JP2016146828A - Oil-in-water type emulsion composition - Google Patents
Oil-in-water type emulsion composition Download PDFInfo
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- JP2016146828A JP2016146828A JP2016023161A JP2016023161A JP2016146828A JP 2016146828 A JP2016146828 A JP 2016146828A JP 2016023161 A JP2016023161 A JP 2016023161A JP 2016023161 A JP2016023161 A JP 2016023161A JP 2016146828 A JP2016146828 A JP 2016146828A
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Landscapes
- Grain Derivatives (AREA)
- Edible Oils And Fats (AREA)
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Abstract
Description
本発明は、食品に使用される水中油型乳化組成物に関するものであり、さらに詳しくは、酸性下や、殺菌に必要な高温での加熱処理に対する安定性が要求される食品に使用される水中油型乳化組成物に関する。 The present invention relates to an oil-in-water emulsified composition used for foods, and more specifically, water used for foods that require stability to heat treatment under acidity or at a high temperature necessary for sterilization. The present invention relates to an oil-type emulsion composition.
水と油脂とタンパクを含む水中油型乳化組成物は、牛乳や生クリームの代替としてケーキ生地、ゼリー、ムース、スープ類やソース類等にそのまま添加して使用され、あるいは起泡させてホイップクリームとして、製菓、製パン材料に使用されている。 Oil-in-water emulsified composition containing water, fats and oils can be used as an alternative to milk or fresh cream as it is added to cake dough, jelly, mousse, soups, sauces, etc. It is used as a confectionery and bakery material.
近年では、このような水中油型乳化組成物に果汁やフルーツ、あるいは酸味料等の酸味成分を加えて加工したゼリー、ムース、ソース類、スープ類等が多く流通するようになり、これらは常温でかつ、6〜12カ月といった長期間の消費期限が要求されている。 In recent years, a lot of jelly, mousse, sauces, soups, etc. that have been processed by adding sour ingredients such as fruit juice, fruit, or acidulant to such an oil-in-water emulsion composition have been distributed. In addition, a long term expiration period of 6 to 12 months is required.
そのため、高温での殺菌が必要とされることから、耐熱性に優れ、特に高温においても耐酸性に優れた水中油型乳化組成物が求められている。 Therefore, since high temperature sterilization is required, an oil-in-water emulsified composition excellent in heat resistance, particularly excellent in acid resistance even at high temperatures is required.
しかしながら、従来の水中油型乳化組成物は酸性下や高温下、特に高温酸性下では、乳化物中のタンパクの凝集による乳化破壊が起こる問題があり、これを改善するために、乳清タンパクを使用する技術や、乳清タンパクと特定の乳化剤や増粘多糖類を併用する技術が提案されている(特許文献1、2)。 However, conventional oil-in-water emulsified compositions have a problem in that emulsion breakage occurs due to aggregation of proteins in the emulsion under acidic or high temperature conditions, particularly under high temperature acidity. Techniques to be used and techniques to use whey protein in combination with specific emulsifiers and thickening polysaccharides have been proposed (Patent Documents 1 and 2).
しかしながら、耐熱性および耐酸性を向上させる技術にはさらに改良の余地があった。特に、近年この種の水中油型乳化組成物として、フルーツと混合する場合はフルーツの色が映えるよう、また視覚的な味覚向上のために、色の白いものが好まれている。さらにこうした食品は、口溶けが良いこと、乳化剤に起因する異味がないことが望まれている。ところが、耐酸耐熱性と、白色度や口溶けおよび異味の低減を両立する技術は確立されていなかった。 However, there is room for further improvement in the technology for improving heat resistance and acid resistance. In particular, as an oil-in-water emulsified composition of this type in recent years, a white-colored one is preferred so that the color of the fruit can be reflected when mixed with a fruit and for improving the visual taste. Furthermore, it is desired that such foods have good meltability in the mouth and have no off-flavors due to the emulsifier. However, a technology that achieves both acid heat resistance and reduced whiteness, melting in the mouth, and off-flavor has not been established.
本発明は、以上の通りの事情に鑑みてなされたものであり、酸性下でも分離や凝集が抑制され、広範囲のpHにて加熱を受けても乳化状態が安定であり、さらに殺菌に必要な高温での加熱処理による分離や凝集も抑制することができ、これを添加した冷菓等の食品は白色度が良好で、かつ異味がなく口溶けも良い水中油型乳化組成物を提供することを課題としている。 The present invention has been made in view of the circumstances as described above. Separation and aggregation are suppressed even under acidic conditions, the emulsified state is stable even when heated in a wide range of pH, and is further necessary for sterilization. Separation and agglomeration due to heat treatment at high temperatures can be suppressed, and foods such as frozen confectionery to which this is added have a good whiteness, and have an objection to provide an oil-in-water emulsified composition that does not have a taste and melts in the mouth. It is said.
本発明者らはこの課題を解決するために鋭意検討した結果、乳化剤として水溶性の特定のポリグリセリン脂肪酸エステルを使用し、かつ油脂としてラウリン系油脂を含む特定の油脂を使用するとともに、油脂、乳化剤、および油滴のメディアン径の関係に着目し、これらが特定の関係を満足することによって、耐酸耐熱性が良く、これを添加した冷菓、ソース類、スープ類等の食品は白色度が良好で、かつ異味がなく口溶けも良いものが得られることを見出し、本発明を完成するに至った。 As a result of intensive studies to solve this problem, the present inventors used a specific water-soluble polyglycerin fatty acid ester as an emulsifier, and used a specific fat / oil containing lauric fat / oil as an oil / fat, Focusing on the relationship between the emulsifier and the median diameter of the oil droplets, and satisfying a specific relationship, the acid heat resistance is good, and foods such as frozen desserts, sauces and soups to which this is added have good whiteness In addition, the inventors have found that a product having no off-flavor and good meltability can be obtained, and the present invention has been completed.
すなわち、本発明の水中油型乳化組成物は、水相に、HLBが11以上、重合度が10以上、構成脂肪酸の炭素数が18以上であるポリグリセリン脂肪酸エステルを含有し、前記ポリグリセリン脂肪酸エステルの含有量Yが0.3〜3.0質量%、油脂の含有量Xが30〜50質量%、油滴のメディアン径Rが0.4〜1.0μmであり、油脂の含有量Xと、油滴のメディアン径Rと、前記ポリグリセリン脂肪酸エステルの合計量Yが次式(I): That is, the oil-in-water emulsion composition of the present invention contains a polyglycerin fatty acid ester having an HLB of 11 or more, a degree of polymerization of 10 or more, and a constituent fatty acid having 18 or more carbon atoms in the water phase. The content Y of the ester is 0.3 to 3.0% by mass, the content X of the fat and oil is 30 to 50% by mass, the median diameter R of the oil droplet is 0.4 to 1.0 μm, and the content X of the fat and oil And the median diameter R of the oil droplets and the total amount Y of the polyglycerin fatty acid ester is represented by the following formula (I):
で表わされる関係を満足し、前記油脂は、ラウリン系油脂を含有し、かつ融点40℃以上の極度硬化油の含有量が油脂全量に対して1質量%以下であることを特徴としている。 The oil / fat contains a lauric oil / fat, and the content of extremely hardened oil having a melting point of 40 ° C. or higher is 1% by mass or less based on the total amount of the oil / fat.
本発明によれば、酸性下でも分離や凝集が抑制され、広範囲のpHにて加熱を受けても乳化状態が安定であり、さらに殺菌に必要な高温での加熱処理による分離や凝集も抑制することができ、これを添加した冷菓等の食品は白色度が良好で、かつ異味がなく口溶けも良い。 According to the present invention, separation and aggregation are suppressed even under acidic conditions, the emulsified state is stable even when heated in a wide range of pH, and further, separation and aggregation due to heat treatment at a high temperature necessary for sterilization are also suppressed. In addition, foods such as frozen desserts to which this is added have good whiteness, and have no off-flavors and can melt in the mouth.
以下に、本発明を詳細に説明する。 The present invention is described in detail below.
本発明の水中油型乳化組成物は、油脂としてラウリン系油脂を含有する。ラウリン系油脂を使用することで、口溶けが良好で、清涼感のある食品を得ることができる。 The oil-in-water emulsion composition of the present invention contains lauric fat as fat. By using lauric fats and oils, it is possible to obtain a food with good mouth melting and a refreshing feeling.
ラウリン系油脂は、構成脂肪酸にラウリン酸、すなわち炭素数12の飽和脂肪酸を多く含有する油脂である。ラウリン系油脂の構成脂肪酸中におけるラウリン酸の含有量は、通常35質量%以上、好ましくは40質量%以上である。 Laurin-based fats and oils are fats and oils containing a large amount of lauric acid, that is, saturated fatty acids having 12 carbon atoms, in the constituent fatty acids. The content of lauric acid in the constituent fatty acids of the lauric fat is usually 35% by mass or more, preferably 40% by mass or more.
ラウリン系油脂としては、例えば、パーム核油、ヤシ油、これらの硬化油、分別油などが挙げられる。これらは1種単独で使用してもよく2種以上を併用してもよい。 Examples of lauric fats and oils include palm kernel oil, coconut oil, hardened oils thereof, and fractionated oil. These may be used alone or in combination of two or more.
本発明の水中油型乳化組成物におけるラウリン系油脂の含有量は、油脂全量に対して30質量%以上が好ましく、50質量%以上がより好ましい。 The content of the lauric fat in the oil-in-water emulsion composition of the present invention is preferably 30% by mass or more, and more preferably 50% by mass or more, based on the total amount of oil.
近年では、トランス脂肪酸の循環器系へ及ぼす悪影響を懸念し、消費者の健康志向を踏まえてトランス脂肪酸の含有量を低減することが望まれているが、ラウリン系油脂として硬化処理されていないもの、極度硬化処理をされたものを使用すると、トランス脂肪酸の含有量を低減できる。 In recent years, there are concerns about the adverse effects of trans fatty acids on the circulatory system, and it has been desired to reduce the content of trans fatty acids based on the health orientation of consumers, but it has not been cured as a lauric fat. When using an extremely cured material, the content of trans fatty acid can be reduced.
本発明の水中油型乳化組成物は、油脂としてラウリン系油脂以外の油脂を配合することができる。このような油脂としては、食用に適するものであれば特に限定されるものではないが、例えば、パーム油、菜種油、大豆油、綿実油、ヒマワリ油、米油、サフラワー油、オリーブ油、ゴマ油、コーン油などの植物性油脂、豚脂(ラード)、牛脂、魚油などの動物性油脂、乳脂、これらの分別油、硬化油、エステル交換油脂などが挙げられる。中でも、風味が良好となり、乳化剤に起因する異味を抑制できる点からは、乳脂を含有することが好ましい。 In the oil-in-water emulsion composition of the present invention, fats and oils other than lauric fats and oils can be blended as fats and oils. Such fats and oils are not particularly limited as long as they are edible, but for example, palm oil, rapeseed oil, soybean oil, cottonseed oil, sunflower oil, rice oil, safflower oil, olive oil, sesame oil, corn Examples include vegetable oils such as oil, animal fats such as lard, beef tallow and fish oil, milk fats, fractionated oils thereof, hardened oils, transesterified oils and the like. Especially, it is preferable to contain milk fat from the point which flavor becomes favorable and can suppress the unpleasant taste resulting from an emulsifier.
これらの油脂は、1種単独で使用してもよく2種以上を併用してもよい。またエステル交換油脂は、上記のような油脂の1種あるいは2種以上を選択した配合物をエステル交換反応したものであってもよい。 These fats and oils may be used individually by 1 type, and may use 2 or more types together. The transesterified oil / fat may be obtained by transesterification of a compound selected from one or more of the above fats / oils.
本発明の水中油型乳化組成物は、油脂における全構成脂肪酸中のオレイン酸含有量が10〜40質量%であることが好ましい。この範囲内であると、耐酸耐熱性が向上し、酸性下でも分離や凝集が抑制され、広範囲のpHにて加熱を受けても乳化状態が安定であり、さらに殺菌に必要な高温での加熱処理による分離や凝集も抑制することができる。さらに白色度が良好で、口溶けも良いものが得られる。例えば、ラウリン系油脂として硬化処理されていないものを主とする油脂組成によって、オレイン酸含有量をこの範囲内に調整することができる。なお、油脂における全構成脂肪酸中のオレイン酸含有量は、ガスクロマトグラフ法(基準油脂分析試験法(公益社団法人日本油化学会)の「2.4.2.2−2013 脂肪酸組成(FID昇温ガスクロマトグラフ法)」)により測定することができる。 The oil-in-water emulsion composition of the present invention preferably has an oleic acid content of 10 to 40% by mass in all the constituent fatty acids in the oil or fat. Within this range, acid heat resistance is improved, separation and aggregation are suppressed even under acidic conditions, the emulsified state is stable even when heated in a wide range of pH, and heating at a high temperature necessary for sterilization. Separation and aggregation due to processing can also be suppressed. Further, a product having good whiteness and good melting in the mouth is obtained. For example, the oleic acid content can be adjusted within this range by an oil / fat composition mainly composed of an untreated lauric oil / fat. In addition, oleic acid content in all the constituent fatty acids in fats and oils is determined by gas chromatographic method (standard fat and oil analysis test method (Japan Oil Chemists' Society) "2.4.2.2-2013 fatty acid composition (FID temperature rise). It can be measured by gas chromatography method))).
本発明の水中油型乳化組成物は、油脂として乳脂を含有すると、風味が良好となり、乳化剤に起因する異味も抑制できる。これらの点を考慮すると、乳脂の含有量は、油脂全量に対して25〜60質量%が好ましい。この範囲内であると風味が向上するとともに、耐酸耐熱性と白色度も良好である。乳脂の由来としては、特に限定されないが、例えば、バター、バターオイル、生クリームや、加工油脂原料として使用されている、商業的に入手可能な、植物性油脂と乳脂を含む調製食用脂など、あるいは乳脂の由来となるこれらの原料に、分別、脱色、脱臭のうちのいずれか1種または2種以上の処理を施したものを用いることができる。乳脂の由来としては、乳化安定性の面から、水分を含まないものが好ましい。 When the oil-in-water emulsion composition of the present invention contains milk fat as an oil or fat, the flavor becomes good, and an unpleasant taste caused by the emulsifier can also be suppressed. Considering these points, the content of milk fat is preferably 25 to 60% by mass with respect to the total amount of oil. Within this range, the flavor is improved and the acid heat resistance and whiteness are also good. The origin of milk fat is not particularly limited, but, for example, butter, butter oil, fresh cream, processed fats and oils, commercially available, prepared edible fats including vegetable fats and milk fats, etc. Alternatively, those raw materials from which milk fat is derived can be used after any one or more of fractionation, decolorization, and deodorization treatment. The origin of milk fat is preferably one that does not contain water from the viewpoint of emulsion stability.
本発明の水中油型乳化組成物は、融点40℃以上の極度硬化油の含有量が油脂全量に対して1質量%以下である。融点40℃以上の極度硬化油の使用量を少なくすることで、ラウリン系油脂を必須とする本発明の油脂組成において特徴的な、口に入れた後に速やかに溶け、清涼感のある口溶けが得られるとともに、乳化剤に起因する異味も抑制できる。なお、融点は、基準油脂分析法(公益社団法人日本油化学会)の「3.2.2.2−2013 融点(上昇融点)」で測定することができる。 In the oil-in-water emulsion composition of the present invention, the content of extremely hardened oil having a melting point of 40 ° C. or higher is 1% by mass or less based on the total amount of fats and oils. By reducing the amount of extremely hardened oil having a melting point of 40 ° C. or higher, it is characteristic in the oil composition of the present invention that requires lauric oil and fat. In addition, the off-taste attributed to the emulsifier can be suppressed. In addition, melting | fusing point can be measured by "3.2.2.2-2013 melting | fusing point (rising melting | fusing point)" of a reference | standard fats and oils analysis method (Japan Oil Chemical Society).
本発明の水中油型乳化組成物における油脂の含有量Xは、30〜50質量%である。この範囲内であると、耐酸耐熱性が向上し、酸性下でも分離や凝集が抑制され、広範囲のpHにて加熱を受けても乳化状態が安定であり、さらに殺菌に必要な高温での加熱処理による分離や凝集も抑制することができる。 Content X of the fats and oils in the oil-in-water emulsion composition of this invention is 30-50 mass%. Within this range, acid heat resistance is improved, separation and aggregation are suppressed even under acidic conditions, the emulsified state is stable even when heated in a wide range of pH, and heating at a high temperature necessary for sterilization. Separation and aggregation due to processing can also be suppressed.
本発明の水中油型乳化組成物は、水相に、HLBが11以上、重合度が10以上、構成脂肪酸の炭素数が18以上であるポリグリセリン脂肪酸エステルを含有する。 The oil-in-water emulsion composition of the present invention contains a polyglycerin fatty acid ester having an HLB of 11 or more, a polymerization degree of 10 or more, and a constituent fatty acid having 18 or more carbon atoms in the aqueous phase.
このポリグリセリン脂肪酸エステルは、HLBが好ましくは11〜15、構成脂肪酸の炭素数が好ましくは18〜22である。 This polyglycerin fatty acid ester preferably has an HLB of 11 to 15, and the constituent fatty acid preferably has 18 to 22 carbon atoms.
なお、ここでポリグリセリン脂肪酸エステルのHLBは、下記Griffin式(Atlas社法)で計算した値である。
HLB=20×(1−S/A)
上記式中、Sはエステルのケン化価、Aは脂肪酸の酸価である。
Here, the HLB of the polyglycerin fatty acid ester is a value calculated by the following Griffin equation (Atlas method).
HLB = 20 × (1-S / A)
In the above formula, S is the saponification value of the ester, and A is the acid value of the fatty acid.
ポリグリセリン脂肪酸エステルは、ポリグリセリンと脂肪酸がエステル化したものであり、脂肪酸としては、ステアリン酸、オレイン酸、リノール酸、リノレン酸、アラキジン酸、エイコセン酸、ベヘン酸、エルカ酸等が挙げられる。中でも、飽和脂肪酸が好ましく、ステアリン酸、ベヘン酸がより好ましい。 The polyglycerol fatty acid ester is obtained by esterifying polyglycerol and a fatty acid, and examples of the fatty acid include stearic acid, oleic acid, linoleic acid, linolenic acid, arachidic acid, eicosenoic acid, behenic acid, erucic acid and the like. Of these, saturated fatty acids are preferable, and stearic acid and behenic acid are more preferable.
本発明においては、上記ポリグリセリン脂肪酸エステルとして、水を含むものであっても、水を含まないものであってもよく、市販のものを用いることができる。例えば、阪本薬品工業(株)製のSYグリスターMSW−7S、三菱化学フーズ(株)製のDシリーズSWA−10D、SWA−15D、SWA20D、太陽化学(株)製のサンソフトQ−18S、サンソフトQ−182Sなどが挙げられる。 In the present invention, the polyglycerin fatty acid ester may contain water or may not contain water, and commercially available products may be used. For example, SY Grister MSW-7S manufactured by Sakamoto Pharmaceutical Co., Ltd., D Series SWA-10D, SWA-15D, SWA20D manufactured by Mitsubishi Chemical Foods, Inc., Sunsoft Q-18S manufactured by Taiyo Kagaku Co., Ltd. Software Q-182S etc. are mentioned.
ポリグリセリン脂肪酸エステルの含有量Yは、水中油型乳化組成物の全量に対して0.3〜3.0質量%である。この範囲内であると、耐酸耐熱性が良く、白色度が良好で、口溶けも良いものが得られる。なお、ポリグリセリン脂肪酸エステルの含有量Yは、固形分としての値である。 The content Y of the polyglycerin fatty acid ester is 0.3 to 3.0% by mass with respect to the total amount of the oil-in-water emulsion composition. Within this range, a product having good acid heat resistance, good whiteness, and good melting in the mouth can be obtained. In addition, content Y of polyglycerol fatty acid ester is a value as solid content.
本発明の水中油型乳化組成物は、前記ポリグリセリン脂肪酸エステルの含有量Yが0.3〜3.0質量%、油脂の含有量Xが30〜50質量%、油滴のメディアン径Rが0.4〜1.0μmであり、油脂の含有量Xと、油滴のメディアン径Rと、前記ポリグリセリン脂肪酸エステルの合計量Yが前記式(I)で表わされる関係を満足する。この関係を満足することによって、耐酸耐熱性が向上し、酸性下でも分離や凝集が抑制され、広範囲のpHにて加熱を受けても乳化状態が安定であり、さらに殺菌に必要な高温での加熱処理による分離や凝集も抑制することができる。また、これを添加した冷菓等の食品は白色度が良好で、かつ異味がなく口溶けも良い。 In the oil-in-water emulsion composition of the present invention, the polyglycerin fatty acid ester content Y is 0.3 to 3.0 mass%, the fat and oil content X is 30 to 50 mass%, and the median diameter R of the oil droplets is 0.4 to 1.0 μm, and the oil content X, the median diameter R of the oil droplets, and the total amount Y of the polyglycerin fatty acid ester satisfy the relationship represented by the formula (I). By satisfying this relationship, acid heat resistance is improved, separation and aggregation are suppressed even under acidic conditions, the emulsified state is stable even when heated in a wide range of pH, and at a high temperature necessary for sterilization. Separation and aggregation by heat treatment can also be suppressed. In addition, foods such as frozen confectionery to which this is added have good whiteness and have no off-flavors and can melt in the mouth.
前記式(I)は、水中油型乳化組成物における油滴の全表面積に対し、安定し、かつ食品の白色度と口溶けの良好な水中油型乳化組成物を製造できる適当な乳化剤使用量の範囲を示している。油球表面積に対して適切な乳化剤量ではない場合、すなわち不等式の範囲外の乳化剤量を使用した場合、良好な乳化状態を保つことができなくなるか、あるいは食品の白色度や口溶けの低下を抑制することはできなくなる。 The formula (I) is an appropriate amount of emulsifier used to produce an oil-in-water emulsion composition that is stable with respect to the total surface area of the oil droplets in the oil-in-water emulsion composition and that has good whiteness and good meltability in food. The range is shown. If the amount of emulsifier is not appropriate for the surface area of the oil ball, that is, if an emulsifier amount outside the range of the inequality is used, it will not be possible to maintain a good emulsified state, or suppress the decrease in food whiteness and mouth melting You can't do that.
なお、油滴のメディアン径Rは、油滴の粒度分布をレーザー回折散乱法によって測定し、粒度分布からメディアン径(積算で50体積%における直径)を算出することで得ることができる。 The median diameter R of the oil droplets can be obtained by measuring the particle size distribution of the oil droplets by a laser diffraction scattering method and calculating the median diameter (integrated diameter at 50% by volume) from the particle size distribution.
油滴のメディアン径Rが0.4μm以上であると、前記式(I)で表わされる関係を満足することで、白色度が良く異味の少ない食品を得ることができる。油滴のメディアン径Rが1.0μm以下であると、前記式(I)で表わされる関係を満足することで、水中油型乳化組成物の乳化安定性が良好である。 When the median diameter R of the oil droplets is 0.4 μm or more, a food with good whiteness and little off-taste can be obtained by satisfying the relationship represented by the formula (I). When the median diameter R of the oil droplets is 1.0 μm or less, the emulsion stability of the oil-in-water emulsion composition is good by satisfying the relationship represented by the formula (I).
本発明の水中油型乳化組成物には、必要に応じて、水中油型乳化組成物に通常使用される各種の食品素材や食品添加物などを添加することができる。具体的には、乳、乳製品、乳化剤、pH調整剤、糖質、フレーバー、酸化防止剤などが挙げられる。 In the oil-in-water emulsion composition of the present invention, various food materials or food additives usually used in an oil-in-water emulsion composition can be added as necessary. Specific examples include milk, dairy products, emulsifiers, pH adjusters, sugars, flavors, antioxidants and the like.
乳製品としては、濃縮乳、脱脂濃縮乳、無糖練乳、無糖脱脂練乳、加糖練乳、加糖脱脂練乳、全粉乳、ホエイパウダー、脱脂粉乳、クリームパウダー、乳タンパク、バターミルクパウダー、加糖粉乳、調製粉乳などが挙げられる。風味の面から、乳糖を含む乳製品を使用することが好ましく、固形分として乳糖を50質量%以上含む乳製品がより好ましく、70質量%以上含む乳製品がより好ましい。このような乳製品としては、ホエイパウダーや脱脂粉乳が挙げられ、市販品としては、よつ葉乳業株式会社製のホエイパウダー(乳糖含量 78質量%)、脱脂粉乳(乳糖含量 51質量%)等が挙げられる。 As dairy products, concentrated milk, defatted concentrated milk, sugar-free condensed milk, sugar-free defatted condensed milk, sweetened condensed milk, sweetened defatted condensed milk, whole powdered milk, whey powder, skim powdered milk, cream powder, milk protein, buttermilk powder, sweetened powdered milk, Examples include prepared milk powder. From the aspect of flavor, it is preferable to use a dairy product containing lactose, more preferably a dairy product containing 50% by mass or more of lactose as a solid content, and more preferably a dairy product containing 70% by mass or more. Examples of such dairy products include whey powder and skim milk powder, and examples of commercially available products include whey powder (lactose content 78% by mass) and skim milk powder (lactose content 51% by mass) manufactured by Yotsuba Dairy Co., Ltd. It is done.
乳化剤としては、例えば、前記ポリグリセリン脂肪酸エステルの他に、ショ糖脂肪酸エステル、グリセリン脂肪酸エステル、有機酸グリセリン脂肪酸エステル、ポリグリセリン縮合リシノレイン酸エステル、ソルビタン脂肪酸エステル、プロピレングリコール脂肪酸エステル、ポリオキシエチレンソルビタン脂肪酸エステル、ステアロイル乳酸カルシウムなどが挙げられ、本発明の効果を損なわない範囲内において使用することができる。 Examples of the emulsifier include, in addition to the polyglycerin fatty acid ester, sucrose fatty acid ester, glycerin fatty acid ester, organic acid glycerin fatty acid ester, polyglycerin condensed ricinoleic acid ester, sorbitan fatty acid ester, propylene glycol fatty acid ester, polyoxyethylene sorbitan. A fatty acid ester, a stearoyl calcium lactate, etc. are mentioned, It can use within the range which does not impair the effect of this invention.
pH調整剤としては、リン酸塩、メタリン酸塩、ポリリン酸塩、ピロリン酸塩等の無機塩類、クエン酸塩、酒石酸塩等の有機酸塩類などが挙げられる。 Examples of the pH adjuster include inorganic salts such as phosphate, metaphosphate, polyphosphate, and pyrophosphate, and organic acid salts such as citrate and tartrate.
糖質としては、砂糖、異性化糖、液糖、澱粉糖化物、糖アルコール、カラギーナン、グァーガム、キサンタンガム、タマリンドガム、アルギン酸塩、ファーセルラン、ローカストビーンガム、ペクチン、カードラン、ジェランガム、結晶セルロース、ゼラチン、寒天、澱粉、加工澱粉等が挙げられる。これらは1種単独で使用してもよく2種以上を併用してもよい。 Sugars include sugar, isomerized sugar, liquid sugar, saccharified starch, sugar alcohol, carrageenan, guar gum, xanthan gum, tamarind gum, alginate, farsellan, locust bean gum, pectin, curdlan, gellan gum, crystalline cellulose , Gelatin, agar, starch, modified starch and the like. These may be used alone or in combination of two or more.
本発明の水中油型乳化組成物は、従来と同様の方法で製造することができる。例えば、油脂を含む油相と、水相を予備乳化した後、均質化、加熱殺菌、冷却、エージング等の工程を経て製造される。 The oil-in-water emulsion composition of the present invention can be produced by the same method as before. For example, after pre-emulsifying an oil phase containing fats and oils and an aqueous phase, it is produced through steps such as homogenization, heat sterilization, cooling, and aging.
予備乳化では、高圧ホモジナイザー等の均質機で均質化処理を行う前に、ホモミキサー等を用いて油相と水相を混合し、油滴を水相中にある程度分散させる。油相には油脂の他に、親油性の乳化剤等を添加してもよく、親水性の乳化剤、乳製品、pH調整剤、糖質等は水相に添加することができる。 In the pre-emulsification, the oil phase and the aqueous phase are mixed using a homomixer or the like before the homogenization treatment is performed with a homogenizer such as a high-pressure homogenizer, and the oil droplets are dispersed to some extent in the aqueous phase. In addition to fats and oils, lipophilic emulsifiers and the like may be added to the oil phase, and hydrophilic emulsifiers, dairy products, pH adjusters, sugars and the like can be added to the aqueous phase.
予備乳化は、油相については油脂が完全に溶解する温度に加温し、水相については混合後の油相が温度低下を起こさない温度に加温し、油相と水相を混合し、好ましくは55〜80℃、より好ましくは60〜75℃で行うことができる。予備乳化を行った後の乳化物は、減圧して脱泡を行ってもよい。 In the pre-emulsification, the oil phase is heated to a temperature at which fats and oils are completely dissolved, the water phase is heated to a temperature at which the mixed oil phase does not cause a temperature decrease, and the oil phase and the water phase are mixed, Preferably it can carry out at 55-80 degreeC, More preferably, it can carry out at 60-75 degreeC. The emulsion after the preliminary emulsification may be defoamed under reduced pressure.
均質化は、高圧ホモジナイザー等の均質機を用いて、従来より水中油型乳化組成物の製造に用いられている圧力等の条件で行うことができ、圧力は例えば0〜100MPaの範囲で適宜に設定して行うことができる。この均質化の工程において油滴のメディアン径を調整することができる。また均質化の前後の工程として、加熱殺菌処理を行ってもよく、また均質化処理を行った後に加熱殺菌処理を行い、更にその後に均質化処理を行ってもよい。 Homogenization can be performed using a homogenizer such as a high-pressure homogenizer under conditions such as pressure conventionally used in the production of oil-in-water emulsion compositions, and the pressure is suitably in the range of, for example, 0 to 100 MPa. Can be set and done. In this homogenization step, the median diameter of the oil droplets can be adjusted. Further, as a step before and after the homogenization, a heat sterilization treatment may be performed, a heat sterilization treatment may be performed after the homogenization treatment, and a homogenization treatment may be performed thereafter.
均質化処理時の乳化物の液温は、均質化処理の効率等の観点から、好ましくは50〜80℃、より好ましくは60〜70℃である。 The liquid temperature of the emulsion during the homogenization treatment is preferably 50 to 80 ° C, more preferably 60 to 70 ° C, from the viewpoint of the efficiency of the homogenization treatment.
加熱殺菌処理は、水中油型乳化組成物の各成分を混合して調合し、乳化を行った後に、均質化処理の前後等で行うことができる。加熱殺菌処理としては、微生物等を原因とする食品の物性変化を抑制できる処理であれば特に限定されるものではなく、一般に水中油型乳化組成物の製造工程に用いられる方法等を用いることができ、例えば高温短時間殺菌法(HTST)、超高温殺菌法(UHT)等が挙げられる。中でも殺菌効率や風味等を考慮すると超高温殺菌法(UHT)が好ましい。殺菌温度と処理時間は、例えば高温短時間殺菌法(HTST)の場合は82〜85℃で10秒間前後が好ましく、超高温殺菌法(UHT)の場合は、120〜150℃で2〜15秒間が好ましい。 The heat sterilization treatment can be performed before and after the homogenization treatment after mixing and preparing each component of the oil-in-water emulsion composition and emulsifying. The heat sterilization treatment is not particularly limited as long as it is a treatment capable of suppressing changes in the physical properties of foods caused by microorganisms and the like, and generally a method used in the production process of an oil-in-water emulsion composition is used. For example, high temperature short time sterilization method (HTST), ultra high temperature sterilization method (UHT), etc. are mentioned. Of these, the ultra high temperature sterilization method (UHT) is preferable in consideration of sterilization efficiency, flavor, and the like. The sterilization temperature and treatment time are preferably about 82 seconds at 85 to 85 ° C. for high temperature short time sterilization method (HTST), and about 2 to 15 seconds at 120 to 150 ° C. for ultra high temperature sterilization method (UHT). Is preferred.
加熱殺菌処理方式は、乳化物に蒸気を直接吹き込むインジェクション方式、蒸気雰囲気中に乳化物を入れ込むインフュージョン方式等によって、乳化物に直接蒸気を作用させて瞬間的に温度を上げて殺菌した後に減圧工程で蒸発冷却する方法や、プレートやチューブラ等の熱媒体と間接的に乳化物を接触させることで温度を上げて殺菌した後に、同様の方法で冷媒体と間接的に食品を接触させることで冷却する方法等で行うことができる。 The heat sterilization treatment method is a method in which steam is directly applied to the emulsion to sterilize it by instantaneously applying steam to the emulsion, such as an injection method in which steam is directly blown into the emulsion, or an infusion method in which the emulsion is put into a steam atmosphere. After evaporating and cooling in the depressurization process, or sterilizing by raising the temperature by bringing the emulsion into contact with a heat medium such as a plate or tubular indirectly, then bringing the food into contact with the refrigerant in the same way It can be performed by a method such as cooling with.
前記の均質化処理を行った後の乳化物は冷却される。冷却は、油脂の結晶性の制御等も考慮し、例えば、プレート式、チューブ式、掻き取り式等の熱交換器を用いて、短時間で1〜7℃の温度範囲まで冷却することが好ましい。 The emulsified product after the homogenization treatment is cooled. Cooling is preferably performed in a short time using a heat exchanger such as a plate type, a tube type, or a scraping type, taking into account the control of the crystallinity of oils and fats. .
冷却後、タンクに移送し、例えば冷却温度にて1〜2日程度エージングを行ってもよい。その後、水中油型乳化組成物は、適宜所定の容器に充填される。 After cooling, it may be transferred to a tank and aged at, for example, the cooling temperature for about 1 to 2 days. Thereafter, the oil-in-water emulsion composition is appropriately filled in a predetermined container.
本発明の水中油型乳化組成物は、酸性条件や殺菌に必要な加熱処理による分離や凝集が抑制されることから、pHの比較的低い食品や飲料、レトルト殺菌を行う食品や飲料として好適に用いることができる。 The oil-in-water emulsified composition of the present invention is suitably used as a food or beverage having a relatively low pH and a food or beverage for retort sterilization because separation and aggregation due to heat treatment necessary for acidic conditions and sterilization are suppressed. Can be used.
レトルト殺菌は、例えば、アルミパウチ、テーブルカップ、透明パウチ、缶、チアパック等の密封容器に、本発明の水中油型乳化組成物を用いた食品や飲料を封入し、80〜135℃で5〜60分間での処理が行われる。 For retort sterilization, for example, foods and beverages using the oil-in-water emulsion composition of the present invention are sealed in sealed containers such as aluminum pouches, table cups, transparent pouches, cans, cheer packs, and the like. Processing in 60 minutes is performed.
本発明の水中油型乳化組成物は、冷菓、ホワイトソース、デミグラスソース、ドレッシングなどのソース類、クリームシチューなどのシチュー類、カスタードクリーム、フラワーペーストなどのフィリング類、スープ類等の原料として使用することができる。 The oil-in-water emulsified composition of the present invention is used as a raw material for frozen desserts, white sauces, demiglace sauces, dressings and other sauces, stew such as cream stew, custard cream, fillings such as flower paste, soups, etc. Can do.
冷菓としては、ゼリー、ムース、ババロア等が挙げられる。ゼリーは、果汁やワイン等に砂糖等の甘味を加え、ゲル化剤によって固めたもので、これにフレーバー、果肉、乳製品、鶏卵、酸味料などを加えたもの等が挙げられる。ムースは、鶏卵やクリームで作られる軽くふんわりした食感のデザートであり、主にフルーツのピューレやチョコレート等と組み合わされる。果汁やフルーツ、あるいは酸味料等の酸味成分を加えて加工したゼリー、ムース等は、常温でかつ長期間の消費期限が要求される場合もあり、このような場合には高温での殺菌が必要とされるが、本発明の水中油型乳化組成物は酸性下でも分離や凝集が抑制され、広範囲のpHにて加熱を受けても乳化状態が安定である。 Examples of frozen desserts include jelly, mousse and bavaroa. Jelly is obtained by adding sweetness such as sugar to fruit juice, wine, etc., and hardening with a gelling agent, and flavors, pulp, dairy products, chicken eggs, acidulants and the like. Moose is a light and fluffy dessert made from eggs and cream and is mainly combined with fruit puree and chocolate. Jelly, mousse, etc. processed by adding sour ingredients such as fruit juice, fruit, or acidulant may require a long-term expiration date at room temperature. In such cases, sterilization at high temperature is required. However, the oil-in-water emulsion composition of the present invention can be separated and aggregated even under acidic conditions, and the emulsion state is stable even when heated in a wide range of pH.
スープ類としては、コンソメ、ポタージュ、とんこつスープ等のラーメンスープ、トムヤムクン、酸辣湯等の中華スープ、カレースープ等が挙げられる。 Examples of soups include ramen soups such as consomme, potage, and tonkotsu soups, Chinese soups such as Tom Yum Goong and Sodayu, and curry soups.
本発明の水中油型乳化組成物は、酸性条件下において、起泡させることができる。さらに、起泡させて得られたホイップドクリームは、物性面において安定であることから、必要に応じて冷蔵保存した後、二次加工に供される。ここで二次加工には、起泡後にナッペマシーンや、デポジッター等を通過させる機械を用いた成形手法や、スパテラを用いたナッペやしぼり袋を用いた注入等、手作業による成形手法が含まれる。 The oil-in-water emulsion composition of the present invention can be foamed under acidic conditions. Furthermore, since the whipped cream obtained by foaming is stable in terms of physical properties, it is subjected to secondary processing after refrigerated storage as necessary. Here, secondary processing includes manual molding techniques such as molding using a machine that passes a nappe machine or a depositer after foaming, and injection using a nappe or spatula bag using a spatula. .
以下に、実施例により本発明をさらに詳しく説明するが、本発明はこれらの実施例に何ら限定されるものではない。
(1)水中油型乳化組成物の調製
表1〜表5に示す配合で、水中油型乳化組成物を調製した。所定の油脂含量(X)になるよう量った油脂に乳化剤を添加し油相とした。一方、水に乳化剤、乳タンパク、ホエイパウダー、増粘多糖類を添加し水相とした。水相と油相を60℃に加温し、水相に油相を添加し攪拌して乳化した後、直接加熱殺菌機で、高温(約140℃)で殺菌し、高圧ホモジナイザーで最終的な水中油型乳化組成物の油滴のメディアン径が目標値となるように均質化した。さらにプレート式冷却器で3℃に急冷し、5℃で保管した。
EXAMPLES Hereinafter, the present invention will be described in more detail with reference to examples. However, the present invention is not limited to these examples.
(1) Preparation of oil-in-water emulsion composition Oil-in-water emulsion compositions were prepared according to the formulations shown in Tables 1 to 5. An emulsifier was added to the fats and oils weighed so as to have a predetermined fat and oil content (X) to form an oil phase. On the other hand, an emulsifier, milk protein, whey powder and polysaccharide thickener were added to water to obtain an aqueous phase. The water phase and the oil phase are heated to 60 ° C., the oil phase is added to the water phase, and the mixture is stirred and emulsified. The oil droplets of the oil-in-water emulsion composition were homogenized so that the median diameter reached the target value. Further, it was rapidly cooled to 3 ° C. with a plate type cooler and stored at 5 ° C.
※1:太陽化学(株)製 サンラクトN12(乳清タンパク、乳糖含量 7.4質量%)
※2:よつ葉乳業(株)製 ホエイパウダー(乳糖含量 78質量%)
※3:阪本薬品工業(株)製 MSW−7S デカグリセリンモノステアリン酸エステル HLB 13.4 固形分40%
※4:阪本薬品工業(株)製 TS−7S デカグリセリントリステアリン酸エステル HLB 10.0 固形分100%
※5:阪本薬品工業(株)製 MS−5S ヘキサグリセリンモノステアリン酸エステル HLB 11.6 固形分100%
* 1: Sanlacto N12 manufactured by Taiyo Chemical Co., Ltd. (whey protein, lactose content 7.4% by mass)
* 2: Whey powder manufactured by Yotsuba Milk Industry Co., Ltd. (lactose content 78% by mass)
* 3: MSW-7S decaglycerin monostearate manufactured by Sakamoto Pharmaceutical Co., Ltd. HLB 13.4 Solid content 40%
* 4: TS-7S decaglycerin tristearate ester by Sakamoto Pharmaceutical Co., Ltd. HLB 10.0 100% solids
* 5: MS-5S hexaglycerin monostearate manufactured by Sakamoto Pharmaceutical Co., Ltd. HLB 11.6 100% solids
(2)ゼリーの作製
水中油型乳化組成物15質量%に、液糖20質量%、グラニュー糖5質量%、ゲル化剤1.5質量%、クエン酸0.3質量%、クエン酸三ナトリウム0.1質量%、水58.1質量%を配合し、85℃で30分殺菌を行った後、冷却して酸性のゼリーを作製した。
(2) Preparation of jelly 15% by mass of an oil-in-water emulsion composition, 20% by mass of liquid sugar, 5% by mass of granulated sugar, 1.5% by mass of gelling agent, 0.3% by mass of citric acid, trisodium citrate 0.1% by mass and 58.1% by mass of water were blended, sterilized at 85 ° C. for 30 minutes, and then cooled to produce an acidic jelly.
(3)評価
実施例および比較例の各試料について次の評価を行った。
(3) Evaluation The following evaluation was performed about each sample of an Example and a comparative example.
なお、水中油型乳化組成物の油滴のメディアン径(R)は、レーザー回折式粒子径分布測定装置(SALD−2300)を用いて測定した。 In addition, the median diameter (R) of the oil droplets of the oil-in-water emulsion composition was measured using a laser diffraction particle size distribution analyzer (SALD-2300).
[粘度]
製造後、翌々日、水中油型乳化組成物をB型粘度計(東京計器製)を用いて5℃、No.1ローター、20rpm、30秒の条件で粘度を測定し、以下の基準で評価した。
評価基準
◎:70mPa・s超100mPa・s以下
〇:50mPa・s超70mPa・s以下、または100mPa・s超
150mPa・s以下
△:20mPa・s以上50mPa・s以下、または150mPa・s超
200mPa・s以下
×:200mPa・s超
[viscosity]
Two days after the production, the oil-in-water emulsion composition was subjected to 5 ° C. No. using a B-type viscometer (manufactured by Tokyo Keiki). The viscosity was measured under the conditions of 1 rotor, 20 rpm, 30 seconds, and evaluated according to the following criteria.
Evaluation criteria A : 70 mPa · s to 100 mPa · s or less ○: 50 mPa · s to 70 mPa · s or less, or 100 mPa · s to 150 mPa · s or less Δ: 20 mPa · s to 50 mPa · s or 150 mPa · s to 200 mPa · s Less than s ×: More than 200 mPa · s
[乳化安定性]
製造後、一晩静置し、粒度分布測定装置にて油滴の粒度分布を測定し、標準偏差や分布データにより、以下の基準で評価した。目視にてハッキリと分離が確認されたものについては、測定を行わず、×と評価した。
評価基準
◎:標準偏差が0.15未満で、凝集が無く、乳化安定性が良好
〇:標準偏差が0.15以上0.2未満で、わずかに凝集があるが、乳化安定性が良好
△:標準偏差が0.2超で、凝集があり、乳化安定性が不良
×:目視にてハッキリと分離が確認され、乳化安定性が不良
[Emulsification stability]
After the production, the mixture was allowed to stand overnight, the particle size distribution of the oil droplets was measured with a particle size distribution measuring device, and evaluated according to the following criteria based on standard deviation and distribution data. About what confirmed clear and isolation | separation visually, it did not measure but evaluated as x.
Evaluation standard ◎: Standard deviation is less than 0.15, no aggregation, good emulsion stability ◯: Standard deviation is 0.15 or more, but less than 0.2, there is slight aggregation, but emulsion stability is good △ : Standard deviation is more than 0.2, aggregation is present, and emulsion stability is poor. X: Clear and separation is visually confirmed, and emulsion stability is poor.
[耐酸耐熱性試験]
1Lのトールビーカーに精製水900gを加え85℃に加熱した。その後水中油型乳化組成物を100g添加し、クエン酸とクエン酸三ナトリウムでpH3に調整し、85℃で30分加熱後、5℃で18時間保管した後、底からの分離距離(mm)を測定し、以下の基準で評価した。
評価基準
◎:15mm以下
〇:15mm超20mm以下
△:20mm超30mm以下
×:30mm超
[Acid heat resistance test]
To a 1 L tall beaker, 900 g of purified water was added and heated to 85 ° C. Thereafter, 100 g of an oil-in-water emulsion composition was added, adjusted to pH 3 with citric acid and trisodium citrate, heated at 85 ° C. for 30 minutes, stored at 5 ° C. for 18 hours, and separation distance from the bottom (mm) Was measured and evaluated according to the following criteria.
Evaluation standard ◎: 15 mm or less ○: Over 15 mm to 20 mm or less Δ: Over 20 mm to 30 mm or less X: Over 30 mm
[ゼリーの口溶け]
作製したゼリーの口溶けについて、パネル10名により試食し、以下の基準で評価した。
評価基準
◎:パネル10名中8名以上が良好であると評価した。
○:パネル10名中7〜5名が良好であると評価した。
△:パネル10名中4〜3名が良好であると評価した。
×:パネル10名中2名以下が良好であると評価した。
[Melting jelly mouth]
About the mouth melting of the produced jelly, it sampled by 10 panels and evaluated with the following references | standards.
Evaluation Criteria A : Eight or more out of 10 panels were evaluated as good.
○: 7 to 5 out of 10 panelists evaluated as good.
(Triangle | delta): Four to three persons evaluated that it was favorable among 10 panelists.
X: Evaluated that 2 or less of 10 panelists were good.
[ゼリーの白色度]
作製したゼリーの白色度を目視にて観察し、以下の基準で評価した。
評価基準
◎:白濁感が強い
○:白濁感がある
△:白濁感がやや弱い
×:白濁感が弱い
[Jelly whiteness]
The whiteness of the prepared jelly was visually observed and evaluated according to the following criteria.
Evaluation criteria ◎: Strong cloudiness ○: There is cloudiness △: Cloudiness is slightly weak ×: Cloudiness is weak
[ゼリーの異味]
作製したゼリーの異味について、パネル10名により試食し、以下の基準で評価した。
評価基準
◎:パネル10名中8名以上が異味を感じないと評価した。
○:パネル10名中7〜5名が異味を感じないと評価した。
△:パネル10名中4〜3名が異味を感じないと評価した。
×:パネル10名中2名以下が異味を感じないと評価した。
[Jelly taste]
The taste of the prepared jelly was sampled by 10 panelists and evaluated according to the following criteria.
Evaluation Criteria A : Evaluated that 8 or more of 10 panelists did not feel strange.
○: 7 to 5 out of 10 panelists evaluated that they did not feel strange.
Δ: Evaluated that 4 to 3 of 10 panelists did not feel any strange taste.
X: It was evaluated that 2 or less of 10 panelists did not feel a strange taste.
[ゼリーの風味]
作製したゼリーの風味について、パネル10名により試食し、以下の基準で評価した。
評価基準
◎:パネル10名中8名以上が良好であると評価した。
○:パネル10名中7〜5名が良好であると評価した。
△:パネル10名中4〜3名が良好であると評価した。
×:パネル10名中2名以下が良好であると評価した。
[Jelly flavor]
The flavor of the prepared jelly was sampled by 10 panelists and evaluated according to the following criteria.
Evaluation Criteria A : Eight or more out of 10 panels were evaluated as good.
○: 7 to 5 out of 10 panelists evaluated as good.
(Triangle | delta): Four to three persons evaluated that it was favorable among 10 panelists.
X: Evaluated that 2 or less of 10 panelists were good.
上記の評価結果を表6〜表10に示す。 The evaluation results are shown in Tables 6 to 10.
(4)水中油型乳化組成物を用いたホイップドクリームの作製と評価
(4−1)ホイップドクリームの作製
表11の配合割合に従い、卓上ミキサー(Kitchen Aid社製)による起泡性試験を行った。水中油型乳化組成物400gを5クォートミキサーボールへ入れ、グラニュー糖を48g添加し、製品温度5℃、クエン酸にてpHを3.0に調整し、スピード4にて比重が0.3になるまで起泡した。
(4) Production and evaluation of whipped cream using oil-in-water emulsion composition (4-1) Production of whipped cream According to the blending ratio in Table 11, a foaming test using a tabletop mixer (manufactured by Kitchen Aid) was conducted. went. Put 400g of oil-in-water emulsified composition into a 5 quart mixer bowl, add 48g of granulated sugar, adjust the pH to 3.0 with product temperature 5 ° C and citric acid, and the specific gravity to 0.3 at speed 4 Foamed until
(4−2)起泡性試験
起泡後のホイップドクリームは、プラスチックカップに花形状に絞り、直後の造花性、15℃で18時間後の保形性、離水性を評価した。
(4-2) Foaming property test The whipped cream after foaming was squeezed into a flower shape in a plastic cup and evaluated for flowering properties immediately after, shape retention after 15 hours at 15 ° C, and water separation.
[造花性]
評価基準
◎:きれいなツノができる。
○:ほぼきれいなツノができる。またはツノが少し垂れる。
△:きれいなツノができない。またはツノが垂れる。
×:ツノができない。
[Artificial properties]
Evaluation criteria A : A beautiful horn can be formed.
○: An almost beautiful horn can be formed. Or the horn droops a little.
Δ: A beautiful horn cannot be formed. Or horns droop.
X: No horn.
[保形性]
評価基準
◎:造花直後と比較して形状の変化なし。
○:やや形状の変化がある。または若干「しわ」のようなものが見える。
△:かなり形が崩れている。または「しわ」のようなものが見える。
×:完全に形が崩れている。または「ひび」が入っている。
[Shape retention]
Evaluation criteria A : No change in shape compared to immediately after artificial flowering.
○: Some change in shape. Or you can see some “wrinkles”.
Δ: The shape is considerably broken. Or you can see something like “wrinkles”.
X: The shape is completely broken. Or there is a “crack”.
[離水性]
評価基準
◎:造花直後と比較して離水が認められない。
○:やや離水が認められる。
△:かなりの離水が認められる。
×:離水が激しい。
[Water separation]
Evaluation Criteria A : Water separation is not observed compared to immediately after artificial flowering.
○: Some water separation is recognized.
Δ: Considerable water separation is observed.
X: Water separation is intense.
(4−3)二次加工試験
起泡直後のホイップドクリームをデポジッターに通過させ、プラスチックカップに花形状に絞り、直後の造花性、15℃で18時間後の保形性、離水性を評価した。
(4-3) Secondary processing test The whipped cream immediately after foaming is passed through a depositor, and is squeezed into a flower shape in a plastic cup, and immediately after artificial flowering, shape retention after 18 hours at 15 ° C., and water separation are evaluated. did.
[造花性]
評価基準
◎:きれいなツノができる。
○:ほぼきれいなツノができる。またはツノが少し垂れる。
△:きれいなツノができない。またはツノが垂れる。
×:ツノができない。
[Artificial properties]
Evaluation criteria A : A beautiful horn can be formed.
○: An almost beautiful horn can be formed. Or the horn droops a little.
Δ: A beautiful horn cannot be formed. Or horns droop.
X: No horn.
[保形性]
評価基準
◎:造花直後と比較して形状の変化なし。
○:やや形状の変化がある。または若干「しわ」のようなものが見える。
△:かなり形が崩れている。または「しわ」のようなものが見える。
×:完全に形が崩れている。または「ひび」が入っている。
[Shape retention]
Evaluation criteria A : No change in shape compared to immediately after artificial flowering.
○: Some change in shape. Or you can see some “wrinkles”.
Δ: The shape is considerably broken. Or you can see something like “wrinkles”.
X: The shape is completely broken. Or there is a “crack”.
[離水性]
評価基準
◎:造花直後と比較して離水が認められない。
○:やや離水が認められる。
△:かなりの離水が認められる。
×:離水が激しい。
[Water separation]
Evaluation Criteria A : Water separation is not observed compared to immediately after artificial flowering.
○: Some water separation is recognized.
Δ: Considerable water separation is observed.
X: Water separation is intense.
上記の評価結果を表11に示す。 The evaluation results are shown in Table 11.
(4−4)チーズクリームの作製
上記において得られた水中油型乳化組成物を用い、表12の配合割合により起泡を有するチーズクリームを作製した。柔らかくしたクリームチーズ、水中油型乳化組成物、グラニュー糖、加糖練乳、濃縮レモン汁、卵黄加工品を90クォートミキサーボールへ入れ、ミキサー(関東混合機工業株式会社製)にて比重が0.46になるまで起泡した。
(4-4) Production of cheese cream Using the oil-in-water emulsion composition obtained above, a cheese cream having foaming was produced according to the blending ratio in Table 12. Softened cream cheese, oil-in-water emulsified composition, granulated sugar, sweetened condensed milk, concentrated lemon juice, processed egg yolk product are placed in a 90 quart mixer ball, and the specific gravity is 0.46 using a mixer (manufactured by Kanto Blender Kogyo Co., Ltd.). Foamed until
(4−5)起泡性試験
起泡後のクリームは、プラスチックカップに花形状に絞り、直後の造花性、15℃で18時間後の保形性、離水性、異味を評価した。
(4-5) Foaming test The foamed cream was squeezed into a flower shape in a plastic cup, and was evaluated for flower-forming properties immediately afterwards, shape retention after 15 hours at 15 ° C, water releasability, and taste.
[造花性]
評価基準
◎:きれいなツノができる。
○:ほぼきれいなツノができる。またはツノが少し垂れる。
△:きれいなツノができない。またはツノが垂れる。
×:ツノができない。
[Artificial properties]
Evaluation criteria A : A beautiful horn can be formed.
○: An almost beautiful horn can be formed. Or the horn droops a little.
Δ: A beautiful horn cannot be formed. Or horns droop.
X: No horn.
[保形性]
評価基準
◎:造花直後と比較して形状の変化なし。
○:やや形状の変化がある。または若干「しわ」のようなものが見える。
△:かなり形が崩れている。または「しわ」のようなものが見える。
×:完全に形が崩れている。または「ひび」が入っている。
[Shape retention]
Evaluation criteria A : No change in shape compared to immediately after artificial flowering.
○: Some change in shape. Or you can see some “wrinkles”.
Δ: The shape is considerably broken. Or you can see something like “wrinkles”.
X: The shape is completely broken. Or there is a “crack”.
[離水性]
評価基準
◎:造花直後と比較して離水が認められない。
○:やや離水が認められる。
△:かなりの離水が認められる。
×:離水が激しい。
[Water separation]
Evaluation Criteria A : Water separation is not observed compared to immediately after artificial flowering.
○: Some water separation is recognized.
Δ: Considerable water separation is observed.
X: Water separation is intense.
[異味]
作製したチーズクリームの異味について、パネル10名により試食し、以下の基準で評価した。
評価基準
◎:パネル10名中8名以上が異味を感じないと評価した。
○:パネル10名中7〜5名が異味を感じないと評価した。
△:パネル10名中4〜3名が異味を感じないと評価した。
×:パネル10名中2名以下が異味を感じないと評価した。
[Disgusting taste]
About the special taste of the produced cheese cream, it sampled by 10 panels and evaluated on the following references | standards.
Evaluation Criteria A : Evaluated that 8 or more of 10 panelists did not feel strange.
○: 7 to 5 out of 10 panelists evaluated that they did not feel strange.
Δ: Evaluated that 4 to 3 of 10 panelists did not feel any strange taste.
X: It was evaluated that 2 or less of 10 panelists did not feel a strange taste.
(4−6)二次加工試験
起泡直後のチーズクリームをデポジッターに通過させ、プラスチックカップに花形状に絞り、直後の造花性、15℃で18時間後の保形性、離水性を評価した。
[造花性]
評価基準
◎:きれいなツノができる。
○:ほぼきれいなツノができる。またはツノが少し垂れる。
△:きれいなツノができない。またはツノが垂れる。
×:ツノができない。
(4-6) Secondary processing test The cheese cream immediately after foaming was passed through a depositor, and the plastic cup was squeezed into a flower shape. Immediate flower formation, shape retention after 18 hours at 15 ° C., and water separation were evaluated. .
[Artificial properties]
Evaluation criteria A : A beautiful horn can be formed.
○: An almost beautiful horn can be formed. Or the horn droops a little.
Δ: A beautiful horn cannot be formed. Or horns droop.
X: No horn.
[保形性]
評価基準
◎:造花直後と比較して形状の変化なし。
○:やや形状の変化がある。または若干「しわ」のようなものが見える。
△:かなり形が崩れている。または「しわ」のようなものが見える。
×:完全に形が崩れている。または「ひび」が入っている。
[Shape retention]
Evaluation criteria A : No change in shape compared to immediately after artificial flowering.
○: Some change in shape. Or you can see some “wrinkles”.
Δ: The shape is considerably broken. Or you can see something like “wrinkles”.
X: The shape is completely broken. Or there is a “crack”.
[離水性]
評価基準
◎:造花直後と比較して離水が認められない。
○:やや離水が認められる。
△:かなりの離水が認められる。
×:離水が激しい。
[Water separation]
Evaluation Criteria A : Water separation is not observed compared to immediately after artificial flowering.
○: Some water separation is recognized.
Δ: Considerable water separation is observed.
X: Water separation is intense.
上記の評価結果を表12に示す。 The evaluation results are shown in Table 12.
Claims (3)
前記ポリグリセリン脂肪酸エステルの含有量Yが0.3〜3.0質量%、
油脂の含有量Xが30〜50質量%、
油滴のメディアン径Rが0.4〜1.0μmであり、
油脂の含有量Xと、油滴のメディアン径Rと、前記ポリグリセリン脂肪酸エステルの合計量Yが次式(I):
前記油脂は、ラウリン系油脂を含有し、かつ融点40℃以上の極度硬化油の含有量が油脂全量に対して1質量%以下である、水中油型乳化組成物。 The aqueous phase contains a polyglycerin fatty acid ester having an HLB of 11 or more, a polymerization degree of 10 or more, and a constituent fatty acid having 18 or more carbon atoms,
The content Y of the polyglycerin fatty acid ester is 0.3 to 3.0% by mass,
Oil content X is 30-50% by mass,
The median diameter R of the oil droplet is 0.4 to 1.0 μm,
The oil content X, the median diameter R of the oil droplets, and the total amount Y of the polyglycerin fatty acid ester are represented by the following formula (I):
The oil and fat is an oil-in-water emulsified composition containing a lauric oil and fat, and the content of an extremely hardened oil having a melting point of 40 ° C. or higher is 1% by mass or less based on the total amount of the oil and fat.
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JP2009095253A (en) * | 2007-10-15 | 2009-05-07 | Mitsubishi Chemicals Corp | O/d-type emulsified composition |
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JP2012170415A (en) * | 2011-02-23 | 2012-09-10 | Fuji Oil Co Ltd | Nonfat milk solid-containing oil-in-water emulsified product |
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JP2007289074A (en) * | 2006-04-25 | 2007-11-08 | Mitsubishi Chemicals Corp | Oil-in-d-phase emulsified composition |
JP2009095253A (en) * | 2007-10-15 | 2009-05-07 | Mitsubishi Chemicals Corp | O/d-type emulsified composition |
JP2012125155A (en) * | 2010-12-13 | 2012-07-05 | Taiyo Kagaku Co Ltd | Method for producing edible oil and fat emulsified product, the edible oil and fat emulsified product, and food and drink using the edible oil and fat emulsified product |
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