JP2006151871A - Cosmetic composition - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a cosmetic composition obtaining a conditioning effect, especially sliding property in its use on healthy hairs and hairs damaged by the use of a hair color or hair dye, also excellent in finished feeling after drying and further excellent in the improvement of foam quality and touch feeling after its use. <P>SOLUTION: This cosmetic composition is characterized by containing ≥1 kind of dimethyl diallyl ammonium chloride derivatives, and ≥1 kind selected from a cation-modified locust bean gum, cation-modified tara gum and cation-modified fenugreek gum. <P>COPYRIGHT: (C)2006,JPO&NCIPI

Description

  The present invention is a cosmetic composition, particularly a hair treatment composition, which is excellent in foaming power, has good adsorptivity to hair and skin, has a good conditioning effect, and has a good finish without feeling of dryness after drying. About.

  The hair treatment composition for the purpose of washing contains a conditioning agent for damaging hair entangled during washing and rinsing and for improving touch after washing. As a substance that imparts a conditioning effect, since it is essential to adsorb to hair, cationic polymers having an adsorption action mainly based on ionicity are used, and quaternary nitrogen-containing groups are used as natural polymers. A cation-modified cellulose derivative that has been cation-modified by introduction of benzene has been used for a long time. However, for the purpose of improving the texture of dry hair, a synthetic cationic polymer obtained by radical polymerization or the like has been used in place of the natural cationic polymer found in cation-modified cellulose derivatives. Among them, dimethyldiallylammonium chloride derivatives have been used because they can improve the texture of dry hair. For example, Patent Document 1 discloses a shampoo composition with good foaming and good hand combing, Patent Document 2 discloses a shampoo composition that provides glossiness and a smooth texture, and Patent Document 3 discloses an amphoteric composition. Patent Document 4 discloses that shampoo compositions containing dimethyldiallylammonium chloride derivatives of electrolytes improve the combing and gloss of dry hair, and hair and body wash containing dimethyldiallylammonium chloride / acrylic acid copolymer. It has been shown that the agent composition is superior in improving foaming and foam quality and in rinsing performance. In Patent Document 5, a shampoo composition containing a copolymer of a dialkyldiallylammonium salt and a cellulose derivative having a quaternary nitrogen-containing group is introduced, which gives a smooth foam feeling that is smooth when fingers are washed, and It has been shown to give a smooth and smooth finger passage to the hair when rinsed, and to give a good gloss to the hair when finished. Patent Document 6 discloses a detergent composition that has good foaming properties and is not clogged and has a refreshing usability. Patent Document 7 discloses an anionic surfactant and / or an amphoteric surfactant, polyoxygen. In hair cleanser compositions containing alkylene derivatives and water-soluble inorganic salts, by using cationic polymers such as dimethyldiallylammonium chloride derivatives, cationized cellulose, and cationized guar gum, smoothness during rinsing and after rinsing It has been shown that a detergent composition with good fingering is provided.

  In recent years, with the diversification of fashion, the use of hair colors and hair dyes has increased, and as a result, the hair has been significantly damaged, so that the conditioning effect of the conditioning agent, particularly the slipping property during use, has become important. Therefore, in damaged hair, from the dimethyldiallylammonium chloride derivative which is inferior in the conditioning effect at the time of rinsing, cation-modified tara gum, cation-modified locust bean gum, cation-modified fenugreek gum are used for the purpose of improving these. When cation-modified locust bean gum is used in Patent Document 9, cation-modified tara gum, and Patent Document 10 and Patent Document 11 include cation-modified fenugreek gum in a cleaning composition such as shampoo, foaming power and conditioning It has been shown that a detergent composition with excellent properties is provided. Furthermore, Patent Document 12 shows that a detergent composition excellent in foaming power and conditioning properties is provided by blending cation-modified fenugreek gum, cation-modified cellulose, and cation-modified guar gum. Further, Patent Document 13 shows that the conditioning effect of shampoo is enhanced by combining cationized dextran with cationized cellulose or cationized guar gum.

JP-A-63-313716 (Section 1-4) Japanese Patent Laid-Open No. 5-65217 Japanese Laid-Open Patent Publication No.5-246828 JP-A-8-283785 Japanese Unexamined Patent Publication No. 1-128914 (Section 1-4) JP 2001-64678 A (pages 1-8) Japanese Patent Laid-Open No. 11-79956 (Section 1-8) JP 2000-103724 A (page 1-6) JP 2003-327603 A (page 1-11) JP 2004-203799 A (pages 1-17) JP 2004-203800 A (Pages 1-16) JP 2004-203803 A (Pages 1-16) JP 2000-319139 JP

  The dimethyldiallylammonium chloride derivative improves the texture of dry hair, but the conditioning effect is inadequate.Although improvement can be seen in combination with cation-modified cellulose derivatives, the slipperiness and texture of damaged hair are insufficient. In addition, even when a plurality of cationically modified galactomannan polysaccharides having a relatively high conditioning effect are combined, although the improvement of the conditioning effect can be seen, it has not been found that the texture of dry hair is sufficiently satisfied.

The object of the present invention is to obtain a conditioning effect, particularly slipperiness during use in healthy hair, hair color, and hair damaged by the use of a hair dye, and excellent finishing feeling after drying. The present invention provides a cosmetic composition excellent in feel after use.

  In such a situation, the present inventors have improved the slipperiness to wet hair when blended in a hair treatment composition, and improved the finished feeling after drying, and when blended in a skin cosmetic composition. The composition for improving the foam quality and the feeling after use was intensively studied. As a result, a cosmetic composition characterized by containing at least one dimethyldiallylammonium chloride derivative and at least one selected from cation-modified locust bean gum, cation-modified tara gum, and cation-modified fenugreek gum was wetted. It has been found that improvement of slipperiness to hair, improvement of foaming and foam quality, and improvement of touch after drying can be obtained, and the present invention has been completed.

  A cosmetic composition comprising at least one dimethyldiallylammonium chloride derivative of the present invention and at least one selected from cation-modified locust bean gum, cation-modified tara gum, and cation-modified fenugreek gum is a shampoo, When blended in a hair treatment composition such as rinse, a good feel can be obtained after drying while maintaining a slippery feeling. In addition, the foaming is improved, the foam quality is improved, and a good finish is provided.

  Examples of the first essential component of the cosmetic composition of the present invention include dimethyldiallylammonium chloride derivatives such as polydimethylmethylenepiperidinium chloride, dimethyldiallylammonium chloride / acrylamide copolymer, acrylic acid / dimethyldiallylammonium chloride copolymer. And acrylamide / acrylic acid / dimethyldiallylammonium chloride copolymer, dimethyldiallylammonium chloride / methoxypolyethylene glycol acrylate copolymer, etc., and all component names are polyquaternium-6, polyquaternium-7, polyquaternium-22, and polyquaternium. -39. Available in the market are ME polymer H40W, ME polymer 09W (above, Toho Chemical Industry), Marcote 100, Marcote 550, Marcote 280, Marcote 3330 (above, Ondeonalco Japan). is there.

(式中R₁、R₂は各々炭素数1〜3個のアルキル基、R₃は炭素数1〜24のアルキル基を示し、X^-は陰イオンを示す。nは、n=0又はn=1〜30を示し、n=1〜30の時、(R₄O)_nは炭素数2〜4のアルキレンオキサイドの重合体残基であって、単一のアルキレンオキサイドからなるポリアルキレングリコール鎖及び／又は2種類以上のアルキレンオキサイドからなるポリアルキレングリコール鎖を示す。) For the second essential component, cation-modified fenugreek gum, cation-modified tara gum, cation-modified locust bean gum (hereinafter also referred to as each cation-modified galactomannan polysaccharide), the method of cation modification is not particularly limited, For example, it can be obtained by substituting a part of the hydroxyl groups of unmodified fenugreek gum, tara gum, and locust bean gum with a quaternary nitrogen-containing group represented by the following chemical formula (1).

(Wherein R ₁ and R ₂ are each an alkyl group having 1 to ₃ carbon atoms, R ₃ is an alkyl group having 1 to 24 carbon atoms, X ⁻ represents an anion, and n is n = 0 or n = 1 to 30 and when n = 1 to 30, (R ₄ O) _n is a polymer residue of alkylene oxide having 2 to 4 carbon atoms, and is a polyalkylene glycol chain composed of a single alkylene oxide And / or a polyalkylene glycol chain composed of two or more alkylene oxides.)

  One of the second essential components of the present invention, cation-modified fenugreek gum, has about 1 main chain mannose and side chain galactose obtained from the endosperm portion of fenugreek (trigonella foenum-graecum) seeds. Reacting a glycidyl trialkylammonium salt having a quaternary nitrogen-containing group or a 3-halogeno-2-hydroxypropyltrialkylammonium salt with fenugreek gum, which is a natural water-soluble gum bonded in a one-to-one composition Can be manufactured by. In this case, the reaction is carried out in a suitable solvent, preferably a hydrous alcohol, in the presence of alkali. The introduction of such a quaternary nitrogen-containing group can be performed according to a conventionally known method, but is not necessarily limited thereto. For example, after adding an alkylene oxide having 2 to 4 carbon atoms to a part of hydroxyl groups contained in fenugreek gum, the glycidyl trialkylammonium salt or the quaternary 3-halogeno-2-hydroxypropyltrialkylammonium salt is added. Cationic modified fenugreek gum can also be produced by reacting with a nitrogen-containing group. Furthermore, in the present invention, the effect of the present invention can also be obtained by using crude fenugreek gum obtained by pulverizing the endosperm portion of fenugreek seeds. Preferably, the galactomannan content in fenugreek gum is 65 by purification. By using purified fenugreek gum that is not less than mass%, more preferably not less than 85 mass%, more excellent effects of the present invention can be obtained.

  Furthermore, one of the second essential components, cation-modified tara gum, is obtained from the endosperm part of the seed of cod (Caesalpinia spinosa), and the main chain mannose and side chain galactose have a composition of about 1: 3. It can be produced by reacting tara gum, which is a natural water-soluble gum, with a glycidyl trialkylammonium salt having a quaternary nitrogen-containing group or a 3-halogeno-2-hydroxypropyltrialkylammonium salt. . In this case, the reaction is carried out in a suitable solvent, preferably a hydrous alcohol, in the presence of alkali. The introduction of such a quaternary nitrogen-containing group can be performed according to a conventionally known method, but is not necessarily limited thereto. For example, after adding an alkylene oxide having 2 to 4 carbon atoms to a part of the hydroxyl group contained in tara gum, the quaternary nitrogen of the above glycidyl trialkyl ammonium salt or 3-halogeno-2-hydroxypropyl trialkyl ammonium salt The cation-modified tara gum can also be produced by reacting with a containing group. Furthermore, in the present invention, the effect of the present invention can also be obtained by using crude tara gum obtained by pulverizing the endosperm portion of the cod seed, but preferably, the galactomannan content in the tara gum is 65% by mass by purification. As described above, more excellent effects of the present invention can be obtained by using purified tara gum, which is more preferably 85% by mass or more.

  Furthermore, cation-modified locust bean gum, which is one of the second essential components, is composed of main chain mannose and side chain galactose obtained from the endosperm portion of the leguminous evergreen tree, carob (scientific name Ceratonia siliqua). A locust bean gum, which is a natural water-soluble gum bonded in a composition of about 1: 4, is mixed with a glycidyl trialkylammonium salt having a quaternary nitrogen-containing group or a 3-halogeno-2-hydroxypropyltrialkylammonium salt. It can be produced by reacting. In this case, the reaction is carried out in a suitable solvent, preferably a hydrous alcohol, in the presence of alkali. The introduction of such a quaternary nitrogen-containing group can be performed according to a conventionally known method, but is not necessarily limited thereto. For example, after adding an alkylene oxide having 2 to 4 carbon atoms to a part of the hydroxyl group contained in locust bean gum, the glycidyl trialkylammonium salt or 4-halogeno-2-hydroxypropyltrialkylammonium salt 4th is added. Cationic modified locust bean gum can also be produced by reacting with a secondary nitrogen-containing group. Furthermore, in the present invention, the effect of the present invention can also be obtained by using crude locust bean gum obtained by pulverizing the endosperm portion of the carob seed. Preferably, the galactomannan content in the locust bean gum is preferably obtained by purification. By using a refined locust bean gum having a content of 65% by mass or more, more preferably 85% by mass or more, a more excellent effect of the present invention can be obtained.

  As one of the methods for purifying crude fenugreek gum, crude tara gum, and crude locust bean gum, each galactomannan content less than 65% by mass crude fenugreek gum, crude tara gum, crude locust bean gum is dissolved in water to make an aqueous solution, After removing impurities by filtration, the filtrate is reprecipitated in an organic solvent, and the precipitate is dried. Alternatively, it can also be obtained by grinding only the central part of the endosperm obtained by removing the outer part including the seed coat.

  Furthermore, the crude fenugreek gum, crude tara gum, and crude locust bean gum each having a galactomannan content of less than 65% by mass are cation-modified according to a conventionally known method, and then pulverized, classified, or filtered. Each cation-modified galactomannan polysaccharide, which is the second essential component of the present invention, can also be obtained by removing and purifying water-insoluble matter such as the outer skin.

  The cation charge amount derived from the quaternary nitrogen-containing group of each cation-modified galactomannan polysaccharide as the second essential component of the present invention is preferably 0.1 to 3.0 meq / g, more preferably 0.5 to 2.5 meq / g. is there. If the amount of cationic charge is less than 0.1 meq / g, the amount adsorbed to the hair and skin will be insufficient, and in fact, even if it is added to hair treatment compositions such as shampoos, rinses, body cleaners, and skin cosmetic compositions, the effect is recognized. I can't. In addition, when each cation-modified galactomannan polysaccharide having a charge amount of more than 3.0 meq / g is blended with a hair treatment composition and a skin cosmetic composition, the foaming deteriorates, feels sticky, and feels sticky when used. The resulting feeling of use is worsened, and the finished feeling after use is unfavorable because it causes a feeling of stickiness and stickiness.

The cation charge amount derived from the quaternary nitrogen-containing group of each cation-modified galactomannan polysaccharide is the equivalent number of quaternary nitrogen-containing groups contained in 1 g of each cation-modified galactomannan polysaccharide. Usually, the nitrogen content derived from the quaternary nitrogen-containing group can be calculated by the Kjeldahl method (former cosmetic raw material standard, general test method, nitrogen determination method, second method) and calculated from the measured value, but fenugreek gum used in the present invention Since the galactomannan polysaccharides such as tara gum, locust bean gum and the like contain nitrogen, the galacto before cation modification is obtained from the nitrogen content in each cation-modified galactomannan polysaccharide used in the present invention determined by the Kjeldahl method. The value obtained by subtracting the nitrogen content derived from the mannan polysaccharide is the nitrogen content derived from the quaternary nitrogen-containing group. Specifically, the nitrogen content of cation-modified fenugreek gum, which is one of the second essential components of the present invention obtained by cation-modifying fenugreek gum, was measured by the Kjeldahl method. If there is, the cation charge amount of this substance can be obtained by the following formula. The fenugreek gum used in the present invention usually contains about 0.35% nitrogen.

具体的に説明すると、日本バイオコン(株)社製ガラクトマンナン測定キットを用い、本発明の第二の必須成分の一つである、カチオン変性フェヌグリークガムに使用するフェヌグリークガム中のガラクトマンナン含有量を測定した場合、検量線より求められたガラクトース含有量への換算係数A*が1384.6であり、ブランクの340nmにおける吸光度が0.276である時、フェヌグリークガムを固形分換算で12.1 mg採集し、その試料溶液の340nmにおける吸光度が0.663である例では、ガラクトース含有量は44.3質量%となる。フェヌグリークガムはマンノースとガラクトースの組成比が1対1であるから、ガラクトマンナン含有量は88.6質量%となる。 The content of galactomannan is the mass percentage of galactomannan contained per gram of galactomannan polysaccharide, such as fenugreek gum, tara gum, locust bean gum, etc., which are natural water-soluble gums, which is a raw material for cation-modified galactomannan polysaccharide. It is. The measurement method is as follows. In addition to the measurement based on the absorbance after enzymatic decomposition, the measurement can also be performed by liquid chromatography, thin layer chromatography, or the like. As a measuring method, about 20 mg of a sample is accurately weighed, put into a centrifuge tube, 5 mL of ethanol is added and incubated at 85 to 95 ° C., and then centrifuged. 10.0 mL of 50 mM acetate buffer (pH 4.5) was added to the lower phase separated into the upper phase and the lower phase, and the mixture was heated and then allowed to stand at 40 ° C. for 12 hours. Then add 20 μL of β-mannanase and incubate at 40 ° C for 180 minutes. After incubation, centrifuge, take 0.1 mL of the supernatant, and add 0.2 mL of 50 mM acetate buffer (pH 4.5) and 20 μL of α-galactosidase. Incubate this solution at 40 ° C, add 2.5 mL of 200 mM Tris buffer, add 0.1 mL of β-nicotinamide adenine dinucleotide (0.1 g / 10 mL), and add 8 μL of galactose dehydrogenase at 40 ° C. Incubate for 60 minutes and measure the absorbance of the solution at 340 nm. The galactose content is determined from the obtained absorbance using the following formula. Each galactomannan content is calculated from the amount of galactose using the composition ratio of mannose and galactose of the sample.

Specifically, using a galactomannan measurement kit manufactured by Nippon Biocon Co., Ltd., one of the second essential components of the present invention, the galactomannan content in fenugreek gum used for cation-modified fenugreek gum When measured, when the conversion factor A * to the galactose content determined from the calibration curve is 1384.6, and the absorbance of the blank at 340 nm is 0.276, 12.1 mg of fenugreek gum is collected in terms of solid content, and the sample solution In an example in which the absorbance at 340 nm is 0.663, the galactose content is 44.3% by mass. Since fenugreek gum has a one-to-one composition ratio of mannose and galactose, the galactomannan content is 88.6% by mass.

  The present invention is characterized by one or more of dimethyldiallylammonium chloride derivatives as the first component and one or more selected from each cation-modified galactomannan polysaccharide as the second component. Preferred is a combination of a cation-modified fenugreek gum, a dimethyldiallylammonium chloride / acrylamide copolymer and a cation-modified tara gum, a dimethyldiallylammonium chloride / acrylamide copolymer and a cation-modified locust bean gum, and a dimethyldiallylammonium chloride / acrylamide copolymer. Cation-modified fenugreek gum, dimethyldiallylammonium chloride / acrylamide, obtained by cation-modifying a polymer and phenaclique gum having a galactomannan content of 85% by mass or more A cation-modified tara gum obtained by cationically modifying a polymer and tara gum having a galactomannan content of 65% by mass or more, and a cation obtained by cation-modifying a locust bean gum having a galactomannan content of 65% by mass or more. A combination of modified locust bean gum is more preferred.

  The cosmetic composition of the present invention comprises one or more dimethyldiallylammonium chloride derivatives as the first component and one or more selected from the second component, cation-modified fenugreek gum, cation-modified tara gum, and cation-modified locust bean gum. It is preferable that the blending is performed so that the mass ratio is 1/10 to 10/1 in terms of obtaining the intended effect of the present invention.

  Furthermore, the blending amount of the dimethyldiallylammonium chloride derivative and each cation-modified galactomannan polysaccharide with respect to the hair treatment composition or the skin cosmetic composition is not particularly limited, but the total composition is preferably 100% by mass. Is 0.01% by mass or more, more preferably 0.05% by mass or more. If it is less than 0.01% by mass, the synergistic effect when combined is significantly reduced, and the conditioning effect, foaming, foam quality and feeling of use are not improved. The total amount of the dimethyldiallylammonium chloride derivative combined with each cation-modified galactomannan polysaccharide is not particularly limited, but is preferably 0.05 to 5.0% by mass with 100% by mass of the entire composition. . If it is less than 0.05% by mass, the conditioning effect, foaming, foam quality and feeling of use will not be improved. If it exceeds 5% by mass, a feeling of stickiness and stickiness will be produced at the time of use, and the slipping property will be worsened and the feeling of use will be worse. Tend to be.

  As described above, the cosmetic composition of the present invention is obtained, but other components in the cosmetic composition are not particularly limited, and components generally used in cosmetics can be blended as optional components. . Other ingredients that can be blended are exemplified below.

  As an anionic surfactant, alkyl (carbon number 8-24) sulfate, alkyl (carbon number 8-24) ether sulfate, alkyl (carbon number 8-24) benzenesulfonate, alkyl (carbon number 8-24) ) Phosphate, polyoxyalkylene alkyl (carbon number 8-24) ether phosphate, alkyl (carbon number 8-24) sulfosuccinate, polyoxyalkylene alkyl (carbon number 8-24) ether sulfosuccinate, acyl (C8-C24) alanine salt, acyl (C8-C24) N-methyl-β-alanine salt, acyl (C8-C24) glutamate, acyl (C8-C24) Isethionate, acyl (carbon number 8-24) sarcosine salt, acyl (carbon number 8-24) taurine salt, acyl (carbon number 8-24) methyl taurate, α-sulfo fatty acid ester salt, ether Carboxylate, polyoxyalkylene fatty acid monoethanolamide sulfate Examples thereof include a salt and a long chain (carbon number 8 to 24) carboxylate.

  Nonionic surfactants include alkanolamide, glycerin fatty acid ester, polyoxyalkylene alkyl ether, polyoxyalkylene glycol ether, polyoxyalkylene sorbitan fatty acid ester, sorbitan fatty acid ester, polyoxyalkylene sorbite fatty acid ester, sorbite fatty acid ester, polyoxy Alkylene glycerin fatty acid ester, polyoxyalkylene fatty acid ester, polyoxyalkylene alkyl phenyl ether, tetrapolyoxyalkylene ethylene diamine condensate, sucrose fatty acid ester, polyoxyalkylene fatty acid amide, polyoxyalkylene glycol fatty acid ester, polyoxyalkylene castor oil Derivatives, polyoxyalkylene hydrogenated castor oil derivatives, alkyl poly Glycosidic, polyglycerol fatty acid esters, and the like.

  Amphoteric surfactants include alkyl (8 to 24 carbon) amidopropyl betaine, alkyl (8 to 24 carbon) carboxybetaine, alkyl (8 to 24 carbon) sulfobetaine, alkyl (8 to 24 carbon) hydroxy Sulfobetaine, alkyl (carbon number 8-24) amidopropyl hydroxysulfobetaine, alkyl (carbon number 8-24) hydroxyphosphobetaine, alkyl (carbon number 8-24) aminocarboxylate, alkyl (carbon number 8-24) Examples include sodium amphoacetate, alkyl (carbon number 8-24) amine oxide, tertiary nitrogen, and alkyl (carbon number 8-24) phosphate ester containing quaternary nitrogen.

  In addition, as a polymer blended in the hair treatment composition and skin cosmetic composition of the present invention, anionic, cationic, amphoteric, nonionic properties for the purpose of adjusting viscosity and improving usability during styling to some extent. The polymer can be further blended within a range not impairing the effects of the present invention, and examples thereof include the following.

  Examples of anionic polymers include acrylic acid derivatives (polyacrylic acid and salts thereof, acrylic acid / acrylamide / ethyl acrylate copolymers and salts thereof), and methacrylic acid derivatives (polymethacrylic acid and salts thereof, methacrylic acid).・ Acrylamide, diacetone acrylamide, acrylic acid alkyl ester, methacrylic acid alkyl ester copolymers and their salts, etc.), crotonic acid derivatives (vinyl acetate, crotonic acid copolymers, etc.), maleic acid derivatives (maleic anhydride, diisobutylene, etc.) Copolymer, isobutylene / maleic acid copolymer, etc.), polyglutamic acid and its salt, hyaluronic acid and its salt, carboxymethylcellulose, carboxyvinyl polymer and the like.

  Examples of cationic water-soluble polymers include quaternary nitrogen-modified polysaccharides (cation-modified cellulose derivatives, cation-modified guar gums, cation-modified starches, cation-modified tamarind gums, etc.), vinyl pyrrolidone derivatives (vinyl pyrrolidone and dimethylaminoethyl methacrylate). Acid copolymer salt, vinylpyrrolidone / methacrylamidopropyltrimethylammonium chloride copolymer, vinylpyrrolidone / methylvinylimidazolium chloride copolymer, etc.), methacrylic acid derivative (methacryloylethyldimethylbetaine / methacryloylethyltrimethylammonium chloride / methacrylic acid) 2-hydroxyethyl copolymer, methacryloylethyldimethylbetaine, methacryloylethyltrimethylammonium chloride, methoxypolyethylene methacrylate Call copolymers) and the like.

  Examples of amphoteric water-soluble polymers include amphoteric starch, methacrylic acid derivatives (polymethacryloylethyldimethylbetaine, N-methacryloyloxyethyl N, N-dimethylammonium-α-methylcarboxybetaine / alkyl methacrylate copolymer, etc.) Etc.

  Examples of nonionic polymers include acrylic acid derivatives (hydroxyethyl acrylate / methoxyethyl acrylate copolymer, polyacrylic amide, etc.), vinyl pyrrolidone derivatives (polyvinyl pyrrolidone, vinyl pyrrolidone / vinyl acetate copolymer, etc.) And polyoxyalkylene glycol derivatives (polyethylene glycol, polypropylene glycol, etc.), cellulose derivatives (methyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, etc.), polysaccharides and derivatives thereof (guar gum, locust bean gum, dextran, etc.) and the like.

  In still another embodiment, the hair treatment composition and the skin cosmetic composition of the present invention include an organic amidoamine compound obtained by completely or partially neutralizing an amidoamine compound with a neutralizing agent such as an organic acid and / or an inorganic acid. The conditioning effect can be improved by adding an acid salt and / or an inorganic acid salt and a higher fatty acid and / or higher alcohol. The blending amount thereof is preferably 5% by mass or less based on 100% by mass of the entire composition as an amidoamine compound, and if the amount exceeds this, the feeling after use becomes poor or the feeling of use becomes poor.

  The other components blended in the hair treatment composition and skin cosmetic composition of the present invention include cationic surfactants (alkyltrimethylammonium salts, dialkyldimethylammonium salts, alkylpyridium salts, alkyldimethylbenzylammonium salts). Benzethonium chloride, benzalkonium chloride, etc.), solubilizers (ethanol, ethylene glycol, propylene glycol, etc.), waxes (carnauba wax, candelilla wax, etc.), hydrocarbon oils (liquid paraffin, squalane, olive oil, jojoba oil, etc.) ), Moisturizers (glycerin, trehalose, sorbitol, maltitol, dipropylene glycol, 1,3-butylene glycol, sodium hyaluronate, etc.), esters (hexyl laurate, isopropyl myristate, octyldodecyl myristate, myris Myristylate, 2-hexyldecyl myristate, glyceryl trimyristate, isopropyl palmitate, 2-heptylundecyl palmitate, 2-hexyldecyl palmitate, butyl stearate, isocetyl stearate, 12-hydroxystearic acid Cholesteryl acid, cetostearyl alcohol, cetyl octanoate, hexyl decyl dimethyloctanoate, isocetyl isostearate, trimethylolpropane triisostearate, decyl oleate, oil oleate, cetyl lactate, myristyl lactate, ethyl acetate, amyl acetate butyl acetate, Lanolin acetate, cetyl 2-ethylhexanoate, 2-ethylhexyl palmitate, ethylene glycol di-2-ethylhexylate, trimethylolpropane tri-2-ethylhexylate, tri-2-ethylhexyl Glycerol phosphate, pentaerythritol tetra-2-ethylhexylate, cetyl-2-ethylhexanoate, diisobutyl adipate, 2-heptylundecyl adipate, 2-hexyldecyl adipate, dipentaerythritol fatty acid ester, dicaprin Acid neopentyl glycol, diisostearyl malate, glycerin di-2-heptylundecanoate, glyceride tri-2-heptylundecanoate, castor oil fatty acid methyl ester, acetoglyceride, N-lauroyl-L-glutamic acid-2-octyldodecyl Esters, di-2-ethylhexyl sebacate, diisopropyl sebacate, 2-ethylhexyl succinate, triethyl citrate, ethyl laurate, ethyl mink oil fatty acid, etc.), antioxidants (tocopherol, BHT, etc.), silicone (methyl poly Siloxane, Methyl phenyl polysiloxane, high polymerization degree methyl polysiloxane, cyclic polysiloxane, etc.) and silicone derivatives (polyether-modified silicone, amino-modified silicone, etc.), higher alcohols, higher fatty acids (lauric acid, myristic acid, palmitic acid, stearic acid, Behenic acid, isostearic acid, oleic acid, undecylenic acid, tall oil fatty acid, coconut oil fatty acid, palm fatty acid, palm kernel fatty acid, linoleic acid, linolenic acid, eicosapentaenoic acid, docosahexaenoic acid, etc.), amino acids (arginine, glutamic acid, etc.) Ultraviolet absorbers (benzophenone derivatives, paraaminobenzoic acid derivatives, methoxycinnamic acid derivatives, etc.), pearlizing agents (fatty acid ethylene glycol, etc.), suspending agents (polystyrene emulsions, etc.), thickeners, metal sequestering agents (edetic acid) Salt), pH adjuster, bactericidal agent Preservatives, hair growth agents, vitamins, anti-inflammatory agents, dyes, fragrances, foam boosters, and the like.

  The dosage form of the cosmetic composition of the present invention is not limited and can take any dosage form. Further, in addition to the above (essential) component, the dosage form is usually within the range that does not impair the effects of the present invention. Various components to be blended in the cosmetic composition can be added and produced by conventional methods, but among them, it can be preferably used as a hair treatment composition. Examples of the dosage form include shampoos, rinses, conditioners, hair waxes, hair lotions, hair mists, etc., all of which improve the conditioning effect such as the slipperiness of the cosmetic composition of the present invention and the finished feeling after use. Utilizing effects such as improvement, foaming and improvement of foam quality. In addition, it can be used in body cleaning agents, facial cleansers, cleansing agents, lotions, and can be blended into acidic hair dyes, oxidative hair dyes, permanent agents, etc. due to the effect of improving the feeling of use. In addition, various modes such as a solid, powder, liquid, gel, cream, aerosol, and foam can be used in accordance with the use site and use scene.

Hereinafter, the present invention will be described in more detail based on examples, but the present invention is not limited thereto. Unless otherwise specified, the amount is shown in mass%.
(Evaluation) Evaluation in wash-out products (Part 1: Sliding property (healthy hair))
The slipperiness of the cosmetic composition of the present invention on the hair was confirmed with a wash-out product containing an anionic surfactant and an amphoteric surfactant. Shampoos were prepared by a conventional method with the basic shampoo formulation in Table 1 and the compositions shown in Tables 3-10. Ingredient (8) in Table 1 is heated to 80 ° C, and component (1) is slowly added and dissolved while stirring. After confirming dissolution, heating is stopped and ingredients (2) to (4) are added and stirred. The components (5) to (7) were added at 30 to 40 ° C. and mixed uniformly to prepare shampoos for use in the evaluation. Ingredient (1) in Table 1 was prepared with the compositions shown in Tables 3-10.

  After immersing hair strands (manufactured by Beaulux Co., Ltd., human hair with roots aligned, length 60 mm, width 40 mm) in a 5% aqueous solution of each shampoo, thoroughly washing off the shampoo, this wet The dynamic friction coefficient of the intact hair was measured with a friction tester (KES-SE, manufactured by Kato Tech Co., Ltd.) to evaluate the slipperiness. The evaluation results are shown in Tables 3-10.

(Evaluation) Evaluation in wash-out products (Part 2: Sliding property (damaged hair))
The slipperiness of damaged hair of the cosmetic composition of the present invention was confirmed with a rinse-off product. A shampoo was prepared by a conventional method with the basic formulation of Table 1 and the compositions shown in Tables 3-10. Ingredient (8) in Table 1 is heated to 80 ° C, and component (1) is slowly added and dissolved while stirring. After confirming dissolution, heating is stopped and ingredients (2) to (4) are added and stirred. The components (5) to (7) were added at 30 to 40 ° C. and mixed uniformly to prepare shampoos for use in the evaluation. Ingredient (1) in Table 1 was prepared with the compositions shown in Tables 3-10.

A hair strand similar to the one used in the evaluation test (1) in a rinse-off product was added to a bleaching agent of 2: 1 mixture (w / w) of 6% H ₂ O ₂ and 3% aqueous ammonia, bath ratio It was immersed for 60 minutes under the condition of 1: 100 (hair strand: solution weight) at 40 ° C., washed with warm water, and dried with a dryer. The hair strands with remarkable damage obtained by this bleaching treatment were dipped in a 5% aqueous solution of each shampoo prepared, and the dynamic friction coefficient of the wet hair strand was determined by a friction tester (made by Kato Tech Co., Ltd., KES-SE) was used to evaluate slipperiness. The evaluation results are shown in Tables 3-10.

(Evaluation) Evaluation in wash-out products (Part 3: Sensory evaluation)
Further, for each shampoo, the performance evaluation of the following items was carried out by 10 testers, and quantified by the method shown in Table 2 below, and the evaluation values of 10 testers for each item were totaled. The evaluation results are shown in Tables 3-10.
・ Bubbling at the time of hair washing ・ Slipperiness at the time of use (as per finger and hair feel)
・ After use (dry hair) comb and feel

※1）Merquat100（オンデオナルコジャパン）
※2）MEポリマー０９W（東邦化学工業社製）
※3）Merquat280（オンデオナルコジャパン）
※4）Merquat3330（オンデオナルコジャパン）
※5）コロハヒドロキシプロピルトリモニウムクロリド
（カチオン電荷量0.76meq/g、ガラクトマンナン量73%）
※6）コロハヒドロキシプロピルトリモニウムクロリド
（カチオン電荷量0.73meq/g、ガラクトマンナン量89%）
※7）カエサルピニアスピノサヒドロキシプロピルトリモニウムクロリド
（カチオン電荷量0.77meq/g、ガラクトマンナン量77%）
※8）カエサルピニアスピノサヒドロキシプロピルトリモニウムクロリド
（カチオン電荷量0.73meq/g、ガラクトマンナン量95%）
※9）ローカストビーンヒドロキシプロピルトリモニウムクロリド
（カチオン電荷量0.95meq/g、ガラクトマンナン量72%）
※10）ローカストビーンヒドロキシプロピルトリモニウムクロリド
（カチオン電荷量1.00emq/g、ガラクトマンナン量97%）

* 1) Merquat100 (Ondeonalco Japan)
* 2) ME polymer 09W (manufactured by Toho Chemical Industries)
* 3) Merquat280 (Ondeonalco Japan)
* 4) Merquat 3330 (Ondeonalco Japan)
* 5) Koloha hydroxypropyltrimonium chloride (cation charge 0.76 meq / g, galactomannan 73%)
* 6) Koloha hydroxypropyltrimonium chloride (cation charge 0.73 meq / g, galactomannan 89%)
* 7) Caesarpinia spinosa hydroxypropyltrimonium chloride (cation charge 0.77meq / g, galactomannan content 77%)
* 8) Caesarpinia spinosa hydroxypropyltrimonium chloride (cation charge 0.73 meq / g, galactomannan content 95%)
* 9) Locust bean hydroxypropyltrimonium chloride (cation charge 0.95meq / g, galactomannan 72%)
* 10) Locust bean hydroxypropyltrimonium chloride (cation charge 1.00emq / g, galactomannan content 97%)

※11）Gafquat755N（International Specialty Products社製）
※12）GafquatHS-100（International Specialty Products社製）
※13）カチナールHC-100（東邦化学工業社製）
※14）カチナールCG-100（東邦化学工業社製）

* 11) Gafquat755N (made by International Specialty Products)
* 12) GafquatHS-100 (made by International Specialty Products)
* 13) Kachinar HC-100 (Toho Chemical Industries)
* 14) Kachinar CG-100 (manufactured by Toho Chemical Industry Co., Ltd.)

From the results shown in Tables 3 to 10, it was confirmed that the shampoos of the examples of the present invention decreased the coefficient of dynamic friction in wet hair compared to the comparative examples, and were particularly excellent in damaged hair. It was. This also appeared in sensory evaluation, and it was confirmed that the fingering after shampooing was superior to the shampoo of the comparative example. Furthermore, it was confirmed that the touch of the dry hair was excellent. Moreover, since the improvement of the slipperiness with respect to hair, and foaming and the improvement of foam quality are recognized, the touch improvement with respect to skin cosmetics, such as a body washing | cleaning agent and face wash, can also be anticipated.

(Evaluation) Evaluation of wash-out products (Part 4)
The conditioning effect of the cosmetic composition of the present invention was confirmed with a wash-out product containing a cationic surfactant. Hair rinses were prepared in a conventional manner with the basic hair rinse formulations shown in Table 11 and the compositions shown in Tables 13-15. Ingredients (2) to (8) in Table 11 were heated to 80 ° C. and stirred to obtain a uniform solution. The solution prepared by adding component (1) to component (10) while stirring was dissolved in 80 ° C. Heated C was added with stirring, and then component (9) was added while cooling and mixed uniformly to prepare hair rinses used for evaluation. Ingredient (1) in Table 11 was prepared with the compositions shown in Tables 13-15.

About each prepared hair rinse, the performance evaluation of the following item was implemented by 10 testers, it digitized by the method shown in the following Table 12, and the evaluation value of 10 testers was totaled about each item. The evaluation results are shown in Tables 13-15.
・ Sliding property when rinsing (as per finger)
・ Existence of dry hair condition (comb street, squeak, texture)

  From the results of Tables 13 to 15, it was confirmed that the hair rinse of each example of the present invention product containing a cationic surfactant and a higher alcohol (cetanol) was superior to the finger at the time of use compared to the comparative example. As a result, it was confirmed that the combing after drying was excellent in conditioning effects such as little squeak.

(Evaluation) Evaluation in skin washout product The foaming, foam quality improvement, feel improvement and conditioning effect of the cosmetic composition of the present invention were confirmed in a skin washout product containing fatty acid soap. A body cleaning agent (body soap) was prepared by a conventional method using the basic formulation for body cleaning in Table 16 and the compositions shown in Tables 18 and 19. Ingredient (11) in Table 16 was heated to 60 ° C., and component (1) was added and dissolved while stirring.
Add components (2) to (8) with stirring at ° C to homogeneity, and add components (9) and (10) with stirring at 30 to 40 ° C and mix evenly. Each body cleaning agent to be used was prepared. Component (1) in Table 16 was prepared with the compositions shown in Tables 18 and 19, respectively.

For each of the prepared body cleaning agents, the performance evaluation of the following items was performed by 10 testers, and the results were quantified by the method shown in Table 17 below. The evaluation values of 10 testers for each item were totaled. did. The evaluation results are shown in Tables 18 and 19.
・ Amount of foam and foam quality during use ・ Usability during use (ease of rinsing, feeling of tension after rinsing, and feeling of sliminess)
・ Usage after use (after drying) (tiffness, smoothness, moistness)

  From the results of Tables 18 and 19, it was confirmed that the body detergents of the examples of the present invention containing fatty acid soaps were superior in foaming and foam quality and in the feeling of use as compared with the comparative examples.

Hereinafter, a hair treatment composition and a skin cosmetic composition, which are obtained by using the cosmetic composition of the present invention, such as conditioning effects such as slipperiness, improvement of foaming and foam quality, and improvement of touch, etc. The cosmetic compositions having different dosage forms were produced by a conventional method, and further confirmed in each.

As a result of further confirmation in each cosmetic composition with different dosage forms produced in Examples 74 to 92, it was excellent in conditioning effects such as fingering in wet hair and the feeling after drying, and further, foaming and foaming It was excellent in quality and touch.

Claims (4)

A cosmetic composition comprising at least one dimethyldiallylammonium chloride derivative and at least one selected from cation-modified fenugreek gum, cation-modified tara gum, and cation-modified locust bean gum. Dimethyldiallylammonium chloride derivative is polydimethylmethylenepiperidinium chloride, dimethyldiallylammonium chloride / acrylamide copolymer, acrylic acid / dimethyldiallylammonium chloride copolymer, acrylamide / acrylic acid / dimethyldiallylammonium chloride copolymer, chloride The cosmetic composition according to claim 1, wherein the cosmetic composition is one or more selected from dimethyldiallylammonium methoxypolyethylene glycol acrylate copolymers. 3. The weight ratio of one or more of dimethyldiallylammonium chloride derivative and one or more selected from cation-modified fenugreek gum, cation-modified tara gum, and cation-modified locust bean gum is 1/10 to 10/1. The cosmetic composition as described. The composition whose cosmetic composition of Claims 1-3 is a composition for hair treatment.