculite, magnesium carbonate, calcium carbonate, silicic acid. Aluminum, barium silicate, calcium silicate, magnesium silicate, strontium silicate, metal tungstate, magnesium, silica, zeolite, barium sulfate, calcined calcium sulfate (baked gypsum), calcium phosphate, fluorine apatite, hydroxyapatite, ceramic powder , Metal soap (eg, zinc myristate, calcium palmitate, aluminum stearate), boron nitride, etc .; organic powder (eg, polyamide resin powder (nylon powder), polyethylene powder, polymethyl methacrylate powder, polystyrene Powder, copolymer resin powder of styrene and acrylic acid, benzoguanamine resin powder, polytetrafluoroethylene powder, cellulose powder, etc.); inorganic white pigment (eg, titanium dioxide, zinc oxide, etc.); inorganic red pigment (eg, Iron oxide (Bengara), iron titanate, etc .; Inorganic brown pigments (eg, γ-iron oxide, etc.); Inorganic yellow pigments (eg, yellow iron oxide, loess, etc.); Inorganic black pigments (eg, black oxide) Iron, low-order titanium oxide, etc.); inorganic purple pigments (eg, mango violet, cobalt violet, etc.); inorganic green pigments (eg, chromium oxide, chromium hydroxide, cobalt titanate, etc.); inorganic blue pigments (eg, Pearl pigments (eg titanium oxide coated mica, titanium oxide coated bismuth oxychloride, titanium oxide coated talc, colored oxidation) Tan-coated mica, bismuth oxychloride, fish scale foil, etc.); metal powder pigments (eg, aluminum powder, copper powder, etc.); organic pigments such as zirconium, barium or aluminum lake (eg, red 201, red 202, red 204) No., red 205, red 220, red 226, red 228, red 405, orange 203, orange 204, yellow 205, yellow 401, and blue 404, organic pigments such as red 3 , Red 104, Red 106, Red 227, Red 230, Red 401, Red 505, Orange 205, Yellow 4, Yellow 5, Yellow 202, Yellow 203, Green 3 and Blue No. 1 etc.); natural pigments (for example, chlorophyll, β-carotene, etc.) and the like.
[0023]
Examples of liquid oils include avocado oil, camellia oil, turtle oil, macadamia nut oil, corn oil, mink oil, olive oil, rapeseed oil, egg yolk oil, sesame oil, persic oil, wheat germ oil, southern castor oil, castor oil, linseed oil , Safflower oil, cottonseed oil, eno oil, soybean oil, peanut oil, tea seed oil, kaya oil, rice bran oil, cinnagiri oil, Japanese kiri oil, jojoba oil, germ oil, triglycerin and the like.
[0024]
Examples of the solid fat include cacao butter, palm oil, horse fat, hydrogenated palm oil, palm oil, beef tallow, sheep fat, hydrogenated beef tallow, palm kernel oil, pork fat, beef bone fat, owl kernel oil, hydrogenated oil, cattle Leg fats, moles, hydrogenated castor oil and the like.
[0025]
Examples of the wax include beeswax, candelilla wax, cotton wax, carnauba wax, bayberry wax, ibota wax, whale wax, montan wax, nuka wax, lanolin, kapok wax, lanolin acetate, liquid lanolin, sugar cane wax, lanolin fatty acid isopropyl, hexyl laurate, reduced lanolin, Examples include jojoba wax, hard lanolin, shellac wax, POE lanolin alcohol ether, POE lanolin alcohol acetate, POE cholesterol ether, lanolin fatty acid polyethylene glycol, and POE hydrogenated lanolin alcohol ether.
[0026]
Examples of the hydrocarbon include liquid paraffin, ozokerite, squalane, pristane, paraffin, ceresin, squalene, petrolatum, and microcrystalline wax.
[0027]
Examples of higher fatty acids include lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, oleic acid, undecylenic acid, toluic acid, isostearic acid, linoleic acid, linolenic acid, eicosapentaenoic acid (EPA), docosahexaenoic acid ( DHA) and the like.
[0028]
Examples of higher alcohols include linear alcohols (eg, lauryl alcohol, cetyl alcohol, stearyl alcohol, behenyl alcohol, myristyl alcohol, oleyl alcohol, cetostearyl alcohol); branched chain alcohols (eg, monostearyl glycerin ether (batyl alcohol) ), 2-decyltetradecinol, lanolin alcohol, cholesterol, phytosterol, hexyl decanol, isostearyl alcohol, octyldodecanol and the like.
[0029]
Synthetic ester oils include isopropyl myristate, cetyl octanoate, octyldodecyl myristate, isopropyl palmitate, butyl stearate, hexyl laurate, myristyl myristate, decyl oleate, hexyl decyl dimethyloctanoate, cetyl lactate, myristyl lactate Lanolin acetate, isocetyl stearate, isocetyl isostearate, cholesteryl 12-hydroxystearate, ethylene glycol di-2-ethylhexanoate, dipentaerythritol fatty acid ester, monoisostearate N-alkyl glycol, neopentyl glycol dicaprate, apple Acid diisostearyl, di-2-heptylundecanoic acid glycerin, tri-2-ethylhexanoic acid trimethylolpropane, triisostearic acid trimethylo Propane, tetra-2-ethylhexanoate pentaerythritol, glycerol tri-2-ethylhexanoate, glycerol trioctanoate, glycerol triisopalmitate, trimethylolpropane triisostearate, cetyl 2-ethylhexanoate, 2-ethylhexyl palmi Tate, glyceryl trimyristate, glyceride tri-2-heptylundecanoate, castor oil fatty acid methyl ester, oleyl oleate, acetoglyceride, 2-heptylundecyl palmitate, diisobutyl adipate, N-lauroyl-L-glutamic acid-2 -Octyldodecyl ester, di-2-heptylundecyl adipate, ethyl laurate, di-2-ethylhexyl sebacate, 2-hexyldecyl myristate, 2-hexyldecyl palmitate, 2-hexyldecyl adipate Le, diisopropyl sebacate, 2-ethylhexyl succinate, and triethyl citrate.
[0030]
Examples of silicone include linear polysiloxane (for example, dimethylpolysiloxane, methylphenylpolysiloxane, diphenylpolysiloxane, etc.); cyclic polysiloxane (for example, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexa Siloxane, etc.), silicone resins forming a three-dimensional network structure, silicone rubber, various modified polysiloxanes (amino-modified polysiloxane, polyether-modified polysiloxane, alkyl-modified polysiloxane, fluorine-modified polysiloxane, etc.) and the like. .
[0031]
Anionic surfactants include, for example, fatty acid soaps (eg, sodium laurate, sodium palmitate, etc.); higher alkyl sulfates (eg, sodium lauryl sulfate, potassium lauryl sulfate, etc.); alkyl ether sulfates (eg, POE-lauryl sulfate triethanolamine, POE-sodium lauryl sulfate, etc.); N-acyl sarcosine acids (eg, sodium lauroyl sarcosine, etc.); higher fatty acid amide sulfonates (eg, sodium N-myristoyl-N-methyl taurate, palm Oil fatty acid methyl tauride sodium, lauryl methyl tauride sodium, etc .; phosphate ester salt (POE-oleyl ether sodium phosphate, POE-stearyl ether phosphate, etc.); sulfosuccinate (eg, di-2-ethylhexyl sulfo) Sodium succinate, monolauroyl monoethanolamide sodium polyoxyethylene sulfosuccinate, sodium lauryl polypropylene glycol sulfosuccinate, etc.); alkyl benzene sulfonates (eg, sodium linear dodecyl benzene sulfonate, triethanol amine linear dodecyl benzene sulfonate, linear dodecyl) Higher fatty acid ester sulfates (eg, hydrogenated coconut oil fatty acid sodium glycerol sulfate); N-acyl glutamate (eg, monosodium N-lauroyl glutamate, disodium N-stearoyl glutamate, N-myristoyl) -L-glutamic acid monosodium, etc.); sulfated oil (eg funnel oil); POE-alkyl ether carboxylic acid; POE-alkyl allyl ether Α-olefin sulfonates; higher fatty acid ester sulfonates; secondary alcohol sulfates; higher fatty acid alkylolamide sulfates; lauroyl monoethanolamide sodium succinate; N-palmitoyl aspartate ditriethanolamine ; Sodium caseinate and the like.
[0032]
Examples of the cationic surfactant include alkyltrimethylammonium salts (eg, stearyltrimethylammonium chloride, lauryltrimethylammonium chloride, etc.); alkylpyridinium salts (eg, cetylpyridinium chloride, etc.); distearyldimethylammonium dialkyldimethylammonium chloride; Poly (N, N'-dimethyl-3,5-methylenepiperidinium chloride); alkyl quaternary ammonium salt; alkyldimethylbenzylammonium salt; alkylisoquinolinium salt; dialkyl morpholinium salt; POE-alkylamine; Examples include alkylamine salts; polyamine fatty acid derivatives; amyl alcohol fatty acid derivatives; benzalkonium chloride; benzethonium chloride and the like.
[0033]
Examples of amphoteric surfactants include imidazoline-based amphoteric surfactants (eg, 2-undecyl-N, N, N- (hydroxyethylcarboxymethyl) -2-imidazoline sodium, 2-cocoyl-2-imidazolinium hydroxide). Side-1-carboxyethyloxy disodium salt, etc.); betaine surfactants (for example, 2-heptadecyl-N-carboxymethyl-N-hydroxyethylimidazolinium betaine, lauryldimethylaminoacetic acid betaine, alkylbetaine, amide betaine) , Sulfobetaine, etc.).
[0034]
Examples of the lipophilic nonionic surfactant include sorbitan fatty acid esters (for example, sorbitan monooleate, sorbitan monoisostearate, sorbitan monolaurate, sorbitan monopalmitate, sorbitan monostearate, sorbitan sesquioleate, Sorbitan trioleate, diglycerol sorbitan penta-2-ethylhexylate, diglycerol sorbitan tetra-2-ethylhexylate); glycerin polyglycerin fatty acids (eg mono cottonseed oil fatty acid glycerin, monoerucic acid glycerin, sesquioleate glycerin, monostearin) Glycerin acid, α, α'-oleic acid pyroglutamate glycerin, monostearic acid glycerin malic acid, etc.); propylene glycol fatty acid esters (eg monostearies) Propylene glycolate, etc.); hardened castor oil derivative; glycerin alkyl ether, etc.
[0035]
Examples of hydrophilic nonionic surfactants include POE-sorbitan fatty acid esters (for example, POE-sorbitan monooleate, POE-sorbitan monostearate, POE-sorbitan monooleate, POE-sorbitan tetraoleate, etc.); POE sorbite fatty acid esters (eg, POE-sorbite monolaurate, POE-sorbite monooleate, POE-sorbite pentaoleate, POE-sorbite monostearate, etc.); POE-glycerin fatty acid esters (eg, POE-glycerin) Monostearate, POE-glycerol monoisostearate, POE-monooleate such as POE-glycerol triisostearate, etc.); POE-fatty acid esters (for example, POE-distearate, POE-monodiolate, ethylene glycol distearate, etc.); POE-alkyl ethers (eg POE- Uril ether, POE-oleyl ether, POE-stearyl ether, POE-behenyl ether, POE-2-octyldodecyl ether, POE-cholestanol ether, etc.); Pluronic type (for example, Pluronic, etc.); POE / POP-alkyl ether (For example, POE / POP-cetyl ether, POE / POP-2-decyltetradecyl ether, POE / POP-monobutyl ether, POE / POP-hydrogenated lanolin, POE / POP-glycerin ether, etc.); Tetra POE / tetra POP-ethylenediamine condensates (eg Tetronic); POE-castor oil hardened castor oil derivatives (eg POE-castor oil, POE-hardened castor oil, POE-hardened castor oil monoisostearate, POE-hardened castor Oil triisostearate, POE-hardened castor oil monopyroglutamic acid monoisostearic acid diester, POE-hardened castor oil maleic acid, etc.); PO E-beeswax lanolin derivatives (eg POE-sorbite beeswax); alkanolamides (eg coconut oil fatty acid diethanolamide, lauric acid monoethanolamide, fatty acid isopropanolamide, etc.); POE-propylene glycol fatty acid ester; POE-alkylamine POE-fatty acid amide; sucrose fatty acid ester; alkyl ethoxydimethylamine oxide; trioleyl phosphate and the like.
[0036]
Examples of humectants include polyethylene glycol, propylene glycol, glycerin, 1,3-butylene glycol, xylitol, sorbitol, maltitol, chondroitin sulfate, hyaluronic acid, mucoitin sulfate, caronic acid, atelocollagen, cholesteryl-12-hydroxystearate Sodium lactate, bile salt, dl-pyrrolidone carboxylate, short-chain soluble collagen, diglycerin (EO) PO adduct, Izayoi rose extract, yarrow extract, merirot extract and the like.
[0037]
Examples of natural water-soluble polymers include plant-based polymers (for example, gum arabic, gum tragacanth, galactan, guar gum, carob gum, caraya gum, carrageenan, pectin, agar, quince seed (malmello), alge colloid (guckweed extract), starch (Rice, corn, potato, wheat), glycyrrhizic acid); microbial polymers (eg, xanthan gum, dextran, succinoglucan, bullulan, etc.); animal polymers (eg, collagen, casein, albumin, gelatin, etc.), etc. Is mentioned.
[0038]
Semi-synthetic water-soluble polymers include, for example, starch polymers (eg, carboxymethyl starch, methylhydroxypropyl starch, etc.); cellulose polymers (methylcellulose, ethylcellulose, methylhydroxypropylcellulose, hydroxyethylcellulose, sodium cellulose sulfate) Hydroxypropylcellulose, carboxymethylcellulose, sodium carboxymethylcellulose, crystalline cellulose, cellulose powder and the like); alginic acid polymers (for example, sodium alginate, propylene glycol alginate, etc.) and the like.
[0039]
Synthetic water-soluble polymers include, for example, vinyl polymers (eg, polyvinyl alcohol, polyvinyl methyl ether, polyvinyl pyrrolidone, carboxyvinyl polymer); polyoxyethylene polymers (eg, polyethylene glycol 20,000, 40,000, 60,000). Polyoxyethylene polyoxypropylene copolymer, etc.); acrylic polymers (for example, sodium polyacrylate, polyethyl acrylate, polyacrylamide, etc.); polyethyleneimine; cationic polymers, and the like.
[0040]
Examples of thickeners include gum arabic, carrageenan, caraya gum, gum tragacanth, carob gum, quince seed (malmello), casein, dextrin, gelatin, sodium pectate, sodium alginate, methylcellulose, ethylcellulose, CMC, hydroxyethylcellulose, hydroxypropyl Cellulose, PVA, PVM, PVP, sodium polyacrylate, carboxyvinyl polymer, locust bean gum, guar gum, tamarind gum, cellulose dialkyldimethylammonium sulfate, xanthan gum, magnesium aluminum silicate, bentonite, hectorite, silicate A1Mg (vee gum), Examples thereof include laponite and silicic anhydride.
[0041]
Examples of UV absorbers include benzoic acid UV absorbers (eg, paraaminobenzoic acid (hereinafter abbreviated as PABA), PABA monoglycerin ester, N, N-dipropoxy PABA ethyl ester, N, N-diethoxy PABA ethyl ester. N, N-dimethyl PABA ethyl ester, N, N-dimethyl PABA butyl ester, N, N-dimethyl PABA ethyl ester, etc.); anthranilic acid-based ultraviolet absorbers (eg, homomenthyl-N-acetylanthranylate, etc.); Salicylic acid ultraviolet absorbers (for example, amyl salicylate, menthyl salicylate, homomenthyl salicylate, octyl salicylate, phenyl salicylate, benzyl salicylate, p-isopropanol phenyl salicylate, etc.); cinnamic acid ultraviolet absorbers (for example, octylcinnamate, ethyl- 4-isopropyl cinnamate, methyl -2,5-diisopropylcinnamate, ethyl-2,4-diisopropylcinnamate, methyl-2,4-diisopropylcinnamate, propyl-p-methoxycinnamate, isopropyl-p-methoxycinnamate, isoamyl-p-methoxy Cinnamate, octyl-p-methoxycinnamate (2-ethylhexyl-p-methoxycinnamate), 2-ethoxyethyl-p-methoxycinnamate, cyclohexyl-p-methoxycinnamate, ethyl-α-cyano-β-phenyl Cinnamate, 2-ethylhexyl-α-cyano-β-phenylcinnamate, glyceryl mono-2-ethylhexanoyl-diparamethoxycinnamate, etc.); benzophenone UV absorbers (for example, 2,4-dihydroxybenzophenone, 2 , 2'-dihydroxy-4-methoxybenzophenone, 2,2'-dihydroxy-4,4'-dimethoxybenzophenone, 2 , 2 ', 4,4'-Tetrahydroxybenzophenone, 2-hydroxy-4-methoxybenzophenone, 2-hydroxy-4-methoxy-4'-methylbenzophenone, 2-hydroxy-4-methoxybenzophenone-5-sulfonate 4-phenylbenzophenone, 2-ethylhexyl-4′-phenyl-benzophenone-2-carboxylate, 2-hydroxy-4-n-octoxybenzophenone, 4-hydroxy-3-carboxybenzophenone, etc.); 3- (4 ′ -Methylbenzylidene) -d, l-camphor, 3-benzylidene-d, l-camphor; 2-phenyl-5-methylbenzoxazole; 2,2'-hydroxy-5-methylphenylbenzotriazole; 2- (2 '-Hydroxy-5'-t-octylphenyl) benzotriazole; 2- (2'-hydroxy-5'-methylphenylbenzotriazole;dibenzalazine;dianisoylmethane;4-methoxy-4'-t-butyldibenzoylMethane; 5- (3,3-dimethyl-2-norbornylidene) -3-pentan-2-one and the like.
[0042]
Examples of the sequestering agent include 1-hydroxyethane-1,1-diphosphonic acid, 1-hydroxyethane-1,1-diphosphonic acid tetrasodium salt, disodium edetate, trisodium edetate, and tetrasodium edetate. Sodium citrate, sodium polyphosphate, sodium metaphosphate, gluconic acid, phosphoric acid, citric acid, ascorbic acid, succinic acid, edetic acid, trisodium ethylenediaminehydroxyethyl triacetate and the like.
[0043]
Examples of the lower alcohol include ethanol, propanol, isopropanol, isobutyl alcohol, t-butyl alcohol and the like.
[0044]
Examples of the polyhydric alcohol include divalent alcohols (for example, ethylene glycol, propylene glycol, trimethylene glycol, 1,2-butylene glycol, 1,3-butylene glycol, tetramethylene glycol, 2,3-butylene glycol, Pentamethylene glycol, 2-butene-1,4-diol, hexylene glycol, octylene glycol, etc.); trivalent alcohol (eg, glycerin, trimethylolpropane, etc.); tetravalent alcohol (eg, 1,2,6) Pentaerythritol such as hexanetriol); pentahydric alcohol (eg, xylitol, etc.); hexavalent alcohol (eg, sorbitol, mannitol, etc.); polyhydric alcohol polymer (eg, diethylene glycol, dipropylene glycol, triethylene glycol, polypropylene Glycol, tetraethylene glycol, diglycerin, polyethylene glycol, triglycerin, tetraglycerin, polyglycerin, etc.); divalent alcohol alkyl ethers (for example, ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, ethylene) Glycol monophenyl ether, ethylene glycol monohexyl ether, ethylene glycol mono 2-methylhexyl ether, ethylene glycol isoamyl ether, ethylene glycol benzyl ether, ethylene glycol isopropyl ether, ethylene glycol dimethyl ether, ethylene glycol diethyl ether, ethylene glycol dibutyl ether, etc.) ; Dihydric alcohol alkyl ester Tellurium (for example, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol monobutyl ether, diethylene glycol dimethyl ether, diethylene glycol diethyl ether, diethylene glycol butyl ether, diethylene glycol methyl ethyl ether, triethylene glycol monomethyl ether, triethylene glycol monoethyl ether, propylene glycol monomethyl ether , Propylene glycol monoethyl ether, propylene glycol monobutyl ether, propylene glycol isopropyl ether, dipropylene glycol methyl ether, dipropylene glycol ethyl ether, dipropylene glycol butyl ether, etc.); divalent alcohol Ether esters (eg, ethylene glycol monomethyl ether acetate, ethylene glycol monoethyl ether acetate, ethylene glycol monobutyl ether acetate, ethylene glycol monophenyl ether acetate, ethylene glycol diazinate, ethylene glycol disuccinate, diethylene glycol monoethyl ether acetate, diethylene glycol) Monobutyl ether acetate, propylene glycol monomethyl ether acetate, propylene glycol monoethyl ether acetate, propylene glycol monopropyl ether acetate, propylene glycol monophenyl ether acetate, etc .; glycerin monoalkyl ethers (eg, xyl alcohol, ceralkyl alcohol) Sugar alcohol (eg, sorbitol, maltitol, maltotriose, mannitol, sucrose, erythritol, glucose, fructose, amylolytic sugar, maltose, xylitolose, amylolytic sugar reducing alcohol, etc.); Solid; tetrahydrofurfuryl alcohol; POE-tetrahydrofurfuryl alcohol; POP-butyl ether; POP / POE-butyl ether; tripolyoxypropylene glycerin ether; POP-glycerin ether; POP-glycerin ether phosphate; POP / POE-pentaneerythritol Examples include ether and polyglycerin.
[0045]
Monosaccharides include, for example, tricarbon sugars (eg, D-glyceryl aldehyde, dihydroxyacetone, etc.); tetracarbon sugars (eg, D-erythrose, D-erythrulose, D-treose, erythritol, etc.); pentose sugars (eg, , L-arabinose, D-xylose, L-lyxose, D-arabinose, D-ribose, D-ribulose, D-xylulose, L-xylulose, etc .; hexose (eg, D-glucose, D-talose, D) -Bucicose, D-galactose, D-fructose, L-galactose, L-mannose, D-tagatose, etc.); pentose sugar (eg, aldheptose, heproose, etc.); octose sugar (eg, octulose, etc.); For example, 2-deoxy-D-ribose, 6-deoxy-L-galactose, 6-deoxy-L-mannose, etc .; amino sugar (eg, D-glucosamine, D-galactosamine, shea Acid, Aminouron acid, muramic acid); uronic acid (e.g., D- glucuronic acid, D- mannuronic acid, L- guluronic acid, D- galacturonic acid, L- iduronic acid) and the like.
[0046]
Examples of the oligosaccharides include sucrose, gnocyanose, umbelliferose, lactose, planteose, isoliquinoses, α, α-trehalose, raffinose, lycnose, umbilicin, stachyose verbusose and the like.
[0047]
Examples of the polysaccharide include cellulose, quince seed, chondroitin sulfate, starch, galactan, dermatan sulfate, glycogen, gum arabic, heparan sulfate, hyaluronic acid, tragacanth gum, keratan sulfate, chondroitin, xanthan gum, mucoitin sulfate, guar gum, dextran, kerato sulfate. , Locust bingham, succinoglucan, caronic acid and the like.
[0048]
Examples of amino acids include neutral amino acids (eg, threonine, cysteine, etc.); basic amino acids (eg, hydroxylysine, etc.) and the like. Examples of amino acid derivatives include acyl sarcosine sodium (lauroyl sarcosine sodium), acyl glutamate, acyl β-alanine sodium, glutathione, and pyrrolidone carboxylic acid.
[0049]
Examples of the organic amine include monoethanolamine, diethanolamine, triethanolamine, morpholine, triisopropanolamine, 2-amino-2-methyl-1,3-propanediol, and 2-amino-2-methyl-1-propanol. Is mentioned.
[0050]
Examples of the polymer emulsion include an acrylic resin emulsion, a polyethyl acrylate emulsion, an acrylic resin liquid, a polyacryl alkyl ester emulsion, a polyvinyl acetate resin emulsion, and a natural rubber latex.
[0051]
Examples of the pH adjuster include buffers such as lactic acid-sodium lactate, citric acid-sodium citrate, and succinic acid-sodium succinate.
[0052]
Examples of vitamins include vitamins A, B1, B2, B6, C, E and derivatives thereof, pantothenic acid and derivatives thereof, biotin and the like.
[0053]
Examples of the antioxidant include tocopherols, dibutylhydroxytoluene, butylhydroxyanisole, gallic acid esters and the like.
[0054]
Examples of the antioxidant assistant include phosphoric acid, citric acid, ascorbic acid, maleic acid, malonic acid, succinic acid, fumaric acid, kephalin, hexametaphosphate, phytic acid, and ethylenediaminetetraacetic acid.
[0055]
Other ingredients that can be blended include, for example, preservatives (ethyl paraben, butyl paraben, etc.); anti-inflammatory agents (eg, glycyrrhizic acid derivatives, glycyrrhetinic acid derivatives, salicylic acid derivatives, hinokitiol, zinc oxide, allantoin, etc.); Extract, placenta extract, saxifrage extract, arbutin, etc.); various extracts (eg, buckwheat, auren, shikon, peonies, assembly, birch, sage, loquat, carrot, aloe, mallow), iris, grape, yokuinin, loofah, lily , Saffron, nematode, ginger, hypericum, onionis, garlic, red pepper, chimney, red snapper, seaweed, etc.), activator (for example, royal jelly, photosensitizer, cholesterol derivative, etc.); blood circulation promoter (for example, nonenyl acid wallenylamide, nicotine) Acid Gyl ester, nicotinic acid β-butoxyethyl ester, capsaicin, gingerone, cantalis tincture, ictamol, tannic acid, α-borneol, nicotinic acid tocopherol, inositol hexanicotinate, cyclandrate, cinnarizine, trazoline, acetylcholine, verapamil, cephalanthin , Γ-oryzanol, etc.); antiseborrheic agents (eg, sulfur, thianthol, etc.); anti-inflammatory agents (eg, tranexamic acid, thiotaurine, hypotaurine, etc.) and the like.
[0056]
The product form which can take the makeup cosmetics of the present invention is not particularly limited, and for example, product forms such as makeup base, foundation, white powder, blusher, lipstick, mascara, eye shadow, eyeliner and the like can be taken.
[0057]
【Example】
EXAMPLES Next, although an Example demonstrates this invention further in detail, this invention is not limited to these. The blending amount is% by weight. First, test methods and evaluation methods employed in each example and comparative example will be described.
[0058]
"Lightness on the skin"
An actual use test was conducted by 10 expert panelists to examine the lightness of the spread on the skin during use. The evaluation criteria are as follows.
◎ ... More than 8 professional panelists recognized that the skin spreads lightly during use.
○… More than 6 panelists and less than 8 panelists recognized that the skin spreads lightly during use.
Δ: Three or more specialist panelists and less than six people recognized that they spread lightly on the skin during use.
×: Less than 3 professional panelists recognized that the skin spreads lightly during use.
[0059]
“Adhesion to the skin (fitness)”
After use, the actual use test was carried out by 10 professional panelists on the adhesion (fitness) to the skin. The evaluation criteria are as follows.
◎… 8 or more professional panelists recognized that there was adhesion (fitness) to the skin after use.
○… More than 6 panelists and less than 8 panelists recognized that they had good adhesion to the skin after use.
Δ: 3 or more and less than 6 professional panelists recognized that there was adhesion (fitness) to the skin after use.
X: Less than 3 professional panelists recognized that there was adhesion (fitness) to the skin after use.
[0060]
“No makeup collapse (make-up effect)”
After use, there were 10 professional panelists who conducted a practical use test on the absence of makeup collapse (makeup mochi effect). The evaluation criteria are as follows.
◎… 8 or more professional panelists admitted that makeup did not collapse after use (good makeup is good).
○… More than 6 professional panelists and less than 8 recognized that makeup did not collapse after use (good makeup is good).
Δ: 3 or more and less than 6 specialist panelists admitted that makeup did not collapse after use (good makeup is good).
×: Less than 3 professional panelists recognized that makeup did not collapse after use (good makeup is good).
[0061]
"No secondary adhesion to clothes (secondary adhesion-less effect)"
An actual use test was conducted by 10 professional panelists on the lack of secondary adhesion to clothing after use (secondary adhesion-less effect). The evaluation criteria are as follows.
◎ ... More than 8 professional panelists recognized that there was no secondary adhesion to clothes after use.
○… More than 6 panelists and less than 8 panelists recognized that there was no secondary adhesion to clothing after use.
Δ: 3 or more and less than 6 specialist panelists recognized that there was no secondary adhesion to clothes after use.
X: Less than 3 professional panelists recognized that there was no secondary adhesion to clothes after use.
[0062]
"No stickiness on the skin"
An actual use test was conducted by 10 professional panelists to check the absence of stickiness on the skin during and after use. The evaluation criteria are as follows.
◎ ... More than 8 professional panelists recognized that they were not sticky during and after use.
○… More than 6 panelists and less than 8 panelists recognized that they were not sticky during and after use.
Δ: 3 or more specialist panelists and less than 6 panelists recognized that they were not sticky during and after use.
X: Less than 3 professional panelists recognized that they were not sticky during use and after use.
[0063]
Examples 1 to 4 and the oil-in-water emulsion foundations of the formulations shown in Comparative Example 1 were uniformly mixed with 1 to 6 shown in Table 1, and 7 to 11 mixed and pulverized were added and dispersed uniformly. It was prepared by adding 12 to 23 dissolved by heating and uniformly emulsifying. An evaluation test was performed on the above evaluation, and the results are shown in Table 1.
[0064]
[Table 1]

[0065]
Reference Examples 5-8 The oil-in-water emulsified foundation of the formulation shown in Comparative Example 2 was uniformly mixed with 1 to 6 shown in Table 2, and 7 to 12 mixed and pulverized was added and dispersed uniformly. It was prepared by adding ~ 26 and uniformly emulsifying. An evaluation test was performed on the above evaluation, and the results are shown in Table 2.
[0066]
[Table 2]

[0067]
From the above results, it can be seen that the makeup cosmetic of the present invention has excellent effects in all evaluation items. Other examples of the present invention will be given below.
[0068]
[Example 9] Solid powdery foundation
(1) Talc 15.0% by weight
(2) Sericite 20.0
(3) Mica 10.0
(4) PMMA spherical powder 1.0
(5) Methylsiloxane network polymer powder 1.0
(6) Boron nitride 9.0
(7) Titanium dioxide 12.0
(8) Iron oxide 6.0
(9) Mica titanium 1.5
(10) Liquid paraffin residue
(11) Diethoxyethyl succinate 10.0
(12) Sorbitan sesquioleate 2.0
(13) Preservative appropriate amount
(14) Perfume appropriate amount
(Manufacturing method and evaluation)
What mixed each component of 1-9 was pulverized, and what mixed each component of 10-14 was added, stirred and mixed, and it shape | molded in the container, and obtained the solid powdery foundation. The obtained solid powdery foundation was excellent in use feeling, makeup moisturizing effect, and secondary adhesion preventing effect.
[0069]

(Manufacturing method and evaluation)
What mixed and pulverized each component of 1-7 was added and disperse | distributed to what mixed and dissolved each component of 12-19. Next, 8 to 11 which were uniformly mixed and stirred were added and emulsified, and filled into a container to obtain a water-in-oil emulsion foundation. The obtained water-in-oil type emulsion foundation was excellent in use feeling, makeup moisturizing effect, and secondary adhesion preventing effect.
[0070]

(Manufacturing method and evaluation)
To each of the components 1 to 7 mixed and pulverized, a mixture of components 8 to 13 was added, mixed and stirred, and filled into a container to obtain a white powder. The obtained white powder was excellent in use feeling, makeup moisturizing effect, and secondary adhesion preventing effect.
[0071]

(Manufacturing method and evaluation)
To each of the components 1 to 7 mixed and pulverized, the mixture of components 8 to 13 was added and stirred and mixed, and molded into an inner dish to obtain an eye shadow. The obtained eye shadow was excellent in the feeling of use, makeup effect, and secondary adhesion prevention effect.
[0072]
[Example 13] Lipstick
(1) Carnauba wax 1.0% by weight
(2) Candelilla wax 2.0
(3) Ceresin 10.0
(4) Squalane remaining
(5) Triisooctanoic acid glycerin 9.0
(6) Glycerin diisostearate 13.0
(7) Diethoxyethyl succinate 5.0
(8) Silicone resin 8.0
(9) Hydroxypropyl-β-cyclodextrin 1.0
(10) Macadamia nut oil fatty acid cholesteryl 3.5
(11) Synthetic sodium magnesium silicate 0.5
(12) Hydrophobic silica 0.5
(13) Purified water 2.0
(14) Boron nitride 10.0
(15) Coloring agent appropriate amount
(16) Preservative appropriate amount
(17) Fragrance proper amount
(Manufacturing method and evaluation)
Disperse 11 to 12 in 10 heated to 60 ° C., add 9 and 13 uniformly dissolved therein, and stir well. Separately, this was added to 1 to 8 which had been heated and dissolved, and the mixture was sufficiently stirred. Further, 14 to 17 was added and dispersed and stirred, and then filled into a container to obtain a lipstick. The obtained lipstick was excellent in use feeling, makeup effect, and secondary adhesion prevention effect.
[0073]
【The invention's effect】
According to the present invention, makeup cosmetics Diethoxyethyl succinate When makeup powder and boron nitride powder are blended, a makeup cosmetic excellent in use feeling, makeup moisturizing effect and secondary adhesion preventing effect is provided.

Claims (1)

A makeup cosmetic comprising diethoxyethyl succinate and boron nitride powder.