JP2005307381A - Heat storage material for clothing material and microcapsule for clothing material - Google Patents
Heat storage material for clothing material and microcapsule for clothing material Download PDFInfo
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- JP2005307381A JP2005307381A JP2004124225A JP2004124225A JP2005307381A JP 2005307381 A JP2005307381 A JP 2005307381A JP 2004124225 A JP2004124225 A JP 2004124225A JP 2004124225 A JP2004124225 A JP 2004124225A JP 2005307381 A JP2005307381 A JP 2005307381A
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- 238000005338 heat storage Methods 0.000 title claims abstract description 62
- 239000011232 storage material Substances 0.000 title claims abstract description 59
- 239000000463 material Substances 0.000 title claims abstract description 30
- 239000003094 microcapsule Substances 0.000 title claims description 21
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 claims abstract description 8
- 150000001875 compounds Chemical class 0.000 claims abstract description 4
- 230000004927 fusion Effects 0.000 claims description 12
- 125000004432 carbon atom Chemical group C* 0.000 claims description 4
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- 239000000203 mixture Substances 0.000 description 9
- NDJKXXJCMXVBJW-UHFFFAOYSA-N heptadecane Chemical compound CCCCCCCCCCCCCCCCC NDJKXXJCMXVBJW-UHFFFAOYSA-N 0.000 description 8
- LQERIDTXQFOHKA-UHFFFAOYSA-N nonadecane Chemical compound CCCCCCCCCCCCCCCCCCC LQERIDTXQFOHKA-UHFFFAOYSA-N 0.000 description 8
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- DCAYPVUWAIABOU-UHFFFAOYSA-N hexadecane Chemical compound CCCCCCCCCCCCCCCC DCAYPVUWAIABOU-UHFFFAOYSA-N 0.000 description 2
- 238000011065 in-situ storage Methods 0.000 description 2
- 239000001023 inorganic pigment Substances 0.000 description 2
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- PYSRRFNXTXNWCD-UHFFFAOYSA-N 3-(2-phenylethenyl)furan-2,5-dione Chemical compound O=C1OC(=O)C(C=CC=2C=CC=CC=2)=C1 PYSRRFNXTXNWCD-UHFFFAOYSA-N 0.000 description 1
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- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 description 1
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000001856 Ethyl cellulose Substances 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
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- 229920000084 Gum arabic Polymers 0.000 description 1
- 238000012695 Interfacial polymerization Methods 0.000 description 1
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- 206010037660 Pyrexia Diseases 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
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- 229920000147 Styrene maleic anhydride Polymers 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
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- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
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- 125000003118 aryl group Chemical group 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 235000009120 camo Nutrition 0.000 description 1
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- 238000001816 cooling Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
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- 239000000975 dye Substances 0.000 description 1
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- 238000005538 encapsulation Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 125000002573 ethenylidene group Chemical group [*]=C=C([H])[H] 0.000 description 1
- 235000019325 ethyl cellulose Nutrition 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
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- 235000011852 gelatine desserts Nutrition 0.000 description 1
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- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine powder Natural products NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
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- 239000007921 spray Substances 0.000 description 1
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- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
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- 230000002459 sustained effect Effects 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
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- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- ILJSQTXMGCGYMG-UHFFFAOYSA-N triacetic acid Chemical compound CC(=O)CC(=O)CC(O)=O ILJSQTXMGCGYMG-UHFFFAOYSA-N 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Landscapes
- Undergarments, Swaddling Clothes, Handkerchiefs Or Underwear Materials (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Professional, Industrial, Or Sporting Protective Garments (AREA)
Abstract
Description
本発明は衣服や手袋、ソックスなどの被服材料に本発明の蓄熱材を塗工、含浸、付着せしめることにより暖かさ、涼しさ、快適さが長時間持続する蓄熱材に関するものである。 The present invention relates to a heat storage material in which warmth, coolness, and comfort last for a long time by applying, impregnating, and adhering the heat storage material of the present invention to clothing materials such as clothes, gloves, and socks.
蓄熱材を繊維やシートなどの支持体に付着させて、体温調節機能をもたらす手法や被服材料として以下のような例が知られている。繊維構造物にパラフィン封入マイクロカプセルを樹脂バインダーを用いて固着することにより得られる蓄熱性を有する繊維構造物。（例えば、特許文献１）繊維基材及び当該基材全体にマイクロカプセルが分散され、該マイクロカプセルが加熱又は冷却された場合に熱安定性を示すような可逆的熱貯蔵性を示す繊維。（例えば、特許文献２）鞘部が熱可塑性重合体、芯部が潜熱蓄熱材から成る複合繊維。（例えば、特許文献３） The following examples are known as techniques and clothing materials for bringing a thermal storage function by attaching a heat storage material to a support such as a fiber or a sheet. A fiber structure having heat storage properties obtained by fixing paraffin-encapsulated microcapsules to a fiber structure using a resin binder. (For example, patent document 1) The fiber which shows reversible heat | fever storage property which shows thermal stability, when a microcapsule is disperse | distributed to the fiber base material and the said base material, and this microcapsule is heated or cooled. (For example, patent document 2) The composite fiber which a sheath part consists of a thermoplastic polymer, and a core part consists of a latent heat storage material. (For example, Patent Document 3)
また、人体から発する熱を蓄えたり放熱することを防いだりする目的で、繊維自体に蓄熱材を内包したマイクロカプセルを塗工または含浸した布帛類の提案が為されているが、保持されている蓄熱材の重量が極めて少量であるため快適さが長持ちせず、風合いや着心地の点で充分なものではなかった。（例えば特許文献４、５、６） In addition, for the purpose of preventing the heat generated from the human body from being stored or dissipated, proposals have been made for fabrics in which microcapsules containing a heat storage material are coated or impregnated in the fibers themselves, but are retained. Since the weight of the heat storage material is extremely small, the comfort does not last long and it is not sufficient in terms of texture and comfort. (For example, Patent Documents 4, 5, and 6)
これら材料に用いられている蓄熱材は一般に、物質が相変化する際に出入りする熱エネルギーを利用した潜熱蓄熱材が用いられており、具体例としてノルマルパラフィンが高い融解熱量と安全性の点で多用されている。ノルマルパラフィン以外にも、アルコール、脂肪酸、エステルなどの化合物が挙げられるが、これらの化合物は蓄熱能力の低下が生じないように極力単一に近い組成、即ち純品に近い組成で用いることが好ましいことが経験上知られている。多種の蓄熱材を混合して用いることにより融解または凝固時の温度分布幅が広くなり、融解熱量の著しい低下を示すため複数の化合物を混合して用いることは上記被服材料のみならず潜熱蓄熱材を扱う全ての産業上の用途において好ましい手法とは言えなかった。
本発明の課題は、環境温度が快適とされる温度より高温又は低温の雰囲気に移動した場合でも、本発明の蓄熱材を固定化せしめた被服材料を身につけることにより、衣服内の温度は急に変化することはなく快適とされる範囲の温度を長時間維持し、しかも季節や個人差に影響されにくい極めて温度安定性に優れた蓄熱材組成及び被服材料を提供することである。 The problem of the present invention is that even when the environment temperature is moved to a temperature higher or lower than a comfortable temperature, by wearing the clothing material in which the heat storage material of the present invention is fixed, the temperature in the clothes is The object is to provide a heat storage material composition and a clothing material that are maintained at a comfortable temperature without changing suddenly for a long period of time and that are extremely unaffected by seasonal and individual differences and that have excellent temperature stability.
本発明の課題は、蓄熱材組成として炭素数１６〜２１の直鎖の脂肪族炭化水素化合物の中から少なくとも３種以上の化合物から構成され、尚かつ８４ｋＪ／ｋｇ以上の融解熱量を有する蓄熱材を被服材料用として用いることにより達成される。 The subject of the present invention is a heat storage material composed of at least three kinds of straight-chain aliphatic hydrocarbon compounds having 16 to 21 carbon atoms as the heat storage material composition and having a heat of fusion of 84 kJ / kg or more. Is achieved by using as a material for clothing.
本発明の効果は、本発明の蓄熱材を被服材料として用いることにより暖かい、または涼しいそして快適と感じられる時間が長くなることである。更に本発明の蓄熱材をマイクロカプセルなどの固定化手段を用いて被服材料として加工したものを着衣することにより季節や個人差に影響を受けにくい温度調節機能を有する被服材料が得られることが見出された。 The effect of the present invention is that the time when the heat storage material of the present invention is used as a clothing material is warm, cool and comfortable. Furthermore, it is seen that a clothing material having a temperature control function that is hardly affected by the season and individual differences can be obtained by dressing the heat storage material of the present invention processed as a clothing material using an immobilizing means such as a microcapsule. It was issued.
本発明者は、衣服内環境温度が約２５〜３５℃の範囲から著しく逸脱すると急に寒い又は暑いという不快感が顕著になることを見出し、この衣服内温度範囲に長時間安定化させるためには上記炭素数の脂肪族炭化水素化合物の中から敢えて３種以上の蓄熱材を混合することが効果的であり、特に２８〜３２℃の範囲に衣服内温度が維持されることにより最も快適感が感じられることが判明した。この温度域に長時間持続するためには炭素数１７〜２０の範囲の直鎖脂肪族炭化水素化合物の合計質量比率を６０％以上に設定することにより顕著に達成されることも判明した。質量比率が６０％以下であると上記好ましい衣服内温度範囲から逸脱しやすくなるために好ましくない。しかしながら上記設定範囲の組み合わせであっても融解熱量が８４ｋＪ／ｋｇを下回れば本発明の課題は充分達成されないことも見出された。 The present inventor has found that when the environmental temperature in the garment deviates significantly from the range of about 25 to 35 ° C., the discomfort of suddenly becoming cold or hot becomes remarkable, and in order to stabilize the garment in this garment temperature range for a long time. It is effective to dare to mix three or more kinds of heat storage materials from among the aliphatic hydrocarbon compounds having the above-mentioned carbon number, and the most comfortable feeling is achieved especially when the temperature in the clothes is maintained in the range of 28 to 32 ° C. Was found to be felt. It has also been found that in order to maintain this temperature range for a long time, it can be achieved remarkably by setting the total mass ratio of straight chain aliphatic hydrocarbon compounds having 17 to 20 carbon atoms to 60% or more. A mass ratio of 60% or less is not preferable because it tends to deviate from the preferable temperature range in clothes. However, it has also been found that the object of the present invention cannot be sufficiently achieved if the heat of fusion is less than 84 kJ / kg even in the combination of the above setting ranges.
本発明の蓄熱材は、その融点以下では固体であり、融点以上では液体としてふるまうため、被服材料に用いるためには融解時に漏れ出さない様に何らかの固定化処理が必要である。具体的な手法としては吸油性の高分子材料に含浸させてゲル状態として扱う方法、同様に吸油性の無機顔料を用いる方法、多層構造繊維の層間または鞘部に含浸させる方法などが挙げられるがマイクロカプセルに内包させる方法が蓄熱材の漏れ出しがなく安全性の面で最も好ましい方法である。 Since the heat storage material of the present invention is solid below its melting point and behaves as a liquid above the melting point, it needs some immobilization treatment so that it does not leak out during melting in order to be used as a clothing material. Specific methods include a method of impregnating an oil-absorbing polymer material and treating it as a gel state, a method of using an oil-absorbing inorganic pigment, a method of impregnating between layers or sheath portions of multilayer structure fibers, and the like. The method of encapsulating in a microcapsule is the most preferable method in terms of safety because the heat storage material does not leak out.
蓄熱材をマイクロカプセル化する方法としては、複合エマルジョン法によるカプセル化法（特開昭６２−１４５２号公報）、蓄熱材粒子の表面に熱可塑性樹脂を噴霧する方法（同６２−４５６８０号公報）、蓄熱材粒子の表面に液中で熱可塑性樹脂を形成する方法（同６２−１４９３３４号公報）、蓄熱材粒子の表面でモノマーを重合させ被覆する方法（同６２−２２５２４１号公報）、界面重縮合反応によるポリアミド皮膜マイクロカプセルの製法（特開平２−２５８０５２号公報）等に記載されている方法を用いることができる。 As a method for microencapsulating the heat storage material, an encapsulation method by a composite emulsion method (Japanese Patent Laid-Open No. 62-1452), a method of spraying a thermoplastic resin on the surface of the heat storage material particles (JP-A 62-45680) , A method of forming a thermoplastic resin in the liquid on the surface of the heat storage material particles (JP-A 62-149334), a method of polymerizing and coating the monomer on the surface of the heat storage material particles (JP-A 62-225241), interfacial weight A method described in a method for producing a polyamide-coated microcapsule by a condensation reaction (Japanese Patent Laid-Open No. 2-258052) or the like can be used.
カプセル膜材としては特に限定されないが、界面重合法、インサイチュー法等の手法で得られる、ポリスチレン、ポリアクリロニトリル、ポリアミド、ポリアクリルアミド、エチルセルロース、ポリウレタン、アミノプラスト樹脂、またゼラチンとカルボキシメチルセルロース若しくはアラビアゴムとのコアセルベーション法を利用した合成あるいは天然の樹脂が用いられるが、物理的、化学的に安定で、脂肪族系炭化水素化合物でも良好な品質のマイクロカプセルが得られるインサイチュー法による尿素ホルマリン樹脂、メラミンホルマリン樹脂皮膜を用いたマイクロカプセルが特に好ましい。マイクロカプセル分散液のｐＨは特に限定されないが１０以下が好ましい。 The capsule membrane material is not particularly limited, but can be obtained by techniques such as interfacial polymerization method, in situ method, polystyrene, polyacrylonitrile, polyamide, polyacrylamide, ethyl cellulose, polyurethane, aminoplast resin, gelatin and carboxymethyl cellulose or gum arabic. A synthetic or natural resin using the coacervation method is used, but it is physically and chemically stable, and in-situ urea formalin can be obtained with good quality microcapsules even with aliphatic hydrocarbon compounds A microcapsule using a resin or a melamine formalin resin film is particularly preferred. The pH of the microcapsule dispersion is not particularly limited, but is preferably 10 or less.
マイクロカプセルの粒子径の設定は、乳化剤の種類、界面活性剤の濃度、乳化時の乳化液の温度、乳化比（水相と油相の体積比率）、乳化機、分散機等の微粒化装置の種類や運転条件（攪拌回転数、時間等）を変更することにより所望の値に設定することができるが、マイクロカプセルの破壊が少ないように１〜１０μｍの範囲に設定することが好ましい。本発明の粒子径は、ベックマンコールター社製コールターカウンター、マルチサイザーを用いて測定した体積平均粒子径を示す。 The microcapsule particle size is set by the type of emulsifier, the concentration of the surfactant, the temperature of the emulsified liquid during emulsification, the emulsification ratio (volume ratio of the water phase to the oil phase), and the atomizers such as emulsifiers and dispersers. The desired value can be set by changing the type and operating conditions (such as the number of rotations of stirring, time, etc.), but it is preferably set in the range of 1 to 10 μm so that the microcapsules are hardly destroyed. The particle diameter of the present invention indicates a volume average particle diameter measured using a Beckman Coulter Coalter Counter, Multisizer.
本発明の蓄熱材は固定化処理後、被服材料用支持基材に塗工又は含浸される。支持基材の具体例としては、綿、麻（亜麻、ラミー）、絹、羊毛などの繊維、再生繊維としてのレーヨン、キュプラ、半合成繊維としてのアセテート、トリアセテート、プロミックス、合成繊維としてのナイロン、アクリル、ビニロン、ビニリデン、ポリエステル、ポリエチレン、ポリプロピレン、フェノール系などの繊維が用いられ必要に応じて配合できる。 The heat storage material of the present invention is coated or impregnated on the support base for clothing material after the fixing treatment. Specific examples of the supporting substrate include cotton, hemp (flax, ramie), silk, wool and other fibers, rayon as recycled fiber, cupra, acetate as semi-synthetic fiber, triacetate, promix, nylon as synthetic fiber Fibers such as acrylic, vinylon, vinylidene, polyester, polyethylene, polypropylene, and phenol are used and can be blended as necessary.
塗工又は含浸装置の具体例として、エアーナイフコーター、ブレードナイフコーター、ニップコーター、グラビアコーター、スプレーコーター、カーテンコーターなどが用いられる。蓄熱材の付着量は塗工薬剤の濃度、粘度、塗工速度及び支持基材との親和性により調節されるが、本発明の蓄熱材の好ましい固定化手法であるマイクロカプセルを用いた場合には支持基材の単位面積当たり、１〜１００ｇ／ｍ2、好ましくは３〜３０ｇ／ｍ2の範囲で塗工、噴霧又は含浸される。この範囲以下であると蓄熱性能に乏しく、この範囲以上であると剛直性が強くなり風合いに悪影響を与えるため好ましくない。同時に有機、無機の顔料を添加することも可能であり、具体的には活性炭、酸化チタン、染料、着色顔料、赤外線吸収性顔料、中空粒子、磁性粉、珪藻土、香気成分、抗菌剤、防黴剤等を添加できる。 Specific examples of the coating or impregnation apparatus include an air knife coater, a blade knife coater, a nip coater, a gravure coater, a spray coater, and a curtain coater. The adhesion amount of the heat storage material is adjusted by the concentration of the coating agent, the viscosity, the coating speed, and the affinity with the support substrate, but when using the microcapsule that is a preferred immobilization method of the heat storage material of the present invention. the per unit area of the supporting substrate, 1~100g / m 2, preferably coated in the range of 3 to 30 g / m 2, it is sprayed or impregnated. If it is below this range, the heat storage performance is poor, and if it is above this range, the rigidity becomes strong and adversely affects the texture. It is also possible to add organic and inorganic pigments at the same time, specifically activated carbon, titanium oxide, dyes, coloring pigments, infrared absorbing pigments, hollow particles, magnetic powder, diatomaceous earth, aroma components, antibacterial agents, antifungals An agent or the like can be added.
本発明の蓄熱材を支持基材に塗工又は含浸する際には各種バインダーを付与することが可能である。好ましいバインダーとしては、例えば、アクリル系ラテックス、酢ビ系ラテックス、ウレタン系ラテックス、エポキシ系ラテックス、ポリエステル系ラテックス、ＳＢＲ系ラテックス、ＮＢＲ系ラテックス、エポキシ系バインダー、フェノール系バインダー、ＰＶＡ、デンプン等が単独又は併用して使用される。 When the heat storage material of the present invention is coated or impregnated on the support base material, various binders can be added. Preferred binders include, for example, acrylic latex, vinyl acetate latex, urethane latex, epoxy latex, polyester latex, SBR latex, NBR latex, epoxy binder, phenolic binder, PVA, and starch. Or used in combination.
以下本発明に係る具体的な実施例を以下に示す。 Specific examples according to the present invention are shown below.
以下に本発明の実施例を示す。実施例中の部数は固形質量部を表す。また、融点及び融解熱量は示差熱熱量計（米国パーキンエルマー社製、ＤＳＣ−７型）を用いて測定した。 Examples of the present invention are shown below. The number of parts in the examples represents solid mass parts. The melting point and heat of fusion were measured using a differential calorimeter (DSC-7, manufactured by Perkin Elmer, USA).
実施例１
蓄熱材として、ヘキサデカン（Ｃ１６）１％、ヘプタデカン（Ｃ１７）１４％、オクタデカン（Ｃ１８）８２％、ノナデカン（Ｃ１９）２％、エイコサン（Ｃ２０）１％の混合物（融点２５℃、融解熱量１９３ｋＪ／ｋｇ）を混合して被服材料用蓄熱材を得た。
Example 1
As a heat storage material, a mixture of hexadecane (C16) 1%, heptadecane (C17) 14%, octadecane (C18) 82%, nonadecane (C19) 2%, eicosane (C20) 1% (melting point 25 ° C., heat of fusion 193 kJ / kg) ) To obtain a heat storage material for clothing materials.
マイクロカプセルの調整方法
メラミン粉末１２重量部に３７％ホルムアルデヒド水溶液１５．４重量部と水４０重量部を加え、ｐＨを８に調整した後、約７０℃まで加熱してメラミン−ホルムアルデヒド初期縮合物水溶液を得た。ｐＨを４．５に調整した１０％スチレン−無水マレイン酸共重合体のナトリウム塩水溶液１００重量部中に上記組成の蓄熱材７０重量部を激しく撹拌しながら添加し、粒子径が３．０μｍになるまで乳化を行なった。得られた乳化液に、上記メラミン−ホルムアルデヒド初期縮合物水溶液全量を添加し７０℃で２時間撹拌を施した後、ｐＨを９まで上げて水を添加して乾燥固形分濃度４０％の蓄熱材マイクロカプセル分散液を得た。
Preparation method of microcapsule 15.4 parts by weight of 37% formaldehyde aqueous solution and 40 parts by weight of water were added to 12 parts by weight of melamine powder, and the pH was adjusted to 8, followed by heating to about 70 ° C. and aqueous solution of melamine-formaldehyde initial condensate. Got. 70 parts by weight of a heat storage material having the above composition was added to 100 parts by weight of an aqueous sodium salt solution of a 10% styrene-maleic anhydride copolymer adjusted to pH 4.5 with vigorous stirring, so that the particle size became 3.0 μm. Emulsification was carried out until After adding the total amount of the melamine-formaldehyde initial condensate aqueous solution to the obtained emulsion and stirring at 70 ° C. for 2 hours, the pH is raised to 9 and water is added to the heat storage material having a dry solid content concentration of 40%. A microcapsule dispersion was obtained.
このマイクロカプセル分散液を１２０ｇ／ｍ2のレーヨン繊維にマイクロカプセルの固形質量で１２ｇ／ｍ2になる様にニップコーターを用いて含浸、乾燥処理を施して蓄熱性を有する被服材料に加工し更に大人用下着に縫製した。成人男性５人にこの下着を着せ、その上にワイシャツ及び薄手での紳士用上着を着た状態で２０℃、湿度５５％の雰囲気下に３０分安静に着席させた後、真夏の炎天下を模した３５℃、湿度７５％の雰囲気下に移動した後の皮膚面と肌着面の間の温度と湿度を計測した。 The microcapsule dispersion is impregnated into a rayon fiber of 120 g / m 2 using a nip coater so that the solid mass of the microcapsule is 12 g / m 2 , and dried to be processed into a heat-resisting clothing material. Sewed on adult underwear. After five adult men put on this underwear, and then put on a shirt and a thin gentleman's outerwear, sit down at 20 ° C and humidity of 55% for 30 minutes, then under the hot summer heat The temperature and humidity between the skin surface and the underwear surface after moving under the simulated atmosphere of 35 ° C. and humidity 75% were measured.
測定の結果、比較として蓄熱材を全く加工していない同様の衣服を用いて測定を行った結果、衣服内温度は短時間のうちに約３３℃を越え、約６分で過半数以上が暑苦しいと感じ始めた。しかしながら実施例１に示す蓄熱材マイクロカプセルを加工した衣服を身につけて同様の測定を行った結果、約３５分後に過半数が暑苦しいと感じ出し、明らかに両者で快適さが持続する時間に差が生じることが分かった。 As a result of the measurement, as a result of measurement using a similar garment in which no heat storage material was processed, the temperature in the garment exceeded about 33 ° C in a short time, and more than a majority was uncomfortable in about 6 minutes. I started feeling. However, as a result of wearing the clothes processed with the heat storage material microcapsules shown in Example 1 and performing the same measurement, after about 35 minutes, the majority feels uncomfortable, and clearly there is a difference in the time during which the comfort lasts. I found it to happen.
実施例２
蓄熱材として、オクタデカン（Ｃ１８）５％、ノナデカン（Ｃ１９）６４％、エイコサン（Ｃ２０）２３％、ヘンエイコサン（Ｃ２１）５％の混合物から成る混合物（融点３０℃、融解熱量１６４ｋＪ／ｋｇ）から成る被服材料用蓄熱材を得た。この蓄熱材を用いて実施例１と同様にマイクロカプセル化を行い、同様に同じ繊維に含浸加工を行い大人用下着を加工した。成人男性５人にこの下着を着せ、その上にワイシャツ及び防寒着を着た状態で３３℃、湿度５５％の雰囲気下に３０分安静に着席させた後、冬場の外気温を模した１０℃、湿度４０％の雰囲気下に移動した後の皮膚面と肌着面の間の温度と湿度を計測した。
Example 2
Clothing comprising a mixture of 5% octadecane (C18), 64% nonadecane (C19), 23% eicosane (C20), 5% heneicosane (C21) as a heat storage material (melting point 30 ° C., heat of fusion 164 kJ / kg) A heat storage material for the material was obtained. Using this heat storage material, microencapsulation was performed in the same manner as in Example 1, and the same fiber was impregnated in the same manner to process an underwear for adults. 5 adult men wear this underwear, and then sit down at 33 ° C in a 55% humidity atmosphere for 30 minutes with a shirt and cold protection on it, and then 10 ° C imitating the outside temperature in winter The temperature and humidity between the skin surface and the underwear surface after moving in an atmosphere with a humidity of 40% were measured.
測定の結果、比較として蓄熱材を全く加工していない同様の衣服を用いて測定を行った結果、短時間のうちに衣服内温度が約３０℃を下回り、過半数以上が寒いと感じ始めるのに約１５分であった。しかしながら実施例２に示す蓄熱材マイクロカプセルを加工した衣服を身につけて同様の測定を行った結果、約５０分後に過半数が寒いと感じ出し、明らかに両者で快適さが持続する時間に差が生じることが分かった。 As a result of measurement, as a result of measurement using a similar garment that does not process the heat storage material at all, the temperature in the garment falls below about 30 ° C in a short time, and the majority of people start to feel cold. It was about 15 minutes. However, as a result of wearing the clothes processed with the heat storage material microcapsule shown in Example 2 and performing the same measurement, the majority felt that it was cold after about 50 minutes, and clearly there was a difference in the time during which comfort was sustained in both cases. I found it to happen.
比較例１
蓄熱材として、へプタデカン（Ｃ１７）１％、オクタデカン（Ｃ１８）９９％の２成分から成る被服材料用蓄熱材（融点２８℃、融解熱量２３０ｋＪ／ｋｇ）を得た。
この蓄熱材を実施例１と同様の加工を行い同様の評価を行ったところ、
蓄熱材の融解熱量が実施例１の蓄熱材よりはるかに大きいにもかかわらず、約２０分で過半数が暑苦しいと感じ出し実施例１の蓄熱材組成の方が快適さを感じる時間が長いことが分かった。
Comparative Example 1
As a heat storage material, a heat storage material for clothing materials (melting point 28 ° C., heat of fusion 230 kJ / kg) composed of two components of 1% heptadecane (C17) and 99% octadecane (C18) was obtained.
When this heat storage material was processed in the same manner as in Example 1 and the same evaluation was performed,
Although the heat of fusion of the heat storage material is much larger than that of the heat storage material of Example 1, the majority feels uncomfortable in about 20 minutes and the heat storage material composition of Example 1 may feel more comfortable. I understood.
比較例２
蓄熱材として、ヘプタデカン（Ｃ１７）１２％、オクタデカン（Ｃ１８）８０％、ノナデカン（Ｃ１９）２％の他に、イソパラフィン及び芳香族成分を６％含む蓄熱材混合物（融点２３℃、融解熱量７１ｋＪ／ｋｇ）か成る被服材料用蓄熱材を得た。この蓄熱材を実施例１と同様の加工を行い同様の評価を行ったところ、蓄熱材の融解熱量があまりにも小さいために同様の着衣試験においても未加工の衣服とほとんど同等の効果しか得られず衣服内温度の緩衝効果は認められず快適さは感じられなかった。
Comparative Example 2
In addition to 12% heptadecane (C17), 80% octadecane (C18), 2% nonadecane (C19) as a heat storage material, a heat storage material mixture containing 6% isoparaffin and aromatic components (melting point 23 ° C., heat of fusion 71 kJ / kg) A heat storage material for clothing material was obtained. When this heat storage material was processed in the same manner as in Example 1 and the same evaluation was performed, the amount of heat of fusion of the heat storage material was so small that only the same effect as that of unprocessed clothes was obtained in the same clothing test. There was no cushioning effect on the temperature inside the clothes, and no comfort was felt.
本発明の蓄熱材を用いて衣料品のみならず、寝具、医療用保温器具、スポーツ用サポーターなどにも応用可能である。また室温を安定化させる建築用材料として夏場は異常な室温の上昇、冬場は朝夕方の室温の低下を抑え、冷房や暖房などの設備を使用しなくとも快適な環境が得られることが可能な室内材料として利用することも可能である。 Using the heat storage material of the present invention, it can be applied not only to apparel but also to bedding, medical warming equipment, sports supporters, and the like. Also, as a building material that stabilizes the room temperature, it is possible to obtain a comfortable environment without using cooling or heating equipment, suppressing an abnormal rise in room temperature in summer and a drop in room temperature in the morning and evening in winter. It can also be used as an indoor material.
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| WO2014199716A1 (en) | 2013-06-14 | 2014-12-18 | Ｊｘ日鉱日石エネルギー株式会社 | Paraffin latent heat storage material composition and use of paraffin composition as latent heat storage material |
| WO2014199715A1 (en) | 2013-06-14 | 2014-12-18 | Ｊｘ日鉱日石エネルギー株式会社 | Paraffin latent heat storage material composition and use of paraffin composition as latent heat storage material |
| JP2015504451A (en) * | 2011-11-01 | 2015-02-12 | シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイＳｈｅｌｌ Ｉｎｔｅｒｎａｔｉｏｎａｌｅ Ｒｅｓｅａｒｃｈ Ｍａａｔｓｃｈａｐｐｉｊ Ｂｅｓｌｏｔｅｎｖｅｎｎｏｏｔｓｈａｐ | Paraffin wax |
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| JP2008184693A (en) * | 2007-01-26 | 2008-08-14 | Teijin Fibers Ltd | Heat-retaining cloth and textile product |
| JP2015504451A (en) * | 2011-11-01 | 2015-02-12 | シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイＳｈｅｌｌ Ｉｎｔｅｒｎａｔｉｏｎａｌｅ Ｒｅｓｅａｒｃｈ Ｍａａｔｓｃｈａｐｐｉｊ Ｂｅｓｌｏｔｅｎｖｅｎｎｏｏｔｓｈａｐ | Paraffin wax |
| WO2014199716A1 (en) | 2013-06-14 | 2014-12-18 | Ｊｘ日鉱日石エネルギー株式会社 | Paraffin latent heat storage material composition and use of paraffin composition as latent heat storage material |
| WO2014199715A1 (en) | 2013-06-14 | 2014-12-18 | Ｊｘ日鉱日石エネルギー株式会社 | Paraffin latent heat storage material composition and use of paraffin composition as latent heat storage material |
| JP2015000944A (en) * | 2013-06-14 | 2015-01-05 | Ｊｘ日鉱日石エネルギー株式会社 | Paraffin-based latent heat-storing material composition and use as latent heat storing material of paraffin-based composition |
| JP2017025451A (en) * | 2015-07-27 | 2017-02-02 | 群馬県 | Cloth, and processing method of the same |
| JP2020147721A (en) * | 2019-03-15 | 2020-09-17 | アキレス株式会社 | Urethane foam having latent heat storage function |
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