JP2688309B2 - Vacuum decarburization treatment method for molten steel - Google Patents

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

TECHNICAL FIELD The present invention has a carbon content of 0.00.
The present invention relates to a decarburizing treatment method for molten steel suitable for producing ultra-low carbon molten steel at 10% by weight or less.

[0002]

2. Description of the Related Art A decarburizing method for supplying oxygen to molten steel in a vacuum chamber is widely known. However, since ultra-low carbon steel is difficult to decarburize, it takes a long time to decarburize, and there is a problem that the temperature of molten steel is greatly lowered. When oxygen etc. is blown into the molten steel to promote decarburization, a violent splash occurs and a large amount of metal adheres to the inner wall of the vacuum chamber, which necessitates frequent removal of the metal in the vacuum chamber. Become.

Although there is an example in which an electric resistance heating element is arranged in the RH vacuum chamber, the conventional electric resistance heating element is insufficient for preventing the temperature decrease of the molten steel and the adhesion of the metal, and The electric resistance heating element has a problem that the facility cost is high and the electrode cost and the power cost are high.

Japanese Unexamined Patent Publication No. 53-81416 describes a method of adding Al, Si or the like to molten steel and blowing oxygen to the molten steel in a vacuum chamber to decarburize and heat the molten steel. However, this method uses expensive Al, Si, etc., and there is a problem with this method in that a large amount of metal is deposited in the vacuum chamber.

Japanese Unexamined Patent Publication (Kokai) No. 2-77518 describes a method in which oxygen is sprayed onto the surface of molten steel in a vacuum chamber, and the CO gas released by the molten steel in the vacuum chamber is burned by this oxygen. However, this method of using only CO gas released from the molten steel as a heat source is insufficient to prevent the temperature drop of the molten steel due to the small heat source, and the heating of the inner wall of the vacuum chamber is also insufficient due to the small heat source. It is difficult to effectively prevent the adhesion of metal.

In Japanese Patent Laid-Open No. 64-217, a combustible gas is blown into the molten steel in the vacuum chamber, and at the same time, oxygen is supplied from above the molten steel bath surface in the vacuum chamber to heat and raise the temperature of the molten steel. The method is described. However, this method has a problem that C and H in the molten steel rise because the combustible gas is blown into the molten steel.

[0007]

SUMMARY OF THE INVENTION The present invention does not use a large-scale electric resistance heating device and does not use expensive ferroalloys such as Al and Si. An object of the present invention is to provide a vacuum decarburization treatment method for molten steel, which can prevent the temperature from decreasing and can prevent the adhesion of metal to the inner wall of the vacuum chamber.

[0008]

SUMMARY OF THE INVENTION The present invention provides:
(1) At the time of RH vacuum treatment, a heating burner hung in a vacuum tank is placed on the furnace top, and a blowing nozzle for blowing gas is placed below the surface of the molten steel bath in the vacuum tank. A method for vacuum decarburization treatment of molten steel, characterized in that an inert gas such as oxygen or argon or a mixed gas of oxygen and an inert gas such as argon is blown from a blowing nozzle while heating the molten steel. ) In the method for vacuum decarburizing molten steel according to (1), the gas blown from the blowing nozzle when the carbon content of the molten steel in the vacuum tank is 0.01% by weight or less is an inert gas such as argon. is there.

FIG. 1 is an explanatory view of the whole apparatus used in the present invention. In the figure, 1 is a RH vacuum tank, 2 is a ladle, 3 is molten steel,
Reference numeral 4 is a gas nozzle for circulation, and 5 is an exhaust pipe connected to a vacuum pump. In the present invention, the heating burner 6 suspended in the vacuum tank 1 is arranged at the furnace top, and the blowing nozzle 13 for blowing gas is arranged below the molten steel bath surface in the vacuum tank.

FIG. 2 is an explanatory view of the vicinity of the blow-out end of an example of the heating burner 6 used in the present invention. The present inventors have found that a throat portion 7 provided on the shaft core, a divergent end portion 8 connected to the lower part of the throat portion, and a plurality of fuel gas supply holes 9 symmetrically provided on the divergent surface of the divergent end portion 8 with the axial center. The molten steel in the vacuum tank was heated using LNG gas as a fuel using a heating burner having a.

The present inventors have found that the inclination angle θ of the diverging portion and the ratio of the lower end diameter D ₁ of the diverging portion to the upper end diameter D ₂ (D ₁
/ D ₂ ) etc. were examined, but when using a heating burner in which θ is 5 to 10 °, D ₁ / D ₂ is 3 to 5 and the fuel supply hole 9 is arranged in the substantially central portion of the end spread portion, decompression is performed. It was found that the combustion of the heating burner is stable both in the vacuum chamber and in the vacuum chamber at atmospheric pressure described later. 1 in the figure
Reference numeral 0 is oxygen, 11 is a fuel, and 12 is a water cooling section.

The blowing nozzle 13 shown in FIG. 1 is arranged below the bath surface of the molten metal 3 in the vacuum chamber. From the blow nozzle, oxygen or argon or a mixed gas of oxygen and argon is blown. As this blowing nozzle, a known blowing nozzle capable of independently controlling the oxygen blowing amount and the argon blowing amount can be used.

The inventors of the present invention used a molten steel in a ladle of 100 tons and an RH vacuum chamber to obtain a molten steel circulation coefficient of RH of 34 tons /
The molten steel was decarburized as a minute. FIG. 3 is an example of the result.
In Fig. 3, △ is an example of decarburization by blowing top-blown oxygen onto the bath surface of the molten steel, but the ladle molten steel [C] is 100 ppm.
When it becomes the following, the decrease of [C] of the molten steel becomes gradual, and the decarburization rate efficiency decreases.

◎ indicates that the same amount of argon as △ is about 100 below the surface of the molten metal.
In this example, the molten steel [C] was smoothly reduced even when [C] was 100 ppm or less, and the ladle molten steel [C] could be easily reduced to 10 ppm or less.

If oxygen, argon, or a mixed gas is blown from a blowing nozzle provided below the surface of the molten steel bath in the vacuum chamber without making any special measures, a violent splash occurs, and a large amount of the inner wall of the vacuum chamber is generated. The metal adheres and it is unavoidable to remove it frequently. In the present invention, fuel and oxygen are supplied to burn
Use a heating burner to burn, but supply the heating burner
By promoting the mixing of the fuel and oxygen
Forming a beam, the order and at the same time heating the molten steel, the inner wall of the vacuum chamber with strong radiation heat is heated to a high temperature. The splash adhered to the inner wall of the vacuum chamber due to this high-temperature heating drops down and does not adhere as metal.

According to the knowledge of the present inventors, when the heating burner described in FIG. 2 is burned under the atmospheric pressure, oxygen and fuel gas once blown from the lower end of the heating burner are pushed back to the end-spreading part, and at the end-spreading part. Promotes the mixing of oxygen and fuel gas. As a result, the heating burner of Figure 2 forms a short and extremely hot flame under atmospheric pressure.

When the vacuum chamber is waiting to process the next molten steel, the inner wall of the vacuum chamber is heated under atmospheric pressure using a heating burner. At this time, the inner wall of the vacuum chamber is preheated to a high temperature by the short and high temperature frame. If this preheating of the inner wall of the vacuum chamber is sufficiently performed, the adhesion of the metal to the inner wall of the vacuum chamber can be further prevented in the subsequent treatment of molten steel. The heating burner is easier to increase the heat generation capacity than the electric resistance heating device, and the facility cost and the operating cost are lower.

[0018]

[Table 1]

[0019]

EXAMPLES Molten steel produced by melting in a 100-ton converter was decarburized under the conditions shown in Table 1 using a 100-ton RH vacuum degassing apparatus shown in FIG. Experiment Nos. 1 to 5 in Table 1 are examples of the present invention, and the carbon concentration after decarburization is low, the amount of temperature drop is small, and there is no metal adhesion, which is good. No. 6 in Table 1 is a comparative example in which a heating burner is not used, but the temperature after decarburizing treatment is significantly lower than that of No. 1 to No. 5 and there is much metal adhesion in the vacuum chamber. No. 7 is a comparative example, in which LNG gas from the heating burner and the blowing nozzle are not used, and only oxygen is blown upward. At this time, the temperature drop is 30
It was larger at 0 ° C than in the examples of the present invention, the carbon concentration after decarburization was high, and metal adhesion was also observed. No8 is a comparative example,
This is an example using only a heating burner. Also in this case, the carbon concentration after decarburization is higher than that of the examples of the present invention. No. 9 is a comparative example, which is an example in which neither a heating burner nor a gas blower is performed, but the carbon concentration is not sufficiently lowered, the temperature drop is large, and the amount of metal adhered is large.

[0020]

By implementing the present invention, the temperature drop of molten steel can be prevented and the vacuum chamber can be prevented without using a large-scale electric resistance heating device and without using expensive alloy iron such as Al or Si. It is possible to prevent the adhesion of metal to the inner wall of the steel, and to manufacture an ultra-low carbon steel having a sufficiently low carbon concentration.

BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is an explanatory view of an apparatus used in the present invention, FIG. 2 is an explanatory view of a heating burner used in the present invention, and FIG. 3 is an explanatory view of decarburization in an ultra-low carbon region. .

[Explanation of symbols]

1: RH vacuum tank, 2: ladle, 3: molten steel, 4: gas nozzle for reflux, 5: exhaust pipe, 6: heating burner,
7: throat part, 8: divergent part, 9: fuel supply hole, 10: oxygen, 11: fuel gas, 12: water cooling part.

 ─────────────────────────────────────────────────── ─── Continuation of the front page (72) Inventor Hiroshi Nagahama 1 Fuji-machi, Hirohata-ku, Himeji-shi, Hyogo Nippon Steel Corporation Hirohata Works (72) Inventor Koichi Kamei Fuji-cho, Himeji-shi, Hyogo-ken No. 1 Nippon Steel Works Hirohata Works (72) Inventor Takahiro Isono No. 1 Fuji-machi, Hirohata-ku, Himeji City, Hyogo Prefecture Nippon Steel Works Hirohata Works (56) References Japanese Patent Laid-Open No. 2 -217412 (JP, A) JP 64-217 (JP, A) JP 59-110717 (JP, A) JP 56-49968 (JP, B2)

Claims (4)

(57) [Claims] 1. At the time of RH vacuum treatment, a lance-shaped heating burner for supplying and burning fuel and oxygen hung in a vacuum chamber is arranged at the top, and gas is blown into the vacuum chamber below the surface of the molten steel bath. A nozzle is installed and the metal burnt in the vacuum tank is melted by a heating burner and the molten steel in the vacuum tank is heated, while an inert gas such as oxygen or argon or an inert gas such as oxygen and argon is blown from the blowing nozzle. A method for vacuum decarburizing molten steel, which comprises blowing a mixed gas of 2. The blow gas from the blow nozzle when the carbon content of the molten steel in the vacuum chamber is 0.01% by weight or less is an inert gas such as argon, and the blow gas is an inert gas. Vacuum decarburization treatment method for molten steel. 3. A lance-shaped heating burner according to claim 1 or 2.
The throat part (7) provided in the oxygen flow path of the shaft core
The end widening part (8) connected below the funnel and this end
Providing a plurality of symmetrically on the axial center on the flared surface of the flared portion (8)
With a fuel gas supply hole (9)
A method for vacuum decarburization treatment of molten steel, which is characterized in that 4. The lance-shaped heating burner according to claim 3,
The inclination angle of the spread part is 5 to 10 °,
The ratio D1 / D2 of the diameter D1 and the diameter D2 at the upper end is 3 to 5
The fuel supply hole is located near the center of the flared end.
Vacuum decarburization of molten steel characterized by being a thermal burner
Method.