JP2004339678A - Method for producing water-absorbing resin composite material and deposited material of the same - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a method for efficiently producing a composite material of a water-absorbing resin and fibers, capable of stably fastening the fibers to the water-absorbing resin in case of absorbing water and being swollen, to say nothing of being dried, capable of uniformly fastening the water-absorbing resin to the fibers with a high content, capable of making the composite material soft so as to decrease thickness of the material and to subject the material itself to opening, capable of making the composite material uniformly mixed with other materials, and especially capable of extremely efficiently producing the water-absorbing resin composite material having two types of fibers comprising one type of the fiber which is embedded in a water-absorbing resin particle and of which the part is exposed to the outside of the resin particle and the other type of the fiber which is not embedded in the resin particle and of which the part is adhered to a surface of the resin particle. <P>SOLUTION: This method for producing the water-absorbing resin composite material comprises contacting a droplet which contains a polymerizable monomer in a state prior to polymerization and/or in the course of the polymerization and a solvent with a first fiber which is supplied from a first supply port of a reactor in a gaseous phase, so as to make the polymerization of the polymerizable monomer progress, then contacting a droplet which contains the polymerizable monomer in the course of the polymerization, the solvent, and the first fiber with a second fiber which is supplied from a second supply port of the reactor in the gaseous phase, and further making the polymerization of the polymerizable monomer progress. <P>COPYRIGHT: (C)2005,JPO&NCIPI

Description

  TECHNICAL FIELD The present invention relates to a method for producing a water-absorbent resin composite and a deposit thereof. The deposit of the water-absorbent resin composite produced by the present invention is thin, flexible and openable. The water-absorbent resin composite and the deposit thereof produced by the present invention are preferably used for the production of water-absorbent articles such as sanitary materials such as disposable diapers and sanitary napkins, and industrial materials.

  Conventionally, water-absorbing resins that absorb a large amount of water have been widely used for sanitary materials, industrial materials, and the like. When a water-absorbent resin is used as a composite with other materials, such as a disposable diaper, the water-absorbent resin has a fixed property before water absorption, a fixed property after water absorption, a thin composite, flexibility, and a high water-absorbent resin. Improvement such as content increase is required.

  Japanese Patent Application Laid-Open No. 63-63723 (Patent Document 1) discloses that a water-absorbent resin is kneaded and dispersed with hydrophilic fibers in a state where water or a water-containing solvent is absorbed and swollen, followed by drying and pulverization, or water-soluble ethylenic resin. A composite comprising a hydrophilic base material in which at least a part of the fiber is embedded is disclosed by polymerizing the unsaturated monomer while mixing it with the hydrophilic fiber, followed by drying and pulverization. By this technique, a composite comprising a water-absorbent resin and fibers can be obtained. However, the composite obtained by this technique must be ground before it can be used. For this reason, fiber breakage and generation of crushed products are inevitable, causing problems such as generation of fiber waste, fine particles of water-absorbent resin, and generation of non-fixed water-absorbent resin. Furthermore, a reduction in the water absorption ability due to molecular chain cleavage of the water-absorbent resin is unavoidable due to mechanical shock during kneading and dispersion. In addition, by entraining air during the intermixing dispersion, it is inevitable that the water absorption capacity under pressure and the bulk density decrease due to the generation of voids (voids) inside the water absorbent resin. In addition, as long as it is manufactured by this method, only a fiber in which at least a part of the fiber is embedded in the water-absorbent resin can be obtained. I can't get it.

  Japanese Patent Publication No. 5-58030 (Patent Publication 2) describes a water-absorbent article comprising a fibrous base material at least partially composed of hydrophobic fibers and a water-absorbent resin adhered to the base material. ing. This water-absorbent article is characterized in that at least a part of the water-absorbent resin has a substantially spherical shape, wraps the base fiber, and is attached discontinuously. In this technique, since the base material is a fiber, the flexibility of the composite can be ensured. Further, a water absorbing resin is also fixed. However, since the water-absorbent resin surrounds the fibers, it is inevitable that the fibers hinder the swelling of the water-absorbent resin. Also, the ratio of water-absorbent resin / fiber must be reduced in order to make the water-absorbent resin adhere to the fiber discontinuously. However, even if the water-absorbent resins are discontinuous on the same fiber, if the distance between the resins is small, swelling inhibition will occur. Therefore, considering that aspect, it is necessary to increase the ratio of the water-absorbent resin / fiber. Can not. Furthermore, there is a restriction that the base material used is limited to hydrophobic fibers for controlling the morphology of the water absorbent resin.

  Japanese Patent Application Laid-Open No. 11-93073 (Patent Publication 3) discloses a non-molded fiber in which a substantially spherical water-absorbent resin is discontinuously fixed on a surface thereof, and the non-molded fiber is formed by depositing the non-molded fiber. Or a composite in which non-molded fibers are bonded to each other via the water-absorbing resin. It can be said that the immobilization of the water-absorbent resin has been realized in view of the fact that the water-absorbent resin and the fiber are bonded. However, as long as the bonding is on the surface of the fiber, the bonding form must be point bonding or linear bonding, and the bonding strength in a dry state cannot be said to be sufficient. For this reason, there is a problem that the fixability in the dry state is insufficient. In addition, in a state where the water-absorbent resin absorbs water and the surface swells and expands, there is a problem that the water-absorbent resin easily peels off and moves.

  This publication also describes a mode in which the fibers are wrapped by the water-absorbent resin. However, similar to the above-mentioned Japanese Patent Publication No. 5-58030 (Patent Publication 4), the swelling inhibition of the water-absorbent resin by the fibers is also described. There is a disadvantage that is inevitable. Further, since the fibers are bonded to each other via the water-absorbent resin, it is difficult to open the composition, and if the fiber is forcibly opened, the water-absorbent resin itself is damaged, and the water-absorbing performance deteriorates and the non-fixed water-absorbing property is reduced. Problems such as generation of resin occur. Therefore, it is difficult to uniformly mix the composition containing the composite with other materials after opening the composition.

JP-A-63-63723 Japanese Patent Publication No. 5-58030 JP-A-11-93073 Japanese Patent Publication No. 5-58030

  The present invention has been made to solve the problems of the prior art described in the above publication. That is, in the present invention, the fibers are stably fixed to the water-absorbent resin not only at the time of drying but also at the time of water absorption and swelling, and the water-absorbent resin can be uniformly fixed to the fibers at a high content, and is flexible and An object of the present invention is to provide a method for efficiently producing a composite of a water-absorbent resin and a fiber and a deposit thereof, which can be thinned and spread, and can be uniformly mixed with other materials. In particular, fibers that are embedded in the water-absorbent resin particles and partially exposed from the resin particles, and partially adhered to the surface of the resin particles without being embedded in the resin particles. It is an object of the present invention to provide a method for extremely efficiently producing a water-absorbent resin composite having two types of fibers, ie, fibers.

As a result of intensive studies, the present inventors have found that the object can be achieved by a method for producing a water-absorbent resin composite having specific steps described below and a deposit thereof.
That is, the present invention provides a method for producing a water-absorbent resin composite containing one water-absorbent resin particle and two or more fibers in a reactor from a polymerizable monomer and a fiber that form a water-absorbent polymer by polymerizing. In the water-absorbent resin composite, the water-absorbent resin particles are substantially spherical, and at least one of the two or more fibers has a part of the fibers embedded in the resin particles. And a part thereof is exposed from the resin particles, and one or more of the two or more fibers are not embedded in the resin particles, and a part of the fibers is the resin. Adhering to the surface of a particle, the method comprises the steps of: providing a droplet containing the polymerizable monomer and a solvent before and / or during polymerization, and a first droplet supplied from a first supply port of the reactor. The fibers are brought into contact in the gas phase to polymerize the polymerizable monomer. And then contacting the droplets containing the polymerizable monomer, solvent and fiber during polymerization with the second fiber supplied from the second supply port of the reactor in the gas phase, The present invention provides a method for producing a water-absorbent resin composite, which comprises the steps of producing the water-absorbent resin composite by promoting polymerization.
The present invention also provides a method for producing a deposit of a water-absorbent resin composite, comprising a step of depositing the water-absorbent resin composite obtained by this method to produce a deposit.

  According to the production method of the present invention, the fibers are stably fixed to the water-absorbent resin not only at the time of drying but also at the time of water absorption and swelling, and the water-absorbent resin can be uniformly fixed to the fibers at a high content. Efficiently manufactures a composition containing a water-absorbent resin-fiber composite, which is flexible and thin, can be opened itself, and can be uniformly mixed with other materials. can do.

Embodiment of the Invention

  Hereinafter, the method for producing the water-absorbent resin composite and the deposit thereof of the present invention will be described in detail with reference to preferred embodiments. In this specification, a numerical range represented by using “to” means a range including numerical values described before and after “to” as a lower limit and an upper limit.

  The production method of the present invention is a method for producing a novel water-absorbent resin composite having a characteristic structure (hereinafter, “composite A”) and a deposit thereof.

I. Complex A
1. Structure and Components Composite A contains one substantially spherical water-absorbent resin particle and two or more fibers. One or more fibers included in the composite A have a part of the fibers embedded in the water-absorbent resin particles and a part of the fibers is exposed from the water-absorbent resin particles. In addition, one or more fibers included in the composite A have a part of the fibers adhered to the surface of the water-absorbent resin particles without the fibers being embedded in the water-absorbent resin particles. That is, the essential components of the complex A are the following three types.
i) Water-absorbing resin particles
ii) Fiber partially embedded in the water-absorbent resin particles and partially exposed from the water-absorbent resin particles (hereinafter, “partially embedded fiber”)
iii) Fibers that adhere to the surface of the water-absorbent resin particles but are not embedded in the water-absorbent resin particles (hereinafter “surface-adhesive fibers”)
Hereinafter, fibers bonded to the water-absorbent resin particles in the composite A, that is, ii) partially embedded fibers and iii) surface-adhered fibers may be collectively referred to as “bonded fibers”. The dry weight ratio of the binding fiber and the water-absorbent resin particles in the composite A is preferably from 1: 1 to 1: 1,000,000, more preferably from 1: 2 to 1: 100,000, It is even more preferred that the ratio is 1: 3 to 1: 10,000.

2. Each component 1) Water-absorbent resin The water-absorbent resin plays a role in the complex A to absorb liquids such as water, urine, blood, and menstrual blood according to the purpose of use.

(Chemical composition)
The water-absorbing resin in the complex A is generally a polymer having a saturated water-absorbing ability capable of absorbing liquids such as water, urine, blood, menstrual blood, and the like under normal temperature and normal pressure by about 1 to 1,000 times its own weight. In order to absorb these liquids, it is necessary to have a functional group having a high affinity for these liquids in the polymer chain. Such functional groups include (partially) neutralized carboxylic acids, carboxylic acids, (partially) neutralized sulfonic acids, sulfonic acids, and hydroxy. Of these, partially neutralized carboxylic acids are preferred. As such a monomer that provides a partially neutralized carboxylic acid in the polymer chain, an unsaturated carboxylic acid is preferable, and acrylic acid is particularly preferable.
Although the molecular structure of this polymer may be linear, it is necessary to maintain the shape even after absorbing and swelling a desired liquid. For this reason, a crosslinked polymer having a crosslinked structure between polymer chains is usually preferable so that the polymer chains are not dissolved. This cross-linking may be either chemical cross-linking such as covalent bonding or ionic bonding or physical cross-linking due to entanglement of polymer chains. From the viewpoint of chemical stability, chemical crosslinking is preferred, and covalent bonds are more preferred.
Therefore, the preferred water-absorbent resin is a crosslinked unsaturated carboxylic acid polymer, more preferably a crosslinked acrylic acid polymer.

(shape)
The water absorbing resin in the composite A is substantially spherical particles. Here, the term “substantially spherical” means a shape of a true sphere or an ellipsoid as a whole, and fine irregularities (ie, wrinkles, projections, depressions, etc.) may be provided on the surface. In addition, voids such as pores and cracks may be present on the surface or inside. The particle size of the water-absorbing resin particles is preferably from 50 to 1,000 μm. The particle size is more preferably from 100 to 900 μm, particularly preferably from 200 to 800 μm.
As with conventional pulverized water-absorbent resin, if it has an irregular and sharp cut surface, it will cause irritation to the skin, and the sharp cut surface will be lost due to mechanical addition, resulting in fine particles. There is a disadvantage that it occurs. However, the substantially spherical water-absorbing resin particles used in the present invention do not have such a disadvantage. In addition, there is an advantage that the density can be increased because the closest packing can be performed as compared with the irregular-shaped product.

2) Bonding fiber As described above, the bonding fiber is composed of the partially embedded fiber and the surface adhesive fiber. Hereinafter, each fiber will be described in detail.

(Fiber type)
As the fibers, synthetic fibers, natural fibers, semi-synthetic fibers, inorganic fibers, and the like can be used. It is preferable that each fiber is firmly bonded to the water-absorbent resin before and after water absorption from the viewpoint of the fixability of the water-absorbent resin.
In general, it is known that the adhesive force between different substances increases as the affinity between the two substances increases. The water-absorbing resin is one of the substances having the highest hydrophilicity, and in this sense, it can be said that the fibers having higher hydrophilicity have higher adhesive strength. The contact angle of water can be used as a quantitative measure of the hydrophilicity of the fiber. That is, the smaller the contact angle (ie, the greater the hydrophilicity), the greater the adhesive strength. Conversely, the larger the contact angle (ie, the smaller the hydrophilicity), the smaller the adhesive strength. In the present invention, a water-absorbent resin composite having a special shape containing at least two fibers per water-absorbent resin particle is produced using fibers having a contact angle of 60 ° or less on the surface of a fiber material of water. From the viewpoint of the adhesive strength of the fibers to the water-absorbent resin particles, the contact angle of water on the surface of the fiber material is more preferably 50 ° or less, and most preferably 40 ° or less. Examples of such highly hydrophilic fibers, so-called hydrophilic fibers, include cellulose-based fibers such as pulp, rayon, cotton, and regenerated cellulose, and polyamide-based and polyvinyl alcohol-based fibers. The use of such a hydrophilic fiber not only enhances the adhesive strength with the water-absorbent resin, but also has other functions of the hydrophilic fiber, such as an action of attracting water to the water-absorbent resin (so-called water-conducting resin). ) Can also be increased. In particular, for use in sanitary materials, it is preferable to select pulp among hydrophilic fibers in view of low irritation to the skin and a soft feel.

  Conversely, in combination with hydrophilic fibers, fibers having low hydrophilicity from the viewpoint of water permeability and water diffusibility, that is, hydrophobic fibers, can also be used. For example, polyester-based, polyethylene-based, polypropylene-based, polystyrene-based, polyvinyl chloride-based, polyvinylidene chloride-based, polyacrylonitrile-based, polyurea-based, polyurethane-based, polyfluoroethylene-based, and polyvinylidene cyanide-based fibers can be used. . For example, a hydrophilic fiber can be selected as the embedding fiber, and a hydrophobic fiber can be selected as the surface adhesive fiber. If such an embodiment is adopted, it can be expected that the hydrophobic fibers improve the diffusivity of water between the water-absorbing resins.

  The hydrophilicity and hydrophobicity of the exemplified series of fibers are not absolute, and they vary depending on the raw material monomer, modification, and the like. For this reason, the hydrophilicity and hydrophobicity of the fibers used are evaluated by contact angle measurement. The contact angle depends on the shape and the smoothness of the surface of the fiber material to be measured, but the contact angle in the present invention is obtained by molding the fiber material into a film, and determining the contact angle of distilled water on the smooth surface as described below. It is a value measured using an apparatus that performs the measurement.

(shape)
From the viewpoint of blocking prevention, it is also important to select fibers in consideration of the rigidity and diameter of the fibers described below.
In the present invention, preferred as the binding fibers are those having an average fiber length of 50 to 50,000 μm. More preferably, it is 100 to 30,000 μm, and further preferably, it is 500 to 10,000 μm. If the fiber length is too long, the fibers adhere to a plurality of water-absorbent resins, and the independence of each water-absorbent resin composite cannot be ensured, and it tends to be difficult to open a composition containing this composite. Conversely, if the fiber length is too short, it tends to be difficult to embed or adhere to the water absorbent resin.
In order to obtain the desired shape of the composite A, the ratio of the water-absorbent resin particle diameter to the fiber length is preferably from 2: 1 to 1: 1,000. It is more preferably from 1: 1 to 1: 500, particularly preferably from 1: 2 to 1: 100.

The binding fiber used in the present invention is preferably a fiber having a fiber diameter of 0.1 to 500 dtex, more preferably a fiber having 0.1 to 100 dtex, still more preferably 1 to 50 dtex, particularly preferably 1 to 50 dtex. 10 decitex. If the fiber diameter is too large, the rigidity of the fiber is so large that not only embedding and adhesion to the water-absorbing resin become difficult, but also compression molding becomes difficult, which may be unfavorable for thinning. In addition, for applications such as sanitary products, the skin feels unpleasant and unpleasant. Conversely, if the fiber diameter is too small, water conductivity and diffusibility may not be ensured. In addition, due to insufficient rigidity, the blocking phenomenon may not be prevented.
The appearance of the fibers may be linear or have crimps such as crimps.
From the above viewpoints, the fiber type, fiber length, fiber diameter, and appearance are appropriately selected.

(Partially embedded fiber)
The partially embedded fibers play a role in securing the fixability of the water absorbent resin. The fibers also improve the fixability of the water-absorbing resin before and after water absorption. That is, the fibers extending from the surface of the water absorbent resin prevent the water absorbent resin from rotating or translating when pressed. Some of the fibers are embedded in the water-absorbent resin and do not detach from the water-absorbent resin even after water absorption, so that they can play an important role in the fixability after water absorption. The shape of the fiber used may be a hollow or side-by-side type having high rigidity in order to enhance water conductivity.

When the partially embedded fibers are composed of hydrophilic fibers, the fibers have an effect of increasing the water conductivity of the water absorbent resin. That is, water can be directly introduced into the water absorbent resin through the fibers. In order to exhibit this function more effectively, it is preferable to select and use the above-mentioned fibers having high water conductivity.
Further, these fibers also have a role of ensuring the independence of each water absorbent resin composite. In the later-described composite precursor polymerization process, the fibers prevent the water-absorbent resins from fusing with each other due to steric hindrance. That is, the fibers extending from the surface of the water-absorbent resin prevent the water-absorbent resins from contacting each other during the polymerization in the composite precursor, thereby preventing fusion of the water-absorbent resins. As a result, each water-absorbent resin composite (precursor) maintains its independence, prevents adhesion to the reactor wall in the production process and the treatment process, and can impart the composition described later with openability.

  On the other hand, this fiber gives each of the water-absorbing composites an appropriate physical entanglement, and also gives a form retention property that, when a plurality of composites are collected and formed into a lump, the composites do not easily come apart under their own weight. That is, the composite A itself has shape retention even without adding free fibers and the like. Therefore, the composite A has a remarkable feature that it can impart opening properties when formed into a composition and also has shape retention. In addition, the fibers give composite A a soft, smooth feel. Combined with the fact that the water-absorbent resin is substantially spherical, the composite A gives a very soft touch when pressed even in a dry state, and thus is suitable for applications such as sanitary materials.

(Surface adhesive fiber)
The surface adhesive fibers have an effect of securing the fixability of the water-absorbing resin before absorbing water. Further, after swelling, the fibers on the surface of the water-absorbent resin form gaps between the water-absorbent resins, and have an effect of securing a flow path of water. In order to obtain this effect, the fibers need not necessarily adhere to the water-absorbent resin even after water absorption, but it is preferable that at least the fibers be closely arranged on the surface of the water-absorbent resin. Therefore, it is advantageous that the fibers adhere to the surface of the water-absorbent resin before water absorption as in the present invention. In some cases, it is preferable to use fibers having a certain rigidity in order to form a gap between the water-absorbing resins and secure a flow path for water. Further, in combination with the above-mentioned partially embedded fibers, there is also an effect of securing the fixability of the water-absorbing resin before water absorption. The shape of the fiber used may be hollow or side-by-side type or the like in order to enhance the diffusivity.

When the surface-adhesive fibers are composed of hydrophilic fibers, the effect of preventing the blocking phenomenon that the water-absorbent resins come into contact with each other due to the swelling of the water-absorbent resin when the fibers absorb water and hinder the flow path of water. Is shown. That is, at the time of water absorption, it plays a role of transporting and diffusing water evenly to the surface of each water absorbing resin. On the other hand, when the surface-adhesive fibers are made of a hydrophobic resin, the fibers exhibit a function of improving the diffusivity of water between the water-absorbent resins.
Further, this fiber has a role of ensuring the independence of each water-absorbent resin composite, the shape retention, the soft and smooth feel by the same action as the above-mentioned partially embedded fiber, and gives the same effect.

3. Feature 1) Balance between fixability and water absorption capacity (composite effect of each fiber)
Generally, it is not compatible with securing the fixability of the water-absorbing resin and securing the water absorbing ability such as the holding ability and the water absorbing ability under pressure. That is, in order to ensure sufficient fixation not only before water absorption but also after water absorption, a strong adhesive force between the water-absorbent resin and the fiber, which exceeds the water-swelling expansion force, is required even after water absorption. As a matter of course, the fiber causes the water-absorbent resin itself to inhibit the water-absorbing swelling, and does not provide sufficient water-absorbing ability. Conversely, if the bonding surface between the water-absorbent resin and the fiber is allowed to swell freely in an attempt to secure water absorption capacity such as retention capacity and water absorption under pressure, the bonding surface between the water-absorbent resin and the fiber is destroyed, Does not provide sufficient fixation.
In the composite A of the present invention, both the partially embedded fiber and the surface-bonded fiber are essential. That is, a water-absorbent resin composite having only partially embedded fibers is not sufficiently effective in preventing a blocking phenomenon during water absorption. On the other hand, a water-absorbent resin composite having only surface-adhesive fibers does not have sufficient fixability of the water-absorbent resin after absorbing water. Therefore, both fibers are indispensable in order to exhibit the above-mentioned action before and after water absorption. The coexistence of the two fibers makes it possible to simultaneously secure the fixing properties of the water-absorbent resin and the water-absorbing ability, which are originally contradictory to each other. That is, the complex A has a feature that ensures not only the retention ability but also the water absorption ability under pressure while securing sufficient fixability not only before water absorption but also after water absorption. The types of the two fibers may be the same or different, and are appropriately selected for the purpose of use and the respective effects.

2) Spreadability One of the characteristics of the composite A is that not only the aggregate of the composite A has the spreadability but also the spreadability of the water-absorbent resin composite composition containing the composite A. In that it can have Such features are ensured by the fact that each complex is substantially independent. That is, it is desired that the fibers constituting one composite do not substantially adhere to the other composite. For that purpose, it depends on the manufacturing conditions, but can be obtained by appropriately selecting the fiber length of the fiber to be used as described above. As described later, the spreadability can be evaluated by the ease of worsting and the state of breakage of the water-absorbent resin particles after worsting.

3) Morphological Retention In the composite A, not only the aggregate of the composite A has a shape retention property, but also the water-absorbent resin composite composition containing the composite A has a shape retention property. There is also a feature that can be. As described above, the binding fibers in the composite A give each of the water-absorbing composites an appropriate physical entanglement, and when the water-absorbent resin composite composition containing the composite A is agglomerated, it is easily weighed at its own weight. Provides form retention that does not fall apart.

II. 1. Water-absorbent resin composite composition Structure A water-absorbent resin composite composition (hereinafter, “composition of the present invention”) obtained by the production method of the present invention is characterized by containing the above-mentioned composite A, and the following composite B, composite C and Other components such as free fibers may be contained. In the composition of the present invention, the dry weight ratio of the total fiber (bonded fiber + free fiber) to the water-absorbent resin is usually 70:30 to 2:98, preferably 50:50 to 5:95, more preferably. Is 30:70 to 5:95. The ratio of the bonding fibers to the total fibers is usually 3 to 100%.
Further, the composition of the present invention preferably has a bulk density of 0.20 to 0.85 g / cm ³ , more preferably 0.30 to 0.85 g / cm ³ , and more preferably 0.40 to 0. Even more preferably, it is 85 g / cm ³ . Since each component contained in the composition of the present invention is independent and has spreadability, the composition itself also maintains spreadability.

2. Component 1) Complex A
The composition of the present invention usually contains the above-mentioned complex A in a weight fraction of 1 or less, preferably 0.1 or more, more preferably 0.2 or more, and still more preferably 0.3 or more. . The average particle size of the water-absorbing resin constituting the composite A contained in the composition of the present invention is preferably 50 to 1,000 μm, more preferably 100 to 900 μm, and particularly preferably 200 to 800 μm. Further, the average fiber length of the fibers constituting the composite A contained in the composition of the present invention is preferably 50 to 50,000 μm, more preferably 100 to 30,000 μm, and 500 to 10,000 μm. Is particularly preferred. Furthermore, the average fiber diameter of the fibers constituting the composite A contained in the composition of the present invention is preferably 0.1 to 500 dtex, more preferably 0.1 to 100 dtex, and 1 to 50 dtex. Even more preferably, it is decitex, and particularly preferably 1 to 10 decitex.

2) Complex B
“Composite B” is “a water-absorbent resin composite including one or more water-absorbent resin particles and one or more fibers, wherein the water-absorbent resin particles are substantially spherical, and one or more fibers are A part of the fibers is embedded in the resin particles and a part thereof is exposed from the resin particles, and none of the fibers is adhered to the surface of the resin particles. " It is. At least one of the bonding fibers bonded to the water-absorbent resin of the composite B is a partially embedded fiber, and does not include a surface-bonded fiber. That is, the essential components of the composite B are the following two types, and the surface adhesive fiber is not a component.
i) Water-absorbing resin particles
ii) The fibers in the partially embedded fiber composite B can be selected in the same manner as the fibers described above in the section of the binding fiber of the composite A. The weight fraction of the complex B in the composition of the present invention is usually 0 to 90% by weight. If the amount of the composite B is too large, the fixability of the water-absorbent resin before water absorption tends to be impaired.

3) Complex C
“Composite C” is “a water-absorbent resin composite containing one or more water-absorbent resin particles and one or more fibers, wherein the water-absorbent resin particles are substantially spherical, and one or more of the fibers are A part of the fiber is adhered to the surface of the resin particle, and none of the fiber is a water-absorbent resin composite which is embedded in the resin particle. " One or more of the bonding fibers bonded to the water-absorbent resin of the composite C are surface-bonded fibers and do not include partially embedded fibers. That is, the essential components of the composite C are the following two types, and the partially embedded fiber is not a component.
i) Water-absorbing resin particles
ii) The fibers in the surface-bonded fiber composite C can be selected in the same manner as the fibers described above in the section of the binding fiber of the composite A. The weight fraction of the composite C in the composition of the present invention is usually 0 to 90% by weight. If the amount of the complex C is too large, the gel fixability after water absorption tends to be impaired.

  The weight ratio of the composites A to C is usually A: B: C = 10 to 100: 0 to 90: 0 to 90.

4) Free fiber "Free fiber" is "fiber that is neither embedded nor bonded in a water absorbent resin". The composition of the present invention may include one or more free fibers. By adding free fibers, flexibility, softness, water conductivity, water permeability, water diffusivity, air permeability and the like can be further improved.
As the fibers, as in the case of the binding fibers, synthetic fibers, natural fibers, semi-synthetic fibers, inorganic fibers and the like can be used. The fiber used is selected according to the purpose of use of the water-absorbent resin composite composition. For example, when using the composition for a water-absorbent article, it is preferable to select hydrophilic fibers. Cellulose fibers such as pulp, rayon, cotton, and regenerated cellulose, and fibers such as polyamide and polyvinyl alcohol are selected as hydrophilic fibers. Use of such a hydrophilic fiber can enhance water conductivity to the composition. In particular, for use in sanitary materials, it is preferable to select pulp among hydrophilic fibers from the viewpoint of low irritation to the skin and soft feel.
On the other hand, hydrophobic fibers can also be used as free fibers. For example, polyester, polyethylene, polypropylene, polystyrene, polyvinyl chloride, polyvinylidene chloride, polyacrylonitrile, polyurea, polyurethane, polyfluoroethylene, and polyvinylidene cyanide fibers can be selected. it can. By using these hydrophobic fibers, water permeability and water diffusibility in the composition can be improved.
Unlike the binding fiber, the affinity of the free fiber with the water-absorbent resin or the affinity with the water-absorbent resin composite is not particularly limited.

The kind of the fiber used as the free fiber may be the same as or different from the binding fiber contained in the above-mentioned composite A, composite B or composite C. For example, a hydrophilic fiber can be selected as the binding fiber, and a hydrophobic fiber can be selected as the free fiber. By adopting such an embodiment, the hydrophobic fiber exhibits a function of improving the diffusivity of water between the water-absorbent resin composites. From the viewpoint of preventing blocking, it is also important to select fibers in consideration of the rigidity and diameter of the fibers described below.
Preferred free fibers for use in the composition of the present invention are those having a fiber length of 50 to 100,000 μm. More preferably, it is 100 to 50,000 μm, and further preferably, it is 500 to 20,000 μm. If the fiber length is too long, it may be difficult to open the composition. Conversely, if the fiber length is too short, the mobility of the fiber itself is large, and thus a problem such as leakage of the fiber from the composition may occur.

  Free fibers used in the composition of the present invention are preferably fibers having a fiber diameter of 0.1 to 500 dtex, more preferably 0.1 to 100 dtex, even more preferably 1 to 50 dtex, and particularly preferably. Is 1 to 10 dtex. If the fiber diameter is too large, not only is the rigidity of the fiber too large, it becomes difficult to mix with the water-absorbent resin composite, but also the compression molding becomes difficult, which may not be preferable for thinning. In addition, for applications such as sanitary products, the skin feels unpleasant and unpleasant. Conversely, if the fiber diameter is too small, the above-mentioned water conductivity and diffusibility may not be ensured because the fibers are too thin. In addition, since the rigidity is insufficient, the blocking phenomenon may not be prevented.

  The dry weight ratio between the free fiber and the water-absorbent resin is usually from 95: 5 to 0: 100, preferably from 95: 5 to 5:95. If the ratio of the free fibers is too high, the effect of the water-absorbing resin may not be substantially exerted, and the bulk density may be reduced. The free fiber in the composition of the present invention is usually 90% by weight or less.

III. Manufacturing method
IIIA. Production method raw material of composite A 1) Monomer (kind)
The type of the polymerizable monomer used for preparing the water-absorbent resin particles of the composite A is not particularly limited as long as it gives the water-absorbent resin. It is particularly preferable to use a polymerizable monomer whose polymerization is initiated by a redox initiator. Usually, this monomer is preferably water-soluble.

  Representative of such monomers, and also preferred for use in the present invention, are aliphatically unsaturated carboxylic acids or salts thereof. Specific examples include unsaturated monocarboxylic acids or salts thereof such as acrylic acid or salts thereof, methacrylic acid or salts thereof; and unsaturated dicarboxylic acids or salts thereof such as maleic acid or salts thereof, itaconic acid or salts thereof. These may be used alone or in combination of two or more. Among them, preferred are acrylic acid or a salt thereof, and methacrylic acid or a salt thereof, and particularly preferred is acrylic acid or a salt thereof.

  As the polymerizable monomer that gives the water-absorbing resin used in the present invention, an aliphatic unsaturated carboxylic acid or a salt thereof is preferable as described above. Therefore, as the aqueous solution of the polymerizable monomer, an aliphatic unsaturated carboxylic acid or a salt thereof is mainly used. An aqueous solution as a component is preferred. Here, "mainly composed of an aliphatic unsaturated carboxylic acid or a salt thereof" means that the aliphatic unsaturated carboxylic acid or a salt thereof is 50 mol% or more, preferably 80 mol%, based on the total amount of the polymerizable monomer. This means that it is included.

As the salt of the aliphatic unsaturated carboxylic acid, a water-soluble salt, for example, an alkali metal salt, an alkaline earth metal salt, an ammonium salt and the like are usually used. The degree of neutralization is appropriately determined according to the purpose. In the case of acrylic acid, it is preferable that 20 to 90 mol% of the carboxyl groups is neutralized with an alkali metal salt or an ammonium salt. If the degree of partial neutralization of the acrylic acid monomer is too low, the water-absorbing ability of the resulting water-absorbing resin tends to be significantly reduced.
For neutralization of the acrylic acid monomer, an alkali metal hydroxide, bicarbonate or the like, or ammonium hydroxide can be used. Preferred is an alkali metal hydroxide, and specific examples thereof include hydroxides. Sodium and potassium hydroxide.

In the present invention, in addition to the above-mentioned aliphatic unsaturated carboxylic acids, polymerizable monomers copolymerizable therewith, for example, (meth) acrylamide, (poly) ethylene glycol (meth) acrylate, 2-hydroxyethyl ( Although it is a meth) acrylate or a low water-soluble monomer, alkyl acrylates such as methyl acrylate and ethyl acrylate may be copolymerized in an amount within a range that does not decrease the performance of the resulting water absorbent resin. Absent. In this specification, the term “(meth) acryl” shall mean both “acryl” and “methacryl”.
Among these polymerizable monomers, those that give a water-absorbing resin are not used as auxiliary components for aliphatic unsaturated carboxylic acids or salts thereof, but are used as main monomers of "aqueous solution of a polymerizable monomer giving a water-absorbing resin". You can also.

(Monomer concentration)
The concentration of the polymerizable monomer in the aqueous polymerizable monomer solution containing the above-mentioned aliphatic unsaturated carboxylic acid or a salt thereof as a main component is preferably 20% by weight or more, more preferably 25% by weight or more. If the concentration is less than 20% by weight, the water-absorbing resin after polymerization may not have sufficient water-absorbing ability. The upper limit is preferably about 80% by weight from the viewpoint of handling of the polymerization reaction solution.

2) Crosslinking agent Aliphatic unsaturated carboxylic acid or a salt thereof, particularly acrylic acid or a salt thereof may form a self-crosslinking polymer by itself, but a crosslinking agent is used in combination to positively form a crosslinked structure. You can also. When a cross-linking agent is used in combination, the water-absorbing performance of the generally formed water-absorbing resin is improved. As the crosslinking agent, a polyvalent vinyl compound copolymerizable with the polymerizable monomer, for example, N, N′-methylenebis (meth) acrylamide, (poly) ethylene glycol poly (meth) acrylates, or the like, and a reaction with a carboxylic acid A water-soluble compound having two or more functional groups, for example, a polyglycidyl ether such as ethylene glycol diglycidyl ether and polyethylene glycol diglycidyl ether is preferably used. Among them, particularly preferred is N, N'-methylenebis (meth) acrylamide. The amount of the crosslinking agent used is 0.001 to 1% by weight, preferably 0.01 to 0.5% by weight, based on the charged amount of the monomer.

3) Polymerization initiator As the polymerization initiator used in the present invention, those used in aqueous solution radical polymerization can be used. Examples of such a polymerization initiator include inorganic and organic peroxides, such as ammonium and alkali metals, particularly persulfates such as potassium, hydrogen peroxide, t-butyl peroxide and acetyl peroxide. .
Further, a polymerization initiator known as an azo compound can also be used. For example, 2,2′-azobis (2-amidinopropane) dihydrochloride, which shows water solubility to some extent, may be mentioned.
The polymerization is initiated by the decomposition of the radical polymerization initiator. A commonly known technique is pyrolysis. Often, polymerization is initiated by adding an unheated polymerization initiator to the monomer of the reaction solution that has been heated to the decomposition temperature of the polymerization initiator in advance. Belongs to.

Preferred as the polymerization initiator used in the present invention is a combination of an oxidizing agent and a reducing agent, which forms a redox system to some extent water-soluble.
Examples of the oxidizing agent include hydrogen peroxide, persulfates such as ammonium persulfate and potassium persulfate, t-butyl hydroperoxide, cumene hydroperoxide and the like, ceric salts, permanganates, chlorites, Hypochlorite and the like. Of these, hydrogen peroxide is particularly preferred. The amount of the oxidizing agent to be used is 0.01 to 10% by weight, preferably 0.1 to 2% by weight, based on the polymerizable monomer.
The reducing agent is capable of forming a redox system with the oxidizing agent. Specifically, sodium sulfite, a sulfite such as sodium hydrogen sulfite, sodium thiosulfate, cobalt acetate, copper sulfate, ferrous sulfate, L- Ascorbic acid or alkali metal salts of L-ascorbic acid can be mentioned. Above all, L-ascorbic acid or L-ascorbic acid alkali metal salt is particularly preferred. The amount of these reducing agents to be used is 0.001 to 10% by weight, preferably 0.01 to 2% by weight, based on the polymerizable monomer.

4) Fiber The fiber type and shape are appropriately selected as described above.
It is preferred that the fibers are evenly dispersed as microscopically as possible. Generally, the fibers tend to form a fiber mass due to entanglement, but the apparent fiber mass diameter is preferably 20 mm or less, more preferably 10 mm or less, and most preferably 5 mm or less. Of course, it is needless to say that the fibers are preferably independent of one fiber. Generally, a technique called fiber opening is used to ensure uniformity. In addition, "opening" includes both concepts of defibration and fiberization. The defibration includes tearing a sheet-like material such as nylon into a strip shape or a fiber shape. In addition, fibrillation includes severing base paper-like cellulose into pulp.

  As a specific method, there is a cotton spinning type, a worsted type, a woolen type, a hemp spinning type, a silk spinning type or a method described in “Textile Handbook (Processing Edition)” (edited by the Society of Textile Engineers, Maruzen, 1969), p. A rotary blade type pulverizer, a hammer type pulverizer, a pulp defibrator and the like can be appropriately used. Further, as is known as flocking, it is also possible to charge the fibers and to utilize the electrostatic repulsion between the fibers to effectively separate the fibers individually and uniformly disperse them.

2. Production Step The production method of the present invention comprises, in a gas phase, a droplet containing a polymerizable monomer and a solvent before and / or during polymerization and a first fiber supplied from a first supply port of a reactor. A step of bringing into contact (first step), a step of promoting the polymerization of the polymerizable monomer (second step), and then a droplet containing the polymerizable monomer, solvent and fiber during polymerization is supplied from the second supply port of the reactor. The step of bringing the second fiber into contact with the supplied second fiber in the gas phase (third step) and the step of further proceeding the polymerization of the polymerizable monomer (fourth step) are sequentially performed. The production method of the present invention may include steps other than these four steps.

1) First Step In the first step, a specific mode is not particularly limited as long as one or more fibers can be brought into contact with a droplet containing a polymerizable monomer in a gas phase.

The polymerizable monomer contained in the droplet must be before or during polymerization at the time of contact with the first fiber in the first step. The monomer conversion at the time of contact with the fiber is preferably in the range of 0 to 80%. It is more preferably in the range of 0 to 70%, and most preferably in the range of 0 to 60%. If the conversion is too high, the fibers to be contacted may not be embedded or adhered to the water absorbent resin. More preferably, upon contact with the first fiber, the polymerizable monomer is undergoing polymerization.
The droplets may contain a crosslinking agent, a polymerization initiator, and the like. The amounts of the crosslinking agent and the polymerization initiator added to the polymerizable monomer are as described above.

  The method for forming the droplet is not particularly limited. As a preferred droplet forming method, an aqueous solution of a polymerizable monomer that gives a water-absorbing polymer, for example, an aqueous solution of a polymerizable monomer containing an aliphatic unsaturated carboxylic acid or a salt thereof as a main component is provided with a redox-based polymerization initiator, and An example is a method in which polymerization of a monomer is started, and a reaction mixture undergoing polymerization containing the monomer and the produced polymer after the start of the reaction is formed into droplets in a gas phase. Further, as another more preferable droplet forming method, a first liquid comprising an aqueous polymerizable monomer solution containing one of an oxidizing agent and a reducing agent constituting a redox polymerization initiator and the other of the redox polymerization initiator and, if desired, polymerization. A method of forming droplets by mixing a second liquid composed of an aqueous solution containing a hydrophilic monomer in a gas phase can be used.

  In the latter method, for example, the first liquid and the second liquid are ejected from separate nozzles so that the liquids flowing out of the nozzles cross each other at an angle of 15 degrees or more and collide in a liquid column state. Can be implemented. In this way, by making the two liquids have an intersection angle and collide with each other, a part of the outflow energy from the nozzle is used for mixing. The intersection angle between the first liquid and the second liquid flowing out of each nozzle is appropriately selected according to the properties of the polymerizable monomer used, the flow ratio, and the like. For example, if the linear velocity of the liquid is high, the intersection angle can be reduced.

In this case, the temperature of the first liquid is usually from room temperature to about 60 ° C., preferably from room temperature to about 40 ° C., and the temperature of the second liquid is also from room temperature to about 60 ° C., preferably from room temperature to about 40 ° C. ° C.
As described above, the respective aqueous solutions ejected from the nozzles collide in a liquid column state to combine the two liquids. After the merging, a liquid column is formed, and this state is maintained for a certain period of time. Thereafter, the liquid column is disassembled into a droplet. The polymerization of the generated droplets proceeds in the gas phase.

In order for the polymerization of the droplets to proceed and to form an appropriate water-absorbent resin composite upon contact with the fiber, the size of the droplets is particularly preferably in the range of 50 to 1,000 μm. Spatial density of the droplets in the reactor is preferably 0.1~10,000g / m ^3. If this upper limit is exceeded, a water-absorbent resin that does not come into contact with the fiber will be generated. .

  As a gaseous phase gas that provides a reaction field for initiating such polymerization and forming droplets during the progress of polymerization, nitrogen, helium, carbon dioxide, or the like that is inert to the polymerization is preferable, but air may also be used. In addition, there is no particular limitation on the humidity in the gas including the case where only water vapor is used.However, if the humidity is too low, the water in the monomer aqueous solution evaporates before the polymerization proceeds, and the monomer is precipitated. The rate may decrease significantly or the polymerization may stop prematurely. The temperature condition of the gas is not lower than room temperature and not higher than 150 ° C, preferably not higher than 100 ° C. The flow direction of the gas may be either countercurrent or cocurrent with respect to the direction of travel of the liquid column and the droplet.However, when the residence time of the droplet in the gas phase needs to be extended, that is, the polymerization rate of the polymerizable monomer is increased. If it is necessary to increase the viscosity of the liquid droplets, countercurrent (anti-gravity direction) is better.

The formed droplet contacts the first fiber in the first step. The number of times of contact with the first fiber is not particularly limited. Preferred is when the droplet contacts a plurality of fibers.
The first fiber is supplied from a first supply port of the reactor. The cross-sectional shape of the first supply port may be any shape such as a circle, an ellipse, and a rectangle, and may have a U-shaped cross section that is open at the top. Further, a supply port provided with an opening so as to go around the inner wall of the reaction vessel may be used. In this case, it is preferable that the opening part around the inner wall is provided at the same height (level) of the reaction vessel. The number of the first supply ports may be one or plural. For example, a plurality of supply ports having a circular cross section may be provided so as to go around the inner wall of the reactor at equal intervals.
It is preferable that a guide path for supplying the first fiber to an appropriate position in the reactor is provided before and / or after the first supply port.

As a method for supplying the fibers for contacting the droplets during the polymerization, a generally known transport method can be used. The space density of the fibers in the reactor is preferably in the range of 0.005 to 1,000 g / m ³ when the fibers are partially embedded in the water absorbent resin. If the upper limit is exceeded, fibers that are not embedded in the water-absorbent resin composite are generated, and if the lower limit or less is used, a water-absorbent resin that does not embed the fibers is generated, and the yield of the water-absorbent resin composite is relatively reduced. Problems arise. In order to supply the fibers as finely and uniformly as possible, it is preferable to supply the fibers as a multiphase flow with the gas. As the gas used here, those listed as the gaseous phase gas that provides the above-described reaction field can be used. Among them, air is preferable from the viewpoint of economy and reduction of environmental load.

The weight mixing ratio of the fiber and the gas supplied as a multiphase flow is preferably 1: 1 or less, and the linear velocity of the gas is preferably in the range of 1 to 50 m / sec. If the linear velocity of the gas exceeds 50 m / sec, the trajectory of the reaction mixture during polymerization in the reaction field may be disturbed, and adhesion to the inner surface of the reactor may become a problem. On the other hand, if it is less than the lower limit, the uniformity of the fiber may not be secured.
It is desired that the temperature of the gas supplied as a multiphase flow be selected within a range that does not significantly inhibit polymerization. In that sense, it is specifically room temperature or higher and 150 ° C or lower, preferably 100 ° C or lower. From the viewpoint of fiber transport, it is preferable that the humidity in the gas is low.However, if the humidity is too low, the humidity in the reactor is reduced, and the water in the monomer aqueous solution evaporates before the polymerization proceeds, and the monomer precipitates. As a result, there is a possibility that the polymerization rate is remarkably reduced or the polymerization is stopped halfway.

2) Second Step The second step is a step in which the polymerization of the polymerizable monomer contained in the droplet contacted with the first fiber in the first step proceeds. The second step is to increase the conversion rate of the polymerizable monomer when contacting the second fiber in the third step, as compared with the conversion rate of the polymerizable monomer when contacting the first fiber in the first step. What to do.
When a redox-based polymerization initiator is used as the polymerization initiator, the polymerization rate of the polymerizable monomer in the droplet is extremely high. For this reason, if there is a short period of time between the contact of the droplet with the first fiber and the contact with the second fiber, the polymerization of the polymerizable monomer proceeds. When the droplets come into contact with the first fiber and the second fiber one after another while falling, the polymerization of the polymerizable monomer occurs during the fall until the droplet comes into contact with the first fiber after contact with the first fiber. proceed.
When the polymerization rate of the polymerizable monomer in the droplet is low, means for accelerating the polymerization reaction may be provided. For example, the polymerization reaction may be promoted by applying heat to the droplets by a method such as passing through a heating zone.

  The second step is preferably performed such that the conversion of the polymerizable monomer is increased by 10% to 80%. It is more preferably in the range of 10 to 70%, and most preferably in the range of 10 to 60%. The conversion in each contact field is appropriately determined according to the type of monomer, type of fiber, and the like.

3) Third Step The third step is a step of bringing a droplet containing a polymerizable monomer, a solvent, and a fiber being polymerized into contact with a second fiber supplied from a second supply port of the reactor in a gas phase. is there. The conversion of the polymerizable monomer when coming into contact with the second fiber in the third step is preferably 10% to 90%, more preferably 10% to 80%, and more preferably 10% to 70%. Is more preferable.
In the first step, the polymerizable monomer contacts the first fiber at a stage where the conversion is relatively low. For this reason, as the polymerizable monomer gradually changes to a polymerizable polymer as the polymerization proceeds thereafter, the first fibers are embedded by the polymerizable polymer. In the water-absorbent resin composite finally obtained, the first fiber is a fiber partially embedded in the resin particles and partially exposed from the resin particles.
On the other hand, in the third step, the polymerizable monomer comes into contact with the second fiber at a stage where the conversion is relatively high. For this reason, even if the subsequent polymerization proceeds, the second fibers are not embedded in the polymerizable polymer, but only adhere to the surface of the polymerizable polymer. Therefore, in the water-absorbent resin composite finally obtained, the second fibers are fibers that are partially embedded in the surface of the resin particles without being embedded in the resin particles.

The second fiber supplied in the third step may be the same fiber as the first fiber or a different fiber. Further, fibers of the same material but different in fiber diameter and fiber length may be used. In addition, the details of the second supply port for supplying the second fiber can be freely designed similarly to the first supply port. Further, the method and means for supplying the second fiber from the second supply port can be freely selected in the same manner as the method and means for supplying the first fiber from the first supply port.
It is preferable to use a reactor in which the first supply port is installed at a higher position than the second supply port. A first fiber is supplied from a first supply port to a high position in the reactor, a second fiber is supplied from a second supply port to a low position in the reactor, and droplets containing a polymerizable monomer are supplied from above. By dropping, the present invention can be implemented efficiently.
However, the first supply port and the second supply port are installed at the same height, the first supply port supplies the first fiber upward, and the second supply port supplies the first fiber. It is also possible to carry out the present invention by feeding the two fibers downward. All such variations can be adopted as long as the production method of the present invention can be implemented.

4) Fourth Step The fourth step is a step in which the polymerization of the polymerizable monomer contained in the droplet that has come into contact with the second fiber in the third step proceeds. By allowing the polymerization to proceed in the fourth step, the water-absorbent resin composite of the present invention comprising the water-absorbent resin particles and fibers can be finally formed. In the fourth step, a means for accelerating the polymerization may be applied as in the second step.

  In the fourth step, the polymerization need not be completed while the droplets are in the gas phase. That is, the present invention includes a mode in which the polymerization is not completed while the droplet is falling in the reactor, and the polymerization proceeds even after the drop. However, care should be taken so that the water-absorbent resin composite of the present invention having a characteristic structure does not impair the characteristic structure depending on the conditions after falling. Usually, it can be deposited as it is and collected as a deposit. At this time, it is preferable to install a mesh at the bottom of the reactor where the water-absorbent resin composite is deposited, and to suction air from under the mesh. At this time, the pressure difference between the upper and lower portions of the mesh is preferably 100 to 10,000 Pa. Further, it is more preferable that the mesh is formed in a belt shape so that the water-absorbent resin composites that are successively deposited can be continuously extracted from the reactor. That is, the droplets and fibers are continuously supplied to the reactor, and the deposits of the manufactured water-absorbent resin composite are continuously extracted, whereby the deposits can be efficiently obtained.

  In order to obtain more structures of the composite B, it is preferable to supply the fibers at a stage where the polymerization rate is relatively low (for example, in the range of 0 to 60%), and to obtain more structures of the composite C. It is preferable to supply the fibers at a stage where the polymerization rate is relatively high (for example, in the range of 30 to 90%).

  Since the water-absorbent resin composites are independent of each other in the sediment, they can be easily opened. For the fiber opening, the fiber opening method described in the description of the fiber can be used as appropriate, but an apparatus and conditions under which the water-absorbent resin is not damaged by mechanical impact are preferable.

5) Other additional steps In the production method of the present invention, additional steps may be performed in addition to the above four steps. For example, as an additional step, a residual monomer treatment step, a surface cross-linking step, and an additive addition step such as a catalyst, a reducing agent, a deodorant, a human urine stabilizer, and an antibacterial agent for imparting other functions may be added. .
(Residual monomer treatment step)
Examples of the method for treating the residual monomer include 1) a method for promoting the polymerization of the monomer, 2) a method for introducing the monomer to another derivative, and 3) a method for removing the monomer.

Examples of the method of promoting the polymerization of the monomer 1) include a method of further heating the composite of the water-absorbent resin and the fiber, and a method of adding a catalyst or a catalyst component for promoting the polymerization of the monomer to the water-absorbent resin and then heating the resultant. And a method of irradiating ultraviolet rays, and a method of irradiating electromagnetic radiation or particulate ionizing radiation.
In the method of further heating the water-absorbent resin composite, the water-absorbent resin composite is heated at 100 to 250 ° C. to polymerize the monomers remaining in the water-absorbent resin composite.

  In a method of adding a catalyst or a catalyst component for promoting polymerization of a monomer to a water-absorbent resin composite, for example, when polymerization is performed using a redox polymerization initiator, a radical generator often remains. Therefore, a reducing agent solution may be applied to the water absorbent resin. As the reducing agent, sodium sulfite, sodium bisulfite, L-ascorbic acid, or the like used as a redox polymerization initiator may be used, and these are usually applied to the water-absorbent resin composite as a 0.5 to 5% by weight aqueous solution. I do. The amount of the reducing agent applied is preferably 0.1 to 2% by weight based on the dry resin. The application of the reducing agent solution can be performed by an arbitrary method such as spraying using a sprayer or dipping in the reducing agent solution. The water-absorbent resin composite provided with the reducing agent is then heated to polymerize the monomer. Heating may be performed, for example, at 100 to 150 ° C. for about 10 to 30 minutes. This heating lowers the water content of the water-absorbent resin composite, but if the water content is high, it is further dried by a dryer to obtain a water-absorbing material for the product.

  In the method of irradiating the water-absorbent resin composite with ultraviolet light, a normal ultraviolet lamp may be used. Irradiation intensity, irradiation time, and the like vary depending on the type of fiber used, the amount of residual monomer impregnated, and the like. The lamp is 10 to 200 W / cm, preferably 30 to 120 W / cm, the irradiation time is 0.1 second to 30 minutes, and the distance between the lamp and the complex is 2 to 30 cm. The amount of water in the water-absorbent resin composite at this time is generally 0.01 to 40 parts by weight, preferably 0.1 to 1.0 part by weight per 1 part by weight of the polymer. Is done. A water content of less than 0.01 parts by weight or more than 40 parts by weight is not preferred because it has a significant effect on the reduction of residual monomers. As an atmosphere for irradiating ultraviolet rays, any of a vacuum, in the presence of an inorganic gas such as nitrogen, argon, and helium, or in air can be used. The irradiation temperature is not particularly limited, and the object can be sufficiently achieved at room temperature. There is no particular limitation on the ultraviolet irradiation apparatus to be used, and any method such as a method of irradiating for a fixed time in a stationary state or a method of continuously irradiating with a belt conveyor can be used.

  As a method for irradiating the water-absorbent resin composite with radiation, high-energy radiation such as accelerated electrons or gamma rays is used. The dose to be irradiated varies depending on the amount of residual monomers in the composite, the amount of water, and the like, but is generally 0.01 to 100 Mrad, preferably 0.1 to 50 Mrad. If the dose exceeds 100 megarads, the water absorption becomes extremely small. If the dose is less than 0.01 megarads, the water absorption capacity and water absorption rate aimed at in the present invention are large, and it is difficult to obtain those having particularly small residual monomers. The water content of the water-absorbent resin composite at this time is generally 40 parts by weight or less, preferably 10 parts by weight or less, per 1 part by weight of the polymer. If the amount of water exceeds 40 parts by weight, the effect of improving the water absorption rate is small, and it is not preferable because the effect of reducing the amount of unpolymerized monomer is particularly significant. As an atmosphere for irradiating the composite with high-energy radiation, any of under vacuum, in the presence of an inorganic gas such as nitrogen, argon, and helium, or in air can be used. The preferred atmosphere is air. Irradiation in air will increase the water absorption capacity and water absorption rate and reduce the residual monomer in particular. The irradiation temperature is not particularly limited, and the object can be sufficiently achieved at room temperature.

  Examples of the method of introducing the monomer into the other derivative of 2) include a method of adding an amine, ammonia, and the like, and a method of adding a reducing agent such as a bisulfite, a sulfite, and a pyrosulfite.

  As a method of removing the monomer in 3), for example, a method of extracting and distilling off with an organic solvent can be mentioned. In the method of extracting with an organic solvent, the water-absorbent resin composite is immersed in a water-containing organic solvent to extract and remove the remaining monomer. As the water-containing organic solvent, ethanol, methanol, acetone or the like can be used, and its water content is preferably from 10 to 99% by weight, particularly preferably from 30 to 60% by weight. In general, the higher the water content, the higher the ability to remove residual monomers. However, when a water-containing organic solvent having a high water content is used, energy consumption in the subsequent drying step increases. The time for immersing the complex in the aqueous organic solvent is usually about 5 to 30 minutes, and it is also preferable to employ a means for promoting the extraction of the residual monomer, such as rocking the complex. After the immersion treatment, it is usually treated by a dryer and dried.

  As a method for distilling off the monomer, there is a method of treating the complex with superheated steam or a steam-containing gas. For example, the residual monomer in the water-absorbent resin can be reduced by heating the saturated steam at 110 ° C to 120 to 150 ° C and bringing it into contact with the composite as superheated steam. In this method, it is considered that when water in the water-absorbent resin evaporates as water vapor, the residual monomer is also vaporized and escapes from the water-absorbent resin. According to this method, both the removal of the residual monomer and the drying of the product can be performed.

(Surface crosslinking process)
In addition, the surface of the water-absorbent resin can be cross-linked with a cross-linking agent for the purpose of improving the water-absorbing performance. In general, it is known to improve the properties of resin particles by imparting an appropriate amount of moisture together with a crosslinking agent to the surface of the powdery water-absorbing polymer particles and then heating and crosslinking the surface to selectively improve the properties of the resin particles. It is considered that as a result of the formation of the crosslinked structure, when swelling by absorbing water, the shape can be maintained without inhibiting swelling. In this step, first, a solution of the surface crosslinking agent is applied to the water-absorbent resin composite. Examples of the surface cross-linking agent include polyfunctional compounds copolymerizable with polymerizable monomers such as N, N'-methylenebis (meth) acrylamide and (poly) ethylene glycol bis (meth) acrylate, and (poly) ethylene glycol diglycidyl ether. A compound having a plurality of functional groups capable of reacting with the carboxylic acid group is used. These surface cross-linking agents are generally used in an amount of 0.1 to 1% by weight, preferably 0.2 to 0.5% by weight, based on the water-absorbent resin composite. These surface cross-linking agents are diluted with water, ethanol, methanol, or the like, so that the surface cross-linking agent is uniformly applied to the entire water-absorbent resin composite. It is preferably used as a solution by weight. It is generally preferable to apply the crosslinking agent solution by spraying the crosslinking agent solution onto the water-absorbent resin composite using a sprayer, or by applying the crosslinking agent solution with a roll brush. After excessively applying the cross-linking agent solution, the surplus cross-linking agent solution may be removed by squeezing the resin particles lightly with a squeezing roll so that the resin particles are not crushed or by blowing air. The application of the crosslinking agent solution may be performed at room temperature. The water-absorbent resin composite provided with the cross-linking agent solution is then heated to cause a cross-linking reaction to proceed, thereby selectively forming a cross-linked structure on the surface of the water-absorbent resin. The conditions of the cross-linking reaction may be appropriately selected depending on the cross-linking agent to be used. In the present invention, a crosslinked unsaturated carboxylic acid polymer or a crosslinked partially neutralized acrylic acid polymer can be preferably used as the water-absorbing resin.

(Additive addition step)
Various additives can be added to the water-absorbent resin composite or the water-absorbent resin composite composition in order to impart a desired function according to the intended use. Examples of these additives include stabilizers for preventing polymer decomposition and deterioration due to the liquid to be absorbed, antibacterial agents, deodorants, deodorants, fragrances, and foaming agents.

Stabilizer)
Among these, as stabilizers for preventing polymer decomposition and deterioration due to the liquid to be absorbed, decomposition and deterioration of the water-absorbing resin due to excretion (that is, human urine, feces) and body fluid (body fluid such as human blood, menstrual blood, secretion fluid) are included. Stabilizing agents to prevent. JP-A-63-118375 discloses a method of incorporating an oxygen-containing reducing inorganic salt and / or an organic antioxidant in a polymer, and JP-A-63-153060 discloses a method of containing an oxidizing agent. JP-A-63-127754 discloses a method of containing an antioxidant, JP-A-63-272349 discloses a method of containing a sulfur-containing reducing agent, and JP-A-63-146964 discloses a method of containing a metal chelating agent. JP-A-63-15266 discloses a method containing a radical chain inhibitor, JP-A-1-275661 discloses a method containing a phosphinic acid group or phosphonic acid group-containing amine compound or a salt thereof. Japanese Patent Application Laid-Open No. 64-29257 discloses a method for containing a polyvalent metal oxide, and Japanese Patent Application Laid-Open Nos. 2-255804 and 3-179008 disclose a method. How coexist case when a water-soluble chain transfer agent and the like have been proposed. All of these can be used in the present invention. Also, JP-A-6-306202, JP-A-7-53884, JP-A-7-62252, JP-A-7-113048, JP-A-7-145326, JP-A-7-145263, The materials and methods described in JP-A-7-228788 and JP-A-7-228790 can also be used. Specific examples include potassium oxalate titanate, tannic acid, titanium oxide, amine phosphinate (or a salt thereof), amine phosphonate (or a salt thereof), and metal chelates. Of these, stabilizers for human urine, human blood, and menstrual blood may be called human urine stabilizers, human blood stabilizers, and menstrual blood stabilizers, respectively.

Antibacterial agent)
Antimicrobial agents are used to prevent spoilage due to the absorbed liquid. Examples of antibacterial agents include "New Development of Sterilization and Antibacterial Technology", pp. 17-80 (Toray Research Center (1994)), "Testing and Evaluation Methods and Product Design of Antibacterial and Antifungal Agents", pp. 128-344 (NTT) S (1997)), Japanese Patent No. 2760814, JP-A-39-179114, JP-A-56-31425, JP-A-57-25813, JP-A-59-189854, JP-A-59-105448, JP-A-60-158861, JP-A-61-181532, JP-A-63-135501, JP-A-63-139556, JP-A-63-156540 JP-A-64-5546, JP-A-64-5547, JP-A-1-153748, JP-A-1-221242, JP-A-2-253 No. 47, JP-A-3-59075, JP-A-3-103254, JP-A-3-221141, JP-A-4-11948, JP-A-4-92664, JP-A-4-138165 JP, JP-A-4-266947, JP-A-5-9344, JP-A-5-68694, JP-A-5-161671, JP-A-5-17953, JP-A-5-269164, Those introduced in Japanese Patent Application Laid-Open No. 7-165981 can be appropriately selected.

  Examples thereof include alkylpyridinium salts, benzalkonium chloride, chlorhexidine gluconate, zinc pyridione, and silver-based inorganic powder. Representative examples of quaternary nitrogen-based antibacterial agents include methylbenzethonium chloride, benzalkonium chloride, dodecyltrimethylammonium bromide, tetradecyltrimethylammonium bromide and hexadecyltrimethylammonium bromide. Examples of the heterocyclic quaternary nitrogen-based antibacterial agents include dodecylpyridinium chloride, tetradecylpyridinium chloride, cetylpyridinium chloride (CPC), tetradecyl-4-ethylpyridinium chloride, and tetradecyl-4-methylpyridinium chloride.

  Other preferred antimicrobial agents include bis-biguanides. These are described, for example, in U.S. Pat. Nos. 2,684,924, 2,990,425, 2,830,006 and 2,863,019. It is described in. The most preferred bis-biguanide is 1,6-bis (4-chlorophenyl) diguanidehexane, which is known as chlorohexidine and its water-soluble salts. Particularly preferred are the hydrochloride, acetate and gluconate salts of chlorohexidine.

  Some other types of antimicrobial agents are also useful. For example, carbanilides, substituted phenols, metal compounds, and rare earth salts of surfactants can be exemplified. Carbanilides include 3,4,4'-trichlorocarbanilide (TCC, triclocarban) and 3- (trifluoromethyl-4,4'-dichlorocarbanilide (IRGASAN). Mention may be made of 5-chloro-2- (2,4-dichlorophenoxy) phenol (IRGASAN DP-300) Metal compounds include salts of graphite and tin, such as zinc chloride, zinc sulfide and tin chloride. Rare earth salts of surfactants are disclosed in European Patent Publication No. 10819. Examples of this type of rare earth salt include lanthanum salts of linear C10-18 alkylbenzene sulfonates.

Deodorant, deodorant, fragrance)
Further, deodorants, deodorants, and fragrances are used to prevent or reduce the unpleasant odor of the absorbed liquid. Deodorants, deodorants, and fragrances are described in, for example, "New Deodorants and Deodorants, Techniques and Prospects" (Toray Research Center (1994)), JP-A-59-105448, JP-A-60-158861, JP-A-61-181532, JP-A-1-153748, JP-A-1-221242, JP-A-1-265959, JP-A-2-41155, JP-A-2-253847, Those introduced in Japanese Unexamined Patent Publication Nos. 3-103254, 5-269164 and 5-277143 can be appropriately selected. Specifically, examples of the deodorant and the deodorant include iron complexes, tea extract components, and activated carbon. As the fragrance, for example, fragrance (citral, cinnamaldehyde, heliotopin, camphor, bornyl acetate) wood vinegar, paradichlorobenzene, surfactant, higher alcohol, terpene compound (limonene, pinene, camphor, borneol, eucalyptol, Eugenol).

Foaming agent, foaming aid)
In addition, a foaming agent and a foaming aid can be used in combination in order to increase the water absorption performance of the water-absorbent resin by making it porous and increasing the surface area. As the foaming agent and the foaming aid, for example, those introduced in “Rubber / Plastic Compounding Chemicals” (Rubber Digest, 1989, pp. 259-267) can be appropriately selected. For example, sodium bicarbonate, a nitroso compound, an azo compound, sulfonyl hydrazide and the like can be mentioned.
These additives are appropriately added in each step of the production of the water-absorbent resin composite according to the purpose and mechanism of action. For example, the foaming agent is suitably added before or during the polymerization step in the process of producing the water absorbent resin. Human urine stabilizer, human blood stabilizer, antibacterial agent, deodorant, and fragrance can be added in each step of the water-absorbent resin composite production process, the water-absorbent resin composite composition production process, and the water-absorbent article production process. is there. Of course, it is also possible to apply it to the fiber in advance.

IIIB. 1. Method for producing water-absorbent resin composite composition Raw Materials and Manufacturing Process In general, the composition of the present invention is prepared by mixing and dispersing a separately prepared complex B and / or complex C and / or free fiber with respect to the manufactured composite A as appropriate. The composition is prepared by a method of allowing the composition to be simultaneously obtained in the polymerization step of the complex A (simultaneous mixing method), or the like, and then, if necessary, adding a treatment such as consolidation.

1) Post-mixing method: for example, by mixing the above-deposited composite A or the above-described opened and independent composite A with the composite B and / or the composite C and / or the free fiber in a mixer. A water-absorbent resin composite composition mixed with the above composition can be produced. At this time, a solid mixing device capable of mixing powders, powder and fibers, or fibers can be used as a mixer. Specifically, for example, a cylindrical mixer, a V-type mixer, a double-cone-type mixer, a double cubic mixer, and a cube are described in detail in “Chemical Engineering II” (Yoshinori Oyama, Iwanami Zensho, 1963, 229). Examples thereof include a rotary mixer such as a mold mixer, a screw mixer, a ribbon mixer, a rotating disc mixer, and a fixed mixer such as a fluidized mixer.

2) Simultaneous mixing method The composition of the present invention can be substantially obtained by devising the supply position of the fiber. That is, when the droplets are brought into contact with the fiber at a low polymerization rate, a composite B-containing composition is obtained, and when the droplets are brought into contact with the droplets at a high polymerization rate, a composite C-containing composition is obtained.
Alternatively, the free fibers can also be obtained by supplying, mixing, and dispersing the fibers during the production of the water-absorbent resin composite in a manner that does not substantially come into contact with the water-absorbent resin during polymerization or the water-absorbent resin in the water-absorbent resin composite. The resulting composition is obtained.

3) Consolidation method Consolidation is performed while appropriately adjusting conditions such as pressure, temperature, and humidity. For example, a flat press, a roll press, and the like can be used as the press. The pressure may be within a range where the water-absorbing resin particles are not broken. When the water-absorbent resin particles are broken, the broken particle pieces are detached from the fibers and leak from the absorbent product as the final product, or the water-absorbing gel leaks or moves off the fibers when swelling, resulting in the absorption of the absorbent article. Performance will be degraded.
In the case of heating in the consolidation process, the heating can be performed at a temperature lower than the melting point of the fiber used. If heated above the melting point, the fibers will bind together to form a network, impairing the function of the composite.
When humidifying in the consolidation process, humidification is usually performed using steam. By the humidification conditions, the density of the composition can be improved, and the adhesion of the water-absorbent resin particles to the fibers can be improved.

2. Spreading of the water-absorbent resin composite composition The water-absorbent resin composite composition can be easily opened similarly to the aggregate of the composite A because the constituent components themselves are independent of each other. For the fiber opening, the fiber opening method described in the description of the fiber can be used as appropriate, but it is preferable to employ a device and conditions under which the water-absorbent resin is not damaged by mechanical shock.

IV. Measurement method and evaluation method Fiber 1) Contact angle of water (1) A solution having a concentration of 1 to 10% by weight was prepared using a solvent capable of dissolving or dispersing the used fiber.
(2) The solution was spread thinly on a petri dish, and the solvent was gently evaporated with dry air at room temperature to sufficiently dry, thereby obtaining a thinly developed film-like molded product.
(3) The contact angle of distilled water at 25 ° C. to the air surface of the film-shaped molded product was determined. The contact angle was measured using an automatic contact angle meter CA-V (manufactured by Kyowa Interface Science Co., Ltd.).

2) Spatial density The amount of fiber retained in the reaction field is calculated by assuming that the fiber moves from top to bottom along the flow of air supplied together as a multi-phase flow, and the amount of the retained fiber is calculated as the total reaction field. The spatial density of the fiber in the reaction field was calculated by dividing by the volume of the fiber.

2. Droplet 1) Droplet diameter It was calculated from the average particle diameter dp of the water-absorbent resin particles constituting the water-absorbent resin composite and the monomer concentration Cm according to the following formula, which was measured according to the method of 3.2) described later.
Drop diameter dd = dp / (Cm) ^1/3

2) Space density By assuming that the droplets fall in the reaction field with the downward velocity of discharge from the nozzle as the initial velocity, the amount of residence of the droplets in the reaction field is calculated. The spatial density of the droplet in the reaction field was calculated by dividing by the volume.

3) Polymerization rate (polymerization rate at contact position with fiber)
(1) A beaker containing about 150 g of methanol is placed so that the liquid level of methanol is located at the position where the fiber is introduced, and droplets of the reaction mixture that has started polymerization are formed in the gas phase. About 1 g of the polymerization-initiating droplet was allowed to fall into methanol.
(2) The amount of monomer in methanol was measured by liquid chromatography.
(3) After drying the polymer in methanol under reduced pressure at 130 ° C. for 3 hours, the weight was measured.
(4) The polymerization rate was calculated from the respective weights according to the following formula (Mp is the weight of the polymer, and Mm was the weight of the monomer).

Mp
Polymerization rate (%) = ――――――――― x 100
Mm + Mp

3. Water-absorbent resin composite 1) Confirmation of morphology of water-absorbent resin composite (1) By observing the water-absorbent resin composite at a magnification of 20 to 20,000 times with a scanning electron microscope, a part of the fiber is converted to the resin. The structure embedded in the inside and a part of the fiber was exposed from the resin, or the state of adhesion of the fiber to the resin surface was confirmed.
(2) Further, by cutting the cross section continuously by a precision cutting device such as a microtome and observing the cross section at a magnification of 20 to 20,000 times, a part of the fiber is embedded in the resin, The structure in which a part of the fiber was exposed from the resin or the state of adhesion of the fiber to the resin surface was confirmed.

2) Average particle size of water-absorbent resin particles An optical microscope photograph of the water-absorbent resin composite was taken, and 100 water-absorbent resin particles constituting the composite (the water-absorbent resin particles measured in the present specification were: Each of them was substantially spherical), their diameters were measured, and the average value based on the number was defined as the average particle size.

3) A dry weight ratio of about 1 g of the water absorbent resin composite of each absorbent resin composite was classified into a composite A, a composite B and a composite C using an optical microscope. The weight of each composite was measured with a precision balance to obtain the dry weight ratio of each water-absorbing composite.

4) Dry weight ratio of binding fibers and water-absorbent resin constituting each composite 3) Water absorption in the composites for each absorbent resin composite classified by measuring the dry weight ratio of each water-absorbent resin composite The fiber was isolated by using an agent capable of selectively decomposing the reactive resin, and the weight was determined by weighing the fiber.
Specifically, for example, regarding the water-absorbent resin composite A,
(1) The weight of the water-absorbent resin composite A obtained in 3) was defined as Wc. This water-absorbent resin composite A was charged into a 50-ml closed glass container, and an aqueous solution in which 0.03 g of L-ascorbic acid was dissolved in 25 g of distilled water was added to swell, followed by holding at 40 ° C. for 24 hours.
(2) Then, the content of the glass container was filtered off with suction using an aspirator having an ultimate vacuum of 10 to 25 mmHg with a filter paper having a constant weight, which was dried under reduced pressure at 80 ° C. for 3 hours, and the fibers on the filter paper were thoroughly washed with water. After drying at 5 ° C. for 5 hours, the sample was precisely weighed, and the value was defined as Wf.
(3) The dry weight ratio of the binding fiber constituting the water-absorbent resin composite A to the water-absorbent resin was obtained by the following formula.
Wf
Dry weight ratio of binding fiber to water absorbent resin = ――――――――
Wc-Wf

5) Spreadability (1) About 5 g of the water-absorbent resin composite was sandwiched between a pair of hand carders (22 cm × 12.5 cm) manufactured by Ashford and worsted manually five times.
(2) Ease of worsting and the state of breakage of the water-absorbent resin particles after worsting were evaluated in the following three grades.
：: Worssing is easy and the water-absorbing resin particles after worsting are hardly damaged.
Δ: Worsting is felt, and when the worsting is performed, the water-absorbing resin particles after the worsting are damaged.
×: Strong sense of resistance to the extent that it cannot be worsted, or strong sense of resistance to worsted,
When worsted, the water-absorbent resin particles after worsting are markedly damaged.

6) Water retention capacity (1) A required amount of physiological saline (0.9% by weight aqueous sodium chloride solution) was prepared in advance.
(2) The ratio between the binding fiber and the water-absorbent resin in the water-absorbent resin composite is determined by the same method as in the above 3.3) so that the weight of the water-absorbent resin in the water-absorbent resin composite becomes about 1 g. The water-absorbent resin composite was collected and its weight (W1) was measured. The weight (W2) of the fiber in the water-absorbent resin composite was calculated from the ratio of the water-absorbent resin to the fiber.
(3) The water-absorbent resin composite was placed in a 250-mesh nylon bag (20 cm × 10 cm) and immersed in 500 ml of room temperature saline for 30 minutes.
(4) Next, the nylon bag was pulled up, suspended for 15 minutes, drained, and then dehydrated at 90 G for 90 seconds using a centrifuge.
(5) The weight W3 of the nylon bag containing the water-absorbent resin composite after dehydration was measured.
(6) The same fibers as those used in the production are put in a 250-mesh nylon bag (20 cm × 10 cm) in the same weight as the weight (W2) contained in the composite, and the same fiber is placed in 500 ml of physiological saline at room temperature. For 30 minutes.
(7) Next, the nylon bag was pulled up, suspended for 15 minutes, drained, and then dehydrated at 90 G for 90 seconds using a centrifuge. The weight W4 of the nylon bag containing the fibers after dehydration was measured.
(8) The water retention capacity S of the physiological saline was calculated according to the following equation. Here, the units of W1 to W3 are all g.
W3-W4
Water retention capacity S = ――――――――
W1-W2

7) Water absorption capacity under pressure Water absorption capacity under pressure (AUL) is an index of the ability of a water-absorbing material to absorb a liquid when under load (see FIG. 1).
(1) The water-absorbent resin composite was collected so that the weight of the water-absorbent resin in the water-absorbent resin composite was about 0.16 g, and the weight was measured. The weight of the cylindrical tube 12 with the wire mesh 11 (wire mesh # 100, inner diameter 25.4 mmφ) was measured. These weights are referred to as the weight Sd (g) of the water-absorbent resin composite and the weight Td (g) of the cylindrical tube, respectively.
(2) 25 g of artificial urine (composition described later) was placed in a Petri dish 13 (100 mmφ).
(3) The water-absorbent resin composite was uniformly charged in a cylindrical tube with a wire mesh.
(4) A load of 14 (100 g) was placed on the water-absorbent resin composite. In addition, there must be no resistance or friction between the load 14 and the cylindrical tube 12.
(5) The cylindrical tube 12 containing the water-absorbent resin composite was gently immersed in artificial urine in a Petri dish 13 with the wire net facing down.
(6) In this state, water was absorbed for one hour.
(7) The cylindrical tube 12 was gently taken out of the petri dish 13.
(8) The cylindrical tube 12 was gently placed on the filter paper (# 424), and excess water at the bottom (wire mesh) of the cylindrical tube was wiped off.
(9) The load 14 was removed, and the water-absorbing resin attached to the load was transferred to the cylindrical tube side.
(10) The weight of the cylindrical tube 12 was measured. This weight is taken as the weight Tw (g) of the cylindrical tube after water absorption.
(11) The sample weight Sw (g) after water absorption was determined by the following calculation.
Sw = Tw- (Sd + Td)
(12) The same fiber alone used in the production of the water-absorbing composite was measured for its water absorbing capacity under pressure. That is, the operations of 1) to 11) are also performed on the used fibers, the weight of the fibers is set to Nd (g) in 2), and the fiber weight after water absorption Nw (corresponding to the water absorption of the fiber alone obtained in 11) is obtained. g) was determined.
(13) The water absorption capacity under pressure was determined by the following calculation.
Water absorption A (g) = Sw-Nw
Water absorption capacity under pressure (AUL) (g / g) = A / (Sd-Nd)

4. 2. Densified water-absorbent resin composite composition 1) Preparation of densified water-absorbent composite composition Using the weight ratio of each water-absorbent resin composite obtained in and the dry weight ratio of the binding fiber and the water-absorbent resin constituting each water-absorbent composite, the weight of the water-absorbent resin and the fiber (bonded fiber + free fiber) The water-absorbent resin composite and the free fiber were mixed so that the dry weight ratio of the water-absorbent resin became a predetermined value.
For example, the composites A, B, and C have a dry weight ratio of a, b, and c (a + b + c = 1), respectively, and the dry weight ratio of the fibers forming each composite is α, β, and γ. From [g / m ² ] and free fiber y [g / m ² ], the basis weight of the water-absorbent resin is P [g / m ² ], and the dry weight ratio between the free fiber and the water-absorbent resin is F [w / w]. When making a certain densified water-absorbent resin composite composition,
[a (1-α) + b (1-β) + c (1-γ)] x = P [g / m ² ]
When
y
――――――――――――――――――――――― ＝ F [w / w]
[a (1-α) + b (1-β) + c (1-γ)] x
X, y can be calculated if a, b, c, α, β, γ and P, F are given. However, here, P = 300 g / m ² (constant value).
The mixture was evenly spread on a stainless steel plate so as to have a size of 40 cm × 10 cm, a stainless steel plate was further laid thereon, a load of 0.6 MPa was applied from both sides, the pressure was released after standing for 20 minutes, and a high density An absorbent resin composite composition was obtained.
The densified water-absorbent resin composite composition produced by the above procedure was evaluated and measured by the following procedure.

2) Thickness The densified water-absorbent resin composite composition was cut into 5 cm × 5 cm, and the thickness of the densified absorbent resin composite composition was measured according to JIS 1-1096 (FIG. 2).
(1) An adapter 1 having a diameter of 30 mm is attached to a rheometer (a product of FUDOH, model number: NRM-2003J), and the sample table 2 rises at a speed of 2 cm / min and stops when a pressure of 0.2 psi is applied. Was set as follows.
(2) Set the sample 3 on the measuring table, raise the sample table 2 to a pressure of 0.2 psi, and use a caliper to measure the distance 4 from the upper surface of the adapter 1 to the lower surface of the sample table 2 at the stop position. Measured.
(3) Five samples were measured, and the average value was determined.
(4) The blank measurement was also performed at the same time without placing the sample on the sample stand 2.
(5) The thickness was determined from the following equation.
Thickness (mm) = sample measurement (mm)-blank measurement (mm)

3) Bulk Density The densified water-absorbent resin composite composition was cut into 5 cm × 5 cm, the weight was measured, and the bulk density was determined from the following formula. Five samples were measured, and the average value was determined.
Sample weight (g)
Bulk density (g / cm ³ ) = ――――――――――――――――――――――
Sample thickness (cm) X sample area (cm ² )

4) Rigid-softness The high-density water-absorbent resin composite composition is cut into 2 cm × 25 cm, stored at a temperature of 25 ° C. and a humidity of 50 ° C. for 24 hours, and then used for a relatively soft fabric of JIS L-1096 shown in FIG. Rigidity was measured using the loop method.
(1) A sample piece 52 was attached to a grip 51 of a horizontal bar shown in FIG. 3 in the form of a heart loop so that the effective length of the sample piece was 20 cm.
(2) After one minute, the distance L (cm) between the top of the horizontal bar and the lowest point of the loop was measured. Here, L is defined as rigidity. Five samples were measured, and the average value was determined.

5) Restoration rate The high-density water-absorbent resin composite composition is cut into 5 cm × 5 cm, and compressed at 10 MPa for 10 minutes. 4.2) Based on the thickness measurement method, immediately after compression and at a temperature of 25 ° C., humidity The thickness after storage at 50 ° C. for 30 days was measured and calculated by the following equation. Five samples were measured, and the average value was determined.
Thickness 30 days after compression-Thickness immediately after compression (mm)
Restoration rate (%) = ―――――――――――――――――――――― X 100
Thickness immediately after compression (mm)

5. Absorbent articles (production of water absorbent articles)
Using the densified water-absorbent resin composite composition, a diaper as a water-absorbent article was produced by the following procedure.
(1) On a water-impermeable polyethylene sheet (basis weight 18 g / m ² ) 21, a tissue 22 (basis weight 14 g / m ² ) and a densified water-absorbent resin composite composition 24 (water-absorbent resin 300 g / m ² ) m ² and a size of 10 cm × 40 cm), a tissue 25 (basis weight 14 g / m ² ), and a water-permeable polyester fiber nonwoven fabric 26 (basis weight 23 g / m ² ) in this order as shown in FIG. From above, a pressure of 0.6 MPa was applied thereto, left for 20 minutes, and adhered.
(2) The pressure was released, and four sides of the water-absorbent article were thermocompressed.
(3) The outer end of the pressure-bonded portion was cut out to produce a water-absorbent article of about 10 cm × about 40 cm.
The absorbent article produced by the above procedure was measured and evaluated by the following procedure.

1) Desorption rate of water-absorbent resin (1) A water-absorbent article was cut into a size of 10 cm × 10 cm (open on all four sides), and the weight was measured. The total amount of the water-absorbent resin was determined from the weight ratio of the water-absorbent resin in the water-absorbent resin composite. A water-absorbent article cut into a standard mesh screen defined by JISZ8801 (inner frame size: inner diameter 150 mm, depth 45 mm, 20 mesh) was fixed in the center with a tape.
(2) A low-tapping type shaking machine model SS-S-228 manufactured by Tokyo Shinohara Seisakusho Co., Ltd. was prepared, and the water-absorbent article was fixed only to the uppermost stage in the JIS Z8815 (FIG. 5).
(3) The number of impulses was set to 165 times / minute and the number of rotations was 290 times / minute. The weight of the water-absorbent resin particles detached from the water-absorbent article after 60 minutes of shaking was measured, and the drop-off rate was obtained from the following equation.
Amount of water-absorbent resin dropped (g)
Water-absorbent resin falling-off rate (%) = ――――――――――――――― X 100
Total amount of water-absorbing resin before shaking (g)

2) Gel detachment rate When the force acting to rub the water-absorbent article was repeatedly applied, the amount of the water-absorbent gel falling off the water-absorbent article was measured by the following procedure.
(1) A water-absorbent article 31 is placed on a surface smooth table, and a cylinder 32 having an inner diameter of 40 mm and having an open top is attached at the center, and seven parts having a diameter of 5 mm are penetrated in a portion surrounded by the cylinder 32. An acrylic plate 34 (100 × 100 × 10 mm, total weight 150 g) in which holes 33 are provided at substantially equal intervals was placed as shown in FIG.
(2) 150 ml of artificial urine (composition described later) was placed in a cylinder, and the water-absorbent article absorbed water.
(3) After complete water absorption, the sample was allowed to stand at room temperature for 30 minutes, and as shown in FIG. The weight of the cut portion was measured.
(4) After the measurement, the sample was placed on the center of a 20 cm × 20 cm acrylic plate. A load (3 kg) having a bottom area (10 cm × 10 cm) of the same size as the cut sample was placed so as not to protrude according to the shape.
(5) The integrated sample was set so that the cut side of the sample was perpendicular to the moving direction of the shaking machine (product of Inuchi Seieido Co., model number MS-1). The amplitude was 50 mm and the frequency was 80 times / min. Shake for 30 minutes.
(6) The load was removed after shaking, the weight of the water-absorbing gel dropped from the sample was measured, and the gel dropping rate was calculated using the following equation.
Extruded gel amount (g)
Gel shedding rate (%) = ―――――――――――――――― X 100
Total gel amount before extrusion (g)

6. Others 5.1) The artificial urine having the following composition was used for the measurement of the water absorption rate and the amount of discharged water, and for 5.2) the measurement of the gel shedding rate.
Urea 1.94% by weight
0.80% by weight of sodium chloride
0.06% by weight of calcium chloride
Magnesium sulfate 0.11% by weight
97.09% by weight of distilled water

  Hereinafter, features of the present invention will be described more specifically with reference to Examples, Comparative Examples, and Test Examples. The materials, usage amounts, ratios, processing contents, processing procedures, and the like shown in the following specific examples can be appropriately changed without departing from the spirit of the present invention. Therefore, the scope of the present invention should not be construed as being limited by the specific examples described below.

Example 1
133.3 parts by weight of a 25% by weight aqueous sodium hydroxide solution and 3.3 parts by weight of distilled water are added to 100 parts by weight of acrylic acid, and a partially neutralized acrylic acid aqueous solution having a monomer concentration of 50% by weight and a degree of neutralization of 60 mol% is added. Was prepared. To 100 parts by weight of the partially neutralized acrylic acid aqueous solution, 0.14 parts by weight of N, N'-methylenebisacrylamide as a crosslinking agent and 4.55 parts by weight of a 31% by weight aqueous hydrogen peroxide solution as an oxidizing agent were added. Solution A was prepared.

  Separately, 0.14 parts by weight of N, N'-methylenebisacrylamide as a crosslinking agent and 0.57 parts by weight of L-ascorbic acid as a reducing agent are added to 100 parts by weight of the partially neutralized acrylic acid aqueous solution. Solution B was prepared.

The prepared solution A and solution B were mixed using the nozzle shown in FIG. The inner diameter of the nozzle in FIG. 8 is 0.13 mm, and five nozzles for each solution are arranged at intervals of 1 cm. The intersection angle between the solution A and the solution B flowing out of the nozzle was adjusted to 30 degrees, and the distance at the tip of the nozzle was adjusted to 4 mm. The solution A and the solution B were heated at a liquid temperature of 40 ° C., respectively, and supplied by a pump so that the flow rate was 5 m / sec.
The solution A and the solution B join at the exit of each nozzle pair, form a liquid column of about 10 mm each, and form droplets in the gas phase (in air, at a temperature of 50 ° C). The space density of the droplets in the reactor, which was estimated from the space capacity of the reactor, the amount of the supplied monomer, and the falling speed of the droplets, was 2 g / m ³ .

On the other hand, the fibers opened from the supply ports located 0.8 m and 1.6 m below the tip of the nozzle were supplied in a multiphase flow with air (fiber: air = 1: 100). At that time, the temperature of the air in the multiphase flow was room temperature, and the linear velocity was 10 m / sec. The polymerization rates at 0.8 m and 1.6 m below the tip of the nozzle were 15% and 40%, respectively. The fibers used were pulp having a fiber diameter of 2.2 decitex, a length of 2.5 mm, and a water contact angle of 0 °. The feed rates were 11.5 g / min each. The spatial density of the fibers in the reaction field, which was estimated from the space capacity of the reaction field, the fiber supply amount, and the falling speed of the fibers, was 8 g / m ³ .
The droplets collided with the fibers in the gas phase to form a water-absorbent resin composite precursor, and were collected as deposits on a belt conveyor whose transporting portion, which was set 3 m below the tip of the nozzle, was a mesh belt. The lower part of the mesh was controlled by suction using a blower so that the pressure difference between the upper and lower parts of the mesh became 1,000 Pa. Further, the recovered material was dried and sieved to remove free fibers that did not bind to the water-absorbent resin, to obtain a product comprising the water-absorbent resin and the fibers.

  When this product was observed with a microscope, the resin particles were substantially spherical, and were a water-absorbent resin composite containing one water-absorbent resin particle and two or more fibers. In at least one of the fibers, a part of the fibers is embedded in the resin particles and a part of the fibers is exposed from the resin particles, and at least one of the two or more fibers has the fiber It was confirmed that the composite was a water-absorbing composite having a structure in which a part of the fiber was bonded to the surface of the resin particle without being embedded in the resin particle. (Schematic diagram in FIG. 9, photographs 101 and 102)

Example 2
Manufactured in the same manner as in Example 1 except that polyethylene terephthalate (PET) having a fiber diameter of 1.7 decitex, a length of 0.9 mm, and a water contact angle of 80 ° was used instead of the pulp used as the fiber. Then, a product was obtained. The product was confirmed to be a water-absorbent resin composite having the same structure as in Example 1. (Photos 103 and 104 in FIG. 10)

Example 3
Instead of the pulp used as the fiber, the same procedure as in Example 1 was repeated except that nylon having a fiber diameter of 1.7 and a length of 0.9 mm and a water contact angle of 50 ° was used. Got. The product was confirmed to be a water-absorbent resin composite having the same structure as in Example 1. (Photos 105 and 106 in FIG. 11)

Example 4
Instead of the pulp used as the fiber, nylon having a fiber diameter of 1.7 decitex, a length of 0.9 mm and a contact angle of water of 50 ° with the same fiber diameter and length as water, Production was carried out in the same manner as in Example 1 except that a fiber mixture having a weight ratio of 1: 1 to rayon having an angle of 0 ° was used to obtain a product. The product was confirmed to be a water-absorbent resin composite having the same structure as in Example 1. (Photos 107 and 108 in FIG. 12)

Example 5
Example 1 was repeated except that the pulp used as the fiber was polytetrafluoroethylene (PTFE) having a fiber diameter of 1.7 decitex, a length of 0.9 mm, and a water contact angle of 108 °. It was manufactured in the same manner to obtain a product. The product was confirmed to be a water-absorbent resin composite having the same structure as in Example 1.

Comparative Example 1
The product was produced in the same manner as in Example 1 except that the fiber was supplied only from the fiber supply port located 0.8 m below the tip of the nozzle, to obtain a product. Observation of this product with a microscope revealed that it was a composition comprising the following two types of water-absorbent resin composites.
(1) A water-absorbing composite having the same structure as in Example 1 (2) A substantially spherical water-absorbing resin composite containing one water-absorbing resin particle and one or more fibers, A part of the fibers is embedded in the resin particles and a part of the fibers is exposed from the resin particles, and none of the fibers adheres to the surface of the resin particles. Resin composite (schematic in FIG. 13, photo 109
And 110)
As a result of observation with a microscope, the ratio of (1) in the whole was 0.3.

Comparative Example 2
The product was produced in the same manner as in Example 1 except that the fiber was supplied only from the fiber supply port located 1.6 m below the tip of the nozzle, to obtain a product. Observation of this product with a microscope revealed that it was a composition comprising the following two types of water-absorbent resin composites.
(1) A water-absorbing composite having the same structure as in Example 1 (2) A substantially spherical water-absorbing resin composite containing one water-absorbing resin particle and one or more fibers, As for the fibers, a part of the fibers is adhered to the surface of the resin particles, and none of the fibers is embedded in the resin particles (a schematic diagram in FIG. 14, photograph 111 and FIG. 112)
As a result of observation with a microscope, the ratio of (1) in the whole was 0.2.

Comparative Example 3
The following experiment was conducted based on the example of JP-A-63-63723.
45.0 g of acrylic acid and 1.5 g of distilled water were weighed into a 200 ml beaker, and neutralized with 60.0 g of a 25% aqueous sodium hydroxide solution under cooling at 35 ° C. or less to obtain a partially neutralized acrylic acid aqueous solution ( Monomer concentration 50% by weight, degree of neutralization 60 mol%). 41.9 mg of N, N'-methylenebisacrylamide and 0.31 g of L-ascorbic acid were dissolved. A hole was made in the top sheet of a 300 ml stainless steel beaker whose top face was completely sealed with a polyester sheet, and the inside of the system was sufficiently purged with nitrogen through a rubber tube. After pouring the mixed monomer aqueous solution into the stainless steel beaker, the stainless steel beaker was immersed in a bath temperature of 50 ° C., and 0.84 g of a 30% hydrogen peroxide solution was added thereto with stirring to carry out polymerization. After about 1 minute, the maximum temperature was 110 ° C. Thereafter, the substrate was kept in a warm bath at 50 ° C. for 2 hours and then cooled to 20 ° C. to obtain a water-containing water-absorbent resin. After kneading 70 g of this water-absorbent resin (35 g of water-absorbent resin), 200 g of water and 10 g of the opened pulp same as that used in Example 1 for about 2 hours using a screw rotary mixer, the mixture was heated at 100 ° C. It dried with a reduced pressure drier for 8 hours. Thereafter, the mixture was pulverized with a rotary blade type pulverizer and further sieved to remove free fibers to obtain a water-absorbing composite composition.
When this product was observed with a microscope, a structure in which a part of the fiber was embedded in the water-absorbent resin was confirmed. However, no structure was found in which the fibers were not embedded in the resin particles and some of the fibers were adhered to the surfaces of the resin particles. (Schematic in FIG. 15, photographs 113 and 114)

Comparative Example 4
The following experiment was performed based on the example of JP-A-11-93073.
125 parts by weight of an 80% by weight aqueous acrylic acid solution and 133 parts by weight of a 30% by weight aqueous sodium hydroxide solution were mixed to obtain a partially neutralized acrylic acid aqueous solution having a degree of neutralization of 72 mol% and a concentration of 47% by weight. To the aqueous solution of partially neutralized acrylic acid, 0.04 part by weight of a crosslinking agent N, N'-methylenebisacrylamide and 0.3 part by weight of an initiator 2,2'-azobis (2-amidinopropane) dihydrochloride were added. A solution dissolved in 13 parts by weight of distilled water was added thereto, followed by degassing with nitrogen to obtain an aqueous monomer solution.
A one-component spray nozzle was used in place of the nozzle of Example 1, the solution temperature was maintained at 25 ° C., and the solution was supplied by a pump at a flow rate of 40 ml / min.
The monomer solution was dropped in the gas phase (in air, at a temperature of 25 ° C.) as droplets while the polymerization proceeded. The spatial density of the droplets in the reactor, which was estimated from the space capacity of the reactor, the amount of the supplied monomer, and the falling speed of the droplets, was 3 g / m ³ .

On the other hand, the fiber opened from a supply port located 0.8 m below the tip of the nozzle was supplied in a multiphase flow with air (fiber: air = 1: 100). At that time, the temperature of the air in the multiphase flow was 25 ° C., and the linear velocity was 10 m / sec. Further, the polymerization rate of 0.8 m below the tip of the nozzle was less than 1%. The fiber used was a polyethylene terephthalate (PET) having a fiber diameter of 1.7 dtex, a length of 0.9 mm, and a water contact angle of 80 °. The feed rate was 11.5 g / min. The spatial density of the fibers in the reaction field, which was estimated from the space capacity of the reaction field, the fiber supply amount, and the falling speed of the fibers, was 8 g / m ³ .
The droplets collided with the fibers in the gas phase to form a water-absorbent resin composite precursor, and the transport portion set 3 m below the tip of the nozzle was collected as a deposit on a belt conveyor which was a mesh belt. In addition, it controlled so that the pressure difference of the upper and lower sides of a mesh might be set to 1,000 Pa by sucking under a mesh with a blower. Further, the collected product was placed in an oven at 80 ° C., and polymerization of the attached monomer aqueous solution was performed for 30 minutes. Thereafter, hot air treatment was performed at 140 ° C. to obtain a water-absorbent resin composite.
Further, the collected material was sieved to remove free fibers, but the water-absorbing resin was also used as an adhesive between the fibers, and there was virtually no free fibers. Thus, a product comprising the water absorbent resin and the fiber was obtained.
When this product was observed with a microscope, a structure in which a part of the fiber was adhered to the surface of the resin particles was confirmed. However, no structure was found in which a part of the fibers was embedded in the water-absorbing resin. (Schematic in FIG. 16, photos 115 and 116)

Test Examples Regarding the water-absorbent resin composites and the aggregates thereof produced in Examples 1 to 5 and Comparative Examples 1 to 4, the morphological observation, the average particle diameter of the water-absorbent resin, the fibers in the composite A and the water-absorbent resin The dry weight ratio, openability, water retention capacity, and water absorption capacity under pressure were measured.
Further, using the water-absorbent resin composites produced in Examples 1 to 5 and Comparative Examples 1 to 4, a water-absorbent resin composite composition was prepared, and before each densification treatment, each composite and free fibers were prepared. The weight ratio and the dry weight ratio between the free fiber and the water absorbent resin were measured. It was considered that this ratio was not changed by the subsequent consolidation treatment. Further, for the densified water-absorbent resin composite composition obtained by the consolidation treatment of the water-absorbent resin composite composition, the thickness, bulk density, rigidity, and restoration rate were measured.
Further, an absorbent article was produced using the densified water-absorbent resin composite composition, and the water-absorbent resin detachment rate and the gel detachment rate were measured.
Table 1 summarizes the measurement and evaluation results.
In addition, when the water-absorbent resin composites of Comparative Examples 3 and 4 were opened, crushed portions were generated.

  The water-absorbent resin composite and its composition produced by the method of the present invention are suitably used as industrial materials such as sanitary materials such as disposable diapers and sanitary napkins and other water-absorbent articles. Particularly, the water-absorbent resin composite and the composition thereof produced by the method of the present invention include JP-A-63-267370, JP-A-63-10667, JP-A-63-295251, and JP-A-63-295251. JP-A-63-270801, JP-A-63-294716, JP-A-64-64602, JP-A-1-231940, JP-A-1-243927, JP-A-2-30522, The technique used for the sheet-shaped water-absorbing material proposed in Japanese Unexamined Patent Publication No. Hei 2-153731, Japanese Unexamined Patent Application Publication No. 3-213385, Japanese Unexamined Patent Application Publication No. Hei 4-133728, Japanese Unexamined Patent Application Publication No. It can also be used accordingly.

It is a cross-sectional view for demonstrating the water absorption capacity measuring instrument under pressure. It is a cross-sectional view for explaining a thickness measuring tool. It is the schematic for demonstrating the jig | tool which measures the rigidity by the heart loop method. FIG. 2 is a cross-sectional view illustrating a configuration of a water absorbent article. It is the schematic which shows a low tap type shaker. It is a cross-sectional view for explaining the jig which measures a gel falling rate. It is a figure which shows the cutting line of a sample in a gel falling rate measurement. It is the schematic diagram for explaining the nozzle used for producing a water-absorbent resin composite. 1 is a schematic diagram of a sample obtained in Example 1, and a scanning electron micrograph (101 and 102). 9 is scanning electron micrographs (103 and 104) of the sample obtained in Example 2. 9 is a scanning electron micrograph (105 and 106) of the sample obtained in Example 3. 9 is scanning electron micrographs (107 and 108) of the sample obtained in Example 4. 5 is a schematic diagram of a sample obtained in Comparative Example 1, and a scanning electron micrograph (109 and 110). 5 is a schematic diagram of a sample obtained in Comparative Example 2, and scanning electron micrographs (111 and 112). 5 is a schematic diagram of a sample obtained in Comparative Example 3, and scanning electron micrographs (113 and 114). 9 is a schematic diagram of a sample obtained in Comparative Example 4, and scanning electron micrographs (115 and 116).

Explanation of reference numerals

DESCRIPTION OF SYMBOLS 1 Adapter 2 Sample stand 3 Sample 4 Distance 11 Wire mesh 12 Cylindrical tube 13 Petri dish 14 Load 21 Water-impermeable polyethylene sheet 22 Tissue 24 Densified water-absorbent resin composite composition 25 Tissue 26 Water-permeable polyester fiber nonwoven fabric 31 Water absorption Article 32 Cylinder 33 Through hole 34 Acrylic plate 41 Center 42 Cutting line 51 Grab 52 Sample piece

Claims (17)

A method for producing a water-absorbent resin composite containing one water-absorbent resin particle and two or more fibers in a reactor from a polymerizable monomer and a fiber that forms a water-absorbent polymer by polymerization,
In the water-absorbent resin composite, the water-absorbent resin particles are substantially spherical, and at least one of the two or more fibers has a part of the fibers embedded in the resin particles and a part thereof. Exposed from the resin particles, and one or more of the two or more fibers are not embedded in the resin particles, some of the fibers on the surface of the resin particles Glued,
The method comprises contacting a droplet containing the polymerizable monomer and a solvent before and / or during polymerization with a first fiber supplied from a first supply port of the reactor in a gas phase, The polymerization of the polymerizable monomer is allowed to proceed, and then a droplet containing the polymerizable monomer, solvent, and fiber being polymerized is brought into contact with a second fiber supplied from a second supply port of the reactor in a gas phase. And a process for producing the water-absorbent resin composite by further promoting the polymerization of the polymerizable monomer. The method for producing a water-absorbent resin composite according to claim 1, wherein the first supply port is provided at a position higher than the second supply port in the reactor. The method for producing a water-absorbent resin composite according to claim 1, wherein a monomer conversion rate in the droplet at the time of contact with the first fiber is 0 to 80%. The method for producing a water-absorbent resin composite according to any one of claims 1 to 3, wherein a monomer conversion rate in the droplet at the time of contact with the second fiber is 10 to 90%. The monomer conversion in the droplet at the time of contact with the first fiber is 10 to 80% higher than the monomer conversion in the droplet at the time of contact with the second fiber. A method for producing the water-absorbent resin composite according to claim 1. The method for producing a water-absorbent resin composite according to any one of claims 1 to 5, wherein the droplets have a particle size of 50 to 1,000 m. The method for producing a water-absorbent resin composite according to any one of claims 1 to 6, wherein the average fiber length of the fibers is 50 to 50,000 µm. The method for producing a water-absorbent resin composite according to any one of claims 1 to 7, wherein the average fiber diameter of the fibers is 0.1 to 500 decitex. The method for producing a water-absorbent resin composite according to any one of claims 1 to 8, wherein the polymerizable monomer gives a partially neutralized acrylic acid polymer crosslinked body after the polymerization. The method for producing a water-absorbent resin composite according to any one of claims 1 to 9, wherein the fibers are supplied into the reactor as a multiphase flow with air. Method for producing a water-absorbent resin composite according to claim 10 spatial density of the fibers is 0.005~1,000g / m ³ in the reactor. Method for producing a water-absorbent resin composite according to claim 10 or 11 spatial density of the droplets within the reactor is a 0.1~10,000g / m ^3. The water absorption according to claim 10, wherein the droplets and the fibers are continuously supplied into the reactor, and the produced water-absorbent resin composite is continuously extracted from the reactor. Method for producing conductive resin composite. A method for producing a deposit of a water-absorbent resin composite, comprising a step of depositing the water-absorbent resin composite obtained by the method according to any one of claims 1 to 13 to produce a deposit. The method according to claim 14, wherein the water-absorbent resin composite is deposited in a reactor, and the obtained deposit is extracted from the reactor. The method for producing a deposit of a water-absorbent resin composite according to claim 14, wherein the water-absorbent resin composite is deposited on the mesh by sucking air from below the mesh provided at the bottom of the reactor. The method according to claim 16, wherein the pressure difference between the upper and lower portions of the mesh is 100 to 10,000 Pa.