JP2007046024A - Heat insulating water-based coating having incombustibility, method for coating photocatalyst and coated film thereof - Google Patents

Heat insulating water-based coating having incombustibility, method for coating photocatalyst and coated film thereof Download PDF

Info

Publication number
JP2007046024A
JP2007046024A JP2005255700A JP2005255700A JP2007046024A JP 2007046024 A JP2007046024 A JP 2007046024A JP 2005255700 A JP2005255700 A JP 2005255700A JP 2005255700 A JP2005255700 A JP 2005255700A JP 2007046024 A JP2007046024 A JP 2007046024A
Authority
JP
Japan
Prior art keywords
water
paint
heat
coating
insulating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2005255700A
Other languages
Japanese (ja)
Inventor
Chitoshi Jinno
千年 神野
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to JP2005255700A priority Critical patent/JP2007046024A/en
Publication of JP2007046024A publication Critical patent/JP2007046024A/en
Pending legal-status Critical Current

Links

Landscapes

  • Application Of Or Painting With Fluid Materials (AREA)
  • Paints Or Removers (AREA)

Abstract

<P>PROBLEM TO BE SOLVED: To provide a coating by compounding an incombustible water-based inorganic coating with heat insulating hollow balloons, rare element mineral particles, an inorganic aggregate, an inorganic calcined pigment, a colored mica, etc., and imparting incombustible and heat-resistant super heat barrier and heat insulation properties thereto, to provide a method for coating the same and to provide a coated film thereof. <P>SOLUTION: The water-based heat insulating and incombustible coating is obtained as follows. A network structure is formed from polymer particles having silanol groups on the surface of siloxane bonds by dehydration condensation of the silanol groups. A substitution reaction of the unreacted silanol groups with polymeric alkyl groups is then carried out and the resultant water-based inorganic coating chemically bound to the silica system is compounded with the hollow balloons having heat insulating effects. <P>COPYRIGHT: (C)2007,JPO&INPIT

Description

本発明は、多機能性塗料に関するものであり、特に断熱材の中空バルーンを多量に水性無機質塗料に混入して、超断熱化した塗膜上に、水性光触媒塗料を塗布し、不燃、超断熱、防汚性を有する塗膜となる塗料と、その塗装方法に関するものである。  TECHNICAL FIELD The present invention relates to a multifunctional coating, and in particular, a water-borne photocatalyst coating is applied to a super-insulating coating film by mixing a large amount of a heat-insulating hollow balloon into a water-based inorganic coating, thereby preventing incombustion and super-insulation. The present invention relates to a paint which becomes a coating film having antifouling properties and a coating method thereof.

断熱材と称する中空バルーンは、有機質系塗料に混合されて断熱塗料として販売されているのが現状である。しかしその内容は中空バルーンの混入量が少なく又有機系樹脂のため、可燃性で燃焼時に多量のガスが発生、又断熱効果を高めるため、塗膜層を厚く塗布すると収縮による亀裂が起きることから、業界では無機質系断熱塗料の研究開発が盛んである。有機質系塗料は基材接着及び塗布方法が容易なことから、無機質系断熱塗料の開発が遅れている。無機質系塗料は主成分がシリカ系のため耐久性には優れるものの、基材接着が悪く厚膜塗布が困難で多量の中空バルーンが混入できないのが常識とされ、問題点が多く水性断熱不燃塗料の研究開発が遅れているのが実情である。  At present, hollow balloons called heat insulating materials are mixed with organic paints and sold as heat insulating paints. However, because the content of the hollow balloon is small and organic resin, it is flammable and generates a large amount of gas during combustion. To increase the heat insulation effect, cracks due to shrinkage occur when the coating layer is thickly applied. The industry is actively researching and developing inorganic heat-insulating paints. Development of inorganic heat-insulating paints is delayed because organic paints are easy to adhere to and apply to base materials. Although inorganic paints are silica-based, the main component is excellent in durability. However, it is common knowledge that a large amount of hollow balloons cannot be mixed due to poor base material adhesion and thick film coating. The actual situation is that R & D in Japan is delayed.

課題を解決するための手段Means for solving the problem

本発明者は、特殊な水性無機質塗料に、性質およびミクロンの異なる４種の中空バルーン、各種の機能を持つ稀元素鉱物粉、無機質骨材、無機焼成顔料、着色雲母および無機質添加剤を混合することにより、高い接着性、厚膜可能な無収縮性、超遮熱性、超断熱性、遠赤外線性および不燃性を見出し、本発明に至った。同時にまた実塗装作業において、有機塗料に勝る重要な要件を解決した。すなわち、本発明者は特殊な水性断熱不燃塗料の開発により、塗装作業において無用の危険物や有害物を環境に放出しない水系塗料となし、塗膜の硬化にあっては特別の加熱を必要としない常温硬化１液型塗料となし、厚膜塗装にあたり重ね塗り不要の固形分の高い遮熱、断熱性に優れた塗料をなし得た。また水性断熱不燃塗料は、高い接着性、超遮熱性、超断熱性、遠赤外線性、着色性、御影石調の多機能を有するため、１液性１工程で３〜４役をなし、その上に水性光触媒塗料を塗布することにより、基材劣化の防止と有機物の分解による防汚効果が得られ、塗装工程の省略化が図れる、優れた簡易工法をなし得た。かくして、上で述べた課題は、本発明に従って解決することができる。以下、これについて説明する。  The inventor mixes four types of hollow balloons having different properties and micron, rare element mineral powder having various functions, inorganic aggregates, inorganic calcined pigments, colored mica and inorganic additives into a special water-based inorganic paint. As a result, high adhesiveness, non-shrinkable properties capable of thick film formation, super heat insulation properties, super heat insulation properties, far-infrared properties, and incombustibility were found, and the present invention was achieved. At the same time, in the actual painting work, the important requirement over organic paint was solved. That is, the present inventor has developed a special water-based heat-insulating non-combustible paint so that it can be used as a water-based paint that does not release unnecessary dangerous or harmful substances to the environment in painting work, and special heating is required for curing the coating film. It was not a room temperature-curing one-pack type paint, and it was possible to obtain a paint having a high solid content heat insulation and excellent heat insulating property that does not require repeated coating in thick film coating. In addition, the water-based heat-insulating non-combustible paint has three functions such as high adhesion, super heat insulation, super heat insulation, far-infrared light, colorability, granite tone, and it plays 3-4 roles in one liquid process. By applying a water-based photocatalyst coating to the surface, it was possible to obtain an excellent simple construction method that prevented the deterioration of the base material and the antifouling effect due to the decomposition of the organic matter, and the painting process could be omitted. Thus, the above mentioned problems can be solved according to the present invention. This will be described below.

まず、上で述べた第１課題は、本発明にかかわる水性断熱不燃塗料によって解決することができる。
すなわち、上で述べた第１課題は本発明に従って、
１、シロキサン結合の表面にシラノール基を持った高分子粒子で、シラノール基の脱水縮合により網目構造を形成、さらに未反応のシラノール基を高分子アルキル基で置換反応してシリカ系と化学結合で形成されてなる、不燃性の水性無機質塗料。
２、該不燃性水性無機質塗料と断熱性素材の中空バルーン、平均粒径５０〜７０μｍ粒子を１００容積率あたり１０〜９０容積率で配合、その他無機質骨材、無機質焼成顔料、稀元素鉱物粉、着色雲母を添加配合し、１００容積率に対し固形分９０〜９５容積率からなる、水性断熱不燃塗料。
３、該水性断熱不燃塗料は１００容積率あたり、好ましくは水性無機質塗料３０％、断熱性中空バルーン６０％、無機質焼成顔料７％、無機質骨材３％の配合からなり、御影石調配合は、無機質焼成顔料７％を着色雲母に置換すること、また遠赤外線配合は、無機質焼成顔料７％を稀元素鉱物粉に、置換することからなる、水性断熱不燃塗料である、上記１〜２のいずれか１つに記載の水性断熱不燃塗料。によって解決することができる。First, the first problem described above can be solved by the water-based heat-insulating non-combustible paint according to the present invention.
That is, the first problem described above is according to the present invention.
1. A polymer particle with silanol groups on the surface of siloxane bonds, and a network structure is formed by dehydration condensation of silanol groups, and unreacted silanol groups are substituted with polymer alkyl groups to form a chemical bond with silica. A non-combustible water-based inorganic paint formed.
2, hollow balloon of the non-combustible water-based inorganic paint and heat insulating material, blended with particles having an average particle size of 50 to 70 μm at a volume ratio of 10 to 90, and other inorganic aggregates, inorganic fired pigments, rare element mineral powders, A water-based heat-insulating non-combustible paint comprising colored mica added and having a solid content of 90 to 95 volume ratio with respect to 100 volume ratio.
3. The water-based heat-insulating incombustible paint comprises 100% by volume, preferably 30% water-based inorganic paint, 60% heat-insulating hollow balloon, 7% inorganic calcined pigment, 3% inorganic aggregate. Either of the above 1-2, which is a water-based heat-insulating non-combustible paint comprising replacing 7% of the calcined pigment with colored mica, and blending far-infrared ray with 7% of the inorganic calcined pigment with rare element mineral powder. The water-based heat-insulating incombustible paint according to one. Can be solved by.

つぎに、上で述べた第２課題は本発明にかかわる塗装方法によって解決することができる。すなわち、上で述べた第２課題は本発明に従って、
４、上記１〜３のいずれか１つに記載の水性断熱不燃塗料を塗布して、常温乾燥することによって塗膜を形成することを特徴とする、塗装方法。
５、上記４で塗布した水性断熱不燃塗料乾燥後、酸化チタン含有の光触媒能を有する水性光触媒塗料を塗布することによって、塗膜を形成することを特徴とする塗装方法。によって解決することができる。Next, the second problem described above can be solved by the coating method according to the present invention. That is, the second problem described above is in accordance with the present invention.
4. A coating method characterized by forming a coating film by applying the water-based heat-insulating incombustible paint according to any one of the above 1 to 3 and drying at room temperature.
5. A coating method comprising forming a coating film by applying a water-based photocatalytic paint having a photocatalytic activity containing titanium oxide after drying the water-based heat-insulating incombustible paint applied in the above 4. Can be solved by.

さらに、上で述べた第３の課題は、本発明にかかわる塗膜によって解決することができる。すなわち、上で述べた第３の課題は本発明に従って、
６、上記４又は５に記載の塗装方法によって形成された塗膜。
７、水性断熱不燃塗料と、水性光触媒塗料を塗布した塗膜によって解決することができる。Furthermore, the third problem described above can be solved by the coating film according to the present invention. That is, the third problem described above is in accordance with the present invention.
6. A coating film formed by the coating method described in 4 or 5 above.
7. It can be solved by a coating film coated with a water-based heat-insulating incombustible paint and a water-based photocatalyst paint.

以下、これらの発明について、詳しく説明する。
本明細書において水性無機質塗料とは、塗料溶媒が水溶性溶媒を軸としたシロキサン結合によるシリカ系と化学結合することであり、基本配合範囲は重量比で、水溶性溶媒６０〜７０％、無機質高分子粒３９〜２７％、添加剤１〜３％であるが、好ましくは水溶性溶媒６５％、無機質高分子粒３４％、添加剤１％である。Hereinafter, these inventions will be described in detail.
In the present specification, the water-based inorganic coating means that the coating solvent is chemically bonded to a silica-based silica based on a water-soluble solvent, and the basic blending range is a weight ratio, the water-soluble solvent is 60 to 70%, the inorganic The polymer particles are 39 to 27% and the additive is 1 to 3%, but the water-soluble solvent is 65%, the inorganic polymer particles are 34%, and the additive is 1%.

つぎに、本明細書において水性断熱不燃塗料とは、１００容積率あたり水性無機質塗料３０％、断熱中空バルーン６０％、無機質焼成顔料及び着色雲母７％、無機質骨材３％であるが、超遮熱、断熱性効果を高めるための配合は、水性無機質塗料の残存固形分が５％以下、中空バルーンが６０％以上でなければ効果が低く、好ましくは、中空バルーンの添加配合割合は、平均μｍ、１３μｍが１０％、５０μｍが４０％、８０μｍが３５％、１００〜１５０μｍが１５％が最も好ましく断熱効果が高い。Next, in this specification, the water-based heat-insulating incombustible paint is 30% water-based inorganic paint, 100% heat-insulating hollow balloon, 7% inorganic fired pigment and colored mica, and 3% inorganic aggregate. The formulation for enhancing the heat and heat insulation effect is low unless the residual solid content of the aqueous inorganic coating is 5% or less and the hollow balloon is 60% or more. Preferably, the blending proportion of the hollow balloon is an average μm. 13 μm is 10%, 50 μm is 40%, 80 μm is 35%, and 100 to 150 μm is most preferably 15%, and the heat insulation effect is high.

本発明の不燃性でなお耐熱温度を高めるための配合は、１００容積率あたり水性無機質塗料３０％以下、残存固形分４％以下で、断熱材を含む無機系素材の溶解点が１，６００℃以上のものを添加混入しなければ耐熱効果が得られない。The nonflammable composition for increasing the heat-resistant temperature of the present invention has a water-based inorganic paint of 30% or less per 100 volume ratio and a residual solid content of 4% or less, and the melting point of the inorganic material including the heat insulating material is 1,600 ° C. If the above is not added and mixed, the heat resistance effect cannot be obtained.

また上記水性断熱不燃塗料を塗膜とした上に、水性光触媒塗料を塗布して防汚効果と不燃性を高めるためには、浸透性を有する水性光触媒塗料が最も好ましい。Further, in order to increase the antifouling effect and nonflammability by applying the aqueous photocatalytic coating material to the above-mentioned aqueous heat-insulating incombustible coating material, an aqueous photocatalytic coating material having permeability is most preferable.

不燃性、耐熱性、接着性
配合割合による不燃性、耐熱温度、接着性試験を実施。Incombustibility, heat resistance, heat resistance, and adhesiveness test by non-flammability, heat resistance, and adhesive composition ratio.

Figure 2007046024
ａ）上記表１の結果から中空バルーンを複合することにより耐熱温度が高い。
ｂ）上記表１の結果から中空バルーン混合比率が多いほど耐熱温度が高い。
ｃ）上記表１の結果から水性無機質塗料が少なく残留固形分が少ないほど耐熱温度が高い。
ｄ）上記表１の結果から付着強さは、水性無機質塗料が多いほど接着強度が高い。
Figure 2007046024
 a) From the results in Table 1 above, the heat resistant temperature is high by combining the hollow balloons.
b) From the results in Table 1 above, the higher the hollow balloon mixing ratio, the higher the heat resistant temperature.
c) From the results in Table 1 above, the lower the water-based inorganic paint and the lower the residual solid content, the higher the heat resistant temperature.
d) From the results of Table 1, the adhesion strength is higher as the amount of the water-based inorganic paint is larger.

断熱性、遮熱性、収縮性
配合割合による断熱性、遮熱性、収縮性試験を実施。Conducts heat insulation, heat insulation, and heat shrinkability tests by heat insulation, heat insulation, and shrinkage ratio.

Figure 2007046024
ａ）上記表２の結果から、断熱性、遮熱性は、中空バルーンが多いほど温度差が高い。温度差の試験方法は、１ｍｍ厚の鉄板に片面塗布し、塗布面を直射日光に当て、温度を測定し、遮熱効果、断熱効果を見る。ブランクと塗布板の温度差計算式ｙ（温度差）＝０．８６×（ブランク温度）−２４．８
ｂ）上記表２の結果、中空バルーンが多いほど塗布面の収縮が少ない。
Figure 2007046024
 a) From the results in Table 2 above, the heat difference and the heat shielding property have a higher temperature difference as the number of hollow balloons increases. The test method of the temperature difference is to apply one side to a 1 mm thick iron plate, apply the coated surface to direct sunlight, measure the temperature, and see the heat shielding effect and the heat insulation effect. Formula for calculating temperature difference between blank and coated plate y (temperature difference) = 0.86 × (blank temperature) −24.8
b) As a result of Table 2 above, the more hollow balloons, the less the shrinkage of the coated surface.

塗膜の試験成績所Test results for coatings

Figure 2007046024
Figure 2007046024

本発明の水性断熱不燃塗料、および水性光触媒塗料を塗布し、その塗膜を実際の現場で確認するため、一般住宅の塗り替えに実施した。屋根４０ｍ２、１平方１，０００ｃｃの厚吹１回塗装で、２４時間常温乾燥後、水性光触媒塗料を塗布、また壁面１００ｍ２、１平方５００ｃｃ１回塗装で、２４時間常温乾燥後、水性光触媒塗料を塗布して、３日後、１回塗装で厚吹きした屋根も全く収縮による亀裂はなく、また塗装後の遮熱，断熱効果による省エネ効果も確認できた。In order to apply the water-based heat-insulating non-combustible paint and the water-based photocatalyst paint of the present invention and to check the coating film at the actual site, it was applied to repainting a general house. A 40m 2 roof, 1 square 1,000cc thick spray coating, 24 hours room temperature drying, water-based photocatalyst coating applied. A wall 100m 2 1 square 500cc coating once, 24 hours room temperature drying, water photocatalyst coating Three days later, the roof that had been thickly blown once by coating was not cracked due to shrinkage, and it was also confirmed that the heat-shielding and heat-insulating effects after coating were energy-saving.

本発明の水性断熱不燃塗料を厚塗り塗布して、遮熱，断熱効果による温度差の結果を追求したところ、つぎのような結果が得られた。
１、豚舎、鶏舎、牛舎の屋根に２ｍｍ厚で塗布したところ、高い超遮熱性，断熱性効果が得られた。
２、ビル、住宅の屋上水槽タンクに１回目黒色の稀元素鉱物粉混合の水性断熱不燃塗料を１ｍｍ厚塗布、２回目、白色の水性断熱不燃塗料を１ｍｍ厚で塗布したところ、１回目塗布の黒色で光の透過が無く、また稀元素鉱物の水質改善効果、２回目塗布の白色で遮熱，断熱効果で水槽内の汚れが極度に低下した。
３、寒冷地において水道関連の塩ビ管、鉄管、継ぎ手バルブ等に無色の稀元素鉱物配合の水性断熱不燃塗料を５ｍｍ厚で塗布したところ、遠赤外線、断熱効果で水が凍らなく、破裂が皆無となった。When the water-based heat-insulating non-combustible paint of the present invention was applied thickly and the results of the temperature difference due to the heat-shielding and heat-insulating effects were pursued, the following results were obtained.
1. When applied to the roofs of pig houses, poultry houses, and cattle houses with a thickness of 2 mm, high super-insulation and heat insulation effects were obtained.
2. Applying 1mm thick water-based heat-insulating incombustible paint mixed with black rare element mineral powder to the roof tank tank of buildings and houses for the first time, and applying white water-based heat-insulating incombustible paint at 1mm thickness for the first time. The black color has no light transmission, and the water quality improvement effect of the rare element mineral, the white color of the second coating, the heat shielding and the heat insulation effect, the dirt in the water tank was extremely reduced.
3. Water-resistant PVC pipes, iron pipes, joint valves, etc. in cold districts are coated with a colorless, heat-resistant, non-combustible paint containing a rare element mineral at a thickness of 5 mm. It became.

従来の遮熱，断熱塗料品との比較Comparison with conventional heat insulation and heat insulation paint products

Figure 2007046024
Figure 2007046024

 発明の効果The invention's effect

以上の説明からわかるように、本発明にかかわる水性断熱不燃塗料は、有害な有機溶剤を一切放出しない、環境にやさしい水系塗料でありながら、不燃性で耐熱温度が高く、超遮熱性、超断熱性、遠赤外線性、防音性、防露性、透湿性、通気性、防水性等多くの特徴をもつ多機能塗料であり、また弾性、強接着性、耐薬品性、耐候耐久性、耐凍害性であり、また１工程で厚吹しても収縮亀裂を起さなく、御影石調の美感的要素もそなえ、さらに厚膜水性光触媒塗料を１工程塗布することにより、基材の劣化を防ぎ、有害化学物質のＮＯ×分解、有機系煤塵を分解する防汚性、をかねそなえた安全な多機能性、省力化塗装工法である。As can be seen from the above description, the water-based heat-insulating incombustible paint according to the present invention is an environment-friendly water-based paint that does not release any harmful organic solvent, but is non-flammable and has a high heat-resistant temperature, super-heat shielding, super-insulating. Multifunctional paint with many characteristics such as heat resistance, far-infrared properties, soundproofing, dewproofing, moisture permeability, breathability, waterproofness, etc., and elastic, strong adhesion, chemical resistance, weather resistance, frost resistance In addition, it does not cause shrinkage cracks even if blown thick in one step, has a granite-like aesthetic element, and further prevents the deterioration of the substrate by applying a thick film aqueous photocatalyst coating in one step, It is a safe, multifunctional, labor-saving coating method that combines NOx decomposition of harmful chemicals and antifouling properties that decompose organic dust.

本発明にかかわる水性断熱不燃塗料は、多機能でありＣＯ２削減形の省エネ塗料であることから、構築物の外装、屋根、鉄骨住宅、簡易住宅、簡易トイレ、内装等にも利用でき、また寒熱対策としてサイロ、倉庫、工場、車両、自動車、また鶏舎、豚舎、牛舎、厩舎等の耐熱耐寒用としての利用、その他寒冷地の給排水管凍害対策、屋上水槽防汚対策、また超断熱を必要とする電気製品、アスベストの代替対策等数多くの利用が提供される。御影石調水性断熱不燃塗料は、野外のコンクリート製品、木製品等の寒熱による外気温から基材を遮断、断熱して劣化、凍害防止する、保護工法として利用できる。The water-based heat-insulating non-combustible paint according to the present invention is a multifunctional and CO 2 -reducing energy-saving paint, so it can be used for exteriors of buildings, roofs, steel houses, simple houses, simple toilets, interiors, etc. As countermeasures, silos, warehouses, factories, vehicles, automobiles, use for heat and cold resistance in poultry houses, pig houses, cowsheds, stables, etc., other countermeasures against frost damage in water supply and drainage pipes in cold districts, antifouling measures for roof tanks, and super insulation are required Many uses such as electrical products and asbestos alternatives are provided. Granite water-resistant heat-resistant non-combustible paint can be used as a protective construction method that shields the base material from the outside air temperature caused by cold heat, such as outdoor concrete products and wooden products, and prevents deterioration and frost damage.

Claims (10)

高分子シリカ系水性無機質塗料へ、断熱能を有する中空バルーンを配合してなる、水性断熱不燃塗料。  A water-based heat-insulating and non-combustible paint comprising a high-molecular silica-based water-based inorganic paint and a hollow balloon having heat insulation ability. 高分子シリカ系水性無機質塗料は、シロキサン結合の表面にシラノール基をもった高分子粒子で、シラノール基の脱水縮合により網目構造を形成、さらに未反応のシラノール基を高分子アルキル基で置換反応して、シリカ系と化学結合で形成される、水性無機質塗料である。  A polymeric silica-based water-based inorganic coating is a polymer particle having silanol groups on the surface of siloxane bonds, forming a network structure by dehydration condensation of the silanol groups, and further replacing the unreacted silanol groups with polymer alkyl groups. Thus, it is a water-based inorganic paint formed by a silica-based chemical bond. 該水性無機質塗料にミクロン、性質の異なる中空バルーンを３種以上配合してなる、水性断熱不燃塗料である。請求項１または２に記載する水性断熱不燃塗料。  This water-based heat-insulating non-combustible paint is obtained by blending three or more kinds of micron balloons having different properties with the water-based inorganic paint. The water-based heat-insulating incombustible paint according to claim 1 or 2. 該水性断熱不燃塗料に、配合される中空バルーンの配合比率は、１００容積率あたり１０〜９０容積率を含有する、請求項１〜３のいずれか１項に記載する、水性断熱不燃塗料。  The water-based heat insulating incombustible coating material according to any one of claims 1 to 3, wherein a blending ratio of the hollow balloon to be mixed with the water-based heat insulating incombustible paint contains 10 to 90 volume ratio per 100 volume ratio. 該水性断熱不燃塗料に、配合される中空バルーンの大きさは、１３〜１５０μｍの範囲で平均粒径が５０〜７０μｍ、からなる、請求項１〜４のいずれか１項に記載する、水性断熱不燃塗料。  The size of the hollow balloon compounded in the water-based heat-insulating incombustible paint is an aqueous heat-insulating material according to any one of claims 1 to 4, wherein the average particle size is in the range of 13 to 150 µm and the average particle size is 50 to 70 µm. Incombustible paint. 該水性断熱不燃塗料に、配合される無機質系素材は、中空バルーンの他、稀元素鉱物粉、焼成顔料、着色雲母、焼成着色砂、ガラスビーズ、微粒砂、からなる請求項１〜５のいずれか１項に記載する、水性断熱不燃塗料。  The inorganic material blended in the water-based heat-insulating incombustible coating material comprises, in addition to a hollow balloon, rare element mineral powder, calcined pigment, colored mica, calcined colored sand, glass beads, and fine sand. The water-based heat-insulating incombustible paint described in item 1. 該水性断熱不燃塗料の、残存塗料固形分は、重量比率１００に対して１０以下からなる、請求項１〜６のいずれか１項に記載する、水性断熱不燃塗料。  The water-based heat-insulating incombustible paint according to any one of claims 1 to 6, wherein a residual paint solid content of the water-based heat-resistant incombustible paint is 10 or less with respect to a weight ratio of 100. 請求項１〜７のいずれか１項に記載する、水性断熱不燃塗料を塗布し、常温乾燥することによって塗膜を形成することを特徴とする、塗装方法。  The coating method characterized by forming a coating film by apply | coating the water-based heat insulation nonflammable coating material described in any one of Claims 1-7, and drying at normal temperature. 水性断熱不燃塗料を塗布して、常温乾燥することにより、基材との強接着下地効果、単色着色効果、御影石調効果、超遮熱効果、超断熱効果、遠赤外線効果の塗膜を形成し、ついで、その塗膜の上に水性光触媒塗料（特願２００１−１５７９８８）を塗布することを特徴とする、塗装方法。  By applying a water-based heat-insulating incombustible paint and drying at room temperature, it forms a strong adhesion grounding effect with the base material, monochromatic coloring effect, granite tone effect, super heat-insulating effect, super-insulating effect, far-infrared effect coating film Then, a coating method characterized by applying an aqueous photocatalyst paint (Japanese Patent Application No. 2001-157988) on the coating film. 請求項８または９に記載する塗装方法によって形成した塗膜。  A coating film formed by the coating method according to claim 8 or 9.
JP2005255700A 2005-08-09 2005-08-09 Heat insulating water-based coating having incombustibility, method for coating photocatalyst and coated film thereof Pending JP2007046024A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2005255700A JP2007046024A (en) 2005-08-09 2005-08-09 Heat insulating water-based coating having incombustibility, method for coating photocatalyst and coated film thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2005255700A JP2007046024A (en) 2005-08-09 2005-08-09 Heat insulating water-based coating having incombustibility, method for coating photocatalyst and coated film thereof

Publications (1)

Publication Number Publication Date
JP2007046024A true JP2007046024A (en) 2007-02-22

Family

ID=37849118

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2005255700A Pending JP2007046024A (en) 2005-08-09 2005-08-09 Heat insulating water-based coating having incombustibility, method for coating photocatalyst and coated film thereof

Country Status (1)

Country Link
JP (1) JP2007046024A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009191677A (en) * 2008-02-13 2009-08-27 Ishikawa Gasket Co Ltd Insulator for internal combustion engine
JP2011122097A (en) * 2009-12-11 2011-06-23 Kao Corp Coating composition
JP2011122096A (en) * 2009-12-11 2011-06-23 Kao Corp Coating composition
KR101118136B1 (en) 2008-10-15 2012-03-12 한국건설생활환경시험연구원 Fire-retardant composition comprising inorganic hollow-shell particles
CN105949825A (en) * 2016-05-12 2016-09-21 盐城工学院 Preparation method of coating for exterior walls of buildings on tropic island

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5066533A (en) * 1973-10-15 1975-06-04
JPH02115285A (en) * 1988-10-26 1990-04-27 Dainippon Ink & Chem Inc Coating resin composition
JPH11323197A (en) * 1998-05-13 1999-11-26 Nagashima Tokushu Toryo Kk Heat insulating coating

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5066533A (en) * 1973-10-15 1975-06-04
JPH02115285A (en) * 1988-10-26 1990-04-27 Dainippon Ink & Chem Inc Coating resin composition
JPH11323197A (en) * 1998-05-13 1999-11-26 Nagashima Tokushu Toryo Kk Heat insulating coating

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009191677A (en) * 2008-02-13 2009-08-27 Ishikawa Gasket Co Ltd Insulator for internal combustion engine
KR101118136B1 (en) 2008-10-15 2012-03-12 한국건설생활환경시험연구원 Fire-retardant composition comprising inorganic hollow-shell particles
JP2011122097A (en) * 2009-12-11 2011-06-23 Kao Corp Coating composition
JP2011122096A (en) * 2009-12-11 2011-06-23 Kao Corp Coating composition
CN105949825A (en) * 2016-05-12 2016-09-21 盐城工学院 Preparation method of coating for exterior walls of buildings on tropic island

Similar Documents

Publication Publication Date Title
KR101366514B1 (en) No-primer type paint composition for water-proof, erosion-proof, preventiing and flooring system and construction method using thereof
US8172938B2 (en) Heat resistant and fire retardant materials and methods for preparing same
RU2349618C2 (en) Coating, filled with hollow microspheres, preventing ice-covering of surfaces of different objects
CN104087089A (en) Environment-friendly inorganic exterior-wall heat-insulation thermal-insulation coating and preparation process thereof
JP2010018798A (en) Aqueous epoxy resin coating and foaming agent type flame retardant coating composition for indoor and outdoor use
JP2010018798A5 (en)
JPH08120192A (en) Coating material and method for coating using the same
KR20140089074A (en) A composite of eco-friendly organic·inorganic composite coating materials for stain protection of surface and construction method thereof
EP1347107A1 (en) Polyvalent, insulating, anti-vibratory, adhesive and fireproof product for various industrial sectors, especially the building industry
JP2019527183A (en) Photocatalyst composition and use thereof for obtaining water-based paints
KR101180054B1 (en) Functional waterproof mortar for inner and outerwall of building
US11859097B2 (en) Functional aqueous paint composition having incombustibility, flame resistance, heat shielding, heat insulation and dew condensation prevention effects
KR101310324B1 (en) Heat insulating construction method of building wall
JP4176847B2 (en) Thick film type elastic heat insulating coating material and coating heat insulating method using the same
CN107189604A (en) A kind of environment-friendly type building construction finishing paint and preparation method thereof
CN104449238B (en) High fire-resistant fire retardant coating used for expansion steel structure
JP2007046024A (en) Heat insulating water-based coating having incombustibility, method for coating photocatalyst and coated film thereof
JP2007307528A (en) Heat-insulating method and heat-insulating structure
KR101197732B1 (en) Heat insulating and waterproof construction method of building rooftop
KR100679769B1 (en) Paint composition having an adiabatic and no-dew characteristic
JP2013043891A (en) Inorganic or organic hybrid nonflammable coating
RU2304600C2 (en) Application of the composition filled with the hollow microspheres and used as the anticorrosive and heat-insulating coating of the pipelines
CN113354966A (en) Development and preparation method of water-based inorganic real stone paint
RU2245350C1 (en) Heat protective dye
KR101759543B1 (en) Manufacture waterproof ceramic water-based paint method and Waterproof ceramic water-based paint

Legal Events

Date Code Title Description
A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20070719

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20101014

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20101026

A02 Decision of refusal

Free format text: JAPANESE INTERMEDIATE CODE: A02

Effective date: 20110315