JP2020146670A - Wastewater treatment apparatus - Google Patents

Wastewater treatment apparatus Download PDF

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JP2020146670A
JP2020146670A JP2019048675A JP2019048675A JP2020146670A JP 2020146670 A JP2020146670 A JP 2020146670A JP 2019048675 A JP2019048675 A JP 2019048675A JP 2019048675 A JP2019048675 A JP 2019048675A JP 2020146670 A JP2020146670 A JP 2020146670A
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wastewater
inorganic
biological treatment
treated water
coagulation
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僚一郎 中原
Ryoichiro Nakahara
僚一郎 中原
真也 山口
Shinya Yamaguchi
真也 山口
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Kurita Water Industries Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/10Biological treatment of water, waste water, or sewage

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  • Purification Treatments By Anaerobic Or Anaerobic And Aerobic Bacteria Or Animals (AREA)

Abstract

To provide a wastewater treatment apparatus that does not require sorting according to the quality of wastewater and can efficiently process wastewater without excess or shortage of treatment.SOLUTION: Inorganic wastewater is coagulated and sedimented by a coagulation/sedimentation apparatus 1 and then sent to a confluence tank 5 via a fluidized bed type aerobic biological treatment apparatus 2. A bypass line 4 is provided so as to bypass the fluidized bed type aerobic biological treatment apparatus 2, and the coagulation-sedimentation treated water is switched by a valve 3 so as to selectively flow the treated water to the fluidized bed type aerobic biological treatment apparatus 2 or to the bypass line 4. Organic wastewater is nitrified and denitrified in a nitrification/denitrification apparatus 6, then sedimented in a sedimentation tank 7, and then sent to the confluence tank 5. If the TOC concentration in the coagulation/sedimentation treated water is lower than a predetermined concentration A, the coagulation/sedimentation treated water from the coagulation/sedimentation apparatus 1 is flowed into the bypass line 4, and if it is higher than A, the coagulation/sedimentation treated water is introduced into the fluidized bed aerobic biological treatment system 2.SELECTED DRAWING: Figure 1

Description

本発明は、無機系排水と有機系排水とを処理する排水処理装置に関する。詳しくは、本発明は、電子部品等の製造工程等からの排水の処理に好適な排水処理装置に関する。 The present invention relates to a wastewater treatment device for treating inorganic wastewater and organic wastewater. More specifically, the present invention relates to a wastewater treatment apparatus suitable for treating wastewater from a manufacturing process of electronic parts and the like.

電子部品の製造工場では、各製造工程から各種水質の排水が排出される。通常は、主に無機系排水と有機系排水とが異なる水槽に貯留され、それぞれ処理される場合と、無機系排水と有機系排水をそれぞれ処理したのち合流混合した後、一系統で処理することもある。この合流槽からの処理では、有機系排水の処理水に多く含まれるTOCなどの影響を大きく受ける。無機系排水中のTOC濃度は有機系排水に比べ希薄である。この無機系排水についても生物処理等によりTOCを除去していることがあり、除去すべきTOCが少ない場合であっても生物処理(曝気)を稼働させていたため、運転コストがかかっている。 In electronic component manufacturing factories, wastewater of various water qualities is discharged from each manufacturing process. Normally, inorganic wastewater and organic wastewater are mainly stored in different water tanks and treated separately, or inorganic wastewater and organic wastewater are treated respectively, then merged and mixed, and then treated in one system. There is also. The treatment from this confluence tank is greatly affected by TOC and the like, which are abundant in the treated water of organic wastewater. The TOC concentration in the inorganic wastewater is lower than that in the organic wastewater. The TOC of this inorganic wastewater may also be removed by biological treatment or the like, and even when the TOC to be removed is small, the biological treatment (aeration) is operated, so that the operating cost is high.

特許文献1には、各工程からの排水を水質に応じて分別し、分別した排水を水質の似たもの同士でまとめ、各まとめた排水をそれぞれの水質に応じて処理することが記載されている。 Patent Document 1 describes that wastewater from each process is separated according to water quality, the separated wastewater is collected by those having similar water quality, and each collected wastewater is treated according to each water quality. There is.

特開平8−173951号公報Japanese Unexamined Patent Publication No. 8-173951

本発明は、排水の水質に応じた分別が不要であり、また処理の過不足なく効率よく排水を処理することができる排水処理装置を提供することを目的とする。 An object of the present invention is to provide a wastewater treatment apparatus that does not require sorting according to the quality of wastewater and can efficiently treat wastewater without excess or deficiency of treatment.

本発明は次を要旨とする。 The gist of the present invention is as follows.

[1] 無機系排水又はその凝集・沈殿処理水を生物処理して無機系生物処理水を得る無機系排水用生物処理装置と、有機系排水を生物処理して有機系生物処理水を得る有機系排水用生物処理装置と、該無機系生物処理水及び有機系生物処理水が流入する合流槽と
を備える排水処理装置において、該無機系排水用生物処理装置を迂回するバイパスラインと、無機系排水又はその凝集・沈殿処理水中の有機物濃度が所定値以下の場合に、無機系排水又はその凝集・沈殿処理水を該バイパスラインに流すように制御する制御手段とを備えたことを特徴とする排水処理装置。
[1] A biological treatment device for inorganic wastewater, which is obtained by biologically treating inorganic wastewater or its coagulation / sedimentation treated water to obtain inorganic biologically treated water, and an organic, which is obtained by biologically treating organic wastewater to obtain organic biologically treated water. In a wastewater treatment device including a biological treatment device for system wastewater and a confluence tank into which the inorganic biological treatment water and the organic biological treatment water flow in, a bypass line bypassing the inorganic biological treatment device and an inorganic system It is characterized by being provided with a control means for controlling the flow of inorganic wastewater or the agglomeration / precipitation treatment water thereof to the bypass line when the concentration of organic matter in the wastewater or the agglomeration / precipitation treatment water thereof is equal to or less than a predetermined value. Wastewater treatment equipment.

[2] 前記制御手段は、前記無機系排水又はその凝集・沈殿処理水の有機物濃度が合流槽の有機物濃度以下である場合に無機系排水を前記バイパスラインに流すように制御することを特徴とする[1]の排水処理装置。 [2] The control means is characterized in that when the organic matter concentration of the inorganic wastewater or the coagulation / precipitation treated water thereof is equal to or less than the organic matter concentration of the merging tank, the inorganic wastewater is controlled to flow to the bypass line. [1] Wastewater treatment equipment.

[3] 前記有機物濃度がTOC濃度であることを特徴とする[2]の排水処理装置。 [3] The wastewater treatment apparatus according to [2], wherein the organic matter concentration is a TOC concentration.

[4] 前記無機系生物処理装置が、流動床型好気性生物処理装置であることを特徴とする[1]〜[3]のいずれかの排水処理装置。 [4] The wastewater treatment device according to any one of [1] to [3], wherein the inorganic biological treatment device is a fluidized bed type aerobic biological treatment device.

[5] 前記無機系排水用生物処理装置の前段に固液分離装置が設けられていることを特徴とする[1]〜[4]のいずれかの排水処理装置。 [5] The wastewater treatment apparatus according to any one of [1] to [4], wherein a solid-liquid separation apparatus is provided in front of the inorganic wastewater biological treatment apparatus.

[6] 前記有機系排水用生物処理装置が、硝化・脱窒装置であることを特徴とする[1]〜[5]のいずれかの排水処理装置。 [6] The wastewater treatment device according to any one of [1] to [5], wherein the organic wastewater biological treatment device is a nitrification / denitrification device.

[7] 前記有機系排水用生物処理装置の後段かつ前記合流槽の前段に固液分離装置が設置されていることを特徴とする[1]〜[6]のいずれかの排水処理装置。 [7] The wastewater treatment apparatus according to any one of [1] to [6], wherein the solid-liquid separation apparatus is installed after the biological treatment apparatus for organic wastewater and in front of the confluence tank.

本発明の排水処理装置によると、無機系排水の有機物濃度に応じて、生物処理(流動床式担体)など曝気動力で運転コストがかかる部分をバイパスする制御を行うことで、排水処理全体の運転コスト低減が可能になる。 According to the wastewater treatment apparatus of the present invention, the entire wastewater treatment is operated by controlling the biological treatment (fluidized bed type carrier) or the like to bypass the part where the operation cost is high due to the aeration power according to the organic matter concentration of the inorganic wastewater. Cost reduction is possible.

また、有機物濃度が低い生物処理水を混合することで、合流後の有機物負荷を低減し、安定な運転が可能となる。 In addition, by mixing biologically treated water with a low organic matter concentration, the organic matter load after merging can be reduced and stable operation becomes possible.

実施の形態に係る排水処理装置のフロー図である。It is a flow chart of the wastewater treatment apparatus which concerns on embodiment.

以下、図面を参照して実施の形態について説明する。 Hereinafter, embodiments will be described with reference to the drawings.

この排水処理装置は、電子部品の製造工程等から生じた無機系排水と有機系排水とを処理するためのものである。 This wastewater treatment device is for treating inorganic wastewater and organic wastewater generated from the manufacturing process of electronic parts and the like.

この実施の形態では、無機系排水とは、TOC濃度が30ppm未満特に20ppm以下のものである。 In this embodiment, the inorganic wastewater has a TOC concentration of less than 30 ppm, particularly 20 ppm or less.

電子部品が液晶等の場合は、TOC成分は酢酸などの有機酸や希薄なアミン等であることが多い。無機成分としては、リン酸やフッ素などが例示される。有機系排水は、TOC濃度が30ppm以上であり、通常は80ppm以上特に100ppm以上である。 When the electronic component is a liquid crystal or the like, the TOC component is often an organic acid such as acetic acid or a dilute amine or the like. Examples of the inorganic component include phosphoric acid and fluorine. Organic wastewater has a TOC concentration of 30 ppm or more, usually 80 ppm or more, and particularly 100 ppm or more.

電子部品が液晶等の場合は、TOC成分はエッチングプロセス等で排出される有機物が主体であり、例えば剥離液等で使用されるアミン、エーテル系の薬剤が主体となる。有機系排水には、無機成分も微量に存在する。 When the electronic component is a liquid crystal or the like, the TOC component is mainly an organic substance discharged in an etching process or the like, and for example, an amine or ether-based chemical used in a stripping solution or the like is the main component. Inorganic wastewater also contains a small amount of inorganic components.

図1の通り、無機系排水は、凝集・沈殿装置1で凝集及び沈殿処理された後、流動床型好気性生物処理装置2(又は後述のバイパスライン4)を経て合流槽5へ送られる。 As shown in FIG. 1, the inorganic wastewater is coagulated and settled by the coagulation / settling device 1 and then sent to the confluence tank 5 via the fluidized bed type aerobic biological treatment device 2 (or the bypass line 4 described later).

流動床型好気性生物処理装置2を迂回するようにバイパスライン4が設けられており、凝集沈殿処理水を流動床型好気性生物処理装置2又はバイパスライン4に択一的に流すように切替弁3が設けられている。 A bypass line 4 is provided so as to bypass the fluidized bed type aerobic biological treatment device 2, and the coagulated sedimentation treated water is switched so as to selectively flow to the fluidized bed type aerobic biological treatment device 2 or the bypass line 4. A valve 3 is provided.

有機系排水は、硝化・脱窒装置6で硝化及び脱窒処理された後、沈殿槽7で沈殿処理され、次いで前記合流槽5へ送られる。 The organic wastewater is nitrified and denitrified by the nitrification / denitrification apparatus 6, then settled in the settling tank 7, and then sent to the confluence tank 5.

合流槽5内の水は、後段処理装置8で処理され、処理水となる。この後段処理装置としては、加圧浮上装置のほか、重力濾過した後、活性炭濾過し、次いでRO処理するもの等が例示されるが、これに限定されない。 The water in the merging tank 5 is treated by the post-stage treatment device 8 to become treated water. Examples of the post-stage treatment device include, but are not limited to, a pressure flotation device, a device that undergoes gravity filtration, then activated carbon filtration, and then RO treatment.

凝集・沈殿処理水のTOC濃度を測定するようにTOCセンサ(図示略)が設けられると共に、合流槽5にTOCセンサ10が設置されており、これらの検出信号が制御装置11に入力され、該制御装置11が切替弁3を制御する。 A TOC sensor (not shown) is provided to measure the TOC concentration of the agglomerated / settled water, and a TOC sensor 10 is installed in the merging tank 5, and these detection signals are input to the control device 11 and the TOC sensor 10 is installed. The control device 11 controls the switching valve 3.

この実施の形態では、凝集・沈殿処理水のTOC濃度が所定濃度Aよりも低い場合は、凝集・沈殿装置1からの凝集沈殿処理水をバイパスライン4に流し、Aよりも高い場合には凝集沈殿処理水を流動床型好気性生物処理装置2に導入するように切替弁3が制御される。本発明の一態様では、所定濃度Aは合流槽5のTOC濃度又はその±50%の範囲に設定されてもよい。 In this embodiment, when the TOC concentration of the coagulation / precipitation treated water is lower than the predetermined concentration A, the coagulation / precipitation treatment water from the coagulation / precipitation device 1 is flowed to the bypass line 4, and when it is higher than A, the coagulation / precipitation treatment water is agglomerated. The switching valve 3 is controlled so as to introduce the precipitated treated water into the fluidized bed type aerobic biological treatment apparatus 2. In one aspect of the present invention, the predetermined concentration A may be set to the TOC concentration of the confluence tank 5 or a range of ± 50% thereof.

このように構成された排水処理装置によると無機系排水中のTOC濃度が所定濃度Aよりも低い場合には、凝集沈殿処理水が、流動床型好気性生物処理装置2で生物処理されることなくバイパスライン4を介して直接的に合流槽5へ流入するので、流動床型好気性生物処理装置2での曝気動力コストを節減することができる。なお、TOC濃度の低い無機系排水処理水が合流槽5において有機系排水処理水に合流され、合流槽5内の水のTOC濃度が低下するので、後段処理の負荷が低下し、処理が安定して行われるようになる。 According to the wastewater treatment apparatus configured in this way, when the TOC concentration in the inorganic wastewater is lower than the predetermined concentration A, the coagulated sedimentation treated water is biologically treated by the fluidized bed type aerobic biological treatment apparatus 2. Since it directly flows into the merging tank 5 through the bypass line 4, the aeration power cost in the fluidized bed type aerobic biological treatment device 2 can be reduced. Inorganic wastewater treated water having a low TOC concentration is merged with the organic wastewater treated water in the confluence tank 5, and the TOC concentration of the water in the confluence tank 5 is lowered, so that the load of the post-stage treatment is reduced and the treatment is stable. Will be done.

上記実施の形態ではバイパスライン4は流動床型好気性生物処理装置2を迂回するように設けられているが凝集・沈殿装置1を迂回するように設けられてもよい。この場合、無機系排水のTOC濃度が低い場合に無機系排水を凝集装置1をバイパスさせる。 In the above embodiment, the bypass line 4 is provided so as to bypass the fluidized bed type aerobic biological treatment device 2, but may be provided so as to bypass the coagulation / precipitation device 1. In this case, when the TOC concentration of the inorganic wastewater is low, the inorganic wastewater is bypassed by the aggregating device 1.

本発明では、合流槽5内のTOC濃度が所定値よりも低い場合、前記バイパスを行わず、凝集・沈殿装置1での凝集剤やポリマー凝結剤の添加量を減少させるような制御を行ってもよく、また、流動床型好気性生物処理装置2でpHや曝気量を調整する運転を行ってもよい。この所定値は、3〜10ppm特に4〜8ppmの間から選定された値、例えば5ppmに設定される。TOC低減工程での負荷を低下させる運転を行ってもよい。 In the present invention, when the TOC concentration in the merging tank 5 is lower than a predetermined value, the bypass is not performed, and control is performed so as to reduce the amount of the coagulant and the polymer coagulant added in the coagulation / precipitation device 1. Alternatively, the fluidized bed type aerobic biological treatment apparatus 2 may be operated to adjust the pH and the amount of aeration. This predetermined value is set to a value selected from between 3 to 10 ppm, particularly 4 to 8 ppm, for example, 5 ppm. The operation of reducing the load in the TOC reduction step may be performed.

1 凝集・沈殿装置
4 バイパスライン
5 合流槽
6 硝化・脱窒装置
1 Coagulation / sedimentation equipment 4 Bypass line 5 Confluence tank 6 Nitrification / denitrification equipment

この実施の形態では、凝集・沈殿処理水のTOC濃度が所定濃度Aよりも低い場合は、凝集・沈殿装置1からの凝集沈殿処理水をバイパスライン4に流し、Aよりも高い場合には凝集沈殿処理水を流動床型好気性生物処理装置2に導入するように切替弁3が制御される。本発明の一態様では、所定濃度Aは合流槽5のTOC濃度又はその50%の範囲に設定されてもよい。 In this embodiment, when the TOC concentration of the coagulation / precipitation treated water is lower than the predetermined concentration A, the coagulation / precipitation treatment water from the coagulation / precipitation device 1 is flowed to the bypass line 4, and when it is higher than A, the coagulation / precipitation treatment water is agglomerated. The switching valve 3 is controlled so as to introduce the precipitated treated water into the fluidized bed type aerobic biological treatment apparatus 2. In one aspect of the present invention, the predetermined concentration A may be set to the TOC concentration of the confluence tank 5 or a range of + 50% thereof.

Claims (7)

無機系排水又はその凝集・沈殿処理水を生物処理して無機系生物処理水を得る無機系排水用生物処理装置と、
有機系排水を生物処理して有機系生物処理水を得る有機系排水用生物処理装置と、
該無機系生物処理水及び有機系生物処理水が流入する合流槽と
を備える排水処理装置において、
該無機系排水用生物処理装置を迂回するバイパスラインと、
無機系排水又はその凝集・沈殿処理水中の有機物濃度が所定値以下の場合に、無機系排水又はその凝集・沈殿処理水を該バイパスラインに流すように制御する制御手段と
を備えたことを特徴とする排水処理装置。
Inorganic wastewater biological treatment equipment for obtaining inorganic biological treatment water by biologically treating inorganic wastewater or its coagulation / precipitation treated water.
A biological treatment device for organic wastewater that biologically treats organic wastewater to obtain organic biologically treated water,
In a wastewater treatment apparatus provided with a confluence tank into which the inorganic biologically treated water and the organic biologically treated water flow in.
A bypass line that bypasses the inorganic wastewater biological treatment equipment,
It is characterized by being provided with a control means for controlling the flow of the inorganic wastewater or the agglomeration / precipitation treatment water thereof to the bypass line when the organic matter concentration in the inorganic wastewater or the agglomeration / precipitation treatment water thereof is equal to or less than a predetermined value. Wastewater treatment equipment.
前記制御手段は、前記無機系排水又はその凝集・沈殿処理水の有機物濃度が合流槽の有機物濃度以下である場合に無機系排水を前記バイパスラインに流すように制御することを特徴とする請求項1の排水処理装置。 The control means is characterized in that when the organic matter concentration of the inorganic wastewater or the coagulation / precipitation treated water thereof is equal to or less than the organic matter concentration of the merging tank, the inorganic wastewater is controlled to flow to the bypass line. 1 wastewater treatment device. 前記有機物濃度がTOC濃度であることを特徴とする請求項2の排水処理装置。 The wastewater treatment apparatus according to claim 2, wherein the organic matter concentration is a TOC concentration. 前記無機系生物処理装置が、流動床型好気性生物処理装置であることを特徴とする請求項1〜3のいずれかの排水処理装置。 The wastewater treatment device according to any one of claims 1 to 3, wherein the inorganic biological treatment device is a fluidized bed type aerobic biological treatment device. 前記無機系排水用生物処理装置の前段に固液分離装置が設けられていることを特徴とする請求項1〜4のいずれかの排水処理装置。 The wastewater treatment apparatus according to any one of claims 1 to 4, wherein a solid-liquid separation apparatus is provided in front of the biological treatment apparatus for inorganic wastewater. 前記有機系排水用生物処理装置が、硝化・脱窒装置であることを特徴とする請求項1〜5のいずれかの排水処理装置。 The wastewater treatment device according to any one of claims 1 to 5, wherein the organic wastewater biological treatment device is a nitrification / denitrification device. 前記有機系排水用生物処理装置の後段かつ前記合流槽の前段に固液分離装置が設置されていることを特徴とする請求項1〜6のいずれかの排水処理装置。 The wastewater treatment apparatus according to any one of claims 1 to 6, wherein a solid-liquid separation apparatus is installed after the biological treatment apparatus for organic wastewater and in front of the confluence tank.
JP2019048675A 2019-03-15 2019-03-15 Wastewater treatment apparatus Pending JP2020146670A (en)

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Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014148580A1 (en) * 2013-03-22 2014-09-25 東レ株式会社 Fresh water production process

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014148580A1 (en) * 2013-03-22 2014-09-25 東レ株式会社 Fresh water production process

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